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Flow-adjusted trends in dissolved selenium load and concentration in the Gunnison and Colorado Rivers near Grand Junction, Colorado, water years 1986--2008

As a result of elevated selenium concentrations, many western Colorado rivers and streams are on the U.S. Environmental Protection Agency 2010 Colorado 303(d) list, including the main stem of the Colorado River from the Gunnison River confluence to the Utah border. Selenium is a trace metal that bioaccumulates in aquatic food chains and can cause reproductive failure, deformities, and other adverse impacts in birds and fish, including several threatened and endangered fish species. Salinity in the upper Colorado River has been the focus of source-control efforts for many years. Although salinity loads and concentrations have been previously characterized at the U.S. Geological Survey (USGS) streamflow-gaging stations at the Gunnison River near Grand Junction, Colo., and at the Colorado River near the Colorado-Utah State line, trends in selenium load and concentration at these two stations have not been studied. The USGS, in cooperation with the Bureau of Reclamation and the Colorado River Water Conservation District, evaluated dissolved selenium (herein referred to as "selenium") load and concentration trends at these two sites to inform decision makers on the status and trends of selenium. This report presents results of the evaluation of trends in selenium load and concentration for two USGS streamflow-gaging stations: the Gunnison River near Grand Junction, Colo. ("Gunnison River site"), USGS site 09152500, and the Colorado River near Colorado-Utah State line ("Colorado River site"), USGS site 09163500. Flow-adjusted selenium loads were estimated for the beginning water year (WY) of the study, 1986, and the ending WY of the study, 2008. The difference between flow-adjusted selenium loads for WY 1986 and WY 2008 was selected as the method of analysis because flow adjustment removes the natural variations in load caused by changes in mean-daily streamflow, emphasizing human-caused changes in selenium load and concentration. Overall changes in human-caused effects in selenium loads and concentrations during the period of study are of primary interest to the cooperators. Selenium loads for each of the 2 water years were calculated by using normalized mean-daily streamflow, measured selenium concentration, standard linear regression techniques, and data previously collected at the two study sites. Mean-daily streamflow was normalized for each site by averaging the daily streamflow for each day of the year over the 23-year period of record. Thus, for the beginning and ending water years, estimations could be made of loads that would have occurred without the effect of year-to-year streamflow variation. The loads thus calculated are illustrative of the change in loads between water years 1986 and 2008, and are not the actual loads that occurred in those 2 water years. The estimated 50th and 85th percentile selenium concentrations associated with the selenium loads were also calculated for WY 1986 and WY 2008 at each site. Time-trends in selenium concentration at the two sites were charted by using regression techniques for partial residuals for the entire study period (WY 1986 through WY 2008). Annual selenium load for the Gunnison River site was estimated to be 23,196 pounds for WY 1986 and 16,560 pounds for WY 2008, a 28.6 percent decrease. Lower and upper 95-percent confidence levels for WY 1986 annual load were 22,360 and 24,032 pounds. Lower and upper 95-percent confidence levels for WY 2008 annual load were 15,724 and 17,396 pounds. Estimated 50th percentile daily selenium concentrations decreased from 6.41 to 4.57 micrograms/liter from WY 1986 to WY 2008, whereas estimated 85th percentile daily selenium concentrations decreased from 7.21 to 5.13 micrograms/liter from WY 1986 to WY 2008. Annual selenium load for the Colorado River site was estimated to be 56,587 pounds for WY 1986 and 34,344 pounds for WY 2008, a 39.3 percent decrease. Lower and upper 95-percent confidence levels for WY 1986 annual load were 53,785 and 59,390 pounds. Lower and upper 95-percent confidence levels for WY 2008 annual load were 31,542 and 37,147 pounds. Estimated 50th percentile daily selenium concentrations decreased from 6.44 to 3.86 micrograms/liter from WY 1986 to WY 2008, whereas estimated 85th percentile daily selenium concentrations decreased from 7.94 to 4.72 micrograms/liter from WY 1986 to WY 2008.

Colorado↗

Morphodynamic evolution following sediment release from the world’s largest dam removal

Sediment pulses can cause widespread, complex changes to rivers and coastal regions. Quantifying landscape response to sediment-supply changes is a long-standing problem in geomorphology, but the unanticipated nature of most sediment pulses rarely allows for detailed measurement of associated landscape processes and evolution. The intentional removal of two large dams on the Elwha River (Washington, USA) exposed ~30 Mt of impounded sediment to fluvial erosion, presenting a unique opportunity to quantify source-to-sink river and coastal responses to a massive sediment-source perturbation. Here we evaluate geomorphic evolution during and after the sediment pulse, presenting a 5-year sediment budget and morphodynamic analysis of the Elwha River and its delta. Approximately 65% of the sediment was eroded, of which only ~10% was deposited in the fluvial system. This restored fluvial supply of sand, gravel, and wood substantially changed the channel morphology. The remaining ~90% of the released sediment was transported to the coast, causing ~60 ha of delta growth. Although metrics of geomorphic change did not follow simple time-coherent paths, many signals peaked 1–2 years after the start of dam removal, indicating combined impulse and step-change disturbance responses.

Washington↗

Hydrogeology and simulation of groundwater flow at the Green Valley reclaimed coal refuse site near Terre Haute, Indiana

The Green Valley reclaimed coal refuse site, near Terre Haute, Ind., was mined for coal from 1948 to 1963. Subsurface coal was cleaned and sorted at land surface, and waste material was deposited over the native glacial till. Approximately 2.7 million cubic yards of waste was deposited over 159 acres (92.3 hectares) in tailings ponds and gob piles. During 1993, the Indiana Department of Natural Resources, Division of Reclamation, improved the site by grading gob piles, filling tailings ponds, and covering the refuse with a layer of glacial drift. During 2008, the Division of Reclamation and U.S. Geological Survey initiated a cooperative investigation to characterize the hydrogeology of the site and construct a calibrated groundwater flow model that could be used to simulate the results of future remedial actions. In support of the modeling, a data-collection network was installed at the Green Valley site to measure weather components, geophysical properties, groundwater levels, and stream and seep flow. Results of the investigation indicate that (1) there is negligible overland flow from the site, (2) the prevailing groundwater-flow direction is from northeast to southwest, with a much smaller drainage to the northeast, (3) there is not a direct hydraulic connection between the refuse and West Little Sugar Creek, (4) about 24 percent of the groundwater recharge emerges through seeps, and water from the seeps evaporates or eventually flows to West Little Sugar Creek and the Green Valley Mine Pond, and (5) about 72 percent of groundwater recharge moves vertically downward from the coal refuse into the till and follows long, slow flow paths to eventual dischage points.

Indiana↗

Geography of Alaska lake districts: Identification, description, and analysis of lake-rich regions of a diverse and dynamic state

Lakes are abundant landforms and important ecosystems in Alaska, but are unevenly distributed on the landscape with expansive lake-poor regions and several lake-rich regions. Such lake-rich areas are termed lake districts and have landscape characteristics that can be considered distinctive in similar respects to mountain ranges. In this report, we explore the nature of lake-rich areas by quantitatively identifying Alaska’s lake districts, describing and comparing their physical characteristics, and analyzing how Alaska lake districts are naturally organized and correspond to climatic and geophysical characteristics, as well as studied and managed by people. We use a digital dataset (National Hydrography Dataset) of lakes greater than 1 hectare, which includes 409,040 individual lakes and represents 3.3 percent of the land-surface area of Alaska. The selection criteria we used to identify lake districts were (1) a lake area (termed limnetic ratio, in percent) greater than the mean for the State, and (2) a lake density (number of lakes per unit area) greater than the mean for the State using a pixel size scaled to the area of interest and number of lakes in the census. Pixels meeting these criteria were grouped and delineated and all groups greater than 1,000 square kilometers were identified as Alaska’s lake districts. These lake districts were described according to lake size-frequency metrics, elevation distributions, geology, climate, and ecoregions to better understand their similarities and differences. We also looked at where lake research and relevant ecological monitoring has occurred in Alaska relative to lake districts and how lake district lands and waters are currently managed. We identified and delineated 20 lake districts in Alaska representing 16 percent of the State, but including 65 percent of lakes and 75 percent of lake area. The largest lake districts identified are the Yukon-Kuskokwim Delta, Arctic Coastal Plain, and Iliamna lake districts with high limnetic ratios of 19, 17, and 21 percent, respectively. The three smallest districts we considered were Tetlin in the eastern interior, Menhiskof on the Alaska Peninsula, and Matanuska–Susitna at the head of Cook Inlet with limnetic ratios of 14, 9, and 9 percent, respectively. Lake density and limnetic ratio were poorly related among lake districts, such that some districts had a few large lakes like Iliamna with Lakes Iliamna and Becharof—the two largest in the State, compared to other districts with many very small lakes like Yukon-Kuskokwim Delta with 111,130 lakes and 63 percent of these less than 10 hectares. Most lake districts are in regions with relatively low precipitation, but temperature regimes varied widely among lake districts. Approximately one-half of lake districts were glaciated during the Pleistocene and similar numbers occur in regions classified as having continuous, discontinuous, and sporadic permafrost, or perennially unfrozen soils. Most districts are at low elevations (less than 250 meters) with two important exceptions being Tetlin with a mean elevation of 530 meters and Ahtna with a mean elevation of 760 meters. These higher elevation districts, particularly Ahtna, had distinct characteristics from other lake districts such as continuous permafrost and Pleistocene glaciation. Several lake districts share similar boundaries to defined ecoregions with lake districts occurring in less than one-half of these 32 ecoregions of Alaska. Most lake districts are lands fully or partly managed by the U.S. Fish and Wildlife Service and the National Park Service, with other land management by the Bureau of Land Management and State and borough government. Much of the U.S. Geological Survey’s lake water-quality sampling efforts has been done in the Arctic Coastal Plain, Matanuska-Susitna, and Iliamna districts but no recorded collections in nine lake districts. Similarly, most lake limnological studies in Alaska were site-specific and represent only a small portion of Alaska’s lake districts. This identification, characterization, and analysis of lake-rich regions may help provide a template to guide future limnological and other scientific research for Alaska.

Alaska↗

Hydrology of Northern Utah Valley, Utah County, Utah, 1975-2005

The ground-water resources of northern Utah Valley, Utah, were assessed during 2003-05 to describe and quantify components of the hydrologic system, determine a hydrologic budget for the basin-fill aquifer, and evaluate changes to the system relative to previous studies. Northern Utah Valley is a horst and graben structure with ground water occurring in both the mountain-block uplands surrounding the valley and in the unconsolidated basin-fill sediments. The principal aquifer in northern Utah Valley occurs in the unconsolidated basin-fill deposits where a deeper unconfined aquifer occurs near the mountain front and laterally grades into multiple confined aquifers near the center of the valley. Sources of water to the basin-fill aquifers occur predominantly as either infiltration of streamflow at or near the interface of the mountain front and valley or as subsurface inflow from the adjacent mountain blocks. Sources of water to the basin-fill aquifers were estimated to average 153,000 (+/- 31,500) acre-feet annually during 1975-2004 with subsurface inflow and infiltration of streamflow being the predominant sources. Discharge from the basin-fill aquifers occurs in the valley lowlands as flow to waterways, drains, ditches, springs, as diffuse seepage, and as discharge from flowing and pumping wells. Ground-water discharge from the basin-fill aquifers during 1975-2004 was estimated to average 166,700 (+/- 25,900) acre-feet/year where discharge to wells for consumptive use and discharge to waterways, drains, ditches, and springs were the principal sources. Measured water levels in wells in northern Utah Valley declined an average of 22 feet from 1981 to 2004. Water-level declines are consistent with a severe regional drought beginning in 1999 and continuing through 2004. Water samples were collected from 36 wells and springs throughout the study area along expected flowpaths. Water samples collected from 34 wells were analyzed for dissolved major ions, nutrients, and stable isotopes of hydrogen and oxygen. Water samples from all 36 wells were analyzed for dissolved-gas concentration including noble gases and tritium/helium-3. Within the basin fill, dissolved-solids concentration generally increases with distance along flowpaths from recharge areas, and shallower flowpaths tend to have higher concentrations than deeper flowpaths. Nitrate concentrations generally are at or below natural background levels. Dissolved-gas recharge temperature data support the conceptual model of the basin-fill aquifers and highlight complexities of recharge patterns in different parts of the valley. Dissolved-gas data indicate that the highest elevation recharge sources for the basin-fill aquifer are subsurface inflow derived from recharge in the adjacent mountain block between the mouths of American Fork and Provo Canyons. Apparent ground-water ages in the basin-fill aquifer, as calculated using tritium/helium-3 data, range from 2 to more than 50 years. The youngest waters in the valley occur near the mountain fronts with apparent ages generally increasing near the valley lowlands and discharge area around Utah Lake. Flowpaths are controlled by aquifer properties and the location of the predominant recharge sources, including subsurface inflow and recharge along the mountain front. Subsurface inflow is distributed over a larger area across the interface of the subsurface mountain block and basin-fill deposits. Subsurface inflow occurs at a depth deeper than that at which mountain-front recharge occurs. Recharge along the mountain front is often localized and focused over areas where streams and creeks enter the valley, and recharge is enhanced by the associated irrigation canals.

Utah↗

Geologic field-trip guide to the volcanic and hydrothermal landscape of the Yellowstone Plateau

Yellowstone National Park, a nearly 9,000 km 2 (~3,468 mi 2 ) area, was preserved in 1872 as the world’s first national park for its unique, extraordinary, and magnificent natural features. Rimmed by a crescent of older mountainous terrain, Yellowstone National Park has at its core the Quaternary Yellowstone Plateau, an undulating landscape shaped by forces of late Cenozoic explosive and effusive volcanism, on-going tectonism, glaciation, and hydrothermal activity. The Yellowstone Caldera is the centerpiece of the Yellowstone Plateau. The Yellowstone Plateau lies at the most northeastern front of the 17-Ma Yellowstone hot spot track, one of the few places on Earth where time-transgressive processes on continental crust can be observed in the volcanic and tectonic (faulting and uplift) record at the rate and direction predicted by plate motion. Over six days, this field trip presents an intensive overview into volcanism, tectonism, and hydrothermal activity on the Yellowstone Plateau (fig. 1). Field stops are linked directly to conceptual models related to monitoring of the various volcanic, geochemical, hydrothermal, and tectonic aspects of the greater Yellowstone system. Recent interest in young and possible future volcanism at Yellowstone as well as new discoveries and synthesis of previous studies, (for example, tomographic, deformation, gas, aeromagnetic, bathymetric, and seismic surveys), provide a framework in which to discuss volcanic, hydrothermal, and seismic activity in this dynamic region.

Yellowstone Plateau↗

Large-scale variation in density of an aquatic ecosystem indicator species

Monitoring indicator species is a pragmatic approach to natural resource assessments, especially when the link between the indicator species and ecosystem state is well justified. However, conducting ecosystem assessments over representative spatial scales that are insensitive to local heterogeneity is challenging. We examine the link between polychlorinated biphenyl (PCB) contamination and population density of an aquatic habitat specialist over a large spatial scale using non-invasive genetic spatial capture-recapture. Using American mink (Neovison vison), a predatory mammal and an indicator of aquatic ecosystems, we compared estimates of density in two major river systems, one with extremely high levels of PCB contamination (Hudson River), and a hydrologically independent river with lower PCB levels (Mohawk River). Our work supports the hypothesis that the mink densities are substantially (1.64-1.67 times) lower in the contaminated river system. We demonstrate the value of coupling the indicator species concept with well-conceived and spatially representative monitoring protocols. PCBs have demonstrable detrimental effects on aquatic ecosystems, including mink, and these effects are likely to be profound and long-lasting, manifesting as population-level impacts. Through integrating non-invasive data collection, genetic analysis, and spatial capture-recapture methods, we present a monitoring framework for generating robust density estimates across large spatial scales.

New York↗

Status of water quality in groundwater resources used for drinking-water supply in the southeastern San Joaquin Valley, 2013–15—California GAMA Priority Basin Project

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) investigated water quality of groundwater resources used for drinking-water supplies in the Madera-Chowchilla, Kings, Kaweah, Tule, and Tulare Lake groundwater subbasins of the southeastern San Joaquin Valley during 2013–15. The study focused primarily on groundwater resources used for domestic-supply wells in the southeastern San Joaquin Valley (SESJV-D), which correspond mostly to shallower parts of aquifer systems, compared to the groundwater resources used for public-supply wells in the southeastern San Joaquin Valley (SESJV-P). The investigation had three components: (1) characterization of the status of water quality in the SESJV-D, (2) comparison between water quality in the SESJV-D and SESJV-P, and (3) identification of natural and anthropogenic factors that potentially could affect water quality in these resources. The characterization of water quality in the SESJV-D was based on data collected from 198 domestic wells sampled during 2013–15 by the U.S. Geological Survey (USGS); characterization of water quality in the SESJV-P was based on data collected from 124 wells sampled by the USGS during 2005–18 and an additional 1,577 wells with publicly available data reported to the California State Water Resources Control Board Division of Drinking Water (SWRCB-DDW). Measured concentrations were compared to regulatory and non-regulatory drinking-water quality benchmarks. A grid-based method was used to estimate the areal proportions of each study area and the whole southeastern San Joaquin Valley with high (greater than benchmark concentration), moderate (greater than half of the benchmark for inorganic and one-tenth of the benchmark for organic), and low concentrations relative to those benchmarks. Natural and anthropogenic factors that could affect groundwater quality for the SESJV-D were identified in the context of the hydrogeologic setting of the southeastern San Joaquin Valley. The considered factors represented hydrologic conditions and position in the groundwater flow system (well depth, lateral position, presence of hydric soils, percentage of coarse-grained sediment, and aridity index), land-use characteristics (percentages of agricultural, urban, and natural land use, percentage of orchard or vineyard land use, and densities of septic tanks and underground storage tanks near the wells), and geochemical conditions (groundwater age class, oxidation-reduction class, pH, and dissolved oxygen and bicarbonate concentrations). Factors are compared between SESJV-D and SESJV-P at the scale of the five study areas. One or more inorganic constituents with U.S. Environmental Protection Agency (EPA) or California maximum contaminant levels (MCLs) were detected at high concentrations in 47 percent of the SESJV-D and in 32 percent of the SESJV-P. The inorganic constituents most commonly present at high concentrations in the SESJV-D were nitrate, uranium, and arsenic. Within the SESJV-D, the proportion of the study area with high concentrations of inorganic constituents ranged from 19 percent in Madera-Chowchilla to 60 percent in Kings and Tulare Lake. One or more inorganic constituents with California State Water Resources Control Board Division of Drinking Water secondary maximum contaminant levels (SMCL-CAs) were detected at high concentrations in 14 percent of the SESJV-D and in 19 percent of the SESJV-P. The constituents most commonly present at high concentrations were manganese, iron, and total dissolved solids (TDS). Although the proportion of SESJV-D and SESJV-P with high concentrations of TDS greater than the upper SMCL were similar at 4 percent, the proportion of the SESJV-D with moderate concentrations (between the recommended and upper SMCL-CA), 30 percent, was greater than the proportion of the SESJV-P with moderate concentrations, 12 percent. One or more organic constituents with MCLs were present at high concentrations in 19 percent of the SESJV-D and in 12 percent of the SESJV-P. All the constituents detected at high concentrations in the SESJV-D were fumigants, primarily 1,2,3-trichloropropane (1,2,3-TCP) and 1,2-dibromo-3-chloropropane (DBCP). Fumigants also were the constituents most commonly detected at high concentrations in the SESJV-P, although high concentrations of solvents also were detected. The SESJV-D dataset included analysis of many organic constituents without MCL benchmarks and with detection levels far below drinking water benchmark concentrations; detections at these low concentrations can be used as tracers of anthropogenic influence on groundwater. Pesticides and degradates of pesticides were detected in 60 percent of the SESJV-D; the most frequently detected pesticides were the herbicides simazine, didealkylatrazine (CAAT, a degradate of simazine and atrazine), diuron, and bromacil.

California↗

Guidebook of the western United States: Part B - The overland route, with a side trip to Yellowstone Park

The United States of America comprise an area so vast in extent and so diverse in natural features as well as in characters due to human agency that the American citizen who knows thoroughly his own country must have traveled widely and observed wisely. To 'know America first' is a patriotic obligation, but to meet this obligation the railroad traveler needs to have his eyes directed toward the more important or essential things within his field of vision and then to have much that he sees explained by what is unseen in the swift passage of the train. Indeed, many things that attract his attention are inexplicable except as the story of the past is available to enable him to interpret the present. Herein lie the value and the charm of history, whether human or geologic. The present stimulus given to travel in the home country will encourage many thousands of Americans to study geography at first hand. To make this study most profitable the traveler needs a handbook that will answer the questions that come to his mind so readily along the way. Furthermore, the aim of such a guide should be to stimulate the eye in the selection of the essentials in the scene that so rapidly unfolds itself in the crossing of the continent. In recognition of the opportunity afforded in 1915 to render service of this kind to an unusually large number of American citizens as well as to visitors from other countries, the United States Geological Survey has prepared a series of guidebooks covering four of the older railroad routes west of the Mississippi. These books are educational in purpose, but the method adopted is to entertain the traveler by making more interesting what he sees from the car window. The plan of the series is to present authoritative information that may enable the reader to realize adequately the scenic and material resources of the region he is traversing, to comprehend correctly the basis of its development, and above all to appreciate keenly the real value of the country he looks out upon, not as so many square miles of territory represented on the map in a railroad folder by meaningless spaces, but rather as land - real estate, if you please - varying widely in present appearance because differing largely in its history and characterized by even greater variation in values because possessing diversified natural resources. One region may be such as to afford a livelihood for only a pastoral people; another may present opportunity for intensive agriculture; still another may contain hidden stores of mineral wealth that may attract large industrial development; and taken together these varied resources afford the promise of long-continued prosperity for this or that State. Items of interest in civic development or references to significant epochs in the record of discovery and settlement may be interspersed with explanations of mountain and valley or statements of geologic history. In a broad way, the story of the West is a unit, and every chapter should be told in order to meet fully the needs of the tourist who aims to understand all that he sees. To such a traveler-reader this series of guidebooks is addressed. To this interpretation of our own country the United States Geological Survey brings the accumulated data of decades of pioneering investigation, and the present contribution is only one type of return to the public which has supported this scientific work under the Federal Government. In preparing the description of the country traversed by the Overland Route the geographic and geologic information already published as well as unpublished material in the possession of the Geological Survey has been utilized, but to supplement this material Messrs. Lee, Stone, and Gale made a field examination of the entire route in 1914, Mr. Lee working between Omaha and Ogden, Mr. Stone between Ogden and Yellowstone, and Mr. Gale between Ogden and San Francisco. Information has been furnished by Profs. J. C. Merriam a

Bulletin↗

Effects of changes in reservoir operations on water quality and trophic state indicators in Voyageurs National Park, northern Minnesota, 2001-03

Implementation of an order by the International Joint Commission in January 2000 has changed operating procedures for dams that regulate two large reservoirs in Voyageurs National Park in northern Minnesota. These new procedures were expected to restore a more natural water regime and affect water levels, water quality, and trophic status. Results of laboratory analyses and field measurements of chemical and physical properties from May 2001 through September 2003 were compared to similar data collected prior to the change in operating procedures. Rank sum tests showed significant decreases in chlorophyll-a concentrations and trophic state indices for Kabetogama Lake (p=0.021) and Black Bay (p=0.007). There were no significant decreases in total phosphorus concentration, however, perhaps due to internal cycling of phosphorus. No sites had significant trends in seasonal total phosphorus concentrations, with the exception of May samples from Sand Point Lake, which had a significant decreasing trend (tau=-0.056, probability=0.03). May chlorophyll-a concentrations for Kabetogama Lake showed a significant decreasing trend (tau=-0.42, probability=0.05). Based on mean chlorophyll trophic-state indices (2001-03), Sand Point, Namakan, and Rainy Lakes would be classified oligotrophic to mesotrophic, and Kabetogama Lake and Rainy Lake at Black Bay would be classified as mesotrophic. The classification of Sand Point, Namakan, and Rainy Lakes remain the same for data collected prior to the change in operating procedures. In contrast, the trophic classification of Kabetogama Lake and Rainy Lake at Black Bay has changed from eutrophic to mesotrophic.

Minnesota↗

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado↗

Water quality of streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

Data for the Red River of the North (Red River) Basin in Minnesota, North Dakota, and South Dakota were analyzed to determine whether the water quality of streams in the basin is adequate to meet future needs. For the Red River at Emerson, Manitoba, site, pH values, water temperatures, and dissolved-oxygen concentrations generally were within the criteria established for the protection of aquatic life. Dissolved-solids concentrations ranged from 245 to 1,100 milligrams per liter. Maximum sulfate and chloride concentrations were near, but did not exceed, the established secondary maximum contaminant level. The trace elements considered potentially harmful generally were at concentrations that were less than the established guidelines, standards, and criteria. The concentrations of lead that were detected may have occurred as a result of sample contamination. For the Red River upstream from Emerson, Manitoba, sites, pH and other field values rarely exceeded the criteria established for the protection of aquatic life. Many constituent concentrations for the Red River below Fargo, N. site exceeded water-quality guidelines, standards, and criteria. However, the trace-element exceedances could be natural or could be related to pollution or sample contamination. Many of the tributaries in the western part of the Red River Basin had median specific-conductance values that were greater than 1,000 microsiemens per centimeter. Sulfate concentrations occasionally exceeded the established drinking-water standard. Median arsenic concentrations were 6 micrograms per liter or less, and maximum concentrations rarely exceeded the 10-microgram-per-liter drinking-water standard that is scheduled to take effect in 2006. The small concentrations of lead, mercury, and selenium that occasionally were detected may have been a result of sample contamination or other factors. The tributaries in the eastern part of the Red River Basin had median specific-conductance values that were less than 1,000 microsiemens per centimeter. Concentrations of pesticides that were detected and that had regulatory limits were less than the cited water-quality guidelines, standards, and criteria. Concentrations of compounds that were detected generally were less than the sediment- quality standards and criteria. The data considered in this report generally provide a good baseline from which to evaluate changes in water-quality conditions. However, because many of the trace elements detected, including lead and mercury, may have been the result of sample contamination, additional data are needed to confirm that trace-element concentrations generally are low. Concentrations of major ions, including sulfate, and specific conductance may continue to approach drinking-water standards during periods of low flow because the streams, particularly those in the western part of the basin, are sustained mostly by ground-water discharge that generally has large dissolved-solids concentrations.

Scientific Investigations Report↗

Hydrostratigraphic Framework and Selection and Correlation of Geophysical Log Markers in the Surficial Aquifer System, Palm Beach County, Florida

The surficial aquifer system is the major source of freshwater for public water supply in Palm Beach County, Florida, yet many previous studies of the hydrogeology of this aquifer system have focused only on the eastern one-half to one-third of the county in the more densely populated coastal area (Land and others, 1973; Swayze and others, 1980; Swayze and Miller, 1984; Shine and others, 1989). Population growth in the county has resulted in the westward expansion of urbanized areas into agricultural areas and has created new demands on the water resources of the county. Additionally, interest in surface-water resources of central and western areas of the county has increased. In these areas, plans for additional surface-water storage reservoirs are being made under the Comprehensive Everglades Restoration Plan originally proposed by the U.S. Army Corps of Engineers and the South Florida Water Management District (1999), and stormwater treatment areas have been constructed by the South Florida Water Management District. Surface-water and ground-water interactions in the Everglades are thought to be important to water budgets, water quality, and ecology (Harvey and others, 2002). Most of the previous hydrogeologic and ground-water flow simulation studies of the surficial aquifer system have not utilized a hydrostratigraphic framework, in which stratigraphic or sequence stratigraphic units, such as those proposed in Cunningham and others (2001), are delineated in this stratigraphically complex aquifer system. A thick zone of secondary permeability mapped by Swayze and Miller (1984) was not subdivided and was identified as only being within the Anastasia Formation of Pleistocene age. Miller (1987) published 11 geologic sections of the surficial aquifer system, but did not delineate any named stratigraphic units in these sections. This limited interpretation has resulted, in part, from the complex facies changes within rocks and sediments of the surficial aquifer system and the seemingly indistinct and repetitious nature of the most common lithologies, which include sand, shell, sandstone, and limestone. Model construction and layer definition in a simulation of ground-water flow within the surficial aquifer system of Palm Beach County utilized only the boundaries of one or two major hydrogeologic zones, such as the Biscayne aquifer and surficial aquifer system; otherwise layers were defined by average elevations rather than geologic structure or stratigraphy (Shine and others, 1989). Additionally, each major permeable zone layer in the model was assumed to have constant hydraulic conductivity with no allowance for the possibility of discrete (thin) flow zones within the zone. The key to understanding the spatial distribution and hydraulic connectivity of permeable zones in the surficial aquifer system beneath Palm Beach County is the development of a stratigraphic framework based on a consistent method of county-wide correlation. Variability in hydraulic properties in the system needs to be linked to the stratigraphic units delineated in this framework, and proper delineation of the hydrostratigraphic framework should provide a better understanding and simulation of the ground-water flow system. In 2004, the U.S. Geological Survey, in cooperation with the South Florida Water Management District, initiated an investigation to develop a hydrostratigraphic framework for the surficial aquifer system in Palm Beach County.

Scientific Investigations Map↗

Geophysical log analysis of selected test holes and wells in the High Plains Aquifer, Central Platte River Basin, Nebraska

The U.S. Geological Survey in cooperation with the Central Platte Natural Resources District is investigating the hydrostratigraphic framework of the High Plains aquifer in the Central Platte River basin. As part of this investigation, a comprehensive set of geophysical logs was collected from six test holes at three sites and analyzed to delineate the penetrated stratigraphic units and characterize their lithology and physical properties. Flow and fluid-property logs were collected from two wells at one of the sites and analyzed along with the other geophysical logs to determine the relative transmissivity of the High Plains aquifer units. The integrated log analysis indicated that the coarse-grained deposits of the alluvium and the upper part of the Ogallala Formation contributed more than 70 percent of the total transmissivity at this site. The lower part of the Ogallala with its moderately permeable sands and silts contributed some measureable transmissivity, as did the fine-grained sandstone of the underlying Arikaree Group, likely as a result of fractures and bedding-plane partings. Neither the lower nor the upper part of the siltstone- and claystone-dominated White River Group exhibited measurable transmissivity. The integrated analysis of the geophysical logs illustrated the utility of these methods in the detailed characterization of the hydrostratigraphy of the High Plains aquifer.

Nebraska↗

Developing integrated methods to address complex resource and environmental issues

Introduction This circular provides an overview of selected activities that were conducted within the U.S. Geological Survey (USGS) Integrated Methods Development Project, an interdisciplinary project designed to develop new tools and conduct innovative research requiring integration of geologic, geophysical, geochemical, and remote-sensing expertise. The project was supported by the USGS Mineral Resources Program, and its products and acquired capabilities have broad applications to missions throughout the USGS and beyond. In addressing challenges associated with understanding the location, quantity, and quality of mineral resources, and in investigating the potential environmental consequences of resource development, a number of field and laboratory capabilities and interpretative methodologies evolved from the project that have applications to traditional resource studies as well as to studies related to ecosystem health, human health, disaster and hazard assessment, and planetary science. New or improved tools and research findings developed within the project have been applied to other projects and activities. Specifically, geophysical equipment and techniques have been applied to a variety of traditional and nontraditional mineral- and energy-resource studies, military applications, environmental investigations, and applied research activities that involve climate change, mapping techniques, and monitoring capabilities. Diverse applied geochemistry activities provide a process-level understanding of the mobility, chemical speciation, and bioavailability of elements, particularly metals and metalloids, in a variety of environmental settings. Imaging spectroscopy capabilities maintained and developed within the project have been applied to traditional resource studies as well as to studies related to ecosystem health, human health, disaster assessment, and planetary science. Brief descriptions of capabilities and laboratory facilities and summaries of some applications of project products and research findings are included in this circular. The work helped support the USGS mission to “provide reliable scientific information to describe and understand the Earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life.” Activities within the project include the following: Spanned scales from microscopic to planetary; Demonstrated broad applications across disciplines; Included life-cycle studies of mineral resources; Incorporated specialized areas of expertise in applied geochemistry including mineralogy, hydrogeology, analytical chemistry, aqueous geochemistry, biogeochemistry, microbiology, aquatic toxicology, and public health; and Incorporated specialized areas of expertise in geophysics including magnetics, gravity, radiometrics, electromagnetics, seismic, ground-penetrating radar, borehole radar, and imaging spectroscopy. This circular consists of eight sections that contain summaries of various activities under the project. The eight sections are listed below: Laboratory Facilities and Capabilities, which includes brief descriptions of the various types of laboratories and capabilities used for the project; Method and Software Development, which includes summaries of remote-sensing, geophysical, and mineralogical methods developed or enhanced by the project; Instrument Development, which includes descriptions of geophysical instruments developed under the project; Minerals, Energy, and Climate, which includes summaries of research that applies to mineral or energy resources, environmental processes and monitoring, and carbon sequestration by earth materials; Element Cycling, Toxicity, and Health, which includes summaries of several process-oriented geochemical and biogeochemical studies and health-related research activities; Hydrogeology and Water Quality, which includes descriptions of innovative geophysical, remote-sensing, and geochemical research pertaining to hydrogeology and water-quality applications; Hazards and Disaster Assessment, which includes summaries of research and method development that were applied to natural hazards, human-caused hazards, and disaster assessments; and Databases and Framework Studies, which includes descriptions of fundamental applications of geophysical studies and of the importance of archived data.

Circular↗

Base of principal aquifer for the Elkhorn-Loup model area, North-Central Nebraska

In Nebraska, the water managers in the Natural Resources Districts and the Nebraska Department of Natural Resources are concerned with the effect of ground-water withdrawal on the availability of surface water and the long-term effects of ground-water withdrawal on ground- and surface-water resources. In north-central Nebraska, in the Elkhorn and Loup River Basins, ground water is used for irrigation, domestic supply, and public supply; surface water is used in this area for irrigation, recreation, and hydropower production. In recognition of these sometimes competing ground- and surface-water uses in the Elkhorn and Loup River Basins, the U.S. Geological Survey, the Lewis and Clark Natural Resources District, the Lower Elkhorn Natural Resources District, the Lower Loup Natural Resources District, the Lower Niobrara Natural Resources District, the Lower Platte North Natural Resources District, the Middle Niobrara Natural Resources District, the Upper Elkhorn Natural Resources District, and the Upper Loup Natural Resources District agreed to cooperatively study water resources in the Elkhorn and Loup River Basins. The goals of the overall study were to construct and calibrate a regional ground-water flow model of the area and to use that flow model as a tool to assess current and future effects of ground-water irrigation on stream base flow and to help develop long-term water-resource management strategies for this area, hereafter referred to as the Elkhorn-Loup model area. The Elkhorn-Loup model area covers approximately 30,800 square miles, and extends from the Niobrara River in the north to the Platte River in the south. The western boundary of the Elkhorn-Loup model area coincides with the western boundary of the Middle Niobrara, Twin Platte, and Upper Loup Natural Resources Districts; the eastern boundary coincides with the approximate location of the western extent of glacial till in eastern Nebraska. The principal aquifer in most of the Elkhorn-Loup model area is the High Plains aquifer; the principal aquifer in the remaining part of the Elkhorn-Loup model area is an unnamed alluvial aquifer. The upper surface of the geologic units that directly underlie the aquifer is called the 'base of aquifer' in this report. The geologic unit that forms the base of aquifer in the Elkhorn-Loup model area varies by location. The Tertiary-age Brule Formation generally is the base of aquifer in the west; the Cretaceous-age Pierre Shale generally is the base of aquifer in the east. The purpose of this report is to update the altitude and configuration of the base of the principal aquifer in the Elkhorn-Loup model area and a 2-mile buffer area around the Elkhorn-Loup model area, using base-of-aquifer data from test holes, registered water wells, and oil and gas wells within the Elkhorn-Loup model area and a 20-mile buffer area around the Elkhorn-Loup model area that have become available since the publication of earlier maps of the base of aquifer for this area. The base-of-aquifer map is important for the Elkhorn-Loup ground-water flow model because it defines the model's lower boundary. The accuracy of the Elkhorn-Loup ground-water flow model and the accuracy of the model's predictions about the effects of ground-water irrigation on stream base flow are directly related to the accuracy of the model's lower boundary.

Scientific Investigations Map↗

A Next Generation Lunar Orbiter mission

The Moon is the scientific foundation for our knowledge of the early evolution and impact history of the terrestrial planets. Over the last decades the lunar science community has made significant progress in addressing key lunar science and exploration goals, while defining many new high-priority scientific questions regarding the formation and evolution of the Moon. On a broad scale, the last Planetary Decadal Survey defined three scientific objectives to guide studies of the inner planets and Moon. These objectives address the origins and diversity of terrestrial planets, the evolution of life on terrestrial planets, and climate processes on Earth-like planets [1]. Many of these objectives carry forward into exploration goals of a renewed lunar human exploration program, and urgently addressing these objectives will enable the rapid development of exploration plans. A large (Flagship or New Frontiers class) Next Generation Lunar Orbiter (NGLO) mission would address the last Planetary Decadal Survey objective of understanding the origin and diversity of terrestrial planets by studying the geochemistry and geology of the Moon at an unparalleled resolution compared to other lunar mission datasets. Also, NGLO would address the objective of studying the evolution of life on terrestrial planets by furthering knowledge about the composition and distribution of volatile elements on the lunar surface and better characterizing the past and present-day impact rates in the inner Solar System in order to better understand the original delivery of water to Earth. Key exploration goals, including identifying the nature and distribution of lunar volatiles (i.e., water, ice), mapping and characterizing potentially valuable lunar resources, and establishing a human presence on the Moon, also would be addressed by NGLO.

Bulletin of the AAS↗

Development and evaluation of a reservoir model for the Chain of Lakes in Illinois

Forecasts of flows entering and leaving the Chain of Lakes reservoir on the Fox River in northeastern Illinois are critical information to water-resource managers who determine the optimal operation of the dam at McHenry, Illinois, to help minimize damages to property and loss of life because of flooding on the Fox River. In 2014, the U.S. Geological Survey; the Illinois Department of Natural Resources, Office of Water Resources; and National Weather Service, North Central River Forecast Center began a cooperative study to develop a system to enable engineers and planners to simulate and communicate flows and to prepare proactively for precipitation events in near real time in the upper Fox River watershed. The purpose of this report is to document the development and evaluation of the Chain of Lakes reservoir model developed in this study. The reservoir model for the Chain of Lakes was developed using the Hydrologic Engineering Center–Reservoir System Simulation program. Because of the complex relation between the dam headwater and reservoir pool elevations, the reservoir model uses a linear regression model that relates dam headwater elevation to reservoir pool elevation. The linear regression model was developed using 17 U.S. Geological Survey streamflow measurements, along with the gage height in the reservoir pool and the gage height at the dam headwater. The Nash-Sutcliffe model efficiency coefficients for all three linear regression model variables ranged from 0.90 to 0.98. The reservoir model performance was evaluated by graphically comparing simulated and observed reservoir pool elevation time series during nine periods of high pool elevation. In addition, the peak elevations during these time periods were graphically compared to the closest-in-time observed pool elevation peak. The mean difference in the simulated and observed peak elevations was -0.03 feet, with a standard deviation of 0.19 feet. The Nash-Sutcliffe coefficient for peak prediction was calculated as 0.94. Evaluation of the model based on accuracy of peak prediction and the ability to simulate an elevation time series showed the performance of the model was satisfactory.

Illinois↗