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At least 1,135 records · Page 63Linked to original sources
USGS2001

Impacts of heterogeneous organic matter on phenanthrene sorption--Different soil and sediment samples

Organic petrography has been proposed as a tool for characterizing the heterogeneous organic matter present in soil and sediment samples. A new simplified method is proposed as a quantitative means of interpreting observed sorption behavior for phenanthrene and different soils and sediments based on their organic petrographical characterization. This method is tested under singe solute conditions and at phenanthrene concentration of 1 μg/L. Since the opaque organic matter fraction dominates the sorption process, we propose that by quantifying this fraction one can interpret organic content normalized sorption distribution coefficient ( K oc ) values for a sample. While this method was developed and tested for various samples within the same aquifer, in the current study the method is validated for soil and sediment samples from different sites that cover a wide range of organic matter origin, age, and organic content. All 10 soil and sediment samples studied had log K oc values for the opaque particles between 5.6 and 6.8. This range of K oc values illustrates the heterogeneity of opaque particles between sites and geological formations and thus the need to characterize the opaque fraction of materials on a site-by-site basis.

Environmental Science & Technology↗
USGS2008

Lead sequestration and species redistribution during soil organic matter decomposition

The turnover of soil organic matter (SOM) maintains a dynamic chemical environment in the forest floor that can impact metal speciation on relatively short timescales. Here we measure the speciation of Pb in controlled and natural organic (O) soil horizons to quantify changes in metal partitioning during SOM decomposition in different forest litters. We provide a link between the sequestration of pollutant Pb in O-horizons, estimated by forest floor Pb inventories, and speciation using synchrotron-based X-ray fluorescence and X-ray absorption spectroscopy. When Pb was introduced to fresh forest Oi samples, it adsorbed primarily to SOM surfaces, but as decomposition progressed over two years in controlled experiments, up to 60% of the Pb was redistributed to pedogenic birnessite and ferrihydrite surfaces. In addition, a significant fraction of pollutant Pb in natural soil profiles was associated with similar mineral phases (???20-35%) and SOM (???65-80%). Conifer forests have at least 2-fold higher Pb burdens in the forest floor relative to deciduous forests due to more efficient atmospheric scavenging and slower organic matter turnover. We demonstrate that pedogenic minerals play an important role in surface soil Pb sequestration, particularly in deciduous forests, and should be considered in any assessment of pollutant Pb mobility. ?? 2008 American Chemical Society.

Environmental Science & Technology↗
USGS1996

Identification of a new sulfonic acid metabolite of metolachlor in soil

An ethanesulfonic acid metabolite of metolachlor (metolachlor ESA) was identified in soil-sample extracts by negative-ion, fast-atom bombardment mass spectrometry (FAB-MS) and FAB tandem mass spectrometry (FAB-MS/MS). Production fragments from MS/MS analysis of the deprotonated molecular ion of metolachlor ESA in the soil extract can be reconciled with the structure of the synthesized standard. The elemental compositions of the (M - H)- ions of the metolachlor ESA standard and the soil-sample extracts were confirmed by high-resolution mass spectrometry. A dissipation study revealed that metolachlor ESA is formed in soil under field conditions corresponding to a decrease in the concentration of the parent herbicide, metolachlor. The identification of the sulfonated metabolite of metolachlor suggests that the glutathione conjugation pathway is a common detoxification pathway shared by chloroacetanilide herbicides.

Environmental Science & Technology↗
USGS2000

Sorption of selected organic compounds from water to a peat soil and its humic-acid and humin fractions: Potential sources of the sorption nonlinearity

The sorption isotherms of ethylene dibromide (EDB), diuron (DUN), and 3,5-dichlorophenol (DCP) from water on the humic acid and humin fractions of a peat soil and on the humic-acid of a muck soil have been measured. The data were compared with those of the solutes with the whole peat from which the humic-acid (HA) and humin (HM) fractions were derived and on which the sorption of the solutes exhibited varying extents of nonlinear capacities at low relative concentrations (C(e)/S(w)). The HA fraction as prepared by the density-fractionated method is relatively pure and presumably free of high- surface-area carbonaceous material (HSACM) that is considered to be responsible for the observed nonlinear sorption for nonpolar solutes (e.g., EDB) on the peat; conversely, the base-insoluble HM fraction as prepared is presumed to be enriched with HSACM, as manifested by the greatly higher BET- (N2) surface area than that of the whole peat. The sorption of EDB on HA exhibits no visible nonlinear effect, whereas the sorption on HM shows an enhanced nonlinearity over that on the whole peat. The sorption of polar DUN and DCP on HA and HM display nonlinear effects comparable with those on the whole peat; the effects are much more significant than those with nonpolar EDB. These results conform to the hypothesis that adsorption onto a small amount of strongly adsorbing HSACM is largely responsible for the nonlinear sorption of nonpolar solutes on soils and that additional specific interactions with the active groups of soil organic matter are responsible for the generally higher nonlinear sorption of the polar solutes.

Environmental Science & Technology↗
USGS2002

Cycling of beryllium and carbon through hillslope soils in Iowa

Isotopes of Be and C were used to reconstruct loess accumulation, hillslope evolution, and agricultural modification in soils of western Iowa. While both elements are derived from additions by the atmosphere (via plants in the case of carbon), the differences in element cycling allow erosional and depositional processes to be separated from biochemical processing. Based on 10Be, loess accumulation likely occurred simultaneously with hillslope degradation. Rates of loess accumulation declined five-fold between early stages (late Pleistocene and early Holocene) and later stages (late Holocene) of accumulation, but the absolute timing of accumulation requires independent dating methods. Based on 14C measurements, plant inputs and decomposition are significant near the surface, but below 1-1.5 m carbon inputs are minimal and decomposition is nearly arrested. The amount of carbon below 1.5 m is constant (0.1%) and is composed of soil organic matter that was buried by loess. Agricultural modification results in a dramatic redistribution of 10Be through soil erosion and deposition. By contrast, the redistribution of soil organic matter is masked by the rapid cycling of C through the topsoil as it continually decomposes and is replaced by plant inputs.

Biogeochemistry↗
USGS2000

Chamber measurement of surface-atmosphere trace gas exchange: Numerical evaluation of dependence on soil interfacial layer, and source/sink products

We employed a three-dimensional finite difference gas diffusion model to simulate the performance of chambers used to measure surface-atmosphere tace gas exchange. We found that systematic errors often result from conventional chamber design and deployment protocols, as well as key assumptions behind the estimation of trace gas exchange rates from observed concentration data. Specifically, our simulationshowed that (1) when a chamber significantly alters atmospheric mixing processes operating near the soil surface, it also nearly instantaneously enhances or suppresses the postdeployment gas exchange rate, (2) any change resulting in greater soil gas diffusivity, or greater partitioning of the diffusing gas to solid or liquid soil fractions, increases the potential for chamber-induced measurement error, and (3) all such errors are independent of the magnitude, kinetics, and/or distribution of trace gas sources, but greater for trace gas sinks with the same initial absolute flux. Finally, and most importantly, we found that our results apply to steady state as well as non-steady-state chambers, because the slow rate of gas diffusion in soil inhibits recovery of the former from their initial non-steady-state condition. Over a range of representative conditions, the error in steady state chamber estimates of the trace gas flux varied from -30 to +32%, while estimates computed by linear regression from non-steadystate chamber concentrations were 2 to 31% too small. Although such errors are relatively small in comparison to the temporal and spatial variability characteristic of trace gas exchange, they bias the summary statistics for each experiment as well as larger scale trace gas flux estimates based on them.

Journal of Geophysical Research D: Atmospheres↗
USGS1999

Soil water retention and maximum capillary drive from saturation to oven dryness

This paper provides an alternative method to describe the water retention curve over a range of water contents from saturation to oven dryness. It makes two modifications to the standard Brooks and Corey [1964] (B-C) description, one at each end of the suction range. One expression proposed by Rossi and Nimmo [1994] is used in the high-suction range to a zero residual water content. (This Rossi-Nimmo modification to the Brooks-Corey model provides a more realistic description of the retention curve at low water contents.) Near zero suction the second modification eliminates the region where there is a change in suction with no change in water content. Tests on seven soil data sets, using three distinct analytical expressions for the high-, medium-, and low-suction ranges, show that the experimental water retention curves are well fitted by this composite procedure. The high-suction range of saturation contributes little to the maximum capillary drive, defined with a good approximation for a soil water and air system as H cM = ∫ 0 ∞ K rw dh c , where k rw is relative permeability (or conductivity) to water and h c is capillary suction, a positive quantity in unsaturated soils. As a result, the modification suggested to describe the high-suction range does not significantly affect the equivalence between Brooks-Corey (B-C) and van Genuchten [1980] parameters presented earlier. However, the shape of the retention curve near “natural saturation” has a significant impact on the value of the capillary drive. The estimate using the Brooks-Corey power law, extended to zero suction, will exceed that obtained with the new procedure by 25 to 30%. It is not possible to tell which procedure is appropriate. Tests on another data set, for which relative conductivity data are available, support the view of the authors that measurements of a retention curve coupled with a speculative curve of relative permeability as from a capillary model are not sufficient to accurately determine the (maximum) capillary drive. The capillary drive is a dynamic scalar, whereas the retention curve is of a static character. Only measurements of infiltration rates with time can determine the capillary drive with precision for a given soil.

Water Resources Research↗
USGS2000

Testing a full‐range soil‐water retention function in modeling water potential and temperature

Recent work has emphasized development of full‐range water‐retention functions that are applicable under both wet and dry soil conditions, but evaluation of such functions in numerical modeling has been limited. Here we show that simulations using the Rossi‐Nimmo (RN) full‐range function compared favorably with those using the common Brooks‐Corey function and that the RN function can improve prediction of water potentials in near‐surface soil, particularly under dry conditions. Simulations using the RN function also improved prediction of temperatures throughout the soil profile. Such improvements could be important for calculations of liquid and vapor flow in near‐surface soils and in deep unsaturated zones of arid and semiarid regions.

Water Resources Research↗
USGS2004

Effects of the herbicides prosulfuron and metolachlor on fluxes of CO2,N2O, and CH4 in a fertilized Colorado grassland soil

The effect that pesticides have on trace gas production and consumption in agricultural soils is often overlooked. Independent field and laboratory experiments were used to measure the effects that the commonly used herbicides prosulfuron and metolachlor have on trace gas fluxes (CO 2 , N 2 O, and CH 4 ) from fertilized soil of the Colorado shortgrass steppe. Separate sample plots (1 m 2 ) on tilled and no-till soil at the sites included the following treatments: 1) a control without fertilizer or herbicide, 2) a fertilized (NH 4 NO 3 equivalent to 244 kg ha −1 ) control without herbicide, 3) and fertilized plots amended with an herbicide (prosulfuron equivalent to 0.46 kg ha −1 57% by weight active ingredient or metolachlor equivalent to 5.7 L ha −1 , 82.4% by weight active ingredient). During an initial study of one year duration, measurement of gas exchange revealed that prosulfuron-amendment stimulated N 2 O emissions and CH 4 consumption by as much as 1600% and 1300% during a single measurement, respectively. During a second set of flux measurements beginning in August 2001, more frequent weekly measurements were made during a twelve week period. From this second study an increased N 2 O efflux and CH 4 uptake occurred after a 7-week lag period that persisted for about 5 weeks. These changes in gas flux amounted to an overall increase of 41% and 30% for N 2 O emission and CH 4 consumption, respectively. The co-occurrence of stimulated N 2 O and CH 4 fluxes suggests a similar cause that is related to prosulfuron degradation. Evidence suggested that prosulfuron degradation stimulated microbial activity responsible for trace gas flux. Ultimately, prosulfuron-amendment led to an ∼50% reduction in the global warming potential from N 2 O and CH 4 fluxes at this field site, which is equivalent to a reduction of the global warming potential of 0.18 mols CO 2 m −2 d −1 from these gases. Metolachlor application did not significantly affect the trace gas fluxes measured. These results demonstrate the potential impact that pesticides have on trace gas fluxes from agricultural soils, which could mean that the effects of other agricultural practices have been over or under estimated.

Colorado↗
USGS2005

Geomorphic control of radionuclide diffusion in desert soils

Diffusion is a standard model for the vertical migration of radionuclides in soil profiles. Here we show that diffusivity values inferred from fallout 137CS profiles in soils on the Fortymile Wash alluvial fan, Nye County, Nevada, have a strong inverse correlation with the age of the geomorphic surface. This result suggests that radionuclide-bound particles are predominantly transported by infiltration rather than by bulk-mixing processes such as wetting/ drying, freeze/thaw, and bioturbation. Our results provide a preliminary basis for using soil-geomorphic mapping, point-based calibration data, and the diffusion model to predict radionuclide trans desert soils within a pedotransfer-function approach. Copyright 2005 by the American Geophysical Union.

Geophysical Research Letters↗
USGS2008

Climatically driven loss of calcium in steppe soil as a sink for atmospheric carbon

During the last several thousand years the semi-arid, cold climate of the Russian steppe formed highly fertile soils rich in organic carbon and calcium (classified as Chernozems in the Russian system). Analysis of archived soil samples collected in Kemannaya Steppe Preserve in 1920, 1947, 1970, and fresh samples collected in 1998 indicated that the native steppe Chernozems, however, lost 17-28 kg m-2 of calcium in the form of carbonates in 1970-1998. Here we demonstrate that the loss of calcium was caused by fundamental shift in the steppe hydrologic balance. Previously unleached soils where precipitation was less than potential evapotranspiration are now being leached due to increased precipitation and, possibly, due to decreased actual evapotranspiration. Because this region receives low levels of acidic deposition, the dissolution of carbonates involves the consumption of atmospheric CO2. Our estimates indicate that this climatically driven terrestrial sink of atmospheric CO2 is ???2.1-7.4 g C m-2 a-1. In addition to the net sink of atmospheric carbon, leaching of pedogenic carbonates significantly amplified seasonal amplitude of CO2 exchange between atmosphere and steppe soil. Copyright 2008 by the American Geophysical Union.

Global Biogeochemical Cycles↗
USGS2007

Sulfur species behavior in soil organic matter during decomposition

Soil organic matter (SOM) is a primary re??servoir of terrestrial sulfur (S), but its role in the global S cycle remains poorly understood. We examine S speciation by X-ray absorption near-edge structure (XANES) spectroscopy to describe S species behavior during SOM decomposition. Sulfur species in SOM were best represented by organic sulfide, sulfoxide, sulfonate, and sulfate. The highest fraction of S in litter was organic sulfide, but as decomposition progressed, relative fractions of sulfonate and sulfate generally increased. Over 6-month laboratory incubations, organic sulfide was most reactive, suggesting that a fraction of this species was associated with a highly labile pool of SOM. During humification, relative concentrations of sulfoxide consistently decreased, demonstrating the importance of sulfoxide as a reactive S phase in soil. Sulfonate fractional abundance increased during humification irrespective of litter type, illustrating its relative stability in soils. The proportion of S species did not differ systematically by litter type, but organic sulfide became less abundant in conifer SOM during decomposition, while sulfate fractional abundance increased. Conversely, deciduous SOM exhibited lesser or nonexistent shifts in organic sulfide and sulfate fractions during decomposition, possibly suggesting that S reactivity in deciduous litter is coupled to rapid C mineralization and independent of S speciation. All trends were consistent in soils across study sites. We conclude that S reactivity is related to spqciation in SOM, particularly in conifer forests, and S species fractions in SOM change, during decomposition. Our data highlight the importance of intermediate valence species (sulfoxide and sulfonate) in the pedochemical cycling of organic bound S. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗
USGS2008

Boreal soil carbon dynamics under a changing climate: A model inversion approach

Several fundamental but important factors controlling the feedback of boreal organic carbon (OC) to climate change were examined using a mechanistic model of soil OC dynamics, including the combined effects of temperature and moisture on the decomposition of OC and the factors controlling carbon quality and decomposition with depth. To estimate decomposition rates and evaluate their variations with depth, the model was inverted using a global optimization algorithm. Three sites with different drainage conditions that represent a broad diversity of boreal black spruce ecosystems were modeled. The comparison among the models with different depth patterns of decomposition rates (i.e., constant, linear, and exponential decrease) revealed that the model with constant inherent decomposition rates through the soil profile was able to fit the observed data in the most efficient way. There were also lower turnover times in the wettest site compared to the drier site even after accounting for moisture and temperature differences. Taken together, these results indicate that decomposition (especially for the wetter site) was not accurately represented with standard moisture and temperature controls and that other important protection mechanisms (e.g., limitation of O 2 , redox conditions, and permafrost) rather than low inherent decomposition rates are responsible for the recalcitrance of deep OC. The simulation results also showed that most of the soil CO 2 efflux is generated from subsurface layers of OC because of the large OC stocks and optimal moisture conditions, suggesting that these deeper soil OC stocks are likely to be critically important to the future carbon dynamics.

Journal of Geophysical Research Biogeosciences↗
USGS2018

Climate dictates magnitude of asymmetry in soil depth and hillslope gradient

Hillslope asymmetry is often attributed to differential eco‐hydro‐geomorphic processes resulting from aspect‐related differences in insolation. At midlatitudes, polar facing hillslopes are steeper, wetter, have denser vegetation, and deeper soils than their equatorial facing counterparts. We propose that at regional scales, the magnitude in insolation‐driven hillslope asymmetry is sensitive to variations in climate, and investigate the fire‐prone landscapes in southeastern Australia to evaluate this hypothesis. Patterns of asymmetry in soil depth and landform were quantified using soil depth measurements and topographic analysis across a contemporary rainfall gradient. Results show that polar facing hillslopes are steeper, and have greater soil depth, than equatorial facing slopes. Furthermore, we show that the magnitude of this asymmetry varies systematically with aridity index, with a maximum at the transition between water and energy limitation, suggesting a possible long‐term role of climate in hillslope development.

Geophysical Research Letters↗
USGS2019

Salinity yield modeling of the Upper Colorado River Basin using 30-meter resolution soil maps and random forests

Salinity loading in the Upper Colorado River Basin (UCRB) costs local economies upwards of $300 million US dollars annually. Salinity source models have generally included coarse spatial data to represent non‐agriculture sources. We developed new predictive soil property and cover maps at 30 m resolution to improve source representation in salinity modeling. Salinity loading erosion risk indices were also created based on soil properties, remotely sensed bare ground exposure, and topographic factors to examine potential surface soil erosion drivers. These new maps and data from previous SPARROW models were related to recently updated records of salinity at 309 stream gauges in the UCRB using random forest regressions. Resulting salinity yield predictions indicate more diffuse salinity sources, with slightly higher yields in more arid portions of the UCRB, and less overall load coming from irrigated agricultural sources. Model simulations still indicate irrigation to be the major human source of salinity (661,000 Mg, or 12%), but also suggest that 75,000 Mg (1.4%) of annual salinity in the UCRB is coming from areas with excessive exposed bare ground in high elevation mountain areas. Model inputs allow for field scale screening of locations that could be targeted for salinity control projects. Results confirm recent studies indicating limited surface erosional influence on salinity loading in UCRB surface waters, but impacts of monsoonal runoff events are still not fully understood, particularly in drylands. The study highlights the utility of new predictive soil maps and machine learning for environmental modeling.

Arizona, Colorado, New Mexico, Utah, Wyoming↗
USGS2021

Soil organic carbon development and turnover in natural and disturbed salt marsh environments

Salt marsh survival with sea‐level rise (SLR) increasingly relies on soil organic carbon (SOC) accumulation and preservation. Using a novel combination of geochemical approaches, we characterized fine SOC (≤1 mm) supporting marsh elevation maintenance. Overlaying thermal reactivity, source (δ 13 C), and age (F 14 C) information demonstrates several processes contributing to soil development: marsh grass production, redeposition of eroded material, and microbial reworking. Redeposition of old carbon, likely from creekbanks, represented ∼9‐17% of shallow SOC (≤26 cm), indicating that this process may become increasingly important with SLR. Soils stored marsh grass‐derived compounds with a range of reactivities that were reworked over centuries‐to‐millennia. Decomposition decreases SOC thermal reactivity throughout the soil column while the decades‐long disturbance of ponding accelerated this shift in surface horizons. Empirically derived estimates of SOC turnover based on geochemical composition spanned a wide range (640–9,951 years) and have the potential to inform future predictions of marsh ecosystem evolution.

Massachusetts↗
USGS2023

Can hydrological models benefit from using global soil moisture, evapotranspiration, and runoff products as calibration targets?

Hydrological models are usually calibrated to in-situ streamflow observations with reasonably long and uninterrupted records. This is challenging for poorly gage or ungaged basins where such information is not available. Even for gaged basins, the single-objective calibration to gaged streamflow cannot guarantee reliable forecasts because, as has been documented elsewhere, the inverse problem is mathematically ill-posed. Therefore, the inclusion of other observations, and the reproduction of other hydrological variables beyond streamflow, become critical components of accurate hydrological forecasting. In this study, six single- and multi-objective model calibration schemes based on different combinations of gaged streamflow, global-scale gridded soil moisture, actual evapotranspiration (ET), and runoff products are used for the calibration of a process-based hydrological model for 20 catchments located within the Lake Michigan watershed, of the Laurentian Great Lakes. Results show that the addition of gridded soil moisture to gaged streamflow in model calibration improves the ET simulation performance for most of the catchments, leading to the overall best-performing models. The monthly streamflow simulation performance for the experiments using gridded runoff products to inform the model is outperformed by those using the gaged streamflow, but the discrepancy is mitigated with increasing catchment scale. A new visualization method that effectively synthesizes model performance for the simulations of streamflow, soil moisture, and ET was also proposed. Based on the method, it is revealed that the streamflow simulation performance is relatively weak for baseflow-dominated catchments; overall, the 20 catchment models simulate streamflow and ET better than soil moisture.

Lake Michigan↗
USGS2025

Relationship of atmospheric nitrogen deposition to soil nitrogen cycling along an elevation gradient in the Colorado Front Range

Microbial processing of atmospheric nitrogen (N) deposition regulates the retention and mobilization of N in soils, with important implications for water quality. Understanding the links between N deposition, microbial communities, N transformations, and water quality is critical as N deposition shifts toward reduced N and remains persistently high in many regions. Here, we investigated these connections along an elevation transect in the Colorado Front Range. Although rates of N deposition and pools of extractable N increased down the elevation transect, soil microbial communities and N transformation rates did not follow clear elevational patterns. The subalpine microbial community was distinct, corresponding to a high C:N ratio and low pH, while the microbial communities at the lower elevation sites were all very similar. Net nitrification, mineralization, and nitrification potential rates were highest at the Plains (1,700 m) and Montane (2,527 m) sites, suggesting that these ecosystems mobilize N. In contrast, the net immobilization of N observed at the Foothills (1,978 m) and Subalpine (3,015 m) sites suggests that these ecosystems retain N deposition. The contrast in N transformation rates between the plains and foothills, both of which receive elevated N deposition, may be due to spatial heterogeneity not captured in this study and warrants further investigation. Stream N concentrations from the subalpine to the foothills were consistently low, indicating that these soils are currently able to process and retain N deposition, but this may be disrupted if drought, wildfire, or land-use change alter the ability of the soils to retain N.

Colorado↗