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Primary deposition and early diagenetic effects on the high saturation accumulation of gas hydrate in a silt dominated reservoir in the Gulf of Mexico

On continental margins, high saturation gas hydrate systems (>60% pore volume) are common in canyon and channel environments within the gas hydrate stability zone, where reservoirs are dominated by coarse-grained, high porosity sand deposits. Recent studies, including the results presented here, suggest that rapidly deposited, silt-dominated channel-levee environments can also host high saturation gas hydrate accumulations. Here we present several sedimentological data sets, including sediment composition, biostratigraphic age from calcareous nannofossils, grain size, total organic carbon (TOC), C/N elemental ratio, δ 13 C-TOC , CaCO 3 , total sulfur (TS), and δ 34 S-TS from sediments collected with pressure cores from a gas hydrate rich, turbidite channel-levee system in the Gulf of Mexico during the 2017 UT-GOM2-1 Hydrate Pressure Coring Expedition. Our results indicate the reservoir is composed of three main lithofacies, which have distinct sediment grain size distributions (type A-silty clay to clayey silt, type B-clayey silt, and type C-sandy silt to silty sand) that are characteristic of variable turbidity current energy regimes within a Pleistocene (< 0.91 Ma) channel-levee environment. We document that the TOC in the sediments of the reservoir is terrestrial in origin and contained within the fine fraction of each lithofacies, while the CaCO 3 fraction is composed of primarily reworked grains, including Cretaceous calcareous nannofossils, and part of the detrital load. The lack of biogenic grains within the finest grained sediment intervals throughout the reservoir suggests interevent hemipelagic sediments are not preserved, resulting in a reservoir sequence of silt dominated, stacked turbidites. We observe two zones of enhanced TS at the top and bottom of the reservoir that correspond with enriched bulk sediment δ 34 S, indicating stalled or slowly advancing paleo-sulfate-methane transition zone (SMTZ) positions likely driven by relative decreases in sedimentation rate. Despite these two diagenetic zones, the low abundance of diagenetic precipitates throughout the reservoir allowed the primary porosity to remain largely intact, thus better preserving primary porosity for subsequent pore-filling gas hydrate. In canyon, channel, and levee environments, early diagenesis may be regulated via sedimentation rates, where high rates result in rapid progression through the SMTZ and minimal diagenetic mineralization and low rates result in the stalling of the SMTZ, enhancing diagenetic mineralization. Here, we observed some enhanced pyritization to implicate potential sedimentation rate changes, but not enough to consume primary porosity, resulting in a high saturation gas hydrate reservoir. These results emphasize the important implications of sedimentary processes, sedimentation rates, and early diagenesis on the distribution of gas hydrate in marine sediments along continental margins.

Alabama, Louisiana, Mississippi↗

Sources, instream transport, and trends of nitrogen, phosphorus, and sediment in the lower Tennessee River basin, 1980-96

In 1997, the U.S. Geological Survey (USGS) began an assessment of the lower Tennessee River Basin as part of the National Water-Quality Assessment Program. Existing nutrient and sediment data from 1980 to 1996 were compiled, screened, and interpreted to estimate watershed inputs from nutrient sources, provide a general description of the distribution and transport of nutrients and sediments in surface water, and evaluate trends in nutrient and sediment concentrations in the lower Tennessee (LTEN) River Basin. Nitrogen inputs from major sources varied widely among tributary basins in the LTEN River Basin. Point source wastewater discharges contributed between 0 and 0.61 tons per square mile per year [(tons/mi 2 )/yr]. Of the nonpoint sources of nitrogen for which inputs were estimated (atmospheric deposition, nitrogen fixation, fertilizer application, and livestock waste) livestock waste contributed the largest input in about two-thirds (7 out of 11) of the tributary basins, and fertilizer application contributed the largest input in the remaining 4 basins. Nitrogen input from fertilizer application was the most variable spatially among the nonpoint sources of nitrogen, ranging from 1.5 to 23 (tons/mi 2 )/yr. Atmospheric deposition estimates varied the least from basin to basin, ranging from 1.6 to 2.0 (tons/mi 2 )/yr. Estimates of nitrogen input from livestock waste ranged between 2.0 to 13 (tons/mi 2 )/yr. The percentage of the input from each of these nonpoint sources that entered the surface-water system is not known. Wastewater discharge contributed between 0 and 0.14 (ton/mi 2 )/yr of phosphorus to tributary basins. Livestock waste contributed most of the input in 8 out of the 11 basins, and fertilizer application contributed the most in the remaining 3 basins. Estimates of phosphorus input for fertilizer application ranged from 0.35 to 5.1 (tons/mi 2 )/yr and from 0.62 to 4.3 (tons/mi 2 )/yr from livestock waste. Reservoirs on the main stem of the Tennessee River and on the Duck and Elk Rivers affect nutrient transport because hydrodynamic conditions in the reservoirs promote assimilation by aquatic plants and deposition of particulate matter. Observed decreases in total nitrite plus nitrate and dissolved-orthophosphorus concentrations in reservoirs or at sites downstream of reservoirs during summer months were probably related to seasonality of plant growth. Nutrient and sediment data used to estimate annual instream loads and yields were compiled from various water-quality monitoring programs and represent the best available data in the LTEN River Basin, but these data have several characteristics that limit accuracy of load estimates. Many of the monitoring programs were not designed with the objective of annual load estimation, and data representing storm transport are, therefore, sparse; sampling and analytical methods varied through time and among the monitoring programs, hampering spatial and temporal comparisons. The load estimates computed from these data are useful for evaluating broad spatial patterns of instream load, and comparisons of instream load to inputs, but may not be sufficiently accurate for local-scale evaluations of water quality. Estimates of the mean annual instream load of total nitrogen entering (Chattanooga, Tenn.) and leaving (Paducah, Ky.) the LTEN River Basin were 29,000 and 60,000 tons per year (tons/yr), respectively. These estimates represent a gain of 31,000 tons/yr, on average, across the area (18,930 mi 2 ) between these inlet and outlet sites. The sum of the mean annual instream load from gaged tributaries to the main stem within the study unit was 14,000 tons/yr; however, this number cannot be directly compared with the gain between the inlet and outlet sites because (1) the gaged area represents only 30 percent of the total area and (2) the period of record at many tributary sites did not correspond with the period of record at the inlet or outlet sites. Estimates of mean annual instream load of total phosphorus at the inlet and outlet sites of the LTEN River Basin were 1,300 and 5,000 tons/yr, respectively, representing a gain of 3,700 tons/yr, on average, across the study unit. The sum of the gaged tributary load, representing only 28 percent of the area contributing to the main stem, was 4,300 tons/yr. Although this number cannot be closely compared with the gain throughout the study unit, for the same reasons given for total nitrogen, a general comparison suggests that the main stem of the Tennessee River and the tributary embayments along the main stem function as a sink for total phosphorus, removing a substantial amount from the water column through deposition or assimilation. The estimates of inputs can be compared and correlated with yields (area-normalized instream loads); significant correlations between estimates of inputs and yields might be useful as predictive tools for instream water quality where monitoring data are not available. Yields of nitrogen correlated moderately well with inputs from nonpoint sources, based on 1992 estimates. Nitrogen yield was highest [3.5 (tons/mi 2 )/yr] for Town Creek, for which the balance of nonpoint-source inputs to agricultural lands (fertilizer application plus nitrogen fixation plus livestock waste minus harvest) was also the highest [15 (tons/mi 2 )/yr]. Nitrogen yield was low [1.0 (tons/mi 2 )/yr] for the Buffalo River, for which the balance of agricultural nonpoint-source input was correspondingly low [3.2 (tons/mi 2 )/yr, the second lowest]. Correlation of wastewater discharge with yield was poor, and contrasted with the significant correlation between wastewater discharge and median nitrogen concentration during low streamflow. The poor correlation between wastewater discharge and annual yield was expected, however, as wastewater discharge is a small fraction compared with annual yield. In contrast with nitrogen, phosphorus yield did not correlate well with any estimated inputs or land-use types for the tributary basins. Phosphorus yield was highest [1.1 and 0.93 (tons/mi 2 )/yr] at two sites along the Duck River and at Elk River near Prospect [0.89 (ton/mi 2 )/yr]; however, estimates of inputs at these sites were in the middle of their respective ranges. The influence of the outcrop of phosphatic limestone formations of the brown-phosphate districts in the lower Duck and lower Elk River Basins might be responsible for the poor correlation between estimated inputs and yields of phosphorus. The outcrop pattern of these phosphatic limestones are an important factor to consider as regional boundaries are established for attainable, region-specific water-quality criteria for total phosphorus. Estimates of sediment input from cropland soil erosion in 1992 ranged from 51 to 540 (tons/mi 2 )/yr among the major hydrologic units in the LTEN River Basin. Information was not available to estimate this input for individual tributaries. Sediment yield estimates ranged from 65 to 263 (tons/mi 2 )/yr for the three tributary monitoring basins for which instream data were available, and from 17 to 26 (tons/mi 2 )/yr for the Tennessee River at South Pittsburg and at Pickwick Landing Dam, respectively. Lower sediment yields for the main stem sites compared with the tributary sites is probably due to sediment deposition in the main stem of the Tennessee River and tributary embayments along the main stem. Most of the significant trends in nutrient concentrations from about 1985 to about 1995 were decreasing trends, except for total nitrite plus nitrate, which increased at one site on the Elk River. The spatial distribution of decreasing trends of total nitrogen and total ammonia corresponds with the spatial variation among basins in wastewater loading rate. The time period of observed trends corresponds to the period of improvements in municipal treatment, thus decreases in wastewater effluent concentrations of nitrogen might be responsible for the decreasing trend in instream concentrations at these sites. Concentrations of total phosphorus did not decrease during this period at these sites, as might have been expected considering the reductions in wastewater input of phosphorus during this period.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗

Detrital zircon geochronology of Cretaceous and Paleogene strata across the south-central Alaskan convergent margin

Ages of detrital zircons are reported from ten samples of Lower Cretaceous to Paleogene metasandstones and sandstones from the Chugach Mountains, Talkeetna Mountains, and western Alaska Range of south-central Alaska. Zircon ages are also reported from three igneous clasts from two conglomerates. The results bear on the regional geology, stratigraphy, tectonics, and mineral resource potential of the southern Alaska convergent margin. Chugach Mountains - The first detrital zircon data are reported here from the two main components of the Chugach accretionary complex - the inboard McHugh Complex and the outboard Valdez Group. Detrital zircons from sandstone and two conglomerate clasts of diorite were dated from the McHugh Complex near Anchorage. This now stands as the youngest known part of the McHugh Complex, with an inferred Turonian (Late Cretaceous) depositional age no older than 91-93 Ma. The zircon population has probability density peaks at 93 and 104 Ma and a smattering of Early Cretaceous and Jurassic grains, with nothing older than 191 Ma. The two diorite clasts yielded Jurassic U-Pb zircon ages of 179 and 181 Ma. Together, these findings suggest a Mesozoic arc as primary zircon source, the closest and most likely candidate being the Wrangellia composite terrane. The detrital zircon sample from the Valdez Group contains zircons as young as 69 and 77 Ma, consistent with the previously assigned Maastrichtian to Campanian (Late Cretaceous) depositional age. The zircon population has peaks at 78, 91, 148, and 163 Ma, minor peaks at 129, 177, 330, and 352 Ma, and no concordant zircons older than Devonian. A granite clast from a Valdez Group conglomerate yielded a Triassic U-Pb zircon age of 221 Ma. Like the McHugh Complex, the Valdez Group appears to have been derived almost entirely from Mesozoic arc sources, but a few Precambrian zircons are also present. Talkeetna Mountains - Detrital zircons ages were obtained from southernmost metasedimentary rocks of the Talkeetna Mountains (schist of Hatcher Pass) and, immediately to the south, the northernmost sedimentary sequence of the Matanuska forearc basin (Arkose Ridge Formation). Detrital zircons from the Paleogene Arkose Ridge Formation are as young as 61 and 70 Ma; the population is dominated by a single Late Cretaceous peak at 76 Ma; the oldest zircon is 181 Ma. Sedimentological evidence clearly shows that the conglomeratic Arkose Ridge Formation was derived from the Talkeetna Mountains; our detrital zircon data support this inference. Zircons dated at ca. 90 Ma in the Arkose Ridge sample suggest that buried or unmapped plutons of this age may exist in the Talkeetnas. This is a particularly interesting age as it corresponds to the age of the supergiant Pebble gold-molybdenum-copper porphyry prospect near Iliamna and suggests a new area of prospectivity for Pebble-type deposits. The schist of Hatcher Pass, which was previously assigned a Jurassic depositional age, yielded surprisingly young Late Cretaceous detrital zircons, the youngest at 75 Ma. The probability density curve has four Cretaceous peaks from 76 to 102 Ma, a pair of Late Jurassic peaks at 155 and 166 Ma, three Early Jurassic to Late Triassic peaks at 186, 197, and 213 Ma, minor Carboniferous peaks at 303 and 346 Ma, and a minor Paleoproterozoic peak at 1828 Ma. The schist of Hatcher Pass was largely derived from Mesozoic arc sources, most likely the Wrangellia composite terrane, with some contribution from one or more older, inboard sources, probably including the Yukon-Tanana terrane. We postulate that the schist of Hatcher Pass represents metamorphosed rocks of the Valdez Group that were subducted and then exhumed along the Chugach terrane's 'backstop' during Paleogene transtension. Western Alaska Range - Six detrital zircon samples were collected from a little studied belt of turbidites in Tyonek quadrangle on strike with the Kahiltna assemblage of the central Alaska Range.

Alaska↗

Aeromagnetic map and interpretation of geophysical data from the Condrey Mountain Roadless Area, Siskiyou County, California

The Condrey Mountain Roadless Area lies within the Klamath Mountains geologic province, a province composed of four eastward-dipping imbricate thrust slices or belts consisting predominantly of marine arc-related volcanic and sedimentary rocks, but also including significant amounts of ultramafic and other ophiolitic rocks (Irwin, 1981). From west to east the four Klamath Mountains thrust slices are called the western Jurassic belt, the western Paleozoic and Triassic belt, the central metamorphic belt, and the eastern Klamath belt. The Condrey Mountain Road less Area is located within a structural window in the western Paleozoic and Triassic belt, a window in which the structural dome comprised of the Condrey Mountain Schist is exposed (Coleman and others, 1983). North, east and south of the roadless area, the Condrey Mountain Schist is separated from the overlying western Paleozoic and Triassic belt by a low-angle regional thrust, whereas to the west the two units are in high-angle fault contact (Coleman and others, 1983). The Condrey Mountain schist consists mainly of sedimentary and volcanic rocks metamorphosed to greenschist facies. Metasedimentary rocks are exposed over most of the eastern and central parts of the structural window. Metavolcanic rocks occupy the western part of the window but also occur in small exposures within the metasedimentary rocks and along the eastern and southern margins of the window. Tabular bodies of metaserpentinite, the largest of which crops out near White Mountain, are contained within the metasedimentary rocks. Densities of hand samples from 11 sites scattered throughout the Condrey Mountain window average 2.66&plusmn;0.05 g/cm 3 . The four samples of metavolcanic rocks yielded a higher average density than the seven samples of metasedimentary rocks (2.71&plusmn;0.04 g/cm 3 versus 2.63&plusmn;0.03 g/cm 3 ). Along the western edge of the Condrey Mountain Road less Area, numerous narrow north-trending zones of mineralized schist extend from near Copper Butte on the south, northward to Elliot Creek (Coleman and others, 1983). These zones contain abundant pyrite mineralization associated with pyrrhotite, chalcopyrite, qalena, and sphalerite. The Blue Ledge mine area, 2 mi north-northeast of Copper Butte, is located in a zone of mineralized schist. The western Paleozoic and Triassic belt that nearly surrounds the Condrey Mountain Schist is a melange of sedimentary, volcanic, and ultramafic rocks metamorphosed to amphibolite facies (Coleman and others, 1983). Only two samples of the metamorphic melange were collected near the Condrcy Mountain Road less Area, but extensive sampling of this unit southwest of the roadless area yielded an average sample density of 2.86&plusmn;0.15 g/cm 3 (112 samples) (Jachens and others, 1983).

California↗

Application of health-based screening levels to ground-water quality data in a state-scale pilot effort

A state-scale pilot effort was conducted to evaluate a Health-Based Screening Level (HBSL) approach developed for communicating findings from the U.S. Geological Survey (USGS) National Water-Quality Assessment Program in a human-health context. Many aquifers sampled by USGS are used as drinking-water sources, and water-quality conditions historically have been assessed by comparing measured contaminant concentrations to established drinking-water standards and guidelines. Because drinking-water standards and guidelines do not exist for many analyzed contaminants, HBSL values were developed collaboratively by the USGS, U.S. Environmental Protection Agency (USEPA), New Jersey Department of Environmental Protection, and Oregon Health & Science University, using USEPA toxicity values and USEPA Office of Water methodologies. The main objective of this report is to demonstrate the use of HBSL approach as a tool for communicating water-quality data in a human-health context by conducting a retrospective analysis of ground-water quality data from New Jersey. Another important objective is to provide guidance on the use and interpretation of HBSL values and other human-health benchmarks in the analyses of water-quality data in a human-health context. Ground-water samples collected during 1996-98 from 30 public-supply, 82 domestic, and 108 monitoring wells were analyzed for 97 pesticides and 85 volatile organic compounds (VOCs). The occurrence of individual pesticides and VOCs was evaluated in a human-health context by calculating Benchmark Quotients (BQs), defined as ratios of measured concentrations of regulated compounds (that is, compounds with Federal or state drinking-water standards) to Maximum Contaminant Level (MCL) values and ratios of measured concentrations of unregulated compounds to HBSL values. Contaminants were identified as being of potential human-health concern if maximum detected concentrations were within a factor of 10 of the associated MCL or HBSL (that is, maximum BQ value (BQmax) greater than or equal to 0.1) in any well type (public supply, domestic, monitoring). Most (57 of 77) pesticides and VOCs with human-health benchmarks were detected at concentrations well below these levels (BQmax less than 0.1) for all three well types; however, BQmax values ranged from 0.1 to 3,000 for 6 pesticides and 14 VOCs. Of these 20 contaminants, one pesticide (dieldrin) and three VOCs (1,2-dibromoethane, tetrachloroethylene, and trichloroethylene) both (1) were measured at concentrations that met or exceeded MCL or HBSL values, and (2) were detected in more than 10 percent of samples collected from raw ground water used as sources of drinking water (public-supply and (or) domestic wells) and, therefore, are particularly relevant to human health. The occurrence of multiple pesticides and VOCs in individual wells also was evaluated in a human-health context because at least 53 different contaminants were detected in each of the three well types. To assess the relative human-health importance of the occurrence of multiple contaminants in different wells, the BQ values for all contaminants in a given well were summed. The median ratio of the maximum BQ to the sum of all BQ values for each well ranged from 0.83 to 0.93 for all well types, indicating that the maximum BQ makes up the majority of the sum for most wells. Maximum and summed BQ values were statistically greater for individual public-supply wells than for individual domestic and monitoring wells. The HBSL approach is an effective tool for placing water-quality data in a human-health context. For 79 of the 182 compounds analyzed in this study, no USEPA drinking-water standards or guidelines exist, but new HBSL values were calculated for 39 of these 79 compounds. The new HBSL values increased the number of detected pesticides and VOCs with human-health benchmarks from 65 to 77 (of 97 detected compounds), thereby expanding the basis for interpreting contaminant-occu

Scientific Investigations Report↗

Strata-bound Fe-Co-Cu-Au-Bi-Y-REE deposits of the Idaho Cobalt Belt: Multistage hydrothermal mineralization in a magmatic-related iron oxide copper-gold system

Mineralogical and geochemical studies of strata-bound Fe-Co-Cu-Au-Bi-Y-rare-earth element (REE) deposits of the Idaho cobalt belt in east-central Idaho provide evidence of multistage epigenetic mineralization by magmatic-hydrothermal processes in an iron oxide copper-gold (IOCG) system. Deposits of the Idaho cobalt belt comprise three types: (1) strata-bound sulfide lenses in the Blackbird district, which are cobaltite and, less commonly, chalcopyrite rich with locally abundant gold, native bismuth, bismuthinite, xenotime, allanite, monazite, and the Be-rich silicate gadolinite-(Y), with sparse uraninite, stannite, and Bi tellurides, in a gangue of quartz, chlorite, biotite, muscovite, garnet, tourmaline, chloritoid, and/or siderite, with locally abundant fluorapatite or magnetite; (2) discordant tourmalinized breccias in the Blackbird district that in places have concentrations of cobaltite, chalcopyrite, gold, and xenotime; and (3) strata-bound magnetite-rich lenses in the Iron Creek area, which contain cobaltiferous pyrite and locally sparse chalcopyrite or xenotime. Most sulfide-rich deposits in the Blackbird district are enclosed by strata-bound lenses composed mainly of Cl-rich Fe biotite; some deposits have quartz-rich envelopes. Whole-rock analyses of 48 Co- and/or Cu-rich samples show high concentrations of Au (up to 26.8 ppm), Bi (up to 9.16 wt %), Y (up to 0.83 wt %), ∑REEs (up to 2.56 wt %), Ni (up to 6,780 ppm), and Be (up to 1,180 ppm), with locally elevated U (up to 124 ppm) and Sn (up to 133 ppm); Zn and Pb contents are uniformly low (≤821 and ≤61 ppm, respectively). Varimax factor analysis of bulk compositions of these samples reveals geochemically distinct element groupings that reflect statistical associations of monazite, allanite, and xenotime; biotite and gold; detrital minerals; chalcopyrite and sparse stannite; quartz; and cobaltite with sparse selenides and tellurides. Significantly, Cu is statistically separate from Co and As, consistent with the general lack of abundant chalcopyrite in cobaltite-rich samples. Paragenetic relations determined by scanning electron microscopy indicate that the earliest Y-REE-Be mineralization preceded deposition of Co, Cu, Au, and Bi. Allanite, xenotime, and gadolinite-(Y) commonly occur as intergrowths with and inclusions in cobaltite; the opposite texture is rare. Monazite, in contrast, forms a poikiloblastic matrix to cobaltite and thin rims on allanite and xenotime, reflecting a later metamorphic paragenesis. Allanite and xenotime also show evidence of late dissolution and reprecipitation, forming discordant rims on older anhedral allanite and xenotime and separate euhedral crystals of each mineral. Textural data suggest extensive deformation of the deposits by folding and shearing, and by pervasive recrystallization, all during Cretaceous metamorphism. Sensitive high resolution ion microprobe U-Pb geochronology by Aleinikoff et al. (2012) supports these paragenetic interpretations, documenting contemporaneous Mesoproterozoic growth of early xenotime and crystallization of megacrystic A-type granite on the northern border of the district. These ages are used together with mineralogical and geochemical data from the present study to support an epigenetic, IOCG model for Fe-Co-Cu-Au-Bi-Y-REE deposits of the Idaho cobalt belt. A sulfide facies variant of IOCG deposits is proposed for the Blackbird district, in which reducing hydrothermal conditions favored deposition of sulfide minerals over iron oxides. This new model includes Mesoproterozoic vein mineralization and related Fe-Cl metasomatism that formed the biotite-rich lenses, a predominantly felsic magmatic source for metals in the deposits, given their local abundance of Y, REEs, and Be, and a major sedimentary component in the hydrothermal fluids based on independent sulfur isotope and boron isotope data for sulfides and ore-related tourmaline, respectively.

Economic Geology↗

Potential sources of analytical bias and error in selected trace element data-quality analyses

Potential sources of analytical bias and error associated with laboratory analyses for selected trace elements where concentrations were greater in filtered samples than in paired unfiltered samples were evaluated by U.S. Geological Survey (USGS) Water Quality Specialists in collaboration with the USGS National Water Quality Laboratory (NWQL) and the Branch of Quality Systems (BQS). Causes for trace-element concentrations in filtered samples to exceed those in associated unfiltered samples have been attributed to variability in analytical measurements, analytical bias, sample contamination either in the field or laboratory, and (or) sample-matrix chemistry. These issues have not only been attributed to data generated by the USGS NWQL but have been observed in data generated by other laboratories. This study continues the evaluation of potential analytical bias and error resulting from matrix chemistry and instrument variability by evaluating the performance of seven selected trace elements in paired filtered and unfiltered surface-water and groundwater samples collected from 23 sampling sites of varying chemistries from six States, matrix spike recoveries, and standard reference materials. Filtered and unfiltered samples have been routinely analyzed on separate inductively coupled plasma-mass spectrometry instruments. Unfiltered samples are treated with hydrochloric acid (HCl) during an in-bottle digestion procedure; filtered samples are not routinely treated with HCl as part of the laboratory analytical procedure. To evaluate the influence of HCl on different sample matrices, an aliquot of the filtered samples was treated with HCl. The addition of HCl did little to differentiate the analytical results between filtered samples treated with HCl from those samples left untreated; however, there was a small, but noticeable, decrease in the number of instances where a particular trace-element concentration was greater in a filtered sample than in the associated unfiltered sample for all trace elements except selenium. Accounting for the small dilution effect (2 percent) from the addition of HCl, as required for the in-bottle digestion procedure for unfiltered samples, may be one step toward decreasing the number of instances where trace-element concentrations are greater in filtered samples than in paired unfiltered samples. The laboratory analyses of arsenic, cadmium, lead, and zinc did not appear to be influenced by instrument biases. These trace elements showed similar results on both instruments used to analyze filtered and unfiltered samples. The results for aluminum and molybdenum tended to be higher on the instrument designated to analyze unfiltered samples; the results for selenium tended to be lower. The matrices used to prepare calibration standards were different for the two instruments. The instrument designated for the analysis of unfiltered samples was calibrated using standards prepared in a nitric:hydrochloric acid (HNO 3 :HCl) matrix. The instrument designated for the analysis of filtered samples was calibrated using standards prepared in a matrix acidified only with HNO 3 . Matrix chemistry may have influenced the responses of aluminum, molybdenum, and selenium on the two instruments. The best analytical practice is to calibrate instruments using calibration standards prepared in matrices that reasonably match those of the samples being analyzed. Filtered and unfiltered samples were spiked over a range of trace-element concentrations from less than 1 to 58 times ambient concentrations. The greater the magnitude of the trace-element spike concentration relative to the ambient concentration, the greater the likelihood spike recoveries will be within data control guidelines (80–120 percent). Greater variability in spike recoveries occurred when trace elements were spiked at concentrations less than 10 times the ambient concentration. Spike recoveries that were considerably lower than 90 percent often were associated with spiked concentrations substantially lower than what was present in the ambient sample. Because the main purpose of spiking natural water samples with known quantities of a particular analyte is to assess possible matrix effects on analytical results, the results of this study stress the importance of spiking samples at concentrations that are reasonably close to what is expected but sufficiently high to exceed analytical variability. Generally, differences in spike recovery results between paired filtered and unfiltered samples were minimal when samples were analyzed on the same instrument. Analytical results for trace-element concentrations in ambient filtered and unfiltered samples greater than 10 and 40 μg/L, respectively, were within the data-quality objective for precision of ±25 percent. Ambient trace-element concentrations in filtered samples greater than the long-term method detection limits but less than 10 μg/L failed to meet the data-quality objective for precision for at least one trace element in about 54 percent of the samples. Similarly, trace-element concentrations in unfiltered samples greater than the long-term method detection limits but less than 40 μg/L failed to meet this data-quality objective for at least one trace-element analysis in about 58 percent of the samples. Although, aluminum and zinc were particularly problematic, limited re-analyses of filtered and unfiltered samples appeared to improve otherwise failed analytical precision. The evaluation of analytical bias using standard reference materials indicate a slight low bias for results for arsenic, cadmium, selenium, and zinc. Aluminum and molybdenum show signs of high bias. There was no observed bias, as determined using the standard reference materials, during the analysis of lead.

Scientific Investigations Report↗

Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental sigal?

Geochemical studies of Cretaceous strata rich in organic carbon (OC) from Deep Sea Drilling Project (DSDP) sites and several land sections reveal several consistent relationships among amount of OC, hydrocarbon generating potential of kerogen (measured by pyrolysis as the hydrogen index, HI), and the isotopic composition of the OC. First, there is a positive correlation between HI and OC in strata that contain more than about 1% OC. Second, percent OC and HI often are negatively correlated with carbon isotopic composition (σ 13 C) of kerogen. The relationship between HI and OC indicates that as the amount of organic matter increases, this organic matter tends to be more lipid rich reflecting the marine source of the organic matter. Cretaceous samples that contain predominantly marine organic matter tend to be isotopically lighter than those that contain predominantly terrestrial organic matter. Average σ 13 C values for organic matter from most Cretaceous sites are between −26 and −28‰, and values heavier than about −25‰ occur at very few sites. Most of the σ 13 C values of Miocene to Holocene OC-rich strata and modern marine plankton are between −16 to −23‰. Values of σ 13 C of modern terrestrial organic matter are mostly between −23 and −33‰. The depletion of terrestial OC in 13 C relative to marine planktonic OC is the basis for numerous statements in the literature that isotopically light Cretaceous organic matter is of terrestrial origin, even though other organic geochemical and(or) optical indicators show that the organic matter is mainly of marine origin. A difference of about 5‰ in σ 13 C between modern and Cretaceous OC-rich marine strata suggests either that Cretaceous marine planktonic organic matter had the same isotopic signature as modern marine plankton and that signature has been changed by diagenesis, or that OC derived from Cretaceous marine plankton was isotopically lighter by about 5‰ relative to modern plankton OC. Diagenesis does not produce a significant shift in σ 13 C in Miocene to Holocene sediments, and therefore probably did not produce the isotopically light Cretaceous OC. This means that Cretaceous marine plankton must have had σ 13 C values that were about 5‰ lighter than modern marine plankton, and at least several per mil lighter than Cretaceous terrestrial vegetation. The reason for these lighter values, however, is not obvious. It has been proposed that concentrations of CO 2 were higher during the middle Cretaceous, and this more available CO 2 may be responsible for the lighter σ 13 C values of Cretaceous marine organic matter.

Marine Geology↗

Paragenesis and chemistry of multistage tourmaline formation in the sullivan Pb-Zn-Ag deposit, British Columbia

Detailed petrographic study, scanning electron microscope imaging, and electron microprobe analyses of tourmalines from the Sullivan Pb-Zn-Ag massive sulfide deposit (British Columbia, Canada) document multiple paragenetic stages and large compositional variations. The tourmalines mainly belong to two common solid-solution series: dravite-schorl and dravite-uvite. Ca- and Fe-rich feruvite and alkali-deficient tourmalines are present locally. Products of tourmaline-forming stages include (from oldest to youngest): (1) rare Fe-rich dravite-schorl within black tourmalinite clasts in footwall fragmental rocks; (2) widespread Mg-rich, very fine grained, felted dravite in the footwall (the main type of tourmaline in the footwall tourmalinite pipe); (3) recrystallized, Fe-rich dravite-schorl (locally Ca-Fe feruvite) in the tourmalinite pipe, which preferentially occurs near postore gabbroic intrusions; (4) Mg-rich dravite or uvite associated with chlorite-pyrrhotite and chlorite-albite-pyrite-altered rocks in the shallow footwall and hanging wall; (5) discrete Mg-rich tourmaline grains associated with chlorite and discordant Mg-rich tourmaline rims which occur on disseminated Fe-rich schorl in the bedded Pb-Zn-Ag ores. The timing of rare Fe-rich schorl in the bedded ores is uncertain, but it most likely occurred during or between stages 2 and 3. The different paragenetic stages and their respective tourmaline compositions are interpreted in terms of a multistage evolution involving contributions from: (1) variable mixtures of synsedimentary, Fe-rich hydrothermal fluids and entrained seawater; (2) postore, Fe-rich, gabbro-related hydrothermal fluids; and (3) postore metamorphic reactions. Early synsedimentary, Fe-rich hydrothermal fluids which contained little or no entrained seawater formed Fe-rich black tourmalinite clasts locally in the footwall. The major type of tourmaline in the footwall tourmalinite pipe is Mg rich, recording seawater entrainment under high water/rock conditions, rather than control by the chemical composition of the original host sediments. Rare Fe-rich schorl within the bedded Pb-Zn-Ag ores is believed to have formed on the sea floor by reaction of an Fe-rich brine pool with detrital aluminous sediments. Postore emplacement of gabbro sills and local dikes in the footwall produced Fe-rich hydrothermal fluids, which were responsible for formation of minor Fe-rich dravite-schorl which overprinted earlier dravite. Postore, but synsedimentary, hydrothermal alteration involving entrained seawater was responsible for deposition of dravite and uvite in the hanging wall and for dravite in the brown tourmalinites of the shallow footwall. Mg-rich dravite-uvite associated with chlorite and in discordant rims on schorl in the bedded ores formed by sulfide-silicate reactions during greenschist facies regional metamorphism.

Economic Geology↗

A comparison of synthetic flowpaths derived from light detection and ranging topobathymetric data and National Hydrography Dataset High Resolution Flowlines

Bathymetric and topobathymetric light detection and ranging (lidar) digital elevation models created for the Delaware River were provided to the National Geospatial Program and used to evaluate synthetic flowpath extraction from bathymetric/topobathymetric lidar survey data as a data source for improving the density, distribution, and connectivity of the National Hydrography Dataset High Resolution Flowline Network. As the surface-water component of The National Map, the National Hydrography Dataset maintains the Nation’s drainage network flow information and geometries for surface-water features used in hydrologic, hydraulic, and other science and engineering disciplines. The regional lidar survey for the Delaware River between Hancock, New York, and Trenton, New Jersey, was collected for the U.S. Geological Survey using the Experimental Advanced Airborne Research Lidar sensor system and processed by the Coastal National Elevation Database Applications Program. Using 1 percent of the maximum flow accumulation value for the surveyed Delaware River corridor as the flow accumulation threshold for grid cells at 1-, 5-, and 10-meter resolution created 223 to 283 kilometers of synthetic flowpaths potentially representing the river channel thalweg, which is the deepest point in a riverbed cross-section. There was potential for improving the High Resolution National Hydrography Dataset (HR NHD) Flowline network in places where the Delaware River channel, depicted as an Artificial Path in the HR NHD, is offset from the extracted synthetic river flowpath which sometimes appeared better positioned than the Artificial Path to represent the river thalweg. For the same area, using 0.05 percent of the maximum flow accumulation at the 1-, 5-, and 10-meter resolutions extracted 744 to 1,317 kilometers of synthetic flowpaths, with extracted synthetic flowpaths representing the main river channel and additional synthetic flowpaths representing tributaries or streams adjacent to the main channel. Overlaying these results with the HR NHDFlowline Network indicates that some of the additional synthetic flowpaths are connected to or extend HR NHD stream/river feature types. Some disconnected or isolated synthetic flowpaths not included in stream/river feature types were validated in orthoimagery and U.S. Topo Maps and provide examples of how extracted synthetic flowpaths could be used to delineate new stream/river features. Other additional extracted synthetic flowpaths depict linear features such as canals, tree lines, roads, or linear topographic depressions. For some river reaches where obstructions to flow or where low-relief topographic or bathymetric surfaces alter the flow direction, the software tool used to develop the flow direction grid did not calculate a primary flowpath for the river channel. Based on the results of this analysis, site conditions for the Delaware River corridor did not affect the quality of lidar bathymetric survey data. However, depending on the resolution of the lidar bathymetric digital elevation models (BDEMs), site conditions do have different effects on results for extracted synthetic flowpaths. We found that synthetic flowpaths extracted from 1-meter resolution lidar DEMs had more varied flow directions around in-channel landforms that obstructed flow than synthetic flowpaths extracted from 5- or 10-meter resolution lidar DEMs. As a result the 1-meter resolution DEM created some isolated or discontinuous synthetic flowpath segments where the 5- and 10-meter DEMs developed more continuous flowpaths. In this case the river bed upstream from the in-channel obstruction is shallower than the river bed downstream. Under these conditions the 1-meter resolution DEM provided synthetic flowpaths delineating a potential river thalweg. In this same area, the software solution modified (virtually raised) the river bed in the 5- and 10-meter resolution DEMs and flattened the bathymetric surface to create a continuous downstream flow direction, which caused trellis-patterned synthetic flowpaths to form. Under different site conditions and converse to the above development of synthetic flowpaths at different resolutions, at an abandoned river flood plain (terrace) with low relief that is adjacent to the river channel, the flow direction grid for the 1-meter resolution DEM developed continuous synthetic flowpath corresponding to a HR NHD Flowline network stream/river feature that connected to the main river channel but the larger resolution DEMs created isolated or disconnected synthetic flowpaths. A project to continue an evaluation of benefits of or issues caused by extracting synthetic flowpaths to enhance the HR NHD could include a study to assess the potential for merging surface-water flowpaths extracted from lidar topobathymetry and 3D Elevation Program digital elevation models. The merged DEM approach to synthetic flowpath extraction could extend the HR NHDFlowline network and enhance flow accumulations that might develop better flow direction grids in low-relief areas. Because of the confined lateral extent of the Delaware River, the lidar DEMs were not used to create catchments or watersheds; however, the merged DEM approach could also be tested as a resource for enhancing HR NHD catchments and watersheds. This lidar DEM synthetic flowpath extraction project supports the National Geospatial Program efforts to collect and produce high-quality lidar data to provide 3-dimensional representations of natural feature and aligns with the National Spatial Data Infrastructure to improve utilization of geospatial data. The results also can be useful for understanding strategies that can help maintain quality data in the HR NHD programs. KEYWORDS: bathymetric, digital elevation model, extracted synthetic flowpath, lidar, High Resolution National Hydrography Dataset, topobathymetric

New Jersey↗

Groundwater and surface-water interaction within the upper Smith River Watershed, Montana 2006-2010

The 125-mile long Smith River, a tributary of the Missouri River, is highly valued as an agricultural resource and for its many recreational uses. During a drought starting in about 1999, streamflow was insufficient to meet all of the irrigation demands, much less maintain streamflow needed for boating and viable fish habitat. In 2006, the U.S. Geological Survey, in cooperation with the Meagher County Conservation District, initiated a multi-year hydrologic investigation of the Smith River watershed. This investigation was designed to increase understanding of the water resources of the upper Smith River watershed and develop a detailed description of groundwater and surface-water interactions. A combination of methods, including miscellaneous and continuous groundwater-level, stream-stage, water-temperature, and streamflow monitoring was used to assess the hydrologic system and the spatial and temporal variability of groundwater and surface-water interactions. Collectively, data are in agreement and show: (1) the hydraulic connectedness of groundwater and surface water, (2) the presence of both losing and gaining stream reaches, (3) dynamic changes in direction and magnitude of water flow between the stream and groundwater with time, (4) the effects of local flood irrigation on groundwater levels and gradients in the watershed, and (5) evidence and timing of irrigation return flows to area streams. Groundwater flow within the alluvium and older (Tertiary) basin-fill sediments generally followed land-surface topography from the uplands to the axis of alluvial valleys of the Smith River and its tributaries. Groundwater levels were typically highest in the monitoring wells located within and adjacent to streams in late spring or early summer, likely affected by recharge from snowmelt and local precipitation, leakage from losing streams and canals, and recharge from local flood irrigation. The effects of flood irrigation resulted in increased hydraulic gradients (increased groundwater levels relative to stream stage) or even reversed gradient direction at several monitoring sites coincident with the onset of nearby flood irrigation. Groundwater-level declines in mid-summer were due to groundwater withdrawals and reduced recharge from decreased precipitation, increased evapotranspiration, and reduced leakage in some area streams during periods of low flow. Groundwater levels typically rebounded in late summer, a result of decreased evapotranspiration, decreased groundwater use for irrigation, increased flow in losing streams, and the onset of late-season flood irrigation at some sites. The effect of groundwater and surface-water interactions is most apparent along the North and South Forks of the Smith River where the magnitude of streamflow losses and gains can be greater than the magnitude of flow within the stream. Net gains consistently occurred over the lower 15 miles of the South Fork Smith River. A monitoring site near the mouth of the South Fork Smith River gained (flow from the groundwater to the stream) during all seasons, with head gradients towards the stream. Two upstream sites on the South Fork Smith River exhibited variable conditions that ranged from gaining during the spring, losing (flowing from the stream to the groundwater) during most of the summer as groundwater levels declined, and then approached or returned to gaining conditions in late summer. Parts of the South Fork Smith River became dry during periods of losing conditions, thus classifying this tributary as intermittent. The North Fork Smith River is highly managed at times through reservoir releases. The North Fork Smith River was perennial throughout the study period although irrigation diversions removed a large percentage of streamflow at times and losing conditions persisted along a lower reach. The lowermost reach of the North Fork Smith River near its mouth transitioned from a losing reach to a gaining reach throughout the study period. Groundwater and surface-water interactions occur downstream from the confluence of the North and South Fork Smith Rivers, but are less discernible compared to the overall magnitude of the main-stem streamflow. The Smith River was perennial throughout the study. Monitoring sites along the Smith River generally displayed small head gradients between the stream and the groundwater, while one site consistently showed strongly gaining conditions. Synoptic streamflow measurements during periods of limited irrigation diversion in 2007 and 2008 consistently showed gains over the upper 41.4 river miles of the main stem Smith River where net gains ranged from 13.0 to 28.9 cubic feet per second. Continuous streamflow data indicated net groundwater discharge and small-scale tributary inflow contributions of around 25 cubic feet per second along the upper 10-mile reach of the Smith River for most of the 2010 record. A period of intense irrigation withdrawal during the last two weeks in May was followed by a period (early June 2010 to mid-July 2010) with the largest net increase (an average of 71.1 cubic feet per second) in streamflow along this reach of the Smith River. This observation is likely due to increased groundwater discharge to the Smith River resulting from irrigation return flow. By late July, the apparent effects of return flows receded, and the net increase in streamflow returned to about 25 cubic feet per second. Two-dimensional heat and solute transport VS2DH models representing selected stream cross sections were used to constrain the hydraulic properties of the Quaternary alluvium and estimate temporal water-flux values through model boundaries. Hydraulic conductivity of the Quaternary alluvium of the modeled sections ranged from 3x10-6 to 4x10-5 feet per second. The models showed reasonable approximations of the streambed and shallow aquifer environment, and the dynamic changes in water flux between the stream and the groundwater through different model boundaries.

Montana↗

Controls on intrusion of near-trench magmas of the Sanak-Baranof Belt, Alaska, during Paleogene ridge subduction, and consequences for forearc evolution

A belt of Paleogene near-trench plutons known as the Sanak-Baranof belt intruded the southern Alaska convergent margin. A compilation of isotopic ages of these plutons shows that they range in age from 61 Ma in the west to ca. 50 Ma in the east. This migrating pulse of magmatism along the continental margin is consistent with North Pacific plate reconstructions that suggests the plutons were generated by migration of a trench-ridge-trench triple junction along the margin. On the Kenai Peninsula the regional lower greenschist metamorphic grade of the turbiditic host rocks, texture of the plutons, contact-metamorphic assemblage, and isotopic and fluid inclusion studies suggest that the plutons were emplaced at pressures of 1.5–3.0 kbars (5.2–10.5 km) into a part of the accretionary wedge with an ambient temperature of 210–300 °C. The presence of kyanite, garnet, and cordierite megacrysts in the plutons indicates that the melts were generated at a depth greater than 20 km and minimum temperature of 650 °C. These megacrysts are probably xenocrystic remnants of a restitic or contact metamorphic phase entrained by the melt during intrusion. However, it is also possible that they are primary magmatic phases crystallized from the peraluminous melt. Plutons of the Sanak-Baranof belt serve as time and strain markers separating kinematic regimes that predate and postdate ridge subduction. Pre-ridge subduction structures are interpreted to be related to the interaction between the leading oceanic plate and the Chugach terrane. These include regional thrust faults, NE-striking map-scale folds with associated axial planar foliation, type-1 mélanges, and an arrayof faults within the contact aureole indicating shortening largely accommodated by layer-parallel extension. Syn-ridge subduction features include the plutons, dikes, and ductile shear zones within contact aureoles with syn-kinematic metamorphic mineral growth and foliation development. Many of the studied plutons have sheeted margins and appear to have intruded along extensional jogs in margin-parallel strike-slip faults, whereas others form significant angles with the main faults and may have been influenced by minor faults of other orientations. Some of the plutons of the Sanak-Baranof belt have their long axes oriented parallel to faults of an orthorhombic fault set, implying that these faults may have provided a conduit for magma emplacement. This orthorhombic set of late faults is interpreted to have initially formed during the ridge subduction event, and continued to be active for a short time after passage of the triple junction. ENE-striking dextral faults of this orthorhombic fault system exhibit mutually crosscutting relationships with Eocene dikes related to ridge subduction, and mineralized strike-slip and normal faults of this system have yielded 40Ar/39Ar ages identical to near-trench intrusives related to ridge subduction. Movement on the orthorhombic fault system accommodated exhumation of deeper levels of the southern Alaska accretionary wedge, which is interpreted as a critical taper adjustment to subduction of younger oceanic lithosphere during ridge subduction. These faults therefore accommodate both deformation of the wedge and assisted emplacement of near-trench plutons. Structures that crosscut the plutons and aureoles include the orthorhombic fault set and dextral strike-slip faults, reflecting a new kinematic regime established after ridge subduction, during underthrusting of the trailing oceanic plate with new dextral-oblique convergence vectors with the overriding plate. The observation that the orthorhombic fault set both cuts and is cut by Eocene intrusives demonstrates the importance of these faults for magma emplacement in the forearc. A younger, ca. 35 Ma suite of plutons intrudes the Chugach terrane in the Prince William Sound region, and their intrusion geometry was strongly influenced by pre-existing faults developed during ridge subduction. The generation of these plutons may be related to the sudden northward migration of the triple junction at ca. 40–33 Ma, as the ridge was being subducted nearly parallel to the trench during this interval. These younger plutons are used to provide additional constraints on the structural evolution of the wedge. Late- to post-ridge subduction fabrics include a pressure solution cleavage and additional movement on the orthorhombic fault system. After triple junction migration, subduction of the trailing oceanic plate involved a significant component of dextral transpression and northward translation of the Chugach terrane. This change in kinematics is recorded by very late gouge-filled dextral faults in the late structures of the accretionary prism.

Alaska↗

Stable isotope study of water-rock interaction and ore formation, Bayhorse base and precious metal district, Idaho

The Bayhorse base and precious metal district is situated east of the Idaho batholith in south-central Idaho. The ores occur near the Nevada Mountain granitic stock as veins cutting the lower Paleozoic Ramshorn Slate and the Garden Creek Phyllite, and as fillings around breccia fragments within the Bayhorse Dolomite. The veins are dominated by siderite and tetrahedrite, with lesser quartz and galena, whereas the breccia ores dominantly comprise only quartz and galena. Mineralization and intrusive activity were contemporaneous during Cretaceous time. Fluid inclusion and stable isotope data indicate that mineralization formed from hot (ca. 375 degrees -225 degrees C), CO 2 -rich (< or =8.3+ or -1.4 mole %) brines (5-20 wt % NaCl equiv) at confining pressures between 1.1 and 1.7 kbars. Fluid cooling and the resulting CO 2 effervescence were the most important causes of ore deposition.Whole-rock delta 18 O and delta D values from the Garden Creek Phyllite define an isotopically depleted zone (60 km 2 ) around the Nevada Mountain stock and are the result of high-temperature interactions with ancient meteoric waters at water/rock ratios (mass fractions) ranging from 0.002 to 0.09. The delta 18 O (sub H 2 O) and delta D (sub H 2 O) values of the ore fluids ranged from 11.2 to 3.9 per rail and from -55 to -146 per mil, respectively. Comparison of the ore fluid delta 18 O (sub H 2 O) and delta D (sub H 2 O) values with hypothetical waters equilibrated with the Garden Creek Phyllite intricates that the hydrothermal fluids must have also interacted with the basal dolomite of Bayhorse Creek, which underlies the phyllite. Early delta 13 C (sub CO 2 ) values calculated in equilibrium with siderite ranged from -9.1 to -7.4 per mil, whereas later delta 13 C (sub CO 2 ) values obtained from quartz-hosted fluid inclusion extracts range from -4.0 to -1.8 per mil. The delta 13 C (sub CO 2 ) values for the hydrothermal fluids thus also record a transition from early water/rock interactions that were dominated by the Garden Creek Phyllite (organic matter delta 13 C = -23.6 to -20.9ppm) to later interactions that were influenced significantly by the basal dolomite of Bayhorse Creek (delta 13 C = -2.3 to -2.2ppm). The delta 34 S values of main-stage hydrothermal sulfides range from 3.0 to 28.3 per mil and display a distinct mode at approximately 10 per mil. The range of values may be interpreted as either a heterogeneous sedimentary source or mixed sedimentary-magmatic sources. On the basis of mass balance considerations, it is likely that all of the fluid salinity and the dissolved metals were derived from the Garden Creek Phyllite. The paragenetic sequence developed in the ores appears to be related to: (1) processes at the site of deposition, most notably cooling and CO 2 effervescence, and (2) water-rock interactions within the Garden Creek Phyllite in the 60-km 2 isotopically altered area surrounding the Nevada Mountain stock.

Economic Geology↗

Jurassic tectonics of northeastern Nevada and northwestern Utah from the perspective of barometric studies

Jurassic tectonism in the northeastern Great Basin produced varied structures, many closely associated with widespread magmatism at ca. 155–165 Ma and with local metamorphism. Many of the plutons are of suitable mineralogy for Al-in-hornblende barometry, providing the potential for depth data. We have studied conditions of metamorphism in the Pilot Range and barometry for six Jurassic plutons across the northeastern Great Basin. All barometry results are in harmony with pressures estimated from stratigraphic data, requiring little or no tectonic thickening. On the basis of structural styles and barometric data, we divide the northeastern Great Basin into three Jurassic tectonic provinces. An eastern extensional province, largely in western Utah, is characterized by Paleozoic strata that were thrust faulted and then intruded by shallow plutons shortly after or during normal and strike-slip faulting. Extension was probably a short-lived event associated with magmatism, but its west trend indicates a total reorientation of stress at this time, perhaps within transtensional strike-slip zones. A central province of modest, and possibly locally extreme, Jurassic shortening in eastern Nevada is characterized by metamorphosed Paleozoic rocks and by thrusts and kilometer-scale southeast-vergent folds. Upper amphibolite facies, but low pressure (3–4 kbar) metamorphism is present near Jurassic plutons in the Pilot Range and Ruby Mountains, probably indicating metamorphism induced by heat from magmas. In contrast, metamorphism in other ranges, which is known only to be pre–Late Cretaceous, indicates thickening of 10–20 km. This thickening may have entirely postdated the Jurassic. A western province in north-central Nevada is characterized by preserved Jurassic volcanic rocks and shallow plutons, indicating that little erosion, and probably surface uplift, occurred during the late Mesozoic. Folds and thrust faults indicate minor Jurassic shortening but many structures are undated. The low-pressure upper-crustal conditions for demonstrably Jurassic events suggest that higher-pressure metamorphism recorded in the central province is younger (Cretaceous) in age. We suggest that Jurassic structures were caused by distributed minor crustal shortening, manifested mainly as small-scale thrust faults. Local thermal highs created by plutonism produced metamorphic zones in relatively shallow crust. Shortening in the east was manifested by zones of strike-slip, within which plutons were emplaced in tensile niches. Lack of a deep foreland basin and lack of evidence for massive erosion argue against high-relief mountain belts caused by significant crustal shortening. Paleozoic rocks metamorphosed at pressures far in excess of stratigraphic burial are restricted to narrow lenses exhumed during Late Cretaceous and Tertiary extension and are bordered by rocks that always have been part of the shallow crust. The abundant shallow-crustal rocks preserved across the region indicate that a conventional hypothesis of large-scale, regional crustal thickening causing many kilometers of surface uplift and consequent erosion is unlikely to have taken place in the Mesozoic.

Nevada, Utah↗

Status of Water Levels and Selected Water-Quality Conditions in the Sparta-Memphis Aquifer in Arkansas and the Status of Water Levels in the Sparta Aquifer in Louisiana, Spring 2005

The U.S. Geological Survey in cooperation with the Arkansas Natural Resources Commission, the Arkansas Geological Commission, and the Louisiana Department of Transportation and Development has monitored water levels in the Sparta Sand of Claiborne Group and Memphis Sand of Claiborne Group since the 1920's. Ground-water withdrawals have increased while water levels have declined since monitoring was initiated. This report has been produced to describe ground-water levels in the aquifers in the Sparta Sand and Memphis Sand and provide information for the management of this valuable resource. The 2005 potentiometric-surface map of the aquifers in the Sparta Sand and Memphis Sand was constructed using water-level data collected in 333 wells in Arkansas and 120 wells in Louisiana during the spring of 2005. The highest water-level altitude measured in Arkansas was 327 feet above National Geodetic Vertical Datum of 1929 located in Grant County in the outcrop at the western boundary of the study area; the lowest water-level altitude was 189 feet below National Geodetic Vertical Datum of 1929 in Union County. The highest water-level altitude measured in Louisiana was 246 feet above National Geodetic Vertical Datum of 1929 located in Bossier Parish in the outcrop area near the western boundary of the study area; the lowest water-level altitude was 226 feet below National Geodetic Vertical Datum of 1929 in central Ouachita Parish. Three large depressions centered in Columbia, Jefferson, and Union Counties in Arkansas are the result of large withdrawals for industrial and public supplies. In Louisiana, three major pumping centers are in Ouachita, Jackson, and Lincoln Parishes. Water withdrawals from these major pumping centers primarily is used for industrial and public-supply purposes. Withdrawals from Ouachita and Lincoln Parishes and Union County, Arkansas, primarily for industrial purposes, have caused the resulting cones of depression to coalesce so that the -40 foot potentiometric contour encircles the three pumping centers. Seven smaller depressions are evident on the 2005 Sparta-Memphis potentiometric-surface map located in Webster and Winn Parishes, Louisiana, and Calhoun, Cleveland, western Columbia, Desha, and Lafayette Counties, Arkansas. The depression in Calhoun County initially was shown in the 1996-1997 potentiometric surface. The depression in Desha County initially was shown in the 1999 potentiometric surface. The depressions in Webster and Winn Parishes were shown as early as 1975. The depressions in Cleveland, western Columbia, and Lafayette Counties initially were shown in the 2003 potentiometric surface. A map of differences in water-level measurements between 2001 and 2005 was constructed using the difference between water-level measurements from 294 wells in Arkansas and 29 wells in Louisiana. The difference in water levels between 2001 and 2005 ranged from -30.1 to 44.6 feet. The largest rise of 44.6 feet in water level measured was in Union County in Arkansas. The largest decline of 30.1 feet in water level measured was in Columbia County in Arkansas. Areas with a general rise in water levels in Arkansas are shown in Arkansas, Columbia, Craighead, Jefferson, Prairie, and the western half of Union Counties. The area around west-central Union County had rises as much as 44.6 feet, with seven wells showing a rise of 20 feet or greater, which is an annual rise of 5 feet or greater. Areas in Arkansas with a general decline in water level are shown in western Bradley, eastern Calhoun, Cleveland, Cross, Desha, Drew, Lafayette, Lee, Lincoln, Lonoke, Poinsett, and the eastern half of Union Counties. In Louisiana, the water-level difference map showed a general rise in water levels in northern Claiborne, northern Webster, and northwestern Union Parishes mainly because of a decrease in industrial withdrawals in southern Arkansas, particularly Union County. Another rise in water level was indicated in western

Scientific Investigations Report↗

Reservoir evolution, downstream sediment transport, downstream channel change, and synthesis of geomorphic responses of Fall Creek and Middle Fork Willamette River to water years 2012–18 streambed drawdowns at Fall Creek Lake, Oregon

Executive Summary Chapter A. Introduction Fall Creek Dam impounds Fall Creek Lake, a 10-kilometer-long reservoir in western Oregon and is operated by the U.S. Army Corps of Engineers (USACE) primarily for flood-risk management (or flood control) in late autumn through early spring months, as well as for water quality, irrigation, recreation, and habitat in late spring through early autumn. Since 2011 (water year [WY] 2012), Fall Creek Lake has been temporarily drawn down each year to facilitate downstream passage of juvenile spring Chinook salmon ( Oncorhynchus tshawytscha ) through the 55-meter (m) high dam. This annual dam operation is temporary, typically lasting about 1–2 weeks from WY 2012 through 2020 (drawdown operations in WY 2022–24 have increased to more than 6 weeks). Drawdown of the reservoir results in lake levels being lowered to the elevation near the historical, pre-dam streambed. The annual streambed drawdowns of WY 2012–18 have improved fish passage and led the USACE to formally adopt streambed drawdowns as part of annual operations at Fall Creek Dam. However, temporarily lowering the lake to streambed creates free-flowing conditions in the reservoir that result in the erosion and episodic export of predominantly sand and finer-grained sediments (less than 2 millimeters [mm]) to the lower gravel-bed reaches of Fall Creek and the Middle Fork Willamette River. The introduction of large volumes of sand and finer-grain sediment into the dam-regulated reaches downstream from Fall Creek Dam prompted questions about the geomorphic responses to annual streambed drawdowns within Fall Creek Lake and downstream reaches along Fall Creek and the Middle Fork Willamette River. The U.S. Geological Survey (USGS) in partnership with USACE initiated a comprehensive geomorphic and sediment transport investigation to assess the coupled processes of reservoir erosion, sediment evacuation from Fall Creek Lake, and patterns of sediment transport and deposition in reaches downstream from the Fall Creek Dam that have resulted from annual streambed drawdowns. The purpose of this report is to systematically describe the processes of sediment erosion, transport, and deposition at Fall Creek Lake and geomorphic interactions between reaches upstream and downstream from Fall Creek Dam that relate to dam operations. Specifically, this report focuses on evaluating geomorphic responses to streambed drawdowns from WY 2012 through 2018 and placing drawdown-induced geomorphic responses within the broader context of physiographic and historical conditions and dam operations of Fall Creek and Middle Fork Willamette Rivers. Key objectives for this study were to characterize changes in reservoir morphology and substrate at Fall Creek Lake, describe the character and temporal pattern of sediment transport downstream from Fall Creek Dam, characterize geomorphic changes in channel reaches downstream from the Fall Creek Dam, and relate these data to the annual streambed drawdowns of WY 2012–18. This study uses multiple independent monitoring and measurement approaches to assess site, reach, and river-scale geomorphic responses to drawdowns to inform dam and reservoir management. Patterns and processes of reservoir evolution were assessed with geomorphic mapping and volumetric analyses of topography through comparison of multiple digital surface models (DSMs). Just downstream from Fall Creek Dam, analyses of sediment export from the reservoir focused on suspended sediment but also incorporated bedload analyses to assess sediment sizes. Geomorphic assessments downstream from the dam used reach-scale and site-scale approaches to document changes in channel morphology and substrate, including site measurements of sand and finer-grained sediment deposition and in-channel bed-material, volumetric change analyses from comparison of digital elevation models (DEMs), and repeat geomorphic mapping. Findings from this study inform river management and dam operations by providing an understanding of (1) coupled upstream-downstream geomorphic responses to the Fall Creek Lake streambed drawdowns, (2) geomorphic responses of Fall Creek Lake streambed drawdowns in comparison to drawdowns at other large dams, (3) controls on reservoir erosion and downstream geomorphic responses, and (4) implications for future hydrogeomorphic changes that may result from continued drawdowns and monitoring activities to assess those changes. Chapter B. Reservoir Morphology and Evolution Related to Dam Operations at Fall Creek Lake To understand the volume and distribution of sediment accumulation in Fall Creek Lake since dam closure in 1965, decadal-scale sedimentation patterns (spanning approximately 1965–2016) are evaluated using a combination of storage curve analyses and geomorphic mapping. Short-term (drawdown event-scale) patterns of erosion, sedimentation, and sediment export downstream are evaluated using a combination of geomorphic mapping and change detection analyses that quantify the distribution and total volume of sediment erosion and deposition within Fall Creek Lake. Geomorphic mapping of reservoir topography and analyses of historical datasets reveals four categories of landforms and sediment processes within Fall Creek Lake related to lake level operations: lacustrine sedimentation expressed in the reservoir floor, fluvial erosion and deposition within historical stream channels during streambed drawdowns, channel-like features created by erosion within the reservoir floor during streambed drawdowns, and erosion on reservoir hillslopes. Where the reservoir floor is mapped for this study as pelagic (deep water), deposition up to 3 meters (m) thick by lacustrine processes and burial of pre-dam topography with deposits thinning toward the edges of the valley floor and upstream areas of reservoir are observed. Despite over 50 years of sediment accumulation since dam construction, the main stream channels of Fall and Winberry Creeks (or reservoir thalwegs) through the reservoir are well defined, though their distinct morphology is likely influenced by a long history of recurring historical drawdowns to or near streambed since dam construction. Unregulated streamflow and sediment transport through the reservoir primarily are confined to these channels during the streambed drawdown periods. Erosional channel-like features created by drawdowns are carved through underlying, unconsolidated reservoir floor sediments and are most prominent in the lower reservoir below minimum conservation pool (the low pool elevation during winter flood season); sediment generated from the formation of these drawdown channels is more likely to be transported through and out of the reservoir than sediment deposits along the reservoir hillslopes at the valley margins that are separated from main channels by areas of low-gradient reservoir floor. Morphologic changes in the lower reservoir topography between January 2012 and November 2016 indicate overall net erosion of about 129,500 cubic meters (m 3 ). The most prominent geomorphic changes occurred along the main channels of Fall and Winberry Creeks near the Fall Creek Dam where incision, lateral migration, and slumping banks resulted in vertical and lateral adjustments to channel position, whereas most changes fell below the detectable limit on higher-elevation reservoir floor surfaces except where erosion occurred along features mapped as drawdown channels. Chapter C. Sediment Delivery from Fall Creek Lake and Transport through Downstream Reaches USGS implemented a sediment monitoring program in WY 2013–18 to evaluate the quantity and character of reservoir sediment exported from Fall Creek Lake during streambed drawdowns. Turbidity and suspended sediments were monitored annually autumn through spring to span the WY 2013–18 streambed drawdowns; however, unequal monitoring timeframes each year reduced the ability to compare results and factors affecting sediment export from the reservoir difficult between years. These data were originally measured to develop regressions and compute suspended-sediment loads (SSL). Bedload sediment monitoring from a cableway at the Fall Creek streamgage was completed in the autumn-winter of WY 2013 and 2017. The limited number of samples and presumed variability in sediment supply from the reservoir precluded construction of streamflow and bedload discharge relations to compute more than instantaneous bedload. Sand and finer-grained silts and clays were transported from the reservoir in suspension, though some coarser grains (up to 32 mm) were also mobilized and transported downstream from the dam as bedload. Observations of increased sediment transport downstream from Fall Creek Dam coincided with lake levels approaching about 3 m (10 feet [ft] or elevation 690 ft) above the streambed regulating outlets. Suspended-sediment loads computed for the full monitoring periods WY 2013–18 at the Fall Creek streamgage, located 1.4 kilometers (km) downstream from Fall Creek Dam, range from 54,700 metric tons (t) in WY 2013 to 13,900 t in WY 2018. Although the total annual SSL varied from year to year, the overall seasonal patterns of suspended sediment transport throughout each year were similar during monitoring in WY 2013-18. Suspended-sediment loads were low prior to the drawdown, then increased rapidly as lake levels lowered and approached the streambed. In the weeks following the drawdown period, as pool levels were increased, SSL remained slightly elevated above pre-drawdown levels but generally declined through the following winter and spring except during streamflow-driven pulses of suspended-sediment transport. WY 2013 had the greatest total computed SSL for each streambed drawdown and partial-year monitoring period. SSL computed for the partial-year period have generally decreased since WY 2013 and have varied by about 6,800 t with the exception of WY 2014. WY 2014 SSL reflects anomalously low sediment export due to low streamflows and freezing conditions that stabilized reservoir floor deposits. Bedload measurements in the short 1.4-km reach between Fall Creek Dam and the Fall Creek streamgage showed an inverse correlation between bedload transport rates and discharge, which probably reflects diminishing supply of coarse-sized sediment. Sand was more abundant (60–100 percent) than gravel in bedload samples confirming sand and finer-grained sediment dominated sediment evacuated from the reservoir during streambed drawdowns at Fall Creek Lake. Chapter D. Geomorphic Responses to Fall Creek Lake Streambed Drawdowns Downstream from Fall Creek Dam In the days, weeks, and months following streambed drawdown operations at Fall Creek Dam through WY 2018, sites downstream from the dam displayed a variety of geomorphic responses to reservoir sediment delivery within the main channel and overbank areas. Evaluation of streambed elevations at two streamgages located 1.4 km downstream from the dam on Fall Creek and 16.3 km downstream from the dam on the Middle Fork Willamette River indicated the effects of drawdown sediment on bed elevations were modest and transient. Repeat particle size measurements (October 2015 and September 2016) at five sites along Fall Creek and the Middle Fork Willamette River showed similar grain-sized distributions that do not reveal substantial deposition of fine-grained sediment related to the WY 2016 streambed drawdown. Altogether, these findings indicate that transport capacity in the main, low-flow channels of Fall Creek and Middle Fork Willamette River during WY 2012–18 was sufficient to mobilize and evacuate reservoir sediments from streambed drawdowns or other bank material and tributary sources. However, other monitoring for this study indicate low-velocity zones in off-channel areas are prime locations for sand and finer-grain sediment deposition. Patterns of overbank sediment accumulation indicate that the magnitude and timing of overbank deposition on bars and low-elevation floodplain varies with proximity to the dam, geomorphic setting, streamflows, and other factors. Sand and finer-grained reservoir sediments carried as suspended-sediment load in the reaches downstream from Fall Creek Dam were deposited in overbank areas as observed with clay-horizon markers during WY 2016–17. Overbank deposition quantified with Geomorphic Change Detection (GCD) software evaluated landform-scale patterns of erosion and deposition using repeat light detection and ranging (lidar) surveys at two sites in the Upper Fall Creek reach and one site in the Jasper reach for 3 years (2012–15) and one site in the Clearwater reach for 6 years (2009–15). Deposition thickness and spatial patterns from the GCD analysis were variable; some sites had dispersed but measurable deposition while at others, deposition was highly localized and exceeded 1 m in depth. Patterns of overbank deposition illustrate interactions among bar morphology, local hydraulics, and suspended-sediment transport dynamics that can create patches of highly localized deposition. The measured deposition at the two Fall Creek GCD sites likely resulted from reservoir sediments released from Fall Creek Lake during streambed drawdowns in WY 2016 and 2017 because the limited sediment inputs from bank material (geomorphically laterally stable reach) or tributaries (no significant tributaries) provided few other sediment sources. On the Middle Fork Willamette River, observed patterns of overbank deposition could reflect sediment sourced from upstream tributaries, bank erosion, or Fall Creek Lake streambed drawdown operations. Despite the introduction of several thousand tons of reservoir sediment delivered from the Fall Creek Lake streambed drawdowns to below-dam river corridors, reach-scale mapping of channel features downstream from Fall Creek Dam shows minimal evidence of changes in channel planform or landforms that can be attributed to a drawdowns in WY 2012–16. On Upper Fall Creek reach, widespread increases in gravel bars or other in-channel sediment did not result from the five streambed drawdowns. The main changes attributable to sediment releases from Fall Creek Lake were localized increases in vegetated bar area, particularly on channel margin areas where sand and finer-grain sediment was deposited and rapidly colonized by vegetation. The area of mapped secondary water features decreased between 2005 and 2016, but that may be due to lower discharges depicted in the 2016 aerial photographs and less mapped area of inundation. Primary changes along the Lower Fall Creek reach include a 6.4 percent decrease in area of secondary water features between 2011 and 2016, and a nearly twofold increase in the area of unvegetated bars. Immediately downstream from the Fall Creek confluence, there were negligible changes in the location and areas of vegetated bars and the main wetted channel between 2005 and 2016, and local increases in bar area cannot be attributed solely to deposition of reservoir sediments from Fall Creek Lake because (1) areas along the Middle Fork Willamette River just upstream from the Fall Creek confluence display similar type and magnitude of changes and (2) some of the increases at the confluence area pre-date the drawdowns. The cumulative effect of sediment releases from Fall Creek Lake streambed drawdowns from WY 2012 to 2016 on downstream channel planform and landforms are modest compared to the river-scale transformations and planform changes that occurred in the decades following dam construction. Chapter E. Discussion of Geomorphic Responses of Fall Creek and Middle Fork Willamette River to Streambed Drawdowns at Fall Creek Lake Multiple aspects of Fall Creek Dam infrastructure and operations exert first-order controls on the magnitudes of reservoir erosion that occur during the streambed drawdowns and ultimately determine the sediment delivery to downstream reaches. Key aspects of the dam and its operations that are most relevant to assessing geomorphic responses to streambed drawdowns include the (1) dam infrastructure, including configuration and size of regulating outlets and their proximity to the streambed which dictates the capacity and competence of the river to deliver sediment to downstream reaches and mode of sediment transport as suspended-sediment load or bedload; (2) frequency of historical drawdowns and long-term, year-round dam operations and lake level management, which partly dictate reservoir morphology and locations and magnitudes of readily erodible materials; (3) dam operations and hydroclimatic conditions during the streambed drawdown (including length of the drawdown and streamflows entering the reservoir), which directly control the timing, duration and magnitude of reservoir erosion and sediment evacuation; and (4) dam operations following the streambed drawdown operation that regulate streamflows (and thereby sediment transport conditions) downstream of Fall Creek Dam which primarily reflect interactions between hydroclimatic conditions and flood control operations. Patterns of sediment erosion and evacuation observed in this study at Fall Creek Lake from WY 2012–18 suggest that reservoir erosion during annual streambed drawdowns may remain similar or decrease in future years assuming (1) annual streambed drawdown operations are implemented in similar manner as the WY 2012–18 drawdowns (in terms of duration, late autumn or early winter implementation, rate of pool-level lowering to reach streambed, and other factors), (2) streambed drawdowns coincide with similar conditions as were observed WY 2012–18 (similar sediment yield into reservoir, low reservoir inflows, limited precipitation, moderate air temperature), and (3) no major geomorphic changes in the main reservoir channels of Fall and Winberry Creeks occur (for example, channel avulsion). Under such conditions, it is hypothesized that the stream channel within the reservoir would achieve a quasi-equilibrium state with respect to annual influx and export of sediment and aided by the substantial amount of in-channel bedrock, will remain laterally stable without erosion across reservoir deposits. Patterns of sediment transport measured at the Fall Creek streamgage downstream from Fall Creek Dam provide insight into the potential effects of future streambed drawdowns at Fall Creek Lake. Analyses of suspended sediment measured in WY 2013–18 show a major reduction in suspended-sediment loads between WY 2013 and later years, indicating streamflows transporting sediment through the reservoir to downstream reaches during streambed drawdowns have become supply limited. The 6-year suspended-sediment monitoring and sampling program is insufficient to make predictions about future sediment transport conditions because of uneven monitoring periods and varying controls on reservoir sediment erosion. It is likely that future suspended-sediment loads will be variable but similar to those observed in WY 2015–18 if operational, climatic, and geomorphological factors remain similar to those monitored WY 2015–18. Suspended-sediment loads downstream from Fall Creek Lake will likely remain highest when regulating outlets are fully open and Fall Creek is free flowing with the reservoir fully drained with little to no residual pool. Over time, it is possible that the suspended-sediment loads would reflect mobilization of reservoir sediment deposited in the previous year rather than erosion of sediment deposited years or decades earlier. Bedload is likely to remain a small fraction of the total sediment load evacuated from the reservoir and is relatively modest compared with pre-dam bedload transport rates because most coarse sediment remains trapped by the dam. If sediment releases from Fall Creek Lake and ensuing streamflow conditions follow a similar pattern in the future as was assessed in this study spanning WY 2012–18, near-term geomorphic adjustments downstream of the dam are expected to be modest. Barring major operational, climatic, and geomorphological changes, local site-scale deposition on bars, overbank areas, or off-channel features that persists several months after the streambed drawdown will likely continue to be highly variable, ranging from negligible to several centimeters of deposition. At the landform-scale, low velocity areas nearest to Fall Creek Dam will likely continue to undergo rapid deposition immediately during and after a streambed drawdown event, similar to patterns observed for WY 2012–18. Some of the sediment entering these off-channel features and margin areas may be temporarily stored, then later remobilized and dispersed farther downstream. But if newly deposited sediment persists through the following spring, there is a greater likelihood that local vegetation will establish, reinforce deposited material, and trap sediment during later drawdowns. The reach-scale geomorphic changes may become more apparent if (1) streambed drawdowns continued for several decades, and geomorphic changes were measured at decadal scales or (2) the amount of sediment introduced to downstream reaches substantially increased and (or) sediment transport capacity decreased. The continued streamflow regulation of Fall Creek Dam after sediment releases provides an opportunity to strategically manage streamflows during and after the streambed drawdowns to minimize downstream sediment impacts and ensure other operational thresholds are satisfied. This study provides a comprehensive foundation of datasets and geomorphic analyses to inform dam operations at Fall Creek Lake, monitor sediment transport downstream, and consider operational schemes for future drawdowns. The datasets from this study also provide baselines of sediment transport and geomorphic conditions to assess future changes in reservoir and downstream environments. Future monitoring could be tailored to address specific questions regarding the long-term geomorphic effects of streambed drawdowns on fluvial habitats, flood hazards, cultural resources, or downstream water quality. Future monitoring activities could focus on the relevant geomorphic processes and spatial domains within the three categories used for this study: (1) reservoir erosion and net sediment evacuation, (2) sediment delivery to downstream reaches, including magnitude and temporal pattern of sediment transport, and (3) geomorphic responses of downstream reaches to sediment delivery. Specifically, high priority future monitoring activities could include: Repeat topographic or photographic surveys in the reservoir to characterize changes occurring within individual drawdowns, to quantify sediment export, to determine temporal changes in reservoir storage, and to identify locations of erosion and deposition. Continuous, year-round turbidity monitoring supplemented with suspended-sediment measurements at a streamflow-gaging station immediately downstream from the dam to quantify sediment export. Repeat geomorphic monitoring, mapping, or modeling in downstream reaches to track changes in channel and over bank features using a combination of site- and reach-scale monitoring approaches. This could support assessments of sediment deposition and ensuing vegetation encroachment on flood hazards and habitats and examine how sediment transport and depositional processes may be affected by different sediment supply, streamflow, or dam management scenarios.

Oregon↗

Sequence stratigraphic and sedimentologic significance of biogenic structures from a late Paleozoic marginal- to open-marine reservoir, Morrow Sandstone, subsurface of southwest Kansas, USA

Integrated ichnologic, sedimentologic, and stratigraphic studies of cores and well logs from Lower Pennsylvanian oil and gas reservoirs (lower Morrow Sandstone, southwest Kansas) allow distinction between fluvio-estuarine and open marine deposits in the Gentzler and Arroyo fields. The fluvio-estuarine facies assemblage is composed of both interfluve and valley-fill deposits, encompassing a variety of depositional environments such as fluvial channel, interfluve paleosol, bay head delta, estuary bay, restricted tidal flat, intertidal channel, and estuary mouth. Deposition in a brackish-water estuarine valley is supported by the presence of a low diversity, opportunistic, impoverished marine ichnofaunal assemblage dominated by infaunal structures, representing an example of a mixed, depauperate Cruziana and Skolithos ichnofacies. Overall distribution of ichnofossils along the estuarine valley was mainly controlled by the salinity gradient, with other parameters, such as oxygenation, substrate and energy, acting at a more local scale. The lower Morrow estuarine system displays the classical tripartite division of wave-dominated estuaries (i.e. seaward-marine sand plug, fine-grained central bay, and sandy landward zone), but tidal action is also recorded. The estuarine valley displays a northwest-southeast trend, draining to the open sea in the southeast. Recognition of valley-fill sandstones in the lower Morrow has implications for reservoir characterization. While the open marine model predicts a "layer-cake" style of facies distribution as a consequence of strandline shoreline progradation, identification of valley-fill sequences points to more compartmentalized reservoirs, due to the heterogeneity created by valley incision and subsequent infill. The open-marine facies assemblage comprises upper, middle, and lower shoreface; offshore transition; offshore; and shelf deposits. In contrast to the estuarine assemblage, open marine ichnofaunas are characterized by a high diversity of biogenic structures representing the activity of a benthic fauna developed under normal salinity conditions. Trace fossil and facies analyses allow environmental subdivision of the shoreface-offshore successions and suggest deposition in a weakly storm-affected nearshore area. An onshore-offshore replacement of the Skolithos ichnofacies by the Cruziana ichnofacies is clearly displayed. The lower Morrow fluvio-estuarine valley was incised during a drop of sea level coincident with the Mississippian-Pennsylvanian transition, but was mostly filled during a subsequent transgression. The transgressive nature of the estuarine infill is further indicated by the upward replacement of depauperate brackish-water trace fossil assemblages by the open-marine Cruziana ichnofacies. Additional stratal surfaces of allostratigraphic significance identified within the estuary include the bayline surface, the tidal ravinement surface, the wave ravinement surface, and a basinwide flooding surface recording inundation of the valley interfluves. A younger sequence boundary within the lower Morrow is also recorded in the Gentzler field at the base of a forced regression shoreface, demarcated by the firmground Glossifungites ichnofacies, indicating a rapid basinward facies migration during a sea-level drop. Trace fossil models derived from the analysis of Mesozoic and Cenozoic reservoirs are generally applicable to the study of these late Paleozoic reservoirs. Pennsylvanian brackish-water facies differ ichnologically from their post-Paleozoic counterparts, however, in that they have: (1) lower trace fossil diversity, (2) lower degree of bioturbation, (3) scarcity of crustacean burrows, (4) absence of firmground suites, and (5) absence of ichnotaxa displaying specific architectures designed to protect the tracemaker from salinity fluctuations. Morrow open-marine ichnofaunas closely resemble their post-Paleozoic equivalents. ?? 2002 Elsevier Science B.V. All rights reserved.

Sedimentary Geology↗

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗