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At least 1,117 records · Page 62Linked to original sources

USGS1989

Simulated effects of future withdrawals on water levels in the northeastern coastal plain aquifers of New Jersey

In the northeastern Coastal Plain of New Jersey, groundwater withdrawals have produced large cones of depression in all four major regional aquifers. Prior to development, water levels in the four aquifers were 20 to 120 ft above sea level and natural groundwater flow was towards Raritan Bay. In 1983, when total withdrawals exceeded 90 million gal/day, water levels were as low as 185 ft below sea level in the Wenonah-Mount Laurel aquifer, 225 ft below sea leval in the Englishtown aquifer system and 52 and 82 ft below sea level in the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system, respectively. With development, the natural direction of groundwater flow has been reversed, resulting in the movement of saltwater into parts of the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system. An 11-layer finite-difference model of the entire New Jersey Coastal Plain was used to simulate the effects of six scenarios of future groundwater withdrawals on water levels in the northeastern Coastal Plain of New Jersey through the year 2020. In the simulation with the most severe reduction, most of the groundwater withdrawals in the northeastern and west-central areas of the Coastal Plain were limited to 50% of 1983 withdrawals after 1990. Even with such restrictions, the lowest simulated water levels in the northeastern part of the Coastal Plain for 2010 are still well below sea level. (USGS)

Water-Resources Investigations Report↗

USGS2013

Comparison of a karst groundwater model with and without discrete conduit flow

Karst aquifers exhibit a dual flow system characterized by interacting conduit and matrix domains. This study evaluated the coupled continuum pipe-flow framework for modeling karst groundwater flow in the Madison aquifer of western South Dakota (USA). Coupled conduit and matrix flow was simulated within a regional finite-difference model over a 10-year transient period. An existing equivalent porous medium (EPM) model was modified to include major conduit networks whose locations were constrained by dye-tracing data and environmental tracer analysis. Model calibration data included measured hydraulic heads at observation wells and estimates of discharge at four karst springs. Relative to the EPM model, the match to observation well hydraulic heads was substantially improved with the addition of conduits. The inclusion of conduit flow allowed for a simpler hydraulic conductivity distribution in the matrix continuum. Two of the high-conductivity zones in the EPM model, which were required to indirectly simulate the effects of conduits, were eliminated from the new model. This work demonstrates the utility of the coupled continuum pipe-flow method and illustrates how karst aquifer model parameterization is dependent on the physical processes that are simulated.

South Dakota↗

USGS2019

Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA

Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize uranium. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected in 24 percent of 257 domestic, irrigation, and public-supply wells sampled across an approximately 110,000 km2 area. The location of high concentrations depends on the interactions of U sources from fluvial fans that originate in the Sierra Nevada to the east and seepage of irrigation water that contains high concentrations of HCO3 that leaches U from the sediments. In addition, interactions with phosphate (PO4) from fertilized irrigated fields may sequester U in the aquifer. Principal component analysis of the data demonstrates that HCO3 and ions associated with high total dissolved solids in the aquifer and the percentage of agriculture near the well sampled are associated with high U concentrations. Nitrate concentrations do not appear to control release of U to the aquifer. Age dating of the groundwater and generally increasing U concentrations of the past 25 years in resampled wells where irrigation is prevalent suggests that high U concentrations are associated with younger water, indicating that irrigation of fields over the past 100 years has significantly contributed to increasing concentrations and mobilizing U. In some places, the groundwater is supersaturated with uranyl-containing minerals, as would be expected in roll front deposits. In general, the interaction of natural geological sources high in U, the anthropogenically driven addition of HCO3 and possibly phosphate fertilizer, control the location and concentration of U in each individual fluvial fan, but the addition of nitrate in fertilizer does not appear control the location of high U. These geochemical interactions can be used to determine controls on anomalously high U in alluvial aquifers

California↗

USGS2003

Three-dimensional geologic modeling and visualization of the Virttaankangas aquifer, southwestern Finland

A need exists for a reliable and long-term water supply for the 285,000 inhabitants of the Turku area in southwestern Finland . In response to this need, there are plans to replace the present water supply from the surface sources with artificially infiltrated groundwater from a Quaternary esker aquifer called the Virttaankangas aquifer . New sedimentological studies of the Virttaankangas area have revealed the complexities of the esker system and its surrounding glacial, glaciofluvial, and glaciolacustrine geology. This led to the characterization of the hydrogeological units of the aquifer , the result of which has been a three - dimensional (3-D) truly integrated solids model that represents the geometry, interrelationships, and hydrostratigraphy of the study area. The 3-D model was made with Earth Vision geologic modeling software. The 3-D geological model of the Virttaankangas aquifer can be used for planning the infiltration of river water into the aquifer and to understand the geologic and geographic boundaries of the hydrogeologic units hosting the groundwater reserve and the geologic relationships between the units. Another major outcome of this study is a powerful visualization tool that will be provided to municipal and government authorities who must understand the geologic complexities involved with water-resource planning prior to their decision making.

southwest Finland↗

USGS2003

Noble gas loss may indicate groundwater flow across flow barriers in southern Nevada

Average calculated noble gas temperatures increase from 10 to 22 o C in groundwater from recharge to discharge areas in carbonate-rock aquifers of southern Nevada. Loss of noble gases from groundwater in these regional flow systems at flow barriers is the likely process that produces an increase in recharge noble gas temperatures. Emplacement of low permeability rock into high permeability aquifer rock and the presence of low permeability shear zones reduce aquifer thickness from thousands to tens of meters. At these flow barriers, which are more than 1,000 m lower than the average recharge altitude, noble gases exsolve from the groundwater by inclusion in gas bubbles formed near the barriers because of greatly reduced hydrostatic pressure. However, re-equilibration of noble gases in the groundwater with atmospheric air at the low altitude spring discharge area, at the terminus of the regional flow system, cannot be ruled out. Molecular diffusion is not an important process for removing noble gases from groundwater in the carbonate-rock aquifers because concentration gradients are small.

Conference Paper↗

USGS2022

Hydrogeologic characterization of the San Antonio Creek Valley watershed, Santa Barbara County, California

The San Antonio Creek Valley watershed (SACVW) is located in western Santa Barbara County, about 15 miles south of Santa Maria and 55 miles north of Santa Barbara, California. The SACVW is about 135 square miles and encompasses the San Antonio Creek Valley groundwater basin; the SACVW is separated from adjacent groundwater basins by the Casmalia and Solomon Hills to the north, and the Purisima Hills to the south. At the western, downstream part of the valley, uplifted, consolidated rocks cause groundwater to discharge at land surface at Barka Slough. Since the late 1800s, groundwater has been the primary source of water for agricultural, military, municipal, and domestic uses. Groundwater withdrawal by pumping exceeded the amount of water replenishing the aquifer system during water years 1948–2018, causing groundwater-level declines of more than 150 feet in parts of the valley and reducing base flow at Barka Slough. Reliance on groundwater for agricultural water use (primarily for the irrigation and frost protection of vineyards, and fruit and berry crops) continues to strain the sustainability of the groundwater system. Through a cooperative agreement, the Santa Barbara County Water Agency and Vandenberg Space Force Base invited the U.S. Geological Survey to address declines in groundwater levels, develop a better understanding of the hydrogeologic system, and provide tools to help evaluate and manage the effects of future development of the San Antonio Creek Valley groundwater basin within the encompassing San Antonio Creek Valley watershed (SACVW). The objectives of this study were to (1) refine the hydrogeologic framework of the San Antonio Creek Valley watershed, (2) quantify the hydrologic budget of the valley, and (3) develop hydrologic modeling tools to evaluate and aid in managing the groundwater resource. This report focuses on the first and second objectives to construct a hydrogeologic framework and characterize the historical and present-day hydrologic conditions of the SACVW during water years 1948–2018. As part of the second objective, work included quantifying the hydrologic budget and evaluating the hydrogeologic system using a combination of existing data and geologic and hydrologic data collected for this study. The groundwater-flow system in the SACVW consists of five hydrogeologic units. These separate water-bearing units were identified based on hydrogeologic properties, such as sediment grain size, vertical-head differences in multiple-depth, monitoring-well sites, long-term groundwater level responses to pumping and climate, and the chemical character of groundwater and groundwater age in the mostly semi-consolidated to unconsolidated basin-fill sediments. The hydrogeologic units that comprise the different aquifers vary in their lithologic composition. The upper and lower aquifers (upper Paso Robles Formation, and lower Paso Robles Formation and Careaga Sandstone, respectively) are relatively coarse grained and are comprised of sand, gravel, and clay; the middle confining unit (the middle Paso Robles Formation) is relatively fine grained and is comprised of primarily clay, silt, and sand. The Pezzoni-Casmalia and Los Alamos faults, which are inferred to transect the SACVW between the western and eastern areas of the valley floor, do not appear to substantially affect the groundwater system. Present-day recharge to the study area occurs primarily as infiltration from precipitation and streams in the upland areas of the Casmalia Hills and Solomon Hills, and along the main channel of San Antonio Creek. Reported estimates of annual natural recharge during water years 1948–2018 generally ranged from about 5,000 acre-feet to more than about 30,000 acre-feet. Stable and radioactive isotopes show that groundwater from the lower aquifer is old and probably was recharged as infiltration from precipitation and streams in the eastern upland areas of the Solomon Hills; however, the infiltration and recharge from these sources probably does not occur under present-day climatic conditions. Anthropogenic recharge, from sources such as return flow from agricultural irrigation, municipal water systems, and wastewater effluent, was estimated to range from about 600 acre-feet in 1948 to about 6,600 acre-feet in 2018. The average annual amount of groundwater removed from the SACVW by pumping during 1948–2018 was estimated to be about 17,200 acre-feet per year, increasing from about 3,000 acre-feet in 1948 to about 32,600 acre-feet in 2018. Estimates of annual pumpage generally exceeded estimates of annual recharge beginning in the mid-1970s and continuing through 2018. The predominant direction of groundwater flow under historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek to the discharge area in Barka Slough, and from the northern uplands in the Casmalia Hills south to San Antonio Creek. Pumpage since the early 1900s and the subsequent groundwater-level declines have substantially reduced the amount of natural groundwater discharge at Barka Slough. Estimates of base flow to San Antonio Creek at the western, downstream extent of the SACVW have varied over time in response to changes in groundwater pumpage and climate; however, there was an overall decline in base flow during water years 1956–2018, decreasing from an average of about 1,700 acre-feet per year during 1956–69, to about 300 acre-feet per year during 2016–18. The long-term extraction of groundwater correlates with a decrease in groundwater levels by more than about 150 feet since the early 1940s in the eastern part of the basin near Los Alamos, and as much as about 50 feet in the upland areas and in the western part of the basin. At Barka Slough, groundwater levels have declined below land surface in some places, altering native riparian vegetation in and around the slough. Surface-water quality in the SACVW varied depending on location and the time of year the samples were collected and on the amount of annual precipitation Most groundwater in the SACVW was calcium-bicarbonate-type water with total dissolved-solids concentrations of about 500–800 milligrams per liter generally representing water naturally recharged as infiltration from precipitation and streams. Total dissolved-solids concentrations in some wells ranged from 800 to 8,000 milligrams per liter, suggesting mixing of naturally recharged infiltrated water with water associated with oil-bearing geologic formations, agricultural products, or the evaporation of shallow groundwater. Concentrations of total dissolved solids and the chemical constituents chloride, nitrate plus nitrite (as nitrogen), calcium, and magnesium at selected wells generally increased during water years 1980–2018; increasing concentrations of these constituents may be associated with the expansion of agriculture in the watershed over time and the corresponding increase in the use of nitrates and calcium- and magnesium-based fertilizers and soil additives in modern agricultural practices. The predominant direction of groundwater flow during historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek toward Barka Slough, and from the western uplands in the Casmalia Hills south to San Antonio Creek. The age of groundwater in the SACVW was evaluated using radioactive isotopes, and the flow of groundwater within the SACVW was evaluated using radioactive and stable isotopes. Modern groundwater (recharged after 1952) was generally found adjacent to San Antonio Creek and its tributaries in wells with perforated depths that averaged about 270 feet below land surface. Pre-modern groundwater (recharged before 1952) was found in wells that had average perforation depths of about 540 ft below land surface. Pre-modern groundwater identified in wells in the eastern upland area is interpreted to have had long, slow travel times to the western part of the SACVW where it was eventually discharged as base flow at Barka Slough or extracted as groundwater pumpage.

California↗

USGS1993

Does lead affect microbial metabolism in aquifer sediments under different terminal electron accepting conditions?

High concentrations of aliphatic organic acids (∼1 mM acetate) in groundwater from a petroleum hydrocarbon‐contaminated aquifer are associated with elevated concentrations (∼30 μg/L) of lead. This pattern suggests that toxic effects of lead have contributed to the observed accumulation of organic acids. This hypothesis was tested by examining the effects of lead on carbon mineralization and organic acid accumulation in petroleum‐contaminated aquifer material incubated under different terminal electron‐accepting conditions. Lead was found to inhibit fermentation (organic acid accumulation) as well as microbial carbon mineralization (CO 2 or CH 4 production) under aerobic, nitrate‐reducing, sulfate‐reducing, and methanogenic conditions. Thus Pb does not appear to be the primary cause of organic acid accumulation at the field site. Rather, substantial accumulation of aliphatic organic acids occurred only in methanogenic microcosms, and only trace amounts of acetic acid were detected in sulfate‐reducing microcosms. This pattern parallels field observations in which high organic acid concentrations were detected in methanogenic zones, but only low concentrations of acetic acid were detected in sulfate‐reducing zones.

Geomicrobiology Journal↗

USGS2012

Potentiometric surface and water-level difference maps of selected confined aquifers of Southern Maryland and Maryland's Eastern Shore, 1975-2011

Groundwater is the principal source of freshwater supply in most of Southern Maryland and Maryland's Eastern Shore. It is also the source of freshwater supply used in the operation of the Calvert Cliffs, Chalk Point, and Morgantown power plants. Increased groundwater withdrawals over the last several decades have caused groundwater levels to decline. This report presents potentiometric surface maps of the Aquia, Magothy, upper Patapsco, lower Patapsco, and Patuxent aquifers using water levels measured during September 2011. Water-level difference maps also are presented for the first four of these aquifers. The water-level differences in the Aquia aquifer are shown using groundwater-level data from 1982 and 2011, whereas the water-level differences in the Magothy aquifer are presented using data from 1975 and 2011. Water-level difference maps in both the upper Patapsco and lower Patapsco aquifers are presented using data from 1990 and 2011. These maps show cones of depression ranging from 25 to 198 feet (ft) below sea level centered on areas of major withdrawals. Water levels have declined by as much as 112 ft in the Aquia aquifer since 1982, 85 ft in the Magothy aquifer since 1975, and 47 and 71 ft in the upper Patapsco and lower Patapsco aquifers, respectively, since 1990.

Maryl↗

USGS2022

Treatment of the Chicot and Evangeline aquifers as a single hydrogeologic unit and use of geostatistical interpolation methods to develop gridded surfaces of water-level altitudes and water-level changes in the Chicot and Evangeline aquifers (undifferentiated) and Jasper aquifer, greater Houston area, Texas, 2021

The greater Houston area of Texas includes approximately 11,000 square miles and encompasses all or part of 11 counties (Harris, Galveston, Fort Bend, Montgomery, Brazoria, Chambers, Grimes, Liberty, San Jacinto, Walker, and Waller). From the early 1900s until the mid-1970s, groundwater withdrawn from the three primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers—had been the primary source of water for the greater Houston area. The withdrawal of groundwater was unregulated prior to 1975, resulting in land-surface subsidence caused by large water-level declines in the greater Houston area. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, describes updates to the ways in which water-level altitudes and water-level changes in the greater Houston area are presented relative to previous U.S. Geological Survey reports. The first update involves presenting water-level altitudes and water-level changes as a combined (undifferentiated) representation of the Chicot and Evangeline aquifers. The second update concerns the methods used to depict water-level altitudes and water-level changes in the greater Houston area in interpretive reports, with geostatistical interpolation methods replacing manual contouring methods. The Chicot and Evangeline aquifers have historically been described as distinct hydrogeologic units for the purpose of water-level mapping. A confining unit does not separate these two aquifers in the study area, and water-level data from colocated wells screened in these aquifers indicate that there is likely a substantial degree of hydrogeologic connection. From a groundwater-flow perspective, these two aquifer units predominantly function as a single unit. Hence, the decision was made to combine the Chicot and Evangeline aquifers into a single, undifferentiated hydrogeologic unit for the purposes of assessing water-level altitudes and water-level changes over time. The 2020 water-level altitudes for the Chicot, Evangeline, and Jasper aquifers were re-created in this report from computer algorithms of the contoured datasets as gridded surfaces to demonstrate the similarity of results from geostatistical interpolation methods to those from manual contouring methods.

Texas↗

USGS1989

Precipitation, streamflow, and base flow in west-central Texas, December 1974 through March 1977

Precipitation, streamflow, and base-flow data were analyzed for December 1974 through March 1977 as a part of the Edwards-Trinity Regional Aquifer-System Analysis in west-central Texas. The period of record analyzed corresponds to the calibrating period of a digital groundwater-flow model of the aquifer system currently (1988) being developed. Precipitation at individual stations ranged from 6 to 45 in/yr. Precipitation normally (1951-80) ranged from 10 to 32 in/year from east to west in the study area. Precipitation was near normal over most of the area and above normal in the southeastern part of the study area. Streamflow ranged from less than 1 in/year in the western part of the study area to 13 in/yr in the southeastern part. Streamflow was 8 in/yr above normal in the southeast. Base flow ranged from less than 0.1 in/yr in the western part of the study area to 6 in/yr in the southeastern part. (USGS)

Water-Resources Investigations Report↗

USGS2016

The removal kinetics of dissolved organic matter and the optical clarity of groundwater

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d −1 ), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d −1 ). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L −1 ) and ultraviolet absorption coefficient values ( a 254 < 5 m −1 ) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.

California, Colorado, Connecticut, Georgia, Illino↗

USGS2011

Groundwater quality in the Santa Clara River Valley, California

The Santa Clara River Valley (SCRV) study unit is located in Los Angeles and Ventura Counties, California, and is bounded by the Santa Monica, San Gabriel, Topatopa, and Santa Ynez Mountains, and the Pacific Ocean. The 460-square-mile study unit includes eight groundwater basins: Ojai Valley, Upper Ojai Valley, Ventura River Valley, Santa Clara River Valley, Pleasant Valley, Arroyo Santa Rosa Valley, Las Posas Valley, and Simi Valley (California Department of Water Resources, 2003; Montrella and Belitz, 2009). The SCRV study unit has hot, dry summers and cool, moist winters. Average annual rainfall ranges from 12 to 28 inches. The study unit is drained by the Ventura and Santa Clara Rivers, and Calleguas Creek. The primary aquifer system in the Ventura River Valley, Ojai Valley, Upper Ojai Valley, and Simi Valley basins is largely unconfined alluvium. The primary aquifer system in the remaining groundwater basins mainly consists of unconfined sands and gravels in the upper portion and partially confined marine and nonmarine deposits in the lower portion. The primary aquifer system in the SCRV study unit is defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. Public-supply wells typically are completed in the primary aquifer system to depths of 200 to 1,100 feet below land surface (bls). The wells contain solid casing reaching from the land surface to a depth of about 60-700 feet, and are perforated below the solid casing to allow water into the well. Water quality in the primary aquifer system may differ from the water in the shallower and deeper parts of the aquifer. Land use in the study unit is approximately 40 percent (%) natural (primarily shrubs, grassland, and wetlands), 37% agricultural, and 23% urban. The primary crops are citrus, avocados, alfalfa, pasture, strawberries, and dry beans. The largest urban areas in the study unit are the cities of Ventura, Oxnard, Camarillo, Simi Valley, Newhall, and Santa Clarita. Currently, groundwater pumping for agricultural use accounts for the greatest amount of discharge from the aquifer system in the SCRV study unit, followed by municipal use. Recharge to the groundwater system is through stream-channel infiltration from the three main river systems and by direct infiltration of precipitation and irrigation. Recharge facilities in the Oxnard forebay play an important role in recharging the local aquifer systems.

Fact Sheet↗

USGS2008

Selecting remediation goals by assessing the natural attenuation capacity of groundwater systems

Remediation goals for the source areas of a chlorinated ethene‐contaminated groundwater plume were identified by assessing the natural attenuation capacity of the aquifer system. The redox chemistry of the site indicates that sulfate‐reducing (H 2 ∼ 2 nanomoles [nM]) per liter conditions near the contaminant source grade to Fe(III)‐reducing conditions (H 2 ∼ 0.5 nM) downgradient of the source. Sulfate‐reducing conditions facilitate the initial reduction of perchloroethene (PCE) to trichloroethene (TCE), cis ‐dichloroethene ( cis ‐DCE), and vinyl chloride (VC). Subsequently, the Fe(III)‐reducing conditions drive the oxidation of cis ‐DCE and VC to carbon dioxide and chloride. This sequence gives the aquifer a substantial capacity for biodegrading chlorinated ethenes. Natural attenuation capacity (the slope of the steady‐state contaminant concentration profile along a groundwater flowpath) is a function of biodegradation rates, aquifer dispersive characteristics, and groundwater flow velocity. The natural attenuation capacity at the Kings Bay, Georgia site was assessed by estimating groundwater flowrates (∼0.23 ± 0.12 m/d) and aquifer dispersivity (∼1 m) from hydrologic and scale considerations. Apparent biodegradation rate constants (PCE and TCE ∼ 0.01 d −1 ; cis ‐DCE and VC ∼ 0.025 d −1 ) were estimated from observed contaminant concentration changes along aquifer flowpaths. A boundary‐value problem approach was used to estimate levels to which contaminant concentrations in the source areas must be lowered (by engineered removal), or groundwater flow velocities lowered (by pumping) for the natural attenuation capacity to achieve maximum concentration limits (MCLs) prior to reaching a predetermined regulatory point of compliance.

Bioremediation Journal↗

USGS2021

Preliminary geohydrologic assessment of Buenos Aires National Wildlife Refuge, Altar Valley, southeastern Arizona

The Buenos Aires National Wildlife Refuge is located in the southern part of Altar Valley, southwest of Tucson in southeastern Arizona. The primary water-supply well at the Buenos Aires National Wildlife Refuge has experienced a two-decade decrease in groundwater levels in the well, as have other wells in the southern part of Altar Valley. In part to understand this trend, a study was undertaken by the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, to summarize what is known about the geohydrologic system on the refuge and analyze groundwater-level trends and precipitation-groundwater correlations. In addition, available data were compiled where possible on the climate, land cover, soils, geology, and hydrology to provide a foundation for future modeling of the system. Altar Valley is a sedimentary basin bounded by a mixture of Paleozoic to Tertiary sedimentary, volcanic, granitic, and metamorphic rocks. The valley fill is undifferentiated Tertiary to Quaternary sediments underlain by middle Miocene to Pliocene rocks that consist of moderately to strongly consolidated conglomerate and sandstone. Surface water, when present in the predominantly ephemeral streams of the valley, flows from south to north. Arivaca Creek has a cienega (or wetland) where groundwater surfaces before it flows as a short perennial reach out of Arivaca Basin. Groundwater maps compiled between 1934 and 2016 showed groundwater flowing from south to north. Before the 1980s, temporal patterns of groundwater levels in wells in Altar Valley varied substantially from one well to another. In the mid-1980s, comparatively high levels of precipitation occurred: the 1980s median value was 15.3 inches, whereas the median for the period of record was 13.2 inches. In addition, apparently corresponding groundwater level increases were seen in nearly all wells studied. After this initial increase, two different groundwater-level trends began to be observed in two spatially distinct sets of wells: in the northern part, groundwater levels were relatively steady, whereas in the southern part, groundwater levels declined from 10 to 20 feet between 1990 and 2019. Annual groundwater pumpage declined substantially in the northern part of the valley beginning in the early 1980s, but it began to increase again in the 1990s. Pumpage in the southern part has remained low and relatively steady compared to the northern part. Although the precise reasons for the declining groundwater levels in the southern part remain unclear, groundwater levels may be affected by factors such as climate cycles, long-term drought, and temperature-induced declines in recharge, resulting in increased evapotranspiration. Preliminary analyses of two wells, one selected from each part of the valley, using linear regression and lag correlation to investigate correlation between annual precipitation and groundwater levels, showed a maximum correlation at a lag of about 17 years in the southern part of the valley and about 25 years in the northern part, indicating that, although variable sources and traveltimes of recharged water may be needed to propagate to each location, the strongest correlation at each well is with precipitation that was recharged 17 and 25 years prior to the groundwater response in that well. Assuming a constant flow of groundwater from the southern to the northern part of the valley, a decrease in recharge is expected to lead to a decrease in aquifer storage. As to the comparatively stable groundwater levels in the northern part, pumpage is still only about one-half what it was in the early 1980s, even though pumpage has increased there since the 1990s. Water levels in most wells in the northern part were drawn down prior to the decrease in pumping in the early 1980s, possibly owing to a combination of pumping and the nearly 20-year midcentury drought that occurred between 1940 and 1960. Water levels were in the process of recovering when the increase in pumping occurred in the 1990s. Because the water levels were recovering (increasing) instead of remaining static, the increased pumping may have only limited the recovery rather than causing a decrease in water levels, as a new quasi-equilibrium state may have been reached. Additional possible causes for the stable groundwater levels include (1) upgradient aquifer transmissivity that was high enough to offset pumping, (2) a low-permeability barrier, such as bedrock or clay, at the north end of the valley that caused groundwater pooling, (3) higher lateral inflow of groundwater in the northern part of the valley, (4) a delay in the effect of storage declines propagating from the south, or (5) some combination thereof.

Arizona↗

USGS2011

Differential effects of dissolved organic carbon upon re-entrainment and surface properties of groundwater bacteria and bacteria-sized microspheres during transport through a contaminated, sandy aquifer

Injection-and-recovery studies involving a contaminated, sandy aquifer (Cape Cod, Massachusetts) were conducted to assess the relative susceptibility for in situ re-entrainment of attached groundwater bacteria ( Pseudomonas stuzeri ML2, and uncultured, native bacteria) and carboxylate-modified microspheres (0.2 and 1.0 μm diameters). Different patterns of re-entrainment were evident for the two colloids in response to subsequent injections of groundwater (hydrodynamic perturbation), deionized water (ionic strength alteration), 77 μM linear alkylbenzene sulfonates (LAS, anionic surfactant), and 76 μM Tween 80 (polyoxyethylene sorbitan monooleate, a very hydrophobic nonionic surfactant). An injection of deionized water was more effective in causing detachment of micrsopheres than were either of the surfactants, consistent with the more electrostatic nature of microsphere’s attachment, their extreme hydrophilicity (hydrophilicity index, HI, of 0.99), and negative charge (zeta potentials, ζ, of −44 to −49 mv). In contrast, Tween 80 was considerably more effective in re-entraining the more-hydrophobic native bacteria. Both the hydrophilicities and zeta potentials of the native bacteria were highly sensitive to and linearly correlated with levels of groundwater dissolved organic carbon (DOC), which varied modestly from 0.6 to 1.3 mg L −1 . The most hydrophilic (0.52 HI) and negatively charged (ζ −38.1 mv) indigenous bacteria were associated with the lowest DOC. FTIR spectra indicated the latter community had the highest average density of surface carboxyl groups. In contrast, differences in groundwater (DOC) had no measurable effect on hydrophilicity of the bacteria-sized microspheres and only a minor effect on their ζ. These findings suggest that microspheres may not be very good surrogates for bacteria in field-scale transport studies and that adaptive (biological) changes in bacterial surface characteristics may need to be considered where there is longer-term exposure to contaminant DOC.

Environmental Science & Technology↗

USGS1987

Geology and hydrology of the Onondaga aquifer in eastern Erie County, New York, with emphasis on ground-water-level declines since 1982

The Onondaga aquifer is a nearly flat-lying, 25- to 110-foot-thick, cherty limestone with moderately developed karst features such as sinkholes, disappearing streams, and solution-widened joints. Most groundwater moves through solution-widened bedding planes, although some moves through vertical joints. The yield of water from 42 wells ranges from 3 to 100 gal/min, averaging 20 gal/min. Groundwater levels in the Onondaga aquifer declined during the fall of 1981 and summer and fall of 1982-85, near a 2.2-mile-long and 800-foot-wide land surface depression in the eastern part of Erie County. More than 60 wells and several wetlands went dry and at least three sinkholes developed. Groundwater levels were measured in 150 wells during a high water level period in April 1984 and a low water period in October 1984. Water levels fluctuated 20 to 50 ft near the depression and near the quarries but fluctuated only 5 to 10 ft elsewhere. The water level decline was caused by the combined effect of groundwater removal by pumpage from a quarry (the water is then discharged to Dorsch Creek) and by the swallets in the 2.2-mile-long depression area, which are recharge points for the aquifer. In 1982, sinkholes formed in a surface depression area in Harris Hill. The enlargement of these sinkholes seems to be unrelated to the water level decline in the eastern part of the county and is probably caused by local drainage alterations.

New York↗

USGS2005

Radiogenic 4He as a conservative tracer in buried‐valley aquifers

The accumulation of 4 He in groundwater can be a powerful tool in hydrogeologic investigations. However, the use of 4 He often suffers from disagreement or uncertainty related to in situ and external sources of 4 He. In situ sources are quantified by several methods, while external sources are often treated as calibration parameters in modeling. We present data from direct laboratory measurements of 4 He release from sediments and field data of dissolved 4 He in the Mahomet Aquifer, a well‐studied buried‐valley aquifer in central Illinois. The laboratory‐derived accumulation rates (0.13–0.91 μcm 3 STP kg water −1 yr −1 ) are 1–2 orders of magnitude greater than the accumulation rates based on the U and Th concentrations of the sediments (0.004–0.009 μcm 3 STP kg water −1 yr −1 ). The direct measurement of accumulation rates are more consistent with dissolved concentrations of 4 He in the groundwater. We suggest that the direct measurement method is applicable in a variety of hydrogeologic settings. The patterns of accumulation of 4 He are consistent with the conceptual model of flow in the aquifer based on hydraulic and geochemical evidence and show areas where in situ production and external sources of 4 He are dominant. In the southwestern part of the study area, Ne concentrations are less than atmospheric solubility, indicating gases have been lost from the groundwater. Available evidence indicates that the gases are lost as groundwater passes by pockets of CH 4 in glacial deposits overlying the aquifer. However, the external flux from the underlying bedrock appears to dominate the accumulation of radiogenic 4 He in the aquifer in the southwestern part of the study area, and the loss or gain of helium as groundwater passes through the overlying sediments is minor in comparison.

Water Resources Research↗

USGS2012

Hydrogeology of the stratified-drift aquifers in the Cayuta Creek and Catatonk Creek valleys in parts of Tompkins, Schuyler, Chemung, and Tioga Counties, New York

The surficial deposits, areal extent of aquifers, and the water-table configurations of the stratified-drift aquifer systems in the Cayuta Creek and Catatonk Creek valleys and their large tributary valleys in Tompkins, Schuyler, Chemung, and Tioga Counties, New York were mapped in 2009, in cooperation with the New York State Department of Environmental Conservation. Well and test-boring records, surficial deposit maps, Light Detection and Ranging (LIDAR) data, soils maps, and horizontal-to-vertical ambient-noise seismic surveys were used to map the extent of the aquifers, construct geologic sections, and determine the depth to bedrock (thickness of valley-fill deposits) at selected locations. Geologic materials in the study area include sedimentary bedrock, unstratified drift (till), stratified drift (glaciolacustrine and glaciofluvial deposits), and recent alluvium. Stratified drift consisting of glaciofluvial sand and gravel is the major component of the valley fill in this study area. The deposits are present in sufficient amounts in most places to form extensive unconfined aquifers throughout the study area and, in some places, confined aquifers. Stratified drift consisting of glaciolacustrine fine sand, silt, and clay are present locally in valleys underlying the surficial sand and gravel deposits in the southern part of the Catatonk Creek valley. These unconfined and confined aquifers are the source of water for most residents, farms, and businesses in the valleys. A generalized depiction of the water table in the unconfined aquifer was constructed using water-level measurements made from the 1950s through 2010, as well as LIDAR data that were used to determine the altitudes of perennial streams at 10-foot contour intervals and water surfaces of ponds and wetlands that are hydraulically connected to the unconfined aquifer. The configuration of the water-table contours indicate that the general direction of groundwater flow within Cayuta Creek and Catatonk Creek stratified-drift aquifers is predominantly from the valley walls toward the main streams in the valleys. The groundwater discharges from the aquifer system to the main-stem streams in the valleys. Locally, the direction of groundwater flow is radially away from groundwater mounds that have formed beneath upland tributaries that typically lose water where they flow on alluvial fans in the valleys. In some places, groundwater that would normally flow toward streams is intercepted by pumping wells.

New York↗