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Wangyanite, PdNi8S8, a new Pd end-member mineral of the pentlandite group from the J-M reef, Stillwater Complex, Montana, USA

Wangyanite (IMA2024-008a), ideally PdNi 8 S 8 , is a Pd end-member mineral of the pentlandite group that was discovered in the J-M reef of the Stillwater Complex, Montana, USA. Wangyanite occurs as anhedral-subhedral granular crystals 200–400 µm in size, associated with isoferroplatinum, braggite, pentlandite, and chalcopyrite interstitial to plagioclase grains within anorthosite. Wangyanite exhibits a yellowish brown color with a black streak and a metallic luster. It is brittle with uneven fractures, and has a calculated density of 5.14 g/cm 3 . The mineral does not show discernible pleochroism, bireflectance, or anisotropy. It has an average composition of 9.95 wt.% Pd, 31.95 wt.% Ni, 25.02 wt.% Fe, 0.57 wt.% Co, 31.74 wt.% S, totaling 99.23 wt.%. The empirical formula, based on eight sulfur atoms per formula unit, is (Pd 0.76 Co 0.08 ) Σ0.84 (Ni 4.39 Fe 3.60 ) Σ7.99 S 8 . Wangyanite has a cubic cell with a space group of Fm -3 m (#225), having lattice parameters of a = 10.1167(12) Å, V = 1035.4(4) Å 3 , and Z = 4. Its crystal structure has been solved by single-crystal three-dimensional electron diffraction study. The strongest X-ray diffraction lines of wangyanite are claculated at [ d in Å ( I %)( hkl )]: 5.841(14.03)(111), 3.050(100)(311), 1.947(29.16)(115,333), 1.264(11.66)(800), 3.577(8.79)(220), 2.920(20.82)(222), and 2.321(9.34)(331). Wangyanite shares the same crystal structure as pentlandite, but the octahedrally coordinated site is mainly occupied by Pd in wangyanite. Based on the textural features and previous experimental Pd-Fe-Ni-S phase system, wangyanite could form by peritectic reaction between braggite, pentlandite and sulfide liquid. These mineral associations are stable in a Ni-Pd-rich sulfide melt system at about 550 °C or even lower temperature. Therefore, wangyanite can potentially serve as an indicator of the presence of Pd-rich residual melts. The mineral is named in honor of Prof. Christina Yan Wang, a well-known researcher on platinum-group element (PGE) occurrences and enrichment mechanisms in mafic-ultramafic intrusions, notably those deposits related to the Emeishan large igneous province in China.

Montana

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Advancing current understanding of Martian impact-generated hydrothermal systems through novel coupled modeling: Insights from Gale, Jezero, and other craters

Impact-generated hydrothermal systems are considered potentially habitable environments on Mars, Earth, and other planetary bodies for microbial life. However, there is an ongoing debate regarding what geological features on Mars provide definitive evidence for such systems. Although earlier studies have modeled hydrothermal processes in Martian craters, they often lacked integration with shock physics hydrocodes to constrain initial impact conditions. The importance of this two-code coupling was demonstrated by successfully replicating alteration signatures in the Earth's Haughton impact structure. In this study, we use a similar two-code approach, combining the iSALE hydrocode with the HYDROTHERM hydrothermal model to simulate the full evolution of impact-generated hydrothermal systems. We apply this method to craters the size of Jezero (∼50 km) and Gale (∼154 km) in diameter. Although Jezero's interior is largely buried, our results align with hypothesized hydrothermal vents and alteration minerals near central uplifts in similarly sized exposed craters, such as Toro and Auki. Furthermore, our models correspond to alteration patterns observed by the Curiosity in the lower layers of Mount Sharp, which may represent remnants of impact-driven hydrothermal activity. A key finding is that these systems may persist much longer than previously estimated. Our simulations suggest that a Jezero-sized system could remain habitable for thermophiles for approximately 720,000 years, whereas a Gale-sized system could persist for nearly 2 million years. Additionally, simulations under unsaturated crustal conditions reveal that air-dominated near-surface layers can suppress vertical fluid flow, enabling deep subsurface alteration without producing detectable mineral signatures at the surface.

Journal of Geophysical Research - Planets

Hidden system identification: Basin modeling as a tool for examining sedimentary geothermal resource potential

Three-dimensional (3D) geologic and temperature models have been developed for the onshore U.S. Gulf Coast. The results from these models identify areas of moderate- to high-temperature (90°-150°C and >150°C; respectively) geothermal resources at depths <6 km. This modeling study addresses the fundamental challenge of predicting where opportune temperature and lithology coincide. Unlike traditional geothermal systems with surface expressions of hydrothermal circulation (e.g., hot springs, fumaroles, sinter), sedimentary geothermal systems (SGS) are generally hidden. Historically, simplified efforts to predict subsurface temperatures in sedimentary basins have focused on linear temperature extrapolation that does not consider the variable thermal properties of different lithologies or lithologic changes with depth (e.g., compaction, lithification). Therefore, the need to understand basin architecture and predict temperatures in 3D within SGS is paramount to identifying geothermal resources and determining economic feasibility. Basin modeling software has long been used to characterize the subsurface conditions of sedimentary basins, including temperature, in the pursuit of finding hydrocarbons. This tool can also be adapted to evaluate the potential of geothermal resources in a sedimentary basin by predicting the confluence of desirable temperatures and reservoir lithologies. In this work, PetroMod basin modeling software was used to create a regional geologic model of the onshore U.S. Gulf Coast, covering over 500,000 km 2 calibrated to temperature data from wells. Inputs include structural surfaces from commercial databases, lithology information derived from published literature, and corrected bottom-hole temperatures (BHT) from over 6,000 wells. The resulting 3D geologic model can be used to predict temperatures throughout the basin. Maps were exported showing the depth, depositional unit, and reservoir lithology at which temperatures of 90°C and 150°C were reached, revealing over 400,000 km 2 of moderate- to high-temperature resources at depths <6 km. These maps function as a first-order screening tool to identify areas where low-, moderate-, or high-grade resource potential may exist, based on temperature and if optimal reservoir lithologies or depositional units of interest are present. Depending on the success criteria of a project, the same maps can be exported for any isotherm or incorporate other 1407 Gardner and Birdwell subsurface properties. The methodology employed in this work can be applied in any sedimentary basin with available subsurface data. Further calibration incorporating other data, including pressure and porosity, can expand the utility of basin modeling for geothermal evaluations. Basin modeling is a powerful but underutilized tool for identifying prospective geothermal resources in sedimentary basins.

Conference Paper

A synthesis engine for constructing geologic maps of the United States

The geologic history of the United States is cataloged in thousands of geologic maps produced during many decades. However, the disparate nature of these individual maps makes it challenging to assess resources, research geologic histories, or characterize natural hazards holistically across the Nation. The U.S. House of Representatives 2020 appropriations bill for the U.S. Department of the Interior (H.R. 116-100) requires the U.S. Geological Survey to “bring together detailed national and continental-resolution [two-dimensional] and [three-dimensional] information produced throughout the Survey and by [F]ederal and [S]tate partners.” In response to this directive, this report presents a compilation and synthesis of geologic maps across the United States in the form of a relational database. The synthesis database includes thematic maps that synthesize the Nation’s geology, and retains the original input maps as well as linkages to standardized vocabularies to aid the discoverability of geologic information. Specifically, the synthesis database is targeted toward producing four National-resolution maps for the conterminous United States: Quaternary geology, the geology at the Earth’s surface, pre-Quaternary geology, and Precambrian geology. In addition, the synthesis database includes the infrastructure necessary to expand to additional resolutions in the future.

conterminous United States

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

A diatom-based quantitative sea-ice proxy for the Bering and Chukchi seas

Sea ice affects Earth's climate system on both regional and global scales. Its incorporation into climate can be used to achieve more accurate predictions of future climate. However, instrumental records of sea-ice concentration do not extend earlier than 1978. In an effort to extend this record, we constructed a proxy using the generalized additive model based on relative abundances of five easy-to-identify diatom species found in sediment samples across the Bering and Chukchi seas. Here we present the first quantitative diatom-based sea-ice proxy developed for Beringia. The developed proxy has been applied to two sediment cores in the Bering Sea ranging from 0 to 25.7 ka (HLY0204 51JPC) and 369 to 430 ka (IODP Exp 323 Site U1345) and one in the Chukchi Sea ranging from 2.7 to 10 ka (HLY0204 24JPC). The obtained reconstructions of sea-ice concentrations are similar, but not identical to previously published qualitative and nearby records based on other proxies. Because our results are quantitative, they can be incorporated into regional climate models. The proxy is publicly available as an R Shiny application (app) and can be applied to any diatom count from marine sediments in the region.

Bering Sea, Chukchi Sea

Earthquake recurrence estimates for northern Caribbean faults from combinatorial optimization

We use combinatorial optimization to find the optimal spatial distribution of random samples of earthquakes (≥6.5) that minimize the misfit in target slip rates for all faults in the northeast Caribbean, and we derive magnitude-frequency relationships with uncertainties for these faults. Slip rates for many faults are derived from GPS block models, not direct measurements, because of their underwater locations. Predicted recurrence rates for eastern Hispaniola and Puerto Rico Trench faults are 220-450 yr for M7 and 3-5 kyr for M8, with maximum feasible magnitude of M8.2. The most frequent earthquakes with magnitudes ≥7.0 are predicted on the large upper plate strike-slip faults, Enriquillo (EF) and Septentrional Fault, commensurate with the historical record. Calais et al. (2023) suggested that shortening in western Hispaniola is accommodated on the offshore Jérémie and onshore Malpasse faults north and south of EF, instead of on terrestrial faults in western Hispaniola and EF. Because of our system-modeling approach, such a configuration predicts less frequent earthquakes on EF and on western Hispaniola and Muertos convergent zones. Recurrence times of a few 100s yr for M6.7 earthquakes is predicted on the submerged faults in Mona Passage, and infrequent M>7 earthquakes are predicted on the Virgin Islands faults.

Lesser Antilles

Land application of drill waste: A scope analysis

Drilling fluid waste land application, a process where drilling wastes are spread and tilled into the land surface, has become common in some petroleum-producing states, however, the potential benefits and risks of this practice are not well studied. Drilling fluids can be water- or oil-based and can have high concentrations of total soluble salts and total petroleum hydrocarbons. Comprehensive chemical characterization of these fluids is not well documented in the literature, and the extent of land application is largely unknown. We hypothesized that the land application of drill waste would fluctuate over time due to economic factors. To begin to understand the extent of historical and potential future land application, we analyzed data from over 5,800 drilling fluid land application permits collected by the Oklahoma Corporation Commission for years 2000, 2005, 2010, and 2015–2020. During the years studied, drilling fluid wastes were applied to more than 250,000 acres in Oklahoma, with over 54,000 thousand barrels (Mbbl) of liquids and nearly 21,000 Mbbl of solids applied. Land application is widespread (occurring in 59/77 counties), however recent drilling activity, land availability, and the economics of transportation have created conditions favorable for land application specifically in the Anadarko Basin. Land application can co-occur with sensitive areas, such as important groundwater and surface-water drinking sources and agricultural fields used for subsistence or feed crop production. Our approach for quantifying the extent of land application, along with further chemical characterization studies, can aid operators and land managers who are considering this practice in assessing the associated benefits and risks.

Oklahoma

New methodology for assessing underground natural gas storage resources – Example from Michigan Basin, United States

Energy consumption in the United States (U.S.) and across the world is shifting away from traditional fossil fuels like coal and oil, and towards natural gas and renewable sources, including hydrogen. Because gas demand is typically greatest during cold seasons and renewable sources sometimes produce variable supplies, it is important to store energy for use when demand exceeds supply. Whereas batteries and tanks typically store energy above ground, geologic (underground) storage may be able to retain much greater quantities of energy over much longer durations (e.g., Matos et al. 2019; Buursink et al. 2023). Consequently, the U.S. Geological Survey (USGS) is developing a methodology to locate new geologic energy storage sites with an initial focus on depleted hydrocarbon reservoirs followed by estimates of associated pore space or gas storage capacity. Depleted hydrocarbon fields in Michigan Basin in the U.S. already host large quantities of injected natural gas (about 681 billion cubic feet of seasonal gas capacity in 42 gas storage facilities; U.S. Energy Information Administration 2024). Therefore, we used this basin as an example to assess potential new storage resources alongside existing storage capacity and carbon dioxide sequestration resources (e.g., Katz and Coats 1968; Haagsma et al. 2020). In Michigan Basin gas storage is taking place in reservoirs within several key hydrocarbon producing formations with different lithologies, including the informal Stray sandstone of the Michigan Formation and the pinnacle reefs of the Niagara Group (Gautier et al. 1995; Swezey et al. 2015). The assessment methodology introduced here consists of two steps relying on both well information and reservoir data.

Michigan

Predictive regressive models of recent marsh sediment thickness improve the quantification of coastal marsh sediment budgets

Coastal marsh wetlands experience variations in vertical gains and losses through time, which have allowed them to infill relict topography and record variations in drivers. The stratigraphic unit associated with the development of the marsh also reflects the long-term importance of key ecosystem services supplied by the marsh environment, including carbon storage and storm mitigation. Mapping these coastal wetland sediments and the marsh unit thickness is challenging as traditional coastal geophysical tools are not easily deployable (acoustic methods) or are unreliable in saline-soil environments (e.g., ground-penetrating radar), leaving core-based methods the most viable mapping method. In the present study, we utilized prior information on the geologic architecture of the region to select spatial and physical metrics that likely persisted throughout evolution of the marsh during the late Holocene. We then assessed the individual and collective power of these metrics to predict marsh thickness observed from cores. Employing regressive predictive models powered by these data, we improve the quantification of marsh thickness for a coastal fringing marsh within the Grand Bay estuary in Mississippi and Alabama (USA). The information gained from this approach yields improved estimates of the carbon stocks in this environment. Additionally, the stored sediment masses reflect the past, and potential future, persistence of the Grand Bay marsh under historical and present marsh-estuarine sediment exchange fluxes. Such improvements to both the sediment budget of recent marsh stratigraphic units and the spatial extent provide new resources for comparison with large-scale landscape models, the latter of which may be used, when validated, to predict future change and ecosystem transformations.

Alabama. Mississippi

Structural setting and geothermal potential of northeastern Reese River Valley, north-central Nevada: Highly prospective detailed study site for the INGENIOUS project

The northeastern part of the Reese River basin situated ~15 km southeast of Battle Mountain, Nevada, scored highly in the Nevada geothermal play fairway analysis (PFA) for hosting potential hidden geothermal systems. This site (also referred to as Argenta Rise) was therefore chosen for detailed study in the INGENIOUS project (INnovative Geothermal Exploration through Novel Investigations Of Undiscovered Systems). The high PFA scores resulted primarily from favorable structural settings (e.g., fault intersections and pull aparts) with relatively high slip rates on Quaternary faults. The INGENIOUS project is utilizing additional parameters and more rigorous analytical techniques to further advance exploration at this site. This includes integration of geological (e.g., Quaternary fault mapping) and new geophysical datasets (e.g., gravity, magnetics, MT data, and five reprocessed seismic reflection profiles) to build a structural model and to identify specific favorable sites for potential geothermal upwellings. Two-meter temperature surveys were also conducted in the area (139 measurements). This part of north-central Nevada is characterized by systems of intersecting northerly and ENE-striking faults within the broader Humboldt structural zone, a poorly understood belt of ENE-striking faults and relatively high heat flow extending across northern Nevada. Kinematic analysis of exposed fault surfaces shows that ENE-striking faults have accommodated sinistral-normal slip, and normal slip characterizes N- to NNE-striking faults. Northeastern Reese River Valley lies within a broad left step between major ENE-striking fault zones on the northern flanks of the Argenta Rim and Shoshone Range and thus corresponds to a broad pull-apart in the ENE-striking sinistral-normal fault system. Notably, the nearby Beowawe geothermal system in Whirlwind Valley (with abundant sinter, hot springs, and a geothermal power plant) occupies a fault intersection in a relatively small left step in a major ENE-striking sinistral-normal fault and may serve as an analogue for a potential hidden system in northeastern Reese River Valley. Existing geological maps, high-resolution lidar, and seismic reflection data demonstrate that northeastern Reese River Valley is structurally complex with multiple intersections between the ENE- and N- to NNE-striking fault systems. Some of these fault intersections correspond to low resistivity anomalies, magnetic lows, and/or very subtle 2-m temperature anomalies, which may indicate hidden geothermal upwellings. Three-dimensional modeling and temperature-gradient drilling are planned to further evaluate these sites for geothermal activity.

Nevada

Sackung at Bald Eagle ridge, central Colorado: An updated interpretation of ridge-spreading movement, structures, and mechanisms from 50 years (1975–2025) of U.S. Geological Survey research

Slow gravitational failures of mountain peaks and ridges are poorly understood. Herein, we report on 50 years of studies at a slowly spreading castellate ridge in the Sawatch Range in central Colorado. The orientations of geomorphic-structural features indicate that the fractured Precambrian granitic rock underlying the ridge has extended and spread northwestward toward the formerly glacier-covered Busk Creek valley. Results from surveying, field-based geomorphic-structural mapping using lidar, rock mass quality measurements, a passive seismic survey, and satellite radar provide a major update to research started by U.S. Geological Survey researchers in the 1970s and 1980s. New insights include a recognition that the entire ridge has slowly moved by concurrent sliding along an inferred northwest dipping, compound basal-slip surface (or zone), and through the formation of multiple grabens by normal faulting and flexural toppling along sets of pre-existing fractures that dip moderately (∼45°) to the southeast. We were unable to distinguish the presence of a sudden and strong contrast in seismic velocity across the inferred slip surface. Movement during the 50-year study period has been episodic and gradually decreasing, in correspondence with decreasing cumulative annual precipitation and increasing mean annual air temperatures. The fastest moving area, just upslope from the glacier trimline, had an average horizontal velocity of 3 – 4 mm/yr. Evidence suggests that movement started as a paraglacial response mechanism, but because of the site’s proximity to the Rio Grande Rift, we cannot exclude earthquake shaking as a mechanism for initiation or enhancement of slope movement. An estimate of longer-term horizontal movement from the exposed basal-slip surface at the uphill side of the ridgetop graben is ∼1.1 mm/yr for the 13 – 14 ky post-glacial period. Broad implications of our work are that: (1) long-term measurements (decades or longer) of slope movement can add insights into how sackungen form and evolve through time; (2) the identification of thrust faults and toes in zones of compression near valley bottoms can be crucial for interpreting sackung failure mechanisms, and (3) the use of passive-seismic techniques to identify the depth to a slip surface may not be successful in granitic terrain dominated by planar fractures and subtle changes in rock-mass characteristics.

Colorado

USGS 2025 critical minerals review

The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.

Mining Engineering

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri River between Kansas City and St. Louis, Missouri, May 19–26, 2021

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near nine bridges at eight highway crossings of the Missouri River between Kansas City and St. Louis, Missouri, from May 19 to 26, 2021. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 to 1,840 feet (ft) longitudinally and generally extending laterally across the active channel from bank to bank during low to moderate flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a low to moderate flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All the bridge sites in this study were previously surveyed and documented in previous studies. Comparisons between bathymetric surfaces from the previous surveys and those of the current (2021) study do not indicate any consistent correlation between channel-bed elevations and streamflow conditions. The average difference between the bathymetric surfaces varied from 1.59 ft higher to 0.95 ft lower in 2021 than 2017, which corresponds to a gain of 100,200 cubic yards and a loss of 55,800 cubic yards, respectively. The average difference between the bathymetric surfaces varied from 2.74 ft higher to 3.05 ft lower in 2021 than 2013, which corresponds to a gain of 111,500 cubic yards and a loss of 169,200 cubic yards, respectively. The average difference between the bathymetric surfaces varied from 4.52 ft higher to 1.38 ft lower in 2021 than 2011, which corresponds to a gain of 221,100 cubic yards and a loss of 90,300 cubic yards, respectively. The most substantial overall net gain was 221,100 cubic yards between 2011 and 2021 at structures L0550 and A4497 at Jefferson City (site 20). The large net gain likely results from a combination of the mitigation of the scour holes near pier 4 of both bridges and the substantially lower flow in 2021 than in 2011. Alternatively, the most substantial overall net loss was 169,200 cubic yards between 2013 and 2021 at structure A6288 at Hermann (site 21), despite comparable streamflows. Pier size, nose shape, and skew to approach flow had a substantial effect on the size of the scour hole observed at a given pier. Larger and deeper scour holes were present at piers with wide or blunt noses caused by exposed footings or caissons. When a pier was skewed to primary approach flow, the scour hole was generally deeper and larger than at a similar pier without skew; furthermore, the shape of the scour hole near skewed piers in this study generally was longer and deeper on the side with impinging flow. At structure A6288 at Hermann (site 21), the scour hole near pier 5 was difficult to discern from nearby dunes and ripples, whereas the upstream edge of the footing was visible at pier 4, which likely contributes to the larger scour hole near that pier; the top of the footing may blunt the horseshoe vortex at pier 5, but the exposed front of the footing may exacerbate the vortex at pier 4.

Missouri

Satellite tracking of Galapagos Petrel Pterodroma phaeopygia reveals distribution and movements during chick rearing

We tracked 19 adult Galapagos Petrels Pterodroma phaeopygia during the chick-rearing seasons in 2009 and 2010 (Santa Cruz Island [ n = 16] and Floreana Island [ n = 3]) in the Galápagos Islands, Ecuador. Eight petrels performed 27 complete foraging trips lasting 0.6 to 18.8 days. Short trips (3.2 ± 2.1 days; 785 km; max displacement 671 km) and long trips (10.8 ± 3.9 days; 2,856 km; max displacement 1,034 km) resulted in concentrated use of waters off southern and western Isabela Island and within the Galápagos Marine Reserve (GMR). Less concentrated time extended farther southwest and eastward, in that case toward mainland Ecuador. Total distance covered among all completed trips, independent of duration, was strongly correlated with trip duration ( R ² = 0.92), indicating a strategy favoring active searching and foraging over commuting. Petrels ranged across Ecuador's exclusive economic zone (EEZ), as well as other countries' (Colombia, Costa Rica, Perú), and waters beyond; they spent 46%, 27%, and 34% of their time in the GMR during short, long, and apparent (incomplete) trips, respectively. However, overlap with EEZs or marine protected areas (MPAs) does not necessarily confer protection, because commercial tuna fishing, including legal fishing historically permitted inside the GMR, occurs within these waters. Including all complete and incomplete trips, petrels spent 37% of their time in high-seas waters without formal protection, outside both MPAs and EEZs. While some hot spots overlapped Galápagos MPAs, the far-ranging nature of chick-provisioning petrels underscores the importance for this species of also having coordinated, multinational protection of the high seas.

Floreana Island, Galápagos Islands, Santa Cruz Isl

Leveraging wildfire to augment forest management and amplify forest resilience

Successive catastrophic wildfire seasons in western North America have escalated the urgency around reducing fire risk to communities and ecosystems. In historically frequent-fire forests, fuel buildup as a result of fire exclusion is contributing to increased fire severity. The probability of high-severity fire can be reduced by active forest management that reduces fuels, prompting federal and state agencies to commit significant resources to increase the pace and scale of fuel reduction treatments. However, lower severity areas of wildfires also have the potential to act as “treatments,” and even catastrophic fires with large areas of high severity can still have substantial areas of lower severity fire that may be improving forest conditions locally. We quantified active management and wildfire severity across yellow pine and mixed conifer (YPMC) forests in the Sierra Nevada of California over a 22-year period (2001–2022). We did not detect increases in the area treated through time, but the area of beneficial wildfire (low to moderate severity) increased substantially, exceeding active treatment area in 8 of 22 years. Overall, beneficial wildfire treated ~17% more area than all treatments combined, and roughly four times more area than fire-related treatments alone. We then used disturbance history to evaluate resistance to high-severity wildfire and forest loss across the YPMC range. Of the 2.3 million ha YPMC of forests in 2001, 20% lost mature forests due to high-severity fire by 2022, which is nearly half of all YPMC area burned. Most of the landscape (47%) remains at risk of high-severity fire because it had no restorative disturbances, but 33% of the study area has some level of resistance to high-severity wildfire. In these areas, resistance will need to be enhanced and maintained over time via active management or managed wildfire, but these treatment needs will likely outpace capacity even under optimistic implementation scenarios. Given limited resources for implementing active management and the likelihood of a more fiery future, incorporating beneficial wildfire into landscape-level treatment planning has the potential to amplify the impact of active management treatments.

California, Nevada

Nanometer-scale relationships between sedimentary organic matter molecular composition, fluorescence, cathodoluminescence, and reflectance: The importance of oxygen content at low thermal maturities

Molecular characterization of sedimentary organic matter (SOM), termed macerals, is a common goal when seeking to understand petroleum generation as well as other geologic processes in deep time. However, unambiguous measurement of discrete macerals is challenging due to the small size of organic particles in sedimentary rocks, the proximity of different organic matter types to one another, mineral-organic matter interactions, and maceral mixing that occurs during SOM isolation prior to ex situ analysis. The recent advent of infrared spectrometers capable of nanometer-scale resolution and the application of these technologies to geologic samples has enabled advances in rapid, in situ molecular characterization of SOM allowing for insights into paleoenvironmental processes, such as organic matter productivity and preservation, among others. Here we employ one such technology, optical photothermal infrared (OPTIR) spectroscopy, to map SOM functional group distributions at 500-nm resolution in a sample from the Lower Cretaceous Sunniland Limestone of the South Florida Basin. Examined fields of view include occurrences of amorphous organic matter (AOM), inertinite, micrinite, solid bitumen, telalginite, and vitrinite. OPTIR data from these macerals are compared against traditional organic petrographic data from the same organic grains including fluorescence intensity and white light reflectance as well as against cathodoluminescence response, an emerging organic petrographic approach. Maceral oxygen content (using carbonyl functional group abundance as a proxy) is observed to vary widely between maceral types but correlates strongly with fluorescence and cathodoluminescence intensity as well as against reflectance. These findings highlight the important role that oxygen content plays in determining the optical properties of SOM and further demonstrate the ability of OPTIR to discriminate subtle molecular differences between SOM types.

Organic Geochemistry