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At least 1,099 records · Page 61Linked to original sources
USGS2010

Groundwater-flow assessment of the Mississippi River Valley alluvial aquifer of northeastern Arkansas

The Mississippi River Valley alluvial aquifer is a water-bearing assemblage of gravels and sands that underlies about 32,000 square miles of Arkansas, Kentucky, Louisiana, Mississippi, Missouri, and Tennessee. Pumping of groundwater from the alluvial aquifer for agriculture started in the early 1900s in the Grand Prairie area for the irrigation of rice and soybeans. From 1965 to 2005, water use in the alluvial aquifer increased 655 percent. In 2005, 6,242 million gallons per day of water were pumped from the aquifer, primarily for irrigation and fish farming. Water-level declines in the alluvial aquifer were documented as early as 1927. Long-term water-level measurements in the alluvial aquifer show an average annual decline of 1 foot per year in some areas. In this report, the utility of the updated 2009 MODFLOW groundwater-flow model of the alluvial aquifer in northeastern Arkansas was extended by performing groundwater-flow assessments of the alluvial aquifer at specific areas of interest using a variety of methods. One such area is along the western side of Crowleys Ridge, which includes western parts of Clay, Greene, Craighead, Poinsett, Cross, St. Francis, and Lee Counties. This area was designated as the Cache Critical Groundwater Area by the Arkansas Natural Resources Commission in 2009 for the alluvial and Sparta/Memphis aquifers, because of the rate of change in groundwater levels and groundwater levels have dropped below half the original saturated thickness of the alluvial aquifer.

Scientific Investigations Report↗
USGS2011

Estimates of tracer-based piston-flow ages of groundwater from selected sites: National Water-Quality Assessment Program, 1992–2005

This report documents selected age data interpreted from measured concentrations of environmental tracers in groundwater from 1,399 National Water-Quality Assessment (NAWQA) Program groundwater sites across the United States. The tracers of interest were chlorofluorocarbons (CFCs), sulfur hexafluoride (SF 6 ), and tritium/helium-3 ( 3 H/ 3 He). Tracer data compiled for this analysis primarily were from wells representing two types of NAWQA groundwater studies—Land-Use Studies (shallow wells, usually monitoring wells, in recharge areas under dominant land-use settings) and Major-Aquifer Studies (wells, usually domestic supply wells, in principal aquifers and representing the shallow, used resource). Reference wells (wells representing groundwater minimally impacted by anthropogenic activities) associated with Land-Use Studies also were included. Tracer samples were collected between 1992 and 2005, although two networks sampled from 2006 to 2007 were included because of network-specific needs. Tracer data from other NAWQA Program components (Flow System Studies, which are assessments of processes and trends along groundwater flow paths, and various topical studies) were not compiled herein. Tracer data from NAWQA Land-Use Studies and Major-Aquifer Studies that previously had been interpreted and published are compiled herein (as piston-flow ages), but have not been reinterpreted. Tracer data that previously had not been interpreted and published are evaluated using documented methods and compiled with aqueous concentrations, equivalent atmospheric concentrations (for CFCs and SF 6 ), estimates of tracer-based piston-flow ages, and selected ancillary data, such as redox indicators, well construction, and major dissolved gases (N 2 , O 2 , Ar, CH 4 , and CO 2 ). Tracer-based piston-flow ages documented in this report are simplistic representations of the tracer data. Tracer-based piston-flow ages are a convenient means of conceptualizing groundwater age. However, the piston-flow model is based on the potentially limiting assumptions that tracer transport is advective and that no mixing occurs. Additional uncertainties can arise from tracer degradation, sorption, contamination, or fractionation; terrigenic (natural) sources of tracers; spatially variable atmospheric tracer concentrations; and incomplete understanding of mechanisms of recharge or of the conditions under which atmospheric tracers were partitioned to recharge. The effects of some of these uncertainties are considered herein. For example, degradation, contamination, or fractionation often can be identified or inferred. However, detailed analysis of the effects of such uncertainties on the tracer-based piston-flow ages is constrained by sparse data and an absence of complementary lines of evidence, such as detailed solute transport simulations. Thus, the tracer-based piston-flow ages compiled in this report represent only an initial interpretation of the tracer data.

Scientific Investigations Report↗
USGS2011

Hydrogeology and simulation of groundwater flow in fractured rock in the Newark basin, Rockland County, New York

Groundwater in the Newark basin aquifer flows primarily through discrete water-bearing zones parallel to the strike and dip of bedding, whereas flow perpendicular to the strike is restricted, thereby imparting anisotropy to the groundwater flow field. The finite-element model SUTRA was used to represent bedrock structure in the aquifer by spatially varying the orientation of the hydraulic conductivity tensor to reflect variations in the strike and dip of the bedding. Directions of maximum and medium hydraulic conductivity were oriented parallel to the bedding, and the direction of minimum hydraulic conductivity was oriented perpendicular to the bedding. Groundwater flow models were prepared to simulate local flow in the vicinity of the Spring Valley well field and regional flow through the Newark basin aquifer. The Newark basin contains sedimentary rocks deposited as alluvium during the Late Triassic and is one of a series of basins that developed when Mesozoic rifting of the super continent Pangea created the Atlantic Ocean. The westward-dipping basin is filled with interbedded facies of coarse-grained to fine-grained rocks that were intruded by diabase associated with Jurassic volcanism. The Newark basin aquifer is bounded to the north and east by the Palisades sill and to the west by the Ramapo Fault. Although the general dip of bedding is toward the fault, mapping of conglomerate beds indicates the rocks are folded into broad anticlines and synclines. An alternative, more uniform pattern of regional structure, based on interpolated strike and dip measurements from a number of sources, has also been proposed. Two groundwater flow models (A for the former type of bedrock structure and B for the latter type) were developed to represent these alternative depictions of bedrock structure. Transient simulations were calibrated to reproduce measured water-level recoveries in a 9.3 mi&sup2 area surrounding the Spring Valley well field during a 5-day aquifer test in 1992. The models represented a 330-ft thick rock mass divided vertically into 10 equally spaced layers and were calibrated through nonlinear regression. Results of model B best matched the observed water-level recoveries with an estimated hydraulic conductivity of 9.5 ft/day, specific storage of 7.6 x 10 -6 ft -1, and K max : K min anisotropy ratio (hydraulic conductivity parallel to bedding: perpendicular to bedding) of 72:1. Model error was 50 percent greater in model A because the assumed structure did not match the actual strike of bedding in this area. Steady-state simulations of regional flow through the 85.4-mi2 modeled extent of the Newark basin aquifer represented both the alluvial aquifer beneath the Mawah River and the fractured bedrock. The rock mass was divided into two aquifer units: an upper 500-ft thick unit divided into 10 equally spaced layers through which most groundwater is assumed to flow and a lower unit divided into 7 layers with increasing thickness. Models were calibrated through nonlinear regression to average water levels measured in 140 wells from August 2005 through April 2007. Water levels simulated using the two models were similar and generally matched those observed, and the average recharge rate estimated using both models was 19 inches/year for the simulated period. Estimated transmissivity parallel to the strike of bedding (1,100 ft&sup2/d) was uniform in two transmissivity (T) zones in model A, but in model B the transmissivity of a high T zone (1,600 ft&sup2/d), delineated on the basis of aquifer test data, was slightly greater than in a low T zone (1,300 ft&sup2/d). The K max : K min anisotropy was estimated to be 58:1 in model A and 410:1 in model B, so the proportion of flow perpendicular to bedding is less in model B than in model A. Distributions of groundwater age simulated with models A and B are similar and indicate that most shallow ground-water (225 ft below the bedrock surface) is 5 t

Scientific Investigations Report↗
USGS2011

Groundwater conditions and studies in Georgia, 2008-2009

The U.S. Geological Survey collects groundwater data and conducts studies to monitor hydrologic conditions, better define groundwater resources, and address problems related to water supply, water use, and water quality. In Georgia, water levels were monitored continuously at 179 wells during 2008 and 181 wells during 2009. Because of missing data or short periods of record (less than 3 years) for several of these wells, a total of 161 wells are discussed in this report. These wells include 17 in the surficial aquifer system, 19 in the Brunswick aquifer and equivalent sediments, 66 in the Upper Floridan aquifer, 16 in the Lower Floridan aquifer and underlying units, 10 in the Claiborne aquifer, 1 in the Gordon aquifer, 11 in the Clayton aquifer, 12 in the Cretaceous aquifer system, 2 in Paleozoic-rock aquifers, and 7 in crystalline-rock aquifers. Data from the well network indicate that water levels generally rose during the 2008-2009 period, with water levels rising in 135 wells and declining in 26. In contrast, water levels declined over the period of record at 100 wells, increased at 56 wells, and remained relatively constant at 5 wells. In addition to continuous water-level data, periodic water-level measurements were collected and used to construct potentiometric-surface maps for the Upper Floridan aquifer in Camden, Charlton, and Ware Counties, Georgia, and adjacent counties in Florida during September 2008 and May 2009; in the Brunswick, Georgia area during July 2008 and July-August 2009; and in the City of Albany-Dougherty County, Georgia area during November 2008 and November 2009. In general, water levels in these areas were higher during 2009 than during 2008; however, the configuration of the potentiometric surfaces in each of the areas showed little change. Groundwater quality in the Floridan aquifer system is monitored in the Albany, Savannah, Brunswick, and Camden County areas of Georgia. In the Albany area, nitrate as nitrogen concentrations in the Upper Floridan aquifer during 2008-2009 generally increased, with concentrations in two wells above the U.S. Environmental Protection Agency (USEPA) 10-milligrams-per-liter (mg/L) drinking-water standard. In the Savannah area, measurement of specific conductance and chloride concentration in water samples from discrete depths in three wells completed in the Upper Floridan aquifer indicate that chloride concentrations in the Upper Floridan aquifer showed little change and remained below the 250 mg/L USEPA secondary drinking-water standard. Chloride concentrations in the Lower Floridan aquifer increased slightly at Tybee Island and Skidaway Island, remaining above the drinking-water standard. In the Brunswick area, maps showing the chloride concentration of water in the Upper Floridan aquifer were constructed using data collected from 28 wells during July 2008 and from 29 wells during July-August 2009, indicate that chloride concentrations remained above the USEPA secondary drinking-water standard in an approximately 2-square-mile area. During 2008-2009, chloride concentrations decreased, with a maximum decrease of 160 mg/L, in a well located in the northern part of the Brunswick area. In the Camden County area, chloride concentration during 2008-2009 was analyzed in water samples collected from eight wells, six of which were completed in the Upper Floridan aquifer and two in the Lower Floridan aquifer. In most of the wells sampled during this period, chloride concentrations did not appreciably change; however, since the closure of the Durango Paper Company in October 2002, chloride concentrations in the Upper Floridan aquifer near the paper mill decreased from a high of 184 mg/L in May 2002 to 41 mg/L in September 2009. Groundwater studies conducted in Georgia during 2008-2009 include the following: * evaluation of groundwater flow, water-quality, and water-level monitoring in the Augusta-Richmond County area; * evaluation of groundwater flow, water-quality, and water

Georgia↗
USGS2011

Regional water table (2010) in the Mojave River and Morongo Groundwater basins, southwestern Mojave Desert, California

Since 1992, the U.S. Geological Survey (USGS), in cooperation with the Mojave Water Agency (MWA), has constructed a series of regional water-table maps for intermittent years in a continuing effort to monitor groundwater conditions in the Mojave River and Morongo groundwater basins. The previously published data, which were used to construct these maps, can be accessed on the interactive map. The associated reports describing the groundwater conditions for the Mojave River groundwater basin for 1992 (Stamos and Predmore, 1995), the Morongo groundwater basin for 1994 (Trayler and Koczot, 1995), and for both groundwater basins for 1996 (Mendez and Christensen, 1997); for 1998 (Smith and Pimentel, 2000), for 2000 (Smith, 2002), for 2002 (Smith and others, 2004), for 2004 (Stamos and others, 2004), for 2006 (Stamos and others, 2007), and for 2008 (Stamos and others, 2009) can be accessed using this web site. Mapping of water-level contours and water-level change were combined in an interactive map. This interactive map may be customized to your needs and viewed at a scale that is appropriate for the data.

California↗
USGS2012

Groundwater availability in the Lahaina District, west Maui, Hawai'i

Most of the public water supply in the Lahaina District, west Maui, Hawai'i, is pumped from a freshwater lens in volcanic rocks. Because of population growth, groundwater withdrawals from wells in this area are expected to increase from about 5.8 million gallons per day in 2007 to more than 11 million gallons per day by 2030. Currently (2011), the salinity of water pumped from some of the wells in the area exceeds acceptable limits for drinking water. The expected increasing demand for water in an area in which the salinity of water is already unacceptable has led to concern over the long-term sustainability of withdrawals from existing and proposed wells. A three-dimensional numerical groundwater flow and transport model was developed to simulate the effects of hypothetical withdrawal and recharge scenarios on water levels and on the transition zone between freshwater and saltwater. The model was constructed using time-varying recharge, withdrawals, and ocean levels. Hydraulic characteristics used to construct the model were initially based on published estimates but ultimately were varied to obtain better agreement between simulated and measured water levels and salinity profiles in the modeled area during 1926–2008. Scenarios included groundwater withdrawal at 2008–09 rates and locations with projected recharge (based on 2000–04 land use, no agricultural irrigation, and the rainfall record for the period 1926–2004) and withdrawal at redistributed rates and locations with several different recharge scenarios. Simulation results indicate that continuing the 2008–09 withdrawal rates and distribution (6.3 million gallons per day from 21 wells) into the future would result in decreased water levels, a thinner freshwater lens, and increased salinity of water pumped from wells. Groundwater demand projections and proposed new well sites were used to produce a projected withdrawal rate and distribution during 2010–39. Simulation results from this projected withdrawal scenario (11.2 million gallons per day from 28 wells, including 10 proposed wells) also indicate decreased water levels, a thinner freshwater lens, increased water salinity, and unacceptable salinity at several current withdrawal sites, mainly in the Honokōwai Aquifer System; however, more groundwater is available than in the previous scenario. A simulation in which injection of treated wastewater is stopped indicates that several wells will have increased salinities compared to the scenario in which injection continues. A scenario in which increased groundwater withdrawal was redistributed in an attempt to maximize withdrawal while maintaining acceptable salinities in the withdrawn water was simulated. The redistributed withdrawal simulates 20.7 million gallons per day of withdrawal from 26 wells or well fields in the Lahaina District. Simulation results indicate the following: (1) average water levels decrease by about 0.5–1 feet and the transition zone rises 20–50 feet in some areas after 30 years, mainly in the Launiupoko Aquifer System near the proposed wells, and (2), all wells produce water with salinities in the acceptable class (less than one-percent seawater salinity) after 30 years.

Hawai'i↗
USGS2012

Groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri, well field

Source contributions to monitoring and supply wells, contributing recharge areas, groundwater travel times, and current (2012) understanding of alluvial water quality were used to develop a groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri well field. The plan was designed to evaluate long-term alluvial water quality and assess potential changes in, and threats to, well-field water quality. Source contributions were determined from an existing groundwater flow model in conjunction with particle-tracking analysis and verified with water-quality data collected from 1997 through 2010 from a network of 68 monitoring wells. Three conjunctive factors - well-field pumpage, Missouri River discharge, and aquifer recharge - largely determined groundwater flow and, therefore, source contributions. The predominant source of groundwater to most monitoring wells and supply wells is the Missouri River, and this was reflected, to some extent, in alluvial water quality. To provide an estimate of the maximum potential lead time available for remedial action, monitoring wells where groundwater travel times from the contributing recharge areas are less than 2 years and predominately singular sources (such as the Missouri River or the land surface) were selected for annual sampling. The sample interval of the remaining wells, which have varying travel times and intermediate mixtures of river and land-surface contributions, were staggered on a 2-, 3-, or 4-year rotation. This was done to provide data from similar contributing areas and account for inherent aquifer variability yet minimize sample redundancy.

Missouri↗
USGS2012

Hydrogeology and simulation of groundwater flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas, 1891-2009

In cooperation with the Harris–Galveston Subsidence District, Fort Bend Subsidence District, and Lone Star Groundwater Conservation District, the U.S. Geological Survey developed and calibrated the Houston Area Groundwater Model (HAGM), which simulates groundwater flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system in Texas from predevelopment (before 1891) through 2009. Withdrawal of groundwater since development of the aquifer system has resulted in potentiometric surface (hydraulic head, or head) declines in the Gulf Coast aquifer system and land-surface subsidence (primarily in the Houston area) from depressurization and compaction of clay layers interbedded in the aquifer sediments. The MODFLOW-2000 groundwater flow model described in this report comprises four layers, one for each of the hydrogeologic units of the aquifer system except the Catahoula confining system, the assumed no-flow base of the system. The HAGM is composed of 137 rows and 245 columns of 1-square-mile grid cells with lateral no-flow boundaries at the extent of each hydrogeologic unit to the northwest, at groundwater divides associated with large rivers to the southwest and northeast, and at the downdip limit of freshwater to the southeast. The model was calibrated within the specified criteria by using trial-and-error adjustment of selected model-input data in a series of transient simulations until the model output (potentiometric surfaces, land-surface subsidence, and selected water-budget components) acceptably reproduced field measured (or estimated) aquifer responses including water level and subsidence. The HAGM-simulated subsidence generally compared well to 26 Predictions Relating Effective Stress to Subsidence (PRESS) models in Harris, Galveston, and Fort Bend Counties. Simulated HAGM results indicate that as much as 10 feet (ft) of subsidence has occurred in southeastern Harris County. Measured subsidence and model results indicate that a larger geographic area encompassing this area of maximum subsidence and much of central to southeastern Harris County has subsided at least 6 ft. For the western part of the study area, the HAGM simulated as much as 3 ft of subsidence in Wharton, Jackson, and Matagorda Counties. For the eastern part of the study area, the HAGM simulated as much as 3 ft of subsidence at the boundary of Hardin and Jasper Counties. Additionally, in the southeastern part of the study area in Orange County, the HAGM simulated as much as 3 ft of subsidence. Measured subsidence for these areas in the western and eastern parts of the HAGM has not been documented.

Texas↗
USGS2013

Effects of surface applications of biosolids on groundwater quality and trace-element concentrations in crops near Deer Trail, Colorado, 2004-2010

The U.S. Geological Survey (USGS), in cooperation with Metro Wastewater Reclamation District (Metro District), studied biosolids composition and the effects of biosolids applications on groundwater quality and trace-element concentrations in crops of the Metro District properties near Deer Trail, Colorado, during 2004 through 2010. Priority parameters for each monitoring component included the nine trace elements regulated by Colorado for biosolids (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc); other constituents also were analyzed. All concentrations for the priority parameters in monthly biosolids samples were less than Colorado regulatory limits, and the concentrations were relatively consistent. Biosolids likely were the largest source of nitrogen and phosphorus on the Metro District properties. Plutonium isotopes were not detected in the biosolids, but many organic wastewater compounds (organic wastewater compounds: wastewater indicators, pharmaceuticals, and hormones) were detected in substantial concentrations relative to minimum reporting levels and various surface-water concentrations. Bismuth, copper, mercury, nitrogen, phosphorus, silver, biogenic sterols, detergent degradates, disinfectants, fire retardants, fragrances, pharmaceuticals, and plasticizers would be the most likely biosolids signature to indicate the presence of Metro District biosolids in soil or streambed sediment from the study area. Antimony, cadmium, cobalt, copper, molybdenum, nickel, nitrogen, phosphorus, selenium, tungsten, vanadium, zinc, detergent degradates, disinfectants, fire retardants, fragrances, pharmaceuticals or their degradates, and plasticizers would be the most likely biosolids signature for groundwater and surface water in the study area. More biosolids-signature components detected and larger concentration differences from untreated materials, baseline, and blank samples indicate more evidence of biosolids presence or effects. Although the inorganic constituent concentrations were relatively large in samples from one monitoring well, the concentrations of organic wastewater compounds in groundwater samples were not correspondingly large. Concentrations of organic wastewater compounds in the groundwater samples from all five monitoring wells were less than the minimum reporting levels with only a few detections. Some of the organic wastewater compounds detected could have anthropogenic sources that are not biosolids. Concentrations of priority parameters in groundwater varied spatially and temporally but generally were less than Colorado regulatory limits. Concentrations of dissolved nitrate, arsenic, and selenium, in addition to chloride, sulfate, total dissolved solids, boron, iron, manganese, and uranium, in samples from some wells exceeded the Colorado standards. Concentrations of dissolved nitrate (three wells), molybdenum (one well), selenium (two wells), and uranium (one well) in shallow groundwater had significant (alpha = 0.05) upward trends in some parts of the study area. The biosolids-signature results indicate that the aquifers intercepted by the five routinely sampled wells likely have received some recharge through treated (biosolids-applied) fields or biosolids-affected ponds. Adverse effects from this biosolids-related recharge range from few (if any) at one well to large and significantly (alpha = 0.05) increasing nitrate concentrations at another well. A statistical evaluation of five paired wheat-grain samples from treated (biosolids-applied) fields and untreated (control) fields did not indicate any evidence that biosolids applications significantly (alpha = 0.05 or 0.10) increased concentration of any of these constituents in wheat grain. The wheat-grain concentrations from this study were similar to those from other studies for fields in North America where no biosolids were applied. The data for the limited crop samples indicate that biosolids applications are not increasing the concentrations of arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, sulfur, and zinc in mature wheat grain from the study area.

Colorado↗
USGS2013

Conceptual and numerical models of groundwater flow in the Ogallala aquifer in Gregory and Tripp Counties, South Dakota, water years 1985--2009

The Ogallala aquifer is an important water resource for the Rosebud Sioux Tribe in Gregory and Tripp Counties in south-central South Dakota and is used for irrigation, public supply, domestic, and stock water supplies. To better understand groundwater flow in the Ogallala aquifer, conceptual and numerical models of groundwater flow were developed for the aquifer. A conceptual model of the Ogallala aquifer was used to analyze groundwater flow and develop a numerical model to simulate groundwater flow in the aquifer. The MODFLOW–NWT model was used to simulate transient groundwater conditions for water years 1985–2009. The model was calibrated using statistical parameter estimation techniques. Potential future scenarios were simulated using the input parameters from the calibrated model for simulations of potential future drought and future increased pumping. Transient simulations were completed with the numerical model. A 200-year transient initialization period was used to establish starting conditions for the subsequent 25-year simulation of water years 1985–2009. The 25-year simulation was discretized into three seasonal stress periods per year and used to simulate transient conditions. A single-layer model was used to simulate flow and mass balance in the Ogallala aquifer with a grid of 133 rows and 282 columns and a uniform spacing of 500 meters (1,640 feet). Regional inflow and outflow were simulated along the western and southern boundaries using specified-head cells. All other boundaries were simulated using no-flow cells. Recharge to the aquifer occurs through precipitation on the outcrop area. Model calibration was accomplished using the Parameter Estimation (PEST) program that adjusted individual model input parameters and assessed the difference between estimated and model-simulated values of hydraulic head and base flow. This program was designed to estimate parameter values that are statistically the most likely set of values to result in the smallest differences between simulated and observed values, within a given set of constraints. The potentiometric surface of the aquifer calculated during the 200-year initialization period established initial conditions for the transient simulation. Water levels for 38 observation wells were used to calibrate the 25-year simulation. Simulated hydraulic heads for the transient simulation were within plus or minus 20 feet of observed values for 95 percent of observation wells, and the mean absolute difference was 5.1 feet. Calibrated hydraulic conductivity ranged from 0.9 to 227 feet per day (ft/d). The annual recharge rates for the transient simulation (water years 1985–2009) ranged from 0.60 to 6.96 inches, with a mean of 3.68 inches for the Ogallala aquifer. This represents a mean recharge rate of 280.5 ft 3 /s for the model area. Discharge from the aquifer occurs through evapotranspiration, discharge to streams through river leakage and flow from springs and seeps, and well withdrawals. Water is withdrawn from wells for irrigation, public supply, domestic, and stock uses. Simulated mean discharge rates for water years 1985–2009 were about 185 cubic feet per second (ft 3 /s) for evapotranspiration, 66.7 ft 3 /s for discharge to streams, and 5.48 ft 3 /s for well withdrawals. Simulated annual evapotranspiration rates ranged from about 128 to 254 ft 3 /s, and outflow to streams ranged from 52.2 to 79.9 ft 3 /s. A sensitivity analysis was used to examine the response of the calibrated model to changes in model parameters for horizontal hydraulic conductivity, recharge, evapotranspiration, and spring and riverbed conductance. The model was most sensitive to recharge and maximum potential evapotranspiration and least sensitive to riverbed and spring conductances. Two potential future scenarios were simulated: a potential drought scenario and a potential increased pumping scenario. To simulate a potential drought scenario, a synthetic drought record was created, the mean of which was equal to 60 percent of the mean estimated recharge rate for the 25-year simulation period. Compared with the results of the calibrated model (non-drought simulation), the simulation representing a potential drought scenario resulted in water-level decreases of as much as 30 feet for the Ogallala aquifer. To simulate the effects of potential future increases in pumping, well withdrawal rates were increased by 50 percent from those estimated for the 25-year simulation period. Compared with the results of the calibrated model, the simulation representing an increased pumping scenario resulted in water-level decreases of as much as 26 feet for the Ogallala aquifer. Groundwater budgets for the potential future scenario simulations were compared with the transient simulation representing water years 1985–2009. The simulation representing a potential drought scenario resulted in lower aquifer recharge from precipitation and decreased discharge from streams, springs, seeps, and evapotranspiration. The simulation representing a potential increased pumping scenario was similar to results from the transient simulation, with a slight increase in well withdrawals and a slight decrease in discharge from river leakage and evapotranspiration. This numerical model is suitable as a tool that could be used to better understand the flow system of the Ogallala aquifer, to approximate hydraulic heads in the aquifer, and to estimate discharge to rivers, springs, and seeps in the study area. The model also is useful to help assess the response of the aquifer to additional stresses, including potential drought conditions and increased well withdrawals.

South Dakota↗
USGS2013

Chemistry and age of groundwater in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2010-12

Fourteen monitoring wells completed in the Uinta and Green River Formations in the Piceance Creek and Yellow Creek watersheds in Rio Blanco County, Colorado, were sampled for chemical, isotopic, and groundwater-age tracers to provide information on the overall groundwater quality, the occurrence and distribution of chemicals that could be related to the development of underlying natural-gas reservoirs, and to better understand groundwater residence times in the flow system. Methane concentrations in groundwater ranged from less than 0.0005 to 387 milligrams per liter. The methane was predominantly biogenic in origin, although the biogenic methane was mixed with thermogenic methane in water from seven wells. Three BTEX compounds (benzene, toluene, and ethylbenzene) were detected in water from six of the wells, but none of the concentrations exceeded Federal drinking-water standards. The presence of thermogenic methane in the aquifers indicates a connection and vulnerability to chemicals in deeper geologic units. Helium-4 data indicate that groundwater had ages ranging from less than 1,000 years to greater than 50,000 years. The presence of old groundwater in parts of the aquifers indicates that these aquifers may not be useful for large-scale water supply because of low recharge rates.

Colorado↗
USGS2014

Characterization of the structure, clean-sand percentage, dissolved-solids concentrations, and estimated quantity of groundwater in the Upper Cretaceous Nacatoch Sand and Tokio Formation, Arkansas

The West Gulf Coastal Plain, Mississippi embayment, and underlying Cretaceous aquifers are rich in water resources; however, large parts of the aquifers are largely unusable because of large concentrations of dissolved solids. Cretaceous aquifers are known to have large concentrations of salinity in some parts of Arkansas. The Nacatoch Sand and the Tokio Formation of Upper Cretaceous age were chosen for investigation because these aquifers produce groundwater to wells near their outcrops and have large salinity concentrations away from their outcrop areas. Previous investigations have indicated that dissolved-solids concentrations of groundwater within the Nacatoch Sand, 2–20 miles downdip from the outcrop, render the groundwater as unusable for purposes requiring freshwater. Groundwater within the Tokio Formation also exhibits large concentrations of dissolved solids downdip. Water-quality data showing elevated dissolved-solids concentrations are limited for these Cretaceous aquifers because other shallower aquifers are used for water supply. Although not suitable for many uses, large, unused amounts of saline groundwater are present in these aquifers. Historical borehole geophysical logs were used to determine the geologic and hydrogeologic properties of these Cretaceous aquifers, as well as the quality of the groundwater within the aquifers. Based on the interpretation of borehole geophysical logs, in Arkansas, the altitude of the top of the Nacatoch Sand ranges from more than 200 to less than -4,000 feet; the structural high occurs in the outcrop area and the structural low occurs in southeastern Arkansas near the Desha Basin structural feature. The thickness of the Nacatoch Sand ranges from 0 to over 550 feet. The minimum thickness occurs where the formation pinches out in the outcrop area, and the maximum thickness occurs in the southwestern corner of Arkansas. Other areas of large thickness include the area of the Desha Basin structural feature in southeastern Arkansas and in an area on the border of Cross and St. Francis Counties in eastern Arkansas. The clean-sand percentage of the total Nacatoch Sand thickness ranges from less than 20 percent to more than 60 percent and generally decreases downdip. The Nacatoch Sand contains more than 120.5 million acre-feet of water with a dissolved-solids concentration between 1,000 and 10,000 milligrams per liter (mg/L), more than 57.5 million acre-feet of water with a dissolved-solids concentration between 10,000 and 35,000 mg/L, and more than 122.5 million acre-feet of water with a dissolved-solids concentration more than 35,000 mg/L. The altitude of the top of the Tokio Formation, in Arkansas, ranges from more than 200 feet to less than -4,400 feet; the structural high occurs in the outcrop area and the structural low occurs in southeastern Arkansas near the Desha Basin structural feature. The thickness of the Tokio Formation, in Arkansas, ranges from 0 to over 400 feet. The minimum thickness occurs where the formation pinches out in the outcrop area, and the maximum thickness occurs in the southwestern corner of Arkansas. The clean-sand percentage of the total Tokio Formation thickness ranges from less than 20 percent to more than 60 percent and generally decreases away from the outcrop area. The Tokio Formation contains more than 2.5 million acre-feet of water with a dissolved-solids concentration between 1,000 and 10,000 mg/L, more than 12.5 million acre-feet of water with a dissolved-solids concentration between 10,000 and 35,000 mg/L, and nearly 43.5 million acre-feet of water with a dissolved-solids concentration more than 35,000 mg/L.

Arkansas↗
USGS2014

Land subsidence, groundwater levels, and geology in the Coachella Valley, California, 1993-2010

Land subsidence associated with groundwater-level declines has been investigated by the U.S. Geological Survey in the Coachella Valley, California, since 1996. Groundwater has been a major source of agricultural, municipal, and domestic supply in the valley since the early 1920s. Pumping of groundwater resulted in water-level declines as much as 15 meters (50 feet) through the late 1940s. In 1949, the importation of Colorado River water to the southern Coachella Valley began, resulting in a reduction in groundwater pumping and a recovery of water levels during the 1950s through the 1970s. Since the late 1970s, demand for water in the valley has exceeded deliveries of imported surface water, resulting in increased pumping and associated groundwater-level declines and, consequently, an increase in the potential for land subsidence caused by aquifer-system compaction. Global Positioning System (GPS) surveying and Interferometric Synthetic Aperture Radar (InSAR) methods were used to determine the location, extent, and magnitude of the vertical land-surface changes in the southern Coachella Valley during 1993–2010. The GPS measurements taken at 11 geodetic monuments in 1996 and in 2010 in the southern Coachella Valley indicated that the elevation of the land surface changed –136 to –23 millimeters (mm) ±54 mm (–0.45 to –0.08 feet (ft) ±0.18 ft) during the 14-year period. Changes at 6 of the 11 monuments exceeded the maximum expected uncertainty of ±54 mm (±0.18 ft) at the 95-percent confidence level, indicating that subsidence occurred at these monuments between June 1996 and August 2010. GPS measurements taken at 17 geodetic monuments in 2005 and 2010 indicated that the elevation of the land surface changed –256 to +16 mm ±28 mm (–0.84 to +0.05 ft ±0.09 ft) during the 5-year period. Changes at 5 of the 17 monuments exceeded the maximum expected uncertainty of ±28 mm (±0.09 ft) at the 95-percent confidence level, indicating that subsidence occurred at these monuments between August 2005 and August 2010. At each of these five monuments, subsidence rates were about the same between 2005 and 2010 as between 2000 and 2005. InSAR measurements taken between June 27, 1995, and September 19, 2010, indicated that the land surface subsided from about 220 to 600 mm (0.72 to 1.97 ft) in three areas of the Coachella Valley: near Palm Desert, Indian Wells, and La Quinta. In Palm Desert, the average subsidence rates increased from about 39 millimeters per year (mm/yr), or 0.13 foot per year (ft/yr), during 1995–2000 to about 45 mm/yr (0.15 ft/yr) during 2003–10. In Indian Wells, average subsidence rates for two subsidence maxima were fairly steady at about 34 and 26 mm/yr (0.11 and 0.09 ft/yr) during both periods; for the third maxima, average subsidence rates increased from about 14 to 19 mm/yr (0.05 to 0.06 ft/yr) from the first to the second period. In La Quinta, average subsidence rates for five selected locations ranged from about 17 to 37 mm/yr (0.06 to 0.12 ft/yr) during 1995–2000; three of the locations had similar rates during 2003–mid-2009, while the other two locations had increased subsidence rates. Decreased subsidence rates were calculated throughout the La Quinta subsidence area during mid-2009–10, however, and uplift was observed during 2010 near the southern extent of this area. Water-level measurements taken at wells near the subsiding monuments and in the three subsiding areas shown by InSAR generally indicated that the water levels fluctuated seasonally and declined annually from the early 1990s, or earlier, to 2010; some water levels in 2010 were at the lowest levels in their recorded histories. An exception to annually declining water levels in and near subsiding areas was observed beginning in mid-2009 in the La Quinta subsidence area, where recovering water levels coincided with increased recharge operations at the Thomas E. Levy Recharge Facility; decreased pumpage also could cause groundwater levels to recover. Subsidence concomitant with declining water levels and land-surface uplift concomitant with recovering water levels indicate that aquifer-system compaction could be causing subsidence. If the stresses imposed by the historically lowest water levels exceeded the preconsolidation stress, the aquifer-system compaction and associated land subsidence could be permanent.

California↗
USGS2014

Groundwater levels in the Denver Basin bedrock aquifers of Douglas County, Colorado, 2011-2013

More than 70 percent of the municipal water supply in the south Denver metropolitan area is provided by groundwater, and homeowners in rural areas depend solely on self-supplied groundwater for water supply. Increased groundwater withdrawal to meet the demand of the rapidly growing population is causing water levels to decline. The U.S. Geological Survey, in cooperation with the Rural Water Authority of Douglas County, began a study in 2011 to assess the groundwater resources of the Denver Basin aquifers within Douglas County, Colorado. The primary purpose of this study was to monitor changes in the groundwater levels of the bedrock aquifers of the Denver Basin within rural Douglas County. To better assess the water resources of the Denver Basin bedrock aquifers, a groundwater monitoring network was established in 2011. More than 500 manual and 213,900 automated water-level measurements collected from the 36 domestic-well network between April 2011 and June 2013 showed water-level declines in all aquifers. Manual and automated (time-series) water-level data collection from these sites between 2011 and 2013 showed water level declines in 36 wells. Over the 2-year monitoring period, average declines of approximately 0.4 foot per year were observed in the upper Dawson aquifer, declines of over 2.6 feet per year were observed in the lower Dawson aquifer, declines of about 3.2 feet per year were observed in the Denver aquifer, declines of about 1.9 feet per year were observed in the Arapahoe aquifer, and declines of about 9.9 feet per year were observed in the Laramie-Fox Hills aquifer.

Colorado↗
USGS2015

Hydrogeologic framework, hydrology, and refined conceptual model of groundwater flow for Coastal Plain aquifers at the Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2005-12

From 1966 to 2002, activities at the Standard Chlorine of Delaware chemical facility in New Castle County, Delaware resulted in the contamination of groundwater, soils, and wetland sediment. In 2005, the U.S. Geological Survey (USGS), in partnership with the U.S. Environmental Protection Agency, Region 3, and the Delaware Department of Natural Resources and Environmental Control began a multi-year investigation of the hydrogeologic framework and hydrology of the confined aquifer system. The goals of the ongoing study at the site (the Potomac Aquifer Study) are to determine the hydraulic connection between the Columbia and Potomac aquifers, determine the direction of groundwater flow in the Potomac aquifer, and identify factors affecting the fate of contaminated groundwater. This report describes progress made towards these goals based on available data collected through September 2012. The regional hydrogeologic framework indicates that the site is underlain by Coastal Plain sediments of the Columbia, Merchantville, and Potomac Formations. Two primary aquifers underlying the site, the Columbia and the upper Potomac, are separated by the Merchantville Formation confining unit. Local groundwater flow in the surficial (Columbia) aquifer is controlled by topography and generally flows northward and discharges to nearby surface water. Regional flow within the Potomac aquifer is towards the southeast, and is strongly influenced by major water withdrawals locally. Previous investigations at the site indicated that contaminants, primarily benzene and chlorinated benzene compounds, were present in the Columbia aquifer in most locations; however, there were only limited detections in the upper Potomac aquifer as of 2004. From 2005 through 2012, the USGS designed a monitoring network, assisted with exploratory drilling, collected data at monitoring wells, conducted geophysical surveys, evaluated water-level responses in wells during pumping of a production well, and evaluated major aquifer withdrawals. Data collected through these efforts were used to refine the local conceptual flow system. The refined conceptual flow system for the site includes: (a) identification of gaps in confining units in the study area, (b) identification and correlation of multiple water-bearing sand intervals within the upper Potomac Formation, (c) connections between groundwater and surface water, (d) connections between shallow and deeper groundwater, (e) new water-level (or potentiometric surface) maps and inferred flow directions, and (f) identification of major local pumping well influences. The implications of the revised conceptual flow system on the occurrence and movement of site contaminants are that the resulting detection of contaminants in the upper Potomac aquifer at specific well locations can be attributed primarily to either advective lateral transport, direct vertical contaminant transport, or a combination of vertical and lateral movement resulting from changes in water withdrawal rates over time.

Delaware↗
USGS2015

Conceptual and numerical models of groundwater flow in the Ogallala and Arikaree aquifers, Pine Ridge Indian Reservation area, South Dakota, water years 1980-2009

The Ogallala and Arikaree aquifers are the largest sources of groundwater on the Pine Ridge Indian Reservation and are used extensively for irrigation and public and domestic water supplies. To assess the potential for decreased water levels and discharge to streams in the Pine Ridge Indian Reservation, conceptual and numerical models of groundwater flow in the Ogallala and Arikaree aquifers in southwestern South Dakota were developed by the U.S. Geological Survey in cooperation with the Oglala Sioux Tribe. The study area includes most of the Pine Ridge Reservation in Jackson and Shannon Counties and Indian trust lands in Bennett County in southwestern South Dakota. The High Plains aquifer, which includes the Ogallala and Arikaree aquifers, generally is less developed in South Dakota compared with other areas underlain by this aquifer; therefore, water levels in the High Plains aquifer in South Dakota generally fluctuated by less than 5 feet (ft) from 1980 to 1999. Despite minimal water-level changes in the High Plains aquifer in South Dakota, extensive withdrawals of groundwater for irrigation have caused water-level declines in many areas and increased concerns about the long-term sustainability of the aquifer; therefore, continued or increased withdrawals from the aquifer or prolonged drought may have the potential to affect water levels within the aquifer and discharge to important streams in the area. The Ogallala and Arikaree aquifers generally consist of poorly consolidated claystones, siltstones, sandstones, and shale deposited in fluvial and lacustrine environments. Saturated thicknesses ranged from 10 to 314 ft for the Ogllala aquifer and from 10 to 862 ft for the Arikaree aquifer. Previous hydraulic conductivity estimates ranged from less than 1 to 180 feet per day (ft/d) for the Ogallala aquifer and from less than 1 to 13 ft/d for the Arikaree aquifer. Recharge to the Ogallala and Arikaree aquifers is from precipitation on the outcrop areas, and discharge occurs through evapotranspiration, discharge to streams, and well withdrawals. Evapotranspiration generally occurs in topographically low areas along streams, and maximum evapotranspiration occurs when the water level is at the land surface. The generalized groundwater-flow direction is to the northeast with local flow towards streams. Precipitation for water years 1980–2009 ranged from about 11 to 39 inches per year (in/yr) and averaged about 19 in/yr. Estimated mean recharge for water years 1980–2009 was about 17.3 percent of precipitation for the Ogallala aquifer and 7.9 percent of precipitation for the Arikaree aquifer. The estimated mean maximum evapotranspiration for water years 1980–2009 was about 35 in/yr. Estimated mean base flow for gaged streams was about 0.06 cubic foot per second (ft 3 /s) per square mile of drainage area. Estimated mean total water use for water years 1980–2009 was 5.4 ft 3 /s from the Ogallala aquifer and 7.1 ft 3 /s from the Arikaree aquifer. A two-layer numerical groundwater-flow model was constructed using MODFLOW–NWT with a uniformly spaced grid consisting of 166 rows and 288 columns with cells 1,640 ft on a side. The numerical model of the Ogallala and Arikaree aquifers was used to simulate steady-state and transient conditions for water years 1980–2009. Model calibration was accomplished using the Parameter ESTimation (PEST) program that adjusted individual model input parameters and assessed the difference between estimated and model-simulated values of hydraulic head and base flow. Aquifer boundaries were no-flow on the northern and western sides and constant-head on the southern and eastern sides. The mean arithmetic difference was 1.4 ft between the 731 simulated and observed hydraulic heads in the Ogallala aquifer and 9.8 ft between the 2,754 simulated and observed hydraulic heads in the Arikaree aquifer. Simulated mean discharge from the Ogallala and Arikaree aquifers to selected stream reaches was 92.1 ft 3 /s compared to estimated discharge of 88.7 ft 3 /s. Calibrated recharge for the transient simulation averaged 3.3 in/yr for the Ogallala aquifer and 1.1 in/yr for the Arikaree aquifer. The mean maximum potential evapotranspiration rate was 35.4 in/yr. Streambed conductance for perennial stream reaches averaged 530 feet squared per day. Horizontal hydraulic conductivity averaged 27 ft/d for the Ogallala aquifer and 1.0 ft/d for the Arikaree aquifer. The vertical hydraulic conductivity averaged 1.4 ft/d for the Ogallala aquifer and 0.004 ft/d for the Arikaree aquifer. Specific yield for the Ogallala aquifer was 0.15 (dimensionless) and averaged 0.02 for the Arikaree aquifer. Specific storage for the Arikaree aquifer was 1.7x10 -6 per foot. Simulated steady-state model inflow and outflow was 459 ft 3 /s. The percentages of inflows were 17 percent from constant-head boundaries, 9 percent from streams, and 74 percent from recharge. Percentages of outflow were 8 percent to constant-head boundaries, 1 percent to wells, 31 percent to streams, and 59 percent to evapotranspiration. Simulated net inflow from the Ogallala aquifer to the Arikaree aquifer ranged from about 22 ft 3 /s in dry years to about 37 ft 3 /s in wet years. Two hypothetical future stress scenarios were simulated using input from the 30-year calibrated simulation of water years 1980–2009. The first hypothetical scenario represented an increase in groundwater withdrawals from 50 hypothetical production wells completed in the Arikaree aquifer. At the end of the 30-year hypothetical increased pumping simulation, water levels declined as much as 66 ft in the Arikaree aquifer, decreased discharge to streams accounted for about 26 percent (2.6 ft 3 /s) of increased withdrawals, and decreased evapotranspiration accounted for about 53 (5.3 ft 3 /s) percent of increased withdrawals. The second hypothetical scenario represented a 30-year period of decreased recharge (drought) by decreasing recharge 0.2 inch (24 ft 3 /s) for each water year. At the end of the hypothetical drought simulation, water levels declined as much as 10.9 ft in the Arikaree aquifer, decreased discharge to streams accounted for about 23 percent (5.5 ft 3 /s) of decreased recharge, and decreased evapotranspiration accounted for about 72 percent (17.3 ft 3 /s) of decreased recharge. The numerical model is a tool that could be used to better understand the flow system of the Ogallala and Arikaree aquifers, to approximate hydraulic heads in the aquifer, and to estimate discharge to rivers, springs, and seeps in the Pine Ridge Reservation area in Bennett, Jackson, and Shannon Counties. The model also is useful to help assess the response of the aquifer to additional stress, including potential increased well withdrawals and potential drought conditions.

South Dakota↗
USGS2015

Hydrogeology and simulation of groundwater flow in fractured-rock aquifers of the Piedmont and Blue Ridge Physiographic Provinces, Bedford County, Virginia

An annual groundwater budget was computed as part of a hydrogeologic characterization and monitoring effort of fractured-rock aquifers in Bedford County, Virginia, a growing 764-square-mile (mi 2 ) rural area between the cities of Roanoke and Lynchburg, Virginia. Data collection in Bedford County began in the 1930s when continuous stream gages were installed on Goose Creek and Big Otter River, the two major tributaries of the Roanoke River within the county. Between 2006 and 2014, an additional 2 stream gages, 3 groundwater monitoring wells, and 12 partial-record stream gages were operated. Hydrograph separation methods were used to compute base-flow recharge rates from the continuous data collected from the continuous stream gages. Mean annual base-flow recharge ranged from 8.3 inches per year (in/yr) for the period 1931–2012 at Goose Creek near Huddleston (drainage area 188 mi 2 ) to 9.3 in/yr for the period 1938–2012 at Big Otter River near Evington (drainage area 315 mi 2 ). Mean annual base-flow recharge was estimated to be 6.5 in/yr for the period 2007–2012 at Goose Creek at Route 747 near Bunker Hill (drainage area 125 mi 2 ) and 8.9 in/yr for the period 2007–2012 at Big Otter River at Route 221 near Bedford (drainage area 114 mi 2 ). Base-flow recharge computed from the partial-record data ranged from 5.0 in/yr in the headwaters of Goose Creek to 10.5 in/yr in the headwaters of Big Otter River. A steady-state groundwater-flow simulation for Bedford County was developed to test the conceptual understanding of flow in the fractured-rock aquifers and to compute a groundwater budget for the four major drainages: James River, Smith Mountain and Leesville Lakes, Goose Creek, and Big Otter River. Model results indicate that groundwater levels mimic topography and that minimal differences in aquifer properties exist between the Proterozoic basement crystalline rocks and Late Proterozoic-Cambrian cover crystalline rocks. The Big Otter River receives 40.8 percent of the total daily groundwater outflow from fractured-rock aquifers in Bedford County; Goose Creek receives 25.8 percent, the James River receives 18.2 percent, and Smith Mountain and Leesville Lakes receive 15.2 percent. The remaining percentage of outflow is attributed to pumping from the aquifer (consumptive use).

Virginia↗
USGS2016

Arsenic in groundwater of Licking County, Ohio, 2012—Occurrence and relation to hydrogeology

Arsenic concentrations were measured in samples from 168 domestic wells in Licking County, Ohio, to document arsenic concentrations in a wide variety of wells and to identify hydrogeologic factors associated with arsenic concentrations in groundwater. Elevated concentrations of arsenic (greater than 10.0 micrograms per liter [µg/L]) were detected in 12 percent of the wells (about 1 in 8). The maximum arsenic concentration of about 44 µg/L was detected in two wells in the same township. A subset of 102 wells was also sampled for iron, sulfate, manganese, and nitrate, which were used to estimate redox conditions of the groundwater. Elevated arsenic concentrations were detected only in strongly reducing groundwater. Almost 20 percent of the samples with iron concentrations high enough to produce iron staining (greater than 300 µg/L) also had elevated concentrations of arsenic. In groundwater, arsenic primarily occurs as two inorganic species—arsenite and arsenate. Arsenic speciation was determined for a subset of nine samples, and arsenite was the predominant species. Of the two species, arsenite is more difficult to remove from water, and is generally considered to be more toxic to humans. Aquifer and well-construction characteristics were compiled from 99 well logs. Elevated concentrations of arsenic (and iron) were detected in glacial and bedrock aquifers but were more prevalent in glacial aquifers. The reason may be that the glacial deposits typically contain more organic carbon than the Paleozoic bedrock. Organic carbon plays a role in the redox reactions that cause arsenic (and iron) to be released from the aquifer matrix. Arsenic concentrations were not significantly different for different types of bedrock (sandstone, shale, sandstone/shale, or other). However, arsenic concentrations in bedrock wells were correlated with two well-construction characteristics; higher arsenic concentrations in bedrock wells were associated with (1) shorter open intervals and (2) deeper open intervals, relative to the water level. The spatial distribution of arsenic concentrations was compared to hydrogeologic characteristics of Licking County. Elevated concentrations of arsenic (and iron) were associated with areas of flat topography and thick (greater than 100 feet),clay-rich glacial deposits. These characteristics are conducive to development of strongly reducing redox conditions, which can cause arsenic associated with iron oxyhydroxides in the aquifer matrix to be released to the groundwater. Hydrogeologic characteristics conducive to the development of strongly reducing groundwater are relatively wide-spread in the western part of Licking County, which is part of the Central Lowland physiographic province. In this area, a thick layer of clay-rich glacial deposits obscures the bedrock surface and creates flat to gently rolling landscape with poorly developed drainage networks. In the eastern part of the county, which is part of the Appalachian Plateaus physiographic province, the landscape includes steep-sided valleys and bedrock uplands. In this area, elevated arsenic concentrations were detected in buried valleys but not in the bedrock uplands, where glacial deposits are thin or absent. The observation that elevated concentrations of arsenic (and iron) were more prevalent in the western part of Licking County is true for both glacial and bedrock aquifers. In Licking County, thick, clay-rich glacial deposits (and elevated concentrations of arsenic) are associated with two hydrogeologic settings—buried valley and complex thick drift. Most wells in the buried-valley setting had low arsenic concentrations, but a few samples had very high concentrations (30–44 µg/L) and very reducing redox conditions (methanogenic and near-methanogenic). For wells in the complex-thick-drift setting, elevated arsenic concentrations are more prevalent, but the maximum concentration was lower (about 21 µg/L). Similar observations were made about arsenic concentrations in parts of southwestern Ohio. The hydrogeologic settings and characteristics associated with arsenic in Licking County also exist in other parts of Ohio. The statewide extent of these characteristics roughly corresponds to areas where elevated concentrations of arsenic are known to exist. This preliminary conceptual model can be tested and revised as additional wells are sampled for arsenic.

Ohio↗