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The chemistry and isotopic composition of waters in the low-enthalpy geothermal system of Cimino-Vico Volcanic District, Italy

Geothermal energy exploration is based in part on interpretation of the chemistry, temperature, and discharge rate of thermal springs. Here we present the major element chemistry and the δD, δ 18 O, 87 Sr/ 86 Sr and δ 11 B isotopic ratio of groundwater from the low-enthalpy geothermal system near the city of Viterbo in the Cimino-Vico volcanic district of west-Central Italy. The geothermal system hosts many thermal springs and gas vents, but the resource is still unexploited. Water chemistry is controlled by mixing between low salinity,HCO 3 -rich fresh waters (<24.2°C) flowing in shallow volcanic rocks and SO 4 -rich thermal waters (25.3°C to 62.2°C) ascending from deep, high permeability Mesozoic limestones. The (equivalent) SO 4 /Cl (0.01–0.02), Na/Cl (2.82–5.83) and B/Cl ratios (0.02–0.38) of thermal waters differs from the ratios in other geothermal systems from Central Italy, probably implying a lack of hydraulic continuity across the region. The δ 18 O (−6.6‰ to −5.9‰) and δD (−40.60‰ to −36.30‰) isotopic composition of spring water suggest that the recharge area for the geothermal system is the summit region of Mount Cimino. The strontium isotope ratios ( 87 Sr/ 86 Sr) of thermal waters (0.70797–0.70805) are consistent with dissolution of the Mesozoic evaporite-carbonate units that constitute the reservoir, and the ratios of cold fresh waters mainly reflect shallow circulation through the volcanic cover and some minor admixture (<10%) of thermal water as well. The boron isotopic composition (δ 11 B) of fresh waters (−5.00 and 6.12‰) is similar to that of the volcanic cover, but the δ 11 B of thermal waters (−8.37‰ to −4.12‰) is a mismatch for the Mesozoic reservoir rocks and instead reflects dissolution of secondary boron minerals during fluid ascent through flysch units that overlie the reservoir. A slow and tortuous ascent enhances extraction of boron but also promotes conductive cooling, partially masking the heat present in the reservoir. Overall data from this study is consistent with previous studies that concluded that the geothermal system has a large energy potential.

Journal of Volcanology and Geothermal Research↗

Using amphibole phenocrysts to track vapor transfer during magma crystallization and transport: An example from Mount St. Helens, Washington

In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption. In amphibole phenocrysts, Zn and Mn behave compatibly, correlating to FeO ⁎ and Al 2 O 3 , and show no systematic change with time. In contrast, Li and Cu abundances in amphibole vary by up to 3 orders of magnitude (7.6–1140 μg/g and 1.7 to 94 μg/g, respectively), and do not generally correlate with either major or trace elements. However, they do correlate moderately well ( R 2 = 0.54, >> 95% confidence) with each other and show systematic temporal variations that are opposite to those observed for plagioclase, precluding a simple 1-step diffusion model for Li enrichment. We propose a Diffusion-Crystallization Multi-Stage (DCMS) model to explain the temporal variations and co-variations of Li and Cu. In early erupted dacite (October–December 2004) profiles of Li isotopes in conjunction with measured 7 Li intensities and core-to-rim increases in Li concentration are characteristic of Li diffusion into the amphiboles, consistent with prior models of plagioclase enrichment. In amphiboles from 2005 dacite, average Li and Cu concentrations are high (∼ 260–660 μg/g and ∼ 29–45 μg/g, respectively) and in contrast to amphiboles from earlier-erupted dacite, correlate weakly with Al 2 O 3 wt.%. Amphibole Al 2 O 3 concentrations are an indicator of pressure, with high-Al amphiboles crystallizing at higher pressures, and we suggest that Li and Cu are partitioned into a fluid phase during ascent and crystallization of the magma so that amphiboles crystallizing at lower pressure have correspondingly lower Li and Cu concentrations. However, low Li and Cu in amphiboles from the dacite at the start of the eruption also require crystallization from a low Li–Cu bearing melt or residence times long enough for amphiboles to re-equilibrate with a Li–Cu depleted melt. Estimated residence times suggest that amphiboles in early dacite could have been present since the end of the 1980–1986 eruptive episode at Mount St. Helens.

Journal of Volcanology and Geothermal Research↗

Depositional controls on coal distribution and quality in the Eocene Brunner Coal Measures, Buller Coalfield, South Island, New Zealand

The Buller Coalfield on the West Coast of the South Island, New Zealand, contains the Eocene Brunner Coal Measures. The coal measures unconformably overlie Paleozoic-Cretaceous basement rocks and are conformably overlain by, and laterally interfinger with, the Eocene marine Kaiata Formation. This study examines the lithofacies frameworks of the coal measures in order to interpret their depositional environments. The lower part of the coal measures is dominated by conglomeratic lithofacies that rest on a basal erosional surface and thicken in paleovalleys incised into an undulating peneplain surface. These lithofacies are overlain by sandstone, mudstone and organic-rich lithofacies of the upper part of the coal measures. The main coal seam of the organic-rich lithofacies is thick (10-20 m), extensive, locally split, and locally absent. This seam and associated coal seams in the Buller Coalfield are of low- to high-volatile bituminous rank (vitrinite reflectance between 0.65% and 1.75%). The main seam contains a variable percentage of ash and sulphur. These values are related to the thickening and areal distribution of the seam, which in turn, were controlled by the nature of clastic deposition and peat-forming mire systems, marine transgression and local tidal incursion. The conglomeratic lithofacies represent deposits of trunk and tributary braided streams that rapidly aggraded incised paleovalleys during sea-level stillstands. The main seam represents a deposit of raised mires that initially developed as topogenous mires on abandoned margins of inactive braidbelts. Peat accumulated in mires as a response to a rise in the water table, probably initially due to gradual sea-level rise and climate, and the resulting raised topography served as protection from floods. The upper part of the coal measures consists of sandstone lithofacies of flu vial origin and bioturbated sandstone, mudstone and organic-rich lithofacies, which represent deposits of paralic (deltaic, barrier shoreface, tidal and mire) and marine environments. The fluvial sandstone lithofacies accumulated in channels during a sea-level stillstand. The channels were infilled by coeval braided and meandering streams prior to transgression. Continued transgression, ranging from tidal channel-estuarine incursions to widespread but uneven paleoshoreline encroachment, accompanied by moderate basin subsidence, is marked by a stacked, back-stepping geometry of bioturbated sandstone and marine mudstone lithofacies. Final retrogradation (sea-level highstand) is marked by backfilling of estuaries and by rapid landward deposition of the marine Kaiata Formation in the late Eocene.

International Journal of Coal Geology↗

Late Holocene environmental change in Celestun Lagoon, Yucatan, Mexico

Epikarst estuary response to hydroclimate change remains poorly understood, despite the well-studied link between climate and karst groundwater aquifers. The influence of sea-level rise and coastal geomorphic change on these estuaries obscures climate signals, thus requiring careful development of paleoenvironmental histories to interpret the paleoclimate archives. We used foraminifera assemblages, carbon stable isotope ratios (δ 13 C) and carbon:nitrogen (C:N) mass ratios of organic matter in sediment cores to infer environmental changes over the past 5300 years in Celestun Lagoon, Yucatan, Mexico. Specimens (> 125 µm) from modern core top sediments revealed three assemblages: (1) a brackish mangrove assemblage of agglutinated Miliammina and Ammotium taxa and hyaline Haynesina (2) an inner-shelf marine assemblage of Bolivina , Hanzawaia , and Rosalina, and (3) a brackish assemblage dominated by Ammonia and Elphidium . Assemblages changed along the lagoon channel in response to changes in salinity and vegetation, i.e. seagrass and mangrove. In addition to these three foraminifera assemblages, lagoon sediments deposited since 5300 cal yr BP are comprised of two more assemblages, defined by Archaias and Laevipeneroplis, which indicate marine Thalassia seagrasses, and Trichohyalus, which indicates restricted inland mangrove ponds. Our data suggest that Celestun Lagoon displayed four phases of development: (1) an inland mangrove pond (5300 BP) (2) a shallow unprotected coastline with marine seagrass and barrier island initiation (4900 BP) (3) a protected brackish lagoon (3000 BP), and (4) a protected lagoon surrounded by mangroves (1700 BP). Stratigraphic (temporal) changes in core assemblages resemble spatial differences in communities across the modern lagoon, from the southern marine sector to the northern brackish region. Similar temporal patterns have been reported from other Yucatan Peninsula lagoons and from cenotes (Nichupte, Aktun Ha), suggesting a regional coastal response to sea level rise and climate change, including geomorphic controls (longshore drift) on lagoon salinity, as observed today. Holocene barrier island development progressively protected the northwest Yucatan Peninsula coastline, reducing mixing between seawater and rain-fed submarine groundwater discharge. Superimposed on this geomorphic signal, assemblage changes that are observed reflect the most severe regional wet and dry climate episodes, which coincide with paleoclimate records from lowland lake archives (Chichancanab, Salpeten). Our results emphasize the need to consider coastal geomorphic evolution when using epikarst estuary and lagoon sediment archives for paleoclimate reconstruction and provide evidence of hydroclimate changes on the Yucatan Peninsula.

Yucatan, Celestun Lagoon↗

Use of structured decision-making to explicitly incorporate environmental process understanding in management of coastal restoration projects: Case study on barrier islands of the northern Gulf of Mexico

Coastal ecosystem management typically relies on subjective interpretation of scientific understanding, with limited methods for explicitly incorporating process knowledge into decisions that must meet multiple, potentially competing stakeholder objectives. Conversely, the scientific community lacks methods for identifying which advancements in system understanding would have the highest value to decision-makers. A case in point is barrier island restoration, where decision-makers lack tools to objectively use system understanding to determine how to optimally use limited contingency funds when project construction in this dynamic environment does not proceed as expected. In this study, collaborative structured decision-making (SDM) was evaluated as an approach to incorporate process understanding into mid-construction decisions and to identify priority gaps in knowledge from a management perspective. The focus was a barrier island restoration project at Ship Island, Mississippi, where sand will be used to close an extensive breach that currently divides the island. SDM was used to estimate damage that may occur during construction, and guide repair decisions within the confines of limited availability of sand and funding to minimize adverse impacts to project objectives. Sand was identified as more limiting than funds, and unrepaired major breaching would negatively impact objectives. Repairing minor damage immediately was determined to be generally more cost effective (depending on the longshore extent) than risking more damage to a weakened project. Key gaps in process-understanding relative to project management were identified as the relationship of island width to breach formation; the amounts of sand lost during breaching, lowering, or narrowing of the berm; the potential for minor breaches to self-heal versus developing into a major breach; and the relationship between upstream nourishment and resiliency of the berm to storms. This application is a prototype for using structured decision-making in support of engineering projects in dynamic environments where mid-construction decisions may arise; highlights uncertainty about barrier island physical processes that limit the ability to make robust decisions; and demonstrates the potential for direct incorporation of process-based models in a formal adaptive management decision framework.

Mississippi↗

The Steens Mountain (Oregon) geomagnetic polarity transition, 2. Field intensity variations and discussion of reversal models

We carried out an extensive paleointensity study of the 15.5±0.3 m.y. Miocene reversed‐to‐normal polarity transition recorded in lava flows from Steens Mountain (south central Oregon). One hundred eighty‐five samples from the collection whose paleodirectional study is reported by Mankinen et al. (this issue) were chosen for paleointensity investigations because of their low viscosity index, high Curie point and reversibility, or near reversibility, of the strong field magnetization curve versus temperature. Application of the Thellier stepwise double heating method was very successful, yielding 157 usable paleointensity estimates corresponding to 73 distinct lava flows. After grouping successive lava flows that did not differ significantly in direction and intensity, we obtained 51 distinguishable, complete field vectors of which 10 are reversed, 28 are transitional, and 13 are normal. The record is complex, quite unlike that predicted by simple flooding or standing nondipole field models. It begins with an estimated several thousand years of reversed polarity with an average intensity of 31.5±8.5 μT, about one third lower than the expected Miocene intensity. This difference is interpreted as a long‐term reduction of the dipole moment prior to the reversal. When site directions and intensities are considered, truly transitional directions and intensities appear almost at the same time at the beginning of the transition, and they disappear simultaneously at the end of the reversal. Large deviations in declination occur during this approximately 4500±1000 year transition period that are compatible with roughly similar average magnitudes of zonal and nonzonal field components at the site. The transitional intensity is generally low, with an average of 10.9±4.9 μT for directions more than 45° away from the dipole field and a minimum of about 5 μT. The root‐mean‐square of the three field components X , Y , and Z are of the same order of magnitude for the transitional field and the historical nondipole field at the site latitude. However, a field intensity increase to pretransitional values occurs when the field temporarily reaches normal directions, which suggests that dipolar structure could have been briefly regenerated during the transition in an aborted attempt to reestablish a stationary field. Changes in the field vector are progressive but jerky, with at least two, and possibly three, large swings at astonishingly high rates. Each of those transitional geomagnetic impulses occurs when the field intensity is low (less than 10 μT) and is followed by an interval of directional stasis during which the magnitude of the field increases greatly. For the best documented geomagnetic impulse the rapid directional change corresponds to a vectorial intensity change of 6700±2700 nT yr −1 , which is about 15–50 times larger than the maximum rate of change of the nondipole field observed during the last centuries. The occurrence of geomagnetic impulses seems to support reversal models assuming an increase in the level of turbulence within the liquid core during transitions. The record closes with an estimated several thousand years of normal polarity with an average intensity of 46.7±20.1 μT, agreeing with the expected Miocene value. However, the occurrence of rather large and apparently rapid intensity fluctuations accompanied by little change in direction suggests that the newly reestablished dipole was still somewhat unstable.

Journal of Geophysical Research B: Solid Earth↗

Excitation of a buried magmatic pipe: A seismic source model for volcanic tremor

Recent observations of seismic events at various volcanoes suggest that harmonic tremor results from the sustained occurrence of so-called long-period or low-frequency events. Accordingly, we can view the long-period volcanic event as the elementary process of tremor and interpret it as the impulse response of the tremor-generating system. We present a seismic model in which the source of tremor is the acoustic resonance of a fluid-filled volcanic pipe triggered by excess gas pressure. The model consists of three elements, namely, a triggering mechanism, a resonator, and a radiator. For simplicity, we assume a hemispherical trigger, cylindrial resonator, and circular radiator set in a vertical configuration with the trigger capping the top of the pipe and the disk-shaped radiator shutting off its bottom. Considering the simple case of a source buried in a homogeneous half space, we then apply the discrete wave number method to obtain a complete representation of the ground motion response at near and intermediate distances. The results demonstrate that the displacement attributed to the pipe dominates the near-field motion, while that due to the disk is representative of the intermediate and far fields. The trigger itself has a smaller contribution, mainly limited to the field in the proximity of the source. The characteristics displayed by the free surface response evolve from a strong impulsive signature in the immediate vicinity of the epicenter to a well-developed harmonic wave train dominated by Rayleigh waves at larger distances. No clear shear arrival can be detected in the synthetic seismograms. The displacement spectrum reflects the organ-pipe modes of the conduit, and the bandwidth associated with the dominant spectral peak of motion is controlled by the combined losses due to viscous attenuation in the fluid and elastic radiation into the solid. In the case of the cylindrical magma column considered, the radiation loss is proportional to the square of the pipe radius, while the loss related to viscous damping is inversely proportional to the same factor, indicating that the relative importance of the two loss mechanisms is critically dependent on the geometry of the magma reservoir. The relative importance of the pipe and disk elements, likewise, is a function of the conduit cross section. This suggests the possibility of determining the geometry of the source as well as the radiation loss and in situ magma viscosity from a comparison of near- and far-field observations.

Journal of Geophysical Research Solid Earth↗

Assessment of Mars Pathfinder landing site predictions

Remote sensing data at scales of kilometers and an Earth analog were used to accurately predict the characteristics of the Mars Pathfinder landing site at a scale of meters. The surface surrounding the Mars Pathfinder lander in Ares Vallis appears consistent with orbital interpretations, namely, that it would be a rocky plain composed of materials deposited by catastrophic floods. The surface and observed maximum clast size appears similar to predictions based on an analogous surface of the Ephrata Fan in the Channeled Scabland of Washington state. The elevation of the site measured by relatively small footprint delay-Doppler radar is within 100 m of that determined by two-way ranging and Doppler tracking of the spacecraft. The nearly equal elevations of the Mars Pathfinder and Viking Lander 1 sites allowed a prediction of the atmospheric conditions with altitude (pressure, temperature, and winds) that were well within the entry, descent, and landing design margins. High-resolution (~38 m/pixel) Viking Orbiter 1 images showed a sparsely cratered surface with small knobs with relatively low slopes, consistent with observations of these features from the lander. Measured rock abundance is within 10% of that expected from Viking orbiter thermal observations and models. The fractional area covered by large, potentially hazardous rocks observed is similar to that estimated from model rock distributions based on data from the Viking landing sites, Earth analog sites, and total rock abundance. The bulk and fine-component thermal inertias measured from orbit are similar to those calculated from the observed rock size-frequency distribution. A simple radar echo model based on the reflectivity of the soil (estimated from its bulk density), and the measured fraction of area covered by rocks was used to approximate the quasi-specular and diffuse components of the Earth-based radar echos. Color and albedo orbiter data were used to predict the relatively dust free or unweathered surface around the Pathfinder lander compared to the Viking landing sites. Comparisons with the experiences of selecting the Viking landing sites demonstrate the enormous benefit the Viking data and its analyses and models had on the successful predictions of the Pathfinder site. The Pathfinder experience demonstrates that, in certain locations, geologic processes observed in orbiter data can be used to infer surface characteristics where those processes dominate over other processes affecting the Martian surface layer. Copyright 1999 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Historic surface slip along the San Andreas Fault near Parkfield, California

The Parkfield Earthquake Prediction Experiment is focusing close attention on the 44-km-long section of the San Andreas fault that last ruptured seismically in 1966 ( M s 6.0). The 20-km-long central segment of the 1966 Parkfield rupture, extending from the mainshock epicenter at Middle Mountain southeastward to Gold Hill, forms a 1- to 2-km salient northeastward away from the dominant N40°W strike. Following the 1966 earthquake afterslip, aseismic slip has been nearly constant. Moderate Parkfield earthquakes have recurred on average every 21 years since 1857, when a great earthquake ( M ≈8) ruptured at least as far north as the southern Parkfield segment. Many measurements of slip have been made near Parkfield since 1966. Nevertheless, much of the history of surface slip remained uncertain, especially the total amount associated with the 1966 event. In 1985 we measured accumulated slip on the four oldest cultural features offset by the fault along the 1966 Parkfield rupture segment. We interpret net slip on each feature as a sum of event slip (sum of coseismic and rapid preseismic and postseismic slip) from Parkfield earthquakes and steady interseismic slip as measured over the last 20 years on nearby alinement arrays, creep meters, and trilateration lines. We assumed for each site that event slip was identical for the 1922, 1934, and 1966 Parkfield events and that long-term average rate of interseismic slip was constant between all events. Two fences on the southern segment, southeast of Gold Hill, indicate event slip of 13 and 15 cm and interseismic slip rate of 0.36 and 0.30 cm/yr since 1959 and 1908, respectively. At these sites, redundant independent data support our assumption that both event and interseismic slip occur uniformly. On the central segment, near Parkfield, both the 1934 and the 1966 ruptures offset a bridge built in 1932. Interseismic slip rate near the bridge has been about 1.1 cm/yr since 1966; thus we deduce an average event slip of 31 cm for the 1934 and 1966 earthquakes. On a parallel fault trace, 1 km to the southwest, slip was about 8 cm in 1966; thus total event slip summed across the entire fault zone near Parkfield was nearly 40 cm. On Middle Mountain, 4 km north of the 1966 mainshock epicenter, an offset fence indicates 17 cm of slip in 1966 and a 2.26-cm/yr interseismic slip rate since circa 1946. Thus the central segment of the 1966 rupture is characterized by much larger event slip (∼40 cm) than both distal segments (∼15 cm). This amount of surface slip per event is about twice what had been previously assumed. Larger 1966 surface slip in the central part of the rupture is geodetically compatible with a coseismic slip of 65±10 cm slip on a narrow, buried asperity between Middle Mountain and Gold Hill that has been inferred from the depth distribution of early aftershocks. Assuming our characteristic surface slip model, one can further deduce a deficit in slip since the great 1857 earthquake. Taking the long-term slip rate as 3.3 cm/yr, the surface slip deficit is 3±0.2 m south of Gold Hill but only 0.3±0.3 m northward from Parkfield.

Journal of Geophysical Research Solid Earth↗

The Lepanto Cu–Au deposit, Philippines: A fossil hyperacidic volcanic lake complex

Hyperacidic lakes and associated solfatara in active volcanoes are the expression of magmatic gas expansion from source to surface. Here we show for the first time, that the vein system that comprises the ~ 2 Ma high-sulfidation, Lepanto copper–gold deposit in the Mankayan district (Philippines) was associated with a contemporary hyperacidic volcanic lake complex—possibly the first such lake recognized in the geological record. A 15–20‰ difference in sulfur isotopic composition between barite and sulfides and sulfosalts in the vent fumarole encrustations supports the interpretation that SO 2 -rich volcanic gas vented into the base of the lake and marginal to it and ties the mineralization directly to magmatic gas expansion, fracture propagation, and mineralization that occurred through a series of decompression steps within the feeder fracture network. These data confirm that crater lake environments such as Kawah Ijen (Java, Indonesia) provide modern day analogs of the Lepanto and other high sulfidation Cu–Au depositing environments. We also provide extensive analysis of sulfosalt–sulfide reactions during vein formation within the hyperacidic lake complex. Pyrite ± silica deposited first at high temperature followed by enargite that preserves the vapor–solid diffusion of, for example, antimony, tin, and tellurium into the vapor from the crystallizing solid. Subsolidus, intra-crystalline diffusion continued as temperature declined. Pyrite and enargite are replaced by Fe-tennantite in the lodes which initially has low Sb/(Sb + As) atomic ratios around 13.5% close to the ideal tennantite formula, but evolves to higher ratios as crystallization proceeds. Fumarole encrustation clasts and sulfosalts in the lake sediment are more highly evolved with a larger range of trace element substitutions, including antimony. Substitution of especially Zn, Te, Ag, and Sn into tennantite records metal and semi-metal fractionation between the expanding magmatic gas and deposited sulfide sublimates provides a rare insight into the fate of metals and semi-metals in the shallower parts of fracture arrays that feed modern hyperacidic lakes. These data support a growing understanding of the formation of high-sulfidation gold deposits as the consequence of single-phase expansion of gas from magmatic-gas reservoirs beneath the surface of active volcanoes without the intervention of a later aqueous fluid including groundwater. Aggressive sulfide–sulfosalt reactions, including pitting and the almost complete dissolution of earlier minerals, are persistent characteristics of the vein assemblages and precious metals typically occur late in pits or along brittle fractures. These characteristics support a hypothesis of mineral deposition at temperatures of the order of 600 °C in contrast to available fluid inclusion data from enargite that record temperatures following phase transitions in the sulfosalt during the retrograde devolution of the deposit in the presence of groundwater.

Benguet↗

Limnological and climatic environments at Upper Klamath Lake, Oregon during the past 45 000 years

Upper Klamath Lake, in south-central Oregon, contains long sediment records with well-preserved diatoms and lithological variations that reflect climate-induced limnological changes. These sediment archives complement and extend high resolution terrestrial records along a north-south transect that includes areas influenced by the Aleutian Low and Subtropical High, which control both marine and continental climates in the western United States. The longest and oldest core collected in this study came from the southwest margin of the lake at Caledonia Marsh, and was dated by radiocarbon and tephrochronology to an age of about 45 ka. Paleolimnological interpretations of this core, based upon geochemical and diatom analyses, have been augmented by data from a short core collected from open water environments at nearby Howards Bay and from a 9-m core extending to 15 ka raised from the center of the northwestern part of Upper Klamath Lake. Pre- and full-glacial intervals of the Caledonia Marsh core are characterized and dominated by lithic detrital material. Planktic diatom taxa characteristic of cold-water habitats (Aulacoseira subarctica and A. islandica) alternate with warm-water planktic diatoms (A. ambigua) between 45 and 23 ka, documenting climate changes at millennial scales during oxygen isotope stage (OIS) 3. The full-glacial interval contains mostly cold-water planktic, benthic, and reworked Pliocene lacustrine diatoms (from the surrounding Yonna Formation) that document shallow water conditions in a cold, windy environment. After 15 ka, diatom productivity increased. Organic carbon and biogenic silica became significant sediment components and diatoms that live in the lake today, indicative of warm, eutrophic water, became prominent. Lake levels fell during the mid-Holocene and marsh environments extended over the core site. This interval is characterized by high levels of organic carbon from emergent aquatic vegetation (Scirpus) and by the Mazama ash (7.55 ka), generated by the eruption that created nearby Crater Lake. For a brief time the ash increased the salinity of Upper Klamath Lake. High concentrations of molybdenum, arsenic, and vanadium indicate that Caledonia Marsh was anoxic from about 7 to 5 ka. After the mid-Holocene, shallow, but open-water environments returned to the core site. The sediments became dominated (>80%) by biogenic silica. The open-water cores show analogous but less extreme limnological and climatic changes more typical of mid-lake environments. Millennial-scale lake and climate changes during OIS 3 at Upper Klamath Lake contrast with a similar record of variation at Owens Lake, about 750 km south. When Upper Klamath Lake experienced cold-climate episodes during OIS 3, Owens Lake had warm but wet episodes; the reverse occurred during warmer intervals at Upper Klamath Lake. Such climatic alternations apparently reflect the variable position and strength of the Aleutian Low during the mid-Wisconsin.

Oregon↗

Debris-flow origin for the Simud/Tiu deposit on Mars

A late Hesperian smooth plains deposit on Mars interpreted as a debris flow extends more than 2000 km from Hydraotes Chaos, through Simud and Tiu Valles, and into Chryse Planitia. The Simud/Tiu deposit widens out to >1000 km and embays streamlined landforms and knobs made up of sedimentary and perhaps volcanic deposits that were carved by earlier channeling activity. Morphologic features of the Simud/Tiu deposit observed in Viking and Pathfinder images are generally consistent with a debris-flow origin, but some of the deposit's salient features are not readily explained by catastrophic flooding or ice flow. Internal depressions appear to be bounded by linear scarps along flow margins where differential shearing may have occurred and in areas where flow spreading may have produced zones of extensional breakup and thinning within the flow. Possible flow lobes within the deposit may have formed by successive flow surges within the flow unit. The Pathfinder landing site is on the Simud/Tiu deposit, and the observations there are consistent with debris flow. The low, longitudinal ridges at the site may have formed by clast interactions as the flow ground to a halt. Imbricated, planar rocks on the ridges, such as in the Rock Garden, also may have been emplaced by debris or ice flow. However, stream energy calculations at Ares Vallis and channel geology indicate that flooding probably was incapable of emplacing the meter-size boulders observed at the Pathfinder site. Dewatering of pressurized zones in the debris flow or underlying material may be responsible for mud eruptions that formed a couple of patches of low pancakelike shields up to 5 km in diameter and for probable water flows that formed two small rille channels a few kilometers long. Local irregular grooves may be cracks that resulted from later desiccation and contraction of the flow material. The debris-flow unit apparently coalesced from outflows of water-fluidized debris originating from beneath chaotic and hummocky terrains within and along the margins of Simud and Tiu Valles. The deposit is onlapped from the north by another flow deposit originating from Acidalia Planitia. If the Simud/Tiu debris flow had entered a standing body of water, a turbidity current may have arisen from the debris flow and then backflowed over the debris flow to account for the Acidalia deposit.

Journal of Geophysical Research E: Planets↗

Seafloor environments within the Boston Harbor- Massachusetts Bay sedimentary system: A regional synthesis

Modern seafloor sedimentary environments within the glaciated, topographically complex Boston Harbor and Massachusetts Bay area have been interpreted and mapped from an extensive collection of sidescan sonar records and supplemental marine geologic data. Three categories of environments are present that reflect the dominant long-term processes of erosion or nondeposition, deposition, and sediment reworking. (1) Environments of erosion or nondeposition comprise exposures of bedrock, glacial drift, coarse lag deposits, and possibly coastal plain rocks that contain sediments (where present) ranging from boulder fields to gravelly sands and occur in areas of relatively strong currents. (2) Environments of deposition contain fine-grained sediments ranging from muddy sands to muds that have accumulated in areas of predominantly weak bottom currents. (3) Environments of sediment reworking contain patches with textures ranging from sandy gravels to muds that have been produced by a combination of erosion and deposition in areas with variable bottom currents. The distribution of sedimentary environments across the Boston Harbor-Massachusetts Bay area is extremely patchy. Locally, this patchiness is due either to modifications of bottom-current strength (caused by the irregular topography and differences in water depth) or to small-scale changes in the supply of fine-grained sediments. Regional patchiness, however, reflects differences in geologic and oceanographic conditions among the estuarine, inner shelf, and basinal parts of the sedimentary system. The estuarine part of the system (Boston Harbor) is a depositional trap for fine-grained sediments because it is protected from large waves, has generally weak and variable tidal currents, and receives a large supply of fine grained detritus from natural and anthropogenic sources. The inner shelf, on the other hand, is largely an area of erosion or nondeposition due to sediment removal and redistribution during past sea-level changes, to sediment resuspension and winnowing by modern waves and currents, and to an inadequate supply of fine-grained sediments. The basinal part of the system (Stellwagen Basin) is mainly a tranquil depositional environment in which fine-grained sediments from several potential sources settle through the water column and accumulate under weak bottom currents. This study indicates areas within the Boston Harbor-Massachusetts Bay sedimentary system where fine-grained sediments and associated contaminants are likely to be either moved or deposited. It also provides a guide to the locations and variability of benthic habitats.

Massachusetts Bay↗

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗

Three-dimensional models of deformation near strike-slip faults

We use three-dimensional elastic models to help guide the kinematic interpretation of crustal deformation associated with strike-slip faults. Deformation of the brittle upper crust in the vicinity of strike-slip fault systems is modeled with the assumption that upper crustal deformation is driven by the relative plate motion in the upper mantle. The driving motion is represented by displacement that is specified on the bottom of a 15-km-thick elastic upper crust everywhere except in a zone of finite width in the vicinity of the faults, which we term the “shear zone.” Stress-free basal boundary conditions are specified within the shear zone. The basal driving displacement is either pure strike slip or strike slip with a small oblique component, and the geometry of the fault system includes a single fault, several parallel faults, and overlapping en echelon faults. We examine the variations in deformation due to changes in the width of the shear zone and due to changes in the shear strength of the faults. In models with weak faults the width of the shear zone has a considerable effect on the surficial extent and amplitude of the vertical and horizontal deformation and on the amount of rotation around horizontal and vertical axes. Strong fault models have more localized deformation at the tip of the faults, and the deformation is partly distributed outside the fault zone. The dimensions of large basins along strike-slip faults, such as the Rukwa and Dead Sea basins, and the absence of uplift around pull-apart basins fit models with weak faults better than models with strong faults. Our models also suggest that the length-to-width ratio of pull-apart basins depends on the width of the shear zone and the shear strength of the faults and is not constant as previously suggested. We show that pure strike-slip motion can produce tectonic features, such as elongate half grabens along a single fault, rotated blocks at the ends of parallel faults, or extension perpendicular to overlapping en echelon faults, which can be misinterpreted to indicate a regional component of extension. Zones of subsidence or uplift can become wider than expected for transform plate boundaries when a minor component of oblique motion is added to a system of parallel strike-slip faults.

Journal of Geophysical Research B: Solid Earth↗

The competition between thermal contraction and differentiation in the stress history of the Moon

The scarcity of both extension and compression features on the Moon strongly constrains the history of the lunar radius—to variations of less than ±1 km over the past 3.8 Gyr. This limit has traditionally been interpreted as requiring a delicate balance between thermal contraction of the near‐surface and expansion of a substantial cold interior region. Recent theories of lunar origin (e.g., giant impact), in contrast, favor a “hot” initial state. We propose that a reconciliation may be possible by taking account of the volume change Δ V / V | d due to differentiation. We calculate STP densities based on simplified normative mineralogies for a suite of estimates of the bulk lunar composition, of primary lunar basalt, and of the residuum left when the maximum amount of the latter is extracted from the former. Typically Δ V / V | d ≃ 2 to 5%—an expansion equivalent to heating by ∼10 3 K. Provided the timing of differentiation is correct, one might offset the cooling of a magma ocean as much as 630 km deep by differentiation of the remainder of the Moon (which need not start much below the solidus temperature). A large but not impossible amount of gabbroic melt production is implied: ∼100 times the volume of mare basalts known to have been extruded. We do not address the detailed genetic relationship of this melt to the basalts observed on the lunar surface but point out that it need not have reached the surface directly or even have entered the crust in order for the expansion to have occurred. To assess the timing of melt formation, we investigate a simple conductive lunar thermal model which takes account of both Δ V / V | d and thermal contraction. Our initial state is characterized by a central temperature T c and a depth Z 0 above which the material (derived from the magma ocean) is already at the solidus and is not suceptible to volume changes upon further differentiation. We find a range of models satisfying the limits on radius increase and decrease. The hottest has T c = 1210 K, Z 0 = 400 km; without Δ V / V | d , we would need a larger or colder (or both) core, e.g., T c ≲ 700 K for Z 0 = 200–400 km, in agreement with previous investigators. Our modeling thus lends credence to the idea that the Moon could have been initially ≳50% molten (with the remainder relatively close to the solidus) and yet experienced little volume change over the last 3.8 Gyr.

Journal of Geophysical Research B: Solid Earth↗

Late Quaternary stratigraphy and depositional history of the Long Island Sound basin

The stratigraphy of Late Quaternary geologic units beneath Long Island Sound (LIS) is interpreted from 3,500 km of high-resolution, seismic-reflection profiles supplemented by vibracore data. Knowledge gained from onshore regional geologic studies and previous offshore investigations is also incorporated in these interpretations. Glacial deposits overlie and nearly fill an Inner Lowland which is floored by crystalline rocks in the north and bounded to the south by an irregular, north-facing cuesta scarp in Cretaceous Coastal-Plain strata. The thick glacial section consists largely of sediment that was deposited in glacial Lake Connecticut during the retreat of the last (late Wisconsin) ice sheet. Ice-marginal lacustrine fan deposits and submerged extensions of the southeastern Connecticut recessional moraines mark positions of the ice margin during systematic northward retreat. When the ice margin stood at positions just north of the present shoreline of Connecticut (17.6-16.5 ka), glacial Lake Connecticut was slightly larger than Long Island Sound is today. Ice-marginal deltas and near-ice marginal fluviodeltaic deposits occur along coastal Connecticut. Delta-building was diachronous; progressively younger deltas record northwesterly retreat of the ice margin and lowering lake levels. Distally from the deltas, varied lake-clays (up to 150 m thick) drape the underlying topography. The lake spillway cut across the Harbor Hill-Roanoke Point-Fishers Island-Charlestown end moraine at its lowest point just west of Fishers Island (The Race). Lake levels fell as the spillway notch was erosionally deepened, and gradually the lakebed became subaerially exposed. A largely preserved channel system cuts the lake-deposit surface; fluvial channel-fill sediments are overlain by estuarine sediments in the channel system. Perhaps as early as 15 ka, but no later than 13 ka, the sea entered the Basin through the channel at The Race and quickly transgressed westward via the lakebed channel system. As the sea rose further and spread throughout the Basin, a wave-cut surface was formed. Extensive marine deltaic deposits, up to 40 m thick, overlie the wave-cut marine unconformity in the east-central part of the Basin. These sediments were derived from erosion of the drained bed of Lake Hitchcock, in the Connecticut valley to the north, and were deposited in a -40-m relative sea at about 12.4 ka. Where quiet waters prevail, marine mud generally less than 15 m thick blankets the older deposits of the Basin. Elsewhere, especially in eastern LIS, tidal currents are actively reworking and transporting glacial and postglacial deposits.

Connecticut, New York↗

Application of morphologic burrow interpretations to discern continental burrow architects: Lungfish or crayfish?

A methodology for trace fossil identification using burrowing signatures is tested by evaluating ancient and modern lungfish and crayfish burrows and comparing them to previously undescribed burrows in a stratigraphic interval thought to contain both lungfish and crayfish burrows. Permian burrows that bear skeletal remains of the lungfish Gnathorhiza , from museum collections, were evaluated to identify unique burrow morphologies that could be used to distinguish lungfish from crayfish burrows when fossil remains are absent. The lungfish burrows were evaluated for details of the burrowing mechanism preserved in the burrow morphologies together forming burrowing signatures and were compared to new burrows in the Chinle Formation of western Colorado to test the methodology of using burrow signatures to identify unknown burrows. Permian lungfish aestivation burrows show simple, nearly vertical, unbranched architectures and relatively smooth surficial morphologies with characteristic quasi‐horizontal striae on the burrow walls and vertical striae on the bulbous terminus. Burrow lengths do not exceed 0.5 m. In contrast, modern and ancient crayfish burrows exhibit simple to highly complex architectures with highly textured surficial morphologies. Burrow lengths may reach 4 to 5 m. Burrow morphologies unlike those identified in Gnathorhiza aestivation burrows were found in four burrow groups from museum collections. Two of these groups exhibit simple architectures and horizontal striae that were greater in sinuosity and magnitude, respectively. One of these burrows contains the remains of Lysoro‐phus , but the burrow surface reveals no reliable surficial characteristics. It is not clear whether Lysorophus truly burrowed or merely occupied a pre‐existing structure. The other two groups exhibit surficial morphologies similar to those found on modern and ancient crayfish burrows and may provide evidence of freshwater crayfish in the Permian. Burrows from the Upper Triassic Chinle Formation in western Colorado exhibit simple to moderately complex architectural morphologies, ranging from predominantly vertical, unbranched, with little or no chamber development to predominantly vertical, few branches, and with minor chamber development. Surficial burrow morphologies are moderate to highly textured. The burrows have scrape marks, scratch marks, mud and lag‐liners, knobby surfaces, pleopod striae, and body impressions. Although no fossil remains of the burrowing organism were found within or associated with the Chinle burrows from western Colorado, the similarity of architectural and surficial burrow morphologies to those in the Chinle of Canyonlands, Utah and to modern crayfish burrows, clearly indicates that the Colorado burrows are the product of burrowing crayfish rather than lungfish. Evaluation of burrowing signatures preserved in the architectural and surficial burrow morphologies is a very useful tool to compare and contrast Chinle burrows from different regions on the Colorado Plateau. Documentation of crayfish burrows in the Chinle of Utah and Colorado strongly suggests that other large‐diameter Chinle burrows elsewhere on the Colorado Plateau and in stratigraphically equivalent units may also be the product of crayfish activity.

Colorado, Utah↗