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Chemicals of emerging concern in water and bottom sediment in the Great Lakes Basin, 2012: collection methods, analytical methods, quality assurance, and study data

In synoptic surveys of surface-water quality across the United States, a large group of organic chemicals associated with agricultural, household, and industrial waste have been detected. These chemicals are referred to collectively as chemicals of emerging concern (CECs) and include prescription drugs and antibiotics, over-the-counter medications, reproductive hormones, personal-care products, detergent metabolites, and flame retardants. The U.S. Geological Survey (USGS) collaborated with the U.S. Fish and Wildlife Service and the U.S. Environmental Protection Agency on a study to identify the presence of CECs in water and bottom-sediment samples collected during 2012 at 66 sites throughout the Great Lakes Basin. The 2012 effort is part of a long-term study that was initiated in 2010. The purposes of this report are to document the collection and analytical methods, provide the quality-assurance data and analyses, and provide the water and bottom-sediment data for this study of CECs in the Great Lakes Basin for 2012. A previous report documents data collected during 2010 and 2011. The methods used for chemical analyses were identical between the 2010–11 and 2012 studies, with the exception that a method to determine nontarget chemicals was used during 2010–11. The data from this study are published as a USGS Data Series Report to ensure adequate documentation of the original methods and provide a citable source for study data. This report contains no interpretations of the study data. The chemical data are as reported by the laboratory and have not been censored or adjusted unless otherwise noted. Field measurements were recorded and samples were collected in April and May and in September 2012, by U.S. Geological Survey, U.S. Fish and Wildlife Service, and U.S. Environmental Protection Agency personnel. Study sites included tributaries to the Great Lakes located near Duluth, Minnesota; King, Wisconsin; Green Bay, Wis.; Detroit, Michigan; Monroe, Mich.; Toledo, Ohio, and Rochester, New York. Water and bottom-sediment samples were analyzed at the USGS National Water Quality Laboratory in Denver, Colorado, for a broad suite of CECs. During this 2012 study, 140 environmental and 8 field duplicate samples of surface water and wastewater effluent, 1 field blank water sample, and 5 field spike water samples were collected or prepared. Water samples were analyzed at the USGS National Water Quality Laboratory using laboratory schedule 4433 for wastewater indicators, research method 8244 for pharmaceuticals, and laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A. For wastewater indicators in unfiltered water, 61 of the 68 chemicals analyzed using laboratory schedule 4433 had detectable concentrations ranging from 0.002 to 64.4 micrograms per liter. Thirty-eight of the 48 chemicals analyzed using research method 8244 for pharmaceuticals in unfiltered water had detectable concentrations ranging from 0.002 to 3.32 micrograms per liter. Twelve of the 20 chemicals analyzed using laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A in unfiltered water had detectable concentrations ranging from 0.43 to 120,000 nanograms per liter. During this study, 53 environmental samples, 4 field duplicate samples, and 8 field spike samples of bottom sediment and laboratory matrix-spike samples were analyzed for a wide variety of CECs at the USGS National Water Quality Laboratory using laboratory schedule 5433 for wastewater indicators; research method 6434 for steroid hormones, sterols, and bisphenol A; and research method 9008 for human-use pharmaceuticals and antidepressants. Forty of the 57 chemicals analyzed using laboratory schedule 5433 had detectable concentrations ranging from 1 to 49,000 micrograms per kilogram. Fourteen of the 20 chemicals analyzed using research method 6434 had detectable concentrations ranging from 0.04 to 24,940 nanograms per gram. Ten of the 20 chemicals analyzed using research method 9008 had detectable concentrations ranging from 0.59 to 197.5 micrograms per kilogram. Five of the 11 chemicals analyzed using research method 9008 had detectable concentrations ranging from 1.16 to 25.0 micrograms per kilogram.

Great Lakes Basin↗

Bathymetry of New York City’s East of Hudson reservoirs and controlled lakes, 2017 to 2019

New York City maintains an extensive system of reservoirs and aqueducts to provide drinking water to its residents, including 16 reservoirs and controlled lakes in Westchester and Putnam Counties in southern New York, east of the Hudson River (also called “East of Hudson reservoirs and controlled lakes”). These reservoirs were put into service from 1842 to 1915, and their capacities have likely changed since their original construction. To provide updated bathymetric surface, contour, and capacity data, the U.S. Geological Survey, in cooperation with New York City Department of Environmental Protection, surveyed the bathymetry of the 16 East of Hudson reservoirs and controlled lakes from 2017 to 2019 using a multibeam echosounder. The points measured with the multibeam echosounder were combined with light detection and ranging data to generate 3.28-foot raster grids of the bathymetric surfaces, bathymetric contours at 2-foot intervals of elevation, and elevation-area-capacity tables. The results of the bathymetric survey show that the East of Hudson reservoirs range from about 25 feet deep (Kirk Lake) to about 162 feet deep (Kensico Reservoir) and have a total capacity of 142.9 billion gallons, with a combined surface area of more than 11,600 acres. The accuracy of the mapped bathymetric data was evaluated using quality assurance datasets collected with a single-beam echosounder; about 284,000 quality assurance points were spatially joined with the mapped raster surface to compute measurement errors. The calculated mean point elevation error for the East of Hudson reservoirs was 0.35 foot, the median error was 0.21 foot, and the 95-percent accuracy was 1.68 feet; the 95-percent accuracy of the computed capacity at spillway elevation was 1.6 percent or less. The largest errors occurred in the steepest areas of the reservoirs and in areas where the data were interpolated. Geospatial files of the bathymetry data, including mapped bathymetric surfaces, contours, and capacity tables, quality assurance points, and associated metadata are available for download as part of an accompanying U.S. Geological Survey data release.

New York↗

Geologic studies in Alaska by the U.S. Geological Survey, 1995

This collection of 20 papers continues the annual series of U.S. Geological Survey (USGS) reports on geologic investigations in Alaska1 . Contributions cover a broad spectrum of earth science topics and report results from all parts of the State (fig. 1). USGS activities in Alaska include studies of environment and climate, hazards, resources, and geologic framework. Five papers in this volume discuss aspects of environment and climate. Environmental geochemistry of parts of southwestern and south-central Alaska is the focus of four articles; a fifth study, of emergent postglacial lake shorelines in southwestern Alaska, contributes to ongoing investigations of paleoclimate. Two papers address geologic hazards. The first assesses ground deformation in Katmai National Park at Novarupta dome, site of the largest volcanic eruption in this century, and the second evaluates earthquake risks related to the "Twin Peak fault" near Anchorage. Resources, including metallic minerals in northern, southwestern, and southeastern Alaska and coal in south-central Alaska, are discussed in four articles. Nine geologic framework studies apply a variety of techniques to a wide range of subjects throughout Alaska, including tectonics, geophysics, geochronology, bio stratigraphy, sedimentology, paleogeography, and paleomagnetism. Two bibliographies at the end of the volume list reports about Alaska in USGS publications released in 1995 and reports about Alaska by USGS authors in non-USGS publications in 1995.

Alaska↗

Simulation of Multiscale Ground-Water Flow in Part of the Northeastern San Joaquin Valley, California

The transport and fate of agricultural chemicals in a variety of environmental settings is being evaluated as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. One of the locations being evaluated is a 2,700-km2 (square kilometer) regional study area in the northeastern San Joaquin Valley surrounding the city of Modesto, an area dominated by irrigated agriculture in a semi-arid climate. Ground water is a key source of water for irrigation and public supply, and exploitation of this resource has altered the natural flow system. The aquifer system is predominantly alluvial, and an unconfined to semiconfined aquifer overlies a confined aquifer in the southwestern part of the study area; these aquifers are separated by the lacustrine Corcoran Clay. A regional-scale 16-layer steady-state model of ground-water flow in the aquifer system in the regional study area was developed to provide boundary conditions for an embedded 110-layer steady-state local-scale model of part of the aquifer system overlying the Corcoran Clay along the Merced River. The purpose of the local-scale model was to develop a better understanding of the aquifer system and to provide a basis for simulation of reactive transport of agricultural chemicals. The heterogeneity of aquifer materials was explicitly incorporated into the regional and local models using information from geologic and drillers? logs of boreholes. Aquifer materials were differentiated in the regional model by the percentage of coarse-grained sediments in a cell, and in the local model by four hydrofacies (sand, silty sand, silt, and clay). The calibrated horizontal hydraulic conductivity values of the coarse-grained materials in the zone above the Corcoran Clay in the regional model and of the sand hydrofacies used in the local model were about equal (30?80 m/d [meter per day]), and the vertical hydraulic conductivity values in the same zone of the regional model (median of 0.012 m/d), which is dominated by the finer-grained materials, were about an order of magnitude less than that for the clay hydrofacies in the local model. Data used for calibrating both models included long-term hourly water-level measurements in 20 short-screened wells installed by the USGS in the Modesto and Merced River areas. Additional calibration data for the regional model included water-level measurements in 11 wells upslope and 17 wells downslope from these areas. The root mean square error was 2.3 m (meter) for all wells in the regional model and 0.8 m for only the USGS wells; the associated average errors were 0.9 m and 0.3 m, respectively. The root mean square error for the 12 USGS wells along a transect in the local model area was 0.08 m; the average error was 0.0 m. Particle tracking was used with the local model to estimate the concentration of an environmental tracer, sulfur hexafluoride, in 10 USGS transect wells near the Merced River that were sampled for this constituent. Measured and estimated concentrations in the mid-depth and deepest wells, which would be most sensitive to errors in hydraulic conductivity estimates, were consistent. The combined results of particle tracking and sulfur hexafluoride analysis suggest that most water sampled from the transect wells was recharged less that 25 years ago.

Scientific Investigations Report↗

Predicting methane emissions and developing reduction strategies for a Central Appalachian Basin, USA, longwall mine through analysis and modeling of geology and degasification system performance

Coal mine methane is a safety concern in active mines due to explosion risk and an environmental concern due to the greenhouse gas (GHG) properties of methane emissions to the atmosphere. Depending on the mine design and operation, structural and stratigraphic characteristics of the geology, and the properties of coal beds affected by mining, a significant amount of methane can be released during coal extraction. These emissions may be low and uniform, but they also can be high and abrupt, if not captured by using pre- and post-mining methods of degasification or not controlled by ventilation during mining. Therefore, emissions should be monitored and predicted accurately for underground safety and GHG reduction. Ventilation and degasification systems should be designed accordingly by taking into account the mine geological properties and the degasification system's performance. This paper presents a comprehensive study to predict emissions and proposes alternatives to reduce emissions in a longwall mine extracting metallurgical coal from the Pocahontas No. 3 coal bed in Virginia (Central Appalachian Basin), USA. The work focused on mining activity in four adjacent panels through analysis and modeling of geology and evaluation of the performance of the methane control system. Results showed that the mine geology contained a significant amount of gas within and around the panel areas, which was controlled by utilizing different degasification methods besides ventilation during mining. The study showed that after pre-mining degasification using fractured vertical wells and in-seam horizontal wells, each panel potentially contained ∼19 MMscf and ∼ 2 MMscf of gas remaining to be handled by the gob gas ventholes (GGVs) and the ventilation, respectively, per acre of mining. It was shown that extending the pre-mining degasification duration of vertical wells by as much as 4 years or drilling more horizontal wells with closer spacing could significantly reduce ventilation and gob emissions during the mining of coal.

Kentucky, Virginia, West Virginia↗

Groundwater quality in the Delaware, Genesee, and St. Lawrence River Basins, New York, 2015

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, collected groundwater samples from 5 production wells and 5 domestic wells in the Delaware River Basin, 8 production wells and 7 domestic wells in the Genesee River Basin, and 1 municipal well, 7 production wells, and 13 domestic wells in the St. Lawrence River Basin in New York. All samples were collected from May through November 2015 in an effort to characterize groundwater quality in these basins. The samples were collected and processed by using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds, radionuclides, and indicator bacteria. The Delaware River Basin study area covers 2,360 square miles (mi 2 ) in southeastern New York. Of the 10 wells sampled in the Delaware River Basin, 3 are completed in sand and gravel, and 7 are completed in bedrock. Groundwater in the Delaware River Basin was generally of good quality, although properties and concentrations of some constituents—pH, iron, manganese, aluminum, radon-222, and total coliform bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (10 of 10 samples) was radon-222. The Genesee River Basin study area includes the entire 2,439 mi 2 of the basin in western New York. Of the 15 wells sampled in the Genesee River Basin, 6 are completed in sand and gravel, and 9 are completed in bedrock. Groundwater in the Genesee River Basin was generally of good quality, although properties and concentrations of some constituents—chloride, sodium, dissolved solids, iron, manganese, aluminum, arsenic, radon-222, methane, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (12 of 15 samples) was radon-222. The St. Lawrence River Basin study area includes the entire 5,650 mi 2 of the basin in northeastern New York. Of the 21 wells sampled in the St. Lawrence River Basin, 7 are completed in sand and gravel, and 14 are completed in bedrock. Groundwater in the St. Lawrence River Basin was generally of good quality, although properties and concentrations of some constituents—pH, chloride, sodium, dissolved solids, iron, manganese, sulfate, nitrate, radon-222, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (14 of 21 samples) was radon-222.

New York↗

Environmental processes that affect mineral deposits in the eastern United States

A thorough understanding of the environmental processes that affect mineral deposits and mine wastes has become increasingly important as the Nation wrestles with how to meet our current demand for metals without compromising the environment and how to mitigate the damage caused by the mining practices of previous generations. Regulatory requirements are dominated by empirical approaches to environmental problems associated with mining, but mitigation and reclamation can be enhanced greatly by a theoretical and conceptual understanding of the processes that affect the availability, transport, and fixation of metals and the generation of acidic waters. U.S. Geological Survey (USGS) research efforts in the Eastern United States are concentrating on environmental processes that affect a class of mineral deposits known as massive sulfide deposits. These occurrences were valued historically for their sulfur content and recently for their metals. This deposit type is a research priority because of its economic significance and high potential for adverse environmental impact due to its high sulfide content and the low acid-buffering capacity of host rocks. Numerous examples of these deposits are found in the East, including reclaimed mine sites, abandoned mines, active mines, and sites currently in the permitting process for future production. Published studies of mine drainage chemistry from the Iron Mountain massive sulfide deposit in California have documented extreme conditions of very low pH and high heavy-metal concentrations. These extreme conditions are attributed to the unique hydrologic and climatic settings of the deposit and probably are independent of the mineral deposit type. Areas currently under study include Bald Mountain, Maine, the Great Smoky Mountains National Park, the Vermont copper belt, Contrary Creek, Virginia, and Prince William Forest Park, Virginia (fig.1). Goals of the research are (1) to give land-use planners and the mining industry a better empirical framework from which to assess potential environmental impacts of mining, particularly under eastern climatic conditions, and (2) to provide a better theoretical and conceptual framework from which to design more effective and cost efficient mitigation and reclamation programs.

Information Handout↗

Applications of imaging spectroscopy data: A case study at Summitville, Colorado

From 1985 through 1992, the Summitville open-pit mine produced gold from lowgrade ore using cyanide heap-leach techniques, a method to extract gold whereby the ore pile is sprayed with water containing cyanide, which dissolves the minute gold grains. Environmental problems due to mining activity at Summitville include significant increases in acidic and metal-rich drainage from the site, leakage of cyanide-bearing solutions from the heap-leach pad into an underdrain system, and several surface leaks of cyanide-bearing solutions into the Wightman Fork of the Alamosa River. In general, drainage from the Summitville mine moves downslope into the Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the Terrace Reservoir before entering the agricultural lands of the San Luis Valley. The increase in the trace-metal burden of the Alamosa River watershed due to the mining activities at Summitville is of concern to farmers and fisherman, as well as Federal and State of Colorado agencies having responsibility for land stewardship. The environment of the Summitville area is a result of 1) its geologic evolution, that culminated in the formation of precious-metal mineral deposits; and 2) previous metal mining activity. Mining accentuates, accelerates, and pertubates natural geochemical processes. The development of underground workings, open pits, mill tailings, and spoil heaps and the extractive processing of ore enhances the likelihood of releasing chemicals and elements to the surrounding areas and at increased rates relative to unmined areas. Both mined and unmined mineralized areas can produce acid drainage from the formation and movement of highly acidic water rich in heavy metals. This acidic water forms principally through the chemical reaction of oxygenated surface water and shallow subsurface water with rocks that contain sulfide minerals, producing sulphuric acid. Heavy metals can be leached by the acid solution that comes in contact with mineralized rocks, a process that may be enhanced by bacterial action. The resulting fluids may be highly toxic and, when mixed with groundwater, surface water, and soil, may have harmful effects on humans, animals, and plants. Thus, understanding the geologic and hydrologic history of this area is a critical piece of the environmental puzzle in the Summitville area. The Summitville mine operators had ceased active mining and begun environmental remediation, including treatment of the heap-leach pile and installation of a water-treatment facility, when it declared bankruptcy in December 1992 and abandoned the mine site. The U.S. Environmental Protection Agency (EPA) immediately took over the Summitville site under EPA Superfund Emergency Response authority. Summitville has focused public attention on the environmental effects of modern mineral-resource development. Soon after the mine was abandoned, Federal, State, and local agencies, along with Alamosa River water users and private companies, began extensive studies at the mine site and surrounding areas. These studies included analysis of water, soil, livestock and vegetation. The role of the U.S. Geological Survey (USGS) was to provide geologic, hydrologic and agricultural information about the mine and surrounding area and to describe and evaluate the environmental condition of the Summitville mine and the downstream effects of the mine on the San Luis Valley (King 1995).

Colorado↗

Southeast Regional Assessment Project for the National Climate Change and Wildlife Science Center, U.S. Geological Survey

The Southeastern United States spans a broad range of physiographic settings and maintains exceptionally high levels of faunal diversity. Unfortunately, many of these ecosystems are increasingly under threat due to rapid human development, and management agencies are increasingly aware of the potential effects that climate change will have on these ecosystems. Natural resource managers and conservation planners can be effective at preserving ecosystems in the face of these stressors only if they can adapt current conservation efforts to increase the overall resilience of the system. Climate change, in particular, challenges many of the basic assumptions used by conservation planners and managers. Previous conservation planning efforts identified and prioritized areas for conservation based on the current environmental conditions, such as habitat quality, and assumed that conditions in conservation lands would be largely controlled by management actions (including no action). Climate change, however, will likely alter important system drivers (temperature, precipitation, and sea-level rise) and make it difficult, if not impossible, to maintain recent historic conditions in conservation lands into the future. Climate change will also influence the future conservation potential of non-conservation lands, further complicating conservation planning. Therefore, there is a need to develop and adapt effective conservation strategies to cope with the effects of climate and landscape change on future environmental conditions. Congress recognized this important issue and authorized the U.S. Geological Survey (USGS) National Climate Change and Wildlife Science Center (NCCWSC; http://nccw.usgs.gov/) in the Fiscal Year 2008. The NCCWSC will produce science that will help resource management agencies anticipate and adapt to climate change impacts to fish, wildlife, and their habitats. With the release of Secretarial Order 3289 on September 14, 2009, the mandate of the NCCWSC was expanded to address climate change-related impacts on all Department of the Interior (DOI) resources. The NCCWSC will establish a network of eight DOI Regional Climate Science Centers (RCSCs) that will work with a variety of partners to provide natural resource managers with tools and information that will help them anticipate and adapt conservation planning and design for projected climate change. The forecasting products produced by the RCSCs will aid fish, wildlife, and land managers in designing suitable adaptive management approaches for their programs. The DOI also is developing Landscape Conservation Cooperatives (LCCs) as science and conservation action partnerships at subregional scales. The USGS is working with the Southeast Region of the U.S. Fish and Wildlife Service (FWS) to develop science collaboration between the future Southeast RCSC and future LCCs. The NCCWSC Southeast Regional Assessment Project (SERAP) will begin to develop regional downscaled climate models, land cover change models, regional ecological models, regional watershed models, and other science tools. Models and data produced by SERAP will be used in a collaborative process between the USGS, the FWS (LCCs), State and federal partners, nongovernmental organizations, and academia to produce science at appropriate scales to answer resource management questions. The SERAP will produce an assessment of climate change, and impacts on land cover, ecosystems, and priority species in the region. The predictive tools developed by the SERAP project team will allow end users to better understand potential impacts of climate change and sea level rise on terrestrial and aquatic populations in the Southeastern United States. The SERAP capitalizes on the integration of five existing projects: (1) the Multi-State Conservation Grants Program project "Designing Sustainable Landscapes," (2) the USGS multidisciplinary Science Thrust project "Water Availability for Ecological Needs," (3) the USGS Southeast Pilot Project "Climate Change in the Southeastern U.S. and its Impacts on Bird Distributions and Habitats," (4) a sea-level rise impacts study envisioned jointly with the National Oceanic and Atmospheric Administration (NOAA), and (5) two USGS sea-level rise impact assessment projects that address inundation hazards and provide probabilistic forecasts of coastal geomorphic change. The SERAP will expand on these existing projects and include the following tasks, which were initiated in summer 2009: * Regionally downscaled probabilistic climate-change projections * Integrated coastal assessment * Integrated terrestrial assessment * Multi-resolution assessment of potential climate change effects on biological resources: aquatic and hydrologic dynamics * Optimal conservation strategies to cope with climate change The SERAP seeks to formally integrate these tasks to aid conservation planning and design so that ecosystem management decisions can be optimized for providing desirable outcomes across a range of species and environments. The following chapters detail SERAP's efforts in providing a suite of regional climate, watershed, and landscape-change analyses and develop the interdisciplinary framework required for the biological planning phases of adaptive management and strategic conservation. The planning phase will include the identification of conservation alternatives, development of predictive models and decision support tools, and development of a template to address similar challenges and goals in other regions. The project teams will explore and develop ways to link the various ecological models arising from each component. The SERAP project team also will work closely with members of the LCCs and other partnerships throughout the life of the project to ensure that the objectives of the project meet resources mangers needs in the Southeast.

Open-File Report↗

Environmental Setting and Implications on Water Quality, Upper Colorado River Basin, Colorado and Utah

The Upper Colorado River Basin in Colorado and Utah is 1 of 60 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment program, which began full implementation in 1991. Understanding the environmental setting of the Upper Colorado River Basin study unit is important in evaluating water-quality issues in the basin. Natural and human factors that affect water quality in the basin are presented, including an overview of the physiography, climatic conditions, general geology and soils, ecoregions, population, land use, water management and use, hydrologic characteristics, and to the extent possible aquatic biology. These factors have substantial implications on water-quality conditions in the basin. For example, high concentrations of dissolved solids and selenium are present in the natural background water conditions of surface and ground water in parts ofthe basin. In addition, mining, urban, and agricultural land and water uses result in the presence of certain constituents in the surface and ground water of the basin that can detrimentally affect water quality. The environmental setting of the study unit provides a framework of the basin characteristics, which is important in the design of integrated studies of surface water, ground water, and biology.

Water-Resources Investigations Report↗

Developing integrated methods to address complex resource and environmental issues

Introduction This circular provides an overview of selected activities that were conducted within the U.S. Geological Survey (USGS) Integrated Methods Development Project, an interdisciplinary project designed to develop new tools and conduct innovative research requiring integration of geologic, geophysical, geochemical, and remote-sensing expertise. The project was supported by the USGS Mineral Resources Program, and its products and acquired capabilities have broad applications to missions throughout the USGS and beyond. In addressing challenges associated with understanding the location, quantity, and quality of mineral resources, and in investigating the potential environmental consequences of resource development, a number of field and laboratory capabilities and interpretative methodologies evolved from the project that have applications to traditional resource studies as well as to studies related to ecosystem health, human health, disaster and hazard assessment, and planetary science. New or improved tools and research findings developed within the project have been applied to other projects and activities. Specifically, geophysical equipment and techniques have been applied to a variety of traditional and nontraditional mineral- and energy-resource studies, military applications, environmental investigations, and applied research activities that involve climate change, mapping techniques, and monitoring capabilities. Diverse applied geochemistry activities provide a process-level understanding of the mobility, chemical speciation, and bioavailability of elements, particularly metals and metalloids, in a variety of environmental settings. Imaging spectroscopy capabilities maintained and developed within the project have been applied to traditional resource studies as well as to studies related to ecosystem health, human health, disaster assessment, and planetary science. Brief descriptions of capabilities and laboratory facilities and summaries of some applications of project products and research findings are included in this circular. The work helped support the USGS mission to “provide reliable scientific information to describe and understand the Earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life.” Activities within the project include the following: Spanned scales from microscopic to planetary; Demonstrated broad applications across disciplines; Included life-cycle studies of mineral resources; Incorporated specialized areas of expertise in applied geochemistry including mineralogy, hydrogeology, analytical chemistry, aqueous geochemistry, biogeochemistry, microbiology, aquatic toxicology, and public health; and Incorporated specialized areas of expertise in geophysics including magnetics, gravity, radiometrics, electromagnetics, seismic, ground-penetrating radar, borehole radar, and imaging spectroscopy. This circular consists of eight sections that contain summaries of various activities under the project. The eight sections are listed below: Laboratory Facilities and Capabilities, which includes brief descriptions of the various types of laboratories and capabilities used for the project; Method and Software Development, which includes summaries of remote-sensing, geophysical, and mineralogical methods developed or enhanced by the project; Instrument Development, which includes descriptions of geophysical instruments developed under the project; Minerals, Energy, and Climate, which includes summaries of research that applies to mineral or energy resources, environmental processes and monitoring, and carbon sequestration by earth materials; Element Cycling, Toxicity, and Health, which includes summaries of several process-oriented geochemical and biogeochemical studies and health-related research activities; Hydrogeology and Water Quality, which includes descriptions of innovative geophysical, remote-sensing, and geochemical research pertaining to hydrogeology and water-quality applications; Hazards and Disaster Assessment, which includes summaries of research and method development that were applied to natural hazards, human-caused hazards, and disaster assessments; and Databases and Framework Studies, which includes descriptions of fundamental applications of geophysical studies and of the importance of archived data.

Circular↗

Delineation of groundwater recharge areas, western Cape Cod, Massachusetts

The unconfined sand-and-gravel aquifer in western Cape Cod, Massachusetts, which is the sole source of water supply for the communities in the area, is recharged primarily from precipitation. The rate of recharge from precipitation is estimated to be about 26 inches per year (in/yr), or about 60 percent of the precipitation rate. This recharge rate yields a flow through the aquifer of about 180 million gallons per day (Mgal/d). Groundwater flows radially outward from the top of the water-table mound in the north-central part of the flow system toward the coast, as indicated by the water-table contours on the large map on this sheet. Recharge that reaches the water table near the top of the mound travels deeper through the aquifer than recharge that reaches the water table closer to the coast. All recharge to the aquifer ultimately discharges to pumping wells, streams, or coastal areas; however, some of this recharge may flow first through kettle ponds before eventually reaching these discharge points. Continued land development and population growth on western Cape Cod, and activities related to the operation of the Massachusetts Military Reservation (MMR), have created concerns regarding the supply of potable water in western Cape Cod and the quality and quantity of water discharging to ponds, streams, and coastal areas. Recent investigations estimated the future demand for drinking water in western Cape Cod, as well as the areas that contribute water to existing and proposed public-supply wells. Determining the source of freshwater that discharges to ponds, streams, and coastal areas is of critical importance in the protection of these natural resources for the communities of western Cape Cod. The purpose of this report is to illustrate concepts of ground-water recharge areas under average pumping and recharge conditions. This report presents results of an investigation conducted by the U.S. Geological Survey (USGS), in cooperation with the Air Force Center for Environmental Excellence (AFCEE), to delineate the areas that contribute recharge to public-supply wells, ponds, streams, and coastal areas on western Cape Cod for average annual pumping and recharge rates for the period of 1994–1996. The time period of 1994–1996 was selected for this analysis because it represents the average stress conditions prior to large-scale pumping, treatment, and reinjection of water from the MMR Installation Restoration Program's ground-water remediation systems. The pumping and reinjection of large amounts of water from these remediation systems would complicate greatly the delineation of ground-water recharge areas and therefore is beyond the scope of this analysis. The Chemical Spill-4 plume-containment system, however, is included in the simulation since it has been operating since 1993 and has been pumping, treating, and reinjecting only about 0.2 Mgal/d of water. Since 1996, however, AFCEE has constructed remediation systems for seven additional contaminant plumes that are not included in this analysis. Currently (1999), these systems are pumping, treating, and reinjecting about 9.7 Mgal/d. By 2002, when all of these systems, including those being designed, are expected to be operating, it is estimated that they will be pumping, treating, and reinjecting as much as 15.6 Mgal/d of water in the western Cape Cod aquifer. For additional information on the hydrology and geology of western Cape Cod, the reader is referred to the following reports: LeBlanc and others (1986), Barlow and Hess (1993), Masterson and others (1997a), Masterson and others (1997b), Masterson and others (1998), Ogden Environmental and Energy Services, Inc. (1998) and Jacobs Engineering Group, Inc. (1999).

Massachusetts↗

The 7Q10 in South Carolina water-quality regulation: Nearly fifty years later

The annual minimum 7-day average streamflow with a 10-year recurrence interval, often referred to as the 7Q10, has a long history of being an important low-flow statistic used in water-quality management in South Carolina as evidenced by its adoption into South Carolina law in 1967. State agencies, such as the South Carolina Department of Health and Environmental Control and the South Carolina Department of Natural Resources, use such lowflow statistics to determine Wasteload Allocations for National Pollutant Discharge Elimination System discharges, develop Total Maximum Daily Loads for streams, prepare the State Water Plan, and restrict the quantity of water that can be transferred out of basin. The U.S. Geological Survey, working cooperatively with the South Carolina Department of Health and Environmental Control, is updating low-flow statistics at continuous-record streamflow gages in South Carolina on a basin-by-basin approach. Such statistics are influenced by length of record and hydrologic conditions under which the record was collected. Statewide low-flow statistics in South Carolina were last updated in 1987. Since that time several droughts have occurred with the most severe occurring from 1998-2002 and the most recent occurring from 2006-2009. The low-flow statistics for the Pee Dee River basin were the first to be completed in this ongoing investigation.

South Carolina↗

Groundwater-Quality Survey of the South Coast Aquifer of Puerto Rico, April 2 through May 30, 2007

The increased potential for variability of groundwater quality in the South Coast aquifer of Puerto Rico due to saline water encroachment from the Caribbean Sea and from deep parts of the aquifer has become a major concern of water planners and managers. In an effort to determine the extent and sources of this encroachment, the U.S. Geological Survey (USGS) and the Puerto Rico Department of Natural and Environmental Resources conducted a synoptic groundwater-quality survey from April 2 through May 30, 2007, for the South Coast aquifer between Ponce and Arroyo (fig. 1). Groundwater resources in this aquifer extend 150 square miles in south-central Puerto Rico and provide an estimated 44.2 million gallons per day (Mgal/d) or about 61 percent of the total water needs. This amount includes: 15.3 Mgal/d for irrigation, 27.4 Mgal/d for public supply, and 1.5 Mgal/d for industrial and other uses (W.L. Molina-Rivera, U.S. Geological Survey, written commun., 2007). Since 1980 when most of the south coastal plain was intensively cultivated for sugarcane, total groundwater withdrawals have declined about 32 Mgal/d with the greatest decline occurring in irrigation (37.2 Mgal/d) and the greatest increase occurring in public supply (5.5 Mgal/d). Although withdrawals have declined substantially, a major concern is that aquifer recharge provided by irrigation return flow from surface-water irrigation canals has essentially dropped to zero because of the large-scale implementation of groundwater drip irrigation systems.

Scientific Investigations Map↗

Geohydrology and water quality of the northern and central parts of the Tug Hill glacial aquifer, Jefferson and Oswego Counties, north-central New York

The northern and central parts of the Tug Hill glacial aquifer consist of a 29-mile-long, crescent-shaped, mixture of glaciofluvial, glaciolacustrine, and recent alluvial deposits of predominantly sand and gravel on the western side of the Tug Hill Plateau in Jefferson and Oswego Counties in north-central New York. Approximately 11,400 people are supplied by groundwater that is withdrawn from municipal and nonmunicipal wells in the northern and central parts of the aquifer. In addition, many farms, several industries, and a large New York State fish hatchery also rely on the water from the aquifer. In the early 2000s, anticipated developmental pressures from potential new industries (including a proposed water-bottling plant in the central part of the Tug Hill glacial aquifer) and expansion of the Fort Drum military base north of Watertown (with the projected increase in population extending into the northern part of the aquifer) prompted the Tug Hill Commission, local municipal officials, and representatives from the New York State Department of Environmental Conservation to initiate a geohydrologic study with the U.S. Geological Survey. The information from this study is intended to help the state, counties, and local communities make sound policy decisions about their use of this large groundwater resource. The northern part of the Tug Hill glacial aquifer is a combination of glaciofluvial outwash and alluvial sand and gravel in the Sandy Creek Valley northeast of Adams, New York, and mostly glaciolacustrine beach and deltaic sand or sand and gravel north and south of the village of Adams. The southern and eastern areas of the central part of the aquifer are composed mostly of glaciofluvial sediments such as kames, kame moraines, and kame terraces, whereas most of the western areas of the central part are composed mostly of glaciolacustrine sediments such as deltaic sand and beach sand and gravel. The northern and central parts of the aquifer are unconfined. Recharge to the northern and central parts of the aquifer is from three main sources: (1) precipitation that falls directly onto the aquifer; (2) unchannelized runoff (overland flow) and groundwater from till and bedrock in the Tug Hill Plateau that seeps into the eastern side of the aquifer; and (3) streams that drain the Tug Hill Plateau and flow across and lose water to the aquifer. Groundwater discharges to springs, seeps, headwaters of streams, and wetlands in the middle area of the central part of the aquifer and along the entire western boundary of the northern and central parts of the aquifer; pumping wells; artificial ditches; and deeply incised streams in the northern and central parts of the aquifer. The groundwater discharge to such streams is critical in supporting the salmonid fishery in the central part of the aquifer. Groundwater levels were measured on July 17, 2014, at 22 wells throughout the northern and central parts of the aquifer. Water-table contours were drawn on the basis of the measured July 2014 water levels, historical water-level data, and surface-water levels where surface water in the channels was expected to be hydraulically connected to the groundwater system. The water table generally slopes from east to west throughout the northern and central parts of the aquifer; this slope also indicates that the direction of groundwater flow is generally from east to west. Water-quality samples were collected from 23 stream sites during base-flow conditions, and groundwater-quality and other types of environmental samples were collected from 20 wells in the northern and central parts of the Tug Hill glacial aquifer. The results of the sampling indicate that surface water and groundwater are generally of good quality. Comparison of the median concentration values of major ions in groundwater samples indicated that hardness in the northern part of the aquifer was about twice as great, and concentrations of calcium and sodium were more than three times as great, as in the central part of the aquifer. As was the case with surface water, the much greater median concentrations in groundwater of calcium, hardness, and alkalinity in the northern part of the aquifer are due to the dissolution of limestone that underlies most of that area and to the high-carbonate content of the clasts in the sand and gravel. There was little to no difference among the median values for bromide, fluoride, silica, and iron in the two parts of the aquifer. Concentrations of most other major ions were slightly greater in the northern part than in the central part of the Tug Hill glacial aquifer, except for magnesium, whose concentration was greater in the central part. Median concentrations of nutrients were generally greatest in surface water and groundwater in the northern part of the aquifer.

New York↗