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Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters

Uncertainty in ground-motion-to-intensity conversions significantly affects earthquake early warning alert regions

We examine how the choice of ground‐motion‐to‐intensity conversion equations (GMICEs) in earthquake early warning (EEW) systems affects resulting alert regions. We find that existing GMICEs can underestimate observed shaking at short rupture distances or overestimate the extent of low‐intensity shaking. Updated GMICEs that remove these biases would improve the accuracy of alert regions for the ShakeAlert EEW system for the West Coast of the United States. ShakeAlert uses ground‐motion prediction equations (GMPEs), which calculate spatial distributions of peak ground acceleration (PGA) and peak ground velocity (PGV) from earthquake source estimates, combined with GMICEs to translate GMPE output into modified Mercalli intensity (MMI). We find significant epistemic uncertainty in alert distances; near‐source MMI estimates from different GMICEs can differ by over 1 MMI unit, and MMI extents used for public EEW alerts can differ by hundreds of kilometers for larger magnitude earthquakes ( M ∼6.5+). We use a catalog of “Did You Feel It?” shaking reports to evaluate how well GMICEs predict observed shaking. Our preferred GMICE is the one that computes MMI using PGV for high intensities and transitions to using PGA for nondamaging intensities. These results motivate updating GMICE relationships more generally, including in ShakeMap applications.

The Seismic Record

Digitizer Suite: The Albuquerque Seismological Laboratory Digitizer Testing Suite

Laboratory testing of digitizers and seismometers helps ensure that prior to deployment the instrumentation can produce high quality data and is operating within specifications. In this work we detail the software package called: the Albuquerque Seismological Laboratory (ASL) Digitizer Test Suite. This Java software package provides several algorithms to verify various performance parameters of digitizers commonly used for recording analog seismic instruments. The goal of these tests is not to be exhaustive, but to identify common failures that could compromise the integrity of seismic data being recorded on the digitizer. For example, Sandia National Laboratories (e.g., Slad and Merchant, 2018) routinely do comprehensive testing of digitizers for various monitoring missions. While these tests reports are valuable for comprehensively characterizing a recording system, it would be resource intensive to conduct such tests on every seismic recorder used in a network. We focus on tests that include ways to estimate the sensitivity, timing, self-noise, and clip-level of the digitizer, as well as the fidelity of the signal being recorded. The software is publicly available and provides a way for the community to verify the integrity of a digitizer using a minimum amount of outside equipment.

Seismological Research Letters

Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis

Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.

Michigan, Wisconsin

Mesoproterozoic to Paleozoic tectonics, Pleistocene landforms, and Holocene seismicity in the Blue Ridge: Results from integrated studies of the 9 August 2020, Mw 5.1 earthquake area near Sparta, North Carolina, USA

This field trip examines the results of integrated geologic studies of the 9 August 2020, M w 5.1 earthquake near Sparta, North Carolina, USA. The earthquake generated ~4 km of coseismic surface rupture of the Little River fault and uplifted a surface area of ~11 km 2 . The Little River fault is a thrust fault oriented 110–130°/45–70°SW, and mapped fault segments are en echelon with scarp heights from <5–30 cm. The epicenter is in polydeformed rocks of the Ashe and Alligator Back Metamorphic Suites in the eastern Blue Ridge. Bedrock structure formed during multiple Paleozoic orogenies; the regional foliation strikes NE-SW and dips SE (mean orientation 063°/52°SE). Mapping identified late Paleozoic veins and shear zones, a regional joint set striking 330–340° and 250–240°, and brittle faults that cut the Paleozoic foliation. Brittle faults oriented similar to the Little River fault are mapped up to 4 km along strike from the coseismic rupture along Bledsoe Creek valley, and the combined length of the Little River fault system is ~8 km. Paleoseismic trenches across the Little River fault corroborate the reactivation of an older fault by the 2020 earthquake and reveal two events during late Pleistocene (<50 ka). Surficial mapping identified several terrace deposits, including a deposit along Bledsoe Creek that yielded a 26 Al/ 10 Be isochron burial age of 0.46 ± 0.13 Ma and overlies a brittle fault, thus constraining the timing of movement of the fault at that location. Paleoliquefaction studies document soft-sediment deformation features in alluvium that may represent paleoseismic events. Collectively, these results highlight long-lived paleoseismicity of the Blue Ridge and that the 9 August 2020 earthquake reactivated an older, suitably oriented brittle fault in the bedrock. The Little River fault is an example of a previously unknown but active fault lying outside of known seismic zones with demonstrated recurrence of paleo-ruptures, raising questions about the assumption that damaging earthquakes are limited to areas of ongoing background seismicity, which is counter to seismic hazard assessments in the eastern United States. Bedrock mapping separates eastern Blue Ridge lithostratigraphy of the Lynchburg Group and Ashe and Alligator Back Metamorphic Suites into separate fault-bound packages juxtaposed over various 1.3–1.0 Ga basement rocks of the northern French Broad massif by the Gossan Lead fault.

North Carolina

Tectonic implications of transitional melting regimes from petrological, geochronological, and compositional characterization of the ophiolitic Seventymile terrane, Alaska, USA

New geochemical, U-Pb geochronology, and Sr-Nd-Hf isotope data provide evidence for the tectonic evolution of the Seventymile terrane in interior Alaska, USA. Ultramafic and mafic rocks of the Seventymile terrane are thought to represent components of a dismembered ophiolite and provide unique constraints on regional terrane evolution and accretion. The Seventymile ophiolite represents fragments of the Devonian to Permian Slide Mountain Ocean (SMO) that separated allochthonous and parautochthonous continental fragments of western North America. It now occurs as multiple thrust sheets containing Permian mafic and ultramafic rocks overlying and/or possibly imbricated with amphibolite-facies supracrustal rocks of allochthonous Yukon-Tanana terrane and parautochthonous North America. Seventymile klippen contain variably serpentinized peridotite, primarily harzburgite, low-grade meta-mafic rocks, and minor oceanic sedimentary rocks (argillite, chert, limestone, and metasandstone). Mafic rocks include gabbro to diabase, typically as dikes, veinlets, or rare massive stocks intruding peridotite. Mafic rocks also include greenstones of the Seventymile assemblage in klippen structurally underlying, and in shear zone contact with, ultramafic klippen. New trace element and radiogenic isotope data from mafic magmatic rocks associated with the Seventymile ultramafic bodies show evidence for a weakly subduction-modified mantle source, like the mantle source of normal mid-ocean-ridge basalt (N-MORB) or back-arc basin basalt (BABB). Seventymile assemblage greenstones are more heterogeneous. They range from N-MORB to enriched mid-ocean-ridge basalt (E-MORB) and ocean-island basalt (OIB), with a subset of samples indicative of continental arc affinity. These geochemistry results indicate that distinct tectonic environments are represented by at least two, and possibly three, lithological and structural units comprising the Seventymile terrane. Hf-Nd isotope systematics are consistent with a depleted MORB mantle (DMM)−like component that overlaps with Pacific MORB. Primary zircon is rare, but new in situ U-Pb data for gabbro and greenstone indicate ca. 274−272 Ma peak zircon and titanite crystallization. Scattered younger zircons define a ca. 255 Ma zircon peak and correspond to secondary crystallization associated with baddeleyite reaction of high-Si fluids during low-grade metamorphism. If Seventymile suites are contemporaneous, obduction associated with the closure of the SMO resulted in the stacking of ophiolitic packages representing distinct tectonomagmatic settings across the transition from pericontinental, to epicontinental, to distal ocean back-arc. Intrusions hosted in klippe of ultramafic rocks, plus the least subduction-modified greenstones underlying them, geologically and compositionally resemble Slide Mountain rocks of the Campbell Range formation in eastern Yukon and may provide a new piercing point across the Tintina fault.

Alaska, British Columbia

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, situated in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the impact of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study we constructed the Strawberry Creek integrated hydrological model (SCIHM) to increase this understanding. The SCIHM is an integrated surface runoff and groundwater model that uses the coupled groundwater and surface-water flow model (GSFLOW), which is based on the integration of the precipitation-runoff modeling system (PRMS) and the modular groundwater flow model commonly called MODFLOW, version MODFLOW-2005 software to simulate surface runoff and infiltration and groundwater flow. The model has three layers, 263 rows, and 176 columns. The model area includes the Strawberry Creek and four adjacent watersheds. The PRMS model was calibrated using two streamflow gaging stations and the GSFLOW model was calibrated to reported spring diversion discharge and a sparse number of groundwater-level measurements. The SCIHM was run with and without diversions active and simulated streamflow was compared, finding that in the headwaters of Strawberry Creek about 35 percent of the diversion flow was captured from base flow.

EarthArXiv

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

Florida

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology

A conceptual framework to assess post-wildfire water quality: State of the science and knowledge gaps

Wildfire substantially alters aquatic ecosystems by inducing moderate to catastrophic physical and chemical changes. However, the relations of environmental and watershed variables that drive those effects are complex. We present a Driver-Factor-Stressor-Effect (DFSE) conceptual framework to assess the current state of the science related to post-wildfire water-quality. We reviewed 64 peer-reviewed papers using the DFSE framework to identify drivers, factors, stressors, and effects associated with each study. A total of five drivers were identified and ranked according to their frequency of occurrence in the literature: atmospheric processes > fire characteristics > ecologic processes and characteristics > land surface characteristics > soil characteristics. Commonly reported stressors include increased nutrients, runoff, and sediment transport. Furthermore, although several different factors have been used at least once to explain water-quality effects, relatively few factors outside of precipitation and fire characteristics are frequently studied. We identified several gaps indicating the need for long-term monitoring, multi-factor studies, consideration of organic contaminants, consideration of groundwater, and inclusion of soil characteristics. This assessment expands on other reviews and meta-analyses by exploring causal linkages between influential variables and overall effects in post-wildfire watersheds. Information gathered from our assessment and the framework itself can be used to inform future monitoring plans and as a guide for modeling efforts focused on better understanding specific processes or to mitigate potential risks of post-wildfire water quality.

Water Resources Research

Forecast, monitor, adapt: A multi-agency strategy to protect people from postfire debris flows

In 2020, a wildfire burned across Glenwood Canyon in Colorado, USA. A history of postfire debris flows in the region and a hazard assessment for the burn area indicated that potentially life-threatening debris flows could be triggered by rainfall within months of a wildfire. As a result, four government agencies evaluated strategies to help mitigate hazards, including the loss of human life, that may be associated with debris-flow events. After the fire, 26 large debris flows occurred in the summer of 2021 and three sediment-laden flows occurred in the summer of 2023, but there were no major injuries or fatalities reported. We found that integrating hazard assessment/ forecasting, monitoring, and adaptation scenarios was a successful strategy for reducing postfire debris-flow risks to human life (including injuries and fatalities). Weather forecasts and estimates of debris-flow triggering rainfall thresholds, likelihood, and volume were used to anticipate the timing, location, and magnitude of debris-flow events. Rainfall monitoring and detailed recordkeeping of storms that triggered debris flows were used to validate and update debris-flow warning thresholds that varied with time following the wildfire. Although the governmental agencies working in this burn area had distinct and differing agency mandates, they were able to integrate information to reduce the risk of debris-flow events to human life.

Colorado

Limited preservation of strike-slip surface displacement in the geomorphic record

Offset geomorphic markers are commonly used to interpret slip history of strike-slip faults and have played an important role in forming earthquake recurrence models. These data sets are typically analyzed using cumulative probability methods to interpret average amounts of slip in past earthquakes. However, interpretation of the geomorphic record to infer surface slip history is complicated by slip variability, measurement uncertainty, and modification of offset features in the landscape. To investigate how well geomorphic data record surface slip, we use offset measurements from recent strike-slip surface ruptures ( n = 39), faults with geomorphic evidence of multiple strike-slip earthquakes ( n = 29), and synthetic slip distributions with added noise ( n > 10,000) to examine the constraints of the geomorphic record and the underlying assumptions of the cumulative offset probability distribution analysis method. We find that the geomorphic record is unlikely to resolve more than two paleo-slip distributions, except in specific cases with low slip variability, high slip-per-event, and semiarid climate. In cases where site-specific conditions allow for interpretation of more than two earthquakes, lateral extrapolation along a fault is not straightforward because on-fault displacement and distributed deformation may be spatially variable in each earthquake. We also find that average slip in modern earthquakes is adequately recovered by probability methods, but the reported prevalence of strike-slip faults with characteristic slip history is not supported by geomorphic data. We also propose updated methods to interpret slip history and construct uncertainty bounds for paleo-slip distributions.

Journal of Geophysical Research: Solid Earth

False positives in the identification of dynamic earthquake triggering

Dynamic earthquake triggering is commonly identified through the temporal correlation between increased seismicity rates and global earthquakes that are possible triggering events. However, correlation does not imply causation. False positives may occur when unrelated seismicity rate changes coincidently occur at around the time of candidate triggers. We investigate the expected false positive rate in Southern California with global M ≥ 6 earthquakes as candidate triggers. We compute the false positive rate by applying the statistical tests used by DeSalvio and Fan (2023), https://doi.org/10.1029/2023jb026487 to synthetic earthquake catalogs with no real dynamic triggering. We find a false positive rate of ∼3.5%–8.5% when realistic earthquake clustering is present, consistent with the 95% confidence typically used in seismology. However, when this false positive rate is applied to the tens of thousands of spatial-temporal windows in Southern California tested in DeSalvio and Fan (2023), https://doi.org/10.1029/2023jb026487 , thousands of false positives are expected. The expected false positive occurrence is large enough to explain the observed apparent triggering following 70% of large global earthquakes (DeSalvio & Fan, 2023, https://doi.org/10.1029/2023jb026487 ), without requiring any true dynamic triggering. Aside from the known triggering from the nearby El Mayor-Cucapah, Mexico, earthquake, the spatial and temporal characteristics of the reported triggering are indistinguishable from random false positives. This implies that best practice for dynamic triggering studies that depend on temporal correlation is to estimate the false positive rate and investigate whether the observed apparent triggering is distinguishable from the correlations that may occur by chance.

JGR Solid Earth

Magnitude conversion relations create substantial differences in seismic hazard models

Earthquake catalogs are essential data inputs for seismic hazard modeling. Because earthquake magnitudes are reported in a variety of types (e.g., local magnitudes and moment magnitudes), magnitude conversion relationships must be used to convert the different magnitude types present in a catalog to a uniform magnitude type to avoid biases in the hazard computation. However, these conversion relationships are often uncertain and have been shown to sometimes perform poorly. Here, we investigate the sensitivity of the gridded seismicity component of the National Seismic Hazard Model (NSHM) to the catalog conversion equations in the Eastern United States. In the 2023 NSHM, magnitudes of various types were converted to moment magnitudes using equations developed by the Central and Eastern United States Seismic Source Characterization for Nuclear Facilities (CEUS‐SSCn), based on least‐squares (LS) regressions made using data from a catalog containing events up through 2008. We recompute these equations using events in the Advanced National Seismic System Comprehensive Earthquake Catalog with multiple magnitudes from 2000 to 2023. Although we prefer the use of orthogonal regressions for our datasets, LS regressions produce broadly similar results, with both approaches exhibiting large deviations from the CEUS‐SSCn conversions, especially at smaller magnitudes. We compare the spatial distribution of annual rates using three different models: (1) the 2023 NSHM conversions, (2) our updated conversions, and (3) no conversions. We find that the choice of conversions leads to substantial differences in the rate forecasts, which can greatly impact the seismic hazard model, particularly in regions with low‐seismicity rates such as the Eastern United States, where the hazard is dominated by gridded seismicity rather than a fault model.

Seismological Research Letters

Long-term communication of aftershock forecasts: The Canterbury earthquake sequence in New Zealand

On 14 February 2016, a magnitude (M)5.7 earthquake struck in Christchurch New Zealand (Aotearoa in the Maori language). The shaking caused damage to historic facades, power outages, cliff collapses, rock falls, and liquefaction but no reported injuries or fatalities. This Valentine’s Day earthquake was an aftershock in the Canterbury earthquake sequence (CES), which began on 4 September 2010 with the M7.1 Darfield Earthquake and included the destructive and fatal M6.2 Christchurch aftershock on 22 February 2011. This study, eight months after the Valentine’s Day earthquake and six years after the initiation of the CES, is the first to explore long-term aftershock forecast information and communication needs. The exploratory study also aimed to gather feedback on aftershock scenarios, an alternative form for communicating the forecast. The qualitative study involved workshops with emergency managers, public health officials, and members of the public in Christchurch. Key findings for long-term communication throughout an earthquake sequence include: 1. divergent earthquake experiences affect aftershock communication response and information needs; 2. understanding aftershock sequence behavior is foundational to sense-making when large aftershocks occur; 3. strategic earthquake sequence updates from the trusted science agency and local agencies could serve as important reminders for earthquake preparedness; 4. communication of aftershock forecast uncertainty could aid with both the credibility of the information and living with uncertainty, and 5. inclusion of impact information and preparedness advice into aftershock forecast scenarios could provide links to actionable information. The paper derives implications for research and practice of long-term communications during an aftershock sequence.

Christchurch

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington

Patterns and drivers of cliff erosion in Big Sur, California, USA using repeat photogrammetry, 2017–2023

Seacliff erosion in steep terrain poses major risks to transportation and critical infrastructure. In Big Sur, California, USA, seacliff erosion threatens the sustainability of the central coast stretch of California State Route 1, a transportation corridor that is critical to the region's economy. Published cliff retreat rates for the region range from 1 to 40 cm yr −1 , highlighting that high-resolution, process-based studies could enhance understanding of the causes of spatial and temporal variability. We quantified cliff erosion and investigated its drivers along ∼13 km of the Big Sur coastline at week–month timescales during the late fall to early spring wet seasons between January 2017 and June 2023 by analyzing 3D point clouds developed from aerial imagery using four-dimensional structure-from-motion (4D SfM) photogrammetry techniques. We calculated cliff face retreat rates of 2.23 ± 3.06 cm yr −1 (mean ±1 σ ), an order of magnitude lower than long-term estimated rates for the region (which included large deep-seated landslides), but in line with short-term rates reported across California. Change detection imagery comparison, cliff profiles through time, and statistical analysis reveal a cyclical cliff evolution process in which erosion by wave action at the cliff base destabilizes the cliff and primes it for subsequent failure during precipitation events. Although more erosion by volume could be attributed to precipitation-induced increases in soil moisture (784 m 3 km −1 yr −1 ) compared with erosion attributed to wave power (282 m 3 km −1 yr −1 ), our observations underscore the coupled nature of these processes in driving cliff evolution, consistent with established theory and observations.

California