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Apparent Resistivity and Estimated Interaction Potential of Surface Water and Groundwater along Selected Canals and Streams in the Elkhorn-Loup Model Study Area, North-Central Nebraska, 2006-07

In 2005, the State of Nebraska adopted new legislation that in part requires local Natural Resources Districts to include the effect of groundwater use on surface-water systems in their groundwater management plan. In response the U.S. Geological Survey, in cooperation with the Upper Elkhorn, Lower Elkhorn, Upper Loup, Lower Loup, Middle Niobrara, Lower Niobrara, Lewis and Clark, and Lower Platte North Natural Resources Districts, did a study during 2006-07 to investigate the surface-water and groundwater interaction within a 79,800-square-kilometer area in north-central Nebraska. To determine how streambed materials affect surface-water and groundwater interaction, surface geophysical and lithologic data were integrated at four sites to characterize the hydrogeologic conditions within the study area. Frequency-domain electromagnetic and waterborne direct- current resistivity profiles were collected to map the near-surface hydrogeologic conditions along sections of Ainsworth Canal near Ainsworth, Nebraska; Mirdan and Geranium Canals near Ord, Nebraska; North Loup River near Ord, Nebraska; and Middle Loup River near Thedford, Nebraska. Lithologic data were collected from test holes at each site to aid interpretation of the geophysical data. Geostatistical analysis incorporating the spatial variability of resistivity was used to account for the effect of lithologic heterogeneity on effective hydraulic permeability. The geostatistical analysis and lithologic data descriptions were used to make an interpretation of the hydrogeologic system and derive estimates of surface-water/groundwater interaction potential within the canals and streambeds. The estimated interaction potential at the Ainsworth Canal site and the Mirdan and Geranium Canal site is generally low to moderately low. The sediment textures at nearby test holes typically were silt and clay and fine-to-medium sand. The apparent resistivity values for these sites ranged from 2 to 120 ohm-meters. The vertical and horizontal variability of the apparent resistivity data were consistently low. Low resistive variability indicates little lithologic heterogeneity for either canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the narrow frequency distribution of resistivity, low apparent resistivities, low spatial heterogeneity, and test-hole grain-size ranges. The estimated surface-water/groundwater interaction potential at the North Loup and Middle Loup River sites is moderate to moderately high. The sediment textures at nearby test holes were predominantly fine, medium, and coarse sand with some silt and silty to sandy clay. The apparent resistivity values for these sites ranged from 34 to 1,338 ohm-meters. The vertical variability of the resistivity data was moderately high. The horizontal variability at these sites is low to moderately low. The higher resistive variability at these sites indicates generally greater lithologic heterogeneity than at either the Ainsworth Canal site or the Mirdan and Geranium Canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the generally moderate to high apparent resistivity, the greater spatial heterogeneity, and the variable lithologic texture. A higher interaction potential as compared to the canal sites is expected because of the higher subsurface resistivity and greater lithologic heterogeneity.

Scientific Investigations Report↗

Surface infiltration and unsaturated zone characterization in support of managed aquifer recharge in Bedell Flat, Washoe County, Nevada

Aquifer storage and recovery (ASR) expands the portfolio of public water supply and improves resiliency to drought and future water demand. This study investigated the feasibility of ASR in the Bedell Flat Hydrographic Area using land-based methods including in-channel managed aquifer recharge (MAR) and rapid infiltration basins (RIB). Bedell Flat, one of two flow-through groundwater basins near Reno, Nevada, was a likely candidate for ASR because of its deep basin fill, proximity to supplemental water sources and infrastructure, and lack of development. In-channel MAR feasibility was determined from seepage losses along the Bird Springs ephemeral channel measured using Parshall flumes and heat-as-a-tracer inverse modeling. The feasibility of RIB was evaluated by characterizing vadose zone boreholes installed with roto-sonic drilling to water table. Field characterization of sediment and lithologic descriptions was accomplished at 1-foot (ft) increments. Bulk sediment samples were collected every 5 ft and cores from a split spoon were sampled at 10, 20, 30, 40, 60 and 100 ft below land surface (bls). Collected samples were analyzed for texture, moisture content, and geochemistry. Infiltration rates in Bird Springs channel increased downgradient with the hydraulic conductivity of the upper reaches ranging from 0.002 to 0.14 meter per hour (m/h) and the lower reaches from 0.5 to 1.5 m/h. Differences in discharge measurements indicate that seepage losses also increase down channel. When normalized to 1 ft of channel stage, modeled seepage loss rates ranged from 0.02 to 5.34 cubic feet per second (ft 3 /s) per mile (mi). Perched zones of soil moisture residing on top of dry fine-textured, clay-rich layers were prevalent in the Bird Springs drainage, indicating complicated flow paths for any supplement recharge water. Characterization of boreholes in Bird Springs drainage indicates low permeability clay layers 1–10 ft thick interbedded within extensive, grussy sands of high permeability. The presence of low permeability clay layers (1–10 ft thick) prompted a shift in analysis to the adjacent Sand Hills drainage where four additional boreholes indicated fewer perched water zones and at greater depths. Nitrates in the sediment pore-water (a condition that would discourage ASR) were integrated with depth to the aquifer 180 ft bls. Wells BF-MW-04 (Bird Springs) and BF-MW-07 (Sand Hills) contained 4,270 and 2,436 kilograms per hectare of nitrogen, respectively, which could potentially load excessive nitrogen to a receiving aquifer. An economically viable ASR project requires a minimum input of 2 million gallons per day (approximately 3 ft 3 /s), which either channel appears to have the sufficient capacity to infiltrate such a volume before reaching the valley bottom of Bedell Flat. However, the trajectory of the infiltrated water is complicated by the lithology and lateral transmissivity of the underlying sediments. There is also concern that this volume of infiltrated water may cause undesirable groundwater levels at the outflow in less than 5 years.

Nevada↗

Integrated assessment of chemical and biological recovery after diversion and treatment of acid mine drainage in a Rocky Mountain stream

Responses of stream ecosystems to gradual reductions in metal loading following remediation or restoration activities have been well documented in the literature. However, much less is known about how these systems respond to the immediate or more rapid elimination of metal inputs. Construction of a water treatment plant on the North Fork of Clear Creek (NFCC; CO, USA), a US Environmental Protection Agency Superfund site, captured, diverted, and treated the two major point-source inputs of acid mine drainage (AMD) and provided an opportunity to investigate immediate improvements in water quality. We conducted a 9-year study that included intensive within- and among-year monitoring of receiving-stream chemistry and benthic communities before and after construction of the treatment plant. Results showed a 64%–86% decrease in metal concentrations within months at the most contaminated sites. Benthic communities responded with increased abundance and diversity, but downstream stations remained impaired relative to reference conditions, with significantly lower taxonomic richness represented by a few dominant taxa (i.e., Baetis sp., Hydropsyche sp., Simulium sp., Orthocladiinae). Elevated metal concentrations from apparent residual sources, and relatively high conductivity from contributing major ions not removed during the treatment process, are likely limiting downstream recovery. Our study demonstrates that direct AMD treatment can rapidly improve water quality and benefit aquatic life, but effectiveness is limited, in part, to the extent that inputs of metals are captured and treated. Consideration should also be given to the effects of elevated major ion concentrations from the treated effluent not removed during the lime treatment process. Continued chemical and biological monitoring will be needed to quantify the NFCC recovery trajectory and to inform future remediation strategies.

Colorado↗

Geohydrology of the alluvial and terrace deposits of the North Canadian River from Oklahoma City to Eufaula Lake, central Oklahoma

This investigation was undertaken to describe the geohydrology of the alluvial and terrace deposits along the North Canadian River between Lake Overholser and Eufaula Lake, an area of about 1,835 square miles, and to determine the maximum annual yield of ground water. A 1982 water-level map of the alluvial and terrace aquifer was prepared using field data and published records. Data from test holes and other data from the files of the U.S. Geological Survey and the Oklahoma Water Resources Board were used to establish the approximate thickness of the alluvial and terrace deposits. The North Canadian River from Lake Overholser, near Oklahoma City, to Eufaula Lake is paralleled by a 2- to 3-mile wide band of alluvium. Scattered terrace deposits on either side of the alluvium reach an extreme width of 8 miles. Rocks of Permian age bound the alluvial and terrace deposits from the west to the midpoint of the study area; Pennsylvanian rocks bound the alluvial and terrace deposits from that point eastward. Three major aquifers are present in the study area: the alluvial and terrace aquifer, consisting of alluvium and terrace deposits of Quaternary age in a narrow band on either side of the North Canadian River; the Garber-Wellington aquifer of Permian age, consisting of an upper unconfined zone and a lower confined zone separated by relatively impermeable shales; and the Ada-Vamoosa aquifer of Pennsylvanian age. At locations were the alluvial and terrace aquifer overlies either of the other aquifers, there is hydraulic continuity between the alluvial and terrace aquifer and the other aquifers, and water levels are the same. Most large-scale municipal and industrial pumping from the Garber-Wellington aquifer is from the lower zone and has little discernible effect upon the alluvial and terrace aquifer. The total estimated base flow of the North Canadian River for the studied reach is 264 cubic feet per second. Evapotranspiration from the basin in August is about 60 cubic feet per second for the North Canadian River from Lake Overholser to a measuring station above Eufaula Lake. Estimated recharge rates to the alluvial and terrace aquifer in the basin range from 1.7 inches at the west edge of the study area to 7.0 inches at the east edge. Total permitted withdrawal from the aquifer, according to records of the Oklahoma Water Resources Board, ranged from 2,107 acre-feet per year in 1942 to about 21,415 acre-feet per year in 1982. Simulations of the alluvial and terrace aquifer from Lake Overholser to Eufaula Lake were made using a finite-difference model developed by McDonald and Harbaugh (1984). The area of the aquifers was subdivided into a finite-difference grid having 30 rows and 57 columns with cells measuring 1 mile in the north-south direction and 2 miles in the east-west direction. The model was calibrated in two steps: A steady-state calibration simulated head distribution prior to extensive pumping of the aquifer in 1942, and a transient calibration simulated head distribution after extensive pumpage. The final horizontal hydraulic conductivity used for the alluvial and terrace aquifer was 0.0036 feet per second (310 feet per day) at all locations. The recharge rate for the alluvial and terrace aquifer ranged from 1.7 inch per year in the west to 7.0 inches per year in the east, and averaged about 3.3 inches per year. A specific yield of 15 percent was used for the transient simulation. Permitted pumpage for 1942 through 1982 was used in the digital model to estimate the annual volume of water in storage in the alluvial and terrace aquifer for the years for this time period. The 1982 permitted pumpage rates were used for projections for 1983 to 2020. The estimated volume of water in storage was 1,940,000 acre-feet in 1982. Because the estimated recharge rate is equal to the allowed pumpage rate in 1982, the projected volume of water in storage in both 1993 and 2020 was 1,890,000 acre-feet.

Water-Resources Investigations Report↗

Comparison of U.S. Geological Survey and Bureau of Reclamation water-use reporting in the Colorado River Basin

The use of water in the United States is arguably one of the most important factors determining water availability at any specific place and time. Numerous local, State, and Federal entities develop, compile, and report water-use data, which can lead to confusing or conflicting information. This report was authored jointly by the U.S. Geological Survey (USGS) and Bureau of Reclamation (Reclamation) to compare and contrast the two agencies’ water-use information programs in the Colorado River Basin. The report also describes the legal drivers for each program, clarifies confusing terminology, compares the methods used, and contrasts the information reported by each agency. This detailed comparison demonstrates that these two Federal agencies have different missions, different programmatic drivers, and different user communities, all of which lead to different approaches to water-use data collection, analysis, and reporting. This report highlights those differences and explains why the USGS and Reclamation programs exist and how the data serve different user communities. Even though the two water-use programs are different by design and purpose, the program comparison presented in this report has identified opportunities for closer coordination and sharing of information between the USGS and Reclamation, as well as program components where agency collaboration can improve water-use estimate methodologies. This comparison effort emphasizes that it is incumbent upon each agency to clearly define the meaning of the terms used and the appropriate application of the reported information to avoid confusion or the accidental misuse of the information. An additional benefit of this comparison effort is the formation of a joint USGS/Reclamation water-use team that will continue to investigate opportunities to expand and coordinate future water-use data compilation and reporting.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Ground water stratification and delivery of nitrate to an incised stream under varying flow conditions

Ground water processes affecting seasonal variations of surface water nitrate concentrations were investigated in an incised first-order stream in an agricultural watershed with a riparian forest in the coastal plain of Maryland. Aquifer characteristics including sediment stratigraphy, geochemistry, and hydraulic properties were examined in combination with chemical and isotopic analyses of ground water, macropore discharge, and stream water. The ground water flow system exhibits vertical stratification of hydraulic properties and redox conditions, with sub-horizontal boundaries that extend beneath the field and adjacent riparian forest. Below the minimum water table position, ground water age gradients indicate low recharge rates (2-5 cm yr-1) and long residence times (years to decades), whereas the transient ground water wedge between the maximum and minimum water table positions has a relatively short residence time (months to years), partly because of an upward increase in hydraulic conductivity. Oxygen reduction and denitrification in recharging ground waters are coupled with pyrite oxidation near the minimum water table elevation in a mottled weathering zone in Tertiary marine glauconitic sediments. The incised stream had high nitrate concentrations during high flow conditions when much of the ground water was transmitted rapidly across the riparian zone in a shallow oxic aquifer wedge with abundant outflow macropores, and low nitrate concentrations during low flow conditions when the oxic wedge was smaller and stream discharge was dominated by upwelling from the deeper denitrified parts of the aquifer. Results from this and similar studies illustrate the importance of near-stream geomorphology and subsurface geology as controls of riparian zone function and delivery of nitrate to streams in agricultural watersheds.

Maryland↗

Hydrogeologic investigation of the Malvern TCE Superfund Site, Chester County, Pennsylvania

The Malvern TCE Superfund Site, a former solvent recycling facility that now stores and sells solvents, consists of a plant and disposal area, which are approximately 1,900 ft (feet) apart. The site is underlain by an unconfined carbonate bedrock aquifer in which permeability has been enhanced in places by solution. Water levels respond quickly to precipitation and show a similar seasonal variation, response to precipitation, and range of fluctuation. The altitude of water levels in wells at the disposal area is nearly identical because of the small hydraulic gradient. A comparison of water-table maps for 1983, 1993, and 1994 shows that the general shape of the water table and hydraulic gradients in the area have remained the same through time and for different climatic conditions. The plant area is underlain by dolomite of the Elbrook Formation. The dolomite at the plant area does not yield as much water as the dolomite at the disposal area because it is less fractured, and wells penetrate few water-bearing fractures. Yields of nine wells at the plant area range from 1 to 200 gal/min (gallons per minute); the median yield is 6 gal/min. Specific capacities range from 0.08 to 2 (gal/min)/ft (gallons per minute per foot). Aquifer tests were conducted in two wells; median transmissivities estimated from the aquifer-test data ranged from 528 to 839 feet squared per day. Maximum concentrations of volatile organic compounds (VOC's) in ground water at the plant area in 1996 were 53,900 ug/L (micrograms per liter) for trichloroethylene (TCE), 7,110 ug/L for tetrachloroethylene (PCE), and 17,700 ug/L for 1,1,1-trichloroethane (TCA). A ground-water divide is located between the plant area and the disposal area. Ground-water withdrawal for dewatering the Catanach quarry has caused a cone of depression in the water-table surface that reaches to the plant area. From the plant area, ground water flows 1.2 miles to the northeast and discharges to the Catanach quarry. The regional hydraulic gradient between the plant and the Catanach quarry is 0.019. Concentrations of VOC's in water from wells drilled northeast and donwgradient of the plant property boundary are one to two orders of magnitude less than concentrations in water from wells less than 100 ft away at the plant. A capture-zone analysis was performed for two wells at the plant area. The analysis showed that pumping well CC-19 at 20 gal/min would be sufficient to capture all ground-water flow from the plant area. Although water from other wells at the plant site contains higher concentrations of VOC's than water from well CC-19, pumping well CC-19 would induce the flow of water with higher concentrations of VOC's; however, pumping well CC-19 might causes VOC's to move lower into the aquifer. The disposal area is underlain by the Ledger Dolomite. The dolomite at the disposal area is much more fractured than the dolomite at the plant area. Although many of the fractures are filled or partially filled with clay, the dolomite at the disposal area yields more water than the dolomite at the plant area. Yields of eight wells at the disposal area range from 15 to more than 200 gal/min; the median yield is greater than 100 gal/min. Specific capacities range from 2 to 280 (gal/min)/ft. Aquifer tests were conducted in two wells; estimated transimissivities were 34,900 and 56,300 feet squared per day. Concentrations of VOC's in ground water are lower at the disposal area than at the plant area. Water samples collected from wells at the disposal area in 1996 had maximum concentrations of TCE of 768 ug/L, PCE of 111 ug/L, and TCA of 108 ug/L. These concentrations are lower than concentrations in water samples collected before cleanup of drums in the disposal area was completed in 1984. Ground water from the disposal area flows south-southeast toward Valley Creek. The hydraulic gradient between the disposal area and Valley Creek is 0.001. A well-defined plume of VOC’s in ground water extends downgradient from the disposal area toward Valley Creek. A comparison of data from 1995 to 1996 with data from 1981 to 1984 shows that concentrations of TCE, PCE, and TCA in water from most off-site wells have decreased and that water from fewer wells contains detectable concentrations of those compounds. A capture-zone analysis was performed for three wells at the disposal area. The analysis showed that pumping wells CC-16, CC-17, and CC-18 at a combined rate of 270 gal/min would form a capture zone ranging from approximately 443 to 477 ft wide at a distance 500 ft upgradient from the center of the pumping wells. Pumping wells CC-16 and CC-17 together at a combined rate of 172 gal/min would form a capture zone ranging from approximately 172 to 400 ft wide at a distance 500 ft upgradient from the center of the pumping wells.

Pennsylvania↗

Investigation of the distribution of organochlorine and polycyclic aromatic hydrocarbon compounds in the Lower Columbia River using semipermeable-membrane devices

Organochlorine and polycyclic aromatic hydrocarbon compounds are of concern in the Columbia River Basin because of their adverse effects on fish and wildlife. Because these compounds can have important biological consequences at concentrations well below the detection limits associated with conventional water-sampling techniques, we used semipermeable membrane devices (SPMDs) to sample water, and achieved sub-parts-per-quintillion detection limits. We deployed SPMDs during 1997 low-flow conditions and 1998 high-flow conditions at nine main-stem sites and seven tributary sites, spanning approximately 700 miles of the Columbia River. We also collected streambed sediment from three sites. SPMD extracts and sediments were analyzed for polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, polychlorinated biphenyls, organochlorine pesticides and related transformation products, and polycyclic aromatic hydrocarbons. Our data indicate that (1) in the absence of additional sources, mechanisms such as volatilization, dilution, and settling of suspended particles can act to significantly reduce concentrations of contaminants along the river's flow path, (2) elevated concentrations of contaminants in the Portland-Vancouver area are primarily from local rather than upstream sources, (3) elevated concentrations of many compounds tend to be diluted during periods of high discharge, (4) much higher discharge in the main stem considerably dilutes elevated concentrations entering from tributaries, (5) the distribution of hydrophobic organic compounds in streambed sediment is not necessarily indicative of their distribution in the dissolved-phase, and (6) SPMDs can reveal patterns of contaminant occurrence at environmentally relevant concentrations that are undetectable by conventional water-sampling techniques.

Oregon↗

Nitrate and ammonia in shallow ground water, Carson City urban area, Nevada, 1989

As part of the National Water-Quality Assessment program (NAWQA) of the U.S. Geological Survey, a network of 26 wells at 20 sites was established in 1989 to investigate the quality of shallow ground water beneath the oldest and most developed part of the Carson City urban area. Nitrate was detected in water samples from 16 of the sites. The nitrate, as nitrogen, concentration was between 0.1 and 3.0 mg/L (milligrams per liter) at four sites, greater than 3.0 mg/L but less than 10 mg/L at six sites, and 10 mg/L, the Nevada drinking-water standard, or greater, at six sites; the highest concentration measured during the study was 38 mg/L. Ammonia, as nitrogen, concentrations exceeded 0.15 mg/L at 2 of the 20 sites; the highest concentration detected during the study was 0.26 mg/L. Nitrate concentrations were positively correlated with dissolved-oxygen concentrations, and negatively correlated with ammonia, dissolved-iron, and dissolved-manganese concentrations. Ammonia concentrations were positively correlated with calcium, magnesium, potassium, bicarbonate, iron, manganese, strontium, and dissolved organic carbon concentrations, and were negatively correlated with nitrate and dissolved-oxygen concentrations. Principal components analysis identified five groups of water quality constituents that suggest that the ammonia or nitrate source might be nitrogen-based fertilizers, septic systems, or leaking municipal sewer lines, and that nitrification and denitrification, or nitrate reduction, control nitrate and ammonia concentrations as well as dissolved-oxygen, iron, and manganese concentrations in the shallow ground water beneath the Carson City urban area.

Nevada↗

Detection and quality of previously undetermined Floridan aquifer system discharge to the St. Johns River, Jacksonville, to Green Cove Springs, northeastern Florida

Potentiometric surface maps of the Upper Floridan aquifer show two depressions around the St. Johns River frm the city of Jacksonville south toward Green Cove Springs. These depressions, depending on their locations, are the result of withdrawals from agricultural, industrial, domestic and public-supply wells, diffuse upward leakage, and discharge from springs. Submerged springs that discharge into the St. Johns River between Jacksonville and Green Cove Springs have been thought to exist, but locating and evaluating these springs had not been attempted before this investigation. Thermal infrared imagery, seismic reflection, and numerous interviews with local residents were used to locate springs. An airborne thermal infrared survey was conducted along a section of the St. Johns River in northeastern Florida during February 1992 to detect possible sources of ground-water discharge to the river. An infrared image displayed one thermal anomaly in the St. Johns River which is associated with a previously unknown spring discharge from the Floridan aquifer system. Thermal anomalies also were observed at six locations where municipal facilities discharge treated wastewater to the river. Results of seismic reflection surveys indicate the presence of collapse and other karst features underlying the St. Johns River. These features indicate that the surficial deposits and the Hawthorn Formation that underlie the river probably do not consist of continuous beds. The collapse or deformation of the Hawthorn Formation or the presence of permeable sediment of localized extent could create zones of relatively high vertical leakance. This could provide a more direct hydraulic connection between the Upper Floridan aquifer and the river. Water samples collected from the only submerged spring in the St. Johns River within the Jacksonville-Green Cove Springs reach indicate that the source of the water is the Floridan aquifer system. Chloride and sulfate concentrations were 12 and 340 milligrams per liter, respectively. Specific conductance was 826 microsiemens per centimeter and the temperature of the water discharging from the spring was 25.1 degrees Celsius. The ratio of 87 Strontium/86 Strontium also indicates that the springwater has been in contact with rock materials of Eocene age, providing additional evidence that the springwater is derived from the Floridan aquifer system.

Water-Resources Investigations Report↗

Development and evaluation of clear-water pier and contraction scour envelope curves in the Coastal Plain and Piedmont Provinces of South Carolina

The U.S. Geological Survey in cooperation with the South Carolina Department of Transportation collected clear-water pier- and contraction-scour data at 116 bridges in the Coastal Plain and Piedmont Physiographic Provinces of South Carolina. Pier-scour depths collected in both provinces ranged from 0 to 8.0 feet. Contraction-scour depths collected in the Coastal Plain ranged from 0 to 3.9 feet. Using hydraulic data estimated with a one-dimensional flow model, predicted clear-water scour depths were computed with scour equations from the Federal Highway Administration Hydraulic Engineering Circular 18 and compared with measured scour. This comparison indicated that predicted clear-water scour depths, in general, exceeded measured scour depths and at times were excessive. Predicted clear-water contraction scour, however, was underpredicted approximately 30 percent of the time by as much as 7.1 feet. The investigation focused on clear-water pier scour, comparing trends in the laboratory and field data. This comparison indicated that the range of dimensionless variables (relative depth, flow intensity, relative grain size) used in laboratory investigations of pier scour, were similar to the range for field data in South Carolina, further indicating that laboratory relations may have some applicability to field conditions in South Carolina. Variables determined to be important in developing pier scour in laboratory studies were investigated to understand their influence on the South Carolina field data, and many of these variables appeared to be insignificant under field conditions in South Carolina. The strongest explanatory variables were pier width and approach velocity. Envelope curves developed from the field data are useful tools for evaluating reasonable ranges of clear-water pier and contraction scour in South Carolina. A modified version of the Hydraulic Engineering Circular 18 pier-scour equation also was developed as a tool for evaluating clearwater pier scour. The envelope curves and modified equation offer an improvement over the current methods for predicting clear-water scour in South Carolina. Data from this study were compiled into a database that includes photographs, measured scour depths, predicted scour depths, limited basin characteristics, limited soil data, and modeled hydraulic data. The South Carolina database can be used to compare studied sites with unstudied sites to evaluate the potential for scour at the unstudied sites. In addition, the database can be used to evaluate the performance of various methods for predicting clear-water pier and contraction scour.

South Carolina↗

Ground water in the Blanchard area, McClain County, Oklahoma

A letter from Lloyd L. Bowser, City Clerk, dated January 8, 1948, in behalf of the town council and Mayor Walter Casey, indicates that a serious shortage of water is faced by the town of Blanchard, McClain County, Oklahoma. The town is near the eastern boundary of Grady County, where an investigation of the ground-water resources is being made by the Oklahoma Geological Survey in cooperation with the U.S. Geological Survey as part of a State-wide investigation. Information obtained thus far may aid the town by showing where additional ground water for municipal supply may be sought.

Oklahoma↗

Water-chemistry data collected in and near Kaloko-Honokohau National Historical Park, Hawaii, 2012–2014

Kaloko-Honokōhau National Historical Park (KAHO) on western Hawaiʻi was established in 1978 to preserve, interpret, and perpetuate traditional Native Hawaiian culture and activities, including the preservation of a variety of culturally and ecologically significant water resources that are vital to this mission. KAHO water bodies provide habitat for 1 threatened, 11 endangered, and 3 candidate threatened or endangered species. These habitats are sustained by, and in the case of ʻAimakapā Fishpond and the anchialine pools, entirely dependent on, groundwater from the Keauhou aquifer system. Development of inland impounded groundwater in the Keauhou aquifer system may affect the coastal freshwater-lens system on which KAHO depends, if the inland impounded-groundwater and coastal freshwater-lens systems are hydrologically connected. This report documents water-chemistry results from a U.S. Geological Survey study that collected and analyzed water samples from 2012 to 2014 from 25 sites in and near KAHO to investigate potential geochemical indicators in water that might indicate the presence or absence of a hydrologic connection between the inland impounded-groundwater and coastal freshwater-lens systems in the area. Samples were collected under high-tide and low-tide conditions for KAHO sites, and in dry-season and wet-season conditions for all sites. Samples were collected from two ocean sites, two fishponds, three anchialine pools, and three monitoring wells within KAHO. Two additional nearshore wells were sampled on property adjacent to and north of KAHO. Additional samples from the freshwater-lens system were collected from six inland wells located upslope from KAHO, including three production wells. Seven production wells in the inland impounded-groundwater system also were sampled. Water samples were analyzed for major ions, selected trace elements, rare-earth elements, strontium-isotope ratio, and stable isotopes of water. Precipitation samples from five sites were collected roughly along a transect upslope from KAHO. All precipitation samples were analyzed for stable isotopes of water and some precipitation samples were analyzed for rare-earth and selected trace elements.

Hawai'i↗

Occurrence and distribution of nitrate and herbicides in the Iowa River alluvial aquifer, Iowa: May 1984 to November 1985

From May 1984 to November 1985, the U.S. Geological Survey, in cooperation with the University of Iowa Hygienic Laboratory and the Iowa Department of Natural Resources, Geological Survey Bureau, investigated nitrate and herbicides in the Iowa River alluvial aquifer. The occurrence and distribution of nitrate and selected herbicides were determined in the Iowa River alluvial aquifer, a sand and gravel aquifer beneath agricultural land along the Iowa River in Iowa County, Iowa. Test drilling and water-quality sampling of the aquifer indicated that the areal distribution of nitrate in the aquifer is variable. Nitrate (as nitrogen) concentrations range from less than 0.10 to 79 milligrams per liter. Although nitrate distribution is variable, extensive aquifer contamination by nitrate is not apparent. Median nitrate concentrations were 5.9 milligrams per liter for municipal wells and 7.2 milligrams per liter for area streams, but were less than 2.0 milligrams per liter for test wells and domestic wells. Atrazine, cyanazine, metribuzin, alachlor, metolachlor, and trifluralin were detected in ground-water samples. Maximum concentration of atrazine in ground-water samples was 2.4 micrograms per liter; maximum concentration of metribuzin was 8.1 micrograms per liter. Area streams also contained herbicides in concentrations generally larger than concentrations in ground water. At a municipal well adjacent to a stream, similar seasonal concentrations of atrazine were detected for both ground- and surface-water samples. Surface water sometimes may be a source of nitrate and herbicides to adjacent ground water. Detailed sampling of vertical profiles using well nests indicated that the distribution of nitrate and selected herbicides is not vertically homogeneous. Generally, larger nitrate concentrations were detected at shallow depths in the aquifer; at greater depths, the nitrate concentrations were near the detection limit. Herbicides were detected in a pattern similar to that determined for nitrate. The true areal distribution of nitrate may be masked by inconsistent depths of sampling or incomplete vertical sampling. Variations in nitrate concentrations with depth possibly are because local aquifer flow is predominantly horizontal and may limit significant vertical dispersion of nitrate and herbicides, and because nitrate may not act conservatively in ground water and may be removed from the system by denitrification. For nested wells, the seasonal variations of nitrate and herbicides were greater at the shallower sampling depths for domestic and test wells. Seasonal variations of nitrate and herbicides illustrate that these constituents move quickly from surface application to shallow underlying aquifers. These constituents can be detected in ground water soon after chemical applications, usually within 6 weeks.

Iowa↗

Use of water by bottom-land vegetation in lower Safford Valley, Arizona

Lower Safford Valley, Graham County, Ariz., is an alluvial lowland plain 1 to 3 measurements, and the rate of ground-water inflow to the bottom-land area was determined on the basis of the hydraulic gradient, of the water table at. the time of each set of seepage measurements, the transmissibility of the aquifer, and the length of the reach. Although the methods differed greatly, the figure for use of ground water computed by each method was within 20 percent of the mean determined by averaging the results of all six methods. As a part of the investigation, the quality of the waters of lower Safford Valley was studied in detail. The quality-of-water studies included more than 5,000 analyses of surface and ground waters. These analyses showed that surface waters of the area contain 250 to about 6,000 parts per million of dissolved solids and that ground waters contain 200 to more than 10,000 parts per million. The waters of low dissolved-solids concentration contain mostly sodium or calcium and bicarbonate. Highly mineralized waters contain mostly sodium and chloride. Based on the results obtained by the six methods, the total use of water by vegetation during the 12-month period ending September 30, 1944, was 28,000 acre-feet in a total of 9,303 acres in the 46-mile reach of Gila River from Thatcher to Calva. As precipitation and runoff were subnormal in most of the period of the investigation, it is possible that the total use of water in other years may exceed 28,000 acre-feet. Of the total water used, 23,000 acre-feet was derived frown the ground-water reservoir, and the remainder was derived from precipitation on the area. Of the 23,000 acre-feet, more than 75 percent was used by saltcedar.

Water Supply Paper↗

Mercury and methylmercury in reservoirs in Indiana

Mercury (Hg) is an element that occurs naturally, but evidence suggests that human activities have resulted in increased amounts being released to the atmosphere and land surface. When Hg is converted to methylmercury (MeHg) in aquatic ecosystems, MeHg accumulates and increases in the food web so that some fish contain levels which pose a health risk to humans and wildlife that consume these fish. Reservoirs unlike natural lakes, are a part of river systems that are managed for flood control. Data compiled and interpreted for six flood-control reservoirs in Indiana showed a relation between Hg transport, MeHg formation in water, and MeHg in fish that was influenced by physical, chemical, and biological differences among the reservoirs. Existing information precludes a uniform comparison of Hg and MeHg in all reservoirs in the State, but factors and conditions were identified that can indicate where and when Hg and MeHg levels in reservoirs could be highest. As part of a statewide monitoring network for Hg and MeHg in Indiana streams, 66 water samples were collected from four reservoir tailwater sites (downstream near the dams) on a quarterly schedule for 5 years. The reservoirs were Brookville Lake, Cagles Mill Lake, J. Edward Roush Lake, and Mississinewa Lake. Particulate-bound Hg concentrations were significantly lower in tailwater samples than in samples from free-flowing streams in the statewide network. (Free-flowing streams were not affected by dams and were not upstream from these reservoirs.) These data indicated the reduced flow velocity of water upstream from dams was allowing particulate-bound Hg to settle out of the water in the reservoir pools. The concentration ratios of MeHg to Hg were significantly higher in the tailwater samples than in samples from free-flowing streams, and the MeHg to Hg ratios were significantly higher in summer than in other seasons. To evaluate the conditions related to MeHg formation, pools of three reservoirs (Brookville Lake, Monroe Lake, and Patoka Lake) were investigated during summer hydrologic conditions. Water temperature and dissolved oxygen were measured from the water surface to the lake bottom at 10 to 17 transects across each reservoir to identify three thermal strata, defined by water temperature, dissolved oxygen concentration, and depth. Depth-specific water samples were collected from these thermal strata throughout each reservoir, from the headwaters to the dam and from the tailwater. Mercury concentrations higher than 0.04 nanogram per liter (ng/L) were detected in all 53 samples, and MeHg concentrations higher than 0.04 ng/L were detected in 53 percent of the samples. The investigation found a zone of water below 8 or 9 meters, with temperatures less than 18 degrees Celsius and dissolved oxygen less than 3.5 milligrams per liter, extending through nearly half the reservoir area in Monroe Lake and Patoka Lake. This zone had abundant dissolved MeHg and concentration ratios of dissolved MeHg to Hg that ranged from 25 to 82 percent. This zone also had water with pH less than 7 and decreased dissolved sulfate, conditions indicating sulfate reduction by microorganisms that promoted a high potential for the conversion of Hg to MeHg. Reservoir outflow came from this zone at Monroe Lake and contributed to a tailwater concentration ratio for dissolved MeHg to Hg of 56 percent. Reservoir outflow at Patoka Lake was not from this zone, and dissolved MeHg was not detected in the tailwater. In contrast, samples from the summer pool at Brookville Lake had no MeHg detections even though Hg was detected, probably because the water pH higher than 7 inhibited sulfate reduction and did not promote the conversion of Hg to MeHg. Mercury and MeHg concentrations and the concentration ratios of MeHg to Hg in water varied among the six reservoirs in Indiana, and the differences were related to a combination of factors that could apply to other reservoirs. In areas with moderate to high rates of atmospheric Hg wet and dry deposition, Hg runoff and transport to streams and reservoirs was potentially highest for reservoirs with heavily forested watersheds in steep terrains of near-surface bedrock. Methylmercury concentrations and concentration ratios of MeHg to Hg were highest for reservoirs with the longest summer pools and highest inflow-to-outflow retention times, where water-chemistry conditions favoring sulfate reduction promoted conversion of Hg to MeHg. Methylmercury (reported as Hg) in fish-tissue samples collected for the State fish consumption advisory program was used to describe MeHg food-web accumulation and magnification in the reservoirs. The highest percentages of fish-tissue samples with Hg concentrations that exceeded the criterion of 0.30 milligram per kilogram for protection of human health were from Monroe Lake (38 percent) and Patoka Lake (33 percent). A review of the number and size of fish species caught from these two reservoirs resulted in two implications for fish consumption by humans. First, the highest numbers of fish harvested for potential human consumption were species more likely to have MeHg concentrations lower than the human-health criterion (crappie, bluegill, and catfish). Second, although largemouth bass were likely to have MeHg concentrations higher than the human-health criterion, they were caught and released more often than they were harvested. However, the average size largemouth bass (in both reservoirs) and above-average size walleye (in Monroe Lake) that were harvested for potential human consumption were likely to have MeHg concentrations higher than the human-health criterion.

Indiana↗

Groundwater quality data for the Tahoe-Martis study unit, 2007: Results from the California GAMA Program

Groundwater quality in the approximately 460-square-mile Tahoe–Martis study unit was investigated in June through September 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within the Tahoe–Martis study unit (Tahoe–Martis) and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 52 wells in El Dorado, Placer, and Nevada Counties. Forty-one of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 11 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N -nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, strontium isotope ratio, and stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 240 constituents and water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at 12 percent of the wells, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate of compliance or noncompliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from the Tahoe–Martis wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides) were detected in about 40 percent of the samples from grid wells, and most concentrations were less than 1/100th of regulatory and nonregulatory health-based thresholds, although the conentration of perchloroethene in one sample was above the USEPA maximum contaminant level (MCL-US). Concentrations of all trace elements and nutrients in samples from grid wells were below regulatory and nonregulatory health-based thresholds, with five exceptions. Concentrations of arsenic were above the MCL-US in 20 percent of the samples from grid wells. Gross alpha particle activity (MCL-US), boron (CDPH notification level, NL-CA), and molybdenum (USEPA lifetime health advisory, HAL-US) were each detected above thresholds in two of the samples from grid wells, and radon (proposed alternative MCL-US) was detected above the threshold in one sample from a grid well. Most of the samples from Tahoe–Martis grid wells had concentrations of major elements, total dissolved solids, and trace elements below the CDPH secondary maximum contaminant levels, nonenforceable thresholds set for aesthetic and technical concerns. Fifteen percent of the samples from grid wells contained iron, manganese, or total dissolved solids at concentrations above these levels.

California, Nevada↗

Groundwater-quality data in the Madera-Chowchilla study unit, 2008: Results from the California GAMA Program

Groundwater quality in the approximately 860-square-mile Madera–Chowchilla study unit (MADCHOW) was investigated in April and May 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within MADCHOW, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 35 wells in Madera, Merced, and Fresno Counties. Thirty of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and five more were selected to provide additional sampling density to aid in understanding processes affecting groundwater quality (flow-path wells). Detection summaries in the text and tables are given for grid wells only, to avoid over-representation of the water quality in areas adjacent to flow-path wells. Groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], low-level 1,2-dibromo-3-chloropropane [DBCP] and 1,2-dibromoethane [EDB], pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds), constituents of special interest (N-nitrosodimethylamine [NDMA], perchlorate, and low-level 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), and radioactive constituents (uranium isotopes, and gross alpha and gross beta particle activities). Naturally occurring isotopes and geochemical tracers (stable isotopes of hydrogen, oxygen, and carbon, and activities of tritium and carbon-14), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, approximately 300 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at approximately 11 percent of the wells sampled for each analysis, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from MADCHOW wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides) were detected in about 40 percent of the samples from grid wells, and most concentrations were less than 1/100 of regulatory or non-regulatory health-based thresholds, although the concentrations of low-level DBCP in 10 percent and low-level EDB in 3 percent of the samples from grid wells were above the corresponding USEPA maximum contaminant levels (MCL-USs). Perchlorate was detected in 70 percent of the samples from grid wells, and most concentrations were less than one-tenth of the CDPH maximum contaminant level (MCL-CA). Low-level 1,2,3-TCP was detected in 33 percent of the samples from grid wells, and all concentrations were less than 1/1,000 of the USEPA lifetime health advisory level (HAL-US). Most concentrations of trace elements and nutrients in samples were below regulatory and non-regulatory health-based thresholds. Concentrations were above the MCL-US for nitrate in 7 percent of the samples from grid wells, for arsenic and uranium in 13 percent each of the samples from grid wells; and the concentration of vanadium was above the CDPH notification level (NL–CA) in 3 percent of the samples from grid wells. Detections of radioactive constituents were below regulatory and non-regulatory health-based thresholds in most samples. Combined activities of uranium isotopes were detected above the MCL-CA in 20 percent of the subset of 25 grid well samples analyzed, and gross alpha particle activity was detected above the MCL-US in 20 percent of the samples from the 30 total grid wells. Most of the samples from MADCHOW grid wells had concentrations of major and minor ions, total dissolved solids, and trace elements below the CDPH secondary maximum contaminant levels (SMCL-CAs), which are nonenforceable thresholds set for aesthetic and technical concerns. Twenty percent of the samples from grid wells contained specific-conductance values, or concentrations of chloride, total dissolved solids, or manganese above the respective SMCL–CAs.

California↗