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1,216 records · Page 60Linked to original sources

Reassessing water availability in the Nile River Basin using satellite-based irrigation water use accounting

Existing estimates of irrigation areas and water use in the Nile River Basin vary widely and are based on inconsistent data and methodologies. This study leverages advances in remote sensing to provide an up-to-date and consistent basin-wide reassessment of water use in the Nile River Basin. Land cover and actual evapotranspiration data from 2013 to 2022 were used to quantify irrigated areas, irrigation water use, and the average naturalized water yield. Across the basin, 7.1 million hectares of irrigated land consume an average of 72.5 ± 2.6 billion cubic meters (BCM) of blue water annually. Egypt and Sudan together account for 92% of the irrigated area and 97% of the irrigation water use. The basin’s average naturalized yield, evaluated at Dongola station, is determined to be between 108 and 114.4 ± 3.2 BCM. Although conservative, this updated analysis indicates the basin’s average naturalized yield is 14%–20% higher than the previous naturalized yield estimate (95 BCM) and 29%–36% higher than the commonly cited observed flow of 84 BCM, which is frequently treated as the total basin-wide available water. Importantly, the study underscores that the 84 BCM represents flow at the Aswan gauging station after upstream consumptive uses, not the total water available in the basin under naturalized conditions. This distinction is critical for accurate water accounting, planning, and governance in this water-scarce basin. This study demonstrates the value of open-source remote sensing resources in data-scarce regions while emphasizing the need for region specific validation and bias correction for improved accuracy.

Nile River Basin

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research

Emerging investigator series: Post-wildfire sediment geochemical characterization reveals manganese reactivity and a potential link to water quality impairment in the Gallinas Creek watershed, New Mexico

Water quality post-wildfire is often impaired by increased turbidity and elevated concentrations of elements such as manganese (Mn) and iron (Fe). Precipitation events exacerbate these issues, due in part to increased erosion and transport of sediment from hillslopes to surface water. Both Mn and Fe are major redox-active elements in sediments that drive a variety of biogeochemical cycles, precipitate adsorptive phases, and can themselves be drinking water contaminants. By investigating Mn and Fe sediment geochemistry in post-wildfire sediment deposits, related water quality hazards can be assessed. To establish and strengthen this connection, we analyzed the geochemistry of sediment deposits and surface water in the Gallinas Creek watershed, New Mexico over 1.5 years post-wildfire. Analyses included particle size analysis, water extractions, sequential extractions and aqua regia extractions to determine metal partitioning in sediment deposits. Data demonstrate Mn concentrations were distributed across labile and reactive fractions, such as the exchangeable and oxyhydroxide fractions, while Fe concentrations were mainly associated with the residual fraction. Manganese concentrations in aqua regia extractions and several fractions of sequential extractions were also strongly and significantly correlated with fine-grained sediment while the same pools of Fe concentrations were not. Dissolved Mn concentrations in surface water were elevated (>50 μg L −1 ) multiple times over the 1.5 years post-wildfire, highlighting a relationship between sediment geochemistry and water quality. This work shows Mn in sediments mobilized post-wildfire has an influence on water quality and highlights how further investigation into Mn sediment redox processes and mineralogy post-wildfire can inform risk assessments and resource management.

New Mexico

Comparative crop yield forecasting using satellite-derived biophysical and agro-climatic predictors in Sub-Saharan Africa

Timely and accurate crop yield forecasting is central to food security early warning systems, particularly in climate-vulnerable regions. While operational forecasting frameworks commonly rely on precipitation and vegetation indices such as NDVI, their ability to provide actionable lead time remains limited. Here, we evaluate the added value of satellite-derived biophysical Essential Climate Variables (ECVs): Leaf Area Index (LAI) and Fraction of Photosynthetically Active Radiation (FAPAR), for forecasting millet yield in Burkina Faso (BF) and maize yield in South Africa (ZA) and Malawi (MW). Using Random Forest models, we quantify forecast skill across the growing season at both national and sub-national scales. Results show that LAI and FAPAR provide effective forecast lead times of approximately 4 months in BF, 2 months in ZA, and up to 6 months in MW relative to harvest. At peak performance, Mean Absolute Percentage Error (MAPE) reaches 19.8% (LAI) and 23.8% (FAPAR) in BF, 12.0% and 9.8% in ZA, and 21.8% and 20.8% in MW, respectively. Across countries, biophysical parameters often outperform NDVI and precipitation, particularly in arid and semi-arid regions. At the sub-national level, LAI and FAPAR enable classification of administrative units into high and moderate-skill forecast units, revealing strong spatial heterogeneity linked to crop dominance. However, forecast skill declines where the target crop is not the dominant type, highlighting an important limitation for operational deployment. Overall, the findings suggest that satellite-derived biophysical parameters can provide earlier and more spatially resolved yield signals than commonly used predictors, with potential to improve the timeliness and effectiveness of food security early warning systems.

Remote Sensing Applications: Society and Environme

International data gaps at the Center for Engineering Strong Motion Data

The Center for Engineering Strong Motion Data (CESMD) is utilized by seismologists, engineers, and disaster management professionals in the US and has historically achieved and distributed waveforms from across the globe for significant earthquakes. The increased access to the waveforms via Web API (Application Programming Interface) offers a unique opportunity to provide the community complete datasets, sampling a variety of tectonic environments and geologic conditions, increasing the number of available ground motion records for use in ground motion models (GMMs) and improving the accuracy of earthquake engineering evaluations. The objective of this study is to programmatically identify gaps in global event data from the past decade and backfill missing data gaps at CESMD. We first compare the CESMD catalog with the Advanced National Seismic System (ANSS) Comprehensive Earthquake Catalog identifying regions and time periods where strong-motion data is limited or inadequate. To backfill datasets at CESMD for significant events, we pinpoint regions and time intervals that lack information, creating a list of events for which we’d like to obtain data. An important facet of this work is identifying the source of data and metadata across earthquake repositories around the world and integrating these data repositories into our current strong-motion data processing workflow. In parallel with these newly processed datasets, we are developing a script to produce data origination citations to include provenance and attribution information to associate with respective datasets at CESMD. We showcase our methodology for identifying and filling data gaps at CESMD using three case studies (the 2018 Anchorage Alaska earthquake sequence, seismicity associated with the 2018 Hawaiian Kilauea volcano eruption, and several earthquakes in Turkey) and then outline our strategy to apply our data gap backfilling methods on an international scale.

Conference Paper

Cascading land surface hazards as a nexus in the Earth system

Earth’s surface is sculpted by numerous processes that move sediment, ranging from gradual and benign to abrupt and catastrophic. Although infrequent, high-magnitude sediment mobilization events can be hazardous to people and infrastructure, leaving topographic imprints on the landscape and remarkable narratives in the historical record. Hazardous events such as fires, storms, and earthquakes accelerate erosion and sediment transport, increasing landscape sensitivity to subsequent perturbations, thus forming a cascading hazard. Although the redistribution of sediment across Earth’s landscape can result in higher risks to vulnerable populations, cascading processes are commonly unaccounted for in hazard assessments. Cascading hazards can occur almost immediately after triggering events, such as coseismic landslides, or over months, years, or even decades after an initial perturbation, such as debris flows after wildfires or flooding in channels alluviated by volcanic debris. Sediment cascades span Earth’s surface, from mountaintops to river valleys, where erosion, deposition, and aggradation can lead to a myriad of hazardous processes, including decreased river conveyance capacity, which increases the likelihood of downstream flooding. An improved understanding of the magnitude, frequency, and persistence of cascading hazards is critical given the rapid changes in the frequency and severity of storms, fires, sea-level change, and cryospheric melting, as well as the expansion of high-population-density urban footprints in regions susceptible to solid Earth hazards. Understanding the full consequences and underlying physics of Earth’s cascading land surface hazards can help minimize future human and economic losses.

California

New measurements indicate that natural geologic methane emissions from microseepage in the Michigan Basin are likely negligible

The magnitude of natural geologic methane (CH 4 ) emissions to the atmosphere (including emissions of fossil CH 4 from offshore and onshore gas and oil seeps, diffuse microseepage, mud volcanoes, volcanic vents, and geothermal areas) is highly uncertain. The largest component of geologic emissions is thought to be microseepage, which is the diffuse flux of CH 4 from soils across large areas of productive hydrocarbon basins. The accuracy of existing bottom-up estimates of microseepage is limited by low spatial coverage of published microseepage measurements. We present the first soil—atmosphere CH 4 flux measurements from Michigan Basin, USA. Results from 335 measurements taken during summer and winter seasons across a large portion of the basin suggest microseepage is nonexistent in the sampled region. Even areas with predictive features for microseepage (e.g., underlying mature, organically rich source rocks, proven gas accumulations, faults, and lineaments) yield null or negative fluxes, suggesting that CH 4 emissions from microseepage are negligible throughout our study region. A Monte Carlo method was used to place an upper limit on the regional-mean microseepage flux, in which synthetic patchy microseepage distributions were generated and tested against our observations to assess the impact of possible emission hot spots that were missed by our sampling strategy. Our analysis finds it is very unlikely that regional-mean emissions are as high as assumed in a previous global microseepage study. The observed lack of seepage may be explained by groundwater flow, active methanotrophy, glacial sediments, and bedded salt deposits, which could inhibit vertical gas migration and release to atmosphere.

Michigan

Detrital zircons and the magmatic history of Viti Levu, Fiji

We integrate the existing detrital zircon data from multiple modern river sediment samples on Viti Levu, Fiji, with the most current available geological and topographic mapping of the respective river drainage basins to compare detrital populations with potential bedrock sources. The temporal and spatial variations in zircon geochemistry supplement what is known from igneous rocks and confirm the petrological differences between plutonic and volcanic rocks from the Eocene to early Oligocene (Yavuna age, >30 Ma), middle Oligocene to middle Miocene (Wainimala age, 30–12.5 Ma), late Miocene (Colo age, 12.5–6.5 Ma) and latest Miocene (Namosi age, 6.5–5 Ma). The >30 Ma Yavuna-age zircons are restricted to areas that drain the previously mapped Yavuna Group. The 30–12.5 Ma zircons are found across central Viti Levu from west to east, and the 30–15 Ma zircons have distinctively low U/Yb and high Dy/Yb ratios. They are the best radiometric evidence of widespread early to middle Miocene arc magmatism in Fiji that was relatively U-poor. Peak deconvolution of the Colo age zircons from individual basins suggests the following ages for undated or poorly dated plutons from central Viti Levu. The large Mavuvu pluton is probably composed of multiple intrusions in the 12–10 Ma range, the Waiqa pluton is probably ca 10 Ma, and the Noikoro pluton is probably ca 9 Ma. There are zircons from unknown plutonic or volcanic sources between 8 and 7 Ma in western Viti Levu that have distinct Eu/Eu* ratios. We attribute the highest U/Yb ratios in some Colo age zircons to crustal anatexis. Namosi-age zircons are abundant in the Medrausucu Group and can be found scattered across Viti Levu.

Viti Levu

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2024

Potentiometric-surface and depth-to-water maps for spring 2024 were created for the Mississippi River Valley alluvial aquifer using groundwater-altitude data from 1,151 wells completed in the Mississippi River Valley alluvial aquifer and from the altitude of the top of the water surface in area rivers from 160 U.S. Geological Survey and U.S. Army Corps of Engineers streamgages. The potentiometric-surface and depth-to-water maps for 2024 were created to support investigations to characterize the Mississippi River Valley alluvial aquifer as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the Mississippi River Valley alluvial aquifer for spring 2024 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 330 feet (ft) above the North American Vertical Datum of 1988. The regional direction of the groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient direction was into the depression, and near rivers, where the groundwater gradient direction was either from the aquifer to the river or from the river into the aquifer. Groundwater depressions in the potentiometric-surface map are in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions. Depth to water by well in the Mississippi River Valley alluvial aquifer in spring 2024 ranged from 0.27 ft above land surface to 145.65 ft below land surface.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Development of a hydrogeologic visualization model for western Sarpy County, Nebraska

Population in western Sarpy County, Nebraska, has steadily increased over the last several decades and has led to increased groundwater use for domestic purposes. To meet the increase in demand, the Papio-Missouri River Natural Resources District is seeking to use all available sources of groundwater in western Sarpy County. Additionally, elevated groundwater nitrate plus nitrite as nitrogen concentrations were detected, indicating the need to better understand the groundwater quality of the area. Although the general geology of the area is understood, the area does not have detailed information on the extent of the various aquifers, particularly the Dakota aquifer. To characterize these aquifers, the Papio-Missouri River Natural Resources District invested in airborne electromagnetic surveys of the area to better understand the subsurface geology. Although these surveys improved understanding of the groundwater systems in the area, the Papio-Missouri River Natural Resources District wanted to integrate the subsurface information with available water-quality and groundwater-level data. In response, the U.S. Geological Survey, in cooperation with the Papio-Missouri River Natural Resources District, the Nebraska Natural Resources Commission, and the Nebraska Department of Natural Resources, assembled geologic, hydrogeologic and nitrate plus nitrite as nitrogen information for the selected area into a three-dimensional visualization computer software package called GeoScene3D. The completed GeoScene3D project was assembled to provide a visualization of the groundwater systems and associated water-quality results in Sarpy County and to provide the Papio-Missouri River Natural Resources District managers with information that can be used to make more informed groundwater resource-planning decisions in the future. This report details the development of a three-dimensional model created within GeoScene3D to visualize the subsurface, particularly the Dakota Sandstone in western Sarpy County.

Nebraska

Selected water-quality data from the Cedar River and Cedar Rapids well fields, Cedar Rapids, Iowa, 2017–22

The Cedar River alluvial aquifer is the source of drinking water in Cedar Rapids, Iowa. Production wells are completed in the alluvial aquifer approximately 40 to 80 feet below land surface. The City of Cedar Rapids and the U.S. Geological Survey have studied the groundwater-flow system and water quality of the aquifer in the vicinity of Cedar Rapids since 1992. Results of these studies documented hydrologic conditions, water quality, and geochemistry of the alluvial aquifer and interactions with the Cedar River. Water-quality samples were collected for studies involving well field monitoring, trends, source-water protection, groundwater geochemistry, surface-water–groundwater interaction, and pesticides in groundwater and surface water. Water quality was analyzed for dissolved major ions (boron, bromide, calcium, chloride, fluoride, iron, magnesium, manganese, potassium, silica, sodium, sulfate, and total dissolved solids), dissolved nutrients (ammonia as nitrogen, ammonia plus organic nitrogen as nitrogen, nitrite plus nitrate as nitrogen, nitrite as nitrogen, orthophosphate as phosphorus, and phosphorus), dissolved organic carbon, and selected pesticides. Physical characteristics (alkalinity, dissolved oxygen, pH, specific conductance, and water temperature) were measured on site and recorded for each water sample collected. This report presents the results of routine water-quality data-collection activities from October 2017 through September 2022. Methods of data collection, quality assurance, water-quality analyses, and statistical procedures are presented. Data include the results of water-quality analyses from quarterly sampling from monitoring wells, production wells, two water treatment plants, and the Cedar River at Blairs Ferry Road at Palo, Iowa, streamgage (U.S. Geological Survey station number 05464420), as well as monthly nutrient sampling from the Cedar River and Morgan Creek near Covington, Iowa, streamgage (U.S. Geological Survey station number 05464475).

Iowa

A journey to the center of the USGS National Strong-motion Project processing and beyond

The United States Geological Survey (USGS) National Strong Motion Project (NSMP) has the primary U.S. government responsibility to acquire, process, and disseminate significant strong-motion earthquake ground motion records measured at surficial free-field stations, structures (buildings, dams, and bridges, and geotechnical arrays to the earthquake engineering community. As a result of the deployment of modern seismic instrumentation and growth of tools such as web-services, earthquake data from U.S. and international seismic networks are more accessible than ever. Our mission is to provide raw and processed strong-motion waveforms with PGA values greater than 0.1%g for M3.0 earthquakes and larger in California and M4.0 and larger within the conterminous US, Hawaii, Puerto Rico, and Alaska. Datasets of interest to the engineering and geophysics communities, such as event sequences in areas of induced seismicity and significant global events, are also processed and posted at the Center for Engineering Strong Motion Data (CESMD) at strongmotioncenter.org when available through collaboration with the international strong-motion data community. Here we outline (1) the NSMP’s current workflow to acquire, process, and distribute data at CESMD; (2) our new endeavours and collaborations focusing on comparison and integration of waveform processing software, development of techniques for metadata quality checks before and after earthquakes, and construction of a dynamic site characterization repository; and (3) our topics for possible collaboration topics across the global strong-motion community.

Conference Paper

Fiber-optic sensing for earthquake hazards research, monitoring and early warning

The use of fiber‐optic sensing systems in seismology has exploded in the past decade. Despite an ever‐growing library of ground‐breaking studies, questions remain about the potential of fiber‐optic sensing technologies as tools for advancing if not revolutionizing earthquake‐hazards‐related research, monitoring, and early warning systems. A working group convened to explore these topics; we comprehensively examined the application of fiber optics in various aspects of earthquake hazards, encompassing earthquake source processes, crustal imaging, data archiving, and technological challenges. There is great potential for fiber‐optic systems to advance earthquake monitoring and understanding, but to fully unlock their capabilities requires continued progress in key areas of research and development, including instrument testing and validation, increased dynamic range for applications focused on larger earthquakes, and continued improvement in subsurface and source imaging methods. A key current stumbling block results from the lack of clear data archiving requirements, and we propose an initial strategy that balances data volume requirements with preserving key data for a broad range of future studies. In addition, we demonstrate the potential for fiber‐optic sensing to impact monitoring efforts by documenting the data completeness in a number of long‐term experiments. Finally, we outline the features of a instrument testing facility that would enable progress toward reliable and standardized distributed acoustic sensing data. Overcoming these current obstacles would facilitate progress in fiber‐optic sensing and unlock its potential application to a broad range of earthquake hazard problems.

California, Oregon, Washington

Wildfire, extreme precipitation and debris flows, oh my! Channel response to compounding disturbances in a mountain stream in the Upper Colorado Basin, USA

Compounding changes in climate and human activities stand to increase sediment input to rivers in many landscapes, including via discrete perturbations such as post-fire debris flows. Because sediment supply is a dominant control on river morphology, understanding mountain river responses to sediment regime perturbations is critical to predicting and addressing downstream effects to infrastructure, water security and aquatic habitat. A growing body of literature explores the causes, likelihood, size and composition of post-fire debris flows, but the channel response to these disturbances remains poorly studied. This study used repeat field surveys, time-lapse photographs and pre- and post-disturbance remote sensing datasets to document and analyse space- and time-varying channel response to post-fire debris flows along a steep mountain stream in the Upper Colorado River Basin, USA. Specifically, we evaluated channel morphology and bed composition changes, correlations between channel changes and valley and channel attributes, and the relative importance of spring snowmelt versus summer monsoon events. Several cross-sectional channel change types were observed from lidar a month after post-fire debris-flow events, including channelized and braided incision into deposits, incision into the pre-fire channel bed, bank erosion and no change. Channel changes were most correlated with pre-fire channel width, valley width and unit stream power, and these relationships could be tested in other burned locations to evaluate their transferability. Repeat channel surveys before and after snowmelt indicate rapid recovery and channel narrowing following major sediment disturbances, although sediment deposits remained in the channel margins. Together, these results highlight the importance of field and remote sensing-based channel surveys to improve understanding of, and potential to predict, mountain channel response to compounding climate disturbances.

Earth Surface Processes and Landforms

A framework for integrating spatiotemporal deep learning methods with landsat for annual land cover and impervious surface mapping

Land cover information is essential for understanding Earth’s surface dynamics and how vegetation, water, soil, climate, and terrain interact. The National Land Cover Database (NLCD) has been the authoritative source for consistent U.S. land cover mapping. To extend NLCD’s temporal resolution and reduce production latency, we developed the Land Cover Artificial Mapping System (LCAMS)—a prototype spatiotemporal deep learning framework piloted as the foundation for the new Annual NLCD. LCAMS builds on concepts from legacy NLCD and the U.S. Geological Survey Land Change Monitoring, Assessment, and Projection (LCMAP) initiatives. It employs a loosely coupled two-stage architecture consisting of independent but functionally interdependent spatial and temporal models. Spatial models extract per-year information from Landsat data, while the temporal models refine the spatial outputs to enforce inter-annual consistency—critical for reliable land change monitoring. LCAMS produces annual 30 m resolution land cover and impervious surface outputs, with region-specific fine-tuning to generalize across diverse landscapes and temporal dynamics. Validation was conducted using an independent dataset of 1925 randomly sampled plots from five U.S. Landsat Analysis Ready Data (ARD) tiles spanning 1985-2021, selected for spatial and temporal variability. This dataset was used consistently to evaluate LCAMS, Legacy NLCD, and LCMAP. Using the NLCD legend, LCAMS achieved 72.1 ± 1.60% overall agreement, compared to 71.1 ± 1.7% agreement for Legacy NLCD. Using the LCMAP legend, LCAMS achieved 83.4 ± 1.22% agreement, compared to 84.6 ± 1.11% agreement for LCMAP. Overall, LCAMS delivers comparable accuracy while offering higher thematic resolution, longer temporal coverage, and automated production of annual 30 m CONUS land cover.

Remote Sensing of Environment

Rapid seismic and infrasound assessment of large landslides: A case study from Denali National Park and Preserve (Alaska)

Large, rapid landslides are a global hazard that can occur in remote, mountainous areas. Eyewitness reports of landslides and satellite imagery can often be limited or delayed, particularly during inclement weather. However, landslide-generated seismic and infrasound (low-frequency atmospheric sound) waves can be remotely detected in near real-time. This information can significantly expedite characterization and possible landslide response activities. Here, we highlight these capabilities using a > 4 million m³ ice–rock avalanche in Denali National Park and Preserve (Alaska). This event was detected via a landslide-specific seismic location and volume estimation algorithm deployed in Alaska, and — notably — by standard earthquake monitoring systems. Following rapid detection of this event, we combined its seismic and infrasound dataset with optical, synthetic aperture radar, and oblique aerial imagery, multitemporal digital elevation models, and a numerical flow model to reconstruct its failure timeline and dynamics. We apply array processing to infrasound signals traveling > 250 km and find that two precursory events occurred minutes prior to the main failure. We use long-period seismic signals to infer the force exerted by the landslide on the Earth and constrain the rheological parameters of our numerical flow simulation with this result and deposit morphology. The main failure produced a steeply-dipping impulsive initial downward force and reached speeds exceeding 60 m/s. This impulsive force generated relatively strong seismic body waves, which contributed to the earthquake system detection. This large, remote Alaska landslide underscores the key value of seismic and infrasound analysis for rapid landslide assessment and motivates efforts to further operationalize these approaches.

Alaska

lasertram: A Python library for time resolved analysis of laser ablation inductively coupled plasma mass spectrometry data

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data has a wide variety of uses in the geosciences for in-situ chemical analysis of complex natural materials. Improvements to instrument capabilities and operating software have drastically reduced the time required to generate large volumes of data relative to previous methodologies. Raw data from LA-ICP-MS, however, is in counts per unit time (typically counts per second), not elemental concentrations and converting these count ratesto concentrations requires additional processing. For complex materials where the ablated volume may contain a range of material compositions, a moderate amount of user input is also required if appropriate concentrations are to be accurately calculated. In geologic materials such as glasses and minerals that potentially have numerous heterogeneities (e.g., microlites or other inclusions) within them, this is typically determiningwhether the total ablation signal should be filtered to remove these heterogeneities. This necessitates that the LA-ICP-MS data processing pipeline is one that is not automated, but is also designed to enable rapid and efficient processing of large volumes of data. Here we introduce , a Python library for the time resolved analysis of LA-ICP-MS data. We outline its mathematical theory, code structure, and provide an example of how it can be used to provide the time resolved analysis necessitated by LA-ICP-MS data of complex geologic materials. Throughout the pipeline we show how metadata and data are incrementally added to the objects created such that virtually any aspect of an experiment may be interrogated and its quality assessed. We also show, that when combined with other Python libraries for building graphical user interfaces, it can be utilized outside of a pure scripting environment. can be found at https://doi.org/10.5066/P1DZUR3Z

Applied Computing and Geosciences

Upper Triassic igneous rocks of the southern Kenai Peninsula, Alaska – Prelude to Early Jurassic subduction along the western Wrangellia composite terrane margin

New U–Pb zircon geochronology identifies a latest Triassic (ca 214–201 Ma) igneous suite of tuff, hypabyssal dikes, and a pluton on the southern Kenai Peninsula, Alaska. The igneous suite was emplaced within Upper Triassic sedimentary rocks along the southern margin of Western Wrangellia, the western-most fragment of the Wrangellia composite terrane. The igneous rocks range from mafic (50.6% SiO 2 ) to felsic (78.3% SiO 2 ), characteristically have less than 1.55% K 2 O, and generally have low trace element abundances. The tonalitic and trondhjemitic magmas were largely sourced in mafic-rich lower crust and incompletely assimilated quartz and other mineral xenocrysts are common. Fractionation involving plagioclase and amphibole is indicated for some magmas and composite intrusions and igneous xenoliths indicate magma mixing was possible. Paleozoic and Precambrian inherited zircons and initial 87 Sr/ 86 Sr (0.704103–0.705609) and 143 Nd/ 144 Nd (0.512396–0.512777) ratios indicate that the Western Wrangellia crustal sources are heterogeneous and contain sialic components. The latest Triassic magmatism reflects processes that preceded Early Jurassic subduction along the Wrangellia composite terrane and Pacific Ocean plate boundary. These processes involved heating and melting of mantle lithosphere and lower crust as mantle instabilities accompanied the breaking of the plate boundary linkages. The Late Triassic transition to subduction along the Wrangellia composite terrane margin coincided with the transition to subduction cessation in the Late Triassic arcs of the western Intermontane terranes of Canada. The shift to subduction along the outboard Wrangellia composite terrane margin marks the beginning of the Pacific Ocean–Cordillera plate interactions that came to dominate the tectonic evolution of the northern Cordillera from the Early Jurassic to today.

Alaska