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World minerals outlook—Cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium through 2029

Given the rapid expansion in the demand for mineral commodities that underpin worldwide economic growth and technological advancement, information regarding expected country-level mine production and production capacity is becoming increasingly important to industry stakeholders, end users, and policymakers. Production capacity can limit future supply, depending on how rapidly that capacity is able to expand. Current capacity can be evaluated on the basis of past production. Decreases to future capacity can be taken into account from announcements of planned shutdowns of mines or processing facilities, which are frequently publicized well in advance of such closures. Likewise, capacity expansions, which usually involve multiple stages—such as permitting, financing, and construction (all of which take time)—can also be estimated. As such, it is possible to evaluate midterm future capacity based on estimates of today’s capacities along with consideration of future investment plans. This World Minerals Outlook provides estimated capacities for cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium for 2025 through 2029. The results of this analysis indicate that two mineral commodities important to the manufacture of lithium-ion batteries—cobalt and lithium—are expected to have large capacity growth in the next few years, likely owing to expectations for increased demand for these batteries. For gallium, helium, palladium, and platinum, capacity is expected to remain stable or exhibit moderate growth. Still, these expected capacity levels are higher than current production, allowing for future production growth. The production capacity outlook is opaque for magnesium and titanium metal, which have a significant fraction of current production in nonmarket economies, such as China and Russia. Ultimately, though, where free market conditions prevail, full utilization of capacity potential for those commodities is likely to depend on supply deficits and prices that are above production costs.

Scientific Investigations Report

Testing rate‐and‐state predictions of aftershock decay with distance

We analyze aftershocks of the 2019 M 7.1 Ridgecrest mainshock and isolated M 5–6 mainshocks in southern California to test predictions made by the rate‐and‐state friction model of Dieterich (1994) . Rate‐and‐state friction predicts that the seismicity rate after a stress step follows Omori decay, where the Omori c ‐value, which is the saturation in aftershock rate observed at small times, is larger for smaller stress steps. Put in the context of an aftershock sequence, this predicts that the Omori c ‐value will be systematically larger at greater distances from the mainshock. To our knowledge, this predicted effect has not been observed. In part this may be because the Omori c ‐value is difficult to measure because it often reflects short‐term catalog incompleteness rather than a true saturation in aftershock rate. We explore the dependence of the Omori c ‐value on the distance to the mainshock by applying the “ a ‐positive” method ( van der Elst and Page, 2023 ). This method is insensitive to short‐term aftershock incompleteness and allows resolution of the true aftershock rate deep into the mainshock coda. For aftershocks of the Ridgecrest mainshock and stacked M 5–6 mainshocks, we observe systematic differences in early aftershock rates, relative to mainshock distance, consistent with the predictions of rate‐and‐state friction. Furthermore, for the larger Ridgecrest dataset, we observe that aftershocks nearer to the mainshock start earlier, and we resolve a flattening of the Omori curve consistent with a larger Omori c ‐value for the farthest aftershocks, as predicted by Dieterich (1994) .

Seismological Research Letters

A global database of soil microbial phospholipid fatty acids and enzyme activities

Soil microbes drive ecosystem function and play a critical role in how ecosystems respond to global change. Research surrounding soil microbial communities has rapidly increased in recent decades, and substantial data relating to phospholipid fatty acids (PLFAs) and potential enzyme activity have been collected and analysed. However, studies have mostly been restricted to local and regional scales, and their accuracy and usefulness are limited by the extent of accessible data. Here we aim to improve data availability by collating a global database of soil PLFA and potential enzyme activity measurements from 12,258 georeferenced samples located across all continents, 5.1% of which have not previously been published. The database contains data relating to 113 PLFAs and 26 enzyme activities, and includes metadata such as sampling date, sample depth, and soil pH, total carbon, and total nitrogen. This database will help researchers in conducting both global- and local-scale studies to better understand soil microbial biomass and function.

Scientific Data

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Post-glacial stratigraphy and late Holocene record of great Cascadia earthquakes in Ozette Lake, Washington, USA

Ozette Lake is an ~100-m-deep coastal lake located along the outer coast of the Olympic Peninsula (Washington, USA); it is situated above the locked portion of the northern Cascadia megathrust but also relatively isolated from active crustal faults and intraslab earthquakes. Here we present a suite of geophysical and geological evidence for earthquake-triggered mass transport deposits (MTDs) and related turbidite deposition in Ozette Lake since ca. 14 ka. Comprehensive high-resolution bathymetry data, seismic reflection profiles, and sediment cores are used to characterize the post-glacial stratigraphic framework and examine paleoseismic evidence in the lacustrine sediments. Stacked sequences of MTDs along the steep eastern flanks of the lake appear to grade basin-ward from thick, chaotic, blocky masses to thin, parallel-bedded turbidite beds. The discrete turbidite event layers are separated by fine-grained (silt and clay) lake sedimentation. The event layers are observed throughout the lake, but the physical characteristics of the deposits vary considerably depending on proximity to primary depocenters, steep slopes, and subaqueous deltas. A total of 30–34 event deposits are observed in the post-glacial record. Radiometric dating was used to reconstruct a detailed sedimentation history over the last ~5.5 k.y., develop an age model, and estimate the recurrence (365–405 yr) for the most recent 12 event layers. Based on sedimentological characteristics, temporal overlap with other regional paleoseismic chronologies, and recurrence estimates, at least 10 of the dated event layers appear to be sourced from slope failures triggered by intense shaking during megathrust ruptures; the recurrence interval for these 10 events is 440–560 yr. Thus, Ozette Lake contains one of the longest and most robust geological records of repeated shaking along the northern Cascadia subduction zone.

Washington

Utilization of multiple geochronology techniques to constrain the age of laterization and mineralization of the world-class Mount Weld rare earth element deposit, Western Australia

Pervasive chemical weathering on stable cratons may form thick regoliths and elemental enrichment, but constraining the age of regolith formation is challenging. In this study we utilize multiple geochronological techniques on different minerals from the world-class Mount Weld rare earth element (REE) deposit, formed by lateritic weathering of a carbonatite, to constrain the age of formation and provide insight into landscape evolution. The oldest dates, ca. 100 to 38 Ma, are from Lu-Hf dating of churchite [HREE(PO 4 )·2(H 2 O)], a heavy REE phosphate mineral. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane [K(Mn 4+ ,Mn 2+ )₈O₁₆] yielded dates from ca. 40 to 27 Ma. Similarly, (U-Th)/He geochronology of goethite [FeO(OH)] yielded dates ranging from ca. 45 to 19 Ma. Integrating results into regional constraints, suggests 1) churchite formed by mineral saturation in a karst-like setting below the water table from ca. 100 to 40 Ma, 2) with minor uplift and erosion, cryptomelane and goethite formed at or near the water table between ca. 45 and 19 Ma, 3) after ca. 15 to 10 Ma chemical weathering within the profile had ended. Other studies document that the region experienced minimal uplift and a wet, warm climate from ca. 100 Ma to 15 Ma. These conditions and the high carbonate content of the carbonatite promote extensive chemical weathering, a deep weathering profile, and the preservation of the weathered section. This study highlights the use of multiple geochronological techniques utilizing different minerals to provide insight into how laterites form and to constrain the timing and history of the formation of this important mineral deposit.

Western Australia

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

Determining Volcanic Risk in Auckland (DEVORA) Research Programme—A transdisciplinary approach to address the challenge of distributed volcanism in an urban environment

The Determining Volcanic Risk in Auckland (DEVORA) Research Programme was launched in 2008 to address the challenges associated with monogenetic volcanism in an urban setting and to enhance volcanic risk management in Tāmaki Makaurau Auckland in Aotearoa New Zealand. It is a multi-agency, increasingly transdisciplinary (defined here as research that transcends traditional disciplinary boundaries by integrating diverse types of knowledge, perspectives, and methods from academic and non-academic participants to create novel solutions to complex problems), and collaborative research program jointly led by Waipapa Taumata Rau University of Auckland and Earth Sciences New Zealand (ESNZ; formerly GNS Science), with core funding from Natural Hazards Commission Toka Tū Ake (NHC; formerly the Earthquake Commission, EQC) and Te Kaunihera o Tāmaki Makaurau Auckland Council (AC). The primary research focus of DEVORA is to investigate the geologic history, volcanic hazards, and risk posed by the basaltic intraplate Auckland Volcanic Field. Disruption from ash fall and gas from other Aotearoa New Zealand volcanoes is also considered. DEVORA’s work to explore exposure and vulnerability in Tāmaki Makaurau Auckland is also useful for assessing risks from other non-volcanic natural hazards, such as seismic and tsunami hazards. The greater Tāmaki Makaurau Auckland region has an ethnically and socio-economically diverse population of approximately 1.7 million, representing about one-third of the Aotearoa New Zealand population, and hosts critical infrastructure of national significance. The size and nature of the populace, consequential economic base, and important infrastructure within Tāmaki Makaurau Auckland mean that the effects of a volcanic eruption would be felt nationally, including through the disruption of air travel to Aotearoa New Zealand. The hazards from such an eruption could potentially affect hundreds of thousands of people, businesses, and lifelines (critical infrastructure). A considerable challenge for emergency and risk managers is the monogenetic nature of the volcanic field. It is not known where or when the next eruption will occur, how much warning we may get before an eruption, nor how an eruption and its effects might unfold. In this contribution, we highlight the concept and collaborative intent of the DEVORA Programme and show how it has evolved over the 16 years since its inception. We describe how DEVORA has unified more than 100 researchers (including more than 50 graduate students) and numerous stakeholders to address key issues facing Tāmaki Makaurau Auckland and describe how research findings are being implemented into policy and communicated to stakeholder agencies and the public. We also illustrate the broader influence of the DEVORA Programme and provide some learnings that might benefit others embarking on similar integrated projects, especially those focused on distributed volcanism in and near populated areas.

Auckland

Vegetation cover and composition in environments surrounding uranium mines in the Grand Canyon ecosystem, Northern Arizona

Mining uranium from breccia-pipe deposits in the greater Grand Canyon region has occurred since the mid-1900s. However, possible ecosystem contamination with harmful levels of radionuclides may have occurred due to mining activities in the 21st century. In response, a 20-year Federal moratorium on new mining claims in the Grand Canyon watershed was initiated in 2012, to allow time to evaluate the potential effects of uranium exploration and mining on human health, wildlife, and water resources. This moratorium, nor the 2023 designation of the “Baaj Nwaavjo I’tah Kukveni–Ancestral Footprints of the Grand Canyon National Monument,” precludes operation or development of mining claims predating 2012. Vegetation is a core ecosystem component that may be affected by uranium mining (for instance, through uptake and storage of radionuclides from the air or soil) or may act as a vector of exposure to wildlife, livestock, and humans (for instance, via their consumption of contaminated plant tissues). To provide baseline information about the plant communities associated with uranium mines in the Grand Canyon region, the U.S. Geological Survey surveyed an approximately 200-meter-wide buffer surrounding four breccia-pipe deposits, each in a unique stage of mine development, and at one reference area (a livestock water tank) that underwent ground disturbance but contains no mineral deposits. We sectioned the buffer zones into 0.65–4.52 hectare plots, within which we (1) inventoried all plant species, (2) measured percent cover of plant species, plant functional groups, and ground surface types (dark cyanobacteria, lichen, moss, bedrock, rock, embedded litter, duff, plant bases, and bare soil) using line-point intercept, and (3) measured length and frequency of gaps between perennial plant canopies using canopy gap intercept. We found that plant composition at the mines and the reference area differed from one another but were all characteristic of expected regional vegetation patterns. We provide this data summary as potential baseline information for future research and management efforts.

Arizona

Small earthquake moment magnitude and implications for frequency–magnitude scaling of injection induced earthquakes of the Raton Basin

Accurate estimation of earthquake source parameters—such as moment magnitudes, corner frequencies, and stress drops—is essential for improving seismic hazard assessments and understanding earthquake physics. In this study, moment magnitudes ( M W ) are calculated for 31,581 earthquakes associated with wastewater injection in the Raton Basin (located along the border between northern New Mexico and southern Colorado) between 2016 and 2024 using radiative transfer theory to fit coda decay envelopes. Our results show that it is feasible to estimate moment magnitudes down to M W ~1 with coda envelopes from a small local monitoring network. Significant differences were found between M W and local magnitudes ( M L ) for small earthquakes ( M < 3.0). A linear relationship was optimized to convert M L to M W : M W = 0.7 M L + 0.96 and M W = 0.73 M L + 0.99 (for the events reported by the U.S. Geological Survey), which can be applied in future studies of Raton Basin seismicity. We find that b -values calculated employing different methods and using M L are approximately 1.0, while those using M W range from 1.2 to 1.4. A larger estimate of the b -value could influence interpretations of the statistical behavior of earthquakes associated with injection and consequently seismic hazard assessments based on a magnitude–frequency distribution. The potential differences between local versus moment magnitude-based earthquake statistics should be considered in other seismically active regions.

Colorado, New Mexico

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington

The Great Lakes Geologic Mapping Coalition—Working collaboratively to understand the geology of the Great Lakes Region

Introduction The Great Lakes Geologic Mapping Coalition (GLGMC), commonly referred to as the “Coalition,” is a partnership between the U.S. Geological Survey (USGS), the U.S. States of Illinois, Indiana, Michigan, Minnesota, New York, Ohio, Pennsylvania, and Wisconsin and the Canadian province of Ontario. The member States receive funding for geologic mapping work from the USGS National Cooperative Geologic Mapping Program (NCGMP), whereas Ontario participates as a nonfunded partner. The mission of the GLGMC is to produce three-dimensional (3D) geologic maps that depict unconsolidated sediments and near-surface bedrock in the Great Lakes region of North America. Geologic maps are the basis of most earth science investigations and help support resource exploration (energy, minerals, groundwater), natural hazard mitigation, infrastructure development, and land-use planning, all of which can be used to advance economic development and strengthen national security in the Great Lakes region. During the last few million years, the Great Lakes region has experienced repeated glacial advances and retreats, leaving behind extensive sediments, abundant natural resources, and widespread effects on the underlying bedrock geology (Swezey and others, 2022). Linked by shared histories of past glaciations, industrial agriculture, and legacy automotive, coal, steel, and manufacturing industries, the GLGMC member States collaborate to improve the understanding of the 3D distribution of the sediments overlying the region’s bedrock (fig. 1). Developing a comprehensive subsurface 3D framework of this glaciated terrain can provide earth science data to policymakers at all levels. These insights facilitate informed decisions on the exploration, use, and protection of vital resources, such as critical minerals, industrial materials, and aquifers, thereby supporting economic prosperity and the well-being of the citizens of this region. Since its inception in 1998, the Coalition has completed more than 100 geologic mapping projects across the Great Lakes region. Each project aims to deliver geologic maps, 3D datasets, and other information that improves understanding of the geology of the Great Lakes region, with an emphasis on economic and water resources. Key deliverables include 3D geologic maps and models typically portraying sediment thickness, often derived from top-of-bedrock and borehole data. These products are developed through a combination of fieldwork, subsurface modeling, and the collection and analysis of rock and sediment cores. To support Coalition goals, member States collaborate with scientists working on related STATEMAP, EDMAP, and FEDMAP projects. Coalition scientists also engage with Tribal Nations in the Great Lakes region to ensure that Tribal interests pertaining to Coalition work are addressed. Through this collaboration, the Coalition unites the efforts of State, Federal, and Tribal Nation stakeholders to advance geologic data production and enhance understanding of the geologic resources of the Great Lakes region.

Illinois, Indiana, Michigan, Minnesota, New York,

Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Hypothetical CO2 leakage into, and hydrological plume management within, an underground source of drinking water at a proposed CO2 storage facility, Kemper County, Mississippi, USA

A large Geologic Carbon Sequestration (GCS) hub has been proposed in Kemper County, Mississippi. The target injection interval consists of numerous Cretaceous-aged deep saline aquifers overlain by a competent and extensive regional sealing layer. Above the seal, the deepest Underground Source of Drinking Water (USDW) at the site is the Eutaw aquifer of the Eutaw Group and McShan Formation, undifferentiated. To assess potential risks of leakage from the deep sequestration reservoir, a model of a portion of the Cretaceous Eutaw Group was constructed in this study. Simulations tested various permeabilities, hypothetical leakage rates, and plume mitigation strategies utilizing existing wells. Results suggest that, under the influence of regional groundwater flow fields, leaking CO 2 would effectively bypass the existing wells, and to influence this migration would require very large water extraction rates. Therefore, to ensure plume detection, monitoring for leakage at the injection wells themselves is very important.

Mississippi

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus

Constraining large magnitude event source and path effects using ground motion simulations

The purpose of this study is to use ground motion simulations to investigate ways in which source and path effects for large magnitude events can be represented in non-ergodic GMMs. While we initially developed computation techniques using CyberShake simulations, the range of magnitudes and source-site combinations is not adequate to replicate what is observed empirically. We therefore designed a new ground motion simulation study, which includes earthquakes with a large range of magnitudes distributed uniformly on a fault plane, and sites covering a large range of rupture distances and azimuths. After running a large suite of simulations (M4-M7), we then develop a non-ergodic GMM with the simulation data. We find that the within-site residuals are dominated by the radiation pattern, rupture directivity, and slip patterns. Next, we modify an existing rupture directivity model to fit and remove the observed radiation pattern and rupture directivity from the residuals. We also minimize the contributions of slip patterns by averaging the within-site residuals among multiple source realizations. Finally, after removing the source effects from the within-site residuals, we compare the path effects computed with different magnitude groups using two approaches. The first approach only considers the small events that have the same shortest path to a site with the large events, while the second approach considers all small events on the fault plane. The results indicate that the path effects of large events cannot be satisfactorily approximated with that of small events using either approach.

Conference Paper

Neutron scattering reveals fractionation of natural gas mixtures in unconventional petroleum reservoir pores: Perspectives on energy resource recovery and storage

In unconventional petroleum reservoirs hydrocarbon fluids are hosted by both mineral and organic matter pores. These pores can have diameters that range from microns to less than a single nanometer and, for unconventional reservoirs, there is evidence that small pores ( <20 nm diameter) may constitute a large proportion of the available space. Understanding subsurface volumes and how fluids behave in them can be helpful for predicting hydrocarbon production and storage in the subsurface. One area with knowledge gaps regarding hydrocarbon behavior in small pores is the possibility for mixtures to fractionate (i.e., unmix) based on pore size or pore type. Mixture fractionation as a function of pore size could impact recovery of hydrocarbons, drive compositional shifts during production, and limit fluid storage within candidate reservoirs. To investigate natural gas fractionation in small geologic pores, we applied total neutron scattering to probe methane-ethane mixtures at reservoir pressures (up to ≈30 MPa) and temperature (60°C) within a sample from the Upper Cretaceous Niobrara Formation. Neutron scattering data reveal only minor fractionation occurs between methane and ethane in 20-nm diameter sample mesopores. Increased fractionation is observed for sample micropores, with up to 72% (±1% at 1-sigma) methane found in 2 nm diameter pores following injection of a 50%-50% methane-ethane mixture. These data provide rarely available direct experimental observations of hydrocarbon mixture behavior under nanoconfinement in a sample from an important unconventional petroleum reservoir. Our results are discussed in the context of evaluating hydrocarbon resources in unconventional reservoir meso- and micropores, reconciling observed gas composition changes during production, and more broadly, understanding subsurface pore volumes within an energy storage framework.

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