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At least 1,117 records · Page 62Linked to original sources

Evaluation of effects of changes in canal management and precipitation patterns on salinity in Biscayne Bay, Florida, using an integrated surface-water/groundwater model

Biscayne National Park, located in Biscayne Bay in southeast Florida, is one of the largest marine parks in the country and sustains a large natural marine fishery where numerous threatened and endangered species reproduce. In recent years, the bay has experienced hypersaline conditions (salinity greater than 35 practical salinity units) of increasing magnitude and duration. Hypersalinity events were particularly pronounced during April to August 2004 in nearshore areas along the southern and middle parts of the bay. Prolonged hypersaline conditions can cause degradation of water quality and permanent damage to, or loss of, brackish nursery habitats for multiple species of fish and crustaceans as well as damage to certain types of seagrasses that are not tolerant of extreme changes in salinity. To evaluate the factors that contribute to hypersalinity events and to test the effects of possible changes in precipitation patterns and canal flows into Biscayne Bay on salinity in the bay, the U.S. Geological Survey constructed a coupled surface-water/groundwater numerical flow model. The model is designed to account for freshwater flows into Biscayne Bay through the canal system, leakage of salty bay water into the underlying Biscayne aquifer, discharge of fresh and salty groundwater from the Biscayne aquifer into the bay, direct effects of precipitation on bay salinity, indirect effects of precipitation on recharge to the Biscayne aquifer, direct effects of evapotranspiration (ET) on bay salinity, indirect effects of ET on recharge to the Biscayne aquifer, and maintenance of mass balance of both water and solute. The model was constructed using the Flow and Transport in a Linked Overland/Aquifer Density Dependent System (FTLOADDS) simulator, version 3.3, which couples the two-dimensional, surface-water flow and solute-transport simulator SWIFT2D with the density-dependent, groundwater flow an solute-transport simulator SEAWAT. The model was calibrated by a trial-and-error method to fit observed groundwater heads, estimated base flow, and measured bay salinity and temperatures from 1996 to 2004, as well as the location of the freshwater-saltwater interface in the aquifer, by adjusting ET rate limiters, canal vertical hydraulic conductance, leakage rate coefficients (transition-layer thickness and hydraulic conductivity), Manning's n value, and delineation of rainfall zones. Although flow budget calculations indicate that precipitation, ET, and groundwater flux into the bay represent a small portion of the overall budget, these factors may be important in controlling salinity in some parts of the bay, for example the southern parts of the bay where the canal system is not extensively developed or controlled. The balance of precipitation and ET during the wet season generally results in a reduction of bay salinity, whereas the balance of precipitation and ET during the dry season generally results in an increase in bay salinity. During years when wet season precipitation is lower than average, for example less than 70 percent total precipitation for an average year, ET could outweigh precipitation over the bay for essentially the entire year. Hypersaline conditions are prone to occur near the end of the dry season because precipitation rates are generally lower, canal discharge rates (which are strongly correlated to precipitation rates) are also generally lower, and ET rates are higher than during the rest of the year. The hypersalinity event of 2004 followed several years of relatively low precipitation and correspondingly reduced canal structure releases and was unusually extensive, continuing into July. Thus, hypersalinity is ultimately the result of a cumulative deficit of precipitation. The model was used to test the effects of possible changes in canal flux and precipitation. Simulation results showed that by increasing, reducing, or modifying canal discharge rates, the effects on salinity in the bay were more pronounced in the northern part of the bay where there are more canals and canal-control structures. By doubling and halving precipitation, the effects on bay salinity were more pronounced in the southern part of the bay than in the northern part of the bay where there are fewer canals and canal-control structures. The model is designed to quantify factors that contribute to hypersaline conditions in Biscayne Bay and may be less appropriate for addressing other issues or examining conditions substantially different from those described in this report. Model results must be interpreted in light of model limitations, which include representation of the system and conceptual model, uncertainty in physical properties used to describe the system or processes, the scale and discretization of the system, and representation of the boundary conditions.

Florida↗

Vegetation map for the Seboeis Unit of Katahdin Woods and Waters National Monument

The Katahdin Woods and Waters National Monument, located in the forests of central Maine, is a newly (2016) established unit for the National Park Service. To better understand the condition of lands within the monument and inform management planning, Katahdin Woods and Waters National Monument resource managers wanted better information of the vegetation present within the monument. To meet this need, scientists at the U.S. Geological Survey Upper Midwest Environmental Sciences Center worked with ecologists at the Maine Natural Areas Program to catalog and map the vegetation of the Seboeis Unit of the monument. This report details this process, provides results of the survey and mapping efforts, presents results in the form of a vegetation map for the Seboeis Unit, and provides vegetation descriptions and a dichotomous key for the entire Katahdin Woods and Waters National Monument.

Maine↗

Visualization of petroleum exploration maturity for six petroleum provinces outside the United States and Canada

Outside the United States and Canada, most of the world’s supplies of oil and natural gas are recovered from conventional (or discrete) oil and gas accumulations. This type of hydrocarbon accumulation remains a target for exploration. In this report, exploration and discovery data are used to visually assist in describing the exploration maturity of selected petroleum provinces with respect to conventional oil and natural gas accumulations. The specific provinces are the Campos Basin (Brazil), the Santos Basin (Brazil), the North Sea Graben (northwestern Europe), the Middle Magdelena Basin (Colombia), the Sirte Basin (Libya), and the Kutei Basin (Indonesia). For each province, discovery data and well data through October 2019 are reported; from these data, depth distributions of the oil in oil fields and natural gas in gas fields were computed. The concepts of delineated prospective area and explored area include elements of geographic spatial information and statistical data analytics. Graphs showing dynamic growth of discoveries that are tied to the delineated prospective area provide a means of grading prospective area. Visualizations put the results of exploration in the context of geographic and geologic features of the play or basin and can be a tool to assist geologists with the appraisal of the number and sizes of undiscovered petroleum accumulations. Visualizations of exploration drilling and discoveries can (1) assist in conceptualizing a geologic model of the basin, (2) highlight relations among discovered accumulations in different plays or assessment units within the basin, and (3) allow the geologist to identify the missing information needed to complete the geologic model of a basin. Further, if visualization attributes can be quantified, they may be used for formulating quantitative models that predict numbers and sizes of undiscovered oil and gas accumulations. Such modeling approaches include discovery process models, Bayesian network models that characterize play or assessment unit dependencies, and innovative applications of machine learning to complement standard geologic assessments. The purpose of this report is to show how visualizations can further the understanding of exploration maturity for the six selected petroleum provinces. It also shows how the geologic framework, geologic data, and drilling and discovery trends can give context to the interpretation of the visualizations that lead to appraisal of exploration maturity.

Campos Basin, Kutei Basin, Middle Magdelena Basin,↗

Water-quality indicators of surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia

The U.S. Geological Survey, in cooperation with the West Virginia Department of Health and Human Resources, studied surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia for the purpose of understanding the influence of surface water on groundwater chemistry. Public groundwater supplies obtained from these aquifers receive substantial recharge from surface-water sources and are highly susceptible to degradation from water-soluble contaminants. Water samples were collected from 4 sites in the Ohio River and 23 groundwater wells in the alluvial aquifer from June 2019 to January 2020. Surface-water influence was assessed through characterization of groundwater quality, determination of recharge sources, estimation of groundwater age, and estimation of the fraction of Ohio River water entering groundwater pumped by wells in the alluvial aquifers. Hydrogeochemical processes controlling solute concentrations in the Ohio River alluvial aquifer were evaluated with multivariate statistical analysis and identified to be primarily controlled by redox processes, input from sources of salinity, and carbonate dissolution. Meteoric recharge from the Ohio River and precipitation on the alluvium are the main sources of water entering the aquifer. The age of groundwater in the system was determined to be primarily from a modern source. Groundwater samples from every well included in this study had detections for at least one geochemical indicator of surface-water influence, and every well was determined to be susceptible and vulnerable to contamination from surface sources. Results from binary mixing models and inverse geochemical models showed that sulfate, silica, and bicarbonate concentrations predict the fraction of Ohio River water entering alluvial wells for preliminary determination of surface-water influence when compared to fractions predicted using a numerical groundwater-flow model. In the absence of extensive analytes and geochemical or groundwater modeling capabilities, preliminary assessment of the fraction of Ohio River water entering groundwater wells in the Ohio River alluvium can be estimated for most sites using a linear relation between the equivalent ratio of bicarbonate to sulfate and the fraction of water computed by the average of the three geochemical models presented in this report. This approximation of the fraction of Ohio River water, coupled with information on the hydrogeological framework and geochemical indicators of surface-water influence, may be sufficient for preliminary assessment of surface-water influence in the absence of more detailed site information or reaction-transport models.

West Virginia↗

Potentiometric Surface of the Ozark Aquifer near Springfield, Missouri, 2006-07

INTRODUCTION A study of the water resources of the Springfield, Missouri, area in the 1970s determined that a cone of depression, formed by ground-water pumping, had developed in the Ozark aquifer beneath the city (Emmett and others, 1978). Continued ground-water usage in the 1970s and 1980s caused concern that ground-water resources would not be sufficient to meet the future needs of Springfield, Missouri, during periods of drought. As a result, a ground-water flow model of the Springfield area was developed by the U. S. Geological Survey (USGS) to assess the future role of ground water as a water source for the area (Imes, 1989). Results of the USGS model led to a decision by the City Utilities of Springfield to primarily rely on surface water from Stockton Lake as a source of city drinking water. Municipal and industrial ground-water usage continues in Springfield, but at lower rates than previously experienced (Jim Vandike, Missouri Department of Natural Resources, written commun., 2007). Rapid growth in the area has caused commercial, industrial, and domestic water use to increase. Population growth has been especially rapid in Nixa, Ozark, and Republic, and water use in the vicinity of these cities has grown an estimated 39 percent since 1990 (Dintelmann and others, 2006). Unlike Springfield, ground water is the primary source of water for these cities. The increased stress on the Ozark aquifer, the primary aquifer in the study area, has raised new concerns about possible further water-level declines in the areas of increased ground-water use. Although there continues to be new development in the Ozark aquifer, since 1987 no new water-supply wells that produce water from the Springfield Plateau aquifer have been allowed to be constructed in most of Greene and northern Christian counties (Jim Vandike, Missouri Department of Natural Resources, written commun., 2007). There is concern that if the potentiometric surface of the Ozark aquifer continues to decline, increased leakage of contaminants into the Ozark aquifer from the overlying Springfield Plateau aquifer could occur (Jim Vandike, Missouri Department of Natural Resources, written commun., 2007). To address this concern, the USGS, in cooperation with Greene County, Missouri, the U.S. Army Corps of Engineers, and the Missouri Department of Natural Resources, constructed a map of the potentiometric surface of the Ozark aquifer for 2006?2007. The map can be compared to previously constructed potentiometric-surface maps by Emmett and others (1978) and Imes (1989) to evaluate changes in ground-water flow directions, but the comparison is beyond the scope of this report.

Scientific Investigations Map↗

Review of Trace-Element Field-Blank Data Collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Program, May 2004-January 2008

Trace-element quality-control samples (for example, source-solution blanks, field blanks, and field replicates) were collected as part of a statewide investigation of groundwater quality in California, known as the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB) to assess and monitor the quality of groundwater resources used for drinking-water supply and to improve public knowledge of groundwater quality in California. Trace-element field blanks were collected to evaluate potential bias in the corresponding environmental data. Bias in the environmental data could result from contamination in the field during sample collection, from the groundwater coming into contact with contaminants on equipment surfaces or from other sources, or from processing, shipping, or analyzing the samples. Bias affects the interpretation of environmental data, particularly if any constituents are present solely as a result of extrinsic contamination that would have otherwise been absent from the groundwater that was sampled. Field blanks were collected, analyzed, and reviewed to identify and quantify extrinsic contamination bias. Data derived from source-solution blanks and laboratory quality-control samples also were considered in evaluating potential contamination bias. Eighty-six field-blank samples collected from May 2004 to January 2008 were analyzed for the concentrations of 25 trace elements. Results from these field blanks were used to interpret the data for the 816 samples of untreated groundwater collected over the same period. Constituents analyzed were aluminum (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), boron (B), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), lithium (Li), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), selenium (Se), silver (Ag), strontium (Sr), thallium (Tl), tungsten (W), uranium (U), vanadium (V), and zinc (Zn). The detection frequency and the 90th percentile concentration at greater than 90 percent confidence were determined from the field-blank data for each trace element, and these results were compared to each constituent's long-term method detection level (LT-MDL) to determine whether a study reporting level (SRL) was necessary to ensure that no more than 10 percent of the detections in groundwater samples could be attributed solely to contamination bias. Only two of the trace elements analyzed, Li and Se, had zero detections in the 86 field blanks. Ten other trace elements (Sb, As, Be, B, Cd, Co, Mo, Ag, Tl, and U) were detected in fewer than 5 percent of the field blanks. The field-blank results for these constituents did not necessitate establishing SRLs. Of the 13 constituents that were detected in more than 5 percent of the field blanks, six (Al, Ba, Cr, Mn, Hg, and V) had field-blank results that indicated a need for SRLs that were at or below the highest laboratory reporting levels (LRL) used during the sampling period; these SRLs were needed for concentrations between the LT-MDLs and LRLs. The other seven constituents with detection frequencies above 5 percent (Cu, Fe, Pb, Ni, Sr, W, and Zn) had field-blank results that necessitated SRLs greater than the highest LRLs used during the study period. SRLs for these seven constituents, each set at the 90th percentile of their concentrations in the field blanks, were at least an order of magnitude below the regulatory thresholds established for drinking water for health or aesthetic purposes; therefore, reporting values below the SRLs as less than or equal to (=) the measured value would not prevent the identification of values greater than the drinking-water thresholds. The SRLs and drinking-water thresholds, respectively, for these 7 trace elements are Cu (1.7 ?g/L and 1,300

Scientific Investigations Report↗

Water-quality characteristics of Michigan's inland lakes, 2001-10

The U.S. Geological Survey and the Michigan Department of Environmental Quality (MDEQ) jointly monitored for selected water-quality constituents and properties of inland lakes during 2001–10 as part of Michigan's Lake Water-Quality Assessment program. During 2001–10, 866 lake basins from 729 inland lakes greater than 25 acres were monitored for baseline water-quality conditions and trophic status. This report summarizes the water-quality characteristics and trophic conditions of the monitored lakes throughout the State; the data include vertical-profile measurements, nutrient measurements at three discrete depths, Secchi-disk transparency (SDT) measurements, and chlorophyll a measurements for the spring and summer, with major ions and other chemical indicators measured during the spring at mid-depth and color during the summer from near-surface samples. In about 75 percent of inland lake deep basins (index stations), trophic characteristics were associated with oligotrophic or mesotrophic conditions; 5 percent or less were categorized as hypereutrophic, and 80 percent of hypereutrophic lakes had a maximum depth of 30 feet or less. Comparison of spring and summer measurements shows that water clarity based on SDT measurements were clearer in the spring than in the summer for 63 percent of lakes. For near-surface measurements made in spring, 97 percent of lakes can be considered phosphorus limited and less than half a percent nitrogen limited; for summer measurements, 96 percent of lakes can be considered phosphorus limited and less than half a percent nitrogen limited. Spatial patterns of major ions, alkalinity, and hardness measured in the spring at mid-depth all showed lower values in the Upper Peninsula of Michigan and a southward increase toward the southern areas of the Lower Peninsula, though the location of increase varied by constituent. A spatial analysis of the data based on U.S. Environmental Protection Agency Level III Ecoregions separated potassium, sulfate, and chloride concentrations fairly well, with a pattern of lower values in northern ecoregions trending toward higher values in southern ecoregions; lower and higher concentrations of magnesium, hardness, calcium, and alkalinity were well separated, but middle-range concentrations in central Michigan ecoregions were mixed. The highest concentrations of chloride and sodium were in the southeastern area of the Lower Peninsula. Lakes with multiple basins showed few statistically significant differences in constituent concentrations at the 95-percent confidence level among combinations of depths between basins. The most statistically significant differences were found for water temperature, with significant differences in somewhat less than half the combinations in the spring and just a few combinations in the summer. The lack of significant differences between major basins of multibasin lakes indicates that monitoring of trophic characteristics in all major basins might not be necessary for the majority of constituents in future sampling programs. Trophic characteristics based on the 2001–10 dataset were compared to trophic characteristics resulting from other Michigan sampling programs, including the volunteer Cooperative Lakes Monitoring Program coordinated by the MDEQ (measurements on 250 lakes in 2011), trophic-state predictions produced by relating existing measurements to remotely sensed data (measurements for about 3,000 lakes), and the National Lakes Assessment (NLA) statistically valid, probability-designed lakes program (measurements for 50 lakes in Michigan and about 1,100 lakes nationally). A higher percentage of oligotrophic lakes resulted when using SDT from the volunteer data and the 2001–10 dataset than when using the predicted measurements from remotely sensed data or the NLA. Comparing trophic characteristics from differently designed programs provides multiple interpretations of lake water-quality status in Michigan lakes. No directional statistically significant difference was found at the 95-percent confidence level among historical nutrients and trophic characteristics when comparing 445 lakes with historical data for 1974–84 with the 2001–10 dataset, though SDT did show statistically significant differences at the 95-percent confidence level. Depending on the primary indicator, 50–66 percent of lakes did not change trophic-status class, 13–23 percent moved towards the oligotrophic end of the TSI scale, and 20–25 percent moved a class towards the eutrophic end of the TSI scale. Increasing percentages of urban-dominant land cover in the drainage areas of lakes had a more positive correlation with chloride concentration than did increased percentages of other land-cover classes; there was also a slight correlation of urban-dominant land cover and calcium concentration. Removing data for lakes in southeastern Lower Michigan, known from previous reports to be higher in chloride, still resulted in a positive relation even though the coefficient of determination (R 2 value) decreased from 0.55 to 0.39. Dominant land-cover drainage areas were not strongly related to nutrients with respect to a linear relation, nor were lake drainage-area sizes.

Michigan↗

Maps and grids of hydrogeologic information created from standardized water-well drillers’ records of the glaciated United States

As part of the National Water Availability and Use Program established by the U.S. Geological Survey (USGS) in 2005, this study took advantage of about 14 million records from State-managed collections of water-well drillers’ records and created a database of hydrogeologic properties for the glaciated United States. The water-well drillers’ records were standardized to be relatively complete and error-free and to provide consistent variables and naming conventions that span all State boundaries. Maps and geospatial grids were developed for (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The information included in these maps and grids is required for most assessments of groundwater availability, in addition to having applications to studies of groundwater flow and transport. The texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity were based on an assumed range of hydraulic conductivity values for coarse- and fine-grained deposits and should only be used with complete awareness of the methods used to create them. However, the maps and grids of texture-based estimated equivalent hydraulic conductivity and transmissivity may be useful for application to areas where a range of measured values is available for re-scaling. Maps of hydrogeologic information for some States are presented as examples in this report but maps and grids for all States are available electronically at the project Web site (USGS Glacial Aquifer System Groundwater Availability Study, http://mi.water.usgs.gov/projects/WaterSmart/Map-SIR2015-5105.html ) and the Science Base Web site, https://www.sciencebase.gov/catalog/item/58756c7ee4b0a829a3276352 .

Alaska, Connecticut, Idaho, Illinois, Indiana, Iow↗

Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii↗

Guidelines for Evaluating Ground-Water Flow Models

Ground-water flow modeling is an important tool frequently used in studies of ground-water systems. Reviewers and users of these studies have a need to evaluate the accuracy or reasonableness of the ground-water flow model. This report provides some guidelines and discussion on how to evaluate complex ground-water flow models used in the investigation of ground-water systems. A consistent thread throughout these guidelines is that the objectives of the study must be specified to allow the adequacy of the model to be evaluated.

Scientific Investigations Report↗

Water Budgets for Coeur d'Alene Lake, Idaho, Water Years 2000-2005

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, calculated annual water budgets and a mean annual water budget for Coeur d'Alene Lake, Idaho, for water years 2000 through 2005. Mean annual inflow to Coeur d'Alene Lake, including precipitation, was about 167,110 million cubic feet. Mean annual outflow, including evaporation, but excluding wastewater effluent to the Spokane River, was about 167,850 million cubic feet. The amount of water lost from Coeur d'Alene Lake and the Spokane River to the Spokane Valley-Rathdrum Prairie aquifer was estimated at 7,250 million cubic feet. Mean annual precipitation into Coeur d'Alene Lake was 3,267 million cubic feet, which exceeded mean annual evaporation of 2,483 million cubic feet. Withdrawals directly from the lake and from wells within a 1,000 foot buffer of the lakeshore for domestic and municipal water uses were reported. However, only the estimate for the consumptive use part of the withdrawals, 265 million cubic feet, was considered in the budget. Mean annual change in lake storage resulted in a net loss of about 49 million cubic feet. The mean annual residual value was about -8,310 million cubic feet.

Scientific Investigations Report↗

Provisional maps of thermal areas in Yellowstone National Park, based on satellite thermal infrared imaging and field observations

Maps that define the current distribution of geothermally heated ground are useful toward setting a baseline for thermal activity to better detect and understand future anomalous hydrothermal and (or) volcanic activity. Monitoring changes in the dynamic thermal areas also supports decisions regarding the development of Yellowstone National Park infrastructure, preservation and protection of park resources, and ensuring visitor safety. Because of the challenges associated with field-based monitoring of a large, complex geothermal system that is spread out over a large and remote area, satellite-based thermal infrared images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were used to map the location and spatial extent of active thermal areas, to generate thermal anomaly maps, and to quantify the radiative component of the total geothermal heat flux. ASTER thermal infrared data acquired during winter nights were used to minimize the contribution of solar heating of the surface. The ASTER thermal infrared mapping results were compared to maps of thermal areas based on field investigations and high-resolution aerial photos. Field validation of the ASTER thermal mapping is an ongoing task. The purpose of this report is to make available ASTER-based maps of Yellowstone’s thermal areas. We include an appendix containing the names and characteristics of Yellowstone’s thermal areas, georeferenced TIFF files containing ASTER thermal imagery, and several spatial data sets in Esri shapefile format.

Wyoming↗

Regression models to estimate real-time concentrations of selected constituents in two tributaries to Lake Houston near Houston, Texas, 2005-07

In December 2005, the U.S. Geological Survey in cooperation with the City of Houston, Texas, began collecting discrete water-quality samples for nutrients, total organic carbon, bacteria (total coliform and Escherichia coli), atrazine, and suspended sediment at two U.S. Geological Survey streamflow-gaging stations upstream from Lake Houston near Houston (08068500 Spring Creek near Spring, Texas, and 08070200 East Fork San Jacinto River near New Caney, Texas). The data from the discrete water-quality samples collected during 2005-07, in conjunction with monitored real-time data already being collected - physical properties (specific conductance, pH, water temperature, turbidity, and dissolved oxygen), streamflow, and rainfall - were used to develop regression models for predicting water-quality constituent concentrations for inflows to Lake Houston. Rainfall data were obtained from a rain gage monitored by Harris County Homeland Security and Emergency Management and colocated with the Spring Creek station. The leaps and bounds algorithm was used to find the best subsets of possible regression models (minimum residual sum of squares for a given number of variables). The potential explanatory or predictive variables included discharge (streamflow), specific conductance, pH, water temperature, turbidity, dissolved oxygen, rainfall, and time (to account for seasonal variations inherent in some water-quality data). The response variables at each site were nitrite plus nitrate nitrogen, total phosphorus, organic carbon, Escherichia coli, atrazine, and suspended sediment. The explanatory variables provide easily measured quantities as a means to estimate concentrations of the various constituents under investigation, with accompanying estimates of measurement uncertainty. Each regression equation can be used to estimate concentrations of a given constituent in real time. In conjunction with estimated concentrations, constituent loads were estimated by multiplying the estimated concentration by the corresponding streamflow and applying the appropriate conversion factor. By computing loads from estimated constituent concentrations, a continuous record of estimated loads can be available for comparison to total maximum daily loads. The regression equations presented in this report are site specific to the Spring Creek and East Fork San Jacinto River streamflow-gaging stations; however, the methods that were developed and documented could be applied to other tributaries to Lake Houston for estimating real-time water-quality data for streams entering Lake Houston.

Scientific Investigations Report↗

Effects of including surface depressions in the application of the Precipitation-Runoff Modeling System in the Upper Flint River Basin, Georgia

This report documents an extension of the Precipitation Runoff Modeling System that accounts for the effect of a large number of water-holding depressions in the land surface on the hydrologic response of a basin. Several techniques for developing the inputs needed by this extension also are presented. These techniques include the delineation of the surface depressions, the generation of volume estimates for the surface depressions, and the derivation of model parameters required to describe these surface depressions. This extension is valuable for applications in basins where surface depressions are too small or numerous to conveniently model as discrete spatial units, but where the aggregated storage capacity of these units is large enough to have a substantial effect on streamflow. In addition, this report documents several new model concepts that were evaluated in conjunction with the depression storage functionality, including: ?hydrologically effective? imperviousness, rates of hydraulic conductivity, and daily streamflow routing. All of these techniques are demonstrated as part of an application in the Upper Flint River Basin, Georgia. Simulated solar radiation, potential evapotranspiration, and water balances match observations well, with small errors for the first two simulated data in June and August because of differences in temperatures from the calibration and evaluation periods for those months. Daily runoff simulations show increasing accuracy with streamflow and a good fit overall. Including surface depression storage in the model has the effect of decreasing daily streamflow for all but the lowest flow values. The report discusses the choices and resultant effects involved in delineating and parameterizing these features. The remaining enhancements to the model and its application provide a more realistic description of basin geography and hydrology that serve to constrain the calibration process to more physically realistic parameter values.

Georgia↗

Shallow groundwater quality in the Village of Patchogue, Suffolk County, New York

The onsite disposal of wastewater within the Patchogue River Basin-a riverine estuary that discharges into Great South Bay, Suffolk County, Long Island, N.Y. -has adversely affected water quality and aquatic habitats within both the tidal and non-tidal portions of the river. In response to increased development within the approximately 14 square mile basin, the Village of Patchogue has expanded efforts to manage and protect the local groundwater resources, which sustain freshwater base flow and aquatic habitats. Water-quality samples from 10 shallow wells within the Village were collected in March 2009, before the start of seasonal fertilizer application, to document the effects of onsite wastewater disposal on groundwater discharging into the Patchogue River. Each sample was analyzed for physical properties (pH, dissolved oxygen, specific conductance, and temperature), nutrients, organic carbon, major ions, and trace elements. Water samples from eight wells were analyzed for stable isotopes of nitrogen. The nitrate concentration in one well was 40 milligrams per liter (mg/L), which exceeded the U.S. Environmental Protection Agency (USEPA) and New York State Department of Health (NYSDOH) maximum contamination level in drinking water of 10 mg/L. Sodium concentrations at nine wells exceeded the USEPA Drinking Water Advisory Taste Threshold of 60 mg/L. Dissolved iron concentrations at three wells exceeded the NYSDOH and USEPA Secondary Drinking Water Standard of 300 micrograms per liter (?g/L). Nitrogen isotope signatures (d15N) were determined and compared with those reported from previous studies in Nassau and Suffolk Counties to identify possible sources of the nitrate. Local variations in measured ammonia, nitrate, total nitrogen, phosphorus, and organic carbon concentrations and d15N signatures indicate that nitrate enters the surficial aquifer from several sources (fertilizer, septic waste, and animal waste) and reflects biogeochemical processes such as denitrification.

Scientific Investigations Report↗

Determination of study reporting limits for pesticide constituent data for the California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project, 2004–2018—Part 1: National Water Quality Schedules 2003, 2032, or 2033, and 2060

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality of groundwater resources used for public and domestic drinking water supplies in the State of California, to monitor and evaluate changes to that quality, to investigate the human and natural factors controlling water quality, and to improve the availability of comprehensive groundwater quality data and information. Between May 18, 2004, and May 3, 2018, the GAMA-PBP collected 3001 groundwater samples for analysis of pesticide constituents by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL)(note that ‘pesticide constituents’ includes parent compounds and degradates). Of these samples, 2994 were analyzed for pesticide constituents on schedules 2003, 2032, or 2033 (65 to 84 constituents), and 840 were analyzed for pesticide constituents on schedule 2060 (58 constituents). The original dataset reported by the NWQL to the USGS National Water Information System (NWIS) database contained a total of 2,688 detections of 78 pesticide constituents and 253,825 non-detections. In this original dataset, 33 percent of the 3,001 samples analyzed had reported detections of one or more pesticide constituents. This report describes the GAMA-PBP data-quality objectives for pesticide data, the procedures used to establish study reporting limits, and use of those reporting limits to censor the data from the NWQL so that the final data published by the GAMA-PBP meet these data-quality objectives. The final GAMA-PBP dataset for samples collected from May 2004 to May 2018, after censoring, had a total of 1,632 detections of 37 pesticide constituents. In the final GAMA-PBP dataset, 25 percent of the 3,001 samples analyzed had detections of one or more pesticide constituents. The presence of pesticides in groundwater is commonly evaluated by calculating detection frequencies. Detection frequencies for pesticides are sensitive to detection limits and method performance for concentrations near those limits; therefore, the two primary data quality issues addressed in the GAMA-PBP data-quality objectives for pesticides are (1) establishing criteria for classifying data from the laboratory as detections or non-detections for the purpose of data reporting by the project and (2) accounting for changes in analytical methods or method performance over time. The GAMA-PBP addresses these issues by developing study reporting limits that are used as the boundary between detections and non-detections for the reporting of GAMA-PBP results. These reporting limits are defined from method detection limits (MDLs) provided by the NWQL, unless examination of results from laboratory set blanks (LSBs) and GAMA-PBP field blanks indicates that a higher concentration censoring limit is warranted. The GAMA-PBP selected the MDL as the primary choice for defining study reporting limits for consistency with U.S. Environmental Protection Agency (EPA) guidelines for reporting detections of pesticides and other organic constituents. A five-step procedure is used to develop study reporting limits and censor the GAMA-PBP dataset accordingly. The effect of the censoring at each step is described to provide information about the relative effect of each step on the overall censoring of the dataset. Steps 1 and 2 can be implemented at the time the data are received, whereas steps 3−5 require information accumulated over an extended period. Step 1: Reject results that were most likely the result of specific contamination instances attributable to unusual field or laboratory conditions during sample collection or processing. Two such instances were identified, leading to rejection of 25 detections, which were assigned a data-quality indicator code of “Q” for “reviewed and rejected” in the NWIS database. Step 2: Use the NWQL MDLs in effect at the time each sample was analyzed as the reporting limit. A total of 506 detections were censored on this basis. Step 3: Use the maximum MDL established by the NWQL during July 2004–August 2018 (MDLmax) as the reporting limit. The rationale for using the MDLmax as the reporting limit is based primarily on the observation that the concentrations of MDLs generally increased over time. A total of 438 detections were censored on this basis. Step 4: Use the LSBs to identify periods of greater potential laboratory contamination bias and define raised reporting limits to be used during those periods. These periods were defined by using a moving average detection frequency approach. For consistency with the NWQL procedures for defining raised reporting limits on the basis of detections in LSBs, the raised reporting limits were defined as equal to three times the highest concentration measured in an LSB during the period. A total of 25 detections in groundwater samples analyzed during periods of increased laboratory contamination bias were censored. Step 5: Use the LSBs and field blanks to identify potential contamination bias from field or laboratory processes outside of the time periods identified in step 4. The NWQL protocols were used to define the MDLs from blanks analyzed outside of the periods identified in step 4. If an MDL defined from blanks was greater than the MDLmax, the MDL defined from blanks was used to censor the data. One constituent had a study reporting limit defined on this basis, and a total of 62 detections in groundwater samples were censored. As of 2019, the USGS NWIS database does not have the capability to store both the original value reported by the NWQL and the final value published by the GAMA-PBP that reflects application of the quality-control censoring described in this report. In the interim, while this capability is developed, the 1,031 results censored in steps 2−5 are blocked from public release in NWIS, and the GAMA-PBP has published the original and final values in a USGS data release accompanying this report. The entire GAMA-PBP final dataset for pesticide constituents on schedules 2003, 2032, or 2033, or on schedule 2060 is publicly available in that USGS data release, through the USGS GAMA-PBP public web portal, and through the California State Water Resources Control Board GAMA public groundwater information system.

California↗

Chemical evaluation of water and gases collected from hydrothermal systems located in the central Aleutian arc, August 2015

Five volcanic-hydrothermal systems in the central Aleutians Islands were sampled for water and gas geochemistry in 2015 to provide baseline data to help predict future volcanic unrest. Some areas had not been sampled in 20–30 years (Makushin volcano, Geyser Bight), and other areas had minimal to no prior sampling (Tana volcano and Fisher Caldera). The chemical and isotopic data of the waters show a wide variety of characteristics typical of hydrothermal settings. Stable isotopic analyses of the waters show no evidence for primary magmatic water, rather that waters have a meteoric origin that is variably influenced by boiling and evaporation processes. The carbon and helium isotopic analyses of gases suggest they contain a primary magmatic component typical of the upper mantle at most locations, and the CO 2 /S ratios show that these gases have been modified by interactions with groundwater along the flow paths. Some areas demonstrate stable compositions since the last sampling (for example, Akutan hydrothermal areas), with some being remarkably steady over very long periods (for example, Geyser Bight). Other areas show modifications because of either lower amounts of upwelling from hydrothermal sources or lower amounts of magmatic influence on the surface chemistry (for example, Upper Glacial valley of Makushin, an informally named valley leading south of the volcano toward Makushin Bay to the south). Finally, this report highlights that previously unsampled regions in the Aleutian Islands, such as Tana volcano and Fisher Caldera (the latter found to have one of the highest helium isotopic signatures ever measured in the Aleutian Islands), show evidence of ongoing subsurface magmatism that warrants continued investigation in terms of volcanic hazard.

Alaska↗