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Wetlands in intermittently closed estuaries can build elevations to keep pace with sea-level rise

Sea-level rise is a threat to coastal ecosystems, which have important conservation and economic value. While marsh response to sea-level rise has been well characterized for perennially open estuaries, bar-built intermittently-closed estuaries and their sea-level rise response are seldom addressed in the literature – despite being common globally. We seek to advance the conceptual understanding of sea-level rise response of marshes by incorporating the unique nature of intermittently-closed estuaries in a marsh model. We hypothesize that intermittently-closed-estuary marshes may be more resilient to sea-level rise than open-estuary marshes due to greater initial elevation capital and higher accretion rates due to closure events. Using California, USA as a case study, spatial analysis shows that marshes in intermittently-closed-estuaries had significantly greater elevations (x̄ = 1.93 m ± 0.2 standard error, n = 14) than marshes in permanently open estuaries (x̄ = 0.94 m ± 0.1 standard error, n = 8; P = 0.003). We then used a process-based model to determine marsh elevation change under 840 simulated responses to sea-level rise to 2100. Our modeling shows that regular annual mouth closure can promote accretion rates and increase marsh elevations fast enough to match even high rates of sea-level rise, as fluvial sediment pulses can be captured in the estuary. Modeled suspended sediment concentration had the strongest effect on accretion, followed by probability of annual mouth closure. Intermittently closed estuaries are critical environments where marshes may be sustained under high rates of sea-level rise, thus reducing the anticipated global loss of these important ecosystems. Our results begin to fill an important gap in the knowledge about marsh accretion and identify research needs to inform coastal management.

Estuarine, Coastal and Shelf Science↗

Integrating adaptive management and ecosystem services concepts to improve natural resource management: Challenges and opportunities

Executive Summary—Overview Natural resource managers must make decisions that affect broad-scale ecosystem processes involving large spatial areas, complex biophysical interactions, numerous competing stakeholder interests, and highly uncertain outcomes. Natural and social science information and analyses are widely recognized as important for informing effective management. Chief among the systematic approaches for improving the integration of science into natural resource management are two emergent science concepts, adaptive management and ecosystem services. Adaptive management (also referred to as “adaptive decision making”) is a deliberate process of learning by doing that focuses on reducing uncertainties about management outcomes and system responses to improve management over time. Ecosystem services is a conceptual framework that refers to the attributes and outputs of ecosystems (and their components and functions) that have value for humans. This report explores how ecosystem services can be moved from concept into practice through connection to a decision framework—adaptive management—that accounts for inherent uncertainties. Simultaneously, the report examines the value of incorporating ecosystem services framing and concepts into adaptive management efforts. Adaptive management and ecosystem services analyses have not typically been used jointly in decision making. However, as frameworks, they have a natural—but to date underexplored—affinity. Both are policy and decision oriented in that they attempt to represent the consequences of resource management choices on outcomes of interest to stakeholders. Both adaptive management and ecosystem services analysis take an empirical approach to the analysis of ecological systems. This systems orientation is a byproduct of the fact that natural resource actions affect ecosystems—and corresponding societal outcomes—often across large geographic scales. Moreover, because both frameworks focus on resource systems, both must confront the analytical challenges of systems modeling—in terms of complexity, dynamics, and uncertainty. Given this affinity, the integration of ecosystem services analysis and adaptive management poses few conceptual hurdles. In this report, we synthesize discussions from two workshops that considered ways in which adaptive management approaches and ecosystem service concepts may be complementary, such that integrating them into a common framework may lead to improved natural resource management outcomes. Although the literature on adaptive management and ecosystem services is vast and growing, the report focuses specifically on the integration of these two concepts rather than aiming to provide new definitions or an indepth review or primer of the concepts individually. Key issues considered include the bidirectional links between adaptive decision making and ecosystem services, as well as the potential benefits and inevitable challenges arising in the development and use of an integrated framework. Specifically, the workshops addressed the following questions: How can application of ecosystem service analysis within an adaptive decision process improve the outcomes of management and advance understanding of ecosystem service identification, production, and valuation? How can these concepts be integrated in concept and practice? What are the constraints and challenges to integrating adaptive management and ecosystem services? And, should the integration of these concepts be moved forward to wider application—and if so, how?

Circular↗

Research to improve ShakeAlert earthquake early warning products and their utility

Earthquake early warning (EEW) is the rapid detection of an earthquake and issuance of an alert or notification to people and vulnerable systems likely to experience potentially damaging ground shaking. The level of ground shaking that is considered damaging is defined by the specific application; for example, manufacturing equipment may experience damage at a lower intensity ground shaking than would cause damage to a building. Along the West Coast of the United States, the warning times for ground shaking could range as high as tens of seconds for moderate levels of ground shaking, or potentially longer, if a lower ground-shaking threshold is used to issue alerts. However, it is not always possible to provide advance warning of ground shaking, particularly for locations close to an earthquake that are most likely to experience very strong ground shaking. EEW alerts may be useful to individuals who can use a few seconds to move to a safe zone and to electromechanical systems that can take automatic actions to reduce damage and injuries. An EEW system, ShakeAlert, has been under development in the United States since 2006. Federal and State governments, as well as the private sector, are now investing in the ShakeAlert prototype system that will, when completed, become an operational public system for the West Coast of the United States. While the current prototype is delivering alerts to test users, improvements to the accuracy, timeliness, and utility of the alerts are needed. For this reason, it is essential that the ShakeAlert system be continuously improved through targeted research, involving not only the current ShakeAlert partner organizations, but also the broader scientific, engineering, and emergencyresponse communities. To this end, this report describes the opportunities for improvement that can be addressed through research and development over the next 5 years. Our recommendations are organized into four areas: (1) understand EEW capabilities and user needs, (2) make alerts as fast and accurate as possible, (3) ensure reliability when it counts, and (4) explore the use of new instrumentation. The first challenge is to understand EEW capabilities and user needs. EEW must deliver actionable information to people and to automated systems to mitigate short- and longterm impacts of damaging ground shaking, so development of EEW must be motivated by the needs of users. Within this challenge, we must study the technical capabilities and limitations of EEW in general, and the ShakeAlert system specifically. This includes development of performance metrics that assess the timeliness and accuracy of alerts to understand the value and utility of the ShakeAlert EEW product(s) for various user groups, including different industry sectors, emergency-management agencies, and the public. Research is needed to define the alerting choices that maximize the utility of the system for users and to determine what the available communication pathways are for providing timely alert information. Additionally, we engage users to assess how alerts will be used by different sectors to mitigate losses and to inform EEW product design. Further, social-science research is needed to develop alert messaging, including what relevant prior and follow-up information are required, to ensure effective use of alerts. The second challenge is to make alerts as fast and as accurate as possible. The timeliness and accuracy of an EEW alert is important because it will set in motion a series of actions and downstream products. An EEW alert will trigger notification across emergency-alert systems and across multiple communication channels to populations in impacted regions. The EEW alert region may grow as the earthquake fault-rupture length increases, and the EEW system’s characterization of it, evolves. We must continue research into new or improved seismic and geodetic waveform-processing methods necessary to rapidly characterize the expected ground shaking and associated uncertainties. It is important to thoroughly evaluate whether new methods improve alerts through more accurate ground-motion estimates and (or) reduced latencies (that is, longer warning times). New methods could include tracking the extent of a large rupture in real time (known as finite-fault algorithms) and ground-motionbased EEW algorithms. Additionally, ground motion predictions could be optimized for each earthquake as the earthquake fault rupture progresses by using, for example, event terms to shift ground-motion curves for more (or less) energetic ruptures. The third challenge is to ensure reliability when it counts. This challenge requires us to explore approaches that assess the expected performance of ShakeAlert across the range of earthquake magnitudes, locations, and depths that may occur within the alerting region. Large, damaging earthquakes and their associated aftershock sequences matter most for hazard and for EEW, but these large-earthquake sequences occur infrequently. We expect ShakeAlert to respond robustly to these large-earthquake sequences despite potentially long periods of relative seismic quiescence in the intervening years, and in spite of inevitable communication challenges that arise during and after a large earthquake. We must develop methods to utilize the broadest available datasets to test EEW performance, including ground-motion data recorded in other parts of the world. The observational period for large, damaging earthquakes in any particular region has been short in comparison to estimated large-earthquake recurrence times. Ground-motion records for very large, damaging western United States events and major aftershock sequences do not yet exist, nor do data exist for all potential sources of noise and spurious signals that ShakeAlert must be “tuned” to reject. In addition, robust synthetic data could provide the flexibility to test a wider range of earthquake magnitude, tectonic-setting, and noise scenarios than are covered by existing observational data. Synthetic ground-motion data must be thoroughly vetted against records of smaller magnitude earthquakes to ensure that they accurately capture both the onset and the amplitude of the ground shaking. The final challenge is to explore the use of new instrumentation. The development of EEW around the world to date has focused on the use of high-quality, scientific-grade seismic and geodetic instrumentation. The use of additional types of instrumentation or information may also improve EEW products by filling gaps in sensor coverage in countries that already have dense seismic networks or enable EEW in countries without such networks. We must keep up with these developments and continuously assess their value in supplementing existing EEW systems, such as ShakeAlert, or enabling EEW where such systems do not exist. Such developments include low-cost instrumentation with microelectromechanical system (MEMS) sensors and global positioning system (GPS)/global navigation satellite system (GNSS) antennas embedded in low-cost consumer electronics, sea-floor seismometers, geodetic instrumentation deployed along the Cascadia and Alaska megathrust margins of western North America, and borehole strainmeters that are already deployed across the region.

Open-File Report↗

Stress changes ahead of an advancing tunnel

Instrumentation placed ahead of three model tunnels in the laboratory and ahead of a crosscut driven in a metamorphic rock mass detected stress changes several tunnel diameters ahead of the tunnel face. Stress changes were detected 4 diameters ahead of a model tunnel drilled into nearly elastic acrylic, 2·50 diameters ahead of a model tunnel drilled into concrete, and 2 diameters ahead of a model tunnel drilled into Silver Plume Granite. Stress changes were detected 7·50 diameters ahead of a crosscut driven in jointed, closely foliated gneisses and gneissic granites in an experimental mine at Idaho Springs, Colorado. These results contrast markedly with a theoretical elastic estimate of the onset of detectable stress changes at 1 tunnel diameter ahead of the tunnel face. A small compressive stress concentration was detected 2 diameters ahead of the model tunnel in acrylic, 1.25 diameters ahead of the model tunnel in concrete, and 1 diameter ahead of the model tunnel in granite. A similar stress peak was detected about 6 diameters ahead of the crosscut. No such stress peak is predicted from elastic theory. The 3-dimensional in situ stress determined in the field demonstrate that geologic structure controls stress orientations in the metamorphic rock mass. Two of the computed principal stresses are parallel to the foliation and the other principal stress is normal to it. The principal stress orientations vary approximately as the foliation attitude varies. The average horizontal stress components and the average vertical stress component are three times and twice as large, respectively, as those predicted from the overburden load. An understanding of the measured stress field appears to require the application of either tectonic or residual stress components, or both. Laboratory studies indicate the presence of proportionately large residual stresses. Mining may have triggered the release of strain energy, which is controlled by geologic structure.

Colorado↗

Measured efficacy, bioaccumulation, and leaching of a transfluthrin-based insecticidal paint: A case study with a nuisance, nonbiting aquatic insect

BACKGROUND Pest management professionals will require a diverse, adaptive abatement toolbox to combat advanced challenges from disease vector and nuisance insect populations. Designed for post-application longevity, insecticidal paints offer extended residual effects on targeted insect pest populations; a measured understanding of active ingredient bioavailability over time is valuable to fully assess treatment efficacy and potential environmental risks. This study was initiated because a nuisance net-spinning caddisfly, Smicridea fasciatella , is lowering the quality of life for riverfront residents at the type locality. RESULTS We tested the efficacy and potential mobility of a transfluthrin-based paint (a.i. 0.50%), comparing the impacts of UV exposure and substrate texture over time. Direct UV exposure decreased efficacy (β ± S.E. = 0.008 ± 0.001, P < 0.001) and a coarse texture maintained greater efficacy (β ± S.E. = −3.7 ± 1.3, P = 0.004) over time. Notably, the coarse texture + indirect UV treatment maintained 100% mortality after 240 days. UV exposure and substrate texture did not have a significant impact on leachate concentrations over time, and successive immersion tests indicated a two-phase emission pattern. Bioaccumulation increased with time on the cuticle of dead adult S. fasciatella ; after 24 h of direct exposure the concentration of transfluthrin was 25.3 ± 0.9 ng/caddisfly with a maximum concentration of 345 ng/caddisfly after 7 days. CONCLUSION Our predictions were validated with measured, time-dependent impacts on efficacy, leachability, and bioaccumulation. Because of the mobility of active ingredient in the environment, insecticidal paints merit low-impact protocols to improve public health outcomes and environmental safety. © 2022 Society of Chemical Industry.

Pest Management Science↗

Seasonal flows of international British Columbia-Alaska rivers: The nonlinear influence of ocean-atmosphere circulation patterns

The northern portion of the Pacific coastal temperate rainforest (PCTR) is one of the least anthropogenically modified regions on earth and remains in many respects a frontier area to science. Rivers crossing the northern PCTR, which is also an international boundary region between British Columbia, Canada and Alaska, USA, deliver large freshwater and biogeochemical fluxes to the Gulf of Alaska and establish linkages between coastal and continental ecosystems. We evaluate interannual flow variability in three transboundary PCTR watersheds in response to El Ni&ntilde;o-Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), Arctic Oscillation (AO), and North Pacific Gyre Oscillation (NPGO). Historical hydroclimatic datasets from both Canada and the USA are analyzed using an up-to-date methodological suite accommodating both seasonally transient and highly nonlinear teleconnections. We find that streamflow teleconnections occur over particular seasonal windows reflecting the intersection of specific atmospheric and terrestrial hydrologic processes. The strongest signal is a snowmelt-driven flow timing shift resulting from ENSO- and PDO-associated temperature anomalies. Autumn rainfall runoff is also modulated by these climate modes, and a glacier-mediated teleconnection contributes to a late-summer ENSO-flow association. Teleconnections between AO and freshet flows reflect corresponding temperature and precipitation anomalies. A coherent NPGO signal is not clearly evident in streamflow. Linear and monotonically nonlinear teleconnections were widely identified, with less evidence for the parabolic effects that can play an important role elsewhere. The streamflow teleconnections did not vary greatly between hydrometric stations, presumably reflecting broad similarities in watershed characteristics. These results establish a regional foundation for both transboundary water management and studies of long-term hydroclimatic and environmental change.

Alaska, British Columbia↗

Molluscan phylogeny: The paleontological viewpoint

Stasek theorized that the extant mollusks are the progeny of three separate lineages that separated before the phylum was well established. He wrote that no known intermediate forms, fossil or living, bridge the "enormous gaps between any two of the three lineages," and therefore treated each as a separate subphylum. These subphyla are (i) the subphylum Aculifera Hatscheck 1891, containing only the class Aplacophora, derived from the most primitive ancestors of the Mollusca; (ii) the subphylum Placophora von Jhering 1876, containing only the class Polyplacophora, and emphasizing the pseudometamerism of its more advanced premollusk ancestor; and (iii) the subphylum Conchifera Gegenbaur 1878, containing the Monoplacophora and the other classes derived from it. We point out that the Polyplacophora may be derived from the Monoplacophora instead of a more primitive ancestral stock. We also suggest that the Conchifera can be separated into two major lineages, each worthy of the rank of subphylum. The fossil record indicates that the Monoplacophora gave rise to the Gastropoda, Cephalopoda, Rostroconchia, and possibly Polyplacophora, and that the Pelecypoda and Scaphopoda are derived from the Rostroconchia. These last three classes thus form a lineage that diverged from the Monoplacophora in the Early Cambrian. They emphasized a shell form that in all groups is primitively open at both ends, allowing the gut to remain relatively straight, with an anterior mouth and posterior anus. They became burrowing (infaunal) deposit or filter feeders. We coin the term Diasoma (through-body) for the subphylum containing these three classes (Rostroconchia, Pelecypoda, and Scaphopoda). The remaining three classes (Monoplacophora, Gastropoda, and Cephalopoda) emphasize a conical univalved shell, usually twisted into a spiral. The relatively small single aperture forces the anus to lie close to the mouth, and the gut is bent into a "U." Most are surface-dwelling (epifaunal) grazers or carnivores. We coin the name Cyrtosoma (hunchback-body) for the subphylum containing these three classes. Strictly speaking, the cyrtosomes are the ancestors of the diasomes but, in fact, both subphyla appeared and began to diversify within a few million years in the Early Cambrian.

Science↗

A long-term geothermal observatory across subseafloor gas hydrates, IODP Hole U1364A, Cascadia accretionary prism

We report 4 years of temperature profiles collected from May 2014 to May 2018 in Integrated Ocean Drilling Program Hole U1364A in the frontal accretionary prism of the Cascadia subduction zone. The temperature data extend to depths of nearly 300 m below seafloor (mbsf), spanning the gas hydrate stability zone at the location and a clear bottom-simulating reflector (BSR) at ∼230 mbsf. When the hole was drilled in 2010, a pressure-monitoring Advanced CORK (ACORK) observatory was installed, sealed at the bottom by a bridge plug and cement below 302 mbsf. In May 2014, a temperature profile was collected by lowering a probe down the hole from the ROV ROPOS. From July 2016 through May 2018, temperature data were collected during a nearly two-year deployment of a 24-thermistor cable installed to 268 m below seafloor (mbsf). The cable and a seismic-tilt instrument package also deployed in 2016 were connected to the Ocean Networks Canada (ONC) NEPTUNE cabled observatory in June of 2017, after which the thermistor temperatures were logged by Ocean Networks Canada at one-minute intervals until failure of the main ethernet switch in the integrated seafloor control unit in May 2018. The thermistor array had been designed with concentrated vertical spacing around the bottom-simulating reflector and two pressure-monitoring screens at 203 and 244 mbsf, with wider thermistor spacing elsewhere to document the geothermal state up to seafloor. The 4 years of data show a generally linear temperature gradient of 0.055°C/m consistent with a heat flux of 61–64 mW/m 2 . The data show no indications of thermal transients. A slight departure from a linear gradient provides an approximate limit of ∼10 −10 m/s for any possible slow upward advection of pore fluids. In-situ temperatures are ∼15.8°C at the BSR position, consistent with methane hydrate stability at that depth and pressure.

Cascadia subduction zone↗

Cosmogenic exposure-age chronologies of Pinedale and Bull Lake glaciations in greater Yellowstone and the Teton Range, USA

We have obtained 69 new cosmogenic 10Be surface exposure ages from boulders on moraines deposited by glaciers of the greater Yellowstone glacial system and Teton Range during the middle and late Pleistocene. These new data, combined with 43 previously obtained 3He and 10Be ages from deposits of the northern Yellowstone outlet glacier, establish a high-resolution chronology for the Yellowstone-Teton mountain glacier complexes. Boulders deposited at the southern limit of the penultimate ice advance of the Yellowstone glacial system yield a mean age of 136??13 10Be ka and oldest ages of ???151-157 10Be ka. These ages support a correlation with the Bull Lake of West Yellowstone, with the type Bull Lake of the Wind River Range, and with Marine Isotope Stage (MIS) 6. End moraines marking the maximum Pinedale positions of outlet glaciers around the periphery of the Yellowstone glacial system range in age from 18.8??0.9 to 16.5??1.4 10Be ka, and possibly as young as 14.6??0.7 10Be ka, suggesting differences in response times of the various ice-cap source regions. Moreover, all dated Pinedale terminal moraines in the greater Yellowstone glacial system post-date the Pinedale maximum in the Wind River Range by ???4-6 kyr, indicating a significant phase relationship between glacial maxima in these adjacent ranges. Boulders on the outermost set and an inner set of Pinedale end moraines enclosing Jenny Lake on the eastern Teton front yield mean ages of 14.6??0.7 and 13.5??1.1 10Be ka, respectively. The outer Jenny Lake moraines are partially buried by outwash from ice on the Yellowstone Plateau, hence their age indicates a major standstill of an expanded valley glacier in the Teton Range prior to the Younger Dryas, followed closely by deglaciation of the Yellowstone Plateau. These new glacial chronologies are indicative of spatially variable regional climate forcing and temporally complex patterns of glacier responses in this region of the Rocky Mountains during the Pleistocene. ?? 2008 Elsevier Ltd. All rights reserved.

Quaternary Science Reviews↗

Effect of land cover type on 3D deformation recovery from synthetically deformed high-resolution satellite optical imagery

The limits of detection for earthquake surface deformation in the spatial domain have improved with advances in remote sensing imagery data availability, resolution, and analysis. Sub-pixel correlation and digital elevation model (DEM) differencing from sub-meter, earthquake-spanning satellite optical imagery has enhanced surface rupture mapping and deformation measurements. However, knowledge of measurement accuracy and uncertainty is limited. To address this, we construct orthophotos and digital elevation models (DEMs) from repeat high resolution (∼0.5 m) satellite optical imagery along two sections of the Garlock fault, California with clear fault geomorphology and differing land cover. We deform later sets of DEMs and images with synthetic earthquakes containing both diffuse and discrete horizontal and vertical displacements. Sub-pixel image correlation and DEM differencing demonstrate how vegetation degrades recovered displacement accuracy. In barren land cover, horizontal displacements are detectable to an expected ∼1/10th-pixel size. With shrubs, trees, and grass, detectable displacements increase to >1/2-pixel size, and filtering results by correlation score and using elevation values as input rather than image values improves accuracy. Vertical displacement detection thresholds remain lower in vegetation, at >1-pixel size. Higher slope angles degrade displacement recovery, worsened by vegetation. Diminishing seasonal separation improves accuracy over vegetated regions, though not to the level achieved in barren environments. These results will inform research and operational efforts on the utility of high resolution satellite optical imagery for detecting deformation in varied land cover. Furthermore, they reveal where alternative measurements, such as from LiDAR or radar interferometry, are required to mitigate the effects of vegetation and capture fine-scale crustal deformation.

California↗

Potential pollutant sources in a Choptank River (USA) subwatershed and the influence of land use and watershed characteristics

Row-crop and poultry production have been implicated as sources of water pollution along the Choptank River, an estuary and tributary of the Chesapeake Bay. This study examined the effects of land use, subwatershed characteristics, and climatic conditions on the water quality parameters of a subwatershed in the Choptank River watershed. The catchments within the subwatershed were defined using advanced remotely-sensed data and current geographic information system processing techniques. Water and sediment samples were collected in May&ndash;October 2009 and April&ndash;June 2010 under mostly baseflow conditions and analyzed for select bacteria, nitrate-N, ammonium-N, total arsenic, total phosphorus (TP), orthophosphate (ortho-P), and particle-phase phosphorus (PP); n = 96 for all analytes except for arsenic, n = 136, and for bacteria, n = 89 (aqueous) and 62 (sediment). Detections of Enterococci and Escherichia coli concentrations were ubiquitous in this subwatershed and showed no correlation to location or land use, however larger bacterial counts were observed shortly after precipitation. Nitrate-N concentrations were not correlated with agricultural lands, which may reflect the small change in percent agriculture and/or the similarity of agronomic practices and crops produced between catchments. Concentration data suggested that ammonia emission and possible deposition to surface waters occurred and that these processes may be influenced by local agronomic practices and climatic conditions. The negative correlation of PP and arsenic concentrations with percent forest was explained by the stronger signal of the head waters and overland flow of particulate phase analytes versus dissolved phase inputs from groundwater. Service roadways at some poultry production facilities were found to redirect runoff from the facilities to neighboring catchment areas, which affected water quality parameters. Results suggest that in this subwatershed, catchments with poultry production facilities are possible sources for arsenic and PP as compared to catchment areas where these facilities were not present.

Choptank River↗

Estimation of nonlinear water-quality trends in high-frequency monitoring data

Recent advances in high-frequency water-quality sensors have enabled direct measurements of physical and chemical attributes in rivers and streams nearly continuously. Water-quality trends can be used to identify important watershed-scale changes driven by natural and anthropogenic influences. Statistical methods to estimate trends using high-frequency data are lacking. To address this gap, an evaluation of the generalized additive model (GAM) approach to test for trends in high-frequency data was conducted. Our proposed framework includes methods for handling serial correlation, trend estimation and slope-change detection, and trend interpretation at arithmetic scale for log-transformed variables. Water-temperature and turbidity data, representing two analytes with different temporal patterns, collected from the James River at Cartersville, Virginia, USA, were chosen for this analysis. Results indicated that the model, including flow, season, time covariates, and interaction between flow and season performed well for both analytes. The same model structure was applied to specific conductance data, collected from a small highly urbanized watershed, with satisfactory model performance. The water temperature GAM results indicated that the significant decreasing-then-increasing patterns after 2012 were mainly driven by air temperature changes. The turbidity trend was not significant over time. The specific conductance results showed a consistently upward trend over the last decade due to ever-increasing urbanization in the small watershed. This study suggests that the GAM method has great potential as a useful tool for trend analysis on high-frequency data, and for informing watershed managers of hydro-climatic and human influences on water quality by detecting crucial signal variation over time.

Chesapeake Bay watershed↗

Evaluating the adequacy of a reference site pool for ecological assessments in environmentally complex regions

Many advances in the field of bioassessment have focused on approaches for objectively selecting the pool of reference sites used to establish expectations for healthy waterbodies, but little emphasis has been placed on ways to evaluate the suitability of the reference-site pool for its intended applications (e.g., compliance assessment vs ambient monitoring). These evaluations are critical because an inadequately evaluated reference pool may bias assessments in some settings. We present an approach for evaluating the adequacy of a reference-site pool for supporting biotic-index development in environmentally heterogeneous and pervasively altered regions. We followed common approaches for selecting sites with low levels of anthropogenic stress to screen 1985 candidate stream reaches to create a pool of 590 reference sites for assessing the biological integrity of streams in California, USA. We assessed the resulting pool of reference sites against 2 performance criteria. First, we evaluated how well the reference-site pool represented the range of natural gradients present in the entire population of streams as estimated by sites sampled through probabilistic surveys. Second, we evaluated the degree to which we were successful in rejecting sites influenced by anthropogenic stress by comparing biological metric scores at reference sites with the most vs fewest potential sources of stress. Using this approach, we established a reference-site pool with low levels of human-associated stress and broad coverage of environmental heterogeneity. This approach should be widely applicable and customizable to particular regional or programmatic needs.

California↗

A new method for discovering behavior patterns among animal movements

Advanced satellite tracking technologies enable biologists to track animal movements at fine spatial and temporal scales. The resultant data present opportunities and challenges for understanding animal behavioral mechanisms. In this paper, we develop a new method to elucidate animal movement patterns from tracking data. Here, we propose the notion of continuous behavior patterns as a concise representation of popular migration routes and underlying sequential behaviors during migration. Each stage in the pattern is characterized in terms of space (i.e., the places traversed during movements) and time (i.e. the time spent in those places); that is, the behavioral state corresponding to a stage is inferred according to the spatiotemporal and sequential context. Hence, the pattern may be interpreted predictably. We develop a candidate generation and refinement framework to derive all continuous behavior patterns from raw trajectories. In the framework, we first define the representative spots to denote the underlying potential behavioral states that are extracted from individual trajectories according to the similarity of relaxed continuous locations in certain distinct time intervals. We determine the common behaviors of multiple individuals according to the spatiotemporal proximity of representative spots and apply a projection-based extension approach to generate candidate sequential behavior sequences as candidate patterns. Finally, the candidate generation procedure is combined with a refinement procedure to derive continuous behavior patterns. We apply an ordered processing strategy to accelerate candidate refinement. The proposed patterns and discovery framework are evaluated through conceptual experiments on both real GPS-tracking and large synthetic datasets.

International Journal of Geographical Information ↗

Atmospheric mercury and its deposition during the phasing out of an amalgam electrolysis plant: Temporal, seasonal, and spatial patterns

Large amounts of mercury (Hg) were consumed and emitted into the atmosphere during the process of amalgam electrolysis used to produce chlorine and caustic soda since the nineteenth century. In Europe, amalgam electrolysis has been gradually replaced by advanced Hg-free technologies. In this work, we describe changes in atmospheric Hg and bulk Hg wet deposition during the phasing out of an amalgam electrolytic production line of a chlor-alkali plant in Neratovice, Czech Republic, central Europe. Bulk wet deposition Hg near the chlor-alkali plant was low at 3.6 ± 0.8 μg m −2 year −1 due in part to low annual precipitation amounts (486 ± 97 mm) in the period 2015–2021. Nevertheless, Hg deposition was elevated relative to a nearby reference site both before and after decommissioning of the electrolytic line. Switching off the amalgam electrolytic line did not notably affect bulk wet deposition Hg near the chlor-alkali plant. Levels of gaseous elemental Hg (GEM) and particle-bound Hg (PBM) monitored seasonally four times per year over 24-h time periods indicated rapid declines in four nearby settlements set in cardinal directions from the Hg emission source. Mean atmospheric GEM and PBM concentrations decreased rapidly from 9.0 ± 2.1 ng m −3 and 243 ± 255 pg m −3 in the period 2013–2017 when amalgam electrolysis was operating to 3.3 ± 0.4 ng m −3 and 32 ± 6 pg m −3 in the period 2018–2021 after its decommissioning in November 2017. Seasonal changes of GEM coincided with changes in temperature with the highest concentrations in summer, while PBM air levels were lowest in summer due to the highest seasonal precipitation amount. GEM concentrations at the four monitored settlements at Neratovice remained elevated at 2.8 ng m −3 with respect to regional background, but PBM levels decreased to background levels.

Neratovice↗

Combined impacts of current and future dust deposition and regional warming on Colorado River Basin snow dynamics and hydrology

The Colorado River provides water to 40 million people in seven western states and two countries and to 5.5 million irrigated acres. The river has long been overallocated. Climate models project runoff losses of 5&ndash;20% from the basin by mid-21st century due to human-induced climate change. Recent work has shown that decreased snow albedo from anthropogenic dust loading to the CO mountains shortens the duration of snow cover by several weeks relative to conditions prior to western expansion of the US in the mid-1800s, and advances peak runoff at Lees Ferry, Arizona, by an average of 3 weeks. Increases in evapotranspiration from earlier exposure of soils and germination of plants have been estimated to decrease annual runoff by more than 1.0 billion cubic meters, or ~5% of the annual average. This prior work was based on observed dust loadings during 2005&ndash;2008; however, 2009 and 2010 saw unprecedented levels of dust loading on snowpacks in the Upper Colorado River Basin (UCRB), being on the order of 5 times the 2005&ndash;2008 loading. Building on our prior work, we developed a new snow albedo decay parameterization based on observations in 2009/10 to mimic the radiative forcing of extreme dust deposition. We convolve low, moderate, and extreme dust/snow albedos with both historic climate forcing and two future climate scenarios via a delta method perturbation of historic records. Compared to moderate dust, extreme dust absorbs 2&times; to 4&times; the solar radiation, and shifts peak snowmelt an additional 3 weeks earlier to a total of 6 weeks earlier than pre-disturbance. The extreme dust scenario reduces annual flow volume an additional 1% (6% compared to pre-disturbance), a smaller difference than from low to moderate dust scenarios due to melt season shifting into a season of lower evaporative demand. The sensitivity of flow timing to dust radiative forcing of snow albedo is maintained under future climate scenarios, but the sensitivity of flow volume reductions decreases with increased climate forcing. These results have implications for water management and suggest that dust abatement efforts could be an important component of any climate adaptation strategies in the UCRB.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews↗

The assessment and remediation of mercury contaminated sites: A review of current approaches

Remediation of mercury (Hg) contaminated sites has long relied on traditional approaches, such as removal and containment/capping. Here we review contemporary practices in the assessment and remediation of industrial-scale Hg contaminated sites and discuss recent advances. Significant improvements have been made in site assessment, including the use of XRF to rapidly identify the spatial extent of contamination, Hg stable isotope fractionation to identify sources and transformation processes, and solid-phase characterization (XAFS) to evaluate Hg forms. The understanding of Hg bioavailability for methylation has been improved by methods such as sequential chemical extractions and porewater measurements, including the use of diffuse gradient in thin-film (DGT) samplers. These approaches have shown varying success in identifying bioavailable Hg fractions and further study and field applications are needed. The downstream accumulation of methylmercury (MeHg) in biota is a concern at many contaminated sites. Identifying the variables limiting/controlling MeHg production—such as bioavailable inorganic Hg, organic carbon, and/or terminal electron acceptors (e.g. sulfate, iron) is critical. Mercury can be released from contaminated sites to the air and water, both of which are influenced by meteorological and hydrological conditions. Mercury mobilized from contaminated sites is predominantly bound to particles, highly correlated with total sediment solids (TSS), and elevated during stormflow. Remediation techniques to address Hg contamination can include the removal or containment of Hg contaminated materials, the application of amendments to reduce mobility and bioavailability, landscape/waterbody manipulations to reduce MeHg production, and food web manipulations through stocking or extirpation to reduce MeHg accumulated in desired species. These approaches often rely on knowledge of the Hg forms/speciation at the site, and utilize physical, chemical, thermal and biological methods to achieve remediation goals. Overall, the complexity of Hg cycling allows many different opportunities to reduce/mitigate impacts, which creates flexibility in determining suitable and logistically feasible remedies.

Science of the Total Environment↗