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Seismic moment and local magnitude scales in Ridgecrest, CA from the SCEC/USGS Community Stress Drop Validation Study

We illustrate the systematic difference between moment magnitude and local magnitude caused by underlying earthquake source physics, using seismic moments submitted to the Statewide California Earthquake Center/United States Geological Survey Community Stress Drop Validation Study 2019 Ridgecrest data set. While the relationship between seismic moment and moment magnitude ( M or M w ) of log 10 ( M 0 ) ~ 1.5* M is uniformly valid for all earthquake sizes by definition (Hanks and Kanamori, 1979), the relationship between local magnitude M L and moment is itself magnitude dependent. For moderate events, ~3< M < ~6, M and M L are coincident; for earthquakes smaller than ~3, M L ~ 1.0 log 10 M 0 (Hanks and Boore, 1984). This is a physical consequence of the corner frequency fc becoming larger than the upper frequency of observation and implies that M L and M differ systematically by a factor of 1.5 for these small events. While this idea is not new, we propose a new, continuous relationship between local magnitude and moment, for magnitudes 2 to 6 which extrapolates to smaller and larger magnitudes, applicable to southern California specific to the Ridgecrest region. We make use of the plethora of seismic moments as submitted by many participants of the Community Stress Drop study, compared to the Southern California Seismic Network (SCSN) catalog magnitudes. Overall, the seismic moments in the Community Study recover moment magnitude well, so we use our new M L - M 0 to convert M L to M , refining the SCSN operational M Lr scale. This systematic difference of 50% in slope between local and moment magnitude at small magnitudes has implications for spectral stress drop estimates, earthquake ground motion modeling, as well as other magnitude scales and earthquake occurrence statistics.

California

Patterns and drivers of cliff erosion in Big Sur, California, USA using repeat photogrammetry, 2017–2023

Seacliff erosion in steep terrain poses major risks to transportation and critical infrastructure. In Big Sur, California, USA, seacliff erosion threatens the sustainability of the central coast stretch of California State Route 1, a transportation corridor that is critical to the region's economy. Published cliff retreat rates for the region range from 1 to 40 cm yr −1 , highlighting that high-resolution, process-based studies could enhance understanding of the causes of spatial and temporal variability. We quantified cliff erosion and investigated its drivers along ∼13 km of the Big Sur coastline at week–month timescales during the late fall to early spring wet seasons between January 2017 and June 2023 by analyzing 3D point clouds developed from aerial imagery using four-dimensional structure-from-motion (4D SfM) photogrammetry techniques. We calculated cliff face retreat rates of 2.23 ± 3.06 cm yr −1 (mean ±1 σ ), an order of magnitude lower than long-term estimated rates for the region (which included large deep-seated landslides), but in line with short-term rates reported across California. Change detection imagery comparison, cliff profiles through time, and statistical analysis reveal a cyclical cliff evolution process in which erosion by wave action at the cliff base destabilizes the cliff and primes it for subsequent failure during precipitation events. Although more erosion by volume could be attributed to precipitation-induced increases in soil moisture (784 m 3 km −1 yr −1 ) compared with erosion attributed to wave power (282 m 3 km −1 yr −1 ), our observations underscore the coupled nature of these processes in driving cliff evolution, consistent with established theory and observations.

California

Beyond the mangroves: A global synthesis of tidal forested wetland types, drivers and future information opportunities

There is increasing awareness of the global diversity of tidal forested wetlands (TFWs) and their significance in the provision of ecosystem services. These ecosystems, including mangrove forests, tidal freshwater forested wetlands, supratidal forests and transitional forests together span multiple climatic zones, geomorphic settings, and inundation and salinity regimes. We utilise case studies across five continents to demonstrate the state of knowledge among TFWs. Intertidal mangroves are the best-defined of the TFWs thanks to decades of research on their geomorphology, hydrology and ecology across their broad distribution. Non-mangrove forest settings, however, demonstrate more diverse hydrological, biochemical and vegetation conditions. In many cases, non-mangrove forests are situated at upper intertidal or supratidal elevations, where surface waters and groundwater are subject to interactions between tides freshwater inputs. Salinity datasets show variations ranging from tidal freshwater forested wetlands and ‘low-salinity mangroves’ to mesohaline or marine salinities, often with high temporal variability. While the floristic composition of non-mangrove forests vary among biogeographic regions, locally dominant TFW species are commonly distributed beyond the tidal niche into non-tidal wetland and upland forests. This presents challenges for traditional remote sensing approaches to ecosystem mapping, which are mostly lacking for non-mangrove forests. Geomorphic approaches and developments in machine learning offer opportunities to address this.

Preprint

Federal lands greenhouse gas emissions and sequestration in the United States: Estimates for 2005–22

In 2016, the Secretary of the U.S. Department of the Interior requested that the U.S. Geological Survey (USGS) produce a publicly available and annually updated database of estimated greenhouse gas emissions associated with the extraction and use of fossil fuels from Federal lands. The first report in this series included emissions estimates from 2005 to 2014 and were reported for 29 States and two offshore areas. Native American and Tribal lands were not included in that analysis. This report recalculates those previous years (2005–14) with updated data and methods and extends the estimates to 2022. Nationwide emissions from fossil fuels produced on Federal lands in 2022 were 1,081.2 million metric tons of carbon dioxide equivalent (MMT CO 2 Eq.) for CO 2 , 33.4 MMT CO 2 Eq. for methane (CH 4 ), and 4.3 MMT CO 2 Eq. for nitrous oxide (N 2 O). Compared to 2005, the 2022 totals represent decreases in emissions for all three greenhouse gases (by 17 percent for CO 2 , 37 percent for CH 4 , and 30 percent for N 2 O). Emissions from fossil fuels produced on Federal lands represent, on average, 21.8 percent of U.S. emissions for CO 2 , 6.1 percent for CH 4 , and 1.3 percent for N 2 O over the 18 years included in this estimate. The trends and relative magnitudes of the greenhouse gas emissions estimated are roughly parallel to the Federal lands fossil fuel production volumes. In 2021, Federal lands of the conterminous United States stored 70,424 MMT CO 2 Eq. in terrestrial ecosystems. Soils stored most of the terrestrial ecosystem carbon (66 percent), followed by live vegetation (25 percent), deadwood (5 percent), and litter (4 percent). Carbon sequestration on Federal lands was highly variable over time, owing primarily to interannual variability in climate and weather, and variability in land use and land cover (LULC) change and disturbances, among these are wildfires and logging. Between 2005 and 2021, Federal lands sequestered an average of 83 MMT CO 2 Eq./yr. By subtracting the cumulative effects of LULC and disturbance-related CO 2 losses to the atmosphere from the total, we estimate that ecosystems at the national level sequestered CO 2 at an annual mean rate of 17 MMT CO 2 Eq./yr in a term called the net ecosystem exchange (NEE). This annual NEE sequestration value represents about 1.4 percent of average fossil fuel emissions over the same period. The USGS estimates presented in this report represent an accounting for the emissions resulting from fossil fuel extraction on Federal lands and the end-use combustion of those fuels, as well as for the sequestration of carbon in terrestrial ecosystems on Federal lands. A combined net CO 2 emissions estimate, which is the difference between the emitted and sequestered CO 2 from both the fossil fuel and ecosystems estimates, provides context for evaluating the greenhouse gas contributions of activities on these lands. The estimates included in this report can provide context for future energy decisions, as well as a basis to track change in the future.

Scientific Investigations Report

Preparing for today's and tomorrow's water-resources challenges in eastern Long Island, New York

Freshwater is a vital natural resource. Although New York is a water-rich State, the wise and economical use of water resources is needed to ensure that there is enough water of adequate quality for both human and ecological needs—both for today and for tomorrow. Nowhere in New York is this more evident than in Nassau and Suffolk Counties on Long Island, where the public water supply is obtained from the sole-source aquifers located directly beneath the nearly 3 million people who live there. In 2023, in eastern Long Island’s Suffolk County, groundwater was pumped from these aquifers by more than 1,100 public water-supply wells to meet the needs of about 1.5 million people.

New York

High-precision earthquake catalog for Minto Flats fault zone, central Alaska, reveals complex and conjugate faulting

The Minto Flats fault zone (MFFZ) in central Alaska is a left‐lateral strike‐slip fault system situated between the continental‐scale right‐lateral Denali and Kaltag‐Tintina faults. The MFFZ has the potential to generate magnitude 7 earthquakes, and it hosted a magnitude 6 earthquake in 1995. It has also produced exotic events, such as very‐low‐frequency earthquakes and nucleation signals. We use network‐matched filtering and relative earthquake relocation techniques to derive a detailed catalog of earthquake locations for the MFFZ. The catalog spans from August 2014 to December 2019, a time period including 13 temporary seismic stations in the region. Our results provide the most complete catalog for the MFFZ and include deeper events, clusters of shallow seismicity, and a complex and segmented fault structure not observed in the original regional catalog. We document right‐lateral strike‐slip faulting, conjugate to the main northeast‐striking left‐lateral faults of the MFFZ. Below Nenana basin, the relocated seismicity reveals northwest‐dipping left‐lateral faults, supporting the inference that deep crustal active faulting is associated with recent basin deformation.

Alaska

Hydrogeologic conceptualization of the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory, Edwards Air Force Base, Antelope Valley, California, 2017–21

Research and testing within the Air Force Research Laboratory at Edwards Air Force Base in the southwestern Mojave Desert has been conducted since the 1950s. This testing requires large quantities of groundwater for cooling and operations involving hazardous constituents that have entered the groundwater. To better understand the potential movement of contaminants through the groundwater system, the U.S. Geological Survey entered into a cooperative agreement with the U.S. Air Force Civil Engineer Center with the purpose of (1) gaining a more detailed understanding of the hydraulic connection between the unconsolidated basin-fill sediment and the underlying weathered and crystalline bedrock and (2) investigating faults and their potential effect on groundwater flow. This study was specific to the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory. The refined hydrogeologic characterization was derived by evaluating surface geologic maps, a regional gravity model, new subsurface geophysical surveys, lithology data from boreholes, and groundwater-level data. Refinement of the hydrogeologic characterization of the study area involved developing a map of basin-fill sediment thickness, estimating the geometry and depth to bedrock, determining the presence of weathered bedrock material, and identifying the location of faults and subsurface structures. The thickness of basin-fill sediment was derived from a regional gravity model. Basin-fill sediment ranges from less than 20 feet (ft) thick to about 150 ft thick and increases substantially toward a deep structural basin in the northwestern part of the study area. The top of bedrock estimated from the new surface geophysical surveys is generally deeper than the top of bedrock from the regional gravity model. These differences in interpreted bedrock tops indicate that there may be a zone of weathered bedrock in the subsurface, overlying crystalline bedrock. Additional subsurface data evaluating the geometry and thickness of weathered bedrock are necessary for a comprehensive evaluation of weathered bedrock in the study area. Previously unmapped extensions of the Leuhman Fault, Spring Fault Zone, and Boron Gate Fault were identified in the new surface geophysical surveys. Evaluation of groundwater flow between bedrock and basin-fill sediment, and the effects of faults on groundwater flow, was done using groundwater-level data from 2020. The groundwater table was in crystalline bedrock throughout most of the Arroyos and Northeast Air Force Research Laboratory subareas, with a few exceptions where it was in basin-fill sediment and weathered bedrock. Basin-fill sediment, and likely weathered bedrock, was partially saturated in parts of the study area where basin-fill sediment was as thick as 150 ft. Weathered bedrock material may be present near the Spring Fault Zone, and if so, was likely saturated in 2020. The groundwater-level data near and within Spring Fault Zone indicate that the Spring Fault Zone acts as a vertical-along-strike conduit for, and as an across-strike impediment to, groundwater flow. In addition, steep groundwater-level gradients in the southeastern part of the study area indicate that a subsurface structure affecting groundwater flow could be related to the Leuhman Fault. Sufficient groundwater-level data were not available to conclusively determine if the Arroyos, Rich, and Boron Gate Faults, and their inferred extensions from the geophysical surveys, affect the movement or direction of groundwater flow.

California

Quantitative risk of earthquake disruption to global copper and rhenium supply

Earthquakes have the potential to substantially affect mining operations, potentially leading to supply chain disruptions and adversely affecting the global economy. This study explores the quantification of earthquake risk to copper and rhenium commodity supply by examining the spatial concentration of high earthquake hazard areas and the commodity-specific mining, smelting, and refining operations across the globe. Because many of the largest facilities are concentrated geographically near the highly seismic regions of South America, East Asia, and the Pacific, there is a potential for cascading effects on the entire supply chain. The analysis indicates that the expected annual disruption of global production is 0.3–1.1 percent for copper mines, 1.8–4.0 percent for smelters, and 1.5–3.3 percent for refineries. Expected annual disruption of global rhenium production capacity is 0.32–1.32 percent. The research highlights that the potential lost revenue from earthquake disruptions is from $315 million to $1.29 billion for copper mining, $1.92 billion to $4.33 billion for copper smelting, $2.06 billion to $4.52 billion for copper refining, and $337,000 to $1.40 million for rhenium production capacity.

Open-File Report

Geologic map of MTM −15032 and −20032 quadrangles, western Ladon basin, Mars

Our mapping efforts focused on the geomorphic terrains and geologic units contained within Mars Transverse Mercator (MTM) −15032 and −20032 quadrangles. These two quadrangles are located along the west side of Ladon basin and span lat −12.5° N. to −22.5° N. and long 325° E. to 330° E. The western part of Ladon basin and its bounding basin ring structures to the west preserved features that help to understand the long history of drainage across the Margaritifer Terra region of Mars. Our geologic map provides new insight into the extent of aqueous activity across western Ladon basin and the adjoining highlands, which includes the northern part of Ladon Valles, Arda Valles, numerous small valleys in the western highlands, and light-toned layered deposits associated with these fluvial features. The Mars Odyssey Thermal Emission Imaging System (THEMIS) infrared (IR) daytime mosaic (100 meters per pixel) was used as the primary base map. We constructed the geologic map of western Ladon basin at 1:1,000,000 scale. We identified 20 geologic units in the map area, which we divided into the following groups: crater units; volcanic units; chaotic units; basin fill units; crater, valley, and channel units; and plateau and highlands units. We observed the following sequence of events: (1) formation of Ladon and Holden impact basins in the middle Noachian, producing a mountainous unit; (2) landscape degradation and infilling during the Late Noachian to Late Hesperian forming terra units; (3) formation of Ladon Valles in the Late Noachian to Early Hesperian by catastrophic flooding, producing channel units; (4) accumulation of sediments in the Late Noachian to Early Amazonian, forming basin fill units; (5) formation of a smooth crater fill unit during the Early to Late Hesperian; (6) deposition during the Late Hesperian to Early Amazonian, creating light-toned layered units within Ladon Valles, Ladon basin, and other smaller valley networks along the western uplands, as well as formation of a light-toned unit along some crater floors; (7) formation a of chaotic unit in the Early to Middle Amazonian, formation of alluvial fans in the Early Amazonian, and eruption of a volcanic unit in the Middle Amazonian; and (8) formation of craters throughout the geologic history of the map region.

Scientific Investigations Map

Solute transport and modeling of water quality in a small stream

An injection of chloride, sodium, and stable strontium was made at a constant rate for 3 hours into Uvas Creek, Santa Clara County, Calif., to determine the mass transport processes in a small stream. Five observation points were selected within a 610-metre reach of the stream below the injection site. Water samples were collected at the observation points during and immediately after the injection. A mathematical model of the stream was obtained by solving analytically and optimally the one-dimensional mass transport equation of the solutes in the stream. Comparison of field results with a simplified mathematical model indicates the dominance of convection in the behavior of sodium and chloride. The concentration of chloride and sodium can be closely simulated by the model. However, strontium cannot be well represented by the simplified model, which contains a first-order decay-type sink.

California

The Sand AbrasioN Device for Aeolian Research (SANDAR): A new experimental device for investigating how wind transport affects sand on Earth and Mars

On Earth and Mars, aeolian transport causes sand grains to become abraded, resulting in mineralogic and textural changes. Understanding how sands evolve, or mature, with transport via experimental studies is important for understanding the origins, geologic history, and cycling of sediments, as well as dust production. Previous experimental works have used a variety of methods to simulate aeolian transport in the laboratory, but practical limitations and similitude concerns have limited such research. Here, we present and validate the Sand AbrasioN Device for Aeolian Research (SANDAR), a modified air mill that uses pressurized air to circulate sand around a small abrasion chamber, simulating the effects of aeolian transport. This device is re-circulating to simulate long-distance transport, and it allows for repeated analyses of well-constrained sediment samples, revealing their evolution over time. It is compatible with the grain sizes (74–500 μm) and grain impact velocities (∼0.6–3.7 m/s) typically expected for natural aeolian environments, and is also adaptable for diverse applications simulating different wind conditions. We show that the SANDAR achieves similitude of kinetic energy with respect to saltating sand on both Earth and Mars. SEM and optical microscope imaging reveal that the SANDAR produces microtextures on the surfaces of sand grains similar to those found with natural aeolian transport, demonstrating that it effectively simulates the mechanical effects of aeolian processes. Thus, the SANDAR is a valid tool for use in experimental research to improve our understanding of sedimentary processes across the Solar System.

Aeolian Research

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

Colorado

New occurrences of the rare, REE minerals daqingshanite, törnebohmite, biraite, sahamalite, and ferriperbøeite from the Sheep Creek area, Montana, USA

Over 30 small, discontinuous, tabular carbonatite bodies are located in the Sheep Creek area, Ravalli County, southwest Montana. The age and origin of these REE-Nb-rich deposits are currently being investigated. The purpose of this paper is to document the occurrence of several rare minerals, including daqingshanite, törnebohmite, biraite, sahamalite, and ferriperbøeite, in two of the carbonatite bodies. These minerals are found in association with monazite, hydroxylbastnäsite, ferriallanite, calcite, dolomite, baryte, quartz, actinolite, apatite, celsian, and Sr-rich aragonite. Automated SEM-EDS was used to target the areas of interest in polished specimens for more detailed spot SEM-EDS and electron probe microanalysis. Raman spectra were also acquired for each of the rare minerals. The complex mineralogy of the Sheep Creek carbonatites is most likely due to several overlapping thermal events, including primary magmatic, overprinting hydrothermal, and supergene weathering stages. The rare minerals described in this study are believed to be hydrothermal and/or carbothermal in origin, although no estimates of temperature are available at this time.

Montana

Mineral commodity summaries 2025

Introduction Each mineral commodity chapter of the 2025 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2024 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the MCS 2025 are welcomed.

Mineral Commodity Summaries

Mineral commodity summaries 2026

Introduction Each mineral commodity chapter of the 2026 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2025 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the 2026 MCS are welcomed.

Mineral Commodity Summaries

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.

Connecticut, Massachusetts

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis