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Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Macroseismology

In this chapter I discuss the use of so-called macroseismic data, i.e., reports of damage and other effects of shaking on humans and the built environment, to improve the characterization of earthquakes and the ground motions they produce. Macroseismic data are critical not only to investigate earthquakes that occurred before the start of the instrumental era in seismology, but are also, by virtue of the spatially rich nature of the data, of tremendous potential importance to investigate early instrumental and even recent earthquakes. Fueled by both the advent of on-line systems that now produce unprecedented volumes of macroseismic intensity data and by recognition of the importance of understanding key historical earthquakes, there has been a growing appreciation for the value of macroseismic data. It is, however, critical to understand both the unique challenges and the unique opportunities associated with these data. I review the evolution of thought and practices regarding analysis of macroseismic data, and the use of such data to improve the characterization of historic and early instrumental earthquakes.

Book chapter

Mesoproterozoic to Paleozoic tectonics, Pleistocene landforms, and Holocene seismicity in the Blue Ridge: Results from integrated studies of the 9 August 2020, Mw 5.1 earthquake area near Sparta, North Carolina, USA

This field trip examines the results of integrated geologic studies of the 9 August 2020, M w 5.1 earthquake near Sparta, North Carolina, USA. The earthquake generated ~4 km of coseismic surface rupture of the Little River fault and uplifted a surface area of ~11 km 2 . The Little River fault is a thrust fault oriented 110–130°/45–70°SW, and mapped fault segments are en echelon with scarp heights from <5–30 cm. The epicenter is in polydeformed rocks of the Ashe and Alligator Back Metamorphic Suites in the eastern Blue Ridge. Bedrock structure formed during multiple Paleozoic orogenies; the regional foliation strikes NE-SW and dips SE (mean orientation 063°/52°SE). Mapping identified late Paleozoic veins and shear zones, a regional joint set striking 330–340° and 250–240°, and brittle faults that cut the Paleozoic foliation. Brittle faults oriented similar to the Little River fault are mapped up to 4 km along strike from the coseismic rupture along Bledsoe Creek valley, and the combined length of the Little River fault system is ~8 km. Paleoseismic trenches across the Little River fault corroborate the reactivation of an older fault by the 2020 earthquake and reveal two events during late Pleistocene (<50 ka). Surficial mapping identified several terrace deposits, including a deposit along Bledsoe Creek that yielded a 26 Al/ 10 Be isochron burial age of 0.46 ± 0.13 Ma and overlies a brittle fault, thus constraining the timing of movement of the fault at that location. Paleoliquefaction studies document soft-sediment deformation features in alluvium that may represent paleoseismic events. Collectively, these results highlight long-lived paleoseismicity of the Blue Ridge and that the 9 August 2020 earthquake reactivated an older, suitably oriented brittle fault in the bedrock. The Little River fault is an example of a previously unknown but active fault lying outside of known seismic zones with demonstrated recurrence of paleo-ruptures, raising questions about the assumption that damaging earthquakes are limited to areas of ongoing background seismicity, which is counter to seismic hazard assessments in the eastern United States. Bedrock mapping separates eastern Blue Ridge lithostratigraphy of the Lynchburg Group and Ashe and Alligator Back Metamorphic Suites into separate fault-bound packages juxtaposed over various 1.3–1.0 Ga basement rocks of the northern French Broad massif by the Gossan Lead fault.

North Carolina

Three-dimensional hydrogeologic framework model of the Russian River watershed, California

The Russian River watershed is in northern Sonoma County and southern Mendocino County, California, in the northern part of the California Coast Ranges. The Russian River serves as a supply for agricultural irrigation and for municipal, domestic, and commercial uses. Through a cooperative agreement with the California State Water Resources Control Board and Sonoma County Water Agency, the U.S. Geological Survey has completed studies to better understand the hydrogeologic system and develop numerical hydrologic modeling tools to evaluate and aid in managing groundwater resources. This report focuses on the development of a digital three-dimensional hydrogeologic framework model of the Russian River watershed for use in groundwater resource assessment and numerical models. The digital three-dimensional hydrogeologic framework model of the Russian River watershed portrays the altitude, thickness, and extent of five hydrogeologic units. These five hydrogeologic units include (1) a basement unit, (2) the Sonoma Volcanics, (3) a consolidated sedimentary rock unit, (4) an unconsolidated sediment unit, and (5) channel alluvium. Model input data were compiled from published geologic maps, interpreted well data, and a model of the top of basement derived from gravity data. These data were used to construct surfaces that represent the upper and lower subsurface boundaries of each hydrogeologic unit. Top surfaces were created for the five hydrogeologic units and then stacked in three dimensions to create a solid-volume digital model. The digital three-dimensional hydrogeologic framework model described in this report and the corresponding data represent the generalized geometry of the subsurface geologic units; the model reproduces the input geologic data with reasonable accuracy and is consistent with previously published subsurface conceptualizations of the region. The model indicates the overall geometry of the basement within the watershed and the spatial extent, altitude, and thickness of the basin-filling units. The hydrogeologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

California

Characterization of change in tree cover state and condition over the conterminous United States

Variability in the effects of disturbances and extreme climate events can lead to changes in tree cover over time, including partial or complete loss, with diverse ecological consequences. It is therefore critical to identify in space and time the change processes that lead to tree cover change. Studies of change are often hampered by the lack of data capable of consistently detecting different types of change. Using the Landsat satellite record to create a long time-series of land cover and land cover change, the U.S. Geological Survey Land Change Monitoring Assessment and Projection (LCMAP) project has made an annual time series of land cover across the conterminous United States for the period 1985 to 2018. Multiple LCMAP products analyzed together with map validation reference plots provide a robust basis for understanding tree cover change. In LCMAP (Collection 1.2), annual change detection is based on harmonic model breaks calculated at each Landsat pixel from the Continuous Change Detection and Classification (CCDC) algorithm. The results showed that the majority of CCDC harmonic model breaks (signifying change) indicated partial tree cover loss (associated with management practices such as tree cover thinning) as compared to complete tree cover loss (associated with practices like clearcut harvest or fire disturbance). Substantially fewer occurrences of complete tree cover loss were associated with change in land cover state. The area of annual tree cover change increased after the late 1990s and stayed high for the rest of the study period. The reference data showed that tree harvest dominated across the conterminous United States. The majority of tree cover change occurred in evergreen forests. Large estimates of disturbance-related tree cover change indicated that tree cover loss may have previously been underreported due to omission of partial tree cover loss in prior studies. This has considerable implications for forest carbon accounting along with tracking ecosystem goods and services.

Forests

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California

Comparisons of shoreline positions from satellite-derived and traditional field- and remote-sensing techniques

Satellite-derived shorelines (SDS) have the potential to help researchers answer critical coastal science questions and support work to predict coastal change by filling in the spatial and temporal gaps present in current field-based and remote-sensing data collection methods. The U.S. Geological Survey conducted comparison analyses of traditionally sourced shorelines and SDS in diverse coastal landscapes to determine how SDS could be used in ongoing and future work across varied coastal environments and provided some initial findings that could be used for implementation. Using CoastSeg, a browser-based program for SDS detection and mapping, SDS for the period 1984–2023 for multiple locations across the United States were compared to shoreline positions from traditionally sourced shoreline data. In this report, the authors present these comparisons alongside lessons learned and challenges encountered when building SDS workflows in different coastal locations. Results show that individual SDS have larger uncertainty and yet produced similar linear trends to sparser, traditionally sourced shoreline data; because SDS methods provide orders of magnitude more data than traditional shoreline-detection methods, they can be used to evaluate shoreline behaviors. Refining average scalar slopes used in tidal corrections did not result in substantial decreases in uncertainty. Using lessons from this work to outline needs for regional implementation, initial setup time would be considerable, being on the order of weeks. However, once complete, shoreline detections and analyses are fast (on the order of minutes to hours) and achievable using a desktop computer.

Alaska, Florida, Massachusetts, Washington

Earthquake effects surveyed during the nineteenth century as ecological features of Chinookan tidelands

Lasting effects of a Cascadia earthquake in 1700 were documented during surveys of Chinookan tidelands near the mouth of the Columbia River between 1805 and 1868. The effects resemble estuarine consequences, near Anchorage, of the 1964 Alaska earthquake: fatal drowning of subsided meadows and forests by post-earthquake tides, rebirth of marshes and forests through post-earthquake sedimentation, and uplift. Chinookan remains of killed forests were recorded by James Graham Cooper, John J. Lowell, and Cleveland Rockwell. Cooper, attached to a railroad survey and the Smithsonian Institution, wrote of redcedar stumps and trunks standing dead in tidal marshes of Shoalwater (now Willapa) Bay. Two such snags served as bearing trees for Lowell as he platted a Shoalwater Bay township under contract with the General Land Office. Rockwell, of the US Coast Survey, flecked landward edges of tidal flats west of Astoria with symbols that evoke remains of a bygone spruce forest. The Lewis and Clark Expedition, while in that area in 1805–1806, mapped and puzzled over tideland vegetation that post-1700 succession helps explain.

Alaska, British Columbia, California, Oregon, Wash

Utilizing hydrophones to detect streambed mobilization in the Wild and Scenic reach of the Rio Chama

This paper describes a study that deployed underwater acoustic sensors (hydrophones) to detect streambed mobilization in the Wild and Scenic reach of the Rio Chama, New Mexico. Fine sediment accumulation in the gravel‑cobble bed affects brown trout spawning habitat, and understanding incipient motion thresholds is essential for planning effective environmental flushing flows released from El Vado Dam. Two hydrophone stations were operated during 2021–2022, capturing audio data during a high‑flow pulse in late 2021. Acoustic processing techniques, including spectral analysis and threshold‑based impact detection, were used to identify sediment‑generated noise associated with coarse sediment transport. Results indicate detectable sediment mobilization during the high‑flow pulse, demonstrating hydrophones’ potential as a passive monitoring tool for environmental flow planning and sediment‑management decision support.

Conference Paper

Hydraulic properties of the Madison aquifer system in the western Rapid City area, South Dakota

Available information on hydrogeology, data from borehole geophysical logs, and aquifer tests were used to determine the hydraulic properties of the Madison aquifer. From aquifer-test analysis, transmissivity and storage coefficient were determined for the Minnelusa and Madison aquifers, and vertical hydraulic conductivity (K v ') along with specific storage (Ss') for the Minnelusa confining bed. Borehole geophysical well logs were used to determine the thickness and location of the Minnelusa aquifer, the lower Minnelusa confining bed, and the Madison aquifer within the Madison Limestone. Porosity values determined from quantitative analysis of borehole geophysical well logs were used in analyzing the aquifer-test data. The average porosity at the two aquifer-test sites is about 10 percent in the Minnelusa aquifer, 5 percent in the lower Minnelusa confining bed, and 35 percent in the Madison aquifer. The first aquifer test, which was conducted at Rapid City production well #6, produced measured drawdown in the Minnelusa and Madison aquifers. Neuman and Witherspoon's method of determining the hydraulic properties of leaky two-aquifer systems was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. Analysis of the aquifer test for the Minnelusa aquifer yielded a transmissivity value of 12,000 feet squared per day and a storage coefficient of 3 x 10 -3 . The specific storage of the Minnelusa confining bed was 2 x 10 -7 per foot, and its vertical hydraulic conductivity was 0.3 foot per day. The transmissivity of the Madison aquifer at this site was 17,000 feet squared per day, and the storage coefficient was 2 x 10 -3 . The second aquifer test, which was conducted at Rapid City production well #5 (RC-5) produced measured drawdown only in the Madison aquifer. Hantush and Jacob's method of determining the hydraulic properties of leaky confined aquifers with no storage in the confining bed was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. The analysis of data from the RC-5 aquifer test showed that transmissivity was not equal in all directions. Hantush's method was used to determine the direction of radial anisotropy and magnitude of the major and minor axes of transmissivity. The major axis of transmissivity is at an angle of 42° east of north, and the transmissivity along this axis is about 56,000 feet squared per day. The minor axis of transmissivity is at an angle of 48° west of north, and the transmissivity along this axis is about 1,300 feet squared per day. The major axis of transmissivity intersects Cleghorn Springs, a large resurgent spring on the west edge of Rapid City. The shape of the potentiometric contours of the Madison aquifer near RC-5 agree with the orientation of the transmissivity ellipse. The average value of the storage coefficient from the isotropic analysis of the aquifer-test data was 3.5 x 10 -4 , and the average vertical hydraulic conductivity of the lower Minnelusa confining bed was 9.6 x 10 -3 foot per day.

South Dakota

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri

Transmissivity and water quality of water-producing zones in the intermediate aquifer system, Sarasota County, Florida

The intermediate aquifer system is an important water source in Sarasota County, Florida, because the quality of water in it is usually better than that in the underlying Upper Floridan aquifer. The intermediate aquifer system consists of a group of up to three water-producing zones separated by less-permeable units that restrict the vertical movement of ground water between zones. The diverse lithology, that makes up the intermediate aquifer system, reflects the variety of depositional environments that occurred during the late Oligocene and Miocene epochs. Slight changes in the depositional environment resulted in aquifer heterogeneity, creating both localized connection between water-producing zones and abrupt culmination of water-producing zones that are not well documented. Aquifer heterogeneity results in vertical and areal variability in hydraulic and water-quality properties. The uppermost water-producing zone is designated producing zone 1 but is not extensively used because of its limited production capability and limited areal extent. The second water-producing zone is designated producing zone 2, and most of the domestic- and irrigation-supply wells in the area are open to this zone. Additionally, producing zone 2 is utilized for public supply in southern coastal areas of Sarasota County. Producing zone 3 is the lowermost and most productive water-producing zone in the intermediate aquifer system. Public-supply well fields serving the cities of Sarasota and Venice, as well as the Plantation and Mabry Carlton Reserve well fields, utilize producing zone 3. Heads within the intermediate aquifer system generally increase with aquifer depth. However, localized head-gradient reversals occur in the study area, coinciding with sites of intense ground-water withdrawals. Heads in producing zones 1, 2, and 3 range from 1 to 23, 0.2 to 34, and 7 to 42 feet above sea level, respectively. Generally, an upward head gradient exists between producing zones 3 and 2. However, an upward head gradient between producing zones 2 and 1 does not consistently occur throughout Sarasota County, probably the result of greater ground-water withdrawals from producing zone 2 than from producing zone 1. The transmissivity of the intermediate aquifer system is spatially variable. Specific-capacity data from selected wells penetrating producing zones 2 and 3, were used to estimate transmissivity. Estimated transmissivity values for producing zones 2 and 3 range from about 100 to 26,000 feet squared per day and from about 1,300 to 6,200 feet squared per day, respectively. Because the capacity of specific water-producing zones is highly variable from site to site, estimating the performance of a specific water-producing zone as a water resource is difficult. Water samples collected during the study were analyzed for major-ion concentrations. Generally, bicarbonate type water from rock interaction occurs in northern Sarasota County; enriched calcium-magnesium-sulfate type water from deeper aquifers occurs in central Sarasota County; and sodium-chloride type water from saltwater mixing occurs in southern Sarasota County. In some areas of northern Sarasota County, the major-ion concentrations in water are lower in producing zone 2 than in producing zone 1. Major-ion concentrations in water are higher in producing zone 3 throughout the study area. A major objective of the study was to evaluate hydraulic and water-quality data to determine distinctions that could be used to characterize a particular producing zone. However, data indicate that both hydraulic and water-quality properties are highly variable within and between zones, and are more related to the degree of connection between and areal extent of water-producing zones than to aquifer depth and distance from the coast.

Florida

Water-quality conditions and relation to drainage-basin characteristics in the Scituate Reservoir Basin, Rhode Island, 1982-95

The Scituate Reservoir Basin covers about 94 square miles in north central Rhode Island and supplies more than 60 percent of the State of Rhode Island's drinking water. The basin includes the Scituate Reservoir Basin and six smaller tributary reservoirs with a combined capacity of about 40 billion gallons. Most of the basin is forested and undeveloped. However, because of its proximity to the Providence, Rhode Island, metropolitan area, the basin is subject to increasing development pressure and there is concern that this may lead to the degradation of the water supply. Selected water-quality constituent concentrations, loads, and trends in the Scituate Reservoir Basin, Rhode Island, were investigated locate parts of the basin likely responsible for exporting disproportionately large amounts of water-quality constituents to streams, rivers, and tributary reservoirs, and to determine whether water quality in the basin has been changing with time. Water-quality data collected between 1982 and 1995 by the Providence Water Supply Board PWSB) in 34 subbasins of the Scituate Reservoir Basin were analyzed. Subbasin loads and yields of total coliform bacteria, chloride, nitrate, iron, and manganese, estimated from constituent concentrations and estimated mean daily discharge records for the 1995 water year, were used to determine which subbasins contributed disproportionately large amounts of these constituents. Measurements of pH, color, turbidity, and concentrations of total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese made between 1982 and 1995 by the PWSB were evaluated for trends. To determine the potential effects of human-induced changes in drainage- basin characteristics on water quality in the basin, relations between drainage-basin characteristics and concentrations of selected water-quality constituents also were investigated. Median values for pH, turbidity, total coliform bacteria, sodium, alkalinity, chloride, nitrate, and iron were largest in subbasins with predominately residential land use. Median instantaneous loads reflected drainage-basin size. However, loads normalized by drainage area (median instantaneous yields) also were largest in residential areas where point and non-point sources are likely, and in areas of poorly drained soils. Significant trends in water-quality constituents from 1982 to 1995 in the Scituate Reservoir Basin indicate that the quality of the water resources in the basin may be slowly changing. Scituate Reservoir subbasins with large amounts of residential land use showed increasing trends in alkalinity and chloride. In contrast, subbasins distributed throughout the drainage basin showed increasing trends in pH, color, nitrate, and iron concentrations, indicating that these characteristics and constituents may be affected more by atmospheric deposition. Although changing, water-quality constituent concentrations in the Scituate Reservoir Basin only occasionally exceeded Rhode Island and USEPA water-quality guidelines and standards. Result of correlation analysis between pH, color, turbidity, and concentrations total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese and land use, geology, wetlands, slope, soil drainability, and roads indicated that the percentage of wetlands, roads, and slope appear have the greatest effect on water-quality in the Scituate Reservoir Basin. The percentage of urban, residential, and commercial land use also are important, but to a lesser degree than wetlands, roads, and slope. Finally, geology appears to have the least effect on water quality compared to other drainage-basin characteristics investigated.

Rhode Island

Flood-inundation maps of the Blue River and major tributaries in and near Kansas City, Missouri, 2023–25

Digital flood-inundation maps for 35.5 miles of the Blue River, in and near Kansas City, Missouri, were created by the U.S. Geological Survey (USGS) in cooperation with the City of Kansas City. Maps were also developed for a combined 7.3 miles of Brush Creek (4.4 miles) and Indian Creek (2.9 miles), two primary tributaries to the Blue River in the study reach. The flood-inundation maps, available through the USGS Flood Inundation Mapping Program website at https://water.usgs.gov/osw/flood_inundation/ , depict estimates of the areal extent and depth of flooding, depth of water above first-floor elevations in selected buildings, water velocity, water-surface elevations, and time of travel corresponding to selected water levels or gage heights (hereafter referred to as “stages”) at nine reference USGS streamgages—five on the Blue River (USGS station numbers 06893590, 06893578, 06893500, 06893150, and 06893100), two on Brush Creek (USGS station numbers 06893562 and 06893557), one on Indian Creek (USGS station number 06893390), and one on the Missouri River (USGS station number 06893000). Near-real-time stages at these streamgages may be obtained from USGS Water Data for the Nation at https://doi.org/10.5066/F7P55KJN or the National Weather Service National Water Prediction Service at http://water.noaa.gov/ , which also forecasts flood hydrographs at seven of these sites (USGS station numbers 06893000, 06893590, 06893578, 06893500, 06893150, 06893557, and 06893390). Flood profiles were computed for eight map reaches by means of two-dimensional hydraulic models. The models were calibrated using the USGS-developed stage–streamflow relations at each reference streamgage. Two map reaches on the lower Blue River also include the effects of backwater from the Missouri River on flood inundation extent and hydraulic characteristics. The hydraulic models were used to compute water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datums. The profile stages ranged from the National Weather Service “Action Stage” or near bankfull to a stage exceeding the highest recorded water level at each streamgage. The simulated water-surface profiles were then combined with a digital elevation model (derived from light detection and ranging data having a nonvegetated vertical accuracy of a maximum 10-centimeter root-mean-square error) to delineate the area flooded at each water level and the associated hydraulic characteristics. The availability of these maps, along with information regarding current stage from the USGS streamgage and forecasted high-flow stages from the National Weather Service, will provide emergency management personnel, resource managers, and residents with information that could be critical for flood-response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Kansas, Missouri

A multidisciplinary approach that considers occurrence, geochemistry, bioavailability, and toxicity to prioritize critical minerals for environmental research

Critical minerals (or critical elements) are minerals or elements that are essential to global security and development and have supply chains vulnerable to disruption. In general, knowledge of the environmental behavior and health effects of critical elements is needed to support the development of safe and environmentally responsible supplies. This knowledge includes identifying potential consequences of increased critical element production and use, alternative critical element sources such as mine wastes, and adverse effects of critical elements on ecosystem condition and organismal health. Here we identify significant data gaps in the understanding of critical elements in surficial and aquatic environments, and the need, given the large number of commodities (50) identified on the 2022 critical minerals list for the United States, for an approach to prioritize them for study of their environmental fate and effects. We propose a multidisciplinary approach for this prioritization, considering measures of occurrence, geochemistry, bioavailability, and toxicity. We describe relatively easy-to-obtain metrics for each of these topic areas and demonstrate the utility of this integrated prioritization approach using indium and zinc as examples. This approach facilitates prioritizing research with a focus on those critical elements that are most mobile in the environment, bioavailable, toxic, or simply lacking data in these categories.

Environmental Science & Technology

Revisiting an enigma on California's north coast: The Mw6.5 Fickle Hill earthquake of 21 December 1954

Many earthquakes occur along the North Coast of California in the vicinity of the Mendocino Triple Junction (MTJ), where the Pacific, Gorda, and North American (NA) plates meet, and on the adjacent plate boundaries. The MTJ marks the nexus of the Mendocino and San Andreas faults with the Cascadia subduction zone (CSZ). Historically, most large earthquakes around the MTJ have been within the offshore Gorda plate and its subducted portion beneath the NA plate. North of the MTJ, active faults mapped in the NA plate are part of the CSZ fold‐and‐thrust belt. Although some events have been detected in the NA plate, no large historic events have been associated with mapped surface faults. The 21 December 1954 M w 6.5 earthquake in Humboldt County is one possible exception. Using published data from catalogs and articles, unpublished data from Berkeley’s archives, and S ‐ P times interpreted from two U.S. Coast and Geodetic Survey (USCGS) accelerometers, we determine a probability cloud for the earthquake’s hypocenter using NonLinLoc. The highest probability location lies beneath Fickle Hill just east of the city of Arcata, California, at 40.87° N, 124.03° W, and ∼11 km depth. Using P ‐wave polarities from Berkeley stations and the digitized waveforms from the accelerometers, we find that the focal mechanism most consistent with the data indicates thrust movement with strike, dip, and rake of 350°, 10°, and 90°, respectively, at a depth of 14 km. Given the depth uncertainties of both this event and the megathrust, this implies that the earthquake most likely took place on the subduction interface rather than on the mapped faults in the Mad River fault zone that trend 322° and dip to the northeast. The revisited intensity in the epicentral region also supports a location beneath Fickle Hill to the east of the city of Arcata, California.

California, Idaho, Nevada, Oregon, Washington