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At least 1,135 records · Page 63Linked to original sources

An algal model for predicting attainment of tiered biological criteria of Maine's streams and rivers

State water-quality professionals developing new biological assessment methods often have difficulty relating assessment results to narrative criteria in water-quality standards. An alternative to selecting index thresholds arbitrarily is to include the Biological Condition Gradient (BCG) in the development of the assessment method. The BCG describes tiers of biological community condition to help identify and communicate the position of a water body along a gradient of water quality ranging from natural to degraded. Although originally developed for fish and macroinvertebrate communities of streams and rivers, the BCG is easily adapted to other habitats and taxonomic groups. We developed a discriminant analysis model with stream algal data to predict attainment of tiered aquatic-life uses in Maine's water-quality standards. We modified the BCG framework for Maine stream algae, related the BCG tiers to Maine's tiered aquatic-life uses, and identified appropriate algal metrics for describing BCG tiers. Using a modified Delphi method, 5 aquatic biologists independently evaluated algal community metrics for 230 samples from streams and rivers across the state and assigned a BCG tier (1–6) and Maine water quality class (AA/A, B, C, nonattainment of any class) to each sample. We used minimally disturbed reference sites to approximate natural conditions (Tier 1). Biologist class assignments were unanimous for 53% of samples, and 42% of samples differed by 1 class. The biologists debated and developed consensus class assignments. A linear discriminant model built to replicate a priori class assignments correctly classified 95% of 150 samples in the model training set and 91% of 80 samples in the model validation set. Locally derived metrics based on BCG taxon tolerance groupings (e.g., sensitive, intermediate, tolerant) were more effective than were metrics developed in other regions. Adding the algal discriminant model to Maine's existing macroinvertebrate discriminant model will broaden detection of biological impairment and further diagnose sources of impairment. The algal discriminant model is specific to Maine, but our approach of explicitly tying an assessment tool to tiered aquatic-life goals is widely transferrable to other regions, taxonomic groups, and waterbody types.

Freshwater Science↗

Regional hydraulic geometry characteristics of stream channels in the Ouachita Mountains of Arkansas

Many stream channel infrastructure, habitat, and restoration projects are being undertaken on small streams throughout Arkansas by various Federal, State, and local agencies and by private organizations and businesses with limited data on local geomorphology and streamflow relations. Equations are needed that relate drainage area above stable stream reaches and the associated basin characteristics to bankfull streamflow and the associated channel dimensions. These equations, along with streambed material particle information, provide information that can improve stream channel projects. The U.S. Geological Survey and the Arkansas Natural Resources Commission in cooperation with the U.S. Army Corps of Engineers, Little Rock District, undertook a study to develop these equations for streams in the Ouachita Mountains of Arkansas. Seventeen streamgages operated by the U.S. Geological Survey, located on streams in the Ouachita Mountains, were selected for analysis. Regional hydraulic geometry curves that express the mathematical relation between the bankfull channel dimensions (cross-sectional area, top width, mean depth, and streamflow) and the contributing drainage areas were developed. Streambed material measurements were collected to develop descriptive statistics of the streambed particle-size distributions and percentages of substrate type at each study site. Stream reaches at each study site were classified to the Rosgen level II stream type based on the average of stream channel metrics collected from site cross sections and profiles. Of the 17 selected Ouachita Mountain stream reaches, 6 were classified as B stream types, and 11 were classified as C stream types. The B stream types have infrequently spaced pools; very stable plan forms, profiles, and banks; and narrow, gently sloping valleys, where bank vegetation is a moderate component of stability. The C stream types are meandering, point bar, riffle-pool channels associated with broad valleys having well-defined flood plains and terraces composed of alluvial soils, where bank vegetation is typically a high component of stability.

Arkansas↗

Groundwater quality data for the Tahoe-Martis study unit, 2007: Results from the California GAMA Program

Groundwater quality in the approximately 460-square-mile Tahoe–Martis study unit was investigated in June through September 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within the Tahoe–Martis study unit (Tahoe–Martis) and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 52 wells in El Dorado, Placer, and Nevada Counties. Forty-one of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 11 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N -nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, strontium isotope ratio, and stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 240 constituents and water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at 12 percent of the wells, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate of compliance or noncompliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from the Tahoe–Martis wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides) were detected in about 40 percent of the samples from grid wells, and most concentrations were less than 1/100th of regulatory and nonregulatory health-based thresholds, although the conentration of perchloroethene in one sample was above the USEPA maximum contaminant level (MCL-US). Concentrations of all trace elements and nutrients in samples from grid wells were below regulatory and nonregulatory health-based thresholds, with five exceptions. Concentrations of arsenic were above the MCL-US in 20 percent of the samples from grid wells. Gross alpha particle activity (MCL-US), boron (CDPH notification level, NL-CA), and molybdenum (USEPA lifetime health advisory, HAL-US) were each detected above thresholds in two of the samples from grid wells, and radon (proposed alternative MCL-US) was detected above the threshold in one sample from a grid well. Most of the samples from Tahoe–Martis grid wells had concentrations of major elements, total dissolved solids, and trace elements below the CDPH secondary maximum contaminant levels, nonenforceable thresholds set for aesthetic and technical concerns. Fifteen percent of the samples from grid wells contained iron, manganese, or total dissolved solids at concentrations above these levels.

California, Nevada↗

Groundwater quality data in the Mojave study unit, 2008: Results from the California GAMA Program

Groundwater quality in the approximately 1,500 square-mile Mojave (MOJO) study unit was investigated from February to April 2008, as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). MOJO was the 23rd of 37 study units to be sampled as part of the GAMA Priority Basin Project. The MOJO study was designed to provide a spatially unbiased assessment of the quality of untreated ground water used for public water supplies within MOJO, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 59 wells in San Bernardino and Los Angeles Counties. Fifty-two of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and seven were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, and pharmaceutical compounds], constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]) naturally occurring inorganic constituents (nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and trace elements), and radioactive constituents (gross alpha and gross beta radioactivity, radium isotopes, and radon-222). Naturally occurring isotopes (stable isotopes of hydrogen, oxygen, and carbon, stable isotopes of nitrogen and oxygen in nitrate, and activities of tritium and carbon-14), and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 230 constituents and water-quality indicators (field parameters) were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) each were collected at approximately 5–8 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples generally were within acceptable ranges, indicating acceptable analytical reproducibility. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated ground water. However, to provide some context for the results, concentrations of constituents measured in the untreated ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic and technical concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking-water are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. Most constituents that were detected in groundwater samples in the 59 wells in MOJO were found at concentrations below drinking-water thresholds. In MOJO’s 52 grid wells, volatile organic compounds (VOCs) were detected in 40 percent of the wells, and pesticides and pesticide degradates were detected in 23 percent of the grid wells. Results for health-based thresholds in MOJO grid wells showed that all of the detections of organic compounds in samples from MOJO grid wells were below health-based thresholds, with the exception of a single detection of NDMA above the California Department of Public Health notification level (NL-CA). Trace elements and radioactive constituents were sampled for at 19 MOJO grid wells and most detections were below health-based thresholds. Exceptions include: six detections of arsenic above the USEPA maximum contaminant level (MCL-US), two detections of boron and one detection of vanadium above the NL-CA, one detection each of molybdenum and strontium that were above the USEPA lifetime health advisory level (HAL-US), and one detection of fluoride just above the MCL-CA of 2 µg/L. Most detections of radioactive constituents in the MOJO grid wells were below health-based thresholds, with the exception of one detection of gross alpha radioactivity (72-hour count and 30-day count) above the MCL-CA, and 17 grid wells (of 19 sampled) that had activities of radon-222 above the proposed MCL-US of 300 pCi/L, but all were below the proposed alternative MCL-US of 4,000 pCi/L. All of the samples collected from the 19 MOJO grid wells for trace elements, and most of the samples for major ions and total dissolved solids (TDS), had measured concentrations below the non-enforceable thresholds set for aesthetic concerns. Four grid wells had TDS concentrations above the California Department of Public Health secondary maximum contaminant level (SMCL-CA) recommended threshold of 500 mg/L, and three of these wells were also above the SMCL-CA upper threshold of 1,000 mg/L. Four grid wells (of 19 sampled) had sulfate measured at concentrations above the recommended SMCL-CA threshold of 250 mg/L, and one of these detections was also above the upper SMCL-CA threshold of 500 mg/L. One grid well had chloride levels at a concentration above the upper SMCL-CA threshold of 500 mg/L. Eleven grid wells (of 52 sampled) had pH values outside of the SMCL-US range for pH.

California↗

Groundwater-quality data in the South Coast Interior Basins study unit, 2008: Results from the California GAMA Program

Groundwater quality in the approximately 653-square-mile South Coast Interior Basins (SCI) study unit was investigated from August to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to Legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater-Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater used as public supply for municipalities in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). SCI was the 27th study unit to be sampled as part of the GAMA Priority Basins Project. This study was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies within SCI, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 54 wells within the three study areas [Livermore, Gilroy, and Cuyama] of SCI in Alameda, Santa Clara, San Benito, Santa Barbara, Ventura, and Kern Counties. Thirty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 19 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds], constituents of special interest [perchlorate and N-nitrosodimethylamine (NDMA)], naturally occurring inorganic constituents [trace elements, nutrients, major and minor ions, silica, total dissolved solids (TDS), and alkalinity], and radioactive constituents [gross alpha and gross beta radioactivity and radon-222]. Naturally occurring isotopes [stable isotopes of hydrogen, oxygen, and carbon, and activities of tritium and carbon-14] and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 288 constituents and water-quality indicators (field parameters) were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) each were collected at approximately 4–11 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data obtained from the groundwater samples. Differences between replicate samples generally were less than 10 percent relative standard deviation, indicating acceptable analytical reproducibility. Matrix spike recoveries were within the acceptable range (70 to 130 percent) for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and/or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and to nonregulatory thresholds established for aesthetic and technical concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking water are for illustrative purposes only, and are not indicative of compliance or noncompliance with those thresholds. Most inorganic constituents that were detected in groundwater samples from the 35 grid wells in the SCI study unit were found at concentrations below drinking-water thresholds; additionally, all detections of organic constituents in SCI grid well samples were below health-based thresholds.

California↗

U.S. Geological Survey response to flooding in Texas, May–June 2015

As a Federal science agency within the Department of the Interior, the U.S. Geological Survey (USGS) collects and disseminates streamflow stage and discharge information along with other types of water information as a major part of its Water mission area. Data collected at USGS streamflow-gaging stations (hereinafter referred to as “streamgages”) are used for a variety of purposes including flood warning, engineering design, management of water resources, and scientific research. During flood events, the need for timely, accurate, and complete streamflow data is underscored because these data are relied on by local, State, and Federal emergency management personnel for flood response purposes. For example, the National Weather Service uses the data from USGS streamgages to develop flood forecasts for specific locations on a river. Tasks that the USGS performs in response to floods include monitoring the operation of gages and responding to any interruptions in data collection, calibrating and verifying stage-discharge ratings, and documenting extreme events including peak stage and peak discharge. Frequent, severe storms during May and June 2015 caused widespread flooding in Texas. By various measures, the storms that caused the flooding were extreme and persistent. May 2015 was the wettest month on record for Texas, with a statewide average precipitation of 9.06 inches. In comparison, the long-term statewide average monthly precipitation is 3.37 inches, with the previous record average monthly precipitation reported as 6.66 inches during June 2004. The Office of the Texas State Climatologist compiled monthly precipitation amounts for 19 selected cities throughout Texas and for 1 city in Louisiana; the total monthly precipitation amounts exceeded the monthly normal precipitation for 18 of the 19 selected cities in Texas, with 5 of these cities exceeding their previous record for the month of May. The onset of abundant precipitation in May 2015 resulted in the National Weather Service flood stage being exceeded at USGS streamgages on numerous rivers. The widespread and prolonged nature of the flooding was unusual; most flood events in Texas are localized, typically affecting only one or two river basins and generally lasting only a few days. With the exception of the Rio Grande, flooding was widespread in all of the major rivers in Texas during May–June 2015.

Texas↗

Analysis of geophysical logs, at North Penn Area 6 Superfund Site, Lansdale, Montgomery County, Pennsylvania

The U.S. Geological Survey (USGS), as part of technical assistance to the U.S. Environmental Protection Agency (USEPA), collected borehole geophysical log data in 34 industrial, commercial, and public supply wells and 28 monitor wells at the North Penn Area 6 Superfund Site, in Lansdale, Pa., from August 22, 1995, through August 29, 1997. The wells range in depth from 50 to 1,027 feet below land surface and are drilled in Triassic-age shales and siltstones of the Brunswick Group and Lockatong Formation. The geophysical log data were collected to help describe the hydrogeologic framework in the area and to provide guidance in the reconstruction of the 28 monitor wells drilled during summer 1997. At the time of logging, all wells had open-hole construction. The geophysical logs, caliper, fluid-resistivity, and fluid-temperature, and borehole video logs were used to determine the vertical distribution of water-bearing fractures. Heatpulse-flowmeter measurements were used to determine vertical borehole flow under pumping and nonpumping conditions. The most productive fractures generally could be determined from heatpulse-flowmeter measurements under pumping conditions. Vertical borehole flow was measured under nonpumping conditions in most wells that had more than one water-bearing fracture. Upward flow was measured in 35 wells and probably is a result of natural head differences between fractures in the local ground-water-flow system. Downward flow was measured in 11 wells and commonly indicated differences in hydraulic heads of the fractures caused by nearby pumping. Both upward and downward flow was measured in three wells. No flow was detected in eight wells. Natural-gamma-ray logs were used to estimate the attitude of bedding. Thin shale marker beds, shown as spikes of elevated radioactivity in the natural-gamma logs of some wells throughout the area, enable the determination of bedding-plane orientation from three-point correlations. Generally, the marker beds in and near Lansdale strike about N. 48°-60° E. and dip about 11° NW. Acoustic televiewer logs run in selected boreholes indicate that the attitude of many water-bearing fractures commonly is similar to that of bedding.

Pennsylvania↗

Groundwater chemistry and water-level elevations in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2013–16

The Piceance and Yellow Creek watersheds in Rio Blanco County, Colorado, are known to contain important energy resources (oil shale and natural gas) and mineral resources (nahcolite). The primary sources of fresh groundwater in the Piceance and Yellow Creek watersheds are bedrock aquifers in the Uinta and Green River Formations. The aquifers are divided into an upper and lower aquifer separated by a regionally extensive semiconfining layer. These aquifers provide water to streams and springs in the watersheds and are an important resource to people living and working in the area. Development of energy and mineral resources has the potential to affect the quality of groundwater in several ways. The Bureau of Land Management and the U.S. Geological Survey began groundwater monitoring in 2010 to characterize the groundwater quality and water-level elevations of shallow bedrock aquifers in the Piceance and Yellow Creek watersheds. The purpose of this report is to present ground-water chemistry and water-level elevations collected during 2013–16. Comparisons are made to data that were collected from the bedrock aquifers from 2010 to 2012 to identify the potential for changes in water quality and water-level elevations. Appreciable changes in water-level elevations and hydraulic gradient were observed in early April 2015 in two wells completed in the upper and lower aquifers. The hydraulic gradient between the two wells was consistently downward from the upper aquifer to the lower aquifer during 2010–15; however, in early April 2015, the gradient changed from downward to upward between the two aquifers. Overall, water-level elevations declined by about 14 and 11 feet in the upper and lower aquifers, respectively, from 2013 to 2016. Previously published data estimated groundwater ages at 1,200 years old in the upper aquifer and 9,600 years old in the lower aquifer. These groundwater ages indicate that ground-water was recharged over thousands of years. With such long periods of time for aquifer recharge, declines in water-level elevation over short time steps (a few months) have important implications for sustainable management of this resource. Solution mining activities or drilling for oil and natural gas in the area could be related to the changes observed in water-level elevations in these wells; however, further investigation would be needed to evaluate causation. Changes in major-ion chemistry were evaluated in the bedrock aquifer using time series plots of select major-ion data from 2010 to 2016. Major-ion chemistry was variable for a single well from 2010 to 2016 where alkalinity and sulfate were the most variable constituents. One possible explanation for the observed changes in major-ion chemistry may be that the sample depth for that well no longer represents the most appreciable flow in the borehole. On a larger scale, potential changes in flow within the borehole may indicate changes in the regional flow system. Methane and volatile organic compound concentrations were evaluated using a similar approach to that of major ions and had similar findings. Methane concentrations in wells sampled from 2010 to 2016 were generally constant. The only exception was observed at a single well where the range of methane concentrations was from 57.4 (2010) to 4.02 milligrams per liter (2013). This is the same well where changes in water-level elevation, hydraulic gradient, and major-ion chemistry were observed, providing multiple lines of evidence to indicate change in the bedrock aquifers. Sampling of a well located in an area with little energy development but where faults or fractures could provide a path for the migration of fluids indicate mixing of groundwater between the upper and lower aquifers.

Colorado↗

A watershed-scale approach to tracing metal contamination in the environment

Introduction Public policy during the 1800's encouraged mining in the western United States. Mining on Federal lands played an important role in the growing economy creating national wealth from our abundant and diverse mineral resource base. The common industrial practice from the early days of mining through about 1970 in the U.S. was for mine operators to dispose of the mine wastes and mill tailings in the nearest stream reach or lake. As a result of this contamination, many stream reaches below old mines, mills, and mining districts and some major rivers and lakes no longer support aquatic life. Riparian habitats within these affected watersheds have also been impacted. Often, the water from these affected stream reaches is generally not suitable for drinking, creating a public health hazard. The recent Department of Interior Abandoned Mine Lands ( AML ) Initiative is an effort on the part of the Federal Government to address the adverse environmental impact of these past mining practices on Federal lands. The AML Initiative has adopted a watershed approach to determine those sites that contribute the majority of the contaminants in the watershed. By remediating the largest sources of contamination within the watershed, the impact of metal contamination in the environment within the watershed as a whole is reduced rather than focusing largely on those sites for which principal responsible parties can be found. The scope of the problem of metal contamination in the environment from past mining practices in the coterminous U.S. is addressed in a recent report by Ferderer (1996). Using the USGS 1:2,000,000-scale hydrologic drainage basin boundaries and the USGS Minerals Availability System ( MAS ) data base, he plotted the distribution of 48,000 past-producing metal mines on maps showing the boundaries of lands administered by the various Federal Land Management Agencies ( FLMA ). Census analysis of these data provided an initial screening tool for prioritization of watersheds in the western U.S. A different approach to the scope of the abandoned mine problem (Church et al., 1996a) is shown by the water quality data collected by the States under the Clean Water Act, section 305(b). These data document the stream reaches affected by metals from naturally occurring sources as well as from mining, or mineral resource extraction. Permitted discharges from active industrial and mine sites are not covered in the 305(b) data base. Local citizens and state and federal agencies are all part of the collaborative decision process used to select the drainage basins chosen for the AML Initiative pilot studies. Data gathered by these three entities were brought to bear on the watershed selection process. The USGS prepared data available from Federal data bases in the form of interpretative GIS products. Maps of the states of Colorado (Plumlee et al., 1995) and a similar study of the state of Montana ( USGS , unpublished data) were used to select the Animas watershed in southwestern Colorado and the Boulder watershed southwest of Helena Montana as the pilot study areas for the AML Initiative. Thus, the watersheds selected for study were public decisions made on the basis of available scientific data. The role of the U.S. Geological Survey in the Abandoned Mine Land Initiative is outlined in Buxton et al. (1997). The watershed approach to metals contamination in the environment has been studied in several drainage basins (Church et al., 1993, 1994, 1995, 1996b; Kimball et al., 1995). The underlying principles used to successfully discriminate between sources and to quantify the impact of these sources on the environment are the subject of this report.

Conference Paper↗

Interactions between fire and invasive plants in temperate grasslands of North America

A substantial number of invasive grasses, forbs and woody plants have invaded temperate grasslands in North America. Among the invading species are winter annuals, biennials, cool-season perennials, warm-season perennials, vines, shrubs, and trees. Many of these species have been deliberately introduced and widely planted; some are still used for range improvement, pastures, lawns, and as ornamentals, though many are listed as state or federal noxious weeds. Others have been greatly facilitated by widespread land disturbance. Historically, fire has been a major selective force in the evolution of temperate grasslands. Further, prescribed fire is commonly used as a method of ecological management for native grassland communities as well as in conjunction with restoration efforts. Within this context, it is important to understand how invasive species will interact with natural and prescribed fire regimes. In this paper, we consider what is known about how exotic species that invade temperate grasslands relate to fire. The primary issues addressed for each species are (1) Does fire appear to enhance colonization? (2) To what degree does fire affect the survival of plants? (3) Are plants that are burned able to regrow following fire and, if so, how rapidly can they recover? (4) How important is competition with native species to the response to fire? and (5) What effect does an invasive species have on the characteristics of the fire regime? For many species, results are preliminary, incomplete, or inconsistent among studies. For this reason, many of the conclusions drawn for individual species must be considered preliminary. Based on analyses of individual species, a conceptual framework is presented for considering how invasive plants may interact with fire when they invade an ecosystem. The major categories of influences are the native community, the fire regime, growth conditions for both invasive and native species, and influences that disturbances, human impacts, and landscape characteristics have had in the past and will have in the future. The examples considered in this paper provide support for a few, tentative generalizations. First, among our current worst invaders of temperate grasslands, adaptation to fire is quite variable. Some species are not well adapted to burning and can be easily eliminated; other species are better adapted but can still be eliminated if fire occurs during periods of particular vulnerability and/or at high frequency. There is a set of species that is extremely well adapted to fire and will not be eliminated through burning alone. Second, competitive interactions with native species play a crucial role in the success of nonnative invaders. In cases where differential burn responses between invasive and native species can be exploited, and adequate populations of native dominant species are present, fire can sometimes tip the competitive balance away from invasives. Third, there are a few invasive species that have exceptional attributes and for which there are no easy solutions. The ability of cheatgrass ( Bromus tectorum ) to enhance fire, the ability of Chinese tallow ( Triadica sebifera ) to suppress fire, and the ability of leafy spurge ( Euphorbia esula ) to resprout from repeated injury make these species exceptional threats to native diversity. Finally, the available information for many invasive species is very incomplete, partic- ularly with regard to how fire affects competitive interactions with the native community. There is much more we need to know if we are to consistently predict how invasive species will respond to fire and how burning can best be used to manage for natural diversity.

Conference Paper↗

Bison conservation initiative: Bison conservation genetics workshop: Report and recommendations

One of the first outcomes of the Department of the Interior (DOI) Bison Conservation Initiative was the Bison Conservation Genetics Workshop held in Nebraska in September 2008. The workshop brought together scientists from government agencies and non-governmental organizations with professional population geneticists to develop guidance for the genetic management of the federal bison herds. The scientists agreed on the basic tenets of genetic management for the DOI herds and discussed different approaches to meeting those goals. First, the 12 DOI herds are an irreplaceable resource for the long-term conservation of North American plains bison. Most of the herds show low levels of cattle introgression dating from the time when they were saved from extirpation; those herds should not be mixed without careful consideration as to their origin. Herds that show no evidence of cattle ancestry by the current molecular methods are the highest priority for protection from genetic mixing with any other bison herds. Second, despite the fact that most of the herds now managed by the U.S. government were founded with very few bison and have been maintained for many generations at relatively low population sizes, they do not show obvious effects of inbreeding. They have retained significant amounts of genetic variation by the standard measures, heterozygosity and allelic diversity. This may be explained in part by the fact that most of these herds are not remnants of a single population. Third, to preserve genetic variation in federal bison herds over decades and centuries, herds should be managed at a population or metapopulation level of 1,000 animals or more, with a sex ratio that enables competition between breeding bulls. The parks and refuges that currently have bison herds, with the exception of Yellowstone National Park, do not have enough land to support a population of this size. In the short term, it will be important to develop satellite herds to attain population targets, and develop a metapopulation structure between herds. Fourth and finally, the current methods used to evaluate the DOI bison herds, using mitochondrial DNA and a suite of nuclear DNA microsatellites, are highly informative at the herd level. They have confirmed relatedness of herds that we know from historical records have a common origin. They have detected cattle ancestry in most of the herds where it was suspected and have shown some loss of rare alleles. However, they do not sample across the bison genome, and the use of neutral genetic markers as the basis for selection of individual bison—either to breed or move to other herds—would be better supported by more high-resolution molecular methods currently under development.

Natural Resource Report↗

Sources of terrestrially-derived organic carbon in lower Mississippi River and Louisiana shelf sediments: Implications for differential sedimentation and transport at the coastal margin

In this study, we examined the temporal and spatial variability of terrestrial organic carbon sources in lower Mississippi River and Louisiana shelf sediments (during 11 cruises over a 22-month period) to further understand the sorting dynamics and selective transport of vascular plant materials within the primary dispersal system of the river. Bulk ??13C values in lower river sediments ranged from -21.90??? to -24.64??? (mean=-23.20??1.09???), these values were generally more depleted than those found in shelf sediments (-22.5??? to -21.2???). The ??8 (??8 = sum of vanillyl, syringyl and cinnamyl phenols produced from the oxidation of 100 mg of organic carbon) values in the lower river ranged from 0.71 to 3.74 (mean = 1.78??0.23). While there was no significant relationship between ??8 and river discharge (p>0.05), the highest value occurred during peak discharge in April 1999-which corresponded to the highest observed C/N value of 17.41. The ??8 values on the shelf ranged from 0.68 to 1.36 (mean = 0.54??0.30) and were significantly lower (p <0.05) than the average value for lower river sediments. The range of S/V (syringyl/vanillyl) and C/V (cinnamyl/vanillyl) ratios on the shelf, 0.11 to 0.95 and 0.01 to 0.08, respectively, were similar to that found in the lower river. These low C/V ratios are indicative a mixture of woody and non-woody carbon sources. Recent work by Goni et al. [Nature 389 (1997) 275; Geochim. Cosmochim. Acta 62 (1998) 3055], which did not include sampling transects within the primary dispersal system of the Mississippi River, showed a non-woody vascular plant signature on the Louisiana shelf. This suggests that riverine-derived woody tissues preferentially settle out of the water column, in the lower river and inner shelf, prior to the selective dispersal of C3 versus C4 non-woody materials in other regions the shelf and slope. This works further demonstrates the importance of differential settlement of particles, sampling location within the dispersal system, and river discharge, when examining biogeochemical cycles in river-dominated margins. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Chemistry↗

Characterizing mauka-to-makai connections for aquatic ecosystem conservation on Maui, Hawaiʻi

Mauka-to-makai (mountain to sea in the Hawaiian language) hydrologic connectivity – commonly referred to as ridge-to-reef – directly affects biogeochemical processes and socioecological functions across terrestrial, freshwater, and marine systems. The supply of freshwater to estuarine and nearshore environments in a ridge-to-reef system supports the food, water, and habitats utilized by marine fauna . In addition, the ecosystem services derived from this land-to-sea connectivity support social and cultural practices (hereafter referred to as socio-cultural) including fishing, aquaculture, wetland agriculture, religious ceremonies, and recreational activities. To effectively guide island resource management, a better understanding of the linkages from ridge-to-reef across natural and social usages is critical, particularly in the context of climate change, with anticipated increasing temperature and shifting precipitation patterns. The objective of this study was to identify spatial linkages that promote multiple and diverse uses, following the ridge-to-reef concept, at an island-wide scale to identify regions of high conservation importance for aquatic resources. We selected the Island of Maui as a study representative of many Pacific islands. Diverse datasets, including agricultural lands within watersheds, wetland locations, presence of stream species, indicators of freshwater input from streams, coral cover, nearshore fish biomass, socio-cultural data such as fishpond locations, wetland taro cultivation, beach recreation use, and lastly the dynamically downscaled Coupled Model Intercomparison Project Phase (CMIP5) future climate projections scenarios (Representative Concentration Pathway (RCP) 4.5 & 8.5) were used to examine the spatial linkages through hydrological connectivity from land to the sea. Zonation spatial planning software was used to prioritize areas of high management and conservation value and to help inform aquatic resources management. The resulting prioritized areas included many minimally disturbed watersheds in east Maui and western nearshore and coastal zones that are adjacent to diverse coral reefs. These results are driven by the importance of fish biomass and coral reef distribution as well as traditional wetland taro cultivation and coastal access points for recreation. These results underline the importance of examining ridge-to-reef systems for aquatic resource management and including important social and cultural values in resource management upon planning adaptation strategies for climate change. Improving our understanding of diverse natural and socio-cultural influences on habitat conditions and their values in these areas provides an opportunity to strategically plan future management and conservation actions.

Hawaii↗

Selected Geochemical Data for Modeling Near-Surface Processes in Mineral Systems

The database herein was initiated, designed, and populated to collect and integrate geochemical, geologic, and mineral deposit data in an organized manner to facilitate geoenvironmental mineral deposit modeling. The Microsoft Access database contains data on a variety of mineral deposit types that have variable environmental effects when exposed at the ground surface by mining or natural processes. The data tables describe quantitative and qualitative geochemical analyses determined by 134 analytical laboratory and field methods for over 11,000 heavy-mineral concentrate, rock, sediment, soil, vegetation, and water samples. The database also provides geographic information on geology, climate, ecoregion, and site contamination levels for over 3,000 field sites in North America.

Data Series↗

Spatial and temporal variability of trace element concentrations in an urban subtropical watershed, Honolulu, Hawaii

Trace metal concentrations in soils and in stream and estuarine sediments from a subtropical urban watershed in Hawaii are presented. The results are placed in the context of historical studies of environmental quality (water, soils, and sediment) in Hawaii to elucidate sources of trace elements and the processes responsible for their distribution. This work builds on earlier studies on sediments of Ala Wai Canal of urban Honolulu by examining spatial and temporal variations in the trace elements throughout the watershed. Natural processes and anthropogenic activity in urban Honolulu contribute to spatial and temporal variations of trace element concentrations throughout the watershed. Enrichment of trace elements in watershed soils result, in some cases, from contributions attributed to the weathering of volcanic rocks, as well as to a more variable anthropogenic input that reflects changes in land use in Honolulu. Varying concentrations of As, Cd, Cu, Pb and Zn in sediments reflect about 60 a of anthropogenic activity in Honolulu. Land use has a strong impact on the spatial distribution and abundance of selected trace elements in soils and stream sediments. As noted in continental US settings, the phasing out of Pb-alkyl fuel additives has decreased Pb inputs to recently deposited estuarine sediments. Yet, a substantial historical anthropogenic Pb inventory remains in soils of the watershed and erosion of surface soils continues to contribute to its enrichment in estuarine sediments. Concentrations of other elements (e.g., Cu, Zn, Cd), however, have not decreased with time, suggesting continued active inputs. Concentrations of Ba, Co, Cr, Ni, V and U, although elevated in some cases, typically reflect greater proportions attributed to natural sources rather than anthropogenic input. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗

Seabed mapping and characterization of sediment variability using the usSEABED data base

We present a methodology for statistical analysis of randomly located marine sediment point data, and apply it to the US continental shelf portions of usSEABED mean grain size records. The usSEABED database, like many modern, large environmental datasets, is heterogeneous and interdisciplinary. We statistically test the database as a source of mean grain size data, and from it provide a first examination of regional seafloor sediment variability across the entire US continental shelf. Data derived from laboratory analyses ("extracted") and from word-based descriptions ("parsed") are treated separately, and they are compared statistically and deterministically. Data records are selected for spatial analysis by their location within sample regions: polygonal areas defined in ArcGIS chosen by geography, water depth, and data sufficiency. We derive isotropic, binned semivariograms from the data, and invert these for estimates of noise variance, field variance, and decorrelation distance. The highly erratic nature of the semivariograms is a result both of the random locations of the data and of the high level of data uncertainty (noise). This decorrelates the data covariance matrix for the inversion, and largely prevents robust estimation of the fractal dimension. Our comparison of the extracted and parsed mean grain size data demonstrates important differences between the two. In particular, extracted measurements generally produce finer mean grain sizes, lower noise variance, and lower field variance than parsed values. Such relationships can be used to derive a regionally dependent conversion factor between the two. Our analysis of sample regions on the US continental shelf revealed considerable geographic variability in the estimated statistical parameters of field variance and decorrelation distance. Some regional relationships are evident, and overall there is a tendency for field variance to be higher where the average mean grain size is finer grained. Surprisingly, parsed and extracted noise magnitudes correlate with each other, which may indicate that some portion of the data variability that we identify as "noise" is caused by real grain size variability at very short scales. Our analyses demonstrate that by applying a bias-correction proxy, usSEABED data can be used to generate reliable interpolated maps of regional mean grain size and sediment character.

Continental Shelf Research↗

Migratory salmonid redd habitat characteristics in the Salmon River, New York

Non-native migratory salmonids ascend tributaries to spawn in all the Great Lakes. In Lake Ontario, these species include Chinook salmon ( Oncorhynchus tshawytscha ), coho salmon ( O. kisutch ), steelhead ( O. mykiss ), and brown trout ( Salmo trutta ). Although successful natural reproduction has been documented for many of these species, little research has been conducted on their spawning habitat. We examined the spawning habitat of these four species in the Salmon River, New York. Differences in fish size among the species were significantly correlated with spawning site selection. In the Salmon River, the larger species spawned in deeper areas with larger size substrate and made the largest redds. Discriminant function analysis correctly classified redds by species 64–100% of the time. The size of substrate materials below Lighthouse Hill Dam is within the preferred ranges for spawning for these four species indicating that river armoring has not negatively impacted salmonid production. Intra-specific and inter-specific competition for spawning sites may influence redd site selection for smaller salmonids and could be an impediment for Atlantic salmon ( S. salar ) restoration.

New York↗

Windows of opportunity: white-tailed deer and the dynamics of northern hardwood forests of the northeastern US

Herbivory, lighting regimes, and site conditions are among the most important determinants of forest regeneration success, but these are affected by a host of other factors such as weather, predation, human exploitation, pathogens, wind and fire. We draw together > 50 years of research on the Huntington Wildlife Forest in the central Adirondack Mountains of New York to explore regeneration of northern hardwoods. A series of studies each of which focused on a single factor failed to identify the cause of regeneration failure. However, integration of these studies led to broader understanding of the process of forest stand development and identified at least three interacting factors: lighting regime, competing vegetation and selective browsing by white-tailed deer (Odocoileus virginianus). The diverse 100-200 year-old hardwood stands present today probably reflect regeneration during periods of low deer density (< 2.0 deer/km super(2)) and significant forest disturbance. If this hypothesis is correct, forest managers can mimic these 'natural windows of opportunity' through manipulation of a few sensitive variables in the system. Further, these manipulations can be conducted on a relatively small geographic scale. Control of deer densities on a scale of 500 ha and understory American beech (Fagus grandifolia) on a scale of < 100 ha in conjunction with an even-aged regeneration system consistently resulted in successful establishment of desirable hardwood regeneration.

Journal for Nature Conservation↗