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Depletion of Appalachian coal reserves - how soon?

Much of the coal consumed in the US since the end of the last century has been produced from the Pennsylvanian strata of the Appalachian basin. Even though quantities mined in the past are less than they are today, this basin yielded from 70% to 80% of the nation's annual coal production from the end of the last century until the early 1970s. During the last 25 years, the proportion of the nation's coal that was produced annually from the Appalachian basin has declined markedly, and today it is only about 40% of the total. The amount of coal produced annually in the Appalachian basin, however, has been rising slowly over the last several decades, and has ranged generally from 400 to 500 million tons (Mt) per year. A large proportion of Appalachian historical production has come from relatively few counties in southwestern Pennsylvania, northern and southern West Virginia, eastern Kentucky, Virginia and Alabama. Many of these counties are decades past their years of peak production and several are almost depleted of economic deposits of coal. Because the current major consumer of Appalachian coal is the electric power industry, coal quality, especially sulfur content, has a great impact on its marketability. High-sulfur coal deposits in western Pennsylvania and Ohio are in low demand when compared with the lower sulfur coals of Virginia and southern West Virginia. Only five counties in the basin that have produced 500 Mt or more exhibit increasing rates of production at relatively high levels. Of these, six are in the central part of the basin and only one, Greene County, Pennsylvania, is in the northern part of the basin. Decline rate models, based on production decline rates and the decline rate of the estimated, 'potential' reserve, indicate that Appalachian basin annual coal production will be 200 Mt or less by the middle of the next century. Published by Elsevier Science B.V.Much of the coal consumed in the US since the end of the last century has been produced from the Pennsylvanian strata of the Appalachian basin. Even though quantities mined in the past are less than they are today, this basin yielded from 70% to 80% of the nation's annual coal production from the end of the last century until the early 1970s. During the last 25 years, the proportion of the nation's coal that was produced annually from the Appalachian basin has declined markedly, and today it is only about 40% of the total. The amount of coal produced annually in the Appalachian basin, however, has been rising slowly over the last several decades, and has ranged generally from 400 to 500 million tons (Mt) per year. A large proportion of Appalachian historical production has come from relatively few counties in southwestern Pennsylvania, northern and southern West Virginia, eastern Kentucky, Virginia and Alabama. Many of these counties are decades past their years of peak production and several are almost depleted of economic deposits of coal. Because the current major consumer of Appalachian coal is the electric power industry, coal quality, especially sulfur content, has a great impact on its marketability. High-sulfur coal deposits in western Pennsylvania and Ohio are in low demand when compared with the lower sulfur coals of Virginia and southern West Virginia. Only five counties in the basin that have produced 500 Mt or more exhibit increasing rates of production at relatively high levels. Of these, six are in the central part of the basin and only one, Greene County, Pennsylvania, is in the northern part of the basin. Decline rate models, based on production decline rates and the decline rate of the estimated, `potential' reserve, indicate that Appalachian basin annual coal production will be 200 Mt or less by the middle of the next century.

International Journal of Coal Geology↗

Crocoite: An unusual mode of occurrence for lead in coal

What is believed to be a very unusual mode of occurrence for lead in coal has been identified as crocoite (PbCrO4). As part of a larger study on trace elements and mineralogy in the Cretaceous Main Seam in New Zealand, crocoite was found in raw coal samples within the lower part of the coal seam. X-ray diffraction (XRD) and bulk chemical data from a SEM equipped with an energy dispersive X-ray analyser (EDXA) have confirmed the identity of this mineral. This is apparently the first time that crocoite has been reported in coal. Crocoite usually occurs only in the oxidised zone of lead mineral deposits. The occurrence of this mineral in the Main Seam coal implies that the deposit was exposed to an oxidising environment at some stage, most likely after coalification. Published by Elsevier Science B.V.

International Journal of Coal Geology↗

Probabilistic assessment methodology for continuous-type petroleum accumulations

The analytic resource assessment method, called ACCESS (Analytic Cell-based Continuous Energy Spreadsheet System), was developed to calculate estimates of petroleum resources for the geologic assessment model, called FORSPAN, in continuous-type petroleum accumulations. The ACCESS method is based upon mathematical equations derived from probability theory in the form of a computer spreadsheet system. ?? 2003 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

Developmental geology of coalbed methane from shallow to deep in Rocky Mountain basins and in Cook Inlet-Matanuska Basin, Alaska, USA and Canada

The Rocky Mountain basins of western North America contain vast deposits of coal of Cretaceous through early Tertiary age. Coalbed methane is produced in Rocky Mountain basins at depths ranging from 45 m (150 ft) to 1981 m (6500 ft) from coal of lignite to low-volatile bituminous rank. Although some production has been established in almost all Rocky Mountain basins, commercial production occurs in only a few. despite more than two decades of exploration for coalbed methane in the Rocky Mountain region, it is still difficult to predict production characteristics of coalbed methane wells prior to drilling. Commonly cited problems include low permeabilities, high water production, and coals that are significantly undersaturated with respect to methane. Sources of coalbed gases can be early biogenic, formed during the early stages of coalification, thermogenic, formed during the main stages of coalification, or late stage biogenic, formed as a result of the reintroduction of methane-gnerating bacteria by groundwater after uplift and erosion. Examples of all three types of coalbed gases, and combinations of more than one type, can be found in the Rocky Mountain region. Coals in the Rocky Mountain region achieved their present ranks largely as a result of burial beneath sediments that accumulated during the Laramide orogeny (Late Cretaceous through the end of the eocene) or shortly after. Thermal events since the end of the orogeny have also locally elevated coal ranks. Coal beds in the upper part of high-volatile A bituminous rank or greater commonly occur within much more extensive basin-centered gas deposits which cover large areas of the deeper parts of most Rocky Mountain basins. Within these basin-centered deposits all lithologies, including coals, sandstones, and shales, are gas saturated, and very little water is produced. The interbedded coals and carbonaceous shales are probably the source of much of this gas. Basin-centered gas deposits become overpressured from hydrocarbon generation as they form, and this overpressuring is probably responsible for driving out most of the water. Sandstone permeabilities are low, in part because of diagenesis caused by highly reactive water given off during the early stages of coalification. Coals within these basin-centered deposits commonly have high gas contents and produce little water, but they generally occur at depths greater than 5000 ft and have low permeabilities. Significant uplift and removal of overburden has occurred throughout the Rocky Mountain region since the end of the Eocene, and much of this erosion occurred after regional uplift began about 10 Ma. The removal of overburden generally causes methane saturation levels in coals to decrease, and thus a significant drop in pressure is required to initiate methane production. The most successful coalbed methane production in the Rocky Mountain region occurs in areas where gas contents were increased by post-Eocene thermal events and/or the generation of late-stage biogenic gas. Methane-generating bacteria were apparently reintroduced into the coals in some areas after uplift and erosion, and subsequent changes in pressure and temperature, allowed surface waters to rewater the coals. Groundwater may also help open up cleat systems making coals more permeable to methane. If water production is excessive, however, the economics of producing methane are impacted by the cost of water disposal.The Rocky Mountain basins of western North America contain vast deposits of coal of Cretaceous through early Tertiary age. Coalbed methane is produced in Rocky Mountain basins at depths ranging from 45 to 1981 m from coal of lignite to low volatile bituminous rank. Despite more than two decades of exploration for coalbed methane in Rocky Mountain region, it is still difficult to predict production characteristics of coalbed methane wells prior to drilling. Sources of coalbed gases can be early biogenic, formed during the main stages of coa

International Journal of Coal Geology↗

Coalbed methane: from hazard to resource

Coalbed gas, which mainly consists of methane, has remained a major hazard affecting safety and productivity in underground coal mines for more than 100 yr. Coalbed gas emissions have resulted in outbursts and explosions where ignited by open lights, smoking or improper use of black blasting powder, and machinery operations. Investigations of coal gas outbursts and explosions during the past century were aimed at predicting and preventing this mine hazard. During this time, gas emissions were diluted with ventilation by airways (eg, tunnels, vertical and horizontal drillholes, shsfts) and by drainage boreholes. The 1970s 'energy crisis' led to studies of the feasibility of producing the gas for commercial use. Subsequent research on the origin, accumulation, distribution, availability, and recoverability has been pursued vigorously during the past two decades. Since the 1970s research investigations on the causes and effects of coal mine outbursts and gas emissions have led to major advances towards the recovery and development of coalbed methane for commercial use. Thus, coalbed methane as a mining hazard was harnessed as a conventional gas resource.Coalbed gas, which mainly consists of methane, has remained a major hazard affecting safety and productivity in underground coal mines for more than 100 years. Coalbed gas emissions have resulted in outbursts and explosions where ignited by open lights, smoking or improper use of black blasting powder, and machinery operations. Investigations of coal gas outbursts and explosions during the past century were aimed at predicting and preventing this mine hazard. During this time, gas emissions were diluted with ventilation by airways (e.g., tunnels, vertical and horizontal drillholes, shafts) and by drainage boreholes. The 1970's `energy crisis' led to studies of the feasibility of producing the gas for commercial use. Subsequent research on the origin, accumulation, distribution, availability, and recoverability has been pursued vigorously during the past two decades. Since the 1970's research investigations on the causes and effects of coal mine outbursts and gas emissions have led to major advances towards the recovery and development of coalbed methane for commercial use. Thus, coalbed methane as a mining hazard was harnessed as a conventional gas resource.

International Journal of Coal Geology↗

A possible link between Balkan endemic nephropathy and the leaching of toxic organic compounds from Pliocene lignite by groundwater: Preliminary investigation

Balkan endemic nephropathy (BEN) is a fatal kidney disease that is known to occur only in clusters of villages in alluvial valleys of tributaries of the Danube River in Bulgaria, Romania, Yugoslavia, Bosnia, and Croatia. The confinement of this disease to a specific geographic area has led to speculation that an environmental factor may be involved in the etiology of BEN. Numerous environmental factors have been suggested as causative agents for producing BEN, including toxic metals in drinking water, metal deficiency in soils of BEN areas, and environmental mycotoxins to name a few. These hypotheses have either been disproved or have failed to conclusively demonstrate a connection to the etiology of BEN, or the clustering of BEN villages. In previous work, we observed a distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and BEN villages. We hypothesized that the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites by groundwater was a primary factor in the etiology of BEN. In our current work, chemical analysis using 13C nuclear magnetic resonance (13CNMR) spectroscopy indicated a high degree of organic functionality in Pliocene lignite from the Balkans, and suggested that groundwater can readily leach organic matter from these coal beds. Semi-quantitative gas chromatography/mass spectroscopy analysis of solvent extracts of groundwater from shallow wells in BEN villages indicated the presence of potentially toxic aromatic compounds, such as napthalene, fluorene, phenanthrene, and pyrene at concentrations in the ppb range. Laboratory leaching of Balkan Pliocene lignites with distilled water yielded soluble organic matter (> 500 MW) containing large amounts of aromatic structures similar to the simple/discrete aromatic compounds detected in well water from BEN villages. These preliminary results are permissive of our hypothesis and suggest that further work on the possible relationship between the etiology of BEN and toxic aromatic substances leached from Pliocene lignites in well water is warranted.A distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and villages where Balkan endemic nephropathy (BEN) occurs has been observed, indicating a possible link between BEN and the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites. Preliminary investigations by NMR spectroscopy, gas chromatography/mass spectroscopy and leaching experiments show a high degree of organic functionality in the Pliocene lignites, high-leachability by groundwater of organic matter from these beds, and the presence of toxic aromatic compounds.

International Journal of Coal Geology↗

Exploration and discovery in Yellowstone Lake: Results from high-resolution sonar imaging, seismic reflection profiling, and submersible studies

Discoveries from multi-beam sonar mapping and seismic reflection surveys of the northern, central, and West Thumb basins of Yellowstone Lake provide new insight into the extent of post-collapse volcanism and active hydrothermal processes occurring in a large lake environment above a large magma chamber. Yellowstone Lake has an irregular bottom covered with dozens of features directly related to hydrothermal, tectonic, volcanic, and sedimentary processes. Detailed bathymetric, seismic reflection, and magnetic evidence reveals that rhyolitic lava flows underlie much of Yellowstone Lake and exert fundamental control on lake bathymetry and localization of hydrothermal activity. Many previously unknown features have been identified and include over 250 hydrothermal vents, several very large (>500 m diameter) hydrothermal explosion craters, many small hydrothermal vent craters (∼1–200 m diameter), domed lacustrine sediments related to hydrothermal activity, elongate fissures cutting post-glacial sediments, siliceous hydrothermal spire structures, sublacustrine landslide deposits, submerged former shorelines, and a recently active graben. Sampling and observations with a submersible remotely operated vehicle confirm and extend our understanding of the identified features. Faults, fissures, hydrothermally inflated domal structures, hydrothermal explosion craters, and sublacustrine landslides constitute potentially significant geologic hazards. Toxic elements derived from hydrothermal processes also may significantly affect the Yellowstone ecosystem.

Wyoming↗

Spatial patterns in PCB concentrations of Lake Michigan lake trout

Most of the PCB body burden in lake trout ( Salvelinus namaycush ) of the Great Lakes is from their food. PCB concentrations were determined in lake trout from three different locations in Lake Michigan during 1994–1995, and lake trout diets were analyzed at all three locations. The PCB concentrations were also determined in alewife ( Alosa pseudoharengus ), rainbow smelt ( Osmerus mordax ), bloater ( Coregonus hoyi ), slimy sculpin ( Cottus cognatus ), and deepwater sculpin ( Myoxocephalus thompsoni ), five species of prey fish eaten by lake trout in Lake Michigan, at three nearshore sites in the lake. Despite the lack of significant differences in the PCB concentrations of alewife, rainbow smelt, bloater, slimy sculpin, and deepwater sculpin from the southeastern nearshore site near Saugatuck (Michigan) compared with the corresponding PCB concentrations from the northwestern nearshore site near Sturgeon Bay (Wisconsin), PCB concentrations in lake trout at Saugatuck were significantly higher than those at Sturgeon Bay. The difference in the lake trout PCB concentrations between Saugatuck and Sturgeon Bay could be explained by diet differences. The diet of lake trout at Saugatuck was more concentrated in PCBs than the diet of Sturgeon Bay lake trout, and therefore lake trout at Saugatuck were more contaminated in PCBs than Sturgeon Bay lake trout. These findings were useful in interpreting the long-term monitoring series for contaminants in lake trout at both Saugatuck and the Wisconsin side of the lake.

Journal of Great Lakes Research↗

On the interpretation of energy and energy fluxes of nonlinear internal waves: An example from Massachusetts Bay

A self-consistent formalism to estimate baroclinic energy densities and fluxes resulting from the propagation of internal waves of arbitrary amplitude is derived using the concept of available potential energy. The method can be applied to numerical, laboratory or field data. The total energy flux is shown to be the sum of the linear energy flux ??? u??? p??? dz (primes denote baroclinic quantities), plus contributions from the non-hydrostatic pressure anomaly and the self-advection of kinetic and available potential energy. Using highly resolved observations in Massachusetts Bay, it is shown that due to the presence of nonlinear internal waves periodically propagating in the area, ??? u??? p??? dz accounts for only half of the total flux. The same data show that equipartition of available potential and kinetic energy can be violated, especially when the nonlinear waves begin to interact with the bottom. ?? 2006 Cambridge University Press.

Massachusetts Bay↗

Conodonts, stratigraphy, and relative sea-level changes of the tribes hill formation (lower ordovician, east-central New York)

Tremadocian onlap is recorded by the Tribes Hill Formation. The formation is a lower Lower Ordovician (upper conodont Fauna B Interval(?)- Rossodus manitouensis Zone) depositional sequence that unconformably overlies the Upper Cambrian Little Falls Formation. Depositional environments and stratigraphy indicate that the Tribes Hill was deposited on a wave-, not tide-, dominated shelf and that a uniform, “layer-cake” stratigraphy is present. The deepening-shoaling sequence of the Tribes Hill includes the: 1) Sprakers Member (new; peritidal carbonate and overlying tempestite limestone and shale); 2) Van Wie Member (new; subtidal shale and limestone); 3) Wolf Hollow Member (revised; massive carbonates with thrombolitic cap); and 4) Canyon Road Member (new; glauconitic limestone and overlying evaporitic dolostone). The shoaling half-cycle of the Tribes Hill is older than a shoaling event in western Newfoundland, and suggests epeirogenic factors in earliest Ordovician sea-level change in east Laurentia. Conodont and trilobite biofacies track lithofacies, and Rossodus manitouensis Zone conodonts and Bellefontia Biofacies trilobites appear in the distal, middle Tribes Hill Formation. Twenty-four conodont species are illustrated. Ansella ? protoserrata new species, Iapetognathus sprakersi new species, Leukorhinion ambonodes new genus and species, and Laurentoscandodus new genus are described.

Journal of Paleontology↗

Aquatic dissipation of triclopyr in Lake Seminole, Georgia

A field study was conducted to evaluate the environmental dissipation of triclopyr herbicide under aquatic-use conditions. Three 4-h plots in Lake Seminole, Georgia, were selected for use: one control, one aerial plot, and one subsurface plot; both applications were at the maximum aquatic-use rate of 2.5 mg/L. Water, sediment, plants, fish, clams, and crayfish were all analyzed for residues, and water temperature, oxygen levels, pH, and conductivity were monitored. The half-life for aqueous-phase triclopyr ranged from 0.5 to 3.6 days, and the dissipation in surface and bottom waters was equivalent. The intermediate decay product of triclopyr, 3,5,6-trichloro-2-pyridinol (TCP), had an observed aquatic half-life of less than 1 day. No accumulation of triclopyr or TCP on sediment was observed. The half-life of triclopyr metabolized by aquatic plants averaged 4 days. Fish species did not exhibit any bioconcentration of triclopyr or TCP, with only trace amounts of either compound found in fish tissue. Both clams and crayfish contained detectable residues of triclopyr. The elimination of triclopyr from clam tissue was more rapid, with an observed half-life of 1.5 days, vs 12 days for crayfish; retention of triclopyr in the crayfish carcass (carapace, chelopeds, and gills) may have been an important mechanism. There was no detectable decline in water quality in either treatment plot. ?? 1993 American Chemical Society.

Journal of Agricultural and Food Chemistry↗

Stress transfer by the 1988-1989 M=5.3 and 5.4 Lake Elsman foreshocks to the Loma Prieta fault: Unclamping at the site of peak mainshock slip

We study the stress transferred by the June 27, 1988, M = 5.3 and August 8, 1989, M = 5.4 Lake Elsman earthquakes, the largest events to strike within 15 km of the future Loma Prieta rupture zone during 74 years before the 1989 M = 6.9 Loma Prieta earthquake. We find that the first Lake Elsman event brought the rupture plane of the second event 0.3–1.6 bars (0.03–0.16 MPa) closer to Coulomb failure but that the Lake Elsman events did not bring the future Loma Prieta hypocentral zone closer to failure. Instead, the Lake Elsman earthquakes are calculated to have reduced the normal stress on (or “undamped”) the Loma Prieta rupture surface by 0.5–1.0 bar (0.05–0.10 MPa) at the site where the greatest slip subsequently occurred in the Loma Prieta earthquake. This association between the sites of peak unclamping and slip suggests that the Lake Elsman events did indeed influence the Loma Prieta rupture process. Unclamping the fault would have locally lowered the resistance to sliding. Such an effect could have been enhanced if the lowered normal stress permitted fluid infusion into the undamped part of the fault. Although less well recorded, the M L = 5.0 1964 and M L = 5.3 1967 Corralitos events struck within 10 km of the southwest end of the future Loma Prieta rupture. No similar relationship between the normal stress change and subsequent Loma Prieta slip is observed, although the high-slip patch southwest of the Loma Prieta epicenter corresponds roughly to the site of calculated Coulomb stress increase for a low coefficient of friction. The Lake Elsman-Loma Prieta result is similar to that for the 1987 M = 6.2 Elmore Ranch and M = 6.7 Superstition Hills earthquakes, suggesting that foreshocks might influence the distribution of mainshock slip rather than the site of mainshock nucleation.

Journal of Geophysical Research B: Solid Earth↗

Mineralogic and compositional properties of Martian soil and dust: results from Mars Pathfinder

Mars Pathfinder obtained multispectral, elemental, magnetic, and physical measurements of soil and dust at the Sagan Memorial Station during the course of its 83 sol mission. We describe initial results from these measurements, concentrating on multispectral and elemental data, and use these data, along with previous Viking, SNC meteorite, and telescopic results, to help constrain the origin and evolution of Martian soil and dust. We find that soils and dust can be divided into at least eight distinct spectral units, based on parameterization of Imager for Mars Pathfinder (IMP) 400 to 1000 nm multispectral images. The most distinctive spectral parameters for soils and dust are the reflectivity in the red, the red/blue reflectivity ratio, the near-IR spectral slope, and the strength of the 800 to 1000 nm absorption feature. Most of the Pathfinder spectra are consistent with the presence of poorly crystalline or nanophase ferric oxide(s), sometimes mixed with small but varying degrees of well-crystalline ferric and ferrous phases. Darker soil units appear to be coarser-grained, compacted, and/or mixed with a larger amount of dark ferrous materials relative to bright soils. Nanophase goethite, akaganeite, schwertmannite, and maghemite are leading candidates for the origin of the absorption centered near 900 nm in IMP spectra. The ferrous component in the soil cannot be well-constrained based on IMP data. Alpha proton X-ray spectrometer (APXS) measurements of six soil units show little variability within the landing site and show remarkable overall similarity to the average Viking-derived soil elemental composition. Differences exist between Viking and Pathfinder soils, however, including significantly higher S and Cl abundances and lower Si abundances in Viking soils and the lack of a correlation between Ti and Fe in Pathfinder soils. No significant linear correlations were observed between IMP spectral properties and APXS elemental chemistry. Attempts at constraining the mineralogy of soils and dust using normative calculations involving mixtures of smectites and silicate and oxide minerals did not yield physically acceptable solutions. We attempted to use the Pathfinder results to constrain a number of putative soil and dust formation scenarios, including palagonitization and acid-fog weathering. While the Pathfinder soils cannot be chemically linked to the Pathfinder rocks by palagonitization, this study and McSween et al. [1999] suggest that palagonitic alteration of a Martian basaltic rock, plus mixture with a minor component of locally derived andesitic rock fragments, could be consistent with the observed soil APXS and IMP properties.

Journal of Geophysical Research E: Planets↗

Geochemical evidence for a magmatic CO 2 degassing event at Mammoth Mountain, California, September-December 1997

Recent time series soil CO 2 concentration data from monitoring stations in the vicinity of Mammoth Mountain, California, reveal strong evidence for a magmatic degassing event during the fall of 1997 lasting more than 2 months. Two sensors at Horseshoe Lake first recorded the episode on September 23, 1997, followed 10 days later by a sensor on the north flank of Mammoth Mountain. Direct degassing from shallow intruding magma seems an implausible cause of the degassing event, since the gas released at Horseshoe Lake continued to be cold and barren of other magmatic gases, except for He. We suggest that an increase in compressional strain on the area south of Mammoth Mountain driven by movement of major fault blocks in Long Valley caldera may have triggered an episode of increased degassing by squeezing additional accumulated CO 2 from a shallow gas reservoir to the surface along faults and other structures where it could be detected by the CO 2 monitoring network. Recharge of the gas reservoir by CO 2 emanating from the deep intrusions that probably triggered deep long-period earthquakes may also have contributed to the degassing event. The nature of CO 2 discharge at the soil-air interface is influenced by the porous character of High Sierra soils and by meteorological processes. Solar insolation is the primary source of energy for the Earth atmosphere and plays a significant role in most diurnal processes at the Earth surface. Data from this study suggest that external forcing due largely to local orographic winds influences the fine structure of the recorded CO 2 signals.

California↗

Vertical tectonics in northern Escanaba Trough as recorded by thick late Quaternary turbidites

Escanaba Trough, the southernmost segment of the Gorda Ridge, is filled by as much as 500 m of late Quaternary turbidite and hemipelagic sediment. Coring at Deep Sea Drilling Project Site 35 and Ocean Drilling Program (ODP) Sites 1037 and 1038 together with 4.5-kHz deep-tow and 3.5-kHz surface-ship seismic reflection profiles enable a distinct pattern of reflections to be mapped throughout Escanaba Trough in the upper part of this sediment fill. The uppermost 80 m of turbidite sediment, which includes at least 11 turbidity current events, were deposited in <7 kyr. Nine of these turbidites are found throughout Escanaba Trough at water depths >3200 m. The turbidity currents were trapped upon entering Escanaba Trough, resulting in all of the sediment in suspension in the flows being deposited. The thickness of the turbidite layers reflects both the flow thickness and the vertical grain concentration within the flow that deposited the layer. Variations in the turbidite thickness with respect to water depth can be used to estimate the degree of relative vertical movement within the floor of Escanaba Trough. In the area of hydrothermal activity near ODP Site 1038, uplift of as much as 140 m has occurred over the past 8 kyr.

California↗

Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period

We perform a Monte Carlo pattern recognition analysis of the coincidence between three regional volcanic histories from ice coring of Greenland and Antarctica over the period 2 to 45 ka, using SO4 anomalies in Greenland and East Antarctica determined by continuous core chemistry, together with West Antarctic volcanic ash layers determined by remote optical borehole logging and core assays. We find that the Antarctic record of volcanism correlates with Glacial abrupt climate change at a 95% to >99.8% (???3??) significance level and that volcanic depositions at the three locations match at levels exceeding 3??, likely indicating that many common horizons represent single eruptive events which dispersed material world wide. These globally coincident volcanics were associated with abrupt cooling, often simultaneous with onsets or sudden intensifications of millennial cold periods. The striking agreement between sites implies that the consistency of current timescales obtained by isotopic and glaciological dating methods is better than estimated. Copyright 2006 by the American Geogphysical Union.

Journal of Geophysical Research D: Atmospheres↗

Sulfate deposition in subsurface regolith in Gusev crater, Mars

Excavating into the shallow Martian subsurface has the potential to expose stratigraphic layers and mature regolith, which may hold a record of more ancient aqueous interactions than those expected under current Martian surface conditions. During the Spirit rover's exploration of Gusev crater, rover wheels were used to dig three trenches into the subsurface regolith down to 6-11 cm depth: Road Cut, the Big Hole, and The Boroughs. A high oxidation state of Fe and high concentrations of Mg, S, Cl, and Br were found in the subsurface regolith within the two trenches on the plains, between the Bonneville crater and the foot of Columbia Hills. Data analyses on the basis of geochemistry and mineralogy observations suggest the deposition of sulfate minerals within the subsurface regolith, mainly Mg-sulfates accompanied by minor Ca-sulfates and perhaps Fe-sulfates. An increase of Fe2O3, an excess of SiO2, and a minor decrease in the olivine proportion relative to surface materials are also inferred. Three hypotheses are proposed to explain the geochemical trends observed in trenches: (1) multiple episodes of acidic fluid infiltration, accompanied by in situ interaction with igneous minerals and salt deposition; (2) an open hydrologic system characterized by ion transportation in the fluid, subsequent evaporation of the fluid, and salt deposition; and (3) emplacement and mixing of impact ejecta of variable composition. While all three may have plausibly contributed to the current state of the subsurface regolith, the geochemical data are most consistent with ion transportation by fluids and salt deposition as a result of open-system hydrologic behavior. Although sulfates make up >20 wt.% of the regolith in the wall of The Boroughs trench, a higher hydrated sulfate than kieserite within The Boroughs or a greater abundance of sulfates elsewhere than is seen in The Boroughs wall regolith would be needed to hold the structural water indicated by the water-equivalent hydrogen concentration observed by the Gamma-Ray Spectrometer on Odyssey in the Gusev region.

Journal of Geophysical Research E: Planets↗