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At least 1,135 records · Page 63Linked to original sources

USGS1999

Evaluation of processes affecting 1,2-dibromo-3-chloropropane (DBCP) concentrations in ground water in the eastern San Joaquin Valley, California: Analysis of chemical data and ground-water flow and transport simulations

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DBCP), an agricultural fumigant banned from use since the late 1970's, persists at concentrations greater than the maximum contaminant level of 0.2 micrograms per liter (mg/L). Field data indicate that DBCP concentrations in ground water have decreased since the late 1970's. Laboratory experiments by earlier investigators show that DBCP transformed to 2-bromoallyl alcohol (BAA) under conditions similar to in situ conditions, with an estimated half-life ranging from 6.1 (pH 7.8, 21.1 degrees Celsius) to 141 years (pH 7.0, 15 degrees Celsius). For this current study, a detailed hydrogeologic investigation was done to assess the relative importance of chemical transformation, dispersion, and ground-water pumping and reapplication of irrigation water in affecting DBCP concentrations. Ground-water samples were collected from 20 monitoring wells installed along a 4.6-kilometer transect. DBCP concentrations in these samples ranged from less than the detection limit of 0.03 mg/L to a maximum of 6.4 mg/L. Results of chlorofluorocarbon (CFC) age dating indicate that DBCP occurs in water that ranges in age from about 2 to 41 years. The primary transformation product BAA, which was identified during previous laboratory studies, was not detected at or greater than 0.03 mg/L in any of the 20 ground-water samples. The lack of detection of BAA indicates that transformation to BAA is insignificant relative to other processes controlling DBCP concentrations. Results from this current study indicate that the in situ hydrolysis half-life for DBCP to BAA is much greater than the laboratory-determined values. Estimated initial concentrations of DBCP, calculated using CFC-estimated travel times and a half-life of 6.1 years, indicate that maximum initial concentrations are consistent with maximum measured concentrations in ground water. In contrast to initial DBCP concentrations, the estimated initial nitrate concentrations indicate that nitrate concentrations in recharge water have increased with time. A conceptual two-dimensional numerical flow and transport modeling approach was used to test hypotheses addressing dispersion, transformation rate, and in a relative sense, the effects of ground- water pumping and reapplication of irrigation water on DBCP concentrations in the aquifer. The flow and transport simulations, which represent hypothetical steady-state flow conditions in the aquifer, were used to refine the conceptual understanding of the aquifer system rather than to predict future concentrations of DBCP. Results indicate that dispersion reduces peak concentrations, but this process alone does not account for the apparent decrease in DBCP concentrations in ground water in the eastern San Joaquin Valley. Ground-water pumping and reapplication of irrigation water may affect DBCP concentrations to the extent that this process can be simulated indirectly using first-order decay. Transport simulation results indicate that the in situ 'effective' half-life of DBCP caused by processes other than dispersion and transformation to BAA could be on the order of 6 years.

California↗

USGS1991

Soil water and vegetation responses to precipitation and changes in depth to ground water in Owens Valley, California

Vegetation on the floor of Owens Valley, California, is composed predominantly of phreatophytic desert communities that are adapted to small quantities of precipitation and alkaline soils. These plant communities are believed to be dependent on the continuing presence of a shallow water table. Maintaining existing plant communities is important to preserve the environmental quality of the valley. Proposals to pump additional quantities of ground water from the valley for export to the city of Los Angeles caused concern about the effect of pumping on the existing vegetation and how the plants would adapt to short- or long-term declines of the shallow water table. To test the ability of selected major shrub species to adapt to water-table decline, four sites were selected, pump-equipped wells were installed, and water-table drawdown was monitored. Soil samples were collected with a hand auger and analyzed by using the filter-paper method to monitor changes in soil water content and soil matric potential at test sites. Plant reactions were determined by measurements of plant cover, shoot growth, and xylem pressure potential. Results of 3 years of monitoring show that growth and cover repetition of the shrubs studied are affected greatly by the quantity of annual precipitation, especially at sites with coarse-textured soils. Plants were not affected by drying soil in the root zone until the maximum matric potential exceeded 4.3 pF (-1,950 kilopascal) at depths greater than 0.5 meter. Rabbit-brush was most sensitive to dry soil and was the only shrub species that died as the result of water stress from water-table drawdown. The change in cover repetition correlated positively with the magnitude of water-table drawdown at one site and negatively at another site. Measurements of xylem pressure potential taken before dawn correlated well with water content in the upper 1.5 meters of soil. The magnitude of water-table drawdown achieved by the pump-equipped wells was less than expected at three of the four sites. Additional water-table drawdown for a longer period of time would be needed to separate the effects of water-table drawdown from the effects caused by differences in soil textures and natural fluctuations in the quantity of precipitation.

Water Supply Paper↗

USGS2025

Exploring the news media and scientific conversations around water quality in a water-rich basin of the United States

Community concerns about water availability vary depending on local economic, regulatory, environmental, and ecological considerations. In water-rich basins, water quality is often the focus of community concerns. As such, understanding community priorities in the context of water quality is crucial for informing scientists working in water-rich basins. In this work, we compiled over 6,500 local news articles (public discourse) and 190 scientific abstracts (scientific discourse) related to water-quality issues in the water-rich Illinois River Basin (ILRB) published between 2018 and 2022. We applied a Structural Topic Model (STM) to identify key water-quality topics within both datasets and explore the variability of newspaper topics geographically across the basin. Prevalent topics in both the public (local news articles) and scientific (abstracts) discourses were agriculture, drinking water quality, PFAS (per- and polyfluoroalkyl substances), and river ecosystem/fish. Topics exclusive to public discourse included water infrastructure, community development, and public water supply, while the scientific discourse focused more heavily on a wider range of agricultural issues. Furthermore, the public discourse varied geographically across the basin. Some topics are correlated with land use or urban/rural divides within the basin, and the frequency of many topics clearly varied across state (political) boundaries. Understanding and quantifying public and scientific discourses related to water-quality are important for scientists and water managers working in the basin to improve communication of critical science to the public.

Illinois, Indiana, Michigan, Wisconsin↗

USGS2005

Investigating surface water-well interaction using stable isotope ratios of water

Because surface water can be a source of undesirable water quality in a drinking water well , an understanding of the amount of surface water and its travel time to the well is needed to assess a well's vulnerability. Stable isotope ratios of oxygen in river water at the City of La Crosse, Wisconsin, show peak-to-peak seasonal variation greater than 4‰ in 2001 and 2002. This seasonal signal was identified in 7 of 13 city municipal wells, indicating that these 7 wells have appreciable surface water contributions and are potentially vulnerable to contaminants in the surface water. When looking at wells with more than 6 sampling events, a larger variation in δ 18 O compositions correlated with a larger fraction of surface water, suggesting that samples collected for oxygen isotopic composition over time may be useful for identifying the vulnerability to surface water influence even if a local meteoric water line is not available. A time series of δ 18 O from one of the municipal wells and from a piezometerlocated between the river and the municipal well showed that the travel time of flood water to the municipal well was approximately 2 months; non-flood arrival times were on the order of 9 months. Four independent methods were also used to assess time of travel. Three methods (groundwater temperature arrival times at the intermediate piezometer, virus-culture results, and particle tracking using a numerical groundwater-flow model) yielded flood and non-flood travel times of less than 1 year for this site. Age dating of one groundwater sample using 3 H– 3 He methods estimated an age longer than 1 year, but was likely confounded by deviations from piston flow as noted by others. Chlorofluorocarbons and SF 6 analyses were not useful at this site due to degradation and contamination, respectively. This work illustrates the utility of stable hydrogen and oxygen isotope ratios of water to determine the contribution and travel time of surface water in groundwater, and demonstrates the importance of using multiple methods to improve estimates for time of travel of 1 year or less.

Journal of Hydrology↗

USGS2021

Water–rock interaction and the concentrations of major, trace, and rare earth elements in hydrocarbon-associated produced waters of the United States

Studies of co-produced waters from hydrocarbon extraction across multiple energy-producing basins have generally focused on major ions or a few select tracers, and studies that examine trace elements and involve laboratory experiments have generally been basin specific. Here, new perspective is sought through a broad analysis of concentration data for 26 elements from three hydrocarbon well types using the U.S. Geological Survey National Produced Waters Geochemical Database (v2.3). Those data are compared to leachates (water, hydrochloric acid, and artificial brine) from 12 energy-resource related shales from across the United States. Both lower pH and higher ionic strength were associated with greater concentrations of many trace elements in produced waters. However, individual effects were difficult to distinguish because higher ionic strengths drive decreases in pH. Water–rock interactions in the leaching experiments generally replicated produced water concentrations for trace elements including Al, As, Cd, Co, Cu, Mo, Ni, Pb, Sb, Si, and Zn. Enhanced middle rare earth element (REE) mobilization relative to shale REE content occurred with low pH leachates. Produced water concentrations of Li, Sr, and Ba were not replicated by the leaching experiments. Patterns of high Li, Sr, and Ba concentrations and ratios relative to other elements across produced waters types indicate controls on these elements in many settings related to pore space pools of salts, brines, and ion-exchange sites affected by diagenetic processes. The size of those pools is diluted and masked by other water–rock interaction processes at the water–rock ratios necessitated by laboratory experiments. The results broadly link water–rock interaction processes and environmental patterns across a wide variety of produced waters and host formations and thus provide context for trace element data from other environmental and laboratory studies of such waters.

Environmental Science: Processes & Impacts↗

USGS2006

Water-Quality Data, 1999-2005, and Ground-Water Level Data, 2004-2005, for McBaine Bottoms, Including the Eagle Bluffs Conservation Area, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data from June 1999 through August 2005, surface-water quality data from August 1999 through August 2003, and water-level data from February 2004 through August 2005 in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report presents water-quality data, which include water-quality analyses of samples collected from 36 water-quality sampling sites (31 were wells and 5 were surface-water sites), and ground-water level data, which include water-level measurements from more than 80 wells. Water samples were analyzed for physical properties, inorganic chemical constituents, nutrients, and dissolved iron. Selected samples were analyzed for trace elements, wastewater organic compounds, and pesticides. In samples from monitoring wells, chloride concentrations ranged from 2.41 to 259 mg/L (milligrams per liter), sodium concentrations ranged from 1.08 to 175 mg/L, and sulfate concentrations ranged from less than 0.2 to 271 mg/L (all concentrations were dissolved). Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 0.46 mg/L. Total phosphorous concentrations ranged from less than 0.04 to 1.68 mg/L, dissolved phosphorous concentrations ranged from less than 0.04 to 1.50 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 1.83 mg/L. Dissolved iron concentrations ranged from less than 6 to 42,900 g/L (micrograms per liter). Dissolved arsenic concentrations in samples from two monitoring wells ranged from 11 to 37 g/L. In samples from surface-water sampling sites, chloride concentrations ranged from 8.67 to 289 mg/L, sodium concentrations ranged from 6.18 to 219 mg/L, and sulfate concentrations ranged from 33.4 to 119 mg/L. All of the minimum concentrations were detected in samples from Perche Creek. Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 1.53 mg/L. Total phosphorous concentrations ranged from 0.07 to 3.06 mg/L, dissolved phosphorous concentrations ranged from less than 0.05 to 2.88 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 2.86 mg/L. Most of the maximum concentrations were detected in samples from the city outflow. More than 35 wastewater organic compounds and pesticides were detected in samples from the city outflow. However, most concentrations were estimated or their presence verified, but not quantified. Water levels in monitoring wells ranged from 548.54 to 576.55 ft (feet) above the National Geodetic Vertical Datum of 1929 (NGVD 29). The difference in water levels from February 2004 to August 2005 ranged from 0.13 ft to 10.97 ft.

Data Series↗

USGS2008

Water Availability--The Connection Between Water Use and Quality

Water availability has become a high priority in the United States, in large part because competition for water is becoming more intense across the Nation. Population growth in many areas competes with demands for water to support irrigation and power production. Cities, farms, and power plants compete for water needed by aquatic ecosystems to support their minimum flow requirements. At the same time, naturally occurring and human-related contaminants from chemical use, land use, and wastewater and industrial discharge are introduced into our waters and diminish its quality. The fact that degraded quality limits the availability and suitability of water for critical uses is a well-known reality in many communities. What may be less understood, but equally true, is that our everyday use of water can significantly affect water quality, and thus its availability. Landscape features (such as geology, soils, and vegetation) along with water-use practices (such as ground-water withdrawals and irrigation) govern water availability because, together, they affect the movement of chemical compounds over the land and in the subsurface. Understanding the interactions of human activities with natural sources and the landscape is critical to effectively managing water and sustaining water availability in the future.

Fact Sheet↗

USGS2009

Water Use in Georgia by County for 2005; and Water-Use Trends, 1980-2005

Water use for 2005 for each county in Georgia was estimated using data obtained from various Federal and State agencies and local sources. Total consumptive water use also was estimated for each county in Georgia for 2005. Water use is subdivided according to offstream and instream use. Offstream use is defined as water withdrawn or diverted from a ground- or surface-water source and transported to the place of use. Estimates for offstream water use include the categories of public supply, domestic, commercial, industrial, mining, irrigation, livestock, aquaculture, and thermoelectric power. Instream use is that which occurs within a stream channel for such purposes as hydroelectric-power generation, navigation, water-quality improvement, fish propagation, and recreation. The only category of instream use estimated was hydroelectric-power generation. Georgia law (the Georgia Ground-Water Use Act of 1972 and the Georgia Water Supply Act of 1978 [Georgia Department of Natural Resources, 2008a,b]) requires any water user who withdraws more than 100,000 gallons per day on a monthly average to obtain a withdrawal permit from the Georgia Environmental Protection Division. Permit holders generally must report their withdrawals by month. The Georgia Water-Use Program collects the reported information under the withdrawal permit system and the drinking-water permit system and stores the data in the Georgia Water-Use Data System.

Fact Sheet↗

USGS2001

Ground-water levels and water-quality data for wells in the Spring Creek area near Arnold Air Force Base, Tennessee, April and May 2000

Arnold Air Force Base (AAFB) occupies about 40,000 acres in Coffee and Franklin Counties, Tennessee. Numerous site-specific ground-water contamination investigations have been conducted at designated solid waste management units (SWMU’s) at AAFB. Several synthetic volatile organic compounds (VOC’s), primarily chlorinated solvents, have been identified in groundwater samples collected from monitoring wells near SWMU 8 in the Spring Creek area. During April and May 2000, a study of the groundwater resources in the Spring Creek area was conducted to determine if VOC’s from AAFB have affected local private water supplies and to advance understanding of the ground-water-flow system in this area. The study focused on sampling private wells located within the Spring Creek area that are used as a source of drinking water. Ground-water-flow directions were determined by measuring water levels in wells and constructing a potentiometric-surface map of the Manchester aquifer in the study area. Data were collected from a total of 35 private wells and 22 monitoring wells during the period of study. Depths to ground water were determined for 22 of the private wells and all 22 of the monitoring wells. The wells ranged in depth from 21 to 105 feet. Water-level altitudes ranged from 930 to 1,062 feet above sea level. Depths to water ranged from 8 to 83 feet below land surface. Water-quality samples were collected from 29 private wells which draw water from either gravel zones in the upper part of the Manchester aquifer, fractured bedrock in the lower part of the Manchester aquifer, or a combination of these two zones. Concentrations of 50 of the 55 VOC’s analyzed for were less than method detection limits. Chloroform, acetone, chloromethane, 2-butanone, and tetrachloroethylene were detected in concentrations exceeding the method detection limits. Only chloroform and acetone were detected in concentrations equal to or exceeding reporting limits. Chloroform was detected in a sample from one well at a concentration of 1.2 micrograms per liter (µg/L). Acetone was detected in a sample from another well at a concentration of 10 µg/L. Acetone also was detected in a duplicate sample from the same well at an estimated concentration of 7.2 µg/L, which is less than the reporting limit for acetone. The only contaminant of concern detected was tetrachloroethylene. Tetrachloroethylene was detected in only one sample, and this detection was at an estimated concentration below the reporting limit. None of the VOC concentrations exceeded drinking water maximum contaminant levels for public water systems.

Tennessee↗

USGS2002

Average altitude of the water table (1990-99) and frequency analysis of water levels (1974-99) in the Biscayne aquifer, Miami-Dade County, Florida

Miami-Dade County occupies about 2,000 square miles along the southeastern part of peninsular Florida. Five prominent physiographic features are located within the confines of Miami-Dade County and include the Atlantic Coastal Ridge, Big Cypress Swamp, the Sandy Flatlands, coastal marshes and mangrove swamps, and the Everglades (fig. 1). The highest altitudes occur along the Atlantic Coastal Ridge (2 to 10 miles wide), ranging from 8 to 15 feet above sea level but may be as high as 20 feet. The Atlantic Coastal Ridge forms a natural barrier to drainage from the interior. The Sandy Flatlands in northeastern Miami-Dade County ranges from 6 to 18 feet above sea level; this area was poorly drained prior to development. The Everglades forms a natural trough across the county, with altitudes ranging from 9 feet above sea level in the northwestern part to about 3 feet above sea level in the southwestern part. A small section of the Big Cypress Swamp occupies northwestern Miami-Dade County, with altitudes ranging from 7 to 10 feet above sea level. Along the coast, marshes and mangrove swamps have altitudes ranging from 0 to 3 feet above sea level (Fish and Stewart, 1991). The U.S. Geological Survey (USGS), in cooperation with the Miami-Dade County Department of Environmental Resources Management (DERM), conducted a study to determine the average altitude of the water table in the Biscayne aquifer in Miami-Dade County and to perform a water-level frequency analysis for selected time periods. Water-table maps in this report are based on average yearly May, October, high, and low water levels during 1990-94, 1995-99, and 1990-99. Data collected in May and October are used to show the yearly water-level conditions at the end of the dry and wet seasons, respectively. Water-level frequency analysis maps (5-, 10-, and 25-year recurrence water levels) in this report are based on analysis of water-level data from continuous water-level recorders for the 1974-99 period. Water-level data for the maps were collected by Everglades National Park (ENP), the USGS, and the South Florida Water Management District (SFWMD). Data for ENP sites were provided as averages by ENP. Determination of averages for the USGS data was performed using options available in the USGS Automated Data Processing System (ADAPS), and averages for the SFWMD data were determined from options available in the SFWMD Hydrometeorologic and Water-Quality Database (DBHYDRO). The ENP, USGS, and SFWMD data are reported as mean daily water levels and are referenced to sea level. In this report, sea level refers to the National Geodetic Vertical Datum of 1929 (NGVD of 1929)-a geodetic datum derived from a general adjustment of the first-order level nets of both the United States and Canada, formerly called Sea Level Datum of 1929. In this report, horizontal coordinate information is referenced to the North American Datum of 1983 (NAD 83).

Florida↗

USGS2004

Water-level altitudes 2004 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2003 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

This report is one in an annual series of reports that depicts water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers, and compaction in the Chicot and Evangeline aquifers in the Houston-Galveston region. The Houston-Galveston region comprises Harris, Galveston, Fort Bend, Waller, and Montgomery Counties and adjacent parts of Brazoria, Grimes, Walker, San Jacinto, Liberty, and Chambers Counties. The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District, the City of Houston, the Fort Bend Subsidence District, and the Lone Star Groundwater Conservation District. For the Chicot and Evangeline aquifers, maps show approximate water-level altitudes in 2004, water-level changes from 2003 to 2004, approximate water-level changes from 1977 to 2004, and approximate water-level changes from 1990 to 2004 (figs. 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 ). For the Jasper aquifer, maps show approximate water-level altitudes in 2004 and water-level changes from 2003 to 2004 and 2000 to 2004 (figs. 9 , 10 , 11 ). The report also contains a map showing borehole extensometer (well equipped with compaction monitor) site locations ( fig. 12 ) and graphs showing measured compaction of subsurface material at these sites from 1973 or later to 2003 ( fig. 13 ). The U.S. Geological Survey (USGS) has published annual reports of water-level altitudes and water-level changes for the Chicot and Evangeline aquifers in the Houston-Galveston region since 1979; and annual reports of same for the Fort Bend subregion (Fort Bend County and adjacent areas) since 1990. The USGS published its first water-level-altitude map for the Jasper aquifer in the greater Houston area (primarily Montgomery County) in 2001. The 2004 water-level-altitude and water-level-change maps for the three aquifers are included in this report.

Texas↗

USGS2006

Characterization of the hydrology, water chemistry, and aquatic communities of selected springs in the St. Johns River Water Management District, Florida, 2004

The hydrology, water chemistry, and aquatic communities of Silver Springs, De Leon Spring, Gemini Springs, and Green Spring in the St. Johns River Water Management District, Florida, were studied in 2004 to provide a better understanding of each spring and to compile data of potential use in future water-management decisions. Ground water that discharges from these and other north-central Florida springs originates from the Upper Floridan aquifer of the Floridan aquifer system, a karstic limestone aquifer that extends throughout most of the State's peninsula. This report summarizes data about flow, water chemistry, and aquatic communities, including benthic invertebrates, fishes, algae, and aquatic macrophytes collected by the U.S. Geological Survey, the St. Johns River Water Management District, and the Florida Department of Environmental Protection during 2004, as well as some previously collected data. Differences in water chemistry among these springs reflect local differences in water chemistry in the Upper Floridan aquifer. The three major springs sampled at the Silver Springs group (the Main Spring, Blue Grotto, and the Abyss) have similar proportions of cations and anions but vary in nitrate and dissolved oxygen concentrations. Water from Gemini Springs and Green Spring has higher proportions of sodium and chloride than the Silver Springs group. Water from De Leon Spring also has higher proportions of sodium and chloride than the Silver Springs group but lower proportions of calcium and bicarbonate. Nitrate concentrations have increased over the period of record at all of the springs except Green Spring. Compounds commonly found in wastewater were found in all the springs sampled. The most commonly detected compound was the insect repellant N,N'-diethyl-methyl-toluamide (DEET), which was found in all the springs sampled except De Leon Spring. The pesticide atrazine and its degradate 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT) were detected in water from the Silver Springs group and in both boils at Gemini Springs. No pesticides were detected in water samples from De Leon Spring and Green Spring. Evidence of denitrification was indicated by the presence of excess nitrogen gas in water samples from most of the springs. Aquatic communities varied among the springs. Large floating mats of cyanobacteria (blue-green algae), identified as Lyngbya wollei, were observed in De Leon Spring during all sampling events in 2004. At Gemini Springs, the dominant periphyton was Rhizoclonium sp. Of the three springs sampled for benthic invertebrates, De Leon Spring had the highest overall species richness and most disturbance intolerant species (Florida Index = 4). Green Spring had the lowest species richness of the springs sampled. Based on qualitative comparisons, overall macroinvertebrate species richness seemed to be negatively related to magnesium, potassium, sodium, and specific conductance. Invertebrate abundance was greatest when dissolved oxygen and nitrate were high but phosphorus and potassium concentrations were low. Dipteran abundance seemed to be positively associated with specific conductance and total organic carbon but negatively associated with nitrate-N. Amphipods were the numerically dominant group collected in most (six of nine) collections. Shifts in amphipod abundance of the two species collected (Gammarus sp. and Hyalella azteca) varied by season among the three springs, but there were no trends evident in the variation. Fish populations were relatively species-rich at the Silver Springs group, De Leon Spring, and Gemini Springs, but not at Green Spring. Nonindigenous fish species were observed at all springs except Green Spring.

Open-File Report↗

USGS2006

Water-Quality Data for Selected National Park Units within the Southern Colorado Plateau Network, Arizona, Utah, Colorado, and New Mexico, Water Years 2005 and 2006

The National Park Service initiated a Level 1 Water-Quality Inventory program to provide water-quality data to park managers so informed natural resource management decisions could be made. Level 1 water-quality data were collected by the U.S. Geological Survey Arizona Water Science Center at 57 sites in 13 National Park units located in the Southern Colorado Plateau Inventory and Monitoring network in water years 2005 and 2006. These data describe the current water-quality at selected sites within the park units and provide information for monitoring future trends. Water samples were collected three times at each type of site including wells, springs, seeps, tinajas, rivers, a lake, and an irrigation ditch. Field measurements were taken at each site and they included pH, specific conductance, temperature, barometric pressure, dissolved oxygen, alkalinity, turbidity, and discharge rates where applicable. Water samples collected were sent to the U.S. Geological Survey National Water Quality Laboratory and analyzed for major ions, trace elements, and nutrients. The National Water Quality Laboratory also analyzed selected samples for mercury and petroleum hydrocarbons. Additional samples at selected sites were collected and analyzed for cyanide, radiochemistry, and suspended sediment by U.S. Geological Survey contract labs. Fecal-indicator bacteria (Escherichia coli) were sampled for at selected sites as another indicator of water quality. Quality control for this study was achieved through proper training of field personnel, use of standard U.S. Geological Survey field and laboratory protocols, collection of sample blanks and replicates, and a thorough review of the water-quality analyses. Measured field pH ranged from 6.0 to 8.8, within normal range for springs and rivers, at most sites. Concentrations of dissolved solids ranged from 48 to 8,680 mg/L and the majority of samples had concentrations of dissolved solids below 900 mg/L. Trace-element concentrations at most sites were at or near the laboratory reporting levels. The highest overall trace-element concentrations were found at U.S. Highway 160 Spring near Park Entrance to Mesa Verde National Park. Concentrations of uranium in samples at all sites ranged from below the detection limit to 55.7 ?g/L. Water samples from selected sites were analyzed for total petroleum hydrocarbons and concentrations of total petroleum hydrocarbons were at or above the laboratory detection limit in samples at six National Park units. Ten sites were sampled for Escherichia coli and positive counts were found at 9 out of the ten sites, the highest colony counts were found at Chinle Creek at Chinle, AZ in Canyon de Chelly National Monument. Measured concentrations of dissolved ammonia, nitrite, and nitrate were at or near laboratory reporting levels at most sites; nitrate concentrations ranged from below the reporting limit (0.047 mg/L) to 9.77 mg/L. Samples that were analyzed for mercury had concentrations below or at the laboratory reporting level. Concentrations of cyanide were less than the laboratory reporting level for all samples except two, Spruce Tree House Spring in Mesa Verde National Park and Pine Tree Canyon Tinaja in Canyon de Chelly National Monument, which had average concentrations of .042 and .011 ?g/L respectively. Gross alpha/beta radioactivity counts were below the U.S. Environmental Protection Agency maximum contaminant level except for samples from Casa Chiquita Well Middle at Chaco Culture National Historical Park which averaged 35 pCi/L. Suspended-sediment concentrations were variable and ranged from 10 to 150,000 mg/L.

Open-File Report↗

USGS2018

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir Drainage Area, Rhode Island, Water Year 2016

As part of a long-term cooperative program to monitor water quality within the Scituate Reservoir watershed, the U.S. Geological Survey in cooperation with the Providence Water Supply Board collected streamflow and water-quality data at the Scituate Reservoir and tributaries. Streamflow and concentrations of chloride and sodium estimated from records of specific conductance were used to calculate loads of chloride and sodium during water year (WY) 2016 (October 1, 2015, through September 30, 2016) for tributaries to the Scituate Reservoir, Rhode Island. Streamflow was measured or estimated by the U.S. Geological Survey following standard methods at 23 streamgages; 14 of these streamgages are equipped with instrumentation capable of continuously monitoring water level, specific conductance, and water temperature. Water-quality samples were collected by the Providence Water Supply Board at 34 sampling stations that also include 14 continuous-record streamgages maintained by the U.S. Geological Survey during WY 2016 as part of a long-term sampling program; all stations are in the Scituate Reservoir drainage area. Water-quality data collected by the Providence Water Supply Board are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields (loads per unit area) of selected water-quality constituents for WY 2016. The largest tributary to the reservoir, the Ponaganset River, which was monitored by the U.S. Geological Survey, contributed a mean streamflow of 18 cubic feet per second to the reservoir during WY 2016. For the same period, annual mean streamflows measured (or estimated) for the other monitoring stations in this study ranged from about 0.27 to about 12 cubic feet per second. Together, tributaries equipped with instrumentation capable of continuously monitoring specific conductance transported about 2,100,000 kilograms of chloride and 1,300,000 kilograms of sodium to the Scituate Reservoir during WY 2016; chloride and sodium yields for the tributaries ranged from 14,000 to 95,000 kilograms per square mile and from 8,600 to 56,000 kilograms per square mile, respectively. At the stations where water-quality samples were collected by the Providence Water Supply Board, the medians of the median concentrations were 27.9 milligrams per liter for chloride, 0.002 milligram per liter as nitrogen for nitrite, 0.13 milligrams per liter as nitrogen for nitrate, 0.07 milligram per liter as phosphate for orthophosphate, and 700 and 10 colony forming units per 100 milliliters for total coliform bacteria and Escherichia coli ( E. coli ), respectively. The medians of the median daily loads of chloride, nitrite nitrogen, nitrate nitrogen, orthophosphate, and total coliform and E. coli bacteria were 170 kilograms per day, 8.9 grams per day, 570 grams per day, 320 grams per day, 41,000 million colony forming units per day, and 680 million colony forming units per day. The medians of the median yields of chloride, nitrite nitrogen, nitrate nitrogen, orthophosphate, total coliform, and E. coli bacteria were 53 kilograms per day per square mile, 4.7 grams per day per square mile, 130 grams per day per square mile, 165 grams per day per square mile, 23,000 million colony forming units per day per square mile, and 340 million colony forming units per day per square mile, respectively.

Rhode Island↗

USGS2022

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2018–2019

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from calendar year 2019, and additionally uses streamflow statistics from November and December 2018. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2019, total groundwater withdrawals were estimated to be 3,070 acre-feet (acre-ft), industrial withdrawals were 670 acre-ft, and municipal withdrawals were estimated to be 2,400 acre-ft. Total withdrawals during 2019 were about 58 percent less than total withdrawals in 2005 because of Peabody Western Coal Company’s discontinued use of water to transport coal in a coal slurry pipeline after 2005 and cessation of mining operations in 2019. Water levels measured in 2019 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 10 of 16 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 16 wells ranged from +8.2 feet (ft) to −40.0 ft, and the median change was −1.7 ft. Water levels also showed decline in 16 of 18 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −38.8 ft, with changes across all 18 wells ranging from +12.9 ft to −185.0 ft. Spring flow was measured at four springs in 2019. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2019), Dinnebito Wash near Sand Springs 09401110 (1993 to 2019), Polacca Wash near Second Mesa 09400568 (1994 to 2019), and Pasture Canyon Springs 09401265 (2004 to 2019). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was indicated at Moenkopi Wash and Dinnebito Wash. In 2019, water samples collected from four springs and three wells in the Black Mesa area were analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Concentrations of dissolved solids, chloride, and sulfate increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids and chloride at Burro Spring have varied for the period of record, but there is no statistical trend in the data; however, concentrations of sulfate from Burro Spring now show a trend towards lower concentrations. No statistical trend tests were performed for the three wells sampled in 2019 since less historical water-quality data were available for comparison.

Arizona↗

USGS2024

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona↗

USGS1954

Records of wells, ground-water levels, and ground-water withdrawals in the lower Goose Creek Basin, Cassia County, Idaho

Investigations by the United States Geological Survey of Ground Water in the Southern border area of the Snake Rive Plain, south of the Snake River, a re concerned at the present time with delineation of the principal ground-water districts, the extent and location of existing ground-water developments, the possibilities for additional development, and the effects of ground-water development on the regimen of streams and reservoirs whose waters are appropriate for beneficial use. The lower part of the Goose Creek Basin is one of the important ground-water districts of the southern plains area and there are substantial but spotty developments of ground water for irrigation in the basin. Several thousand irrigable acres that are now dry could be put under irrigation if a dependable supply of ground water could be developed. The relations of the ground-water reservoirs to the regime of the Snake River and Goose Cree, and to the large body of ground water in the Snake River Plain north of the Snake, are poorly known. A large amount of geologic and hydrologic study remains to be done before those relations can be accurately determined. Investigations will be continued in the future but file work and preparation of a comprehensive report inevitably will be delayed. Therefore the available records are presented herein in order to make them accessible to farmers, well drillers, government agencies, and the general public. Interpretation of the records is not attempted in this report and is deferred pending the accumulation of additional and quantitative information. The data summarized herein include records of the locations and physical characteristics of wells, the depth to water in wells, fluctuations of water levels in observation wells, and estimated rates and volumes of seasonal ans yearly ground-water pumpage for irrigation, municipal, and other uses. This information is complete for work done as of December 31, 1952. The investigations upon which this report is based were undertaken in cooperation with the U.S. Bureau of Reclamation, Region I, at the request of the Planning Division, Central Snake River District. The report was complied in the first instance for the use of the Bureau of Reclamation but is now released to the public. The observation-well program in the area has been maintained in cooperation with the Idaho State Department of Reclamation as part of the regular cooperative program of the Geological Survey.

Idaho↗

USGS1981

Apparent water resistivity, porosity, and ground-water temperature of the Madison limestone and underlying rocks in parts of Montana, Nebraska, North Dakota, South Dakota, and Wyoming

The need for large quantities of energy has increased interest in the Fort Union coal region of the Northern Great Plains. Extensive coal development would place a heavy demand on the region's limited streamflow. Some Paleozoic rocks that underlie the Fort Union coal region might supply, at least on a temporary basis, a significant amount of the water required for coal development. This report provides information on ground-water resistivity, rock characteristics, and ground-water temperature, from which general inferences relating to water quality and flow direction may be drawn. The area of study covers approximately 200,000 square miles, and includes eastern Montana, western North Dakota and South Dakota, northeastern Wyoming, and northwestern Nebraska. Borehole geophysical data and bottom-hole temperature data were used to determine porosity, apparent electrical resistivity of ground water (Rwa), and temperature of ground water for the Red River Formation (Ordovician), Interlake Formation (Uppermost Ordovician and Silurian), Duperow Formation (Upper Devonian), Birdbear Formation (Upper Devonian), and a chronostratigraphic interval within the Madison Limestone (Mississippian). Rwa indicates the areal distribution of fresh and salty water and the probable direction of water movement. Maps showing areal distribution of Rwa, rock porosity, and ground-water temperature were prepared for each formation. Rwa values ranged from about 13 ohm-meters to 0.04 ohm-meter. The highest Rwa is in recharge areas, and the lowest, in the areas of dense brine in the Williston basin. The areas of brine are not centered in the deepest part of the basin, but are shifted to the east and south, apparently in response to hydraulic effects associated with the flow of less salty water around the brine and into overlying formations. The distribution of water of different quality, which controls Rwa, is governed by the flow system, which in turn is affected by proximity of geologic structures, by the distribution of rock types, and by porosity trends within the rocks. Temperatures of ground water ranged from about 80°F to as much as 320°F. Generally, temperatures are lowest nearer the mountains and uplift areas and highest in the deeper parts of the basins. Temperature anomalies may be caused by geologic structures, thermal conductivity of overlying beds, and deeper than expected circulation of water in fractures related to intrusive igneous rocks. Thermal gradients ranged from 1.0°F/100 ft to 4.2°/100 ft.

Montana, Nebraska, North Dakota, South Dakota, Wyo↗