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At least 1,099 records · Page 61Linked to original sources

Pesticides associated with suspended sediments in the San Francisco Bay Estuary, California

During the study of inputs of sediment-associated pesticides into the San Francisco Bay Estuary, suspended sediments were isolated from large-volume water samples collected over several years at various stations in Suisun Bay and also covering the principal inputs and outlet. The samples were analyzed for 21 pesticides and pesticide degradation products to provide information about the source and fate of pesticides associated with suspended sediments in the estuary. Where multiple samples were collected and analyzed, the data were averaged to provide a more general picture of pesticide transport.

California↗

Preliminary geologic map of the Little Piute Mountains, California: A digital database

The Little Piute Mountains Digital database contains digital geologic and geographic information for the study area. The geology was mapped at a scale of 1:8,000, and the topographic information was input from the Little Piute Mountains, CA 1:24,000 quadrangle. The accuracy of the spatial information is limited to the input scale. Postscript files, originally published in paper format as Open-file map 95-598, have been included for those who do not have access to a geographic information system. The files are equivalent to those which produced the hard-copy open file. They can be printed on any device equipped to print postscript files of the appropriate file size.

California↗

Implementation of the century ecosystem model for an eroding hillslope in Mississippi

The objective of this study was to parameterize and implement the Century ecosystem model for an eroding, cultivated site near Senatobia, in Panola County, Mississippi, in order to understand the loss and replacement of soil organic carbon on an eroding cropland. The sites chosen for this study are located on highly eroded loess soils where USDA has conducted studies on rates of soil erosion. We used USDA sediment data from the study site and historical erosion estimates from the nearby area as model input for soil loss; in addition, inputs for parametization include particle-size data, climate data, and rainfall/runoff data that were collected and reported in companion papers. A cropping scenario was implemented to simulate a research site at the USDA watershed 2 at the Nelson Farm. Model output was compiled for comparison with data collected and reported in companion reports; interpretive comparisons are reported in Harden et al, in press.

Open-File Report↗

Calibration formulae and values for velocity seismometers used in the 1998 Santa Clara Valley, California seismic experiment

Eaton (1975), Bakun and Dratler (1976), Eaton (1977), Healy and O’Neil (1977), Asten (1977), Stewart and O'Neill (1980), Liu and Peselnick (1986), Eaton (1991), Rodgers et al. (1995), and many others (see Asten (1977) for a list of earlier references) have presented formulae for calculating the damped generator constant (or motor constant), and the damping constant (or fractional damping ratio) for magnetically damped velocity seismometers. Unfortunately the notation varies between authors, and not all the formulae allow for some of the significant variables -- differences in input impedance of the recording system in particular. This has become particularly relevant because the USGS seismic networks in California have traditionally set up their velocity sensors for the 10K Ohm impedance of the standard USGS analog telemetry systems (Eaton, 1977), but modern digital recording systems are usually set up with high input impedances, often of a megaohm or greater. Thus the nominal calibration values valid for USGS velocity sensors in their “normal” configuration are incorrect when they are recorded on other systems. In this short note we have collected the relevant formulae needed, and computed the seismometer responses for the various velocity sensors used in the recent Santa Clara Valley Seismic Experiment (SCVSE, see Lindh et al., 1999).

California↗

Land use and land cover information and air-quality planning

The land use and land cover information developed by the U.S. Geological Survey in the Central Atlantic Regional Ecological Test Site project has been proven useful when used in an improved technique for estimating emissions, diffusion, and impact patterns of sulfur dioxide (S02) and particulate matter. Implementation of plans to control air quality requires land use and land cover information, which, until this time, has been inadequate. The land use and land cover data were used in updating information on the sources of point and area emissions of S02 and particulate matter affecting the Norfolk-Portsmouth area of Virginia for the 1971-72 winter (Dec.-Jan.-Feb.) and the annual 1972 period, and for a future annual period-1985. This emission information is used as input to the Air Quality Display Model of the Environmental Protection Agency to obtain diffusion and impact patterns for the three periods previously mentioned. The results are: (1) During the 1971-72 winter, estimated S02 amounts over an area with southwest-northeast axis in the central section of Norfolk exceeded both primary and secondary levels, (2) future annual levels of S02, estimated by anticipated residential development and point-source changes, are not expected to cause serious deterioration of the region's present air quality, and (3) for the 1971-72 winter, and annual 1972, period the diffusion results showed that both primary and secondary standards for particulate matter are regularly exceeded in central Norfolk and Portsmouth. In addition, on the basis of current control programs, the 1985 levels of particulate matter are expected to exceed the presently established secondary air-quality standards through central Norfolk and Portsmouth and in certain areas of Virginia Beach. Land use and land cover information can be used to estimate emissions for inputs to diffusion models and to interpret the implications of diffusion patterns for: (1) Implementing various control strategies, (2) selecting sites of air sampling stations, and (3) predicting the effects that proposed changes in land use and land cover might have on emission patterns and air quality.

Professional Paper↗

An economic analysis of selected strategies for dissolved-oxygen management; Chattahoochee River, Georgia

A method for evaluating the cost-effectiveness of alternative strategies for dissolved-oxygen (DO) management is demonstrated, using the Chattahoochee River, GA., as an example. The conceptual framework for the analysis is suggested by the economic theory of production. The minimum flow of the river and the percentage of the total waste inflow receiving nitrification are considered to be two variable inputs to be used in the production of given minimum concentration of DO in the river. Each of the inputs has a cost: the loss of dependable peak hydroelectric generating capacity at Buford Dam associated with flow augmentation and the cost associated with nitrification of wastes. The least-cost combination of minimum flow and waste treatment necessary to achieve a prescribed minimum DO concentration is identified. Results of the study indicate that, in some instances, the waste-assimilation capacity of the Chattahoochee River can be substituted for increased waste treatment; the associated savings in waste-treatment costs more than offset the benefits foregone because of the loss of peak generating capacity at Buford Dam. The sensitivity of the results to the estimates of the cost of replacing peak generating capacity is examined. It is also demonstrated that a flexible approach to the management of DO in the Chattahoochee River may be much more cost effective than a more rigid, institutional approach wherein constraints are placed on the flow of the river and(or) on waste-treatment practices. (USGS)

Georgia↗

Nutrient Concentrations and Their Relations to the Biotic Integrity of Nonwadeable Rivers in Wisconsin

Excessive nutrient [phosphorus (P) and nitrogen (N)] input from point and nonpoint sources is frequently associated with degraded water quality in streams and rivers. Point-source discharges of nutrients are fairly constant and are controlled by the U.S. Environmental Protection Agency's (USEPA) National Pollutant Discharge Elimination System. To reduce inputs from nonpoint sources, agricultural performance standards and regulations for croplands and livestock operations are being proposed by various States. In addition, the USEPA is establishing regionally based nutrient criteria that can be refined by each State to determine whether actions are needed to improve water quality. More confidence in the environmental benefits of the proposed performance standards and nutrient criteria would be possible with improved understanding of the biotic responses to a range of nutrient concentrations in different environmental settings. To achieve this general goal, the U.S. Geological Survey and the Wisconsin Department of Natural Resources collected data from 282 streams and rivers throughout Wisconsin during 2001 through 2003 to: (1) describe how nutrient concentrations and biotic-community structure differ throughout the State, (2) determine which environmental characteristics are most strongly related to the distribution of nutrient concentrations and biotic-community structure, (3) determine reference conditions for water quality and biotic indices for streams and rivers in the State, (4) determine how the biotic communities in streams and rivers in different areas of the State respond to differences in nutrient concentrations, (5) determine the best regionalization scheme to describe the patterns in reference conditions and the corresponding responses in water quality and the biotic communities (primarily for smaller streams), and (6) develop algorithms to estimate nutrient concentrations in streams and rivers from a combination of biotic indices. The ultimate goal of this study is to provide the information needed to guide the development of regionally based nutrient criteria for Wisconsin streams and rivers. In this report, data collected, primarily in 2003, from 42 nonwadeable rivers are used to describe nutrient concentrations and their relations to the biotic integrity of rivers in Wisconsin. In a separate report by Robertson and others (2006a), the data collected from 240 wadeable streams are used to describe these relations in streams in Wisconsin. Reference water-quality conditions for nonwadeable rivers were found to be similar throughout Wisconsin (approximately 0.035 milligrams per liter (mg/L) for total P (TP), 0.500 mg/L for total N (TN), 4 micrograms per liter for suspended chlorophyll a (SCHL), and greater than 110 centimeters for Secchi-tube depth (SD)). For each category of the biotic community (SCHL, macroinvertebrates, and fish), a few indices were more strongly related to differences in nutrient concentrations than were others. For the indices most strongly related to nutrient concentrations, reference conditions were obtained with a regression approach, from values corresponding to the worst 75th-percentile value from a subset of minimally impacted streams (streams having reference nutrient concentrations), and from the best 25th-percentile value of all the data. Concentrations of TP and TN in nonwadeable rivers increased as the percentage of agricultural land in the basin increased; these increases resulted in increased SCHL concentrations and decreased SDs. The responses in SDs and SCHL concentrations to changes in nutrient concentrations were similar throughout most of the State except in rivers in the southeastern part, where SCHL concentrations were lower than would be expected given their nutrient concentrations. Rivers in the southeastern part of the State had high concentrations of total suspended sediment compared to the SCHL concentrations. Many biotic indices responded to increases in nu

Professional Paper↗

The Cannery Formation: Devonian to Early Permian arc-marginal deposits within the Alexander Terrane, southeastern Alaska

The Cannery Formation consists of green, red, and gray ribbon chert, siliceous siltstone, graywacke-chert turbidites, and volcaniclastic sandstone. Because it contains early Permian fossils at and near its type area in Cannery Cove, on Admiralty Island in southeastern Alaska, the formation was originally defined as a Permian stratigraphic unit. Similar rocks exposed in Windfall Harbor on Admiralty Island contain early Permian bryozoans and brachiopods, as well as Mississippian through Permian radiolarians. Black and green bedded chert with subordinate lenses of limestone, basalt, and graywacke near Kake on Kupreanof Island was initially correlated with the Cannery Formation on the basis of similar lithology but was later determined to contain Late Devonian conodonts. Permian conglomerate in Keku Strait contains chert cobbles inferred to be derived from the Cannery Formation that yielded Devonian and Mississippian radiolarians. On the basis of fossils recovered from a limestone lens near Kake and chert cobbles in the Keku Strait area, the age of the Cannery Formation was revised to Devonian and Mississippian, but this revision excludes rocks in the type locality, in addition to excluding bedded chert on Kupreanof Island east of Kake that contains radiolarians of Late Pennsylvanian and early Permian age. The black chert near Kake that yielded Late Devonian conodonts is nearly contemporaneous with black chert interbedded with limestone that also contains Late Devonian conodonts in the Saginaw Bay Formation on Kuiu Island. The chert cobbles in the conglomerate in Keku Strait may be derived from either the Cannery Formation or the Saginaw Bay Formation and need not restrict the age of the Cannery Formation, regardless of their source. The minimum age of the Cannery Formation on both Admiralty Island and Kupreanof Island is constrained by the stratigraphically overlying fossiliferous Pybus Formation, of late early and early late Permian age. Because bedded radiolarian cherts on both Admiralty and Kupreanof Islands contain radiolarians as young as Permian, the age of the Cannery Formation is herein extended to Late Devonian through early Permian, to include the early Permian rocks exposed in its type locality. The Cannery Formation is folded and faulted, and its stratigraphic thickness is unknown but inferred to be several hundred meters. The Cannery Formation represents an extended period of marine deposition in moderately deep water, with slow rates of deposition and limited clastic input during Devonian through Pennsylvanian time and increasing argillaceous, volcaniclastic, and bioclastic input during the Permian. The Cannery Formation comprises upper Paleozoic rocks in the Alexander terrane of southeastern Alaska. In the pre-Permian upper Paleozoic, the tectonic setting of the Alexander terrane consisted of two or more evolved oceanic arcs. The lower Permian section is represented by a distinctive suite of rocks in the Alexander terrane, which includes sedimentary and volcanic rocks containing early Permian fossils, metamorphosed rocks with early Permian cooling ages, and intrusive rocks with early Permian cooling ages, that form discrete northwest-trending belts. After restoration of 180 km of dextral displacement of the Chilkat-Chichagof block on the Chatham Strait Fault, these belts consist, from northeast to southwest, of (1) bedded chert, siliceous argillite, volcaniclastic turbidites, pillow basalt, and limestone of the Cannery Formation and the Porcupine Slate of Gilbert and others (1987); (2) greenschist-facies Paleozoic metasedimentary and metavolcanic rocks that have Permian cooling ages; (3) silty limestone and calcareous argillite interbedded with pillow basalt and volcaniclastic rocks of the Halleck Formation and the William Henry Bay area; and (4) intermediate-composition and syenitic plutons. These belts correspond to components of an accretionary complex, contemporary metamorphic rocks, forearc-basin deposits, and the roots of a volcanic arc, respectively. The similar early Permian sedimentary, metamorphic, and igneous ages are inferred to represent an arc complex that resulted from juxtaposition of a structural lower plate consisting of metamorphosed Paleozoic arc rocks of the Alexander terrane exposed on Admiralty Island, and a structural upper plate consisting of stratigraphically distinct, unmetamorphosed Paleozoic arc rocks representing another component of the Alexander terrane exposed on Chichagof, Kuiu, and Prince of Wales Islands. The Cannery Formation is associated with the lower-plate package. A volcanic arc with magmatic ages ranging from 293 to 278 Ma formed during subduction of the basin between these two (or more) components of the Alexander terrane in southeastern Alaska. Metamorphic-mineral-cooling ages ranging from 273 to 260 Ma are interpreted to date an early Permian orogenic event. Both the early Permian lower- and upper-plate rocks are unconformably overlain by late early and early late Permian limestone, dolostone, and conglomerate of the Pybus Formation that provide a minimum age for this collision.

Alaska↗

Weathering, landscape equilibrium, and carbon in four watersheds in eastern Puerto Rico: Chapter H in Water quality and landscape processes of four watersheds in eastern Puerto Rico

The U.S. Geological Survey's Water, Energy, and Biogeochemical Budgets (WEBB) program research in eastern Puerto Rico involves a double pair-wise comparison of four montane river basins, two on granitic bedrock and two on fine-grained volcaniclastic bedrock; for each rock type, one is forested and the other is developed. A confounding factor in this comparison is that the developed watersheds are substantially drier than the forested (runoff of 900–1,600 millimeters per year compared with 2,800–3,700 millimeters per year). To reduce the effects of contrasting runoff, the relation between annual runoff and annual constituent yield were used to estimate mean-annual yields at a common, intermediate mean-annual runoff of 1,860 millimeters per year. Upon projection to this intermediate runoff, the ranges of mean-annual yields among all watersheds became more compact or did not substantially change for dissolved bedrock, sodium, silica, chloride, dissolved organic carbon, and calcium. These constituents are the primary indicators of chemical weathering, biological activity on the landscape, and atmospheric inputs; the narrow ranges indicate little preferential influence by either geology or land cover. The projected yields of biologically active constituents (potassium, nitrate, ammonium ion, phosphate), and particulate constituents (suspended bedrock and particulate organic carbon) were considerably greater for developed landscapes compared with forested watersheds, consistent with the known effects of land clearing and human waste inputs. Equilibrium rates of combined chemical and physical weathering were estimated by using a method based on concentrations of silicon and sodium in bedrock, river-borne solids, and river-borne solutes. The observed rates of landscape denudation greatly exceed rates expected for a dynamic equilibrium, except possibly for the forested watershed on volcaniclastic rock. Deforestation and agriculture can explain the accelerated physical erosion in the two developed watersheds. Because there has been no appreciable deforestation, something else, possibly climate or forest-quality change, must explain the accelerated erosion in the forested watersheds on granitic rocks. Particulate organic carbon yields are closely linked to sediment yields. This relation implies that much of the particulate organic carbon transport in the four rivers is being caused by this enhanced erosion aided by landslides and fast carbon recovery. The increase in particulate organic carbon yields over equilibrium is estimated to range from 300 kilomoles per square kilometer per year (6 metric tons carbon per square kilometer per year) to 1,700 kilomoles per square kilometer per year (22 metric tons carbon per square kilometer per year) and is consistent with human-accelerated particulate-organic-carbon erosion and burial observed globally. There is no strong evidence of human perturbation of silicate weathering in the four study watersheds, and differences in dissolved inorganic carbon are consistent with watershed geology. Although dissolved organic carbon is slightly elevated in the developed watersheds, that elevation is not enough to unambiguously demonstrate human causes; more work is needed. Accordingly, the dissolved organic carbon and dissolved inorganic carbon yields of tropical rivers, although large, are of secondary importance in the study of the anthropgenically perturbed carbon cycle.

Professional Paper↗

Petrology and geochronology of 1.48 to 1.45 Ga igneous rocks in the St. Francois Mountains terrane, southeast Missouri

The igneous geology of the St. Francois Mountains terrane in southeast Missouri is dominated by the products of 1.48 to 1.45 billion year old volcanic and plutonic magmatism but also includes volumetrically minor, compositionally bimodal contributions added during plutonism between 1.34 and 1.27 billion years ago. The 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane are bimodally distributed between volumetrically dominant felsic rocks and volumetrically minor rocks with mafic to intermediate compositions. All of these rocks are ferroan, which like most of their trace element abundances, suggests a genesis associated with farfield intraplate extensional tectonism and decompression-related magmatism. The diversity of compositions among 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane probably reflects mixtures of mantle-derived mafic inputs and low-degree partial melting of more evolved crustal protoliths. Newly determined ages define essentially continuous magmatism during the 30-million-year period between 1.48 and 1.45 billion years ago. The products of this magmatism are essentially coeval, whether intrusive or extrusive or having mafic, intermediate, or felsic compositions. In addition, the iron oxide-apatite (for example, Pea Ridge) and likely the iron oxide-copper gold (Boss) deposits in the St. Francois Mountains terrane have ages coincident with this magmatic episode. Spatial and temporal relations between 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane and the mineral deposits they host suggest the associated magmatic and mineralization processes are also genetically related. Geochemical, petrographic, geochronologic, and terrane-wide physical characteristics of the 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane are consistent with an origin involving extension well inboard from the margin of the Laurentian craton, associated mantle upwelling, lower crustal melting in response to mantle-derived thermal inputs, and mixing of mantle- and juvenile lower crustal-derived melts. Significant major and trace element compositional dispersion characteristics of these rocks likely reflect midcrustal magma reservoir fractionation of their principal rock-forming minerals. The resultant magmas constitute a series of variably hybridized reservoirs, emplaced at upper levels in the crust, that form a series of plutonic and associated eruptive products.

Missouri↗

Terrestrial Ecosystems - Topographic Moisture Potential of the Conterminous United States

As part of an effort to map terrestrial ecosystems, the U.S. Geological Survey has generated topographic moisture potential classes to be used in creating maps depicting standardized, terrestrial ecosystem models for the conterminous United States, using an ecosystems classification developed by NatureServe. A biophysical stratification approach, developed for South America and now being implemented globally, was used to model the ecosystem distributions. Substrate moisture regimes strongly influence the differentiation and distribution of terrestrial ecosystems, and therefore topographic moisture potential is one of the key input layers in this biophysical stratification. The method used to produce these topographic moisture potential classes was based on the derivation of ground moisture potential using a combination of computed topographic characteristics (CTI, slope, and aspect) and mapped National Wetland Inventory (NWI) boundaries. This method does not use climate or soil attributes to calculate relative topographic moisture potential since these characteristics are incorporated into the ecosystem model though other input layers. All of the topographic data used for this assessment were derived from the USGS 30-meter National Elevation Dataset (NED ) including the National Compound Topographic Index (CTI). The CTI index is a topographically derived measure of slope for a raster cell and the contributing area from upstream raster cells, and thus expresses potential for water flow to a point. In other words CTI data are 'a quantification of the position of a site in the local landscape', where the lowest values indicate ridges and the highest values indicate stream channels, lakes and ponds. These CTI values were compared to independent estimates of water accumulation by obtaining geospatial data from a number of sample locations representing two types of NWI boundaries: freshwater emergent wetlands and freshwater forested/shrub wetlands. Where these shorelines (the interface between the NWI wetlands and adjacent land) occurred, the CTI values were extracted and a histogram of their statistical distributions was calculated. Based on an evaluation of these histograms, CTI thresholds were developed to separate periodically saturated or flooded land, mesic uplands (moderately moist), and uplands. After the range of CTI values for these three different substrate moisture regimes was determined, the CTI values were grouped into three initial topographic moisture potential classes. As a final step in the generation of this national data layer, the uplands classification was subdivided into either very dry uplands or dry uplands. Very dry uplands were defined as uplands with relatively steep, south-facing slopes, and identification of this class was based on the slope and aspect datasets derived from the NED. The remaining uplands that did not meet these additional criteria were simply re-classified as dry uplands. The final National Topographic Moisture Potential dataset for the conterminous United States contains four classes: periodically saturated or flooded land (CTI = 18.5), mesic uplands (12 =< CTI < 18.5), dry uplands (CTI < 12), and very dry uplands (CTI < 12, Slope > 24 degrees and 91 degrees =< Aspect =< 314 degrees). This map shows a smoothed and generalized image of the four topographic moisture potential classes. Additional information about this map and any of the data developed for the ecosystems modeling of the conterminous United States is available online at http://rmgsc.cr.usgs.gov/ecosystems/.

Scientific Investigations Map↗

Hydrogeology, water quality, and ecology of Anderton Branch near the Quail Hollow Landfill, Bedford County, Tennessee, 1995-99

The Quail Hollow Landfill, located in southeastern Bedford County on the Highland Rim overlooking the Central Basin karst region of Tennessee, is constructed on the gravelly, clay-rich residuum of the Fort Payne Formation of Mississippian age. A conceptual hydrologic model of the landfill indicated that Anderton Branch was at risk of being affected by the landfill. Ground water flowing beneath the landfill mixes with percolating rainwater that has passed through the landfill and discharges to the surface from numerous weeps, seeps, and springs present in the area. Anderton Branch, adjacent to the landfill site on the north and east, receives most of the discharge from these weeps, seeps, and springs. Anderton Branch also receives water from the Powell Branch drainage basin to the west and south because of diverted flow of ground water through Harrison Spring Cave. The U.S. Geological Survey, in cooperation with the Bedford County Solid Waste Authority, conducted a study to evaluate the effect of the Quail Hollow Landfill on ground- and surface-water quality. During storm runoff, specific conductance was elevated, and cadmium, iron, manganese, lead, and nickel concentrations in Anderton Branch frequently exceeded maximum contaminant levels for drinking water for the State of Tennessee. High chloride inputs to Anderton Branch were detected at two locations?a barnyard straddling the stream and a tributary draining a pond that receives water directly from the landfill. The chloride inputs probably contribute to chloride load levels that are three times higher for Anderton Branch than for the control stream Anthony Branch. Although toxic volatile organic compounds were detected in water from monitoring wells at the landfill, no organic contaminants were detected in domestic water wells adjacent to the landfill or in Anderton Branch. Sons Spring, a karst spring near the landfill, has been affected by the landfill as indicated by an increase in chloride concentrations from 4 milligrams per liter in 1974 to 59 milligrams per liter in 1996. Analysis of water samples from Sons Spring detected concentrations of nickel that exceeded primary drinking-water standards and Tennessee Department of Environment and Conservation fish and aquatic life chronic standards. Trichloroethene, 1,1-dichloroethene, and 1,1-dichloroethane also were detected at Sons Spring. The presence of these chlorinated solvents imply the landfill origin of the contaminants in Sons Spring. Continuous monitoring at Sons Spring indicated a pattern of decreased specific conductance and lower contaminant concentrations after a storm. Contaminant concentrations increased with specific conductance to pre-storm levels after several days. The benthic macroinvertebrate community in Anderton Branch adjacent to the landfill was not different from the communities at control sites upstream and in Anthony Branch. Sons Spring, however, has low abundance and numbers of benthic macroinvertebrate taxa. Toxicity studies using Ceriodaphnia dubia indicated no toxicity in the base flow or storm water in Anderton Branch or in a tributary draining a pond that receives water from the landfill and Sons Spring; however, water collected from Sons Spring resulted in 100 percent mortality to all organisms within 48 hours. High concentrations of nickel were detected in crayfish tissue from control sites and Anderton Branch. Analysis of sediment samples also indicates nickel concentrations are high at control sites upstream of the landfill. Increased levels of the biomarker metallothionein detected in crayfish from Anderton Branch likely are not caused by nickel or cadmium because the levels present in the tissue are not correlated with metallothionein levels. Despite the high levels of certain metals in Anderton Branch during storm flow, the lack of toxicity and the health of the benthic community imply no detectable negative effect from the landfill to the stream. Sons Spring, howe

Scientific Investigations Report↗

Chloroform in the hydrologic system--sources, transport, fate, occurrence, and effects on human health and aquatic organisms

Chloroform is one of the volatile organic compounds (VOCs) detected most frequently in both ground and surface water. Because it is also one of the four trihalomethanes (THMs) produced in the highest concentrations during the chlorination of drinking water and wastewater, the frequent detection of this compound in ground and surface water of the United States is presumed to be caused primarily by the input of chlorinated water to the hydrologic system. Although anthropogenic sources of the compound are substantial, they are currently estimated to constitute only 10 percent of the total global input to the hydrologic system. Natural sources of the compound include volcanic gases, biomass burning, marine algae, and soil microorganisms. Under most conditions (except in the presence of unusually high bromide concentrations), chloroform is the THM produced in the highest concentrations during chlorination. Furthermore, in most cases where more than one THM is produced from chlorination, the relative concentrations among the different compounds usually decrease with increasing bromination (chloroform > dichlorobromomethane > chlorodibromomethane > bromoform). This phenomenon is presumed to be responsible for the common observation that when more than one THM is detected during investigations of the occurrence of these compounds in the hydrologic system, this same trend is typically observed among their relative concentrations or, for a uniform reporting limit, their relative frequencies of detection. This pattern could provide a valuable means for distinguishing between chlorinated water and other potential sources of chloroform in the environment. Chloroform has been widely detected in national, regional, and local studies of VOCs in ground, surface, source, and drinking waters. Total THM (TTHM) concentrations of the compound, however, were typically less than the Maximum Contaminant Level (MCL) of 80 ?g/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA) for TTHMs. In the studies that compared land-use settings, frequencies of detection of chloroform were higher beneath urban and residential areas than beneath agricultural or undeveloped areas. Because chloroform is a suspected human carcinogen, its presence in drinking water is a potential human health concern. Liver damage, however, is known to occur at chloroform exposures lower than those required to cause cancer, an observation that has been considered by the USEPA as the basis for setting a new, non-zero Maximum Contaminant Level Goal of 70 ?g/L for the compound. As part of its National Water-Quality Assessment Program, the U.S. Geological Survey has been assembling and analyzing data on the occurrence of VOCs (including chloroform) in ground and surface water on a national scale from studies conducted between 1991 and the present. This report presents a summary of current (2004) information on the uses, sources, formation, transport, fate, and occurrence of chloroform, as well as its effects on human health and aquatic organisms.

Scientific Investigations Report↗

Simulation of ground-water flow in glaciofluvial aquifers in the Grand Rapids area, Minnesota

A calibrated steady-state, finite-difference, ground-waterflow model was constructed to simulate ground-water flow in three glaciofluvial aquifers, defined in this report as the upper, middle, and lower aquifers, in an area of about 114 mi2 surrounding the city of Grand Rapids in north-central Minnesota. The calibrated model will be used by Minnesota Department of Health and communities in the Grand Rapids area in the development of wellhead protection plans for their water supplies. The model was calibrated through comparison of simulated ground-water levels to measured static water levels in 351 wells, and comparison of simulated base-flow rates to estimated base-flow rates for reaches of the Mississippi and Prairie Rivers. Model statistics indicate that the model tends to overestimate ground-water levels. The root mean square errors ranged from +12.83 ft in wells completed in the upper aquifer to +19.10 ft in wells completed in the middle aquifer. Mean absolute differences between simulated and measured water levels ranged from +4.43 ft for wells completed in the upper aquifer to +9.25 ft for wells completed in the middle aquifer. Mean algebraic differences ranged from +9.35 ft for wells completed in the upper aquifer to +14.44 ft for wells completed in the middle aquifer, with the positive differences indicating that the simulated water levels were higher than the measured water levels. Percentage errors between simulated and estimated base-flow rates for the three monitored reaches all were less than 10 percent, indicating good agreement. Simulated ground-water levels were most sensitive to changes in general-head boundary conductance, indicating that this characteristic is the predominant model input variable controlling steady-state water-level conditions. Simulated groundwater flow to stream reaches was most sensitive to changes in horizontal hydraulic conductivity, indicating that this characteristic is the predominant model input variable controlling steady-state flow conditions.

Minnesota↗

Sources of phosphorus to the Carson River upstream from Lahontan Reservoir, Nevada and California, Water Years 2001-02

Discharge of treated municipal-sewage effluent to the Carson River in western Nevada and eastern California ceased by 1987 and resulted in a substantial decrease in phosphorus concentrations in the Carson River. Nonetheless, concentrations of total phosphorus and suspended sediment still commonly exceed beneficial-use criteria established for the Carson River by the Nevada Division of Environmental Protection. Potential sources of phosphorus in the study area include natural inputs from undisturbed soils, erosion of soils and streambanks, construction of low-head dams and their destruction during floods, manure production and grazing by cattle along streambanks, drainage from fields irrigated with streamwater and treated municipal-sewage effluent, ground-water seepage, and urban runoff including inputs from golf courses. In 2000, the U.S. Geological Survey (USGS), in cooperation with Carson Water Subconservancy District, began an investigation with the overall purpose of providing managers and regulators with information necessary to develop and implement total maximum daily loads for the Carson River. Two specific goals of the investigation were (1) to identify those reaches of the Carson River upstream from Lahontan Reservoir where the greatest increases in phosphorus and suspended-sediment concentrations and loading occur, and (2) to identify the most important sources of phosphorus within the reaches of the Carson River where the greatest increases in concentration and loading occur. Total-phosphorus concentrations in surface-water samples collected by USGS in the study area during water years 2001-02 ranged from <0.01 to 1.78 mg/L and dissolved-orthophosphate concentrations ranged from <0.01 to 1.81 mg/L as phosphorus. In streamflow entering Carson Valley from headwater areas in the East Fork Carson River, the majority of samples exceeding the total phosphorus water-quality standard of 0.1 mg/L occur during spring runoff (March, April, and May) when suspended-sediment concentrations are high. Downstream from Carson Valley, almost all samples exceed the water-quality standard, with the greatest concentrations observed during spring and summer months. Estimated annual total-phosphorus loads ranged from 1.33 tons at the West Fork Carson River at Woodfords to 43.41 tons at the Carson River near Carson City during water years 2001-02. Loads are greatest during spring runoff, followed by fall and winter, and least during the summer, which corresponds to the amount of streamflow in the Carson River. The estimated average annual phosphorus load entering Carson Valley was 21.9 tons; whereas, the estimated average annual phosphorus load leaving Carson Valley was 37.8 tons, for an annual gain in load across Carson Valley of 15.9 tons. Thus, about 58 percent of the total-phosphorus load leaving Carson Valley on an annual basis could be attributed to headwater reaches upstream from Carson Valley. During spring and summer (April 1-September 30) an average of 85 percent of the total-phosphorus load leaving Carson Valley could be attributed to headwater reaches. During fall and winter (October 1-March 31) only 17 percent of the phosphorus load leaving Carson Valley could be attributed to headwater reaches. The composition of the phosphorus changes during summer from particulate phosphorus entering Carson Valley to dissolved orthophosphate leaving Carson Valley. Particulate phosphorus entering Carson Valley could be settling out when water is applied to fields and be replaced by dissolved orthophosphate from other sources. Alternatively, the particulate phosphorus could be converted to dissolved orthophosphate as it travels across Carson Valley. Data collected during the study are not sufficient to distinguish between the two possibilities. Eagle Valley and Dayton-Churchill Valleys may act as sinks for phosphorus. On an annual basis, during water years 2001-02, about 90 percent of the phosphorus entering Eagle Valley left the

Scientific Investigations Report↗

Precipitation-runoff processes in the Feather River basin, northeastern California, and streamflow predictability, water years 1971-97

Precipitation-runoff processes in the Feather River Basin of northern California determine short- and long-term streamflow variations that are of considerable local, State, and Federal concern. The river is an important source of water and power for the region. The basin forms the headwaters of the California State Water Project. Lake Oroville, at the outlet of the basin, plays an important role in flood management, water quality, and the health of fisheries as far downstream as the Sacramento-San Joaquin Delta. Existing models of the river simulate streamflow in hourly, daily, weekly, and seasonal time steps, but cannot adequately describe responses to climate and land-use variations in the basin. New spatially detailed precipitation-runoff models of the basin have been developed to simulate responses to climate and land-use variations at a higher spatial resolution than was available previously. This report characterizes daily rainfall, snowpack evolution, runoff, water and energy balances, and streamflow variations from, and within, the basin above Lake Oroville. The new model's ability to predict streamflow is assessed. The Feather River Basin sits astride geologic, topographic, and climatic divides that establish a hydrologic character that is relatively unusual among the basins of the Sierra Nevada. It straddles a north-south geologic transition in the Sierra Nevada between the granitic bedrock that underlies and forms most of the central and southern Sierra Nevada and volcanic bedrock that underlies the northernmost parts of the range (and basin). Because volcanic bedrock generally is more permeable than granitic, the northern, volcanic parts of the basin contribute larger fractions of ground-water flow to streams than do the southern, granitic parts of the basin. The Sierra Nevada topographic divide forms a high altitude ridgeline running northwest to southeast through the middle of the basin. The topography east of this ridgeline is more like the rain-shadowed basins of the northeastern Sierra Nevada than the uplands of most western Sierra Nevada river basins. The climate is mediterranean, with most of the annual precipitation occurring in winter. Because the basin includes large areas that are near the average snowline, rainfall and rain-snow mixtures are common during winter storms. Consequently, the overall timing and rates of runoff from the basin are highly sensitive to winter temperature fluctuations. The models were developed to simulate runoff-generating processes in eight drainages of the Feather River Basin. Together, these models simulate streamflow from 98 percent of the basin above Lake Oroville. The models simulate daily water and heat balances, snowpack evolution and snowmelt, evaporation and transpiration, subsurface water storage and outflows, and streamflow to key streamflow gage sites. The drainages are modeled as 324 hydrologic-response units, each of which is assumed homogeneous in physical characteristics and response to precipitation and runoff. The models were calibrated with emphasis on reproducing monthly streamflow rates, and model simulations were compared to the total natural inflows into Lake Oroville as reconstructed by the California Department of Water Resources for April-July snowmelt seasons from 1971 to 1997. The models are most sensitive to input values and patterns of precipitation and soil characteristics. The input precipitation values were allowed to vary on a daily basis to reflect available observations by making daily transformations to an existing map of long-term mean monthly precipitation rates that account for altitude and rain-shadow effects. The models effectively simulate streamflow into Lake Oroville during water years (October through September) 1971-97, which is demonstrated in hydrographs and statistical results presented in this report.

Northeastern California↗

Changes in streamflow and water quality in selected nontidal sites in the Chesapeake Bay Basin, 1985-2003

Water-quality and streamflow data from 33 sites in nontidal portions of the Chesapeake Bay Basin were analyzed to document annual nutrient and sediment loads and trends for 1985 through 2003 as part of an annual evaluation of water-quality conditions by the Chesapeake Bay Program. As part of this study, different trend tests and methodologies were evaluated for future use in assessment of the effectiveness of management actions in reducing nutrients and sediments to the Chesapeake Bay. Trends in streamflow were tested at multiple time scales (daily, monthly, seasonal, and annual), resulting in only one significant trend (annual flow for Choptank River near Greensboro, Md.). Data summaries for observed concentrations indicate higher ranges in total-nitrogen concentrations in the northern five major river basins in Pennsylvania, Maryland, and Virginia compared to the southern five basins in Virginia. Similar comparisons showed no distinct differences for total phosphorus. Flow-weighted concentration is useful in evaluating changes through time for the Susquehanna, Potomac, and James Rivers. Results indicate the Potomac River had the highest flow-weighted concentrations (2.5 milligrams per liter) for total nitrogen, and the Potomac and James Rivers averaged about the same (0.15 milligram per liter) for total-phosphorus concentrations. Flow-weighted concentrations were lowest in the Susquehanna River for phosphorus and sediment because of the trapping efficiency of three large reservoirs upstream from the sampling point. Annual loads were estimated by use of the U.S. Geological Surveys ESTIMATOR model. Annual nutrient and sediment loads in 2003 were the second highest total nitrogen, total phosphorus, and sediment loads for the River Input Monitoring sites since 1990. Trends in concentrations, when adjusted for flow, can be used as an indicator of human activity and management actions. The flow-adjusted trends indicated significant decreasing trends at approximately 55, 75, and 48 percent of the sites for total nitrogen, total phosphorus, and sediment, respectively. This suggests management actions are having some effect in reducing nutrients and sediments. Sampling protocols for the river inputs to the bay have targeted high flows. Because this sampling strategy creates the potential for bias in estimated loads and trends, calculations are limited to flow-adjusted loads and trends in this report.

Scientific Investigations Report↗

Questa baseline and pre-mining ground-water quality investigation. 5. Well installation, water-level data, and surface- and ground-water geochemistry in the Straight Creek drainage basin, Red River Valley, New Mexico, 2001-03

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, northern New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site, proximal analog. The Straight Creek drainage basin, chosen for this purpose, consists of the same quartz-sericite-pyrite altered andesitic and rhyolitic volcanic rock of Tertiary age as the mine site. The weathered and rugged volcanic bedrock surface is overlain by heterogeneous debris-flow deposits that interfinger with alluvial deposits near the confluence of Straight Creek and the Red River. Pyritized rock in the upper part of the drainage basin is the source of acid rock drainage (pH 2.8-3.3) that infiltrates debris-flow deposits containing acidic ground water (pH 3.0-4.0) and bedrock containing water of circumneutral pH values (5.6-7.7). Eleven observation wells were installed in the Straight Creek drainage basin. The wells were completed in debris-flow deposits, bedrock, and interfingering debris-flow and Red River alluvial deposits. Chemical analyses of ground water from these wells, combined with chemical analyses of surface water, water-level data, and lithologic and geophysical logs, provided information used to develop an understanding of the processes contributing to the chemistry of ground water in the Straight Creek drainage basin. Surface- and ground-water samples were routinely collected for determination of total major cations and selected trace metals; dissolved major cations, selected trace metals, and rare-earth elements; anions and alkalinity; and dissolved-iron species. Rare-earth elements were determined on selected samples only. Samples were collected for determination of dissolved organic carbon, mercury, sulfur isotopic composition (34S and 18O of sulfate), and water isotopic composition (2H and 18O) during selected samplings. One set of ground-water samples was collected for helium-3/tritium and chlorofluorocarbon (CFC) age dating. Several lines of evidence indicate that surface water is the primary input to the Straight Creek ground-water system. Straight Creek streamflow and water levels in wells closest to the apex of the Straight Creek debris fan and closest to Straight Creek itself appear to respond to the same seasonal inputs. Oxygen and hydrogen isotopic compositions in Straight Creek surface water and ground water are similar, and concentrations of most dissolved constituents in most Straight Creek surface-water and shallow (debris-flow and alluvial) aquifer ground-water samples correlate strongly with sulfate (concentrations decrease linearly with sulfate in a downgradient direction). After infiltration of surface water, dilution along the flow path is the dominant mechanism controlling ground-water chemistry. However, concentrations of some constituents can be higher in ground water than can be accounted for by concentrations in Straight Creek surface water, and additional sources of these constituents must therefore be inferred. Constituents for which concentrations in ground water can be high relative to surface water include calcium, magnesium, strontium, silica, sodium, and potassium in ground water from debris-flow and alluvial aquifers and manganese, calcium, magnesium, strontium, sodium, and potassium in ground water from the bedrock aquifer. All ground water is a calcium sulfate type, often at or near gypsum saturation because of abundant gypsum in the aquifer material developed from co-existing calcite and pyrite mineralization. Calcite dissolution, the major buffering mechanism for bedrock aquifer ground water, also contributes to relatively higher calcium concentrations in some ground water. The main source of the second most abundant cation, magnesium, is probably dissolution of magnesium-rich carbonates or silicates.

New Mexico↗