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Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico

Groundwater budget for the surficial aquifer surrounding Lake Nokomis, Minneapolis, Minnesota

During prolonged periods of above-average precipitation, rising groundwater levels have the potential to cause damage to and interfere with underground infrastructure and building foundations. To understand the relations between precipitation and groundwater in the vicinity of Lake Nokomis, the U.S. Geological Survey, in collaboration with the University of Minnesota, quantified five components of the groundwater budget: groundwater recharge, change in surficial aquifer storage, surficial aquifer groundwater discharge to Lake Nokomis, groundwater evapotranspiration, and groundwater discharge to underlying bedrock aquifers. Field data, geologic records, and empirical calculation methods were used to quantify groundwater budget components for April 2023 through April 2024. Lake water budget data indicate that Lake Nokomis is a flowthrough system during periods with no outflow through the weir, with groundwater inputs equal to outputs. Roughly 40 percent of precipitation that fell in the study area was added to the surficial aquifer as recharge. Uncertainty in the vertical hydraulic conductivity resulted in wide-ranging estimates (spanning three orders of magnitude) of water discharging from the surficial aquifer to the underlying bedrock aquifer. Drought conditions persisted for the duration of this study and were not representative of the conditions that motivated this study. This study is a start towards understanding relations between precipitation, Lake Nokomis levels, and groundwater levels that could affect local underground infrastructure.

Minnesota

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming

Slow slip detectability in seafloor pressure records offshore Alaska

In subduction zones worldwide, seafloor pressure data are used to observe tectonic deformation, particularly from megathrust earthquakes and slow slip events (SSEs). However, such measurements are also sensitive to oceanographic circulation-generated pressures over a range of frequencies that conflate with tectonic signals of interest. Using seafloor pressure and temperature data from the Alaska Amphibious Community Seismic Experiment, and sea surface height data from satellite altimetry, we evaluate the efficacy of various seasonal and oceanographic pressure signal proxy corrections and conduct synthetic tests to determine their impact on the timing and amplitude prediction of ramp-like signals typical of SSEs. We find that subtracting out the first mode of the complex empirical orthogonal functions of the pressure records on either the shelf or slope yields signal root-mean-square error (RMS) reductions up to 73% or 80%, respectively. Additional correction with proxies that exploit the depth-dependent spatial coherence of pressure records provides cumulative variance reductions up to 83% and 93%, respectively. Our detectability tests show that the timing and amplitude of synthetic SSE-like ramps can be well constrained for ramp amplitudes ≥4 cm on the shelf and ≥2 cm on the slope, using a fully automated detector. The principal limits on detectability are residual abrupt changes in pressure that occur as part of the transition to and from summer to winter conditions but are not adequately characterized by our seasonal corrections, as well as the inability to properly account for instrumental drift, which is not readily separated from the seasonal signal.

Alaska

The new self-anchored suspension (SAS) San Francisco Bay Bridge- Its response to a small earthquake

This paper presents a summary of previously published work (Celebi 2023) related to the new Self-Anchored Suspension (SAS) bridge that went into service within the last decade as a replacement for the older truss bridge spanning between Yerba Buena Island and Oakland, California, within the San Francisco Bay Area. During the October 19, 1989 M6.9 Loma Prieta earthquake, which occurred ~100 km south of the Bay Bridge, a section of the upper deck of the truss bridge fell onto the lower deck – thus closing this important lifeline between San Francisco and Oakland. The SAS is unique, self-anchored, and suspended by a single tower that is pivotal in trafficking the cable and hanger system to support the decks. The SAS bridge is extensively instrumented by the California Geological Survey’s Strong Motion Instrumentation Program (CSMIP). There are approximately 85 channels of accelerometers in the seismic monitoring system that recorded the October 14, 2019 Mw4.6 Pleasant Hill earthquake. The data allow a complex but identifiable coupled response of the deck, tower, and cable system. Both acceleration and displacement time-history data are used to extract significant frequencies using system identification methods, including spectral analyses. Results are compared to those from finite-element-model (FEM) analyses carried out during the design and analysis process of the bridge in 2002 (Nader et al. 2002). There are differences between FEM analyses results and those from the low amplitude shaking caused by a seismic event. An apparent frequency (period) of the SAS bridge is assessed (approximately 5.2 seconds). In a plot of deck length versus period, there is an almost linear relationship with periods of other regular suspension bridges, such as the Golden Gate Bridge and the Carquinez Bridge, both in the San Francisco Bay.

California

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California

Sensitivity of Alabama freshwater gastropod species to nickel exposure

Snails are effective bioindicators due to their prolific distribution, high level of endemism, and capacity to accumulate contaminants. Freshwater snails have unique ecological niches which are imperiled by land‐use change and the introduction of hazardous chemicals. To assess how environmental alterations affect gastropods, lab‐based studies are needed to characterize the toxicity of specific stressors. This can help guide policy decisions and remediation efforts. The aim of this research was to characterize acute toxicity of nickel (Ni) on endemic snails ( Somatogyrus georgianus [Walker, 1904], Elimia cahawbensis [Lea, 1861], and Elimia spp.) and measure the accumulation of Ni and mineral elements including calcium (Ca), magnesium, potassium, and sodium (Na). Snails were exposed to six concentrations (25–800 µg/L) of Ni for 96 h. Among the studied snail species, E. cahawbensis was the most sensitive to Ni, with the lowest lethal concentration where 50% of the organisms died (LC50) at 88.88 µg/L Ni after 96 h. The LC50 at 96 h for S. georgianus was 167.78 µg/L Ni, and 393.13 μg/L Ni for Elimia spp. Except for Elimia spp., mortality of the other two snail species corresponded to the whole‐body uptake of Ni. Nickel exposure also influenced Ca and Na uptake for Elimia spp. All three endemic species are potential candidate species for evaluating localized effects of human activities, and the present study provides a first step in characterizing how snails would be affected by environmental alterations. More research could further characterize potential effects of other human stressors on these endemic snail species. Future research into subindividual responses and routes of exposure can further elucidate variations in species sensitivity.

Alabama

Grand Canyon landslide-dam and paleolake triggered by the Meteor Crater impact at 56 ka

This paper hypothesizes that the Meteor Crater impact in Arizona, USA, 56,000 years ago triggered landslides in Grand Canyon that dammed the Colorado River and formed Nankoweap paleolake. This is compatible with shock and earthquake physics for the impact that infer a M5.4 seismic event, attenuated to an effective magnitude of M3.5 at Grand Canyon. Results that support the hypothesis include radiocarbon dating of driftwood and luminescence dating of associated slack-water lake sediments that are preserved in caves up to 60 m above the modern Colorado River. Radiocarbon ages from two locations, including Stanton’s Cave, date the driftwood as 55.25 ± 2.44 ka (n = 4). Sediments associated with the driftwood gave a luminescence age of 56.00 ± 6.39 ka (n = 2). These six Grand Canyon dates, and three published ages for the Meteor Crater impact, show statistically indistinguishable results that support the hypothesis for a geologically instantaneous series of events with a mean age of 55.60 ± 1.30 ka. This work highlights the value of radiocarbon dating near the limits of the technique, integration of multiple dating methods, and seismic and landslide hazards associated with meteorite impacts in regions of extreme topography like Grand Canyon.

Arizona

Preface to the focus section on earthquake-induced ground deformation

Ground failure due to earthquake-induced liquefaction, surface fault rupture, and landsliding has caused substantial damage in the past and continues to pose risks to critical infrastructure in the future. The consideration of ground failure is central to engineering analysis and design, ranging from site-specific engineering assessments of ground failure potential to broader regional-scale ground failure assessments of near-real-time earthquake impacts or longer-term portfolio risk. Uncertainties in all aspects of the problem complicate the prediction of earthquake-induced ground failure, including the identification of hazard-susceptible geomaterials, characterizing their spatial extent and physical properties, spatio-temporal variability in groundwater conditions, characterization of earthquake ground motions, assessing ground failure severity, and linking ground failure severity to infrastructure damage and loss.

Seismological Research Letters

Estimation of magnitude and frequency of floods for streams in Puerto Rico: New empirical models

Flood-peak discharges and frequencies are presented for 57 gaged sites in Puerto Rico for recurrence intervals ranging from 2 to 500 years. The log-Pearson Type III distribution, the methodology recommended by the United States Interagency Committee on Water Data, was used to determine the magnitude and frequency of floods at the gaged sites having 10 to 43 years of record. A technique is presented for estimating flood-peak discharges at recurrence intervals ranging from 2 to 500 years for unregulated streams in Puerto Rico with contributing drainage areas ranging from 0.83 to 208 square miles. Loglinear multiple regression analyses, using climatic and basin characteristics and peak-discharge data from the 57 gaged sites, were used to construct regression equations to transfer the magnitude and frequency information from gaged to ungaged sites. The equations have contributing drainage area, depth-to-rock, and mean annual rainfall as the basin and climatic characteristics in estimating flood peak discharges. Examples are given to show a step-by-step procedure in calculating a 100-year flood at a gaged site, an ungaged site, a site near a gaged location, and a site between two gaged sites.

Puerto Rico

Ground deformation and gravity for volcano monitoring

Introduction When magma accumulates or migrates, it can cause pressurization and related ground deformation. Characterization of surface deformation provides important constraints on the potential for future volcanic activity, especially in combination with seismic activity, gas emissions, and other indicators. A wide variety of techniques and instrument types have been applied to the study of ground deformation at volcanoes (sidebar, p. 2; Dzurisin, 2000, 2003, 2007). Geodetic instruments include continuously recording Global Navigation Satellite System (GNSS; of which the United States’ Global Positioning System is one example) stations (fig. D1), borehole tiltmeters, and interferometric synthetic aperture radar (InSAR) measurements (from satellites, occupied and unoccupied aircraft systems, and ground-based sensors). Additional geodetic measurements like continuous- and survey-mode gravity (fig. D2) can contribute substantially to interpreting these data. Borehole strainmeters (see chapter K , this volume, by Hurwitz and Lowenstern, 2024) also have outstanding utility for monitoring deformation, although because of cost and permitting challenges, we do not include them as part of standard volcano monitoring networks for U.S. volcanoes. Still other techniques like light detection and ranging (lidar), structure from motion, and optical satellite data can be used to derive gross topographic changes, which can be used to map volcanic deposits, infer eruption rates, and gain insights into the source processes associated with eruptive activity (see chapter G , this volume, on tracking surface changes caused by volcanic activity; Orr and others, 2024). Experience has shown that no single geodetic monitoring technique is adequate to detect and track the entire range of ground-motion patterns that occur at volcanoes, primarily because of the temporal and spatial diversity of volcano deformation (fig. D3). Similarly, the magnitude of surface deformation varies widely. Geodetic monitoring strategies should therefore include multiple techniques and instrument types to cover a wide range of spatial and temporal scales. In identifying recommendations for geodetic instrumentation for volcano monitoring networks, we attempted to maximize the diversity of instrument types to measure the full range of deformation signals and minimize their expense and number; thus, we do not include several well-known deformation-monitoring techniques in our recommendations. Extensometers, for example, measure strains over distances of a few meters and have an excellent record of success in detecting changes in preeruptive localized ground motion across existing cracks, including at Mount St. Helens, Washington (Iwatsubo and others, 1992), and Piton de la Fournaise, Réunion Island (Peltier and others, 2006). Despite being relatively inexpensive, extensometers are best used primarily when localized ground displacements (for example, ground cracks) need to be tracked, and are not necessary at all volcanoes. In considering volcano deformation monitoring strategies, two complicating factors are deserving of special attention. First, not all deformation is driven by subsurface magmatic activity—for example, at many large stratovolcanoes (for example, Mount Rainier), flank collapses and landslides are significant geologic hazards (Reid and others, 2001) that may occur even in the absence of magmatic activity. Monitoring the stability of volcanoes is thus another critical application of geodetic monitoring networks to inform hazard assessment. One of the most famous examples of edifice instability is the large flank collapse that initiated the May 18, 1980, eruption of Mount St. Helens. Deformation monitoring had detected a bulge on the north flank of the mountain in April 1980 that was expanding by several meters per day (Lipman and others, 1981). Given that flank collapses can happen at any time during a period of volcanic unrest (or even outside a period of unrest), the capability to assess edifice stability is critical. Second, although volcanoes are commonly treated as idealized structures that erupt from single points, like centralvent stratovolcanoes, many are characterized by long rift zones from which eruptions may originate, and distributed volcanic fields are characterized by broadly spaced vents. For example, linear dikes are common at Kīlauea, Mauna Loa, and between Mount Shasta and Medicine Lake in California. At Kīlauea, one of these linear dikes emerged more than 40 kilometers (km) away from the summit of the volcano during the lower East Rift Zone eruption in 2018. Other volcanic fields, like Lassen volcanic center, California, or the San Francisco Volcanic Field, Arizona, have many small vents spread over a wide area. Although the instrumentation guidelines presented in this chapter remain phrased for central-vent volcanoes, they should be modified as needed in the context of the eruptive characteristics of each individual volcanic system. Spatial analysis of geodetic network coverage could help to ensure adequate instrumentation in areas where volcanism can occur over a broad area as opposed to a central vent. As an example, consider the adjacent volcanoes Mount Shasta and Medicine Lake. If station locations are chosen based only on the distance from the centers of the volcanoes, then any geodetic anomalies between the two volcanoes—an area of potential volcanism as indicated by the presence of volcanic features—may remain undetected by ground-based instrumentation. The spatial analysis is accomplished via a grid of pressure point sources (Mogi, 1958) evenly distributed across the map area, at a depth of 5 km in this example (fig. D4). Each source is inflated until predicted deformations exceed the GNSS white noise uncertainty estimates at one site (Langbein, 2017; Murray and Svarc, 2017). This volume of detectable magma provides a measure of the quality of the coverage (fig. D4). The results indicate that, as of 2022, there is a large area between Mount Shasta and Medicine Lake volcano with existing mapped dikes in which a substantial amount of magma could intrude without being detected geodetically. Applying this style of analysis to individual volcanic systems can provide a guide for designing network geometry given the expected locations of future eruptions.

Scientific Investigations Report

Color-Shaded Relief Bathymetry of Lake Chelan, Washington

In 2023, the U.S. Geological Survey (USGS) completed a 3-week field operation in Lake Chelan, Washington, the third deepest lake in the conterminous United States, to acquire sediment cores, high-resolution bathymetry data, and chirp sub-bottom profiles. The high-resolution bathymetry displayed in this map publication was collected using a Norbit Winghead i67-curved array multibeam system; raw data were cleaned and gridded (3 by 3 meters [m]) in the Teledyne CARIS software. In some locations where the slopes of Lake Chelan are near-vertical, multibeam returns were sparse, resulting in artifacts resembling holes that appear as grey dots within the color-shaded bathymetric relief. Although the 2023 bathymetric mapping of Lake Chelan resulted in similar morphometric characteristics to previous hydrographic campaigns (table 1; Kendra and Singleton, 1987; Pelletier and others, 1989), these new data provide a much more detailed understanding of the two physiographic basins that comprise Lake Chelan: the deeper (as deep as 445.8 m [fig. 1]; previously reported as 453 m) and narrower (1–2 kilometers [km] wide) Lucerne Basin to the north, and the shallower (as deep as 127.8 m [fig. 1]), and wider (2–3 km wide) Wapato Basin to the south. With this detailed imaging of Lake Chelan, we find pervasive morphological evidence of slope failure and mass-transport deposits (MTDs) in at least 89 locations within the lake and 63 subaqueous deltas (fig. 2). The deeper Lucerne Basin is dominated by steep slopes and numerous subaqueous deltas fed by steep fluvial catchments, whereas the Wapato Basin contains numerous landslide scarps, scars, and debris aprons along the more gently sloping lake margins, and abundant relict kettle structures from the Pleistocene deglaciation. Lake Chelan’s geomorphic, geophysical, and sediment data contain important records of glacial retreat and advance, regional volcanic eruptions, and earthquakes that generate ground motions severe enough to induce landslides recorded in the sediment as MTDs. The epicenter of the 1872 Washington State Earthquake (M 6.5–7.2; Bakun and others, 2002; Brocher and others, 2017; Sherrod and others, 2021) is along the Spencer Canyon Fault, near the southern end of Lake Chelan. Shaking from this earthquake was strong enough to affect local aquifers, induce liquefaction of unconsolidated sediments, produce large seiches (Brocher and others, 2018), and likely cause landslides within Lake Chelan.

Washington

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada

Bathymetric and acoustic-backscatter mapping of Lake Sammamish, Washington, during USGS field activity 2021-656-FA

In 2021, scientists from the U.S. Geological Survey (USGS) acquired bathymetric and acoustic-backscatter data within Lake Sammamish, Washington. Mapping was completed to find evidence of past earthquakes such as underwater landslides and is part of a larger USGS project to understand the overall geologic hazards history of the Cascadia Margin region. The survey was conducted using the USGS research vessel Parke Snavely outfitted with an interferometric sidescan-sonar system for swath mapping. Three estimates of bathymetric uncertainty were calculated from the post-processed bathymetric data. This report provides a summary of the mapping mission.

Washington

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Ground-motion aleatory-variability models for Puerto Rico and the U.S. Virgin Islands

I develop independent logic trees for aleatory variability for crustal and subduction-zone (interface and intraslab) earthquakes for seismic hazards analyses in Puerto Rico and the U.S. Virgin Islands (PRVI) from existing suites of ground-motion models (GMMs) and from ground-motion datasets, including a regional PRVI dataset. The aleatory variability models are parameterized using a partially nonergodic partitioning of standard deviation that consists of independently developed between-event ( ), site-to-site ( ), and event-corrected single-station ( ) standard deviation components. The effects of nonlinear site response on aleatory variability are incorporated through additional terms that modify the standard deviation components. Because one goal of this work is to develop independent logic trees for aleatory variability that synthesize the aleatory variability models from GMMs, I make use of the functional forms of the input GMMs. The PRVI dataset contains a limited number of stations with high-quality site metadata and does not contain records from earthquakes with magnitudes greater than 6.1, so I choose not to develop the aleatory variability models from the regional dataset alone. Instead, the standard deviation components from regional ground-motion data are evaluated against the components derived from GMMs and from available global datasets, and regionalized standard deviation components are incorporated where there is evidence that regional effects exhibit substantial differences. The resulting logic trees for aleatory variability consist of models of and that are consistent with semiempirical GMMs for active crustal and subduction-zone regimes, and two alternative models of , including one model that exhibits site-to-site variability informed by PRVI data, with values that exceed global models. The aleatory variability models may be considered in future hazards assessments in PRVI to simplify the hazard calculations, to incorporate regional ground-motion variability effects, and to enable direct logic-tree weighs of aleatory variability.

Puerto Rico, U.S. Virgin Islands

Grammar to graph—An approach for semantic transformation of annotations to triples

Data annotation is the process of labeling data to show the outcome that a related data model should predict. In this study, annotation data were transformed into semantic graph triples, mainly for use with the Resource Description Framework (RDF), a type of entity-relationship-attribute data model for graph databases. The transformation of annotation data to semantic graph triples provides complex linguistic meaning with data handling advantages such as reduced data storage needs, improved logical specification of relations between objects, and reusable classes and properties that support logic and inference. A grammar-based framework in graph form supports user questions and queries. The words defining approximately 334 topographic feature types compiled by the U.S. Geological Survey were tokenized as units of analysis and grouped by part of speech. Their dependency relations were identified for this study using natural language processing libraries. Dependency concepts are used as structured semantic relations among part-of-speech classes. Tokens, units equivalent to words, form instances of classes and were quantified within a tabular output format using PostgreSQL data storage software. Table data were logically aligned as triples following a mapping file and stored with an ontology file using Ontop virtual triplestore software. A grammar ontology schema for the data was synchronized to match queries whose results validated the graph’s structure. The text analysis produced 8 part-of-speech classes of content words for object representations and 4 classes of function words for operational applications. Dependency relations formed 27 ontology properties for topographic subgraph structures. Token occurrences shaped overall ontology salience and formed a lexicon of syntactic terms for subgraph objects and properties. The schema ontology of class and property population shapes formed the lexicon of English terms. SPARQL Protocol and RDF Query Language (SPARQL) was used with the lexicon to conform data to RDF guidelines. This study confirms the hypothesis that although linguistic logic varies from description logic, its approximation applies to ontology design. Property and query use case patterns extracted from the analysis support queries concerning complex topographic relations and patterns normally embedded within text definitions. The method used in this study could be applied to text forms in other domains, such as survey notes.

Scientific Investigations Report

Predicting hydrothermal reservoir depth from chemical geothermometers using a three-dimensional temperature model in the Great Basin, USA

Recent work in the Great Basin region of the western United States has made it possible to predict the depth of hydrothermal reservoirs (i.e., the depth at which heat is accumulated prior to ascent via hydrothermal upflow) identified through geochemistry and to contextualize the spatial patterns of these reservoir depths. Chemical geothermometers use the chemical and mineral constituents of hydrothermal fluids to predict the temperature at which fluids equilibrated with the host rocks at depth. Assuming that most of the Great Basin is dominated by conductive conditions until a vertically connected hydrothermal flow path is created (e.g., by faulting), geothermometers reflect the chemical and thermal conditions at the depth interval that the fluid has conductively equilibrated over a long period before a vertical conduit allows convective upflow. By pairing geothermometer temperature estimates with our recent three-dimensional temperature model of conductive heat flow in the Great Basin, we estimate the corresponding reservoir depths and construct a map of circulation depths. The predicted depths from geothermometers have spatial patterns across the Great Basin that relate to patterns seen in other geologic and geophysical data. Deeper springs generally occur disproportionately in areas with higher strain rates and in basins. We posit that current elevated strain rates reflect patterns of historic deformation where ongoing tectonic activity maintains permeable pathways to deeper reservoirs, some of which are estimated to exceed 6 km depth. Basins, as expected, contain a disproportionate number of these deep systems, because the underlying aquifers are closer to the surface in basins, thus requiring less water pressure to reach the surface than in mountain ranges. Most springs estimated to have their source in a deep reservoir occur at places known to host a hydrothermal system; these refined depth estimates of the source reservoir can help to better constrain the source depth for many known hydrothermal systems across the Great Basin.

Arizona, California, Idaho, Nevada, Oregon, Utah