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Ground-water hydraulics, regional flow, and ground-water development of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

The Floridan aquifer system is one of the major sources of groundwater supplies in the United States. This productive aquifer system underlies all of Florida, southeast Georgia, and small parts of adjoining Alabama and South Carolina, for a total area of about 100,000 square miles. About 3 billion gallons of water per day were withdrawn from the aquifer system in 1980, and in many areas the Floridan is the sole source of freshwater. The Floridan aquifer system is a sequence of hydraulically connected carbonate rocks (principally limestone with some dolomite) ranging in age generally from late Paleocene to early Miocene. The rocks vary in thickness from a featheredge where they crop out to more than 3,500 feet where the aquifer is deeply buried. The aquifer system generally consists of an upper aquifer and a lower aquifer separated by a lesspermeable confining unit of highly variable properties. In parts of north Florida and southwest Georgia, where little permeability contrast exists among the units, the Floridan is effectively one continuous aquifer. The upper and lower aquifers, named the Upper Floridan aquifer and the Lower Floridan aquifer, are defined on the basis of permeability and their boundaries locally do not coincide with those for either time-stratigraphic or rock-stratigraphic units. Overlying much of the Floridan aquifer system are low-permeability clastic rocks. The lithology, thickness, and integrity of these rocks determine the degree of confinement and influence the distribution of natural recharge, discharge, and ground-water flow in the Floridan. The permeability of the Floridan aquifer system is derived from small openings including fossil hashes and solution-widened joints as well as large cavernous openings in karst areas. Diffuse flow predominates where the small openings occur, whereas conduit flow may occur where large cavernous openings are. Transmissivities are highest (greater than 1,000,000 feet squared per day) in the unconfined karst areas of central and northern Florida. Lowest transmissivities (less than 50,000 feet squared per day) occur in panhandle Florida and southernmost Florida where the Upper Floridan aquifer is confined by thick clay sections. The hydraulic properties of the Lower Floridan aquifer are not well known; however, intervals of high transmissivity occur that have been attributed to paleokarst development. Springs, nearly all of which occur in unconfined and semiconfined parts of the Upper Floridan aquifer in Florida are the dominant feature of the Floridan flow system. Before ground-water development, spring flow and point discharge to surface-water bodies were about 88 percent of the estimated 21,500 cubic feet per second total discharge, or about 19,000 cubic feet per second. Diffuse upward leakage, which occurs primarily in confined areas, accounted for the remaining 12 percent or about 2,500 cubic feet per second. Most of the recharge necessary to sustain springflow and aquifer discharge to streams and lakes occurs relatively close to springs and areas of point discharge to surface-water bodies. Recharge to the Upper Floridan is highest, averaging 10-20 inches per year, in unconfined or semiconfined spring areas. The proximity of high recharge to high discharge implies a vigorous and well-developed shallow flow system in the unconfined and semiconfined parts of the Upper Floridan aquifer. Ground-water flow is very sluggish in the parts of the aquifer system that are deeply buried and tightly confined, primarily southeast Georgia and northeast Florida, south Florida, and far-west panhandle Florida. Discharge to springs, streams, and lakes is practically nonexistent in the tightly confined areas and natural discharge occurs almost exclusively by diffuse upward leakage through thick overburden. The regional flow system has not been appreciably altered by groundwater development. However, increasing pumpage that reached 3 billion gallons per day by 1980 has resulted in long-term regional water level decline of more than 10 feet in three broad areas: coastal Georgia, adjacent South Carolina, and northeast Florida; west-central Florida; and panhandle Florida. Saltwater encroachment as a result of pumping has occurred locally in coastal areas. Pumpage from the Upper Floridan aquifer is supplied primarily by reduction of natural discharge and by increased recharge rather than by depletion of aquifer storage. About 20 percent is from reduced discharge to springs, streams, and lakes, about 20 percent is from reduced upward leakage, and about 60 percent is from increased recharge. Compared to predevelopment conditions, discharge to springs, streams, and lakes is reduced by less than 5 percent, upward leakage is reduced by about 30 percent, and recharge is increased by about 12 percent. Total recharge and, therefore, discharge increased from a predevelopment rate of 21,500 cubic feet per second to about 24,100 cubic feet per second by 1980. A considerable area remains of the Floridan aquifer system where large ground-water supplies may be developed. This area is largely inland from the coasts and characterized by high transmissivity and minimal development prior to the early 1980's. The major constraint on future development probably is degradation of water quality rather than water-quantity limitations.

Alabama, Florida, Georgia, South Carolina↗

Estimation of groundwater use for a groundwater-flow model of the Lake Michigan Basin and adjacent areas, 1864-2005

The U.S. Geological Survey, at the request of Congress, is assessing the availability and use of the Nation's water resources to help characterize how much water is available now, how water availability is changing, and how much water can be expected to be available in the future. The Great Lakes Basin Pilot project of the U.S. Geological Survey national assessment of water availability and use focused on the Great Lakes Basin and included detailed studies of the processes governing water availability in the Great Lakes Basin. One of these studies included the development of a groundwater-flow model of the Lake Michigan Basin. This report describes the compilation and estimation of the groundwater withdrawals in those areas in Wisconsin, Michigan, Indiana, and Illinois that were needed for the Lake Michigan Basin study groundwater-flow model. These data were aggregated for 12 model time intervals spanning 1864 to 2005 and were summarized by model area, model subregion, category of water use, aquifer system, aquifer type, and hydrogeologic unit model layer. The types and availability of information on groundwater withdrawals vary considerably among states because water-use programs often differ in the types of data collected and in the methods and frequency of data collection. As a consequence, the methods used to estimate and verify the data also vary. Additionally, because of the different sources of data and different terminologies applied for the purposes of this report, the water-use data published in this report may differ from water-use data presented in other reports. These data represent only a partial estimate of groundwater use in each state because estimates were compiled only for areas in Wisconsin, Michigan, Indiana, and Illinois within the Lake Michigan Basin model area. Groundwater-withdrawal data were compiled for both nearfield and farfield model areas in Wisconsin and Illinois, whereas these data were compiled primarily for the nearfield model area in Michigan and Indiana. Overall water use for the selected areas in Wisconsin, Michigan, Indiana, and Illinois was less during early time intervals than during more recent intervals, with large increases beginning around the 1960s. Total estimated groundwater withdrawals for model input range from 18.01 million gallons per day (Mgal/d) for interval 1 (1864-1900) to 1,280.25 Mgal/d for interval 12 (2001-5). Withdrawals for the public-supply category make up the majority of the withdrawals in each of the four states. In Wisconsin and Michigan, the second largest withdrawals are for the irrigation category; in Indiana and Illinois, industrial withdrawals account for the second largest withdrawal amounts. The smallest withdrawals are for miscellaneous uses in Wisconsin and irrigation uses in Indiana and Illinois. Estimated groundwater withdrawals in the Southern Lower Peninsula of Michigan, Northeastern Illinois, and the farfield model area are generally larger than in the other model subregions. Withdrawals in Michigan and Indiana are predominantly from the Quaternary aquifer system, whereas withdrawals in Illinois are predominantly from the Cambrian-Ordovician aquifer systems. Withdrawals in Wisconsin are about equal from the Quaternary and Cambrian-Ordovician aquifer systems. Estimated groundwater withdrawals in Michigan and Indiana are predominantly from the unconfined unconsolidated aquifer type. Withdrawals in Illinois are largely from the deep confined bedrock aquifer type, although they decreased considerably in more recent time intervals. Wisconsin withdrawals are about equal from unconfined unconsolidated and deep confined bedrock aquifer types. Groundwater-withdrawal estimates in Wisconsin were compiled for the 47 easternmost counties within the boundary of the Lake Michigan Basin model, of which 32 counties, though not entirely contained, are at least partly within the Lake Michigan Basin. Overall, 6,457 withdrawal locations were estima

Scientific Investigations Report↗

Ground-water quality and geochemistry of Las Vegas Valley, Clark County, Nevada, 1981-83: Implementation of a monitoring network

As a result of rapid urban growth in Las Vegas Valley, rates of water use and wastewater disposal have grown rapidly during the last 25 years. Concern has developed over the potential water quality effects of this growth. The deep percolation of wastewater and irrigation return flow (much of which originates as imported water from Lake Mead), along with severe overdraft conditions in the principal aquifers of the valley, could combine to pose a long-term threat to groundwater quality. The quantitative investigations of groundwater quality and geochemical conditions in the valley necessary to address these concerns would include the establishment of data collection networks on a valley-wide scale that differ substantially from existing networks. The valley-wide networks would have a uniform areal distribution of sampling sites, would sample from all major depth zones, and would entail repeated sampling from each site. With these criteria in mind, 40 wells were chosen for inclusion in a demonstration monitoring network. Groundwater in the northern half of the valley generally contains 200 to 400 mg/L of dissolved solids, and is dominated by calcium, magnesium , and bicarbonate ions, reflecting a chemical equilibrium between the groundwater and the dominantly carbonate rocks in the aquifers of this area. The intermediate to deep groundwater in the southern half of the valley is of poorer quality (containing 700 to 1,500 mg/L of dissolved solids) and is dominated by calcium, magnesium, sulfate, and bicarbonate ions, reflecting the occurrence of other rock types including evaporite minerals among the still-dominant carbonate rocks in the aquifers of this part of the valley. The poorest quality groundwater in the valley is generally in the lowland parts of the valley in the first few feet beneath the water table, where dissolved solids concentrations range from 2,000 to > 7,000 mg/L , and probably reflects the effects of evaporite dissolution, secondary recharge, and evapotranspiration. The most common water quality constraint on potential groundwater use is the high salinity. No evidence of large-scale contamination of deep groundwater was found in this study.

Nevada↗

Potentiometric surface, ground-water withdrawals, and recharge area for the Lisbon aquifer in Alabama, fall 1982

The U.S. Geological Survey began a nationwide program in 1978, termed Regional Aquifer-System Analysis (RASA), to study a number of the major aquifer systems that provide a significant part of the country 's water supply. One of the aquifer systems chosen for study was the thick and extensive sequence of sands of Cretaceous and early Tertiary age that underlies the Coastal Plain of the southeastern United States. This system, which extends from Mississippi eastward to South Carolina, is called the Southeastern Coastal Plain aquifer system. It can be divided geohydrologically into several separate aquifers. The map presented, one of a series that portray the potentiometric surface, groundwater withdrawals, and recharge areas for aquifers in Alabama that are included in the regional system, deals with the Lisbon aquifer. (Lantz-PTT)

Water-Resources Investigations Report↗

Effects of structure and volcanic stratigraphy on groundwater and surface water flow: Hat Creek basin, California, USA

Hydrogeologic systems in the southern Cascade Range in California (USA) develop in volcanic rocks where morphology, stratigraphy, extensional structures, and attendant basin geometry play a central role in groundwater flow paths, groundwater/surface-water interactions, and spring discharge locations. High-volume springs (greater than 3 m 3 /s) flow from basin-filling (<800 ka) volcanic rocks in the Hat Creek and Fall River tributaries and contribute approximately half of the average annual flow of the Pit River, the largest tributary to Shasta Lake. A hydrogeologic conceptual framework is constructed for the Hat Creek basin combining new geologic mapping, water-well lithologic logs, a database of active faults, LiDAR mapping of faults and volcanic landforms, streamflow measurements and airborne thermal infrared remote sensing of stream temperature. These data are used to integrate the geologic structure and the volcanic and volcaniclastic stratigraphy to create a three-dimensional interpretation of the hydrogeology in the basin. Two large streamflow gains from focused groundwater discharge near Big Spring and north of Sugarloaf Peak result from geologic barriers that restrict lateral groundwater flow and force water into Hat Creek. The inferred groundwater-flow barriers divide the aquifer system into at least three leaky compartments. The two downstream compartments lose streamflow in the upstream reaches (immediately downstream of the groundwater-flow barriers) and gain in downstream reaches with the greatest inflows immediately upstream of the barriers.

California↗

Hydrogeology, hydrologic effects of development, and simulation of groundwater flow in the Borrego Valley, San Diego County, California

Executive Summary The Borrego Valley is a small valley (110 square miles) in the northeastern part of San Diego County, California. Although the valley is about 60 miles northeast of city of San Diego, it is separated from the Pacific Ocean coast by the mountains to the west and is mostly within the boundaries of Anza-Borrego Desert State Park. From the time the basin was first settled, groundwater has been the only source of water to the valley. Groundwater is used for agricultural, recreational, and municipal purposes. Over time, groundwater withdrawal through pumping has exceeded the amount of water that has been replenished, causing groundwater-level declines of more than 100 feet in some parts of the basin. Continued pumping has resulted in an increase in pumping lifts, reduced well efficiency, dry wells, changes in water quality, and loss of natural groundwater discharge. As a result, the U.S. Geological Survey began a cooperative study of the Borrego Valley with the Borrego Water District (BWD) in 2009. The purpose of the study was to develop a greater understanding of the hydrogeology of the Borrego Valley Groundwater Basin (BVGB) and to provide tools to help evaluate the potential hydrologic effects of future development. The objectives of the study were to (1) improve the understanding of groundwater conditions and land subsidence, (2) incorporate this improved understanding into a model that would assist in the management of the groundwater resources in the Borrego Valley, and (3) use this model to test several management scenarios. This model provides the capability for the BWD and regional stakeholders to quantify the relative benefits of various options for increasing groundwater storage. The study focuses on the period 1945&ndash;2010, with scenarios 50 years into the future. This report documents and presents (1) an analysis of the conceptual model, (2) a description of the hydrologic features, (3) a compilation and analysis of water-quality data, (4) the measurement and analysis of land subsidence by using geophysical and remote sensing techniques, (5) the development and calibration of a two-dimensional borehole-groundwater-flow model to estimate aquifer hydraulic conductivities, (6) the development and calibration of a three-dimensional (3-D) integrated hydrologic flow model, (7) a water-availability analysis with respect to current climate variability and land use, and (8) potential future management scenarios. The integrated hydrologic model, referred to here as the &ldquo;Borrego Valley Hydrologic Model&rdquo; (BVHM), is a tool that can provide results with the accuracy needed for making water-management decisions, although potential future refinements and enhancements could further improve the level of spatial and temporal resolution and model accuracy. Because the model incorporates time-varying inflows and outflows, this tool can be used to evaluate the effects of temporal changes in recharge and pumping and to compare the relative effects of different water-management scenarios on the aquifer system. Overall, the development of the hydrogeologic and hydrologic models, data networks, and hydrologic analysis provides a basis for assessing surface and groundwater availability and potential water-resource management guidelines.

California↗

A plan for study of hexavalent chromium, CR(VI) in groundwater near a mapped plume, Hinkley, California, 2016

The Pacific Gas and Electric Company (PG&E) Hinkley compressor station, in the Mojave Desert 80 miles northeast of Los Angeles, is used to compress natural gas as it is transported through a pipeline from Texas to California. Between 1952 and 1964, cooling water used at the compressor station was treated with a compound containing chromium to prevent corrosion. After cooling, the wastewater was discharged to unlined ponds, resulting in contamination of soil and groundwater in the underlying alluvial aquifer (Lahontan Regional Water Quality Control Board, 2013). Since 1964, cooling-water management practices have been used that do not contribute chromium to groundwater. In 2007, a PG&E study of the natural background concentrations of hexavalent chromium, Cr(VI), in groundwater estimated average concentrations in the Hinkley area to be 1.2 micrograms per liter (μg/L), with a 95-percent upper-confidence limit of 3.1 μg/L (CH2M-Hill, 2007). The 3.1 μg/L upper-confidence limit was adopted by the Lahontan Regional Water Quality Control Board (RWQCB) as the maximum background concentration used to map the plume extent. In response to criticism of the study’s methodology, and an increase in the mapped extent of the plume between 2008 and 2011, the Lahontan RWQCB (Lahontan Regional Water Quality Control Board, 2012) agreed that the 2007 PG&E background-concentration study be updated. The purpose of the updated background study is to evaluate the presence of natural and man-made Cr(VI) near Hinkley, Calif. The study also is to estimate natural background Cr(VI) concentrations in the aquifer upgradient and downgradient from the mapped Cr(VI) contamination plume, as well as in the plume and near its margins. The study was developed by the U.S. Geological Survey (USGS) in collaboration with a technical working group (TWG) composed of community members, the Independent Review Panel (IRP) Manager (Project Navigator, Ltd.), the Lahontan RWQCB, PG&E, and consultants for PG&E.&E.

California↗

Quality of groundwater used for public supply in the continental United States: A comprehensive assessment

The presence of contaminants in a source water can constrain its suitability for drinking. The quality of groundwater used for public supply was assessed in 25 principal aquifers (PAs) that account for 84% of groundwater pumped for public supply in the U.S. (89.6 million people on a proportional basis). Each PA was sampled across its lateral extent using an equal-area grid, typically with 60 wells per PA. Samples were analyzed for 502 constituents, of which 374 had either a regulatory or nonregulatory human health benchmark (HHB). Nationally, elevated concentrations (relative to HHBs) of geogenic constituents have a larger effect than anthropogenic constituents, as indicated by three metrics: detection frequency, 35% versus 8.1%; prevalence (based on area), 41% versus 6.4%; and population potentially affected, 31.2 million versus 7.1 million. Prevalence of any constituent at elevated concentrations was high─40 to 75%─in PAs comprising unconsolidated sediment (eight PAs) and sandstone or interbedded sandstones and carbonates (four PAs) in the West and Central Interior. Prevalence was lower─15 to 35%─in PAs comprising sediment and sedimentary rocks along the Gulf and Atlantic Coasts (four PAs), carbonates distributed across the continental U.S. (seven PAs), and hard rock (two PAs).

continental United States↗

Geohydrology of the stratified-drift aquifer system in the lower Sixmile Creek and Willseyville Creek trough, Tompkins County, New York

In 2002, the U.S. Geological Survey, in cooperation with the Tompkins County Planning Department began a series of studies of the stratified-drift aquifers in Tompkins County to provide geohydrologic data for planners to develop a strategy to manage and protect their water resources. This aquifer study in lower Sixmile Creek and Willseyville Creek trough is the second in a series of aquifer studies in Tompkins County. The study area is within the northern area of the Appalachian Plateau and extends about 9 miles from the boundary between Tompkins County and Tioga County in the south to just south of the City of Ithaca in the north. In lower Sixmile Creek and Willseyville Creek trough, confined sand and gravel aquifers comprise the major water-bearing units while less extensive unconfined units form minor aquifers. About 600 people who live in lower Sixmile Creek and Willseyville Creek trough rely on groundwater from the stratified-drift aquifer system. In addition, water is used by non-permanent residents such as staff at commercial facilities. The estimated total groundwater withdrawn for domestic use is about 45,000 gallons per day (gal/d) or 0.07 cubic foot per second (ft3/s) based on an average water use of 75 gal/d per person for self-supplied water systems in New York. Scouring of bedrock in the preglacial lower Sixmile Creek and Willseyville Creek valleys by glaciers and subglacial meltwaters truncated hillside spurs, formed U-shaped, transverse valley profiles, smoothed valley walls, and deepened the valleys by as much as 300 feet (ft), forming a continuous trough. The unconsolidated deposits in the study area consist mostly of glacial drift, both unstratified drift (till) and stratified drift (laminated lake, deltaic, and glaciofluvial sediments), as well as some post-glacial stratified sediments (lake-bottom sediments that were deposited in reservoirs, peat and muck that were deposited in wetlands, and alluvium deposited by streams). Multiple advances and retreats of the ice in the study area resulted in several sequences of various types of glacial deposits. A large moraine (Valley Heads Moraine) dominates the southern part of the study area, a large delta dominates the central part, and ground moraine (mostly till) dominates the northern part. Glacial sediments in the center of the lower Sixmile Creek and Willseyville Creek trough typically range from 150 to 200 ft but can be greater than 300 ft in some places. Where the sediments are composed of sand and gravel they form aquifers. In most parts of the lower Sixmile Creek and Willseyville Creek trough, there is an upper and a basal confined aquifer. However, underlying the central parts of the Brooktondale delta, there are as many as four confined aquifers, whereas in the northern part of the study area, only one extensive confined aquifer is present. The major sources of recharge to these confined aquifers are (1) direct infiltration of precipitation where confined aquifers crop out at land surface (mostly along the western trough wall in the southern and central parts of the study area and, to a lesser degree, along the eastern trough wall); (2) unchanneled surface and subsurface runoff from adjacent upland areas that seeps into the aquifer along the western trough walls; (3) subsurface flow from underlying till or bedrock at the lateral contacts at trough walls; (4) adjacent fine-grained stratified drift, especially when the aquifer is pumped; and (5) discharge from bedrock at the bottom and sides of the trough. In the central part of the study area, the surficial coarse-grained sediments (sand and gravel) comprise a delta near Brooktondale and form a small unconfined aquifer (0.3 square mile). Although much of the upper part of the delta has been removed by several aggregate mining operations, sufficient amounts of sand and gravel remain in most places to form a thin unconfined aquifer. The major sources of recharge to the unconfined aquifer are (1)

Scientific Investigations Report↗

Aquifer-system compaction, Tucson Basin and Avra Valley, Arizona

Groundwater declines of several ft/yr since the 1940 's have induced aquifer-system compaction and land subsidence of as much as 0.5 ft in the Tucson basin and 1.1 ft in Avra Valley, Arizona. Aquifer system compaction is affected by the layering, hydraulic diffusivity, preconsolidation-stress threshold, and stress history of the aquifer system. Layering at extensometer sites can be categorized into three general groups that typify the fine-grained and coarse-grained layering within the Fort Lowell Formation and upper Tinaja beds. Data from the first group show almost as much elastic as inelastic compaction, a layering frequency of six layers/100 ft, and weighted-average aquitard thicknesses of 20 to 50 ft. Data from the second group show inelastic compaction, a layering frequency of two to three layers/100 ft, an average aquitard thickness of less than 20 ft. Data from the third group show inelastic compaction, a layering frequency of fewer than two layers/100 ft, an average aquitard thickness of more than 30 ft. A one-dimensional compaction model was applied to data from six extensometers to simulate aquifer-system compaction of less than 0.1 ft. Values of elastic and some values of inelastic specific storage are comparable to values estimated in California. Parts of the aquifer system appear to be in transition from predominantly elastic to inelastic compaction. Water level declines since 1940 at six extensometer sites are within an estimated preconsolidation-stress threshold of 50 to 150 ft. (USGS)

Water-Resources Investigations Report↗

Hydrogeology and flow of water in a sand and gravel aquifer contaminated by wood-preserving compounds, Pensacola, Florida

The sand and gravel aquifer in southern Escambia County, Florida , is a typical surficial aquifer composed of quartz sands and gravels interbedded locally with silts and clays. Problems of groundwater contamination from leaking surface impoundments are common in surficial aquifers and are a subject of increasing concern and attention. A potentially widespread contamination problem involves organic chemicals from wood-preserving processes. Because creosote is the most extensively used industrial preservative in the United States, an abandoned wood-treatment plant near Pensacola was chosen for investigation. This report describes the hydrogeology and groundwater flow system of the sand and gravel aquifer near the plant. A three-dimensional simulation of groundwater flow in the aquifer was evaluated under steady-state conditions. The model was calibrated on the basis of observed water levels from January 1986. Calibration criteria included reproducing all water levels within the accuracy of the data (one-half contour interval in most cases). Sensitivity analysis showed that the simulations were most sensitive to recharge and vertical leakance of the confining units between layers 1 and 2, and relatively insensitive to changes in hydraulic conductivity and transmissivity and to other changes in vertical leakance. Applications of the results of the calibrated flow model in evaluation of solute transport may require further discretization of the contaminated area, including more sublayers, than were needed for calibration of the groundwater flow system itself. (USGS)

Water-Resources Investigations Report↗

Geochemical Modeling of the Madison Aquifer in Parts of Montana, Wyoming, and South Dakota

Stable isotope data for dissolved carbonate, sulfate, and sulfide are combined with water composition data to construct geochemical reaction models along eight flow paths in the Madison aquifer in parts of Wyoming, Montana, and South Dakota. The sulfur isotope data are treated as an isotope dilution problem, whereas the carbon isotope data are treated as Rayleigh distillations. All reaction models reproduce the observed chemical and carbon and sulfur isotopic composition of the final waters and are partially validated by predicting the observed carbon and sulfur isotopic compositions of dolomite and anhydrite from the Madison Limestone. The geochemical reaction models indicate that the dominant groundwater reaction in the Madison aquifer is dedolomitization (calcite precipitation and dolomite dissolution driven by anhydrite dissolution). Sulfate reduction, [Ca 2+ + Mg 2+ ]/Na + cation exchange, and halite dissolution are locally important, particularly in central Montana. The groundwater system is treated as closed to CO 2 gas from external sources such as the soil zone or cross‐formational leakage but open to CO 2 from oxidation of organic matter coupled with sulfate reduction and other redox processes occurring within the aquifer. The computed mineral mass transfers and modeled sulfur isotopic composition of Madison anhydrites are mapped throughout the study area. Carbon 14 groundwater ages, adjusted for the modeled carbon mass transfer, range from modern to about 23,000 years B.P. and indicate flow velocities of 7–87 ft/yr (2.1–26.5 m/yr). Most horizontal hydraulic conductivities calculated from Darcy's Law using the average 14 C flow velocities are within a factor of 5 of those based on digital simulation. The calculated mineral mass transfer and adjusted 14 C groundwater ages permit determination of apparent rates of reaction in the aquifer. The apparent rate of organic matter oxidation is typically 0.12 μmol/L/yr. Sulfate and, to a lesser extent, ferric iron are the predominant electron acceptors. The (kinetic) biochemical fractionation of 34 S between sulfate and hydrogen sulfide is approximately −44‰ at 25°C, with a temperature variation of −0.4‰ per °C. The rates of precipitation of calcite and dissolution of dolomite and anhydrite typically are 0.59, 0.24, and 0.95 μmol/L/yr, respectively. This paper is not subject to U.S. copyright. Published in 1990 by the American Geophysical Union.

Montana, Wyoming, South Dakota↗

Potentiometric surfaces, 2011–12, and water-level differences between 1995 and 2011–12, in wells of the “200-foot,” “500-foot,” and “700-foot” sands of the Lake Charles area, southwestern Louisiana

Water levels were determined in 90 wells to prepare 2011–12 potentiometric surfaces focusing primarily on the “200-foot,” 500-foot,” and “700-foot” sands of the Lake Charles area, which are part of the Chicot aquifer system underlying Calcasieu and Cameron Parishes of southwestern Louisiana. These three aquifers provided 34 percent of the total water withdrawn and 93 percent of the groundwater withdrawn in Calcasieu and Cameron Parishes in 2012 (84.5 million gallons per day [Mgal/d]). This work was completed by the U.S. Geological Survey, in cooperation with the Louisiana Department of Transportation and Development, to assist in developing and evaluating groundwater-resource management strategies. The highest water levels determined in wells screened in the “200-foot,” “500-foot,” and “700-foot” sands were about 8 feet (ft) above the National Geodetic Vertical Datum of 1929 (NGVD 29), 2 ft below NGVD 29, and 14 ft below NGVD 29, respectively, and were located in northwestern Calcasieu Parish. The lowest water levels determined in wells screened in the “200-foot,” “500-foot,” and “700-foot” sands were approximately 50, 80, and 70 ft below NGVD 29, respectively, and were located in the southern Lake Charles metropolitan area, to the west of Prien Lake, and between the cities of Lake Charles and Sulphur, respectively. The primary groundwater flow direction in these three aquifers was radially towards pumping centers overlying the water-level lows. Comparisons of water-level differences in 42 wells measured in 1995 and 2011–12 indicated that the maximum increases in water levels for wells screened in the “200-foot,” “500-foot,” and “700-foot” sands were approximately 7, 31, and 19 ft, respectively. Water-level increases coincided with a decline in total groundwater withdrawals during the period (about 25 Mgal/d from 1995 to 2012) from these sands. More specifically, withdrawals from the “500-foot” sand affected water levels in wells screened in the “200-foot” and “700-foot” sands because the three are hydraulically connected and withdrawals from the “500-foot” sand were greater by volume than withdrawals from the “200-foot” and “700-foot” sands.

Louisiana↗

Status of water quality in groundwater resources used for drinking-water supply in the southeastern San Joaquin Valley, 2013–15—California GAMA Priority Basin Project

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) investigated water quality of groundwater resources used for drinking-water supplies in the Madera-Chowchilla, Kings, Kaweah, Tule, and Tulare Lake groundwater subbasins of the southeastern San Joaquin Valley during 2013–15. The study focused primarily on groundwater resources used for domestic-supply wells in the southeastern San Joaquin Valley (SESJV-D), which correspond mostly to shallower parts of aquifer systems, compared to the groundwater resources used for public-supply wells in the southeastern San Joaquin Valley (SESJV-P). The investigation had three components: (1) characterization of the status of water quality in the SESJV-D, (2) comparison between water quality in the SESJV-D and SESJV-P, and (3) identification of natural and anthropogenic factors that potentially could affect water quality in these resources. The characterization of water quality in the SESJV-D was based on data collected from 198 domestic wells sampled during 2013–15 by the U.S. Geological Survey (USGS); characterization of water quality in the SESJV-P was based on data collected from 124 wells sampled by the USGS during 2005–18 and an additional 1,577 wells with publicly available data reported to the California State Water Resources Control Board Division of Drinking Water (SWRCB-DDW). Measured concentrations were compared to regulatory and non-regulatory drinking-water quality benchmarks. A grid-based method was used to estimate the areal proportions of each study area and the whole southeastern San Joaquin Valley with high (greater than benchmark concentration), moderate (greater than half of the benchmark for inorganic and one-tenth of the benchmark for organic), and low concentrations relative to those benchmarks. Natural and anthropogenic factors that could affect groundwater quality for the SESJV-D were identified in the context of the hydrogeologic setting of the southeastern San Joaquin Valley. The considered factors represented hydrologic conditions and position in the groundwater flow system (well depth, lateral position, presence of hydric soils, percentage of coarse-grained sediment, and aridity index), land-use characteristics (percentages of agricultural, urban, and natural land use, percentage of orchard or vineyard land use, and densities of septic tanks and underground storage tanks near the wells), and geochemical conditions (groundwater age class, oxidation-reduction class, pH, and dissolved oxygen and bicarbonate concentrations). Factors are compared between SESJV-D and SESJV-P at the scale of the five study areas. One or more inorganic constituents with U.S. Environmental Protection Agency (EPA) or California maximum contaminant levels (MCLs) were detected at high concentrations in 47 percent of the SESJV-D and in 32 percent of the SESJV-P. The inorganic constituents most commonly present at high concentrations in the SESJV-D were nitrate, uranium, and arsenic. Within the SESJV-D, the proportion of the study area with high concentrations of inorganic constituents ranged from 19 percent in Madera-Chowchilla to 60 percent in Kings and Tulare Lake. One or more inorganic constituents with California State Water Resources Control Board Division of Drinking Water secondary maximum contaminant levels (SMCL-CAs) were detected at high concentrations in 14 percent of the SESJV-D and in 19 percent of the SESJV-P. The constituents most commonly present at high concentrations were manganese, iron, and total dissolved solids (TDS). Although the proportion of SESJV-D and SESJV-P with high concentrations of TDS greater than the upper SMCL were similar at 4 percent, the proportion of the SESJV-D with moderate concentrations (between the recommended and upper SMCL-CA), 30 percent, was greater than the proportion of the SESJV-P with moderate concentrations, 12 percent. One or more organic constituents with MCLs were present at high concentrations in 19 percent of the SESJV-D and in 12 percent of the SESJV-P. All the constituents detected at high concentrations in the SESJV-D were fumigants, primarily 1,2,3-trichloropropane (1,2,3-TCP) and 1,2-dibromo-3-chloropropane (DBCP). Fumigants also were the constituents most commonly detected at high concentrations in the SESJV-P, although high concentrations of solvents also were detected. The SESJV-D dataset included analysis of many organic constituents without MCL benchmarks and with detection levels far below drinking water benchmark concentrations; detections at these low concentrations can be used as tracers of anthropogenic influence on groundwater. Pesticides and degradates of pesticides were detected in 60 percent of the SESJV-D; the most frequently detected pesticides were the herbicides simazine, didealkylatrazine (CAAT, a degradate of simazine and atrazine), diuron, and bromacil.

California↗

Use of a numerical groundwater-flow model and projected climate scenarios to simulate the effects of future climate conditions on base flow for reach 1 of the Washita River alluvial aquifer and Foss Reservoir storage, western Oklahoma

To better understand the relation between climate variability and future groundwater resources in reach 1 of the Washita River alluvial aquifer and Foss Reservoir in western Oklahoma, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used a previously published numerical groundwater-flow model and climate-model data to investigate changes in base flow and reservoir storage by evaluating three scenarios. The three projected climate scenarios were (1) a central-tendency scenario, (2) a warmer/drier scenario, and (3) a less-warm/wetter scenario. To estimate future base flow and groundwater availability in western Oklahoma, specifically in reach 1 of the Washita River alluvial aquifer, downscaled climate-model data from 231 Coupled Model Intercomparison Project phase 5 (CMIP5) projections coupled with a previously published numerical groundwater-flow model were used to compare the effects of different climate scenarios on the aquifer. Changes in base flow and groundwater-level elevations during a 30-year baseline scenario (1985–2014) and the three 30-year projected climate scenarios (2050–79) under central-tendency, warmer/drier, and less-warm/wetter climatic conditions were assessed by using the calibrated model. In the simulations, the amount of base flow and reservoir storage declined in the central-tendency and warmer/drier scenarios compared to the amount of base flow and reservoir storage under historical climatic conditions (baseline scenario). Mean annual change in reservoir storage decreased from the baseline scenario the most in the warmer/drier scenario, followed by the central-tendency scenario, but increased in the less-warm/wetter scenario compared to the baseline scenario. At the end of the simulation period (2079), the largest magnitude differences in groundwater-level elevations in all three projected climate scenarios relative to the baseline scenario occurred upstream from Foss Reservoir. Results from incorporating downscaled climate projections into localized numerical groundwater-flow models can highlight potential future changes in and implications for groundwater resources and availability.

Oklahoma↗

Glacial geology and hydrogeology of valley-fill aquifers in the Oneonta area, Otsego and Delaware Counties, New York

The glacial geology and hydrogeology of valley-fill aquifers and their surrounding uplands are described within a 112-square-mile area in southern Otsego and northwestern Delaware Counties, New York, centered around the City of Oneonta. The major valleys include those of the Susquehanna River, Otego Creek, Charlotte Creek, and Schenevus Creek. A variety of data were analyzed to provide a broad picture of the glacial deposits, hydrogeologic framework, aquifer occurrence, and water-resource potential in the area. Both valley-fill and bedrock aquifers are used for water supply within the study area. The valley-fill aquifers consist of coarse-grained stratified drift, are mostly limited to the larger valleys, and have well yields that typically are much greater than those obtained from the bedrock aquifers. The bedrock aquifers generally have lower well yields, are the sole source of groundwater in upland areas, and are tapped in valley areas where sediments are very silty or are absent. Through and non-through valleys and their orientations relative to ice flow have resulted in a variety of deglacial environments and deposits, some of which depart from glacial stratigraphy typically observed elsewhere in central New York. In comparison to through valleys with low in-valley divides, the regional thinning of ice over the high bedrock divides of the non-through valleys resulted in the earlier and more widespread stagnation of glacial ice, development of dead-ice sinks, and earlier diversion of meltwater from ice north of the divides. As the main through valley in the study area, the Susquehanna River valley is characterized by multiple inferred ice-margin positions with associated outwash deposition or ice-contact deposits. Throughout the study area, valleys orientated parallel or subparallel to the ice flow facilitated the development of long ice tongues; valleys oriented perpendicular to the ice flow led to little ice-tongue development, but they did facilitate the deposition of the extensive kame moraines that now occupy several-mile-long valley reaches. Lacustrine sediments were deposited in proglacial lakes. These sediments underlie most valleys that were oriented parallel and subparallel to ice flow, but they are largely absent in the Charlotte Creek valley, which was oriented perpendicular to the ice flow and now contains an extensive kame moraine. Beneath these lacustrine deposits, sand and gravel were deposited as subaqueous fans, eskers, and the distal parts of delta (kame) terraces, each with variable silt content. The presence of coarse-grained stratified deposits, their saturated thicknesses, and their recharge potential are the primary controls on aquifer locations in the study area. The most widespread aquifers in the study area consist of sand and gravel and are confined mostly beneath lacustrine deposits. Confined aquifer yields are enhanced by hydraulic connections with unconfined ice-contact deposits along the valley walls, especially where tributary streams cross these deposits and provide additional recharge through streambed infiltration. The Susquehanna River and other large valley creeks provide a potentially large source of recharge to aquifers where groundwater withdrawals from nearby production wells induce infiltration of river water into aquifers. Unconfined aquifers are present where ice-contact deposits extend below the valley floor and are sufficiently saturated. Most surficial outwash deposits in the study area are thinly saturated; thus their water-resource potential is likely to be limited. The upland areas contain very little stratified drift; therefore, characterization was limited to delineating areas of thick till and thin, or absent, till. Recharge of bedrock aquifers is greatest in areas overlain by thin till or where bedrock is exposed at land surface.

New York↗

Hindcast of water availability in regional aquifer systems using MODFLOW Farm Process

Coupled groundwater and surface-water components of the hydrologic cycle can be simulated by the Farm Process for MODFLOW (MF-FMP) in both irrigated and non-irrigated areas and aquifer-storage and recovery systems. MF-FMP is being applied to three productive agricultural regions of different scale in the State of California, USA, to assess the availability of water and the impacts of alternative management decisions. Hindcast simulations are conducted for similar periods from the 1960s to near recent times. Historical groundwater pumpage is mostly unknown in one region (Central Valley) and is estimated by MF-FMP. In another region (Pajaro Valley), recorded pumpage is used to calibrate model-estimated pumpage. Multiple types of observations are used to estimate uncertain parameters, such as hydraulic, land-use, and farm properties. MF-FMP simulates how climate variability and water-import availability affect water demand and supply. MF-FMP can be used to predict water availability based on anticipated changes in anthropogenic or natural water demands. Keywords groundwater; surface-water; irrigation; water availability; response to climate variability/change

Conference Paper↗

Hydrogeologic framework and groundwater characterization in selected alluvial basins in the upper Rio Grande basin, Colorado, New Mexico, and Texas, United States, and Chihuahua, Mexico, 1980 to 2015

Increasing demand for the limited water resources of the United States continues to put pressure on resource management agencies to balance the competing needs of ecosystem health with municipal, agricultural, and other uses. To meet these needs, the U.S. Geological Survey conducted a multiyear study to evaluate water resources in the upper Rio Grande Basin in the southwestern United States. The upper Rio Grande Basin extends from south-central Colorado, through New Mexico, into west Texas near Fort Quitman, including parts of Chihuahua, Mexico. The upper Rio Grande Basin consists of a sequence of alluvial basins that formed in the Rio Grande rift approximately 30 million years ago. This report describes the hydrogeology of the upper Rio Grande Basin and how the groundwater resources in the basin have changed from 1980 to 2015. The hydrogeologic framework includes the horizontal delineation of the alluvial basins within the upper Rio Grande Basin from the headwaters in Colorado to Fort Quitman, Texas, including part of Mexico. Groundwater-level measurements from existing State and Federal data were used to construct groundwater-level altitude and groundwater-level change maps. Of the 2,699 wells with groundwater-level data used in this study, 1,055 wells had data for only a single 5-year period, 703 wells had data for 50 percent or more of the 35 years of the study, and only 57 wells have 5-year groundwater-level data for the entire study period. The median decline in water levels in the upper Rio Grande Basin was 0.13 foot (ft) per 5-year period, and declines were measured in 53 percent of the 703 wells that contained data for 50 percent or more of the study period. Rates of groundwater-level decline greater than 1 ft per 5-year period were measured in 17 percent of the wells, greater than 2 ft per 5-year period, in 3 percent of the wells, and greater than 3 ft per 5-year period, in 1 percent of the wells. Overall, groundwater levels rose in 6 percent of the 703 wells that contained data for 50 percent or more of the study period, and in 4 percent of the wells, groundwater levels rose by 1 ft or more per 5-year period. Groundwater-level changes in wells with consecutive 5-year measurement periods exhibited the most variability in the Española, Middle Rio Grande, and Mesilla/Conejos-Médanos alluvial basins. The largest declines in groundwater-level altitudes in individual wells were observed in the Española alluvial basin during 1995–2000, in the Palomas alluvial basin during 2010–2015, and in the Jornada del Muerto alluvial basin during 2005–10. The largest rises in groundwater-level altitudes in individual wells were observed in the Española alluvial basin during 2005–10, in the Middle Rio Grande alluvial basin during 1995–2000, and in the Mesilla/Conejos-Médanos alluvial basin during 1980–85. Changes in groundwater storage throughout the study period varied by alluvial basin, likely based largely on changes in groundwater withdrawals because of increased demands during drier periods and population growth. All alluvial basins except the Tularosa-Hueco alluvial basin were evaluated for changes in groundwater storage from 1980 to 2015. Extremely limited data availability in 2010–15 for the Tularosa-Hueco alluvial basin led to this 5-year period being dropped from the groundwater-level change map and storage analysis for this basin. In the San Luis Valley in southern Colorado, efforts to reverse groundwater depletion in the unconfined aquifer recovered approximately 250,000 acre-feet in storage between late 2013 and early 2018, following the implementation of a “pay-to-pump” groundwater program. However, severe drought that persists in the upper Rio Grande Basin, particularly in southern Colorado, has undone some of the conservation efforts. Within the Española alluvial basin, groundwater storage varied because municipal demand increased the demand on groundwater resources and conservation efforts were implemented. A groundwater-flow model evaluated for the Española alluvial basin indicated declines in groundwater storage from 1947 through 1982. Groundwater storage decreased in the Española alluvial basin in 1980–85, 1985–90, 1990–95, 1995–2000, and 2005–10 and increased in 2000–05 and 2010–15 leading to groundwater storage in 2015 about even with that in 1985. Based on gridded groundwater-level altitudes, groundwater storage decreased in the Middle Rio Grande Basin from 1980 to 2015, except for during the 1980–85, 2000–05, and 2010–15 periods with an overall cumulative storage decrease from 1980 to 2015. Groundwater-flow models evaluated for the Middle Rio Grande alluvial basin showed groundwater storage in the Middle Rio Grande alluvial basin has been reduced since the mid-1950s through the end of the study period except for a brief recovery (reduction in storage outflow) in the mid-1980s. Simulated groundwater storage has also decreased in parts of the Palomas and Mesilla/Conejos-Médanos alluvial basins, and the northern part of the Conejos-Médanos alluvial basin starting in 1995 (excluding 2005 and 2007) and in the Tularosa-Hueco alluvial basin from the early 1940s to the end of the study period. Groundwater storage increased in the Mesilla/Conejos-Médanos alluvial basin during 1980–85 and slightly during 1990–95 and then decreased in the other 5-year periods. Groundwater storage in the Tularosa-Hueco alluvial basin increased from 1985 to 1990, but otherwise decreased, leading to an overall net groundwater-level decline in this part of the basin from 1980 to 2010.

Colorado, New Mexico, Texas, Chihuahua↗