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Optical satellite data volcano monitoring: a multi-sensor rapid response system

In this chapter, the use of satellite remote sensing to monitor active geological processes is described. Specifically, threats posed by volcanic eruptions are briefly outlined, and essential monitoring requirements are discussed. As an application example, a collaborative, multi-agency operational volcano monitoring system in the north Pacific is highlighted with a focus on the 2007 eruption of Kliuchevskoi volcano, Russia. The data from this system have been used since 2004 to detect the onset of volcanic activity, support the emergency response to large eruptions, and assess the volcanic products produced following the eruption. The overall utility of such integrative assessments is also summarized. The work described in this chapter was originally funded through two National Aeronautics and Space Administration (NASA) Earth System Science research grants that focused on the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument. A skilled team of volcanologists, geologists, satellite tasking experts, satellite ground system experts, system engineers and software developers collaborated to accomplish the objectives. The first project, Automation of the ASTER Emergency Data Acquisition Protocol for Scientific Analysis, Disaster Monitoring, and Preparedness , established the original collaborative research and monitoring program between the University of Pittsburgh (UP), the Alaska Volcano Observatory (AVO), the NASA Land Processes Distributed Active Archive Center (LP DAAC) at the U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center, and affiliates on the ASTER Science Team at the Jet Propulsion Laboratory (JPL) as well as associates at the Earth Remote Sensing Data Analysis Center (ERSDAC) in Japan. This grant, completed in 2008, also allowed for detailed volcanic analyses and data validation during three separate summer field campaigns to Kamchatka Russia. The second project, Expansion and synergistic use of the ASTER Urgent Request Protocol (URP) for natural disaster monitoring and scientific analysis , has expanded the project to other volcanoes around the world and is in progress through 2011. The focus on ASTER data is due to the suitability of the sensor for natural disaster monitoring and the availability of data. The instrument has several unique facets that make it especially attractive for volcanic observations (Ramsey and Dehn, 2004). Specifically, ASTER routinely collects data at night, it has the ability to generate digital elevation models using stereo imaging, it can collect data in various gain states to minimize data saturation, it has a cross-track pointing capability for faster targeting, and it collects data up to ±85° latitude for better global coverage. As with any optical imaging-based remote sensing, the viewing conditions can negatively impact the data quality. This impact varies across the optical and thermal infrared wavelengths as well as being a function of the specific atmospheric window within a given wavelength region. Water vapor and cloud formation can obscure surface data in the visible and near infrared (VNIR)/shortwave infrared (SWIR) region due mainly to non-selective scattering of the incident photons. In the longer wavelengths of the thermal infrared (TIR), scattering is less of an issue, but heavy cloud cover can still obscure the ground due to atmospheric absorption. Thin clouds can be optically-transparent in the VNIR and TIR regions, but can cause errors in the extracted surface reflectance or derived surface temperatures. In regions prone to heavy cloud cover, optical remote sensing can be improved through increased temporal resolution. As more images are acquired in a given time period the chances of a clear image improve dramatically. The Advanced Very High Resolution Radiometer (AVHRR) routine monitoring, which commonly collects 4-6 images per day of any north Pacific volcano, takes advantage of this fact. The rapid response program described in this chapter also improves the temporal resolution of the ASTER instrument. ASTER has been acquiring images of volcanic eruptions since soon after its launch in December 1999. An early example included the observations of the large pyroclastic flow deposit emplaced at Bezymianny volcano in Kamchatka, Russia. The first images in March 2000, just weeks after the eruption, revealed the extent, composition, and cooling history of this large deposit and of the active lava dome (Ramsey and Dehn, 2004). The initial results from these early datasets spurred interest in using ASTER data for expanded volcano monitoring in the north Pacific. It also gave rise to the multi-year NASA-funded programs of rapid response scheduling and imaging throughout the Aleutian, Kamchatka and Kurile arcs. Since the formal establishment of the programs, the data have provided detailed descriptions of the eruptions of Augustine, Bezymianny, Kliuchevskoi and Sheveluch volcanoes over the past nine years (Wessels et al., in press; Carter et al., 2007, 2008; Ramsey et al., 2008; Rose and Ramsey, 2009). The initial research focus of this rapid response program was specifically on automating the ASTER sensor’s ability for targeted observational scheduling using the expedited data system. This urgent request protocol is one of the unique characteristics of ASTER. It provides a limited number of emergency observations, typically at a much-improved temporal resolution and quicker turnaround with data processing in the United States rather than in Japan. This can speed the reception of the processed data by several days to a week. The ongoing multi-agency research and operational collaboration has been highly successful. AVO serves as the primary source for status information on volcanic activity, working closely with the National Weather Service (NWS), Federal Aviation Administration (FAA), military and other state and federal emergency services. Collaboration with the Russian Institute of Volcanology and Seismology (IVS)/Kamchatka Volcanic Eruption Response Team (KVERT) is also maintained. Once a volcano is identified as having increased thermal output, ASTER is automatically tasked and the volcano is targeted at the next available opportunity. After the data are acquired, scientists at all the agencies have access to the images, with the primary science analysis carried out at the University of Pittsburgh and AVO. Results are disseminated to the responsible monitoring agencies and the global community through e-mail mailing lists.

Book chapter↗

Roles of climatic and anthropogenic factors in shaping Holocene vegetation and fire regimes in Great Dismal Swamp, eastern USA

The Great Dismal Swamp wetland, spanning >400 km 2 along the Virginia and North Carolina border, was shaped by a complex combination of geomorphic, climatic, and anthropogenic forcings during the last 14,000 years. Pollen, macrofossils, charcoal, and physical properties from sediment cores at seven sites provide a detailed record of the spatial heterogeneity of the wetland and the roles played by natural hydrologic variability, wildfire, and human modification of drainage in shaping vegetation and habitats. Cold-temperate forests occupied regional uplands from at least 13.5–10.3 cal ka BP. Marshes dominated by grasses and other herbaceous taxa began developing along low-elevation streams as early as 10.3 cal ka BP, resulting in accumulation of organic silts. Long-hydroperiod, peat accumulating marshes, with abundant floating aquatic plants, developed as early as 9.6 cal ka BP, as rapid rates of sea-level rise elevated the water table and facilitated wetland development and peat accumulation along stream courses. By the mid-Holocene (c. 7–6.5 cal ka BP), when local sea-level rise began slowing and reached about 12–15 m below present, shorter hydroperiod, peat-accumulating marshes dominated the landscape, with increased wildfire activity. Great Dismal Swamp vegetation shifted from marshes to peat-accumulating forested wetlands by c. 3.7 cal ka BP; these were dominated by varying combinations of Nyssa (tupelo), Taxodium (cypress), and Chamaecyparis thyoides (Atlantic white cedar). Wildfires were infrequent during this time, and the forested wetlands persisted, with minor compositional changes related to climate-driven fluctuations in stream flow, until colonial ditching and logging began in the swamp during the late 18th century. These activities decreased cypress and cedar populations, and, by the mid-20th century, expanded ditching resulted in even drier conditions and expansion of maple-gum (dominated by Acer and Liquidambar ) , and pine-pocosin (dominated by Pinus ) forests. The distribution of these forests differs from that of the late Holocene and represents a fundamental shift in hydrology, peat structure, vegetation, and fire regime due to landscape alterations of the last few centuries.

North Carolina, Virginia↗

Thermal detectability of subsurface water ice on Mars: A comparative analysis for the Subsurface Water Ice Mapping (SWIM) Project

We have developed a new global map of shallow ground ice distribution, SWIM23, based on Mars Global Surveyor Thermal Emission Spectrometer data and made systematic comparisons between this new map and two similar, previously developed data products. We have explored the origin of differences between the three ice maps by detailing technical and procedural differences in their development, by making global pixel-by-pixel comparisons, and by carrying out a series of one-dimensional thermal simulations to explore fundamental physical limitations of thermal ice-detection techniques. These efforts and the production of a composite thermal ice-consistency map supported integration of multiple geophysical data products relevant to ice detection in the upper meter of the Martian regolith into the larger Mars Subsurface Water Ice Mapping project. Our work also highlights fundamental physical limitations to thermal ice detection as a technique, particularly the rapid fall-off in ice detection sensitivity at depths >30 cm, which produces maximum uncertainty in the presence and depth of ice within regions preferred for potential human landing sites. A future Mars orbiter mission designed to detect ice and support crewed landing site selection in the midlatitude region should give payload priority to an instrument capable of probing the 1–5 m depth range (i.e., a high-frequency radar), over a next-generation thermal spectrometer, which is unlikely to offer clarity on ice table depths or lateral continuity of the ice table in the locations of highest interest.

Planetary Science Journal↗

The approaching obsolescence of 137Cs dating of wetland soils in North America

The peak fallout in 1963 of the radionuclide 137 Cs has been used to date lake, reservoir, continental shelf, and wetland sedimentary deposits. In wetlands such dating is used to project the ability of wetlands to keep pace with sea level rise and develop strategies for mitigating carbon pollution using biological carbon sequestration. Here we demonstrate that reliable 137 Cs profiles are increasingly difficult to obtain from wetland soils. Among 58 soil cores recently collected from a range of wetland types and 137 Cs fallout densities across the United States, 25% contain no identifiable 137 Cs peaks. Less than 40% of 137 Cs ages are consistent with 210 Pb dating. We provide a new measure of 137 Cs peak clarity (τ) for our core dataset by comparing the 50% interquartile range of data around the 137 Cs peak for “ideal” cores profiles determined using 137 Cs fallout data to that of observed core profiles. Our results show that overall τ is approximately 10 times greater for observed cores than ideal cores. The deterioration in the 137 Cs peak has occurred due to radionuclide decay, 137 Cs migration in situ , which is ubiquitous in this study, and 137 Cs amendments from surface waters. Such deterioration likely extends to both Mexican and non-permafrost, Canadian wetlands. We recommend continued use of 137 Cs only if the full bound of dating uncertainty for both 137 Cs and an additional method such as 210 Pb is propagated into estimates of wetland vertical accretion and carbon sequestration.

Quaternary Science Reviews↗

The influence of climate variability on the accuracy of NHD perennial and non-perennial stream classifications

National Hydrography Dataset (NHD) stream permanence classifications (SPC; perennial, intermittent, and ephemeral) are widely used for data visualization and applied science, and have implications for resource policy and management. NHD SPC were assigned using a combination of topographic field surveys and interviews with local residents. However, previous studies indicate that non‐NHD, in situ streamflow observations (NNO) frequently disagree with NHD SPC. We hypothesized that differences in annual climate conditions between map creation years and the years NNO were collected contributed to disagreement between NNO and NHD SPC. We compared NHD SPC to 10,055 NNO (classified as “wet” or “dry”) collected in the Pacific Northwest between 1977 and 2015. Annual climate conditions were described with the Palmer Drought Severity Index (PDSI). Stream order was added as a covariate to account for different effects along the stream network. NHD SPC agreed with 80.5% of NNO. “Dry” NNO were five times more likely to disagree with NHD than “wet” NNO ( p < 0.0001). Disagreement was greatest on first‐order streams. When NHD SPC were collected during a wetter period than NNO the probability of disagreement increased by a factor of 1.17 ( p < 0.0001) per unit difference in PDSI. The influence of climate on disagreements between NNO and NHD SPC provides support for the continued development of dynamic models representing SPC as opposed to static NHD classifications.

Journal of the American Water Resources Associatio↗

Vulnerability of shallow groundwater and drinking-water wells to nitrate in the United States

Two nonlinear models were developed at the national scale to (1) predict contamination of shallow ground water (typically < 5 m deep) by nitrate from nonpoint sources and (2) to predict ambient nitrate concentration in deeper supplies used for drinking. The new models have several advantages over previous national-scale approaches. First, they predict nitrate concentration (rather than probability of occurrence), which can be directly compared with water-quality criteria. Second, the models share a mechanistic structure that segregates nitrogen (N) sources and physical factors that enhance or restrict nitrate transport and accumulation in ground water. Finally, data were spatially averaged to minimize small-scale variability so that the large-scale influences of N loading, climate, and aquifer characteristics could more readily be identified. Results indicate that areas with high N application, high water input, well-drained soils, fractured rocks or those with high effective porosity, and lack of attenuation processes have the highest predicted nitrate concentration. The shallow groundwater model (mean square error or MSE = 2.96) yielded a coefficient of determination ( R 2 ) of 0.801, indicating that much of the variation in nitrate concentration is explained by the model. Moderate to severe nitrate contamination is predicted to occur in the High Plains, northern Midwest, and selected other areas. The drinking-water model performed comparably (MSE = 2.00, R 2 = 0.767) and predicts that the number of users on private wells and residing in moderately contaminated areas (>5 to ≤10 mg/L nitrate) decreases by 12% when simulation depth increases from 10 to 50 m.

Environmental Science & Technology↗

In-stream attenuation of neuro-active pharmaceuticals and their metabolites

In-stream attenuation was determined for 14 neuro-active pharmaceuticals and associated metabolites. Lagrangian sampling, which follows a parcel of water as it moves downstream, was used to link hydrological and chemical transformation processes. Wastewater loading of neuro-active compounds varied considerably over a span of several hours, and thus a sampling regime was used to verify that the Lagrangian parcel was being sampled and a mechanism was developed to correct measured concentrations if it was not. In-stream attenuation over the 5.4-km evaluated reach could be modeled as pseudo-first-order decay for 11 of the 14 evaluated neuro-active pharmaceutical compounds, illustrating the capacity of streams to reduce conveyance of neuro-active compounds downstream. Fluoxetine and N -desmethyl citalopram were the most rapidly attenuated compounds ( t 1/2 = 3.6 &plusmn; 0.3 h, 4.0 &plusmn; 0.2 h, respectively). Lamotrigine, 10,11,-dihydro-10,11,-dihydroxy-carbamazepine, and carbamazepine were the most persistent ( t 1/2 = 12 &plusmn; 2.0 h, 12 &plusmn; 2.6 h, 21 &plusmn; 4.5 h, respectively). Parent compounds (e.g., buproprion, carbamazepine, lamotrigine) generally were more persistent relative to their metabolites. Several compounds (citalopram, venlafaxine, O -desmethyl-venlafaxine) were not attenuated. It was postulated that the primary mechanism of removal for these compounds was interaction with bed sediments and stream biofilms, based on measured concentrations in stream biofilms and a column experiment using stream sediments.

Environmental Science & Technology↗

The developing zebrafish kidney is impaired by Deepwater Horizon crude oil early-life stage exposure: A molecular to whole-organism perspective

Crude oil is known to induce developmental defects in teleost fish exposed during early life stages (ELSs). While most studies in recent years have focused on cardiac endpoints, evidence from whole-animal transcriptomic analyses and studies with individual polycyclic aromatic hydrocarbons (PAHs) indicate that the developing kidney (i.e., pronephros) is also at risk. Considering the role of the pronephros in osmoregulation, and the common observance of edema in oil-exposed ELS fish, surprisingly little is known regarding the effects of oil exposure on pronephros development and function. Using zebrafish ( Danio rerio ) ELSs, we assessed the transcriptional and morphological responses to two dilutions of high-energy water accommodated fractions (HEWAF) of oil from the Deepwater Horizon oil spill using a combination of qPCR and whole-mount in situ hybridization (WM-ISH) of candidate genes involved in pronephros development and function, and immunohistochemistry (WM-IHC). To assess potential functional impacts on the pronephros, three 24 h osmotic challenges (2 hypo-osmotic, 1 near iso‐osmotic) were implemented at two developmental time points (48 and 96 h post fertilization; hpf) following exposure to HEWAF. Changes in transcript expression level and location specific to different regions of the pronephros were observed by qPCR and WM-ISH. Further, pronephros morphology was altered in crude oil exposed larvae, characterized by failed glomerulus and neck segment formation, and straightening of the pronephric tubules. The osmotic challenges at 96 hpf greatly exacerbated edema in both HEWAF-exposed groups regardless of osmolarity. By contrast, larvae at 48 hpf exhibited no edema prior to the osmotic challenge, but previous HEWAF exposure elicited a concentration-response increase in edema at hypo-osmotic conditions that appeared to have been largely alleviated under near iso‐osmotic conditions. In summary, ELS HEWAF exposure impaired proper pronephros development in zebrafish, which coupled with cardiotoxic effects, most likely reduced or inhibited pronephros fluid clearance capacity and increased edema formation.

Science of the Total Environment↗

Evidence for landscape-level, pollen-mediated gene flow from genetically modified creeping bentgrass with CP4 EPSPS as a marker

Sampling methods and results of a gene flow study are described that will be of interest to plant scientists, evolutionary biologists, ecologists, and stakeholders assessing the environmental safety of transgenic crops. This study documents gene flow on a landscape level from creeping bentgrass (Agrostis stolonifera L.), one of the first wind-pollinated, perennial, and highly outcrossing transgenic crops being developed for commercial use. Most of the gene flow occurred within 2 km in the direction of prevailing winds. The maximal gene flow distances observed were 21 km and 14 km in sentinel and resident plants, respectively, that were located in primarily nonagronomic habitats. The selectable marker used in these studies was the CP4 EPSPS gene derived from Agrobacterium spp. strain CP4 that encodes 5-enol-pyruvylshikimate-3-phosphate synthase and confers resistance to glyphosate herbicide. Evidence for gene flow to 75 of 138 sentinel plants of A. stolonifera and to 29 of 69 resident Agrostis plants was based on seedling progeny survival after spraying with glyphosate in greenhouse assays and positive TraitChek, PCR, and sequencing results. Additional studies are needed to determine whether introgression will occur and whether it will affect the ecological fitness of progeny or the structure of plant communities in which transgenic progeny may become established.

Proceedings of the National Academy of Sciences of↗

Holocene thermokarst lake dynamics in northern Interior Alaska: The interplay of climate, fire, and subsurface hydrology

The current state of permafrost in Alaska and meaningful expectations for its future evolution are informed by long-term perspectives of previous permafrost degradation. Thermokarst processes in permafrost landscapes often lead to widespread lake formation and the spatial and temporal evolution of thermokarst lake landscapes reflects the combined effects of climate, ground conditions, vegetation, and fire. This study provides detailed analyses of thermokarst lake sediments of Holocene age from the southern loess uplands of the Yukon Flats; including bathymetry and sediment core analyses across a water depth transect. The sediment core results, dated by radiocarbon and 210Pb, indicate the onset of finely laminated lacustrine sedimentation between ~10,000 and 9,000 cal yr BP following basin development through inferred thermokarst processes. Thermokarst expansion to modern shoreline configurations continued until ~5000 cal yr BP, which may have been influenced by increased fire. Between ~5000 and 2000 cal yr BP, the preservation of fine laminations at intermediate and deep-water depths indicate higher lake levels than present. At that time, the lake likely overflowed into an over-deepened gully system that is no longer occupied by perennial streams. By ~2000 cal yr BP, massive sedimentation at intermediate water depths indicates that lake levels lowered, which is interpreted to reflect a response to drier conditions based on correspondence with Yukon Flats regional fire and local paleoclimate reconstructions. Consideration of additional contributing mechanisms include the possible influence of catastrophic lake drainages on downgradient base flow levels that may have enhanced subsurface water loss, although this mechanism is untested. The overall consistency between the millennial lake level trends documented here with regional paleoclimate trends indicates that after lakes formed, their size and depth has likely been affected directly by North Pacific atmospheric circulation changes and indirectly through evolution of permafrost, ground ice and sub-surface hydrology. As the first detailed study of Holocene thermokarst basin expansion, stabilization and subsequent climate-driven lake level variations in a loess upland, results provide a framework for future investigations of paleoclimatic signals from similar lake systems that characterize large regions of Alaska and Siberia.

Alaska↗

Kinetic study on clogging of a geothermal pumping well triggered by mixing-induced biogeochemical reactions

The sustainability of ground-source geothermal systems can be severely impacted by microbially mediated clogging processes. Biofouling of water wells by hydrous ferric oxide is a widespread problem. Although the mechanisms and critical environmental factors associated with clogging development are widely recognized, effects of mixing processes within the wells and time scales for clogging processes are not well characterized. Here we report insights from a joint hydrological, geochemical, and metagenomics characterization of a geothermal doublet in which hydrous ferric oxide and hydrous manganese oxide deposits had formed as a consequence of mixing shallow groundwater containing dissolved oxygen and nitrate with deeper, anoxic groundwater containing dissolved iron (Fe II ) and manganese (Mn II ). Metagenomics identify distinct bacteria consortia in the pumping well oxic and anoxic zones, including autotrophic iron-oxidizing bacteria. Batch mixing experiments and geochemical kinetics modeling of the associated reactions indicate that Fe II and Mn II oxidation are slow compared to the residence time of water in the pumping well; however, adsorption of Fe II and Mn II by accumulated hydrous ferric oxide and hydrous manganese oxide in the well bore and pump riser provides “infinite” time for surface-catalyzed oxidation and a convenient source of energy for iron-oxidizing bacteria, which colonize the surfaces and also catalyze oxidation. Thus, rapid clogging is caused by mixing-induced redox reactions and is exacerbated by microbial activity on accumulated hydrous oxide surfaces.

Orleans↗

Where the waters meet: sharing ideas and experiences between inland and marine realms to promote sustainable fisheries management

Although inland and marine environments, their fisheries, fishery managers, and the realm-specific management approaches are often different, there are a surprising number of similarities that frequently go unrecognized. We contend that there is much to be gained by greater cross-fertilization and exchange of ideas and strategies between realms and the people who manage them. The purpose of this paper is to provide examples of the potential or demonstrated benefits of working across aquatic boundaries for enhanced sustainable management of the world&rsquo;s fisheries resources. Examples include the need to (1) engage in habitat management and protection as the foundation for fisheries, (2) rethink institutional arrangements and management for open-access fisheries systems, (3) establish &ldquo;reference points&rdquo; and harvest control rules, (4) engage in integrated management approaches, (5) reap conservation benefits from the link to fish as food, and (6) reframe conservation and management of fish to better engage the public and industry. Cross-fertilization and knowledge transfer between realms could be realized using environment-independent curricula and symposia, joint scientific advisory councils for management, integrated development projects, and cross-realm policy dialogue. Given the interdependence of marine and inland fisheries, promoting discussion between the realms has the potential to promote meaningful advances in managing global fisheries.

Canadian Journal of Fisheries and Aquatic Sciences↗

Trends in nitrogen, phosphorus, and sediment concentrations and loads in streams draining to Lake Tahoe, California, Nevada, USA

Lake Tahoe, a large freshwater lake of the eastern Sierra Nevada in California and Nevada, has 63 tributaries that are sources of nutrients and sediment to the lake. The Tahoe watershed is relatively small, and the surface area of the lake occupies about 38% of the watershed area (1313 km 2 ). Only about 6% of the watershed is urbanized or residential land, and as part of a plan to maintain water clarity, wastewater is exported out of the basin. The lake's clarity has been diminishing due to algae and fine sediment, prompting development of management plans. Much of the annual discharge and nutrient load to the lake results from snowmelt in the spring and summer months. To understand the relative importance of land use, climate, forest management, and other factors affecting trends in nutrient stream concentrations and loads, a Weighted Regression on Time Discharge and Season (WRTDS) model simulated these trends over a time frame of >25 years (mid-1970s to 2017). All studied locations generally show nitrate concentration and load trending down. Ammonium concentration and load initially trended down then increased continuously after 2005. Some locations show initially decreasing orthophosphate trends, followed by small significant increases in concentration and loads starting around 2000 to 2005. Total Kjeldahl nitrogen, total phosphorus and suspended sediment mostly trended downward. Overall, the trends in various forms of nitrogen were observed at most sites irrespective of the degree of development and indicate a change in ecological conditions is affecting the nitrogen cycle throughout the watershed, most likely attributable to forest aggradation and fire suppression. Ratios of bioavailable nitrogen in the form of nitrate and ammonium to orthophosphate have also trended downward during the period of record suggesting a shift of these streams from phosphorus limited to nitrogen limited.

California, Nevada↗

An improved method for quantifying soil macroporosity

Quantitative information on macroporosity is needed to predict water flow and solute transport in field soils. A method was developed for determining the number, shape, and size distribution of soil macropores. Horizontal serial sections sawed from paraffin-impregnated soil cores were photographed under ultraviolet (UV) light. Anthracene, mixed with the paraffin, fluoresces a bright bluish white under UV light and provides a sharp contrast between the soil matrix and the paraffin-filled pore space. Section photographs were converted to 256 level, grey-scale digital images using a flat-bed scanner. Image processing was used to classify each pixel in a digital image as pore space or soil matrix, to group the pore space pixels into pores, and to measure the area and perimeter of each pore. The method was able to measure pores with an equivalent radius ≥85 µm. Macroporosity in soil cores sampled form a tillage path and from an adjacent, undisturbed (notill) region was quantified. Tillage sections contained, on the average, 9.4 macropores/cm 2 with an equivalent macroporosity of 8%, while no-till sections contained 0.8 macropores/cm 2 with an equivalent macroporosity of 0.3%. Computed intrinsic permeabilities for tillage sections that included macropore information were significantly larger than values computed using micropore information alone, suggesting that macropores must be included in permeability calculations when the number of macropores is large. The developed method should be useful for quantifying macroporosity in nonskeletal soils.

Soil Science Society of America Journal↗

Archive of bathymetry data collected in South Florida from 1995 to 2015

Description Land development and alterations of the ecosystem in south Florida over the past 100 years have decreased freshwater and increased nutrient flows into many of Florida's estuaries, bays, and coastal regions. As a result, there has been a decrease in the water quality in many of these critical habitats, often prompting seagrass die-offs and reduced fish and aquatic life populations. Restoration of water quality in many of these habitats will depend partly upon using numerical-circulation and sediment-transport models to establish water-quality targets and to assess progress toward reaching restoration targets. Application of these models is often complicated because of complex sea floor topography and tidal flow regimes. Consequently, accurate and modern sea-floor or bathymetry maps are critical for numerical modeling research. Modern bathymetry data sets will also permit a comparison to historical data in order to help assess sea-floor changes within these critical habitats. New and detailed data sets also support marine biology studies to help understand migratory and feeding habitats of marine life. This data series is a compilation of 13 mapping projects conducted in south Florida between 1995 and 2015 and archives more than 45 million bathymetric soundings. Data were collected primarily with a single beam sound navigation and ranging (sonar) system called SANDS developed by the U.S. Geological Survey (USGS) in 1993. Bathymetry data for the Estero Bay project were supplemented with the National Aeronautics and Space Administration's (NASA) Experimental Advanced Airborne Research Lidar (EAARL) system. Data from eight rivers in southwest Florida were collected with an interferometric swath bathymetry system. The projects represented in this data series were funded by the USGS Coastal and Marine Geology Program (CMGP), the USGS South Florida Ecosystem Restoration Project- formally named Placed Based Studies, and other non-Federal agencies. The purpose of the data collection for all these projects was to support one or more of the following scientific aspects: numerical model applications, sea floor change analysis, or marine habitat investigations. This report serves as an archive of processed bathymetry sounding data, digital bathymetric contours, digital bathymetric maps, sea floor surface grids, and formal Federal Geographic Data Committee (FGDC) metadata. Refer to the Abbreviations page for explanations of acronyms and abbreviations used in this report. Since 2006, the USGS St. Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier or Field Activity Number (FAN) for each field data collection. Projects described in this report conducted prior to 2006 do not have a FAN. Data from the 13 projects presented in this report provided critical hydrographic information to support multiple science projects in south Florida. The projects and the types of sounding data collected are: Florida Bay (1995-1999) - single-beam Lake Okeechobee (2001) - single-beam Tampa Bay (2001-2004) - single-beam Caloosahatchee River (2002)- single-beam Estero Bay to Matlacha Pass and offshore to Wiggins Pass (2003) - single-beam and airborne lidar North and Northwest Forks of the Loxahatchee and Lower St. Lucie Rivers (2003) - single-beam South Charlotte Harbor and offshore Sanibel Island (2003-2004) - single-beam Shark River and Trout Creek (2004) - single-beam and interferometric swath Southwest Florida Rivers (2004) - interferometric swath Offshore from Wiggins Pass to Cape Romano (2005) - single-beam Ten Thousand Islands (2009) - single-beam Lemon Bay (2011) - single-beam Southwest Florida Rivers (2015) - interferometric swath

Florida↗

Urban stormwater: An overlooked pathway of extensive mixed contaminants to surface and groundwaters in the United States

Increasing global reliance on stormwater control measures to reduce discharge to surface water, increase groundwater recharge, and minimize contaminant delivery to receiving waterbodies necessitates improved understanding of stormwater-contaminant profiles. A multi-agency study of organic and inorganic chemicals in urban stormwater from 50 runoff events at 21 sites across the United States demonstrated that stormwater transports substantial mixtures of polycyclic aromatic hydrocarbons, bioactive contaminants (pesticides and pharmaceuticals), and other organic chemicals known or suspected to pose environmental health concern. Numerous organic-chemical detections per site (median number of chemicals detected = 73), individual concentrations exceeding 10,000 ng/L, and cumulative concentrations up to 263,000 ng/L suggested concern for potential environmental effects during runoff events. Organic concentrations, loads, and yields were positively correlated with impervious surfaces and highly developed urban catchments. Episodic storm-event organic concentrations and loads were comparable to and often exceeded those of daily wastewater plant discharges. Inorganic chemical concentrations were generally dilute in concentration and did not exceed chronic aquatic life criteria. Methylmercury was measured in 90% of samples with concentrations that ranged from 0.05 to 1.0 ng/L.

Environmental Science & Technology↗

Variability in coastal habitat available for Longfin Smelt Spirinchus thaleichthys in the northeastern Pacific Ocean

An understanding of oceanographic conditions and processes important to marine animal ecology is fundamental to the development of effective management and conservation actions. Longfin Smelt ( Spirinchus thaleichthys ) is a pelagic forage fish found in coastal and estuarine waters along the Pacific coast of North America from Alaska to central California. Substantial population declines in California’s San Francisco Estuary, where Longfin Smelt are protected under California’s Endangered Species Act, have prompted extensive study of estuarine factors associated with the decline. However, coastal factors that affect up to two-thirds of the Longfin Smelt life cycle are poorly understood and may be important drivers of population dynamics. We compiled coastal observations from numerous sources to estimate the range-wide coastal marine distribution of Longfin Smelt and assess habitat factors affecting distribution in the northeast Pacific Ocean. Based on maximum entropy species distribution models, Longfin Smelt distribution was correlated with depth, distance from the nearest estuary, sea surface temperature, and sea surface chlorophyll. Longfin Smelt were found in shallow, higher productivity coastal waters closer to estuaries, with depth and temperature the most consistent factors influencing distribution. Habitat suitability was highly variable at the southern extent of the range, particularly off the California coast, and was largely driven by habitat contractions associated with warm-water conditions. Study results provide insights into the habitat and range-wide distribution of an at-risk estuarine-reliant forage fish and are the first step toward identifying processes that affect the marine portion of the Longfin Smelt life cycle.

Frontiers in Marine Science↗

Corn leaf nitrate reductase - A nontoxic alternative to cadmium for photometric nitrate determinations in water samples by air-segmented continuous-flow analysis

Development, characterization, and operational details of an enzymatic, air-segmented continuous-flow analytical method for colorimetric determination of nitrate + nitrite in natural-water samples is described. This method is similar to U.S. Environmental Protection Agency method 353.2 and U.S. Geological Survey method 1-2545-90 except that nitrate is reduced to nitrite by soluble nitrate reductase (NaR, EC 1.6.6.1) purified from corn leaves rather than a packed-bed cadmium reactor. A three-channel, air-segmented continuous-flow analyzer-configured for simultaneous determination of nitrite (0.020-1.000 mg-N/L) and nitrate + nitrite (0.05-5.00 mg-N/L) by the nitrate reductase and cadmium reduction methods-was used to characterize analytical performance of the enzymatic reduction method. At a sampling rate of 90 h-1, sample interaction was less than 1% for all three methods. Method detection limits were 0.001 mg of NO2- -N/L for nitrite, 0.003 mg of NO3-+ NO2- -N/L for nitrate + nitrite by the cadmium-reduction method, and 0.006 mg of NO3- + NO2- -N/L for nitrate + nitrite by the enzymatic-reduction method. Reduction of nitrate to nitrite by both methods was greater than 95% complete over the entire calibration range. The difference between the means of nitrate + nitrite concentrations in 124 natural-water samples determined simultaneously by the two methods was not significantly different from zero at the p = 0.05 level.

Environmental Science & Technology↗