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Recent, widespread nitrate decreases may be linked to persistent dissolved organic carbon increases in headwater streams recovering from past acidic deposition

Long-term monitoring of water quality responses to natural and anthropogenic perturbation of watersheds informs policies for managing natural resources. Dissolved organic carbon (DOC) and nitrate (NO 3 − ) in streams draining forested landscapes provide valuable information on ecosystem function due to their biogeochemical reactivity and solubility in water. Here we evaluate a 20-year record (2001−2021) of biweekly stream-water samples ( n > 3000) and continuous discharge in three forested catchments in the Adirondack region of New York to investigate and interpret long-term trends in DOC and NO 3 − concentrations. Results from the intensively monitored catchments were compared with data from synoptic surveys of streams throughout the Adirondack region. A weighted regressions on time, discharge, and season (WRTDS) model, used to estimate daily flow-normalized concentrations, determined that DOC increased by ~30 to 50 % while NO 3 − decreased by ~50 to 70 % over the study period. The large amount of data from catchments with different soil properties permitted us to assess the relative effects of hydrology, season, and land cover factors on temporal trends in DOC and NO 3 − concentrations. We found weak evidence of climatic forcing of long-term increases in DOC, and instead contend that declining ionic strength in precipitation linked to declining anthropogenic acid deposition is driving DOC trends in stream waters. Nitrate concentrations were more variable but clearly decreased in recent years possibly related to declining N deposition. The recent increase in DOC:NO 3 − in all catchments indicates a major shift in stream stoichiometry that reflects changes in ecosystem functioning that may have important biogeochemical implications for terrestrial as well as aquatic ecosystems.

Science of the Total Environment↗

Late Cretaceous inoceramid bivalves of the Kuskokwim Basin, southwestern Alaska, and their implications for basin evolution

Upper Cretaceous rocks of the Kuskokwim Group are exposed in a large region of southwestern Alaska and are mainly composed of deformed turbidite deposits that contain few fossils other than inoceramid bivalves. This paper documents the taxonomy of the inoceramids in the Kuskokwim Group, develops an inoceramid biostratigraphy based on known ranges in other regions, and analyzes biogeographic patterns, paleoecology, and depositional history of the Kuskokwim Group. Most of the inoceramid bivalves present in the Kuskokwim Group are of Cenomanian and Turonian age, and an assemblage of species typical of late Turonian age rocks is particularly well developed. Only two localities appear to be as young as Santonian age. The following 16 species or subspecies are discussed and illustrated in detail: Birostrina tamurai Matsumoto and Noda, Inoceramus virgatus Schlüter, I. pennatulus Pergament, I. pictus minus Matsumoto, I. cf. I. yabei Nagao and Matsumoto, I. ? sp. aff. I. costatus Nagao and Matsumoto, I. hobetsensis Nagao and Matsumoto, I. longealatus Tröger, I. frechi Flegel, I. waltersdorfensis waltersdorfensis Andert, I. cf. I. waltersdorfensis hannovrensis Heinz, I. kuskokwimensis n. sp., Mytiloides cf. M. opalensis (Böse), M. teraokai (Matsumoto and Noda), M. cf. M. incertus (Jimbo), and Sphenoceramus naumanni (Yokoyama). In addition, a specimen with affinities to Mytiloides striatoconcentricus carpathicus (Simionescu) and a specimen that may belong to the I. (Cremnoceramus?) rotundatus–I. ( C .) erectus lineage are illustrated. Most of the taxa present in the Kuskokwim region are found in other regions of the North Pacific, particularly Japan and eastern Siberia, or are found throughout the Northern Hemisphere. Only one species, I. kuskokwimensis n. sp., is new and may be endemic. North Pacific taxa are predominant in the Kuskokwim region, but intervals near the Cenomanian–Turonian Stage boundary and in the upper Turonian contain taxa characteristic of Europe and the Western Interior basin of North America; some of these taxa have not been recorded previously in the North Pacific region. Turonian heteromorph ammonite assemblages associated with inoceramids in the finer grained facies of the Kuskokwim region are similar to those found in coeval rocks of Japan and Germany. The depositional area of the Kuskokwim Group can be broken into two northeast-trending subbasins, the Kuskokwim River subbasin to the northwest and the Mulchatna River subbasin to the southeast, connected by the Nushagak Hills corridor. Within the Kuskokwim River subbasin, deposition apparently started earlier in the north (middle Cenomanian) than in the south (late Cenomanian to early Turonian), and prograding deltaic sedimentation along the western margin also appears to have started earlier in the north. No marine fossils younger than latest Turonian to earliest Coniacian are known from the Kuskokwim River subbasin. The youngest fossils identified are Santonian in age and are from deep-water deposits in the Nushagak Hills corridor. Few fossils are known from the Mulchatna River subbasin and age control is limited.

Journal of Paleontology↗

Modern coastal mangrove swamp stratigraphy and the ideal cyclothem

The general stratigraphy of the “ideal” cyclothem of Late Paleozoic age can be recognized in a modern succession of sedimentary units underlying the coastal mangrove swamps of southwestern Florida. Because coal deposition is associated with the formation of cyclothems, this stratigraphic similarity has geologic importance with respect to coal formation. The lower part of the succession in Florida consists of nonmarine sediments, the middle part of brackish-water or fresh-water mangrove peat, and the upper part of brackish-water and marine units. This sequence of sediments records a relative rise in sea level. In comparison, the lower part of the ideal cyclothem consists basically of nonmarine units, the central sedimentary member is coal, and the upper units are brackish-water and marine sediments. The ideal cyclothem is thought to have formed in part in a deltaic environment and to record a periodic fluctuation in terrigenous sediment supply and a relative rise in sea level. In contrast, southwestern Florida has essentially no deltas, as most of its paralic sediments are derived from coastal sources. In view of this, the stratigraphic similarity noted above must reflect a partial duplication of sedimentary environments brought about by a relative rise in sea level across a low coastal platform supporting peat-depositing paralic and fresh-water swamps and forests. This conclusion tends to support the point of view that the coal member of some cyclothems formed in a swampy environment penecontemporaneously with a relative rise in sea level. The coal member, therefore, is in part a transgressive unit.

Florida↗

Dips, ramps, and rolls- Evidence for paleotopographic and syn-depositional fault control on the Western Kentucky No. 4 coal bed, tradewater formation (Bolsovian) Illinois Basin

The Western Kentucky No. 4 coal is a high-volatile B to high-volatile C bituminous coal that has been heavily mined along the southern margin of the Western Kentucky Coal Field. The seam has a reputation for rolling floor elevation. Elongate trends of floor depressions are referred to as "dips" and "rolls" by miners. Some are relatively narrow and straight to slightly curvilinear in plan view, with generally symmetric to slightly asymmetric cross-sections. Others are broader and asymmetric in section, with sharp dips on one limb and gradual, ramp-like dips on the other. Some limbs change laterally from gradual dip, to sharp dip, to offset of the coal. Lateral changes in the rate of floor elevation dip are often associated with changes in coal thickness, and in underground mines, changes in floor elevation are sometimes associated with roof falls and haulage problems. In order to test if coal thickness changes within floor depressions were associated with changes in palynology, petrography and coal quality, the coal was sampled at a surface mine across a broad. ramp-like depression that showed down-dip coal thickening. Increment samples of coal from a thick (150 cm), down-ramp and thinner (127 cm), up-ramp position at one surface mine correlate well between sample sites (a distance of 60 m) except for a single increment. The anomalous increment (31 cm) in the lower-middle part of the thick coal bed contained 20% more Lycospora orbicula spores. The rolling floor elevations noted in the study mines are inferred to have been formed as a result of pre-peat paleotopographic depressions, syn-depositional faulting, fault-controlled pre-peat paleotopography, and from compaction beneath post-depositional channels and slumps. Although the association of thick coal with linear trends and inferred faults has been used in other basins to infer syn-depositional faulting, changes in palynology within increment samples of the seam along a structural ramp in this study provide subtle evidence of faulting within a specific increment of the coal itself. The sudden increase in L. orbicula (produced by Paralycopodites) in a single increment of a down-ramp sample of the Western Kentucky No. 4 coal records the reestablishment of a rheotrophic mire following a sudden change in edaphic conditions. Paralycopodites was a colonizing lycopod, which in this case became locally abundant after the peat was well established along a fault with obvious growth during peat accumulation. Because many coal-mire plants were susceptible to sudden edaphic changes as might accompany faulting or flooding, changes in palynology would be expected in coals affected by syn-depositional faulting. ?? 2001 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology↗

Determining the drivers of suspended sediment dynamics in tidal marsh-influenced estuaries using high-resolution ocean color remote sensing

Sediment budgets are a critical metric to assess coastal marsh vulnerability to sea-level rise and declining riverine sediment inputs. However, calculating accurate sediment budgets is challenging in tidal marsh-influenced estuaries where suspended sediment concentrations (SSC) typically vary on scales of hours and meters, and where SSC dynamics are driven by a complex and often site-specific interplay of hydrodynamic and meteorological conditions. The mapping of SSC using ocean-color remote sensing is well established and can help capture the spatio-temporal variability needed to determine the dominant drivers regulating sediment budgets. However, the coarse spatial resolution of traditional ocean-color sensors (1-km) generally precludes their use in coastal-marsh estuaries. Here, using the Plum Island Estuary (Massachusetts, USA) as an example, we demonstrate that high-spatial-resolution maps of SSC derived from Landsat-8 Operational Land Imager (OLI) and Sentinel-2A/B Multispectral Instruments (MSI) can be used to determine the main drivers of SSC dynamics in tidal marsh-influenced estuaries, despite the long revisit time of these sensors. Local empirical algorithms between SSC and remote sensing reflectance were derived and applied to a total of 46 clear-sky scenes collected by the OLI and the MSI between 2013 and 2018. The analysis revealed that this 5-year record was sufficient to capture a representative range of meteorological and tidal conditions required to determine the main drivers of SSC dynamics in this mid-latitude system. The interplay between river and tidal flows dominated SSC dynamics in this estuary, whereas wind-driven resuspension had more moderate effects. The SSC were higher during spring because of increased river discharge due to snowmelt. Tidal asymmetry also enhanced sediment resuspension during flood tides, possibly favoring deposition on marsh platforms. Together, water level, water-level rate of change, river discharge and wind speed were able to explain > 60% of the variability in the main-channel thalweg-averaged SSC, thereby facilitating future prediction of SSC from these readily available variables. This study demonstrates that the existing multi-year records of high-resolution remote sensing can provide a representative depiction of SSC dynamics in hydrodynamically-complex and small-scale estuaries that moderate-resolution ocean color remote sensing and in situ measurements are unable to capture.

Massachusetts↗

Widespread chemical dilution of streams continues as long-term effects of acidic deposition slowly reverse

Studies of recovery from acidic deposition have focused on reversal of acidification and its associated effects, but as recovery proceeds slowly, chemical dilution of surface waters is emerging as a key factor in the recovery process that has significant chemical and biological implications. This investigation uses long-term chemical records from 130 streams in the Adirondack region of New York, USA, to evaluate the role of ongoing decreases in conductance, an index of dilution, in the recovery of these streams. Stream chemistry data spanning up to 40 years (1980s–2022) showed that acid-neutralizing capacity has increased in 92% of randomly selected streams, but that harmful levels of acidification still occur in 37% of these streams. Conductance and Ca 2+ concentrations decreased in 79% of streams, and SO 4 2− concentrations in streams continued to show strong decreases but remained several times higher than concentrations in precipitation. These changes were ongoing through 2022 even though acidic deposition levels were approaching those estimated for pre-industrialization. Further dilution is continuing through ongoing decreases in stream SO 4 2− . Nevertheless, Ca 2+ continued to be leached from soils by SO 4 2− , organic acids and NO 3 − , limiting the replenishment of available soil Ca 2+ , a prerequisite to stem further dilution of stream water.

Environmental Pollution↗

Cenozoic marine geochemistry of thallium deduced from isotopic studies of ferromanganese crusts and pelagic sediments

Cenozoic records of Tl isotope compositions recorded by ferromanganese (Fe-Mn) crusts have been obtained. Such records are of interest because recent growth surfaces of Fe-Mn crusts display a nearly constant Tl isotope fractionation relative to seawater. The time-series data are complemented by results for bulk samples and leachates of various marine sediments. Oxic pelagic sediments and anoxic marine deposits can be distinguished by their Tl isotope compositions. Both pelagic clays and biogenic oozes are typically characterized by ??205Tl greater than +2.5, whereas anoxic sediments have ??205Tl of less than -1.5 (??205Tl is the deviation of the 205Tl/203Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 104). Leaching experiments indicate that the high ??205Tl values of oxic sediments probably reflect authigenic Fe-Mn oxyhydroxides. Time-resolved Tl isotope compositions were obtained from six Fe-Mn crusts from the Atlantic, Indian, and Pacific oceans and a number of observations indicate that these records were not biased by diagenetic alteration. Over the last 25 Myr, the data do not show isotopic variations that significantly exceed the range of Tl isotope compositions observed for surface layers of Fe-Mn crusts distributed globally (??205 Tl=+12.8??1.2). This indicates that variations in deep-ocean temperature were not recorded by Tl isotopes. The results most likely reflect a constant Tl isotope composition for seawater. The growth layers of three Fe-Mn crusts that are older than 25 Ma show a systematic increase of ??205Tl with decreasing age, from about +6 at 60-50 Ma to about +12 at 25 Ma. These trends are thought to be due to variations in the Tl isotope composition of seawater, which requires that the oceans of the early Cenozoic either had smaller output fluxes or received larger input fluxes of Tl with low ??205Tl. Larger inputs of isotopically light Tl may have been supplied by benthic fluxes from reducing sediments, rivers, and/or volcanic emanations. Alternatively, the Tl isotope trends may reflect the increasing importance of Tl fluxes to altered ocean crust through time. ?? 2004 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

Atmospheric deposition to forests in the eastern USA

Atmospheric mercury (Hg) deposition to forests is important because half of the land cover in the eastern USA is forest. Mercury was measured in autumn litterfall and weekly precipitation samples at a total of 27 National Atmospheric Deposition Program (NADP) monitoring sites in deciduous and mixed deciduous-coniferous forests in 16 states in the eastern USA during 2007–2014. These simultaneous, uniform, repeated, annual measurements of forest Hg include the broadest area and longest time frame to date. The autumn litterfall-Hg concentrations and litterfall mass at the study sites each year were combined with annual precipitation-Hg data. Rates of litterfall-Hg deposition were higher than or equal to precipitation-Hg deposition rates in 70% of the annual data, which indicates a substantial contribution from litterfall to total atmospheric-Hg deposition. Annual litterfall-Hg deposition in this study had a median of 11.7 μg per square meter per year (μg/m 2 /yr) and ranged from 2.2 to 23.4 μg/m 2 /yr. It closely matched modeled dry-Hg deposition, based on land cover at selected NADP Hg-monitoring sites. Mean annual atmospheric-Hg deposition at forest study sites exhibited a spatial pattern partly explained by statistical differences among five forest-cover types and related to the mapped density of Hg emissions. Forest canopies apparently recorded changes in atmospheric-Hg concentrations over time because litterfall-Hg concentrations decreased year to year and litterfall-Hg concentrations were significantly higher in 2007–2009 than in 2012–2014. These findings reinforce reported decreases in Hg emissions and atmospheric elemental-Hg concentrations during this same time period. Methylmercury (MeHg) was detected in all litterfall samples at all sites, compared with MeHg detections in less than half the precipitation samples at selected sites during the study. These results indicate MeHg in litterfall is a pathway into the terrestrial food web where it can accumulate in the prey of songbirds, bats, and raptors.

Environmental Pollution↗

The demise of an icehouse: Calibrating the end of the LPIA

Earth has experienced three complete icehouse-greenhouse turnovers in the Phanerozoic, with the Late Paleozoic Ice Age (LPIA) recognized as the last and most extreme icehouse. The nature, scale and dynamics of the LPIA are characterized by periods of intense glaciation, which are often interrupted by short-lived (1–2 Myrs) intervals associated with ice-free or distal from ice conditions. In this study, we focus on constraining the icehouse-greenhouse turnover across southcentral Gondwana (SCG) reporting new high-resolution U Pb zircon CA-ID-TIMS ages from immediate postglacial facies in the Kalahari and Karoo basins. We integrate these ages with published U Pb zircon CA-ID-TIMS ages ( n = 20) to build a stratigraphic framework for SCG, to investigate the duration and nature of the demise of the LPIA. We confirm the stepwise deglaciation of Gondwana over a ca. 20 Myr period, with deglaciation occurring first in the Paraná Basin at ca. 300 Ma and in the Karoo Basin by 282 Ma. Low-latitude marine carbonates deposited contemporaneously with the final demise of ice is characterized by a major shift towards isotopically depleted δ 13 C and δ 18 O values. We interpret the perturbations in stable isotopes records to be driven by either mantle outgassing or the release of methane and the addition of glacial melt water to the paleo-ocean during warming. The presented stratigraphic framework is built in intracratonic basins, far from any syn - tectonic affects, suggesting a largely climatic driver behind deglaciation events.

Global and Planetary Change↗

Progress report on the geology and ground-water hydrology of part of the Oahe Unit, James River Division, South Dakota

The Oahe Unit, in the James River basin in eastern South Dakota, extends for about 100 miles north and south and is 20 to 80 miles wide, having the river as its east border. The Oahe irrigation project is planned to supply water to 750,000 to 1,500,000 acres of the most suitable land within the area. The studies that have been undertaken in the Oahe area by the Ground Water Division of the U. S. Geological Survey form a part of the investigations which are being carried on by several bureaus of the Department of the Interior and other government agencies for the conservation, control and utilization of the water resources of the Missouri River Basin. The field studies on which the present report is based were made during May 1947 through November 1948 and cover about 1,890 square miles in the southern part of the Oahe area. Data were collected on the character of the surficial geological deposits, and on the occurrence, movement, quantity, and quality of the groundwater supplies. The report describes the several water-bearing formations and presents nine typical logs of deep artesian wells. The records of fluctuation of the water table in 168 wells in or near the Oahe area are listed. Tabulated inventory of 3,257 wells and springs includes information on the observation wells and on all other wells that were noted within the area examined.

South Dakota↗

Geologic Map of the Albuquerque 30' x 60' Quadrangle, North-Central New Mexico

The Albuquerque 30' x 60' quadrangle spans the Rio Grande rift between the Colorado Plateau and Great Plains geologic provinces, and includes parts of the Basin and Range and Southern Rocky Mountain physiographic provinces. Geologic units exposed in the quadrangle range in age from Early Proterozoic schist and granite to modern river alluvium. The principal geologic features of the area, however, chiefly reflect contractional folding and thrusting of the Late Cretaceous Laramide orogeny and the Neogene extension of the Rio Grande rift. Significant parts of the history of the rift in this region are displayed and documented by the geology exposed in the Albuquerque quadrangle. Post-Laramide erosion, beginning at about 60 Ma, is recorded by the Diamond Tail and Galisteo Formations (upper Paleocene and Eocene) that are preserved in the Hagan Basin and around the uplifted margins of the younger Rio Grande rift. Intermediate volcaniclastic deposits of the Espinaso Formation (upper Eocene and Oligocene) were shed in and around the contemporaneous volcanic-intrusive complexes of the Ortiz porphyry belt in the northeastern part of the quadrangle. The earliest fluvial sediments attributed to extension in the Rio Grande rift in this area are the Tanos and Blackshare Formations (upper Oligocene and Miocene) in the Hagan Basin, which indicate extension was underway by 25 Ma. Farther west, the oldest rift-filling sediments are eolian sand and interdune silty deposits of the Zia Formation (lower to middle Miocene). Major extension occurred during the Miocene, but subsidence and sedimentation were highly irregular from place to place. Parts of three rift sub-basins are known within the Albuquerque quadrangle, each basin locally as deep as about 14,000 ft, separated by less-extended zones (structural horsts) where the rift fill is much thinner. The geometry of these early, deep rift sub-basins suggests the primary extension direction was oriented northeast-southwest. Significant local folding and uplift within the complex rift seems to have occurred in the late Miocene, accompanied by erosion and recycling of earlier rift-fill sediments. This deformation may reflect clockwise reorientation of the primary extension direction to its Pliocene and current east-west alignment. Late Miocene and early Pliocene uplift and erosion were widespread in the region, as indicated by channeled and local angular unconformities at the bases of all Pliocene units, especially prominent along basin margins. These Pliocene fluvial and alluvial deposits (Ceja and Ancha Formations and Tuerto Gravel) and the upper part of the Cochiti Formation are all conspicuously coarser grained than the Miocene beds they cover, particularly near source areas along the margins of the rift. These observations together indicate that the regional streams flowed at much greater discharge than the Miocene streams and that the Pliocene onset of cooler, wetter climate worldwide was the most likely cause. Despite these higher discharge conditions, it appears there was no Pliocene trunk stream through the rift valley because the youngest Pliocene beds in the basin center are largely fine grained sand, pebbly sand, and sandy silt. No Pliocene cobble-gravel deposits, or thick crossbed sets indicative of major stream discharge, have been documented in the basin center. Considerable evidence indicates significant erosion began in late Pliocene time, coincident with and following eruption of abundant basalt from several local centers at about 2.7-2.6 Ma. The onset of central valley erosion marks the initiation of the first through-flowing, high-energy trunk stream (the 'ancestral' Rio Grande), which most likely was caused by integration of drainage southward through the Socorro region. No upper Pliocene fluvial deposits have been identified in the valley center; rather, a significant unconformity separates beds with medial (or earliest late) Blancan fauna (older than about 2.2 Ma) from

Scientific Investigations Map↗

Preliminary bedrock geologic map of the Port Henry quadrangle, Essex County, New York, and Addison County, Vermont

Introduction The bedrock geology of the 7.5-minute Port Henry quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 Ga (giga-annum). In the Port Henry quadrangle, the AMCG metaigneous rocks (Yhg, Ygb, Yanw) intruded older, mostly metasedimentary rocks of the Grenville Complex during the middle to late Shawinigan orogeny (~1,160–1,150 Ma [mega-annum]). All rocks were subsequently metamorphosed to upper amphibolite to granulite facies conditions during the 1,080–1,050 Ma Ottawan orogeny. New mapping reveals four periods of deformation: (1) D1 produced rarely preserved isoclinal folds in the paragneiss and marble and predates AMCG magmatism. (2) Subsequent D2 deformation produced the dominant gneissic fabric preserved in the rock, recumbent folding, and deformed all the Proterozoic units in the map area. Syn- to late-D2 felsic magmatism resulted in the regionally extensive Lyon Mountain Granite Gneiss, which hosts numerous magnetite ore bodies. (3) Mylonitic extensional shear zones and core complex formation marked the beginning of D3 deformation. Protracted D3 deformation resulted in F3 upright folding, dome and basin formation, pegmatite intrusion, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron-ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. (4) D4 created northeast- and northwest-trending local high-grade ductile shear zones and boudinage, northwest-trending regional kilometer (km)-wide ductile shear zones, and crosscutting granitic pegmatite dikes. The development of the late-stage regional shear zones (D4) was likely due to the continuation of extensional doming and uplift from upper amphibolite facies conditions at the end of the Ottawan orogeny. The majority of iron-ore deposits in the Port Henry and adjacent Witherbee quadrangles are in the hanging wall of these extensional shear zones. In the Port Henry quadrangle, the km-wide Cheney Mountain shear zone is the result of D4 deformation. Kilometer-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician carbonate bank on the ancient margin of Laurentia. The approximately 1-km-thick Cambrian to Ordovician stratigraphy records a transition from synrift clastics to passive-margin peritidal carbonate buildups to gradually deeper-water subtidal- to shelf-carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Open-File Report includes a bedrock geologic map; a description of map units; a correlation of map units; and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information.

New York, Vermont↗

Channel change and sediment transport in the Puyallup River watershed through 2022

The Puyallup River drains a 990 square mile watershed in western Washington, with headwaters on the glacier-covered flanks of Mount Rainier. Major tributaries include the White, Carbon, and Mowich Rivers. In the levee-confined reaches of the lower watershed, loss of flood conveyance due to sand and gravel deposition has been a chronic issue. Over much of the 20th century, flood conveyance was maintained through sediment removal, but this practice ended in the late 1990s. Flood hazard management activities since the 1990s have primarily involved levee removal or setback projects. Assessments of 1984-2009 repeat cross sections suggested that sediment deposition rates were particularly high in reaches with recent levee setbacks. However, there have been no assessments of recent deposition rates since the 2009 surveys. There are also concerns that intensifying flood hydrology or increased sediment delivery from Mount Rainier may exacerbate deposition. However, assessment of those risks has been hindered by limited understanding of watershed-scale sediment delivery and routing, particularly for coarse sand and gravel. The U.S. Geological Survey, in cooperation with Pierce County, initiated this study to improve understanding of sediment deposition in the lower Puyallup River watershed. This work is primarily based on differencing of multiple aerial lidar datasets collected during 2002–2022, supplemented by early 1990 photogrammetric elevation datasets, geomorphic assessments of streamgage data, historical topographic surveys from 1907, and previously collected sediment transport measurements. Analyses cover the Puyallup, Carbon, and Mowich Rivers, but do not include the White River. During 2004–2020, repeat aerial lidar indicates that 1.3 ± 0.3 million yd3 of sediment accumulated in the lower 20 valley miles (VMs) of the Puyallup River, averaging 80,000 ± 20,000 cubic yards per year (yd3/yr). Deposition was observed during both 2004–11 and 2011–20 lidar differencing intervals. This continued a long-term depositional trend that extends back to at least 1977. From 2004 to 2011, deposition rates along the Soldiers Home levee setback reach, the only setback project downstream of VM 20 completed prior to 2011, were approximately four times higher than in adjacent unmodified reaches. From 2011 to 2020, two additional setback projects were completed; volumetric deposition rates over all three setback reaches were similar to adjacent unmodified reaches, suggesting elevated setback deposition in the 2004–11 interval may have been influenced by an extreme flood in November 2006. These levee setback projects increased the local cross-sectional area of the floodway, used as a rough proxy for relative flood conveyance, by 50 to 200 percent above 2004 conditions. If deposition continued at recent rates, cross-sectional area over the levee setback reaches would be reduced back to 2004 values by 2050-90. Deposition also occurred over the lower six VMs of the Carbon River during 2004–20, though volumes (0.15 ± 0.09 million yd3) were an order of magnitude lower than along the Puyallup River. Relatively lower deposition rates in the Carbon River are most likely the combined result of modestly lower incoming sediment loads, modestly steeper channel slope, and the additional sediment transport capacity provided by two large non-glacial tributaries that enter the Carbon River near VM 5. Upstream of the depositional reaches described above, 2002–22 sediment storage trends along the Puyallup, Carbon, and Mowich Rivers were predominately negative (net erosion) up to the Mount Rainier National Park boundary. Net erosion was the result of bank and bluff erosion exceeding deposition across wetted channel and bare gravel areas, as opposed to uniform vertical downcutting. Net erosion along these river valleys delivered 3.4 ± 0.6 million yd3 to the river system, equivalent to 190,000 ± 35,000 yd3/yr. Most of that volume was supplied by erosion of relatively low (4–10 ft) surfaces along the Puyallup and Mowich Rivers and tall (300 ft) glacial bluffs along the lower Carbon River. Substantial aggradation from 1984 to 2009 reported by Czuba and others (2010) along reaches of the Puyallup River (VM 19–22) where levee confinement has recently been removed was most likely an artifact of methodologic bias. The Puyallup, Mowich, and Carbon Rivers drain five distinct glaciated watersheds on the flanks of Mount Rainier, four of which were assessed in this study. All four watersheds were impacted by an extreme November 2006 rainstorm. Between 2002 and 2008, debris flows occurred in all four headwater areas, collectively eroding at least 2.1 million yd3 of sediment. These debris flows formed distinct deposits one to two miles downstream of source areas, depositing 30-50 percent of the material eroded upstream. From 2008 to 2022, no headwater debris flows were observed and overall rates of geomorphic change in the headwaters were low. Rivers eroded into debris flow deposits emplaced over the 2002–08 interval, but re-deposited equivalent volumes of material within a half mile downstream. Stage-discharge relations at five streamgages on upland rivers draining Mount Rainier show either net channel incision or dynamic variability with no long-term trend over the past 60–100 years. Observations of pervasive river valley erosion and stable or incising trends at long-term streamgages in the upper watershed do not support prior claims of widespread and accelerating aggradation of upland rivers draining Mount Rainier. Erosion and deposition volumes estimated in this report were combined with sediment transport estimates from limited suspended sediment and bedload measurements, estimates of sub-glacial erosion rates, and sediment delivery from non-glacial tributaries to construct watershed-scale sediment budgets for the Puyallup River watershed. During 2004–20, the estimated sediment load entering the depositional lowlands was well balanced by estimated inputs from, in order of relative magnitude, subglacial erosion (33–60 percent of total sediment load), erosion along the major river valleys (25–45 percent), erosion in recently deglaciated headwater areas (7–17 percent) and non-glacial tributaries (3–9 percent). These results are specific to the study period and represent total sediment loads, most of which is fine material carried in suspension. The relative sourcing of sand and gravel may be different than implied by this sediment budget. Downstream of VM 12, comparison of 1907 and 2009 channel surveys show net lowering of the channel thalweg of 4–12 ft. A long-term gage near VM 22 shows lowering of 4–5 ft through the 1960s. Lowering at both locations was inferred to be a channel response to the substantial straightening, and so steepening, of the river during major phases of levee construction through the early and mid-20th century. Application of a simple empirical bedload-discharge power-law relation to an ensemble of model-estimated daily mean discharge records in the lower Puyallup River between 1977 and 2100 projects that annual bedload transport capacity in the lower Puyallup River will increase by 20–60 percent by the middle of the 21st century. Actual changes in bedload transport and deposition rates will depend on concurrent changes in sediment supply and local hydraulics governing deposition. This report presents several key conclusions. First, the persistence and spatial patterns of sand and gravel deposition along the lower Puyallup River support prior claims that deposition is fundamentally caused by decreases in channel slope moving downstream. Given this underlying cause and the abundance of sand and gravel available to be transported downstream, deposition is likely to continue for the foreseeable future. Second, despite continued sediment deposition, recent levee setback projects in the lower Puyallup River will likely provide several decades of flood conveyance benefits relative to a no-action alternative. Third, while the rivers linking Mount Rainier to the Puget Sound lowlands have often been discussed as conduits that either pass or accumulate sediment from Mount Rainier, observations from 2002–22 show these river valleys acting as substantial sediment sources, delivering three times more sediment than recently deglaciated headwater areas on Mount Rainier. While the persistence and underlying cause of recent river valley erosion remain unknown, sediment storage dynamics along these river valleys are likely to be a major control on sand and gravel delivery to the lower watershed.

EarthArXiv↗

Application of ground-penetrating radar to investigation of near-surface fault properties in the San Francisco Bay region

In many geologic environments, ground-penetrating radar (GPR) provides high-resolution images of near-surface Earth structure. GPR data collection is nondestructive and very economical. The scale of features detected by GPR lies between those imaged by high-resolution seismic reflection surveys and those exposed in trenches and is therefore potentially complementary to traditional techniques for fault location and mapping. Sixty-two GPR profiles were collected at 12 sites in the San Francisco Bay region. Results show that GPR data correlate with large-scale features in existing trench observations, can be used to locate faults where they are buried or where their positions are not well known, and can identify previously unknown fault segments. The best data acquired were on a profile across the San Andreas fault, traversing Pleistocene terrace deposits south of Olema in Marin County; this profile shows a complicated multi-branched fault system from the ground surface down to about 40 m, the maximum depth for which data were recorded.

California↗

Geologic map of the Vigo NE quadrangle, Lincoln County, Nevada

This map of the Vigo NE quadrangle, Lincoln County, Nevada records the distribution, stratigraphy, and structural relationships of Tertiary intracaldera lavas and tuffs in the southeastern part of the Kane Springs Wash caldera, extracaldera Tertiary and upper Paleozoic rocks, and late Cenozoic surficial deposits both within and outside the caldera. The alkaline to peralkaline Kane Springs Wash caldera is the youngest (14 Ma) of three chemically related metaluminous to peralkaline calderas (Boulder Canyon caldera, 15 Ma; Narrow Canyon caldera, 16 Ma) of the nested Kane Springs Wash caldera complex. The chemistry of this caldera complex became progressively more alkalic with time, in contrast to the older calc-alkalic calderas and caldera complexes to the north that migrated progressively southward in eastern Nevada. The increasingly peralkaline eruptions from the Kane Springs Wash caldera complex reached a climax that was simultaneous with the end of both rapid extension and magmatism in this part of the Basin and Range. Using the assumption that degree of tilting is related to the degree of extension, the rate of extension increased until the abrupt halt at about 14 Ma. Silicic volcanism terminated at the Kane Springs Wash caldera followed only by local sporadic basaltic eruptions that ended by about 8 Ma. The northern boundary of an east-west-trending amagmatic corridor appears in the Vigo NE quadrangle south of the Kane Springs Wash caldera.

Scientific Investigations Map↗

Landslides in the western Columbia Gorge, Skamania County, Washington

Summary Recent light detection and ranging (lidar) imagery has allowed us to identify and map a large number of previously unrecognized landslides, or slides, in heavily forested terrain in the western Columbia Gorge, Skamania County, Washington, and it has revealed that the few previously recognized areas of instability are actually composites of multiple smaller landslides. The high resolution of the imagery further reveals that landslides in the map area have complex movement histories and span a wide range of relative ages. Movement histories are inferred from relative landslide locations and crosscutting relations of surface features. Estimated age ranges are based on (1) limited absolute dating; (2) relative fineness of landscape surface textures, calibrated by comparison with surfaces of currently active and dated landslides as interpreted from interferometric synthetic aperture radar (InSAR), global positioning system (GPS), and historical records; (3) sharpness and steepness of larger-scale surface morphologic features, calibrated by comparison with similar dated features in other regions; (4) degree of surface erosion; and (5) evidence of erosion or deposition by late Pleistocene (15–22 ka) Missoula floods at or below 200 m altitude. The relative age categories are recent (0 to ~1,000 years old), intermediate-age (~1,000 to ~15,000 years old), and old (>~15,000 years old). Within the 221.5 km 2 map area, we identified 215 discrete landslides, covering 140.9 km 2 (64 percent of the map area). At least 12 of the recent landslides are currently moving or have moved within the last two decades. Mapping for this study expanded the area of previously recognized unstable terrain by 56 percent. Landslide geometries suggest that more than half (62 percent) of these slope failures are translational landslides or composite landslides with translational elements, with failure occurring along gently sloping bedding planes in zones of deeply weathered, locally clay rich volcaniclastic sedimentary units. Approximately two-thirds of the mapped landslide area comprises landslides that have remobilized parts of older slides, and 37 percent of these reactivated slides have involved reactivation of material from two or more older slides. The largest two recent landslides have volumes ≈1 km 3 and runouts ≈6 km. One of these, the Bonneville landslide, temporarily dammed the Columbia River almost 600 years ago, and subsequent dam-break flooding inundated downstream areas. The other, the Red Bluffs landslide, slid into the river adjacent to the Bonneville landslide but apparently did not form a landslide dam. Another such landslide rapidly sliding into the Columbia River today could have a catastrophic impact on downstream communities and on the transportation and energy-distribution infrastructure of the Pacific Northwest.

Washington↗

Alluvial diamond resource potential and production capacity assessment of Mali

In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflictual concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. Over 70 countries were included as members of the KPCS at the end of 2007. To prevent trade in "conflict diamonds" while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was (1) to assess the naturally occurring endowment of diamonds in Mali (potential resources) based on geological evidence, previous studies, and recent field data and (2) to assess the diamond-production capacity and measure the intensity of mining activity. Several possible methods can be used to estimate the potential diamond resource. However, because there is generally a lack of sufficient and consistent data recording all diamond mining in Mali and because time to conduct fieldwork and accessibility to the diamond mining areas are limited, four different methodologies were used: the cylindrical calculation of the primary kimberlitic deposits, the surface area methodology, the volume and grade approach, and the content per kilometer approach. Approximately 700,000 carats are estimated to be in the alluvial deposits of the Kenieba region, with 540,000 carats calculated to lie within the concentration grade deposits. Additionally, 580,000 carats are estimated to have been released from the primary kimberlites in the region. Therefore, the total estimated diamond resources in the Kenieba region are thought to be nearly 1,300,000 carats. The Bougouni zones are estimated to have 1,000,000 carats with more than half, 630,000 carats, contained in concentrated deposits. When combined, the Kenieba and Bougouni regions of Mali are estimated to be host to 2,300,000 carats of diamonds.

Scientific Investigations Report↗

Field performance of an acoustic scour-depth monitoring system

The Herbert C. Bonner Bridge over Oregon Inlet serves as the only land link between Bodie and Hatteras Islands, part of the Outer Banks of North Carolina. Periodic soundings over the past 30 years have documented channel migration, local scour, and deposition at several pilings that support the bridge. In September 1992, a data-collection system was installed to permit the off-site monitoring of scour at 16 bridge pilings. The system records channel-bed elevations at 15-minute intervals and transmits the data to a satellite receiver. A cellular phone connection also permits downloading and reviewing of the data as they are being collected. A digitally recording, acoustic fathometer is the main component of the system. In November 1993, current velocity, water-surface elevation, wave characteristics, and water temperature measuring instruments were also deployed at the site. Several performance problems relating to the equipment and to the harsh marine environment have not been resolved, but the system has collected and transmitted reliable scour-depth and water-level data.

Conference Paper↗