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1,662 records · Page 62Linked to original sources

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

3-D geological modeling for numerical flow simulation studies of gas hydrate reservoirs at the Kuparuk State 7-11-12 Pad in the Prudhoe Bay Unit on the Alaska North Slope

Accurate reservoir evaluation requires reliable three-dimensional (3-D) geological models. This study conducted 3-D geological modeling for numerical flow simulation of the B1 sand gas hydrate reservoir at the Kuparuk State 7-11-12 pad, Prudhoe Bay Unit, Alaska North Slope. The model integrates well logs, core, and seismic data to address spatial heterogeneity in geological structures and reservoir properties. Two modeling types were performed: structural framework modeling and petrophysical property modeling. For structural framework modeling, seismic data and well log markers were used to reproduce subsurface structures characterized by a normal fault system. A volume-based modeling algorithm and stair-step gridding were applied. The resulting 3-D model comprised 2,640,000 grid cells across 264 layers, including seven fault grids. For petrophysical property modeling, total porosity was initially modeled using sequential Gaussian simulation with collocated cokriging. To reproduce the upward coarsening of the B1 sand, upscaled log-derived total porosity and a 3-D trend depicting total porosity variation were used as primary and secondary data, respectively. Gas hydrate saturation distribution was modeled similarly, with secondary data from estimated porosity distribution and seismic-derived acoustic impedance map enhancing accuracy. Results indicate higher gas hydrate saturation in the upper part of the B1 sand and areas with higher acoustic impedance. Intrinsic permeability was modeled from the total porosity and clay-bound water volume, and effective permeability was derived from the gas hydrate saturation and intrinsic permeability distributions based on the “Tokyo model”. Effective permeability distributions were influenced by the total porosity, gas hydrate saturation, and intrinsic permeability. Within the same layer, higher gas hydrate saturation leads to decreased effective permeability. In total, 100 sets of multiple scenarios were prepared, providing input data for dynamic flow simulations to evaluate the effects of lateral heterogeneity in reservoir properties and the hydraulic characteristics of faults on production behavior for preassessment before the long-term production test.

Alaska

A spatiotemporal deep learning approach for predicting daily air-water temperature signal coupling and identification of key watershed physical parameters in a montane watershed

Seasonal shifts from runoff to groundwater dominance influence daily headwater stream temperatures, especially where local groundwater input is strong. This input buffers temperature during hot periods, supporting cold-water habitats. Recent studies use air–water temperature signal metrics to identify zones of strong stream–groundwater connectivity. While Previous studies used air–water signal ratios as proxies for groundwater influence but were limited to specific sites and periods, without dynamic forecasting. This study is the first to forecast daily A r as a spatiotemporal signal using a Graph Convolutional Network–Long Short-Term Memory (GCN-LSTM) model. The model was trained using hydroclimate data (air temperature, precipitation, shortwave radiation, streamflow) and watershed physical features (e.g., sand content, slope). Results showed high predictive skill, achieving R 2 (NSE, RMSE) of 0.86 (0.73, 0.0004) for one-day-ahead to 0.52 (0.50, 0.0009) for seven-days ahead forecasts. Prior studies often have not explicitly incorporated spatial hydrogeologic drivers, but this model explicitly incorporates them to assess their impact on A r forecasting and stream-groundwater connectivity. Feature analysis identified mean sand, elevation, slope, clay, and TWI as key predictors of A r . Stronger groundwater signals appeared in hillslopes, elevations, and tributaries, highlighting watershed influence on streamflow. However, limitations include reliance on historical air–water temperature patterns for training and limited representation of extreme climate conditions. Despite these limitations, unlike previous studies relying on measured in-situ stream and air temperature, this study forecasts A r directly from climate and physiographic features after training, avoiding in-situ data requirements. Findings aiding predictions of stream ecosystem resilience.

New York

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado

New developments at the Center for Engineering Strong-Motion Data (CESMD)

The Center for Engineering Strong-Motion Data (CESMD), an internationally utilized joint center of the U.S. Geological Survey (USGS) and the California Geological Survey (CGS), provides a single access point for earthquake strong-motion records and station metadata from the CGS California Strong-Motion Instrumentation Program (CSMIP), the USGS National Strong-Motion Project (NSMP), the USGS Advanced National Seismic System, and other affiliates. The CESMD has been continuously improving its webtools to facilitate the access of strong-motion data and metadata for use in post-earthquake response and for scientific and engineering research applications. The Center provides raw and processed strong-motion data via the Engineering Data Center (EDC) and the Virtual Data Center (VDC) web portals. This paper focuses on the strong-motion products provided by the EDC where more than 48,000 records with peak ground accelerations greater than 0.1% g from over 2400 earthquakes are currently hosted. and on the ongoing efforts to develop data access tools and applications. The new developments and ongoing efforts in the EDC include: 1) enhancements to the CESMD webservices to facilitate access to station metadata, earthquake information, and strong motion records 2) new features to the interactive map interface, improving the visualization and access to earthquake, station, and record information, 3) efforts to develop a new web application tool for data format conversion from a number of data formats, 4) efforts to unify varying waveform data formats into a consistent format, 5) ongoing efforts to compile seismic station site geology, measured or inferred Vs30 values, shear-wave profiles, NEHRP site class, and available structural instrument deployment schematics, and 6) a special studies pages for research topic-specific ground motion datasets that offer uniform processing of records from a variety of sources.

Conference Paper

Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado

Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia

Color-Shaded Relief Bathymetry of Lake Chelan, Washington

In 2023, the U.S. Geological Survey (USGS) completed a 3-week field operation in Lake Chelan, Washington, the third deepest lake in the conterminous United States, to acquire sediment cores, high-resolution bathymetry data, and chirp sub-bottom profiles. The high-resolution bathymetry displayed in this map publication was collected using a Norbit Winghead i67-curved array multibeam system; raw data were cleaned and gridded (3 by 3 meters [m]) in the Teledyne CARIS software. In some locations where the slopes of Lake Chelan are near-vertical, multibeam returns were sparse, resulting in artifacts resembling holes that appear as grey dots within the color-shaded bathymetric relief. Although the 2023 bathymetric mapping of Lake Chelan resulted in similar morphometric characteristics to previous hydrographic campaigns (table 1; Kendra and Singleton, 1987; Pelletier and others, 1989), these new data provide a much more detailed understanding of the two physiographic basins that comprise Lake Chelan: the deeper (as deep as 445.8 m [fig. 1]; previously reported as 453 m) and narrower (1–2 kilometers [km] wide) Lucerne Basin to the north, and the shallower (as deep as 127.8 m [fig. 1]), and wider (2–3 km wide) Wapato Basin to the south. With this detailed imaging of Lake Chelan, we find pervasive morphological evidence of slope failure and mass-transport deposits (MTDs) in at least 89 locations within the lake and 63 subaqueous deltas (fig. 2). The deeper Lucerne Basin is dominated by steep slopes and numerous subaqueous deltas fed by steep fluvial catchments, whereas the Wapato Basin contains numerous landslide scarps, scars, and debris aprons along the more gently sloping lake margins, and abundant relict kettle structures from the Pleistocene deglaciation. Lake Chelan’s geomorphic, geophysical, and sediment data contain important records of glacial retreat and advance, regional volcanic eruptions, and earthquakes that generate ground motions severe enough to induce landslides recorded in the sediment as MTDs. The epicenter of the 1872 Washington State Earthquake (M 6.5–7.2; Bakun and others, 2002; Brocher and others, 2017; Sherrod and others, 2021) is along the Spencer Canyon Fault, near the southern end of Lake Chelan. Shaking from this earthquake was strong enough to affect local aquifers, induce liquefaction of unconsolidated sediments, produce large seiches (Brocher and others, 2018), and likely cause landslides within Lake Chelan.

Washington

The 17 January 1994 Northridge, California, earthquake: A retrospective analysis

The 17 January 1994 Northridge, California, earthquake was a watershed event, with far-reaching societal and scientific impacts. The earthquake, which occurred in the early days of both broadband seismic networks and the Internet, spurred advances in seismic monitoring, real-time systems, and development of data products. Motivated by the 30th anniversary of the earthquake, we present a brief retrospective of the earthquake and its impact, and reconsider both ground motions and the aftershock distribution using modern tools and best-available data. With improvements in instrumentation and analysis methodology, recent earthquakes continue to reveal increasing complexity of ground motions, fault systems, and earthquake ruptures. Even in the absence of data from state-of-the art instrumentation, a retrospective consideration of ground motion data from the Northridge earthquake reveals complexities beyond what could be characterized (and modeled) thirty years ago. Aftershock relocations for both the 1971 Sylmar and 1994 Northridge earthquakes also reveal an updated view of fault complexity. Our study does provide a cautionary tale regarding legacy data sets and research results that are not easily accessible, which can result in discrepancies between catalog data and products from best-available science. We also briefly describe outreach products produced as part of the anniversary commemoration.

California

Waters divided: A history of alluvial fan research and a view of its future

Flows exiting confined valleys tend to deposit sediment in fan-shaped landforms. Where deposition is wholly or largely by the tractive forces of flowing water, these landforms are called alluvial fans. They are the product of the progressive division of water and sediment downfan, from slopes that may exceed 0.10 to distal slopes that may be below 0.01. Channel depths also tend to decline, from values that approach one to several meters at steep fanheads, to a few decimeters at distal fan margins. The result is a radiating, depositional ramp where confined or unconfined flows transport sediment from source basins to bounding streams, subsiding basins, or stable platforms. Where streams or subsiding basins consume the sediment supply from the source basin, the fan may approach a steady form whose extent and distal slope are set by stream location or subsidence rate. Where boundary conditions do not remove sediment, the fan may prograde out to long distances and low slopes (<0.01). Theoretical and experimental work over the past several decades support the notion that alluvial fan long-profiles become steeper as sediment supply increases or transport capacity decreases, and increasingly concave upward as the rate of bed material deposition decreases downfan. Grainsize distributions of alluvial fans seem to span the range observed in alluvial rivers, with no processes that uniquely identify them, apart from the distributary pattern of deposition. Bed sand cover tends to increase downfan in arid-region fans, with an absence of systematic downfan fining of coarser grain sizes. Surficial mapping and geochronology have demonstrated that fan deposition varies greatly through time, arguably from climate variations that alter hillslope sediment supply. The combination of surficial mapping and hydraulic modeling with high-resolution topography can now produce detailed flood susceptibility maps. The effective use of these maps to protect lives and property, however, depends on answering many of the enduring questions about the mechanics of how water and sediment divide down alluvial fans.

Book chapter

Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

To test the influence of environmental conditions on aromaticity of solid bitumen generated during petroleum generation, four organic-rich (26–36 wt% total organic carbon) oil shale samples collected from the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan, were pyrolyzed under hydrous and anhydrous conditions. Experiments used closed system batch reactors at subcritical water temperatures between 300 and 370°C for 72 h. Thermal conversion of bituminite in the Salt Range oil shales created a newly formed solid bitumen, similar to previous observations from experiments on the Eocene lacustrine Green River Formation Mahogany zone oil shale. Newly formed solid bitumen in the Salt Range Formation oil shales generally has higher reflectance (R o ) in hydrous residues compared to anhydrous experiments subjected to the same time-temperature conditions, also similar to prior observations. This finding supports the hypothesis that radical disproportionation is favored in the presence of hydrogen contributed by water, promoting aromatization in the solid bitumen residue with concomitant increased expulsion of saturated hydrocarbons. Indigenous solid bitumen (and vitrinite in a comparison sample) also shows higher reflectance values in hydrous versus anhydrous residues, indicating that additional aromatization in the presence of exogenous hydrogen occurs both in newly formed organic matter and in organic matter that is present throughout the experiment. Despite similarities in their bulk rock geochemical screening parameters, R o evolution shows different trajectories amongst the four Salt Range oil shales, suggesting as-yet undetermined differences in kinetic properties which are probably related to differences in a priori chemical composition. These results have implications for the use of solid bitumen reflectance (BR o ) as a thermal proxy, suggesting BR o values and appearance could vary as a function of the concentration of water. Variation in water concentration may be present at the reservoir or formation scale, but may also be present at a much finer scale in tight oil shales where permeability is several orders of magnitude lower than conventional reservoirs. Therefore, local variations in the presence of water potentially could explain substantial variation in BR o values and appearance in closely spaced source rock samples and even within an individual microscope field.

Journal of Analytical and Applied Pyrolysis

Unprecedented burning in tropical peatlands during the 20th century compared to the previous two millennia

Tropical peatland wildfire incidence has risen in recent decades, driven by drainage for land use and intensified by severe droughts with global climate change. These disturbances have altered vegetation structure, disrupted ecosystem functioning, and increased carbon emissions, particularly in Southeast Asia. However, the long-term history and characteristics of wildfires in tropical peatlands remain largely unknown. Here, we compiled fifty-eight macro-charcoal records from peatlands across the tropics, ranging from lowland forested to montane peatlands, to assess millennia-scale changes and controlling factors of tropical peatland burning. We divided the datasets into four main sub-regions: Neotropical, Afrotropical, Indomalayan and Australasian ecoregions to explore regional variability. Tropical peatlands had high burning levels between 0 and 850 ce , followed by a relatively low and stable period until a marked increase during the 20th century. The general trend in tropical peatland burning follows changes in global temperature, and climate variables that control the length and severity of drought events have a notable influence on peat burning before 1900 ce . During the 20th century, regional differences were observed, with declining fire trends in the Neotropical and Afrotropical regions and increasing fire trends in the Indomalayan and Australasian regions. This difference is likely attributable to human activities, and such intervention is also evident in palm swamps and hardwood swamps under similar wet, weakly seasonal climates. With the increase in anthropogenic pressures on peatlands and greater climate variability, future wildfires in peatlands are likely to become more frequent and widespread across all tropical ecoregions. Conservation and sustainable land-use practices could be used to mitigate and control peatland burning and protect these carbon-rich sinks.

Global Change Biology

Metal-rich lacustrine sediments from legacy mining perpetuate copper exposure to aquatic-riparian food webs

Historic copper mining left a legacy of metal-rich tailings resulting in ecological impacts along and within Torch Lake, an area of concern in the Keweenaw Peninsula, Michigan, USA. Given the toxicity of copper to invertebrates, this study assessed the influence of this legacy on present day nearshore aquatic and terrestrial ecosystems. We measured the metal (Co, Cu, Ni, Zn, Cd) and metalloid (As) concentrations in sediment, pore water, surface water, larval and adult insects, and two riparian spider taxa collected from Torch Lake and a nearby reference lake. Overall, elevated metal and metalloid concentrations, particularly Cu, were measured in all sediment samples and some surface and pore water samples collected from Torch Lake. For instance, Cu concentrations in the Torch Lake sediment were ∼200% higher than the reference lake and all measured concentrations exceeded predicted effects concentrations by at least ninefold. Within larval insect tissues, we observed 160% higher Cu concentrations than measured in the reference lake, and Cu was the only measured element above predicted effects concentrations in Torch Lake. Adult insects collected at both lakes had similar metal concentrations irrespective of exposure levels. Yet we found 100% higher copper concentrations in Torch Lake riparian spiders, demonstrating elevated exposure risk to insectivores across the aquatic-terrestrial boundary. Our results highlight that other metals in the mixture may not be as concerning to adjacent riparian ecosystems, but copper remains a contaminant of concern in Torch Lake 60 years after mining ceased.

Michigan

Interactive effects of salinity and hydrology on radial growth of bald cypress (Taxodium distichum (L.) Rich.) in coastal Louisiana, USA

Tidal freshwater forests are usually located at or above the level of mean high water. Some Louisiana coastal forests are below mean high water, especially bald cypress ( Taxodium distichum (L.) Rich.) forests because flooding has increased due to the combined effects of global sea level rise and local subsidence. In addition, constructed channels from the coast inland act as conduits for saltwater. As a result, saltwater intrusion affects the productivity of Louisiana’s coastal bald cypress forests. To study the long-term effects of hydrology and salinity on the health of these systems, we fitted dendrometer bands on selected trees to record basal area increment as a measure of growth in permanent forest productivity plots established within six bald cypress stands. Three stands were in freshwater sites with low salinity rooting zone groundwater (0.1–1.3 ppt), while the other three had higher salinity rooting zone groundwater (0.2–4.9 ppt). Water level was logged continuously, and salinity was measured monthly to quarterly on the surface and in groundwater wells. Higher groundwater salinity levels were related to decreased bald cypress radial growth, while higher freshwater flooding increased radial growth. With these data, coastal managers can model rates of bald cypress forest change as a function of salinity and flooding.

Louisiana

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York

Mesoproterozoic to Paleozoic tectonics, Pleistocene landforms, and Holocene seismicity in the Blue Ridge: Results from integrated studies of the 9 August 2020, Mw 5.1 earthquake area near Sparta, North Carolina, USA

This field trip examines the results of integrated geologic studies of the 9 August 2020, M w 5.1 earthquake near Sparta, North Carolina, USA. The earthquake generated ~4 km of coseismic surface rupture of the Little River fault and uplifted a surface area of ~11 km 2 . The Little River fault is a thrust fault oriented 110–130°/45–70°SW, and mapped fault segments are en echelon with scarp heights from <5–30 cm. The epicenter is in polydeformed rocks of the Ashe and Alligator Back Metamorphic Suites in the eastern Blue Ridge. Bedrock structure formed during multiple Paleozoic orogenies; the regional foliation strikes NE-SW and dips SE (mean orientation 063°/52°SE). Mapping identified late Paleozoic veins and shear zones, a regional joint set striking 330–340° and 250–240°, and brittle faults that cut the Paleozoic foliation. Brittle faults oriented similar to the Little River fault are mapped up to 4 km along strike from the coseismic rupture along Bledsoe Creek valley, and the combined length of the Little River fault system is ~8 km. Paleoseismic trenches across the Little River fault corroborate the reactivation of an older fault by the 2020 earthquake and reveal two events during late Pleistocene (<50 ka). Surficial mapping identified several terrace deposits, including a deposit along Bledsoe Creek that yielded a 26 Al/ 10 Be isochron burial age of 0.46 ± 0.13 Ma and overlies a brittle fault, thus constraining the timing of movement of the fault at that location. Paleoliquefaction studies document soft-sediment deformation features in alluvium that may represent paleoseismic events. Collectively, these results highlight long-lived paleoseismicity of the Blue Ridge and that the 9 August 2020 earthquake reactivated an older, suitably oriented brittle fault in the bedrock. The Little River fault is an example of a previously unknown but active fault lying outside of known seismic zones with demonstrated recurrence of paleo-ruptures, raising questions about the assumption that damaging earthquakes are limited to areas of ongoing background seismicity, which is counter to seismic hazard assessments in the eastern United States. Bedrock mapping separates eastern Blue Ridge lithostratigraphy of the Lynchburg Group and Ashe and Alligator Back Metamorphic Suites into separate fault-bound packages juxtaposed over various 1.3–1.0 Ga basement rocks of the northern French Broad massif by the Gossan Lead fault.

North Carolina

Three-dimensional hydrogeologic framework model of the Russian River watershed, California

The Russian River watershed is in northern Sonoma County and southern Mendocino County, California, in the northern part of the California Coast Ranges. The Russian River serves as a supply for agricultural irrigation and for municipal, domestic, and commercial uses. Through a cooperative agreement with the California State Water Resources Control Board and Sonoma County Water Agency, the U.S. Geological Survey has completed studies to better understand the hydrogeologic system and develop numerical hydrologic modeling tools to evaluate and aid in managing groundwater resources. This report focuses on the development of a digital three-dimensional hydrogeologic framework model of the Russian River watershed for use in groundwater resource assessment and numerical models. The digital three-dimensional hydrogeologic framework model of the Russian River watershed portrays the altitude, thickness, and extent of five hydrogeologic units. These five hydrogeologic units include (1) a basement unit, (2) the Sonoma Volcanics, (3) a consolidated sedimentary rock unit, (4) an unconsolidated sediment unit, and (5) channel alluvium. Model input data were compiled from published geologic maps, interpreted well data, and a model of the top of basement derived from gravity data. These data were used to construct surfaces that represent the upper and lower subsurface boundaries of each hydrogeologic unit. Top surfaces were created for the five hydrogeologic units and then stacked in three dimensions to create a solid-volume digital model. The digital three-dimensional hydrogeologic framework model described in this report and the corresponding data represent the generalized geometry of the subsurface geologic units; the model reproduces the input geologic data with reasonable accuracy and is consistent with previously published subsurface conceptualizations of the region. The model indicates the overall geometry of the basement within the watershed and the spatial extent, altitude, and thickness of the basin-filling units. The hydrogeologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

California