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The Alaska Mineral Resource Assessment Program: Guide to information about the geology and mineral resources of the Ketchikan and Prince Rupert quadrangles, southeastern Alaska

The Ketchikan and Prince Rupert 1-degree by 2-degree quadrangles, which encompass about 16,000 km2 at the south tip of southeastern Alaska, have been investigated by integrated field and laboratory studies in the disciplines of geology, geochemistry, geophysics, and Landsat data interpretation to determine their mineral-resource potential. Mineral deposits in the study area have been mined or prospected intermittently since about 1900, and production of small tonnages of ores containing gold, silver, copper, lead, zinc, and tungsten has been recorded. Extensive exploration and development currently (1981) is underway at a molybdenum prospect about 65 km east of Ketchikan. Our mineral-resource assessment indicates that the area contains potentially significant amounts of those metallic commodities, as well as of molybdenum, iron, antimony, and barite. The results of these studies have been published in a folio of maps accompanied by descriptive texts, diagrams, tables, and pertinent references. The present report serves as a guide to these investigations, provides relevant background information, and integrates the component maps and reports. It also describes revisions to the geology based on studies completed since the folio was published and includes a list of specific and general references on the geology and mineral deposits of the study area.

Alaska↗

Tremors from earthquakes and blasting in the Powder River basin of Wyoming and Montana

Coal in the Powder River Basin of Wyoming and Montana (fig. 1) is greatly in demand. It can be economically mined from the surface, and the land is much easier to reclaim than land above underground mines that has been damaged by subsidence or by underground fires. Exploitation of the vast coals resources in the basin has caused a rapid influx of population into the area and an associated increase in building construction. The activity has also generated concern about possible regulation of development. With these facts in mind, the U.S Geological Survey has been investigating the geologic implications of development in the Powder River Basin. One area of study has been the effect of earth tremors caused by blasting in the large coal surface mines or by naturally occurring earthquakes. The basin proper was classified by Algermissen and Perkins (1976) as belonging to a region of low seismic risk. Naturally occurring earthquakes are, therefore, mainly of scientific interest, unless of course there was an isolated event that occurred near a populated area or a surface mine. We are not aware of any damage to people or to property caused by blasting in the coal surface mines even though thousands of tons of explosives are detonated each year in the basin. The maximum weight of an individual explosive charge and the time interval between blasts are regulated so that any nearby structures will not be damaged or the residents disturbed. Blasting, nevertheless, does produce seismic tremors that can be recorded over 200 kilometers away. In addition, at one mine, some very low order aftershocks were recorded relatively close to the source within 2 hours after blasting.

Montana; Wyoming↗

Geology of anthracite in the southwestern part of the Mount Carmel quadrangle, Pennsylvania

This report is the second to be prepared as a result of a geologic investigation of the anthracite fields of Pennsylvania begun after consultation with the Bureau of Topographic and Geologic Surveys of the Commonwealth of Pennsylvania. This report and others in preparation will show (1) the location of coal outcrops, (2) the depth, pitch, and other structural features of representative coal beds, (3) the natural and artificial barriers between mines and the structural relationships between the various coal basins, and (4) the correlation of the beds, the stratigraphic intervals between them, and the thickness, continuity, and other physical characteristics of the coal. The reports will bring up to date and amplify the Grand Atlas of the Anthracite Fields published by the Second Geological Survey of Pennsylvania in 1884-1885, and the reports that supplemented that atlas. It is expected that the reports will aid operators who are mining either on the surface or underground, or who are formulating plans for control of mine water. It is hoped that these reports will also direct attention to overlooked or unutilized reserves of coal. A preceding report described the west-central part of the Mount Carmel quadrangle (Rothrock et al., 1950) and it is planned to publish similar reports on other unit areas as they are completed.

Pennsylvania↗

Geologic map of the Dusar area, Herat Province, Afghanistan; Modified from the 1973 original map compilations of V.I. Tarasenko and others

The geologic maps and cross sections presented in this report are redrafted and modified versions of the Geologic map and map of useful minerals of the Dusar area (scale 1:50,000) and Geologic sketch map of the Dusar and Namak-sory ore occurrences (scale 1:10,000), located in the Herat Province, Afghanistan. The original maps and cross sections are contained in unpublished Soviet report no. 0290 (Tarasenko and others, 1973) prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan, in Kabul during 1973 under contract no. 50728. The redrafted maps and cross sections (modified from Tarasenko and others, 1973) illustrate the geological structure and mineral occurrences of the Dusar copper-gold-silver-lead-zinc prospect area of western Afghanistan, located within the Dusar-Shaida copper and tin area of interest (AOI), Herat Province, Afghanistan. Mineralization in the Dusar area is hosted within Early Jurassic to Early Cretaceous stratified volcanic and sedimentary rocks associated with numerous diabase and gabbro-diabase intrusive bodies and is generally near a major northeast-trending system of faults and quartz veins. Host rocks consist of quartz keratophyre and quartz-feldspar porphyry, with layers of schist, phyllite, and quartz-chlorite and chlorite-sericite slate; and limestone and shale, with schist and carbonate-chlorite and chlorite slate. Known mineralization includes an extensive quartz vein system, shown on the map as the “northern occurrence,” as well as the Dusar and Namak-sory gossan zones, interpreted to have formed from remnant pyrite mineralization. The veins of the northern occurrence and their altered host rocks are known to contain anomalous to economic concentrations of precious and base metals, with concentrations locally in excess of 2 parts per million gold, 100 parts per million silver, 5 percent copper, and 1 percent lead. These veins occur in swarms, and are hosted along structures that are approximately concordant with the plane of the metamorphic fabric. The veins consist mostly of quartz, with minor carbonate and sulfide minerals, and display weak alteration halos along their margins. The gossans are locally anomalous in these metals, but their size and extent makes them attractive exploration targets for potential massive sulfide mineralization. The Dusar gossan zone is a massive, ochreous, and siliceous limonitic rock, approximately 2,200 meters long, 30 to 250 meters wide, and 2.0 to 7.2 meters thick. Drilling below the Dusar gossan intersected a siliceous, sericitic, and limonitic rock underlain by quartz keratophyre with abundant disseminated pyrite. Mineralized sections grade 0.06 weight percent copper and up to 0.05 weight percent zinc. The Namak-sory gossan zone contains a similar deposit with anomalous concentrations of copper, zinc, and gold. The redrafted maps and cross sections reproduce the topology of rock units, contacts, and faults of the original Soviet maps and cross sections, and include minor modifications based on examination of the originals and observations made during two brief field visits by USGS staff in August, 2010, and June, 2013.

Dusar Area, Herat Province↗

Preliminary report on the White Canyon area, San Juan county, Utah

The White Canyon area, in the central part of San Juan County, Utah, consists of approximately two 15-minute quadrangles. Approximately 75 square miles have been mapped by the Geological Survey on a scale of 1 inch equals 1 mile, using a combined aerial photography-plane table method. Structure contours were drawn on top of the Organ Rock member of the Cutler formation. Parts of the Gonway and North Point claims, 1/4 mile east of the Happy Jack mine, were mapped in detail. The principal objectives of the investigations were: (1) to establish ore guides; (2) to select areas favorable for exploration; and (3) to map the general geology and to determine the regional relationships of the uranium deposits. The White Canyon area is comprised of sedimentary rocks of Carboniferous to Jurassic age, more than 2,000 feet thick, having a regional dip of 1° to 2° SW. The nearest igneous rocks are in the Henry Mountains about 7 miles west of the northern part of the area; The Shinarump conglomerate of the late Triassic age, the principal ore horizon in the White Canyon area, consists of lenticular beds of sandstone, conglomeratic sandstone, conglomerate, clay, and siltstone. The Shinarump conglomerate, absent in places, is as much as 75 feet thick. The sandstones locally contain molds of logs and fragments of altered volcanic ash. Some of the logs have been replaced by copper and uranium minerals and iron oxides. The clay and siltstone underlie and are interbedded with the sandstone, and are most common in channels that cut into the underlying Moenkopi formation. The Shinarump conglomerate contains reworked Moenkopi siltstone fragments, clay balls, carbonized wood, and pebbles of quarts, quartzite, and chert. Jointing is prominent in the Western part of the mapped area. The three most prominent joint trends are due east, N. 65°-75° W., and N. 65°-75° E. All joints have vertical dips. The red beds are bleached along some joints, especially those that trend N. 65°-75° W. All uranium ore produced has been from the lower part of the Shinarump conglomerate, where it commonly occurs with copper as disseminations and fracture coatings in sandstone. Uranium and copper minerals also occur in low-grade disseminated deposits in the lower Chinle and in the Moenkopi formation and in veins cutting these formations. Although some uranium deposits occur in Chinarump channels and scours, copper and uranium minerals along fractures suggest that channel control may be secondary. Logs and clay balls apparently have exerted some chemical influences for deposition. The uranium occurs as the oxide in some deposits, and as secondary hydrous sulfates, phosphates, oxides, and silicates in these and several other deposits. Charcoal, iron and manganese oxides, and veinlets of hydrocarbon are abnormally radioactive in most of the deposits. Base-metal sulfides are commonly found inside the oxidized zone. Secondary copper minerals include the hydrous sulfates and carbonate. Gangue minerals include quarts, clay minerals, and manganese oxides, dickite (?), calcite, gypsum, pyrite, and chalcedony (?). Principal wall-rock alteration appears to have been silicification, clay alteration, and bleaching. Most of the shipped ore has contained more than 0.3 percent uranium. The ore also contains copper, commonly in grades lower than 1.0 percent. Criteria believed to be most useful for prospecting for concealed uranium deposits are (1) visible uranium minerals; (2) sulfide minerals; (3) secondary copper minerals; (4) dickite (?); (5) hydrocarbons; and (6) bleaching and alteration of the Moenkopi formation.

Utah↗

Hydrogeology, numerical simulation of groundwater flow, and effects of future water use and drought for reach 1 of the Washita River alluvial aquifer, Roger Mills and Custer Counties, western Oklahoma, 1980–2015

The Washita River alluvial aquifer is a valley-fill and terrace alluvial aquifer along the valley of the Washita River in western Oklahoma that provides a productive source of groundwater for agricultural irrigation and water supply. The Oklahoma Water Resources Board (OWRB) has designated the westernmost section of the aquifer in Roger Mills and Custer Counties, Okla., as reach 1 of the Washita River alluvial aquifer; reach 1 is the focus of this report. The OWRB issued an order on November 13, 1990, that established the maximum annual yield (MAY; 120,320 acre-feet per year [acre-ft/yr]) and equal-proportionate-share (EPS) pumping rate (2.0 acre-feet per acre per year [(acre-ft/acre)/yr]) for reach 1 of the Washita River alluvial aquifer. The MAY and EPS were based on hydrologic investigations that evaluated the effects of potential groundwater withdrawals on groundwater availability in the Washita River alluvial aquifer. Every 20 years, the OWRB is statutorily required to update the hydrologic investigation on which the MAY and EPS were based. Because 30 years have elapsed since the last order was issued, the U.S. Geological Survey, in cooperation with the OWRB, conducted a new hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in the Washita River alluvial aquifer. The Washita River is the primary source of inflow to Foss Reservoir, a Bureau of Reclamation reservoir constructed in 1961 for flood control, water supply, and recreation. Foss Reservoir provides water for Bessie, Clinton, New Cordell, and Hobart, Okla. Nearly 98 percent of the total groundwater use from the Washita River alluvial aquifer during 1967 to 2015 was for irrigation; other uses of groundwater in the study area include public supply, mining, and agriculture. A hydrogeologic framework was developed for the Washita River alluvial aquifer and included the physical characteristics of the aquifer, the geologic setting, the hydraulic properties of hydrogeologic units, the potentiometric surface (water table), and groundwater-flow directions at a scale that captures the regional controls on groundwater flow. The Washita River alluvial aquifer consists of alluvium and terrace deposits that were transported primarily by water and range from clay to gravel in size. The terrace includes windblown deposits of silt size and, in some cases, contains gravel laid down at several levels along former courses of present-day rivers. A conceptual flow model is a simplified description of the aquifer system that includes hydrologic boundaries, major inflow and outflow sources of the groundwater-flow system, and a conceptual water budget with the estimated mean flows between those hydrologic boundaries. During the study period 1980–2015, mean annual groundwater withdrawals, predominantly used for agricultural irrigation, totaled 5,502 acre-ft/yr, or 14 percent of aquifer outflows. When applied across the 132-square-mile aquifer area used for modeling purposes (84,366 acres), mean annual recharge of 3.15 inches per year corresponds to a mean annual recharge volume of 22,169 acre-ft/yr, or 56 percent of aquifer inflows. The annual saturated-zone evapotranspiration outflow was 11,828 acre-ft/yr for the Washita River alluvial aquifer, or about 30 percent of aquifer outflows. For the Washita River alluvial aquifer, lateral flow was 17,157 acre-ft/yr, or 44 percent of the aquifer inflows. The conceptual flow model and hydrogeologic framework were used to conceptualize, design, and build the numerical groundwater-flow model. A numerical groundwater-flow model of the Washita River alluvial aquifer was constructed by using MODFLOW-2005. The Washita River alluvial aquifer groundwater-model grid was spatially discretized into 350-foot (ft) cells and two layers. Layer 1 represented the undifferentiated alluvium and terrace deposits of Quaternary age, and layer 2 represented the bedrock of Permian age, which was given a uniform nominal thickness of 100 ft. The groundwater-simulation period was temporally discretized into 433 monthly transient stress periods, representing January 1980 to December 2015. An initial 365-day steady-state stress period was configured to represent mean annual inflows and outflows from the Washita River alluvial aquifer for the study period. The groundwater-flow model was calibrated manually and by automated adjustment of model inputs by using PEST++. Calibration targets for the Washita River alluvial aquifer model included groundwater-level observations and reservoir-stage observations, as well as base-flow and stream-seepage estimates. Three groundwater-availability scenarios were used in the calibrated groundwater model to (1) estimate the EPS pumping rate that retains the saturated thickness that meets the minimum 20-year life of the aquifer, (2) quantify the effects of projected pumping rates on groundwater storage over a 50-year period, and (3) evaluate how projected pumping rates extended 50 years into the future and sustained hypothetical drought conditions over a 10-year period affect base flow and groundwater in storage. The results of the groundwater-availability scenarios could be used by the OWRB to reevaluate the established MAY of groundwater from the Washita River alluvial aquifer. EPS scenarios for the Washita River alluvial aquifer were run for periods of 20, 40, and 50 years. The 20-, 40-, and 50-year EPS pumping rates under normal recharge conditions were 1.7, 1.6, and 1.6 (acre-ft/acre)/yr, respectively. Given the aquifer area used for modeling purposes (84,366 acres), these rates correspond to annual yields of 142,579, 134,986, and 134,986 acre-ft/yr, respectively. Groundwater storage at the end of the 20-year EPS scenario was about 281,000 acre-feet (acre-ft), or about 306,000 acre-ft (52 percent) less than the starting storage. Considering the land-surface area of the Washita River alluvial aquifer and using a specific yield of 0.12, this decrease in storage was equivalent to a mean groundwater-level decline of about 30 ft. The Washita River downstream from Foss Reservoir and most of the streams in the study area were dry at the end of the 20-year EPS scenario. Foss Reservoir stage was below the dead-pool stage of 1,597 ft after about 7 years of pumping in the 20-year EPS scenario. Four projected 50-year groundwater-use scenarios were used to simulate the effects of selected well withdrawal rates on groundwater storage in the Washita River alluvial aquifer. These four scenarios used (1) no groundwater use, (2) groundwater use at the 2015 pumping rate, (3) mean groundwater use for the simulation period, and (4) increasing groundwater use. Groundwater storage after 50 years with no groundwater use was 545,249 acre-ft, or 693 acre-ft (0.1 percent) greater than the initial groundwater storage; this groundwater storage increase is equivalent to a mean groundwater-level increase of 0.1 ft. Groundwater storage at the end of the 50-year period with 2015 pumping rates was 543,831 acre-ft, or 723 acre-ft (0.1 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage after 50 years with the mean pumping rate for the study period was 543,202 acre-ft, or 1,349 acre-ft (0.2 percent) less than the initial groundwater storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage at the end of the 50-year period with an increasing demand groundwater-pumping rate, which was 38 percent greater than the 2015 groundwater-pumping rate, was 542,584 acre-ft, or 1,967 acre-ft (0.4 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.2 ft. A hypothetical 10-year-drought scenario was used to simulate the effects of a prolonged period of reduced recharge on groundwater storage in the Washita River alluvial aquifer and Foss Reservoir stage and storage. To simulate the hypothetical drought, recharge in the calibrated model was reduced by 50 percent during the simulated drought period (1983–1992). Groundwater storage at the end of the drought period in December 1992 was 562,000 acre-ft, or 36,000 acre-ft (6 percent) less than the groundwater storage of the calibrated groundwater model (598,000 acre-ft). At the end of the hypothetical drought, the largest changes in saturated thickness (as great as 43.5 ft) were in the area upgradient from Foss Reservoir, particularly in the terrace at the model boundary. Substantial decreases in the Foss Reservoir stage began during the fall of 1985 in conjunction with base-flow decreases of up to 100 percent at U.S. Geological Survey streamgage 07324200 Washita River near Hammon, Okla. These lake-stage declines outpaced groundwater-level declines in the surrounding aquifer. The minimum Foss Reservoir storage simulated during the drought period was 77,954 acre-ft, which was a decrease of 46 percent from the nondrought storage.

Oklahoma↗

The chief oxide-burgin area discoveries, East Tintic district, Utah; A case history

The Burgin shaft is in the Chief Oxide area of the E. Tintic district, Utah, and is about a mile E. of any previously known ore bodies; workings from it are currently developing a substantial amount of commercial Pb-Zn ore in several blind ore bodies that lie in folded Paleozoic carbonate rock concealed beneath a blanket of Eocene lava. This area was mapped by Tower and Smith of the U.S. Geological Survey in 1897 and again by Lindgren and Loughlin in 1911, but no detailed work was done until after 1943 when a field party headed by T.S. Lovering began a study of the entire E. Tintic district. The history of the development of exploration concepts is summarized under Historical Summary. The E. Tintic mining district is in the E.-central part of a N.-trending fault-block mountain range near the eastern margin of the Great Basin; dominant structures of the range are a N.-trending syncline on the W. and a less well exposed anticline on the E. Both folds are cut by an intersecting system of transcurrent strike-slip faults and by minor thrust faults and normal faults of moderate displacement. A strong W.-dipping thrust fault cuts the anticline a short distance E. of the fold axis, but is hidden by Eocene lava throughout the E. Tintic district. The pre-Tertiary rocks range from Lower Cambrian to Upper Mississippian and exceed 7,000 ft. in total thickness; they are dominantly marine limestone and dolomite except for a thick basal Cambrian quartzite. The Tertiary rocks are chiefly dacitic lavas and pyroclastic deposits that are intruded by moderately persistent dikes and irregular bodies of monzonite and quartz porphyry. Nearly all the faulting and folding took place before the extrusion of the lavas on a rugged Eocene erosion surface. At about the time of the intrusion of monzonitic magma, many of the faults in the Paleozoic rock were re-opened and in the overlying lava some fracturing took place which was later accented by hydrothermal alteration. Most of the ore mined in the E. Tintic district has come from Pb-Zn-Ag replacement bodies in shattered Jasperoidized hydrothermal dolomite at the intersection of low angle faults and steep mineralized NE.-trending cross fractures. The U.S. Geological Survey studies of 1943 to 1957 concentrated on detailed mapping of geology and alteration in the E. Tintic district, together with field and laboratory studies of the relation of alteration to stages of mineralization and ore deposition. Trenching and core drilling were carried on after World War II to aid in interpreting the subrhyolite geology, and the Chief Oxide area was 1 of 4 localities tested by drilling. Study of the fossils, lithology, and alteration shown here in a deep drill core, together with the knowledge of the regional geology, led to an essentially correct interpretation of subrhyolite structure in the strongly discordant underlying Paleozoic rocks in which a mineralized tear fault cuts a strong thrust fault, and to the conclusion that ore stage mineralization was present in substantial amounts in the Paleozoic rocks below the Chief Oxide alteration patch in the quartz latite lava. Subsequent geothermal and geochemical work strengthened this conclusion, and the recent development work of the Bear Creek Mining Company, which sank the Burgin shaft, has shown the presence of Pb-Zn-Ag ore of commercial grade in substantial amount in blind ore bodies below the lava blanket in the Chief Oxide area.

Utah↗

A review of Alabama lignite deposits

This review of Alabama lignite deposits is a part of the U.S. Geological Survey (USGS) National Coal Resource Assessment (NCRA) of the Gulf Coast region (see Ruppert et al., 2002; Dennen, 2009; and other chapters of this publication). Because lignite is not currently mined in Alabama, a detailed assessment of the state was not made, and only a review is presented in this chapter. Lignite beds are found in several stratigraphic horizons within the Paleocene Midway and Paleocene to Eocene Wilcox Groups in the Gulf Coastal Plain of Alabama (Figure 1). There are three main near-surface (less than 250 ft of overburden) lignite deposits in Alabama. In the Midway Group, the Oak Hill lignite deposit occurs in the upper part of the Oak Hill Member of the Naheola Formation (Figure 2). In the Wilcox Group, the Gravel Creek and the Tuscahoma lignite deposits occur in the Coal Bluff Marl Member of the Nanafalia Formation and the Tuscahoma Sand Member of the Tuscahoma Sand Formation, respectively (Figure 2). The Gravel Creek lignite occurs in central and eastern Alabama, and the Oak Hill and Tuscahoma Sand lignites occur in southwest Alabama. Eighty-five percent of this lignite may be recoverable by surface mining methods (Tolson, 1985). The total amount of lignite reported as a reserve by the state is over 4.7 billion short tons (Self et al., 1978).

Alabama↗

Western Mineral and Environmental Resources Science Center--providing comprehensive earth science for complex societal issues

Minerals in the environment and products manufactured from mineral materials are all around us and we use and come into contact with them every day. They impact our way of life and the health of all that lives. Minerals are critical to the Nation's economy and knowing where future mineral resources will come from is important for sustaining the Nation's economy and national security. The U.S. Geological Survey (USGS) Mineral Resources Program (MRP) provides scientific information for objective resource assessments and unbiased research results on mineral resource potential, production and consumption statistics, as well as environmental consequences of mining. The MRP conducts this research to provide information needed for land planners and decisionmakers about where mineral commodities are known and suspected in the earth's crust and about the environmental consequences of extracting those commodities. As part of the MRP scientists of the Western Mineral and Environmental Resources Science Center (WMERSC or 'Center' herein) coordinate the development of national, geologic, geochemical, geophysical, and mineral-resource databases and the migration of existing databases to standard models and formats that are available to both internal and external users. The unique expertise developed by Center scientists over many decades in response to mineral-resource-related issues is now in great demand to support applications such as public health research and remediation of environmental hazards that result from mining and mining-related activities. Western Mineral and Environmental Resources Science Center Results of WMERSC research provide timely and unbiased analyses of minerals and inorganic materials to (1) improve stewardship of public lands and resources; (2) support national and international economic and security policies; (3) sustain prosperity and improve our quality of life; and (4) protect and improve public health, safety, and environmental quality. The MRP supports approximately 40 USGS research specialists who utilize cooperative agreements with universities, industry, and other governmental agencies to support their collaborative research and information exchange. Scientists of the WMERSC study how and where non-fuel mineral resources form and are concentrated in the earth's crust, where mineral resources might be found in the future, and how mineral materials interact with the environment to affect human and ecosystem health. Natural systems (ecosystems) are complex - our understanding of how ecosystems operate requires collecting and synthesizing large amounts of geologic, geochemical, biologic, hydrologic, and meteorological information. Scientists in the Center strive to understand the interplay of various processes and how they affect the structure, composition, and health of ecosystems. Such understanding, which is then summarized in publicly available reports, is used to address and solve a wide variety of issues that are important to society and the economy. WMERSC scientists have extensive national and international experience in these scientific specialties and capabilities - they have collaborated with many Federal, State, and local agencies; with various private sector organizations; as well as with foreign countries and organizations. Nearly every scientific and societal challenge requires a different combination of scientific skills and capabilities. With their breadth of scientific specialties and capabilities, the scientists of the WMERSC can provide scientifically sound approaches to a wide range of societal challenges and issues. The following sections describe examples of important issues that have been addressed by scientists in the Center, the methods employed, and the relevant conclusions. New directions are inevitable as societal needs change over time. Scientists of the WMERSC have a diverse set of skills and capabilities and are proficient in the collection and integration of

Circular↗

Representativeness of soil samples collected to assess mining-related contamination of flood plains in southeast Kansas

Historical lead and zinc mining in the Tri-State Mining District (TSMD), located in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma, has resulted in a substantial ongoing input of lead and zinc to the environment (Juracek, 2006; Juracek and Becker, 2009). In response to concern about the mining-related contamination, southeast Cherokee County, Kansas, was listed on the U.S. Environmental Protection Agency’s (USEPA) National Priority List as a Superfund hazardous waste site (fig. 1). To provide some of the information needed to support remediation efforts in the Cherokee County Superfund site, a study was begun in 2009 by the U.S. Geological Survey (USGS) that was requested and funded by USEPA. As part of the study, surficial-soil sampling was used to investigate the extent and magnitude of mining-related lead and zinc contamination in the flood plains of the Spring River and several tributaries within the Superfund site. In mining-affected areas, flood-plain soils had lead and zinc concentrations that far exceeded background levels as well as probable-effects guidelines for toxic aquatic biological effects (Juracek, 2013). Lead- and zinc-contaminated flood plains are a concern, in part, because they represent a long-term source of contamination to the fluvial environment. An important issue is the within-site representativeness of the surficial-soil samples collected. Specifically, the question is whether or not the samples collected provide an acceptable representation of the lead and zinc concentrations at each site for the purpose of characterizing and comparing sites. The distribution of mining-contaminated sediment on flood plains is determined by several factors including the size and density of the contaminated particles, flood-plain width and topography, flood characteristics (frequency, magnitude, duration), and fluvial geomorphic processes. To evaluate within-site representativeness, additional samples were simultaneously collected to assess within-site variability. In this paper, the specific objectives were to: Describe the collection and analysis of surficial-soil samples using a 5-point sampling technique; Describe the collection and analysis of additional surficial-soil samples to assess within-site variability; and Evaluate the within-site representativeness of the original 5-point samples for assessing mining-related contamination.

Conference Paper↗

Book review: Mineral resource estimation

Mineral Resource Estimation is about estimating mineral resources at the scale of an ore deposit and is not to be mistaken with mineral resource assessment, which is undertaken at a significantly broader scale, even if similar data and geospatial/geostatistical methods are used. The book describes geological, statistical, and geostatistical tools and methodologies used in resource estimation and modeling, and presents case studies for illustration. The target audience is the expert, which includes professional mining geologists and engineers, as well as graduate-level and advanced undergraduate students. Review info: Mineral Resource Estimation . By Mario E. Rossi, Clayton V. Deutsch . 2014 . ISBN 978-1-4020-5716-8 332 pp.

Economic Geology↗

The fate of cyanide in leach wastes at gold mines: an environmental perspective

This paper reviews the basic chemistry of cyanide, methods by which cyanide can be analyzed, and aspects of cyanide behavior that are most relevant to environmental considerations at mineral processing operations associated with gold mines. The emphasis is on research results reported since 1999 and on data gathered for a series of U.S. Geological Survey studies that began in the late 1990s. Cyanide is added to process solutions as the CN − anion, but ore leaching produces numerous other cyanide-containing and cyanide-related species in addition to the desired cyanocomplex of gold. These can include hydrogen cyanide (HCN); cyanometallic complexes of iron, copper, zinc, nickel, and many other metals; cyanate (CNO − ); and thiocyanate (SCN − ). The fate of these species in solid wastes and residual process solutions that remain once gold recovery activities are terminated and in any water that moves beyond the ore processing facility dictates the degree to which cyanide poses a risk to aquatic organisms and aquatic-dependent organisms in the local environment. Cyanide-containing and cyanide-related species are subject to attenuation mechanisms that lead to dispersal to the atmosphere, chemical transformation to other carbon and nitrogen species, or sequestration as cyanometallic precipitates or adsorbed species on mineral surfaces. Dispersal to the atmosphere and chemical transformation amount to permanent elimination of cyanide, whereas sequestration amounts to storage of cyanide in locations from which it can potentially be remobilized by infiltrating waters if conditions change. From an environmental perspective, the most significant cyanide releases from gold leach operations involve catastrophic spills of process solutions or leakage of effluent to the unsaturated or saturated zones. These release pathways are unfavorable for two important cyanide attenuation mechanisms that tend to occur naturally: dispersal of free cyanide to the atmosphere and sunlight-catalyzed dissociation of strong cyanometallic complexes, which produces free cyanide that can then disperse to the atmosphere. The widest margins of environmental safety will be achieved where mineral processing operations are designed so that time for offgassing, aeration, and sunlight exposure are maximized in the event that cyanide-bearing solutions are released inadvertently.

Applied Geochemistry↗

Isotopic variations of dissolved copper and zinc in stream waters affected by historical mining

Zinc and Cu play important roles in the biogeochemistry of natural systems, and it is likely that these interactions result in mass-dependent fractionations of their stable isotopes. In this study, we examine the relative abundances of dissolved Zn and Cu isotopes in a variety of stream waters draining six historical mining districts located in the United States and Europe. Our goals were to (1) determine whether streams from different geologic settings have unique or similar Zn and Cu isotopic signatures and (2) to determine whether Zn and Cu isotopic signatures change in response to changes in dissolved metal concentrations over well-defined diel (24-h) cycles. Average δ 66 Zn and δ 65 Cu values for streams varied from +0.02‰ to +0.46‰ and −0.7‰ to +1.4‰, respectively, demonstrating that Zn and Cu isotopes are heterogeneous among the measured streams. Zinc or Cu isotopic changes were not detected within the resolution of our measurements over diel cycles for most streams. However, diel changes in Zn isotopes were recorded in one stream where the fluctuations of dissolved Zn were the largest. We calculate an apparent separation factor of ∼0.3‰ ( 66/64 Zn) between the dissolved and solid Zn reservoirs in this stream with the solid taking up the lighter Zn isotope. The preference of the lighter isotope in the solid reservoir may reflect metabolic uptake of Zn by microorganisms. Additional field investigations must evaluate the contributions of soils, rocks, minerals, and anthropogenic components to Cu and Zn isotopic fluxes in natural waters. Moreover, rigorous experimental work is necessary to quantify fractionation factors for the biogeochemical reactions that are likely to impact Cu and Zn isotopes in hydrologic systems. This initial investigation of Cu and Zn isotopes in stream waters suggests that these isotopes may be powerful tools for probing biogeochemical processes in surface waters on a variety of temporal and spatial scales.

Geochimica et Cosmochimica Acta↗

The Iron Hill (Powderhorn) carbonatite complex, Gunnison County, Colorado — A potential source of several uncommon mineral resources

A similar version of this slide show was presented on three occasions during 2008: two times to local chapters of the Society for Mining, Metallurgy, and Exploration (SME), as part of SME's Henry Krumb lecture series, and the third time at the Northwest Mining Association's 114th Annual Meeting, held December 1-5, 2008, in Sparks (Reno), Nevada. In 2006, the U.S. Geological Survey (USGS) initiated a study of the diverse and uncommon mineral resources associated with carbonatites and associated alkaline igneous rocks. Most of these deposit types have not been studied by the USGS during the last 25 years, and many of these mineral resources have important applications in modern technology. The author chose to begin this study at Iron Hill in southwestern Colorado because it is the site of a classic carbonatite complex, which is thought to host the largest known resources of titanium and niobium in the United States.

Colorado↗

Geologic interpretation of gravity data from the Date Creek basin and adjacent areas, west-central Arizona

A gravity survey of the Date Creek Basin and adjacent areas was conducted in June 1977 to provide information for the interpretation of basin geology. A comparison of facies relations in the locally uraniferous Chapin Wash Formation and the position of the Anderson mine gravity anomaly in the Date Creek Basin suggested that a relationship between gravity lows and the development of thick lacustrine sections in the region might exist. A second-order residual gravity map derived from the complete Bouguer gravity map for the survey area (derived from survey data and pre-existing U.S. Department of Defense data) shows an excellent correspondence between gravity lows and sediment-filled basins and suggests considerable variation in basin-fill thickness. Using the Anderson mine anomaly as a model, gravity data and facies relations suggest that the southeastern flank of the Aguila Valley gravity low and the gravity low at the western end of the Hassayampa Plain are likely areas for finding thick sections of tuffaceous lacustrine rocks.

Arizona↗

Sedimentary exhalative (sedex) zinc-lead-silver deposit model

This report draws on previous syntheses and basic research studies of sedimentary exhalative (sedex) deposits to arrive at the defining criteria, both descriptive and genetic, for sedex-type deposits. Studies of the tectonic, sedimentary, and fluid evolution of modern and ancient sedimentary basins have also been used to select defining criteria. The focus here is on the geologic characteristics of sedex deposit-hosting basins that contain greater than 10 million metric tons of zinc and lead. The enormous size of sedex deposits strongly suggests that basin-scale geologic processes are involved in their formation. It follows that mass balance constraints of basinal processes can provide a conceptual underpinning for the evaluation of potential ore-forming mechanisms and the identification of geologic indicators for ore potential in specific sedimentary basins. Empirical data and a genetic understanding of the physicochemical, geologic, and mass balance conditions required for each of these elements are used to establish a hierarchy of quantifiable geologic criteria that can be used in U.S. Geological Survey national assessments. In addition, this report also provides a comprehensive evaluation of environmental considerations associated with the mining of sedex deposits.

Scientific Investigations Report↗

Stress changes ahead of an advancing tunnel

Instrumentation placed ahead of three model tunnels in the laboratory and ahead of a crosscut driven in a metamorphic rock mass detected stress changes several tunnel diameters ahead of the tunnel face. Stress changes were detected 4 diameters ahead of a model tunnel drilled into nearly elastic acrylic, 2·50 diameters ahead of a model tunnel drilled into concrete, and 2 diameters ahead of a model tunnel drilled into Silver Plume Granite. Stress changes were detected 7·50 diameters ahead of a crosscut driven in jointed, closely foliated gneisses and gneissic granites in an experimental mine at Idaho Springs, Colorado. These results contrast markedly with a theoretical elastic estimate of the onset of detectable stress changes at 1 tunnel diameter ahead of the tunnel face. A small compressive stress concentration was detected 2 diameters ahead of the model tunnel in acrylic, 1.25 diameters ahead of the model tunnel in concrete, and 1 diameter ahead of the model tunnel in granite. A similar stress peak was detected about 6 diameters ahead of the crosscut. No such stress peak is predicted from elastic theory. The 3-dimensional in situ stress determined in the field demonstrate that geologic structure controls stress orientations in the metamorphic rock mass. Two of the computed principal stresses are parallel to the foliation and the other principal stress is normal to it. The principal stress orientations vary approximately as the foliation attitude varies. The average horizontal stress components and the average vertical stress component are three times and twice as large, respectively, as those predicted from the overburden load. An understanding of the measured stress field appears to require the application of either tectonic or residual stress components, or both. Laboratory studies indicate the presence of proportionately large residual stresses. Mining may have triggered the release of strain energy, which is controlled by geologic structure.

Colorado↗

The brown iron ores of west-middle Tennessee

A study of the brown iron ore deposits of west-middle Tennessee has been carried on recently under a cooperative agreement between the Tennessee State Geological Survey and the United States Geological Survey. A detailed report on the subject was submitted in the spring of 1925 to the State Survey for publication as a bulletin, and the writing of the present report was completed in March, 1926. The field work was done mainly between October 22 and November 2, 1921, and April 26 and July 18, 1923; but in October, 1924, a visit was made to the mine at Napier. The writer was assisted in the field in 1921 by. R. W. Smith, assistant geologist, and in 1923 by C. C. Anderson, topographer, both of the Tennessee Survey. Mr. Wilbur A. Nelson, State geologist at the time the work was in progress, visited several mines with the writer and on these occasions as well as many times during the preparation of the report rendered helpful suggestions and guidance. Mr. H. D. Miser, of the United States Geological Survey, State geologist from September 1, 1925, to July 1, 1926, who is especially familiar with the southern part of this area, also cooperated heartily in the preparation of this report; and Mr. H. W. Davis, of the United States Bureau of Mines, compiled the statistical data on iron ore and pig iron. To all these gentlemen the writer desires to express his appreciation. Acknowledgments are also due to the officials and employees of the iron mining and manufacturing companies and to people living in the vicinity of inactive mining properties for their courteous attention and for the large amount of information furnished. In the present paper the general features of the region and of the iron-ore deposits are delineated, but only a few typical ore deposits in each county are described, as the State bulletin will contain detailed descriptions of all properties.

Tennessee↗