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Post-wildfire debris flows

Post-wildfire debris flows pose severe hazards to communities and infrastructure near and within recently burned mountainous terrain. Intense heat of wildfires changes the runoff characteristics of a watershed by combusting the vegetative canopy, litter, and duff, introducing ash into the soil and creating water repellant soils. Following wildfire, rainfall on bare ground is less able to infiltrate into the fire-altered soils and overland flow is less impeded by vegetation. Rainfall runoff in recently burned areas can erode hillslopes owing to the removal of soil binding organic matter near the soil surface by fire. In channels, loose, dry-ravel deposits composed of sand and gravel are readily entrained by concentrated runoff in channels. Entrainment of soil on hillslopes and in channels bulks up the sediment concentration of the rainfall runoff to generate debris flows capable of transporting boulders and large woody debris. Post-wildfire debris flows can be triggered by rainfall conditions that would typically produce little runoff during unburned conditions. The primary rainfall trigger for post-wildfire debris flows is high intensity rainfall during short duration convective rainstorms or periods of high rainfall intensity embedded within a long-duration frontal storm. Numerous observations of debris flows triggered by storms lasting less than an hour following periods of little to no rainfall indicate that antecedent rainfall is not a requirement for initiation of post-wildfire debris flows. Post-wildfire debris-flow hazard assessment entails estimating probability and magnitude of debris flows in the burned area, estimating debris-flow runout and intensity, and defining rainfall intensity-duration thresholds for debris-flow initiation. In the United States, probability and magnitude is estimated using empirically derived models largely based on data collected in southern California. The models provide maps to identify watersheds and drainage paths where post-wildfire hazards are most pronounced. Rainfall intensity-duration thresholds can be incorporated into flood hazard forecasting tools. Currently, work is underway to identify how to best implement debris-flow runout models in burned areas with efficiency and accuracy. Post-wildfire debris flows have been a long-recognized process in the Transverse Ranges of southern California; however, climate change is driving more frequent wildfires to burn more mountainous terrain throughout the western United States and worldwide. As a result, post-wildfire debris flows are becoming a more common threat in areas where they were once infrequent. As the threat of post-wildfire debris flow expands into new areas, evaluating the hazard becomes challenging because the degree to which wildfire increases debris-flow susceptibility varies from region to region. This chapter summarizes the knowledge to date for evaluating post-wildfire debris-flow susceptibility and hazard assessment. We summarize the characteristics of wildfire burn severity, topography, underlying soil and geology, and rainfall conditions that contribute to making a watershed most likely to produce post-wildfire debris flows. Methods for hazard assessment in the United States and other countries are summarized. We highlight knowledge gaps for how post-wildfire debris-flow susceptibility varies throughout the western United States and worldwide and identify research needs to improve hazard assessment methods in different geographies.

Book chapter

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes

Uncertainty and spatial correlation in station measurements for mb magnitude estimation

The body‐wave magnitude (⁠⁠) is a long‐standing network‐averaged, amplitude‐based magnitude used to estimate the magnitude of seismic sources from teleseismic observations. The U.S. Geological Survey National Earthquake Information Center (NEIC) relies on in its global real‐time earthquake monitoring mission. Although waveform modeling‐based moment magnitudes are the modern standard to characterize earthquake size, is important because (1) in many cases, waveform modeling is not possible (e.g., low signal‐to‐noise events), (2) is applicable over a broad range of magnitudes, ∼M 4–7, and (3) there is a many decades‐long history of estimating magnitudes. We use the NEIC Preliminary Determination of Epicenters earthquake catalog to investigate the uncertainty in NEIC station measurements. We show that measurements are spatially correlated, which can bias event ⁠, and we describe an empirical relation between this spatial correlation and station‐to‐station distance. We further describe an approach to mitigate bias from the spatial correlation. Accounting for the spatial covariance of observations can change the event from −0.15 to 0.07 units (10th to 90th percentile) for smaller events (⁠⁠). These smaller events have the largest standard deviations ranging from 0.05 to 0.15 units (10th to 90th percentile).

The Seismic Record

Seismicity and anisotropic imaging reveal an active detachment beneath the northern Alaska Range foothills

North of the Denali Fault, the collision between the Yakutat block with North America is accommodated by a fold-thrust belt giving rise to the northern Alaska Range foothills. At the western end, the Kantishna Hills anticline hosts prominent microseismicity and surface deformation, interpreted as active folding of the Kantishna Hills anticline above a midcrustal detachment. We test for this detachment by using anisotropy-aware receiver functions to image fabric contrasts within the crust in context with seismicity. Seismic stations near the crest of the Kantishna Hills anticline and near its southern flank show a single strong contrast in dipping fabric at depths of 12–13 km near microseismicity clustering depths, consistent with a detachment plane beneath the fold. A minimum b -value at 10–13 km depth is consistent with seismicity on the detachment, compatible with the imaged anisotropic contrast, while off-fault seismicity is shallower and deeper with smaller magnitudes. South-dipping imbricate thrusts in schist characterize the northern Alaska Range foothills structure. This supports our interpretation of the observed anisotropy as reflecting SSW–SSE-dipping foliation above a detachment at ∼10–13 km depth that exploits existing crustal weaknesses along subtle fabric contrasts observed in the seismically quiescent region north of the actively deforming belt.

Alaska

Reconnaissance of the occurrence of agricultural chemicals in ground water in Haywood, Lake, Obion and Shelby Counties, Tennessee

Data on the occurrence of agricultural chemicals in ground wafer in Tennessee are sparse. The surficial alluvial aquifer is an important source of domestic water supply in West Tennessee, and potentially is subject fo contamination from the application of agricultural chemicals in the area. Nineteen shallow wells completed in the alluvial aquifers in areas of high density agricultural use were sampled in the winter and again in the summer of 1988 to ascertain the occurrence of agricultural chemical in ground water. Although no triazine herbicides or organophosphorus insecticides were detected in any of the wells sampled, elevated nitrite plus nitrate (as nitrogen) concentrations were detected. Results from the winter sampling period indicate a range of nitrite plus nitrate (as nitrogen) concentrations of less than 0.1 to 7.8 milligrams per liter with a median concentration of 2.6 milligrams per liter. Results from the summer sampling period indicate a range of nitrite plus nitrate (as nitrogen) concentrations of less than 0.1 to 8.9 milligrams per liter, median, 2.5 milligrams per liter. The highest concentrations occurred in the shallowest wells, and, in one instance, in a shallow well near a heavily irrigated field.

Tennessee

Overstorey mortality promotes juvenile piñon pine growth during favourable weather at cooler, wetter sites

Hotter droughts have resulted in widespread tree die-off events globally, frequently leading to regeneration failure. Dry forest recovery often depends on the growth and survival of extant juvenile trees. However, it is unclear how microenvironmental changes following overstorey tree die-off affect juvenile trees, particularly in dryland systems where tree recruitment is typically limited by water availability and heat stress. We simulated an overstorey tree die-off event by girdling trees in piñon-juniper woodlands across the south-western United States. We sampled juvenile piñon pine growth from live and dead overstorey treatments across six study sites spanning a regional latitudinal gradient and local elevational gradients. We examined how juvenile branch and needle growth differed between live and dead overstorey treatments, and whether responses varied with weather conditions and juvenile tree size following overstorey mortality. We found greater juvenile branch and needle growth under dead compared with live overstorey trees for 2 years following overstorey mortality at mid- and high-elevation sites which are typically cooler and wetter than the other sites. These observed growth releases were contingent on favourable post-mortality weather conditions. Higher growth under dead overstorey occurred at sites experiencing near-average climatic water deficits compared with sites experiencing above-average climatic water deficits. Growth at all sites increased from the first to second year after overstorey mortality. Across sites, growth was unrelated to juvenile tree size. Synthesis . Our results underscore differentiation in juvenile responses to overstorey tree die-off driven by local site conditions and weather across the range of Pinus edulis . Overstorey mortality resulted in consistently higher juvenile growth only at climatically favourable sites and during favourable weather, while unmeasured microsite differences could help account for variation observed at the hottest and driest site. Results from less climatically favourable sites suggest that overstorey trees neither directly limit nor facilitate juvenile growth, though further study over longer timeframes is needed to resolve the pace and magnitude of potential recovery or decline. Overall, juvenile vigour may be promoted following overstorey mortality only in a narrow spatial (site) and temporal (weather) environmental context, suggesting additional vulnerabilities for piñon populations under more arid conditions.

Arizona, Colorado

New constraints on location and timing of the Great Lakes tectonic zone, central Upper Peninsula, Michigan, USA

The Great Lakes tectonic zone (GLTZ) forms the boundary between the Wawa–Abitibi and Minnesota River Valley subprovinces within the Archean Superior Province. The GLTZ is concealed for all of its 1100 km length, except for a segment in the central Upper Peninsula of Michigan. There, it is exposed as a northwest-striking mylonite zone along a 11 km segment, extending to the onlap of Paleozoic rocks to the east. Farther east, its location has been unknown. Here, we use aeromagnetic and gravity data to develop interpretations of the expression of the GLTZ and to define its extent under cover. Aeromagnetic gradients over the mylonite zone are interpreted to be produced by structurally juxtaposed rocks with varying magnetizations. Gravity data show a regional gradient along the GLTZ, produced by the juxtaposition of a dense greenstone belt on the north against lower-density gneisses and granites on the south. The GLTZ is interpreted to extend ∼55 km under cover to the east. The GLTZ is terminated on the east by the buried eastern arm of the ca. 1100 Ma Midcontinent Rift. An undeformed granitic dike that cuts the mylonitic foliation produces a U–Pb apatite age of 2523 ± 33 Ma, implying no major post-Archean shearing occurred, and is at odds with previous interpretations of major Proterozoic reactivation. A granite intrusion in the Minnesota River Valley subprovince produces a Pb–Pb zircon age of 2606.9 ± 3.6/7.4 Ma. This suggests that magmatism related to the Sacred Heart orogeny, previously known in Minnesota, extended to Michigan.

Michigan

Indirect mineral import reliance and provenance

Mineral commodity supply chain analyses rely on international trade data reported by individual countries as quantities of a mineral commodity form imported from (or exported to) a partner. However, export quantities frequently exceed a country’s domestic production, or occur when no production data are reported, suggesting that the trade partner is merely an intermediary in a transshipment. These discrepancies can result in misleading conclusions regarding supply chain vulnerabilities and dependencies. We present a two-stage methodology to reconcile gaps between reported material sources and actual producers. First, we construct trade networks for specific mineral forms, treating production as a type of import to distinguish producing nations from entrepôts. By tracing flows through these networks, we attribute a target country’s imports to original producers via both direct (in a single trade link) and indirect (transferring through intermediaries) pathways. Second, these production-attributed flows are incorporated into multi-stage supply chains to determine the upstream provenance of feedstock for domestic refining and processing. This approach provides a more representative picture of trade reliance. For example, while the United States (U.S.) Geological Survey reports no imports of unwrought antimony metal from Russia in 2022 (U.S. Geological Survey (2025). Mineral Commodity Summaries 2025. 10.3133/mcs2025), our analysis reveals that over 16% of U.S. imports can be traced back to Russian mining through intermediate processing in countries such as China, India, and Vietnam. Additionally, our analysis of the aluminum supply chain shows that while the U.S. is reported as 52% net import reliant on aluminum materials in 2022, it is 100% reliant on foreign bauxite, 7% of which arrived indirectly. This unreported reliance, which is predominantly tied to bauxite mined in Brazil (43%) and Jamaica (28%), highlights our methods ability to capture the supply chain’s dependence on foreign feedstock that may be missing in single-stage trade data.

Mineral Economics

Status and performance of the ShakeAlert® earthquake early warning system: 2019-2023

The U.S. Geological Survey (USGS)‐operated ShakeAlert® system is the United States West Coast earthquake early warning system ( Given et al. , 2018 ). In this study we detail ShakeAlert’s performance during some of the largest events seen by the system thus far. Statewide public alerting using ShakeAlert messages was authorized in California in October 2019. Over the next few years, public alerts were expanded into Oregon and then into Washington ( U.S. Geological Survey, 2024 ). ShakeAlert source results are routinely compared to the USGS Comprehensive Catalog (ComCat; Guy et al. , 2015 ; U.S. Geological Survey, Earthquake Hazards Program, 2017 ), which contains the earthquake location and magnitude determined using complete waveform data. M 4.5 and larger is the threshold used for public alerting and was deliberately set below the level where damage is likely to compensate for cases where the system underestimates the magnitude. Between 17 October 2019 and 1 September 2023, the ShakeAlert system created 95 events with maximum magnitude estimates of M ≥4.5, the public alerting threshold. 94 of the 95 events were due to real earthquakes. Seven were categorized “false” per ShakeAlert’s internal definition that there was no matching catalog event within 100 km and 30 s of origin time; however, all but one of these were real earthquakes that were poorly located, primarily because they were at the edges of the seismic network. Three detected events were labeled “missed” because they were very poorly located (>100 km location error). In addition, the system did not produce solutions for four ComCat events M ≥4.5 ( U.S. Geological Survey, Earthquake Hazards Program, 2017 ), which were all at the edge of the alerting and network boundaries. The ShakeAlert system has accurately detected the majority of earthquakes that have occurred within the operational region since completing the public rollout, and alerts from the system have been delivered to millions of cell phone users throughout the West Coast.

California, Oregon, Washington

Debris-flow entrainment modelling under climate change: Considering antecedent moisture conditions along the flow path

Debris-flow volumes can increase along their flow path by entraining sediment stored in the channel bed and banks, thus also increasing hazard potential. Theoretical considerations, laboratory experiments and field investigations all indicate that the saturation conditions of the sediment along the flow path can greatly influence the amount of sediment entrained. However, this process is usually not considered for practical applications. This study aims to close this gap by combining runout and hydrological models into a predictive framework that is calibrated and tested using unique observations of sediment erosion and debris-flow properties available at a Swiss debris-flow observation station (Illgraben). To this end, hourly water input to the erodible channel is predicted using a simple, process-based hydrological model, and the resulting water saturation level in the upper sediment layer of the channel is modelled based on a Hortonian infiltration concept. Debris-flow entrainment is then predicted using the RAMMS debris-flow runout model. We find a strong correlation between the modelled saturation level of the sediment on the flow path and the channel-bed erodibility for single-surge debris-flow events with distinct fronts, indicating that the modelled water content is a good predictor for erosion simulated in RAMMS. Debris-flow properties with more complex flow behaviour (e.g., multiple surges or roll waves) are not as well predicted using this procedure, indicating that more physically complete models are necessary. Finally, we demonstrate how this modelling framework can be used for climate change impact assessment and show that earlier snowmelt may shift the peak of the debris-flow season to earlier in the year. Our novel modelling framework provides a plausible approach to reproduce saturation-dependent entrainment and thus better constrain event volumes for current and future hazard assessment.

Illgraben basin

Factors regulating the potential for freshwater mineral soil wetlands to function as natural climate solutions

There are increasing global efforts and initiatives aiming to tackle climate change and mitigate its impacts via natural climate solutions (NCS). Wetlands have been considered effective NCS given their capacity to sequester and retain atmospheric carbon dioxide (CO 2 ) while also providing a myriad of other ecosystem functions that can assist in mitigating the impacts of climate change. However, wetlands have a dual impact on climate, influencing the atmospheric concentrations of both CO 2 and methane (CH 4 ). The cooling effect associated with wetland CO 2 sequestration can be counterbalanced by the warming effect caused by CH 4 emissions from wetlands. The relative ability of wetlands to sequester CO 2 versus emit CH 4 is dependent on a suite of interacting physical, chemical, and biological factors, making it difficult to determine if/which wetlands are considered important NCS. The fact that wetlands are embedded in landscapes with surface and subsurface hydrological connections to other wetlands (i.e., wetlandscapes) that flow over and through geochemically active soils and sediments adds a new layer of complexity and poses further challenges to understanding wetland carbon sequestration and greenhouse gas fluxes at large spatial scales. Our review demonstrates how additional scientific advances are required to understand the driving mechanisms associated with wetland carbon cycling under different environmental conditions. It is vital to understand wetland functionality at both wetland and wetlandscape scales to effectively implement wetlands as NCS to maximize ecological, social, and economic benefits.

Wetlands

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas

Earthquake cycle mechanics during caldera collapse: Simulating the 2018 Kīlauea eruption

In multiple observed caldera-forming eruptions, the rock overlying a draining magma reservoir dropped downward along ring faults in sequences of discrete collapse earthquakes. These sequences are analogous to tectonic earthquake cycles and provide opportunities to examine fault mechanics and collapse eruption dynamics over multiple events. Collapse earthquake cycles have been studied with zero-dimensional slider-block models, but these do not account for the complicated interplay between fluid and elastic dynamics or for factors such as the heterogeneous fault properties and non-vertical ring fault geometries often inferred at volcanoes. We present two-dimensional axisymmetric mafic piston-like collapse earthquake cycle models that include rate-and-state friction, fully-dynamic elasticity, and compressible viscous fluid magma flow. We demonstrate that collapse earthquake intervals and magnitudes are highly sensitive to inertial effects, evolving stress fields, fault geometry, and depth-varying fault friction. Given the consistent earthquake cycles observed in most eruptions, this suggests that ring faults can quickly stabilize and often become nearly vertical at depth. We use the well-monitored 2018 collapse sequence at Kı̄lauea as a case study. Our model can produce many features of Kı̄lauea seismic and geodetic observations, except for a significant amount of interseismic slip, which cannot be readily explained with simple rate-and-state friction parameterizations.

Hawaii

Wetland sedimentation and vegetation patterns near selected highway crossings in West Tennessee

Wetland sedimentation and vegetation patterns at 11 highway crossings in West Tennessee were studied from 1987 to 1989. The purpose of the study was to investigate potential adverse effects of highway crossings on wetlands. Sedimentation rates, determined from root-burial depths, were highly variable. Average rates offine-grained deposition ranged from 0.005 to 0.033 foot per year for stations in locally ponded areas and from -0.002 to 0.039 foot per year for stations in drained areas. Sedimentation rates upstream from highway crossings were not significantly different from downstream rates at 8 of the 11 study sites. Three study sites had significantly greater sedimentation rates downstream. Sand splays were observed downstream from bridges at most study sites. Vegetation patterns and tree growth appear most strongly related to hydropetiod, defined as the average length of time an area is covered by water each year. The influence of sedimentation on tree growth is difficult to separate from the influence of hydroperiod because areas with high sedimentation rates typically have long hydroperiods. Estimated hydroperiod increased no more than 1 percent because of backwater from the highway crossings at the 11 study sites, while the estimated average depth of flood-plain inundation increased by an average of 6 percent.

Tennessee

Shoals and valley plugs in the Hatchie River watershed

Agricultural land use and gully erosion have historically contributed more sediment to the streams of the Hatchie River watershed than those streams can carry. In 1970, the main sedimentation problem in the watershed occurred in the tributary flood plains. This problem motivated channelization projects (U.S. Department of Agriculture, 1970). By the mid-1980's, concern had shifted to sedimentation in the Hatchie River itself where channelized tributaries were understood to contribute much of the sediment. The Soil Conservation Service [Natural Resources Conservation Service (NRCS) since 1996] estimated that 640,000 tons of bedload (sand) accumulates in the Hatchie River each year and identified roughly the eastern two-thirds of the watershed, where loess is thin or absent, as the main source of sand (U.S. Department of Agriculture, 1986a). The U.S. Geological Survey (USGS), in cooperation with the West Tennessee River Basin Authority (WTRBA), conducted a study of sediment accumulation in the Hatchie River and its tributaries. This report identifies the types of tributaries and evaluates sediment, shoal formation, and valley-plug problems. The results presented here may contribute to a better understanding of similar problems in West Tennessee and the rest of the southeastern coastal plain. This information also will help the WTRBA manage sedimentation and erosion problems in the Hatchie River watershed. The source of the Mississippi section of the Hatchie River is in the sand hills southwest of Corinth, Mississippi (fig. 1). This section of the Hatchie River flows northward in an artificial drainage canal, gathering water from tributary streams that also are channelized. The drainage canal ends 2 miles south of the Tennessee State line. The Tennessee section of the Hatchie River winds north and west in a meandering natural channel to the Mississippi River. Although most of the Hatchie River tributaries are also drainage canals, the river's main stem has kept most of its natural character. The Hatchie River flows through a wide valley bottom occupied mostly by riverine wetland. Historically, the valley bottom has supported hardwood forests. Since publication of the first Hatchie River report (U.S. Department of Agriculture, 1970), the channel of the river has become shallower, and flooding has increased (U.S. Department of Agriculture 1986b). These wetter conditions inhibit growth of hardwoods and lead to premature hardwood mortality. The NRCS has predicted that despite efforts to control erosion in the uplands, most of the valley-bottom forest will die. '...swamping may be so prevalent as to change most of the Hatchie River Basin flood plain into a marsh condition, with the only remnants of the present bottomland hardwood timber remaining. (U.S. Department of Agriculture, 1986b). Loss of channel depth has been concentrated in short reaches near tributary mouths. At the mouths of Richland, Porters, Clover, and Muddy Creeks, navigation has become difficult for recreational users (Johnny Carlin, West Tennessee River Basin Authority, oral commun., 1998). As the low-gradient alluvial system of the Hatchie River accumulates sediment, another common outcome has been the formation of valley plugs, areas where 'channels are filled with sediment, and all the additional bedload brought downstream is then spread out over the flood plain until a new channel has been formed' (Happ, 1975). Valley plugs typically form where the slope of a sand-laden tributary decreases downstream, or where the tributary joins its parent stream (Happ and others, 1940; Diehl, 1994, 1997; Smith and Diehl, 2000).

Mississippi, Tennessee

Critical mineral inventory of select IOA-IOCG deposits, southwestern USA

Critical minerals are necessary for modern technology and strategic purposes. Their increasing importance requires finding new and nontraditional resources. Samples of ore, altered, and unaltered host rock were collected from 26 iron mines and prospects in California, Nevada, and Utah to assess the potential of these deposits to host economic quantities of different critical minerals. Geochemical analyses were conducted by 61 element ICP-OES-MS sodium peroxide fusion and major elements determined by WDXRF. These deposits concentrated many critical minerals beyond what is found in average upper crustal abundances, such as Sb, As, Bi, Co, Ga, Mg, Mn, Ni, Nb, Pd, REE, Sc, Te, Sn, Ti, W, V, and Zn. However, most of these are not concentrated enough in the ore to be considered as economic resources. Those critical minerals that are enriched enough in some of these deposits to possibly be considered as by-product commodities are Ni, REE, V, and potentially Co and Ga. These enrichments were not uniform, with REE more likely to be enriched in IOA deposits, whereas Co, Ga, Ni, and V could be found enriched in either IOA or IOCG deposits.

California, Nevada, Utah

Hydrogeology of the Chickasaw National Recreation Area, Murray County, Oklahoma

The Travertine District (Park) of the Chickasaw National Recreation Area, operated and maintained by the National Park Service, is near the City of Sulphur in south-central Oklahoma. The Park was established in 1902 because of its unique hydrologic setting, which includes Rock Creek, Travertine Creek, numerous mineralized and freshwater springs, and a dense cover of riparian vegetation. Since the turn of the century several flowing artesian wells have been drilled within and adjacent to the Park. Discharge from many of these springs and the numbers of flowing wells have declined substantially during the past 86 years. To determine the cause of these declines, a better understanding of the hydrologic system must be obtained. The U.S. Geological Survey, in cooperation with the National Park Service, has appraised hydrologic information obtained for the Park from several studies conducted during 1902-87. The principal geologic units referred to in this report are the Arbuckle Group and the overlying Simpson Group. These rocks are of Upper Cambrian to Middle Ordovician age and are composed of dolomitic limestone, with some sandstones and shales in the Simpson Group. Surface geologic maps give a general understanding of the regional subsurface geology, but information about the subsurface geology within the Park is poor. The Simpson and Arbuckle aquifers are the principal aquifers in the study area. The two aquifers are not differentiated readily in some parts of the study area because of the similarity of the Simpson and Arbuckle rocks; thus, both water-bearing units are referred to frequently as the Arbuckle-Simpson aquifer. The aquifers are confined under the Park, but are unconfined east and south of the Park. Precipitation on the outcrop area of the Arbuckle aquifer northeast and east of the Park recharges the freshwater springs (Antelope and Buffalo Springs) near the east boundary of the Park. The source of water from mineralized springs located in the central part of the Park, and flowing wells within and north of the Park, is believed to be a mix of waters from rocks of the Arbuckle and Simpson Groups. The source of water from two highly mineralized springs, Bromide and Medicine, that ceased to flow in the early 1970’s is believed to be from the Simpson Group. Water-quality characteristics reflect the sources of ground water in the study area. The highly mineralized springs near the western end of the Park are a sodium chloride type with dissolved solids greater than 4,500 mg/L. The freshwater springs near the eastern end of the Park are a calcium bicarbonate type with total dissolved solids of less than 400 mg/L. Flow from the artesian wells has declined substantially during the past 86 years and the wells are estimated to currently discharge only about 10 percent of the total flow reported in 1939. The depletion is believed to be caused by a gradual lowering of the hydraulic head within the aquifer. The influence on the hydrologic system of local municipal and industrial pumping from the Arbuckle-Simpson aquifer is difficult to discern because the system is much more sensitive to precipitation than to pumpage. Ground-water levels and spring flows in this region respond rapidly to precipitation. The effects of withdrawals from the City of Sulphur and Oklahoma Gas and Electric Company power-plant water-well fields are not discernible at wells and springs. The hydrologic system may be influenced by pumping, particularly during extended dry periods of several years, but the impact of pumping on the system cannot be determined without further investigation.

Oklahoma

Neotectonic mapping of Puerto Rico

Puerto Rico is part of the Puerto Rico-Virgin Islands microplate, along the Caribbean–North American plate boundary between the Puerto Rico trench subduction zone and the Muertos Trough incipient subduction zone. Despite recent seismicity and geodetically constrained deformation of ~3 mm/yr of left-lateral shear across the island, Quaternary fault locations remain largely uncertain. Preservation of recent faulting in the landscape is masked by distributed faulting, high weathering rates of the tropical climate, steep topography, frequent landsliding, and extensive agriculture and urbanization along coastlines and river valleys. We present remote neotectonic mapping of historical aerial imagery from the 1930s-60s and <1-m lidar topography, integrated with field observations, to create an updated active fault map of Puerto Rico. We focus on faults that offset younger geomorphic surfaces, with ages estimated by geologic mapping, OSL and radiocarbon dating, and morphologic interpretations. We present new evidence for Quaternary activity on seven faults, including the South Lajas, Salinas, Punta Montalva, Great Southern Puerto Rico, Cerro Goden, Parguera, and San Marcos faults. We find that active faulting occurs preferentially along the southern and western coasts and does not always spatially coincide with preexisting bedrock faults, possibly reflecting partial reactivation of older faults in the modern strain field.

Puerto Rico