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1,669 records · Page 63Linked to original sources

Spatial differences in soil nutrients along a hydrographic gradient on floodplains in Dongting Lake

The spatial heterogeneity of soil nutrients is crucial for the water bird and whole floodplain wetland ecosystem in large lakes, and it is influenced by the dramatic water level changes and sedimentation progress in West Dongting Lake (WDL). Soil samples were collected at various soil depths along the Yuan River and Li River that feed into WDL. The concentrations of soil total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), and soil grain size were tested. The stoichiometric ratios of C, N, P, and the mean value of soil grain size ( Mz ) were calculated. The differences of soil TOC, TN, TP and the stoichiometric ratio at different sites and soil depths were compared. Linear regression was used to explore the relationships of Mz and nutrient concentrations, and relationships between TOC, TN, and TP. Redundancy analysis was used to explore the relationship between soil nutrients, heavy metal concentrations, and plant community diversity. The results showed that the distributions of soil TOC, TN, and TP concentrations differed across regions in west Dongting Lake along the Yuan and Li Rivers. Total organic carbon concentration differed at different sedimentation depths. Soil grain size showed negative effect with soil TOC, TN, and TP concentrations in this region. Plant community diversity correlated positively with soil TOC and negatively with Hg. West Dongting Lake was N limited despite the high wet deposition of N. It could potentially be attributed to the insufficient presence of aerobic environments for microbes during intermittent flooding of the floodplain, coupled with feeble mineralization. This study can provide valuable insights for the conservation of water bird habitats and wetland ecosystems.

West Dongting Lake

Arctic speleothems reveal nearly permafrost-free Northern Hemisphere in the Late Miocene

Arctic warming is happening at nearly four times the global average rate. Long-term trends of permafrost dynamics cannot be estimated directly from monitoring of present-day thaw processes, requiring paleoclimate-proxy information. Here we use cave carbonates (speleothems) from a northern Siberian cave to determine when the Northern Hemisphere was mostly permafrost-free. At present, thick continuous permafrost in this region prevents speleothem growth. In a series of partially eroded caves, speleothems grew during the late Tortonian stage (8.68 ± 0.09 Ma), a time when the geographic position of this site was already similar to today. Paleotemperatures reconstructed from speleothems show that mean annual air temperatures (MAAT) in the region were + 6.6°C to + 11.1°C, when contemporary global MAAT were ~ 4.5 °C higher than modern. Our findings provide direct evidence that warming to Tortonian-like temperatures would leave most of the Northern Hemisphere permafrost-free. This may release up to ~ 130 petagrams of carbon, enhancing further warming.

Siberia

An inventory of three-dimensional geologic models—U.S. Geological Survey, 2004–22

A database of spatial footprints and characteristics of three-dimensional geological models that were constructed by the U.S. Geological Survey between 2004 and 2022 was compiled as part of ongoing development of subsurface geologic information by the USGS National Cooperative Geologic Mapping Program. This initial inventory resulted in the compilation of 38 three-dimensional geological models that vary widely in their spatial extent, the type and purpose of the model, the number of subsurface units characterized by the model, and the software platforms used to create the model. This Data Report provides the scientific rationale and explanation of the contents of a companion USGS digital data release of spatial data and attributes associated with each three-dimensional model.

Data Report

Corundum discovered by SuperCam and the Perseverance rover at Jezero crater, Mars

Mars is primarily composed of mafic mineral assemblages and their alteration products, but small, scattered rocks strewn across the landscape offer clues to greater petrological diversity. While traversing the Jezero crater rim, the Perseverance rover encountered several plagioclase-rich light-toned float rocks. SuperCam identified the distinctive signature of corundum (α-Al 2 O 3 ) in these rocks using time-resolved luminescence spectroscopy. Two strong peaks (692.7 and 694.1 nm) with millisecond lifetimes, and additional supporting lines, are consistent with Cr 3+ substitution for Al 3+ in corundum. Corundum forms in Al-rich, Si-depleted environments through magmatic or metamorphic processes. Given the rocks' small size, association with plagioclase, and location on the crater rim, we interpret the most plausible formation scenario to be impact induced metamorphism at the interface of a felsic and a mafic/ultramafic member with the likely action of fluids at some stage, although other possibilities are not excluded.

Geophysical Research Letters

Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24

The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.

Scientific Investigations Report

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper

A framework for understanding the effects of subsurface agricultural drainage on downstream flows

Understanding controls on streamflow volume and magnitude is important to water resource management applications, such as critical water and transportation structure design and floodplain mapping. Changes in land use and agricultural practices, such as subsurface agricultural drainage, may be contributing to changes in streamflow characteristics. Subsurface agricultural drainage, also known as tile drainage, is the practice of installing drains in the subsurface of agricultural fields to improve productivity. Because of the complex interactions between subsurface drainage systems, precipitation, local soil conditions, and land management practices, it is difficult to determine how subsurface agricultural drainage affects downstream flow. Previously developed subsurface agricultural drainage conceptual models under dry, saturated, and winter conditions are summarized, and current literature on the effects of subsurface agricultural drainage on downstream flows, focusing on peak flow, non-event flow, and total flow to develop frameworks for discussing these systems is compiled. The effects that subsurface drainage has on hydrologic systems are expected to vary by site and are seasonally based on system design, soil type, moisture conditions, precipitation characteristics, and land conditions. Subsurface drainage can affect the magnitude of peak flow by converting surface runoff from a storm event to subsurface runoff. By increasing hydrologic connectivity of a catchment, subsurface drainage can increase non-event flow or the flow between two storm events, typically dependent on lateral flow through the subsurface and groundwater. Theoretically, by diverting water from groundwater recharge or by reducing water available for evapotranspiration, subsurface drainage may increase the total volume of flow. Precipitation changes may increase infiltration, excess overland flow, and flood risk regardless of the presence or absence of subsurface drainage.

Illinois, Iowa, Michigan, Minnesota, Missouri, Mon

Using public participatory geographic information systems (PPGIS) to explore uses and values for Mojave Trails National Monument, California

Many people ascribe a variety of values to public lands and waters, but some values are more difficult to assess and quantify than others. Public participatory geographic information systems (PPGIS) are tools that have been used to help quantify and map the public’s diverse values for a landscape. This work describes the first known Office of Management and Budget–approved use of PPGIS by a Department of the Interior bureau. The U.S. Geological Survey developed an internet-based application to aid in gathering PPGIS data, called Values Mapping for Planning in Regional Ecosystems (VaMPIRE). Further, this work describes the first pilot of the VaMPIRE application in coordination with the Bureau of Land Management to collect spatial data and other survey data regarding the public’s uses of and values for locations within Mojave Trails National Monument. We emailed the link to the VaMPIRE application to an interested party email list in 2024 with 207 valid emails and received 74 responses; we also received 47 responses from members of an off-roading social media group. Of the list of 16 value options, recreation was the most popular value for the monument, followed by wilderness and inspirational. Over 1,000 points were placed throughout the monument, indicating locations people use or value, with the locations spread throughout the entire monument. Additionally, most survey respondents stated their ability to receive benefits in locations they mapped would not change in response to a hypothetical scenario related to recreational facility development. This report describes exploratory results from the first use of the VaMPIRE tool in Mojave Trails National Monument and includes reflections on how the process went and considerations for future use of VaMPIRE.

California

Eruptive history within the vicinity of Al Madīnah in northern Harrat Rahat, Kingdom of Saudi Arabia

The northernmost part of the Harrat Rahat volcanic field contains early Pleistocene to Holocene mafic eruptive products within the vicinity of the city of Al Madīnah, Kingdom of Saudi Arabia. A detailed geologic investigation into the eruptive history of a 570 square kilometer (km 2 ) area covering Al Madīnah and the surrounding area has yielded 33 mapped Quaternary volcanic units consisting of lava flows, scoria cones, and shield volcanoes. These eruptive products consist of continental, intraplate alkalic and minor transitional basalts, hawaiites, and a single mugearite that were emplaced from at least 1,014±14 thousand years ago (ka) to a single Holocene eruption in 1256 C.E. Lava flows are generally 10 to 15 kilometers (km) long (but can reach 23 km long), 1 to 3 km wide, and at least 10 meters thick. Most of the mapped units erupted episodically between 400 and 340 ka and 180 and 100 ka. Despite small individual volumes (less than 1 cubic kilometers dense rock equivalent), each unit represents eruption of a distinct magma batch that was strongly influenced by clinopyroxene, olivine, and plagioclase fractionation. Some of these units are interpreted to have undergone magma mixing pre- and (or) syneruptively. Integrating eruption ages, geochemistry, and paleomagnetic data yields evidence that some eruptions were temporally and (or) spatially clustered. Aligned scoria cones and elongate vent edifices were constructed atop fissure vent systems that reflect the local stress field, which controls dike ascent through the middle and upper crust.

Professional Paper

Generating geochemical and mineralogy distributions of soil in the conterminous United States using Bayesian hierarchical spatial models

Characterizing geochemical and mineralogical soil distributions across large spatial extents is essential for understanding mineral resources, ecosystem processes, and environmental risks. Rasters of soil geochemical distributions for the conterminous United States, however, are limited. We present a Bayesian modeling workflow and tool for generating predictive geochemical and mineralogy distribution maps for the conterminous United States using integrated nested Laplace approximation (INLA) with the stochastic partial differential equation approach. By modeling soil geostatistical data with environmental covariates (soil properties, topography, climate, and land cover), we generate predictive distributions of soil geochemistry that can be mapped or extracted for further analyses. As an example, we model the spatial distribution of trace elements in soil relevant to vertebrate health (cobalt, copper, iron, manganese, selenium, and zinc) and provide a workflow that can be used to generate and visualize predictive distributions of 39 other major and trace elements and 21 minerals of the soil survey, supporting a variety of ecological, environmental, and agricultural applications.

MethodsX

The feasibility of using lidar-derived digital elevation models for gravity data reduction

Gravity data require submeter elevation accuracy for data processing, and differential global navigation satellite system (dGNSS) equipment is commonly used to acquire three-dimensional positional data to achieve such accuracy. However, lidar (light detection and ranging) data are commonly used to develop digital elevation models (DEMs) of Earth’s surface. Therefore, using elevations from lidar-derived DEMs for gravity-data acquisition and reduction may improve field efficiency and reduce cost. This study examines the feasibility of using DEMs for gravity-data reduction by comparing dGNSS elevation data from 435 gravity stations in Michigan, Wyoming, and Colorado with their respective DEM elevations. The results show that the average difference between DEM and dGNSS elevations is 13 centimeters (cm) and that 93 percent of those differences are less than 50 cm, even in areas with steep terrain. Because an elevation discrepancy of 50 cm corresponds to an error of roughly 0.1 milligals (mGal) in the simple Bouguer gravity anomaly, the results suggest that lidar-derived DEMs are a viable source for acquiring the elevation data needed to process gravity data, thus improving both the cost and efficiency of data collection for regional surveys where an accuracy of less than 1.0 mGal is desired.

Open-File Report

Nanometer-scale relationships between sedimentary organic matter molecular composition, fluorescence, cathodoluminescence, and reflectance: The importance of oxygen content at low thermal maturities

Molecular characterization of sedimentary organic matter (SOM), termed macerals, is a common goal when seeking to understand petroleum generation as well as other geologic processes in deep time. However, unambiguous measurement of discrete macerals is challenging due to the small size of organic particles in sedimentary rocks, the proximity of different organic matter types to one another, mineral-organic matter interactions, and maceral mixing that occurs during SOM isolation prior to ex situ analysis. The recent advent of infrared spectrometers capable of nanometer-scale resolution and the application of these technologies to geologic samples has enabled advances in rapid, in situ molecular characterization of SOM allowing for insights into paleoenvironmental processes, such as organic matter productivity and preservation, among others. Here we employ one such technology, optical photothermal infrared (OPTIR) spectroscopy, to map SOM functional group distributions at 500-nm resolution in a sample from the Lower Cretaceous Sunniland Limestone of the South Florida Basin. Examined fields of view include occurrences of amorphous organic matter (AOM), inertinite, micrinite, solid bitumen, telalginite, and vitrinite. OPTIR data from these macerals are compared against traditional organic petrographic data from the same organic grains including fluorescence intensity and white light reflectance as well as against cathodoluminescence response, an emerging organic petrographic approach. Maceral oxygen content (using carbonyl functional group abundance as a proxy) is observed to vary widely between maceral types but correlates strongly with fluorescence and cathodoluminescence intensity as well as against reflectance. These findings highlight the important role that oxygen content plays in determining the optical properties of SOM and further demonstrate the ability of OPTIR to discriminate subtle molecular differences between SOM types.

Organic Geochemistry

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

Assessment and characterization of ephemeral stream channel stability and mechanisms affecting erosion in Grand Valley, western Colorado, 2018–21

The Grand Valley in western Colorado is in the semiarid Southwest United States. The north side of the Grand Valley has many ungaged ephemeral streams, which are of particular interest because (1) the underlying bedrock geology, Late Cretaceous Mancos Shale, is a sedimentary rock deposit identified as a major salinity contributor to the Colorado River and (2) despite infrequent streamflows of short duration, monsoon-derived floods in these ephemeral streams can carry substantial amounts of sediment downstream, affecting upstream and downstream banks and channel cross sections. The study area is of interest, because salinity, or the total dissolved solids concentration, in the Colorado River causes an estimated $300 million to $400 million per year in economic damages in the United States, and it is estimated 62 percent of the Upper Colorado River Basin’s total dissolved solid loads originate from geologic sources. In an effort to minimize salt contributions to the Colorado River from public lands administered by the Bureau of Land Management, a comprehensive salinity control approach is typically used to reduce nonpoint sources of salinity through land management techniques and practices. In 2018, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, began an assessment of ephemeral streams located on the north side of the Grand Valley, western Colorado, to characterize stream channel stability and identify mechanisms affecting erosion. The U.S. Geological Survey developed a method for automatically extracting channel cross-section geometry from existing remotely sensed terrain models. Based on estimated flood stage and surrogate streamflows, hydraulic characteristics were calculated. Furthermore, the channel geometries and hydraulic characteristics were used to estimate channel stability using a statistical model. Cross-section stabilities were determined from a stream channel stability assessment for a subset of 1,406 visited (field observed) locations out of 13,415 cross sections, which were delineated from remotely sensed terrain models. The application of Manning’s resistance equation in combination with multiple logistic regression models demonstrated channel stability can be estimated with a 0.845 goodness of fit for a validation dataset when using a combination of drainage area, width-to-depth ratio, sinuosity, and shear stress as the explanatory variables. Stream channel stability was extrapolated for 13,415 unvisited (not field observed) cross sections using the multiple logistic regression model and defined explanatory variables. Mapping of the ephemeral streams and their associated stabilities may be used by the Bureau of Land Management to prioritize areas for remediation or changes in management strategies to reduce sediment and salinity loading to the Colorado River. The study found channel stability within the ephemeral streams to be spatially variable, longitudinally discontinuous, and dictated by changes in channel bed slope. The stable ephemeral streams were relatively wide and shallow and often had smaller drainage areas with less potential for producing shear stresses capable of overcoming channel adhesion. A change in channel bed slope can provide the means necessary to generate shear stresses appropriate to initiate erosion and a subsequent stability transition to incising channels. Channel widening happens when either or both banks of an incising channel reach a critical height for mass wasting, or when channel curvature causes higher sidewall stress. Regardless, widening channels can promote increases in sinuosity and subsequently reduce steep channel bed slopes. Consequently, stable and widening channels can have comparable bed slopes, making channel bed slope a poor explanatory variable to predict channel stability overall, despite its function to initiate channel instability. The results were based on a surrogate 0.10 annual exceedance probability (AEP; return period equal to the 10-year flood) interval streamflow, although it was recognized fluctuations in streamflow would also affect channel stability. Past and current changes within the study area affect streamflow; therefore, mechanisms affecting erosion include land use disturbances, soil compaction, loss of vegetation cover, drought, less frequent and more extreme precipitation, and fires—which all intensify the potential runoff and erosion within the study area.

Colorado

Spatiotemporal variability of algal biomass and nitrate in Owasco and Seneca Lakes in the Finger Lakes Region, New York, in 2019

Cyanobacterial harmful algal blooms (CyanoHABs) have become increasingly common, threatening the security of water resources globally. The U.S. Geological Survey conducted high-resolution nearshore mapping surveys using boat-mounted multiparameter sondes and nitrate sensors during the summer and fall of 2019 on Owasco Lake and Seneca Lake, two lakes with documented CyanoHABs in the Finger Lakes region of New York State. Discrete sensor measurements and water-quality samples were collected at fixed points along survey routes and continuous data were generated at open-water monitoring platforms. This investigation examined whether water-quality information from nearshore surveys was representative of open-water conditions and if nearshore surveys could be used to identify areas with localized nearshore CyanoHABs and potential sources of nutrients not captured by tributary sampling. In addition to comparisons across methods, nearshore concentrations of nitrate and chlorophyll were evaluated relative to tributary outlets, cyanobacterial abundance and biovolume at discrete locations, and the locations of near-surface CyanoHABs that were designated as “confirmed with high toxins” by the New York State Department of Environmental Conservation. Nitrate and chlorophyll concentrations were comparable across methods for each lake, although concentration ranges were typically higher for nearshore mapping datasets than for nearshore discrete datasets. Nearshore surveys indicated areas of nitrate enrichment that varied temporally in both lakes. Orthophosphate was not routinely detected. Across methods, median chlorophyll concentrations were higher for the summer survey than for the fall survey in Owasco Lake. Nearshore chlorophyll concentrations varied more temporally in Owasco Lake than in Seneca Lake. Phytoplankton and cyanobacterial abundance and biovolume were about five times higher in Owasco Lake than in Seneca Lake. Cyanobacteria dominated the phytoplankton community in most samples, and Microcystis comprised the bulk of the cyanobacterial biovolume. The most abundant potential cyanotoxin-producing (specifically microcystins) genera were Microcystis , Synechococcus , Aphanocapsa , and Pseudanabaena . The cyanobacterial community composition was comparable between open-water monitoring platforms and nearshore samples. Microcystins were detected in seven survey samples from Owasco Lake, in one survey sample from Seneca Lake, and in one sample each from the open-water monitoring platforms on Owasco and Seneca Lakes that were collected about 7 days before the fall surveys. Microcystin detections were not consistently associated with high cyanobacterial cell counts or cyanotoxin-producing genera. Results from nearshore surveys were comparable to open-water monitoring platforms and discrete nearshore observations in the absence of nearshore or open-water CyanoHABs in these systems during the study. Patterns of nearshore concentrations of nitrate and chlorophyll from nearshore surveys may aid in the identification of areas with localized nitrate loading and shifts in phytoplankton abundance and community composition.

New York

The U.S. Geological Survey National Water Quality Network—Groundwater, 2024

The U.S. Geological Survey (USGS) operates a National Water Quality Network (NWQN) to monitor trends in groundwater quality and assess emerging contaminants of concern. It is a “network of networks” with 81 subnetworks being sampled on a decadal time scale. Each year, 8 of the subnetworks are sampled. Subnetworks have 20–30 wells each and include studies of domestic supply wells or shallow groundwater (20–50 feet deep) underlying urban land use or agricultural land use. Currently there are 2,089 wells in the network. All wells are sampled for physical properties, nutrients, major ions, trace elements, per- and polyfluoroalkyl substances (PFAS), and a subset of wells are sampled for pesticides, volatile organic compounds, radionuclides, and microbiological contaminants.

Contiguous United States

Regreening, restoring, and reconnecting a southwestern wetland ecosystem – the Zeedyk wetland

Alluvial wetland ecosystems are vital as biodiversity hotspots but are increasingly threatened by anthropogenic stressors and drought. These pressures are especially acute in arid and semi-arid regions, where eco-hydrologic connectivity is fragile and recovery is slow. This study quantifies the efficacy of nature-based solutions, particularly the ‘Zeedyk approach,’ which employs low-tech Natural Infrastructure in Dryland Streams (NIDS)—including rock detention structures—to slow surface water, raise groundwater tables, and restore wetland function at a spring-fed wetland in Cebolla Canyon, New Mexico, U.S.A. Our results depict a Restoration Feedback Loop that captures stages of change from a healthy wetland in 1935, altered by 20th-century agriculture and grazing, to the re-establishment of the historical flow regime by 2024 documented through an 89-year archive of aerial imagery (1935–2024). By the end of our study period, the Spring-Fed Wetland had expanded by roughly 229% of the original 1935 area, to 4.13 ha. Using 40 years of satellite data, we assess changes in vegetation and hydrology with remote sensing indices. Spatial and temporal analyses reveal significant increases in vegetation greenness and wetness, particularly in an Expanded Wetland subregion, which exhibited ∼3.5x higher wetness and ∼1.5x higher greenness trends compared to adjacent areas. Monthly metrics highlight seasonal variability, with increases in greenness linked to monsoonal rainfall and lateral water redistribution, indicating that restoration impacts extend beyond the primary wetland. This study demonstrates the utility of cloud-based platforms like Google Earth Engine and USGS EarthExplorer for long-term monitoring of wetland restoration, while quantifying the efficacy of the ‘Zeedyk approach’ and demonstrating its potential as a scalable method to restore and conserve wetland meadows in other arid and semi-arid landscapes.

New Mexico

Examining the compositional selectivity of hydrocarbon oxidation products using liquid–liquid extraction and solid-phase extraction techniques

The effect of extraction methods on detecting hydrocarbon oxidation products (HOPs) in groundwater remains unclear. HOPs are polar, water-soluble byproducts of petroleum biodegradation. Our previous work showed that liquid–liquid extraction (LLE), a method commonly used in regulatory monitoring, has a significantly lower extraction efficiency for HOPs compared to solid-phase extraction (SPE). In this study, we evaluate the analytical limitations and compositional selectivity of LLE and SPE using groundwater samples from the Bemidji, MN, crude oil spill site. Optical properties were characterized using excitation–emission matrix spectroscopy (EEMs), and a three-component PARAFAC model was validated, showing consistent trends across both extracts and whole water samples. Ultrahigh-resolution mass spectrometry (UHR-MS) revealed that LLE selectively recovered aliphatic-like compounds but underrepresented more polar oxygenated HOPs. In contrast, SPE methods were more effective at isolating highly oxidized compound classes. These differences were consistent across a gradient of contamination. Overall, the LLE was less precise and less representative of polar HOPs, introducing bias in the characterization of HOPs. This study is the first to quantitatively demonstrate the compositional selectivity and analytical bias of LLE versus SPE for HOPs using combined EEM-PARAFAC and UHR-MS techniques, with implications for long-term monitoring and site assessment protocols.

Environmental Science and Technology