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At least 1,081 records · Page 60Linked to original sources
USGS1968

The non-colloidal origin of 'colloform' textures in sphalerite ores

" Colloform " ores have generally been considered to have been deposited as colloidal sulfide gels, and even transported as colloidal "sols." However, studies of doubly polished plates of " colloform " sphalerite -wurtzite assemblages from various deposits reveal crystal growth features that cannot have been formed by crystallization from gels, and indicate that most, and perhaps all, grew directly as minute druses of continuously euhedral crystals projecting into an ore fluid. Each of the many textural criteria proposed for recognizing colloidal deposition is shown to be invalid, ambiguous, or inapplicable to these samples, and perhaps also to most other " colloform " mineral samples.Four conclusions pertinent to ore research are derived from this study: (1) Primary fluid inclusions in " colloform " samples are believed to represent the original ore fluid, not merely a residual fluid from the crystallization of a gel. (2) Although euhedral crystals may possibly grow directly from a sol, several features make a noncolloidal (true solution) ore fluid more probable. (3) Maintenance of the large number of crystal nuclei responsible for the " colloform " texture is attributed to relatively high supersaturation, and hence relatively high nucleation and growth rates, for the temperatures involved. (4) Remarkably uniform, regular compositional microbands, traversing many crystals in samples from the east Tennessee, Aachen, and particularly the Pine Point deposits, are tentatively interpreted as annual "varves." No actual growth rates have been determined, but each "varve" consists of a dark and a light band, outlining sharply euhedral former crystal growth patterns and suggesting an annual change in the ore fluid due to dilution with surface waters of varying volume or chemistry (e.g., oxygen or organic content).

Economic Geology↗
USGS1973

Stable isotope and chemical relations during mineralization in the Bodie mining district, Mono County, California

Stable isotope and chemical relations have been determined in a typical epithermal Au-Ag deposit located in the Bodie mining district of California. Analyses were made of altered host rocks, vein minerals, alteration clays, fluid inclusions, modern spring waters, and unaltered rocks of the area.The results indicate that a hydrothermal convection system was set up by the interaction of a cooling shallow intrusion and local meteoric water. The water traveled to depth where it picked up ore constituents and SiO 2 , K, and Rb, without significant shifts in the stable isotope ratios of the water. The altered rocks have equilibrated to various degrees with an ore fluid of constant K/Rb, O 18 /O 16 and D/H ratios. Deposition of ore took place over the approximate temperature range 215 degrees -245 degrees . From C 13 /C 12 ratios of minor calcite, a volcanic source of CO 2 is postulated. The chemical and isotope composition of the ore fluid is strikingly similar to that of modern spring waters in the area.All ore deposition at Bodie took place from essentially isotopically unaltered ground water with delta O 18 = -13ppm and delta D = -98ppm.

California↗
USGS1990

Ground-water control of evaporite deposition

Topographically closed basins may be hydrologically open as a result of seepage losses to underlying or surrounding ground-water systems. In such cases, these losses can have a substantial control over the suite and the thicknesses of evaporite minerals formed in the basin. The ratio of ground-water outflow to inflow (flux ratio) in hydrologically open basins is as important in determining the mineralogy and thicknesses of evaporite deposits as the solute composition of the inflow water. Attainment of steady state flux ratios permits large thicknesses of two or three minerals to form rather than thin veneers of many minerals. The presence or absence of glauberite, mirabilite, halite, bloedite, polyhalite, and hexahydrite, caused by subtle changes in the ground-water seepage is illustrated using an example from the Southern High Plains of Texas and New Mexico. However, the model is general and is applicable with any solute composition including that of seawater and the use of surface rather than ground water. An analytical, lumped parameter, solute mass balance model is developed to define the concept of a ground-water flux ratio as it applies to topographically closed basins in which evaporation exceeds precipitation. Diffusion, advection, and density-driven flow are proposed as mechanisms by which solutes can escape to the ground water from these closed basins. The geochemical reaction computer program PHRQPITZ is used to document the effects of various flux ratios on the mineralogy and thickness of deposits. Solute analyses used in conjunction with the model can be used to screen prospective basins as well as to provide insights for exploratory drilling program.

Texas, New Mexico↗
USGS2005

Geospatial decision support systems for societal decision making

While science provides reliable information to describe and understand the earth and its natural processes, it can contribute more. There are many important societal issues in which scientific information can play a critical role. Science can add greatly to policy and management decisions to minimize loss of life and property from natural and man-made disasters, to manage water, biological, energy, and mineral resources, and in general, to enhance and protect our quality of life. However, the link between science and decision-making is often complicated and imperfect. Technical language and methods surround scientific research and the dissemination of its results. Scientific investigations often are conducted under different conditions, with different spatial boundaries, and in different timeframes than those needed to support specific policy and societal decisions. Uncertainty is not uniformly reported in scientific investigations. If society does not know that data exist, what the data mean, where to use the data, or how to include uncertainty when a decision has to be made, then science gets left out -or misused- in a decision making process. This paper is about using Geospatial Decision Support Systems (GDSS) for quantitative policy analysis. Integrated natural -social science methods and tools in a Geographic Information System that respond to decision-making needs can be used to close the gap between science and society. The GDSS has been developed so that nonscientists can pose "what if" scenarios to evaluate hypothetical outcomes of policy and management choices. In this approach decision makers can evaluate the financial and geographic distribution of potential policy options and their societal implications. Actions, based on scientific information, can be taken to mitigate hazards, protect our air and water quality, preserve the planet's biodiversity, promote balanced land use planning, and judiciously exploit natural resources. Applications using the GDSS have demonstrated the benefits of utilizing science for policy decisions. Investment in science reduces decision-making uncertainty and reducing that uncertainty has economic value.

Boletin Geologico y Minero↗
USGS2016

Are the Columbia River Basalts, Columbia Plateau, Idaho, Oregon, and Washington, USA, a viable geothermal target? A preliminary analysis

The successful development of a geothermal electric power generation facility relies on (1) the identification of sufficiently high temperatures at an economically viable depth and (2) the existence of or potential to create and maintain a permeable zone (permeability >10 -14 m 2 ) of sufficient size to allow efficient long-term extraction of heat from the reservoir host rock. If both occur at depth under the Columbia Plateau, development of geothermal resources there has the potential to expand both the magnitude and spatial extent of geothermal energy production. However, a number of scientific and technical issues must be resolved in order to evaluate the likelihood that the Columbia River Basalts, or deeper geologic units under the Columbia Plateau, are viable geothermal targets. Recent research has demonstrated that heat flow beneath the Columbia Plateau Regional Aquifer System may be higher than previously measured in relatively shallow (<600 m depth) wells, indicating that sufficient temperatures for electricity generation occur at depths 5 km. The remaining consideration is evaluating the likelihood that naturally high permeability exists, or that it is possible to replicate the high average permeability (approximately 10 -14 to 10 -12 m 2 ) characteristic of natural hydrothermal reservoirs. From a hydraulic perspective, Columbia River Basalts are typically divided into dense, impermeable flow interiors and interflow zones comprising the top of one flow, the bottom of the overlying flow, and any sedimentary interbed. Interflow zones are highly variable in texture but, at depths <600 m, some of them form highly permeable regional aquifers with connectivity over many tens of kilometers. Below depths of ~600 m, permeability reduction occurs in many interflow zones, caused by the formation of low-temperature hydrothermal alteration minerals (corresponding to temperatures above ~35 °C). However, some high permeability (>10-14 m 2 ) interflows are documented at depths up to ~1,400 m. If the elevated permeability in these zones persists to greater depths, they may provide natural permeability of sufficient magnitude to allow their exploitation as conventional geothermal reservoirs. Alternatively, if the permeability in these interflow zones is less than 10-14 m 2 at depth, it may be possible to use hydraulic and thermal stimulation to enhance the permeability of both the interflow zones and the natural jointing within the low-permeability interior portions of individual basalt flows in order to develop Enhanced/Engineered Geothermal System (EGS) reservoirs. The key challenge for an improved Columbia Plateau geothermal assessment is acquiring and interpreting comprehensive field data that can provide quantitative constraints on the recovery of heat from the Columbia River Basalts at depths greater than those currently tested by deep boreholes.

Idaho, Oregon, Washington↗
USGS1950

Characteristics of marine uranium-bearing sedimentary rocks

Many marine sedimentary black shale and phosphorite formations contain 0.01 to 0.02 percent uranium, and one, the alum shale of Sweden, contains as much as 0.5 percent. The published fact that uranium is already being recovered on a laboratory scale from Swedish deposits forcefully suggests that similar deposits in the United States and possibly many other countries may prove to be an important future source of uranium.The marine uranium-bearing black shales are rich in organic matter and sulfides and contain little or no carbonate. The best are found in relatively thin formations of pre-Mesozoic age. The nature of the uranium-bearing mineral or compound is not known. In contrast, nonmarine black shales, as a group, are not uraniferous.All marine phosphorites tested thus far are uraniferous and so too are the phosphatic nodules found in many marine black shales. With some exceptions, the uranium increases in a general way with increase in phosphate content and is believed to be in the phosphate mineral. Like the black shales, the phosphorite formations are characteristically thin; many are associated with unconformities or, in other words, periods during which little else in the way of sediment accumulated.Significant concentrations of uranium in marine sediments other than black shales and phosphorites are thus far known only in beach placer deposits and the gold-bearing conglomerates of the Witwatersrand district, South Africa.Uranium may be found in other types of marine sediments on further prospecting, but especially promising are the sediments rich in organic matter, phosphate, or both, found in relatively thin formations believed to be the entire depositional products of long periods of geologic time. Such formations are most characteristic of those areas where, at the time of deposition, the adjacent land masses were so stable and low that the influx of clastic materials was small; the basin of deposition was large or of such configuration that fine-grained sediments could accumulate; and chemical conditions in the seawater prevented deposition of large amounts of carbonate.

Economic Geology↗
USGS2025

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico↗
USGS1984

Uranium mineralization in response to regional metamorphism at Lilljuthatten, Sweden

Analyses of six mineralized and five nonmineralized whole-rock drill core samples from the uranium deposit at Lilljuthatten yield a lead-lead isochron age of 420 + or - 1 m.y. This age corresponds to the last stage of the Caledonian Orogeny. None of the isotopic systems examined have completely retained the intrusive age of the Olden Granite, but data for several systems suggest an age of approximately 1,650 m.y. Indications that Caledonian hydrothermal activity strongly affected most of the Olden Granite. A model for the genesis of the ore deposit is proposed as follows: (1) derivation of a highly evolved granite by partial melting of crustal materials about 1,650 m.y. ago; (2) pervasive hydrothermal alteration and fracturing of the granite in response to the Caledonian Orogeny approximately 420 m.y. ago; (3) mobilization of uranium and lead in response to circulation of heated fluids; (4) precipitation of these elements in open fractures; and (5) recent modification of the Caledonian uranium distribution as a result of exposure to near-surface conditions.

Economic Geology↗
USGS1972

Geology of the Eymir iron mine, Edremit, Turkey

The Eymir mine near Edremit on Turkey's Aegean coast (long 27?30'E.,1at 39?36'N.) was investigated as part of the Maden Tetkik ve Arama Enstitutsu (MTA)-U. S. Geological Survey (USGS) mineral exploration and training project, for the purpose of increasing the known mineral reserves. Geologic mapping of the mine area indicates that hematite is restricted to argillized, silicified, and pyritized dacite and possibly andesite. Hematite is present as massive replacements, impregnations, disseminations, and fracture fillings. Most of the upper part of the iron deposit consists of a breccia composed mostly of silicifiled dacite fragments in a hematite matrix. The iron deposit was apparently formed in three steps: 1. Argillation, silicification, and pyritization of the andesitic lava and dacite units as a result of a regional intrusion. 2. Intrusion of the Dere Oren dacite stock, with associated faulting, fracturing, and breccia formation at the surface. 3. Deposition of hematite by oxidation of pyrite, and transfer of iron via fractures and faults by hydrothermal or meteoric fluids. The Eymir iron deposit is a blanketlike deposit on the crest of the Sivritepe-Eymir ridge. It is 1300 meters long, 80 to 450 meters wide, and has an average thickness of 18.6 meters. Drill holes in the deposit show the iron content to range from 32.0 to 57.6 percent, and to average 46.5 percent. Most of the gangue is silica, and an arsenic impurity averaging 0.39 percent is present. Most of the deposit cannot be utilized as iron ore because of low iron content, high silica content, and high arsenic content. Ore-dressing tests have shown that it is feasible to concentrate the low-grade material, producing a concentrate having increased iron content and reduced silica content. Tests have shown also that the arsenic content of the ore can be reduced substantially by sintering. Further tests and economic feasibility studies are necessary to determine whether an economic marketable iron ore can be produced. If such studies indicate the technical and economic feasibility of utilizing all the Eymir iron deposit, detailed additional studies are recommended including: 1. A detailed drilling and sampling program to include 60 drill holes averaging 40 meters in depth and detailed sampling of mine dumps. 2. Pilot-plant testing of concentration and sintering procedures. 3. A detailed pre-investment economic feasibility study.

Open-File Report↗
USGS2023

Antimony in mine wastes: Geochemistry, mineralogy, microbiology

Antimony (Sb) is a valuable mined commodity, used mostly in fire retardants, and considered a critical element. It is also a potential environment hazard classed as a carcinogen. Antimony is concentrated in tailings and waste rock from Sb mines as well as other locations, such as precious metal deposits, where Sb is present in the ore but not recovered. This review covers the aqueous geochemistry, isotope chemistry, mineralogy, and microbiology of Sb in the context of mine waste. The primary minerals stibnite and sulfosalts may release Sb in surface and groundwaters and result in contamination of soils, plants, and river sediments. In some cases, Sb mobility is limited by its adsorption and incorporation into Fe (oxyhydr)oxides. At higher Sb concentrations, precipitation of Sb secondary hosts such as tripuhyite (FeSbO 4 , relatively insoluble) and brandholzite (Mg[Sb(OH) 6 ] 2 · 6H 2 O, highly soluble) influence Sb concentrations in water associated with mine waste. Although Sb is nonessential to organisms, microorganisms are involved in oxidation, reduction, and methylation processes that can drive biogeochemical transformations. Limited toxicological information about Sb makes it challenging to establish regulations or guidelines limiting the concentration of Sb. Antimony is frequently associated with arsenic in mine waste, and remediation design is often based on the assumption that both metalloids behave in a similar way. However, new research suggests that in some environments, this is not the case, and Sb should be considered based on its unique biogeochemical behavior.

Economic Geology↗
USGS1985

Electrical geophysical investigations of massive sulfide deposits and their host rocks, West Shasta copper-zinc district

The West Shasta copper-zinc district, Shasta County, California, contains many volcanogenic sulfide deposits within Middle Devonian rhyolites that have not been highly metamorphosed. The district was selected by the U.S. Geological Survey for intensive geological, geochemical, and geophysical study under the Development of Assessment Techniques (DAT) project because accessible exposures have been created by erosion and mining. This report describes the geophysical methods applied to characterize the electrical properties of selected West Shasta massive sulfide deposits and their host rocks, at both small (less than 25 ft) and large (greater than 25 ft) scales. The electrical techniques used galvanic (spectral induced polarization--SIP) and induction (very low frequency--VLF, slingram, and time domain electro-magnetics--TDEM) methods.In situ spectral induced polarization measurements were carried out to determine whether or not conductive anomalies in the district could be differentiated by their polarization signatures. The sulfide, in situ, induced polarization-phase spectral signatures (the induced polarization effect as a function of frequency) have much less character and lack the distinctive shape reported for other massive sulfide deposits; however, they do have some identifiable massive sulfide traits, such as low resistivity and variable polarizability. The nondescript sulfide spectral signature is attributed to the poor development of polarization processes due to a high percentage of resistive, nonpolarizable gangue minerals, lack of pore space, and limited electrolytic fluids. Large-scale spectral induced polarization measurements over the Hornet orebody have a greater polarization than the in situ measurements. This observation, in addition to the fact that much of the Hornet sulfide body has been removed by previous mining activity, suggests that the dominant polarization processes occur at the ground-water-sulfide interface.Combined use of induction techniques, which have different depths of penetration, were used to locate conductive anomalies and determine their shape and depth. All the induction surveys over the Hornet orebody detected the conductive tabular-shaped massive pyritic sulfide deposit hosted in resistive rhyolite. Shallow penetrating induction methods near the Keystone mine detected a conductive fault zone where a block of shale has been downfaulted into volcanic rock. Integrated interpretation of deeper penetrating induction data over this conductive fault zone indicates that parts of the shale are also conductive, demonstrating that the integrated use of several induction methods provides better conductor definition than a single method.

Economic Geology↗
USGS1981

Physical factors that could restrict mineral supply

Stages in the metal supply process are affected by each of the following physical (geologic) factors: (1) geographic distribution of concentrations of potential ore minerals, (2) depth of these concentrations, (3) mineralogy, (4) grain size of the minerals, and (5) grade and (6) tonnages of the concentrations. For mineral deposits of each type in each geologic and political environment, the lowest cost metal will tend to be produced first because: (1) the largest deposits tend to be found first, (2) the few largest deposits should reap the benefits of economies of scale and will tend to account for the lion’s share of total metal, (3) higher grade deposits that require substantially less energy per ton of metal than do lower grade deposits will be mined first, and (4) deposits that have the mineralogy and grain sizes that are relatively cheap to process will be produced first. Shallow deposits that are relatively cheap to find and mine and deposits near existing infrastructure will also be produced first. Because stages in the supply process are sequential, problems at any stage caused by the physical factors are reflected in subsequent stages and adversely affect production costs. In the long term, effects of such problems will be not physical shortages of metals but a rapid or persistent increase in real prices of metals.

Economic Geology↗
USGS1967

The porphyry copper deposit exposed in the Liberty open-pit mine near Ely, Nevada; Part 2, The formation of hydrothermal alteration zones

In the southwest part of the Liberty pit a large porphyry body exhibits a zonal alteration pattern related to fissures and pyrite-bearing veins. The outermost zone contains unaltered K-feldspar, kaolinite after plagioclase, and black biotite after hornblende. An intermediate zone contains reconstituted K-feldspar, phlogopitic biotite, and muscovite or muscovite plus K-feldspar replacing only plagioclase. In the innermost zone the only silicates are quartz and muscovite. In some places an alteration band of K-feldspar after plagioclase separates kaolinite and muscovite.The widespread association of kaolinite and K-feldspar in hydrothermal alteration zones suggests that these two minerals were stable together at the time of formation. Experimental data show that, where quartz controls the activity of silica in solution, kaolinite and K-feldspar should react to form muscovite. However, calculations predict that, at 15,000 psi, solutions with silica activities compatible with amorphous or gelatinous silica could stabilize K-feldspar and kaolinite relative to muscovite at temperatures below about 250 degrees C. The rapid decomposition either of plagioclase feldspar or montmorillonite is considered a prime cause for the attainment of such high activities of silica in pore solutions of rock. The supersaturation of pore solutions with silica is a transient condition; quartz precipitates where kaolinite and K-feldspar react to give muscovite. Thus, the zonally distributed alteration at Ely is considered to have taken place after the rock had cooled to below 250 degrees C. In contrast, the diffusely distributed muscovite and montmorillonite found in another portion of the pit probably commenced at 600 degrees to 700 degrees C with only minor formation of alteration products below 250 degrees C.

Nevada↗
USGS2008

The metallogeny of Late Triassic rifting of the Alexander terrane in southeastern Alaska and northwestern British Columbia

A belt of unusual volcanogenic massive sulfide (VMS) occurrences is located along the eastern margin of the Alexander terrane throughout southeastern Alaska and northwestern British Columbia and exhibits a range of characteristics consistent with a variety of syngenetic to epigenetic deposit types. Deposits within this belt include Greens Creek and Windy Craggy, the economically most significant VMS deposit in Alaska and the largest in North America, respectively. The occurrences are hosted by a discontinuously exposed, 800-km-long belt of rocks that consist of a 200- to 800-m-thick sequence of conglomerate, limestone, marine elastic sedimentary rocks, and tuff intercalated with and overlain by a distinctive unit of mafic pyroclastic rocks and pillowed flows. Faunal data bracket the age of the host rocks between Anisian (Middle Triassic) and late Norian (late Late Triassic). This metallogenic belt is herein referred to as the Alexander Triassic metallogenic belt. The VMS occurrences show systematic differences in degree of structural control, chemistry, and stratigraphic setting along the Alexander Triassic metallogenic belt that suggest important spatial or temporal changes in the tectonic environment of formation. At the southern end of the belt, felsic volcanic rocks overlain by shallow-water limestones characterize the lower part of the sequence. In the southern and middle portion of the belt, a distinctive pebble conglomerate marks the base of the section and is indicative of high-energy deposition in a near slope or basin margin setting. At the northern end of the belt the conglomerates, limestones, and felsic volcanic rocks are absent and the belt is composed of deep-water sedimentary and mafic volcanic rocks. This northward change in depositional environment and lithofacies is accompanied by a northward transition from epithermal-like structurally controlled, discontinuous, vein- and pod-shaped, Pb-Zn-Ag-Ba-(Cu) occurrences with relatively simple mineralogy, to sulfosalt-enriched VMS occurrences exhibiting characteristics of vein, diagenetic replacement, and exhalative styles of mineralization, and finally to Cu-Zn-(Co-Au) occurrences with larger and more clearly stratiform orebody morphologies. Occurrences in the middle of the belt are transitional in nature between structurally controlled types of mineralization that formed in a shallow-water, near-arc setting, to those having a more stratiform appearance, formed in a deeper water, rift-basin setting. The geologic setting in the south is consistent with shallow subaqueous emplacement on the flanks of the Alexander terrane. Northward, the setting changes to an increasingly deeper back- or intra-arc rift basin. Igneous activity in the Alexander Triassic metallogenic belt is characterized by a bimodal suite of volcanic rocks and a previously unrecognized association with mafic-ultramafic hypabyssal intrusions. Immobile trace and rare earth element (BEE) geochemical data indicate that felsic rocks in the southern portion of the belt are typical calc-alkaline rhyolites, which give way in the middle of the belt to peralkaline rhyolites. Rhyolites are largely absent in the northern part of the belt. Throughout the belt, the capping basaltic rocks have transitional geochemical signatures. Radiogenic isotope data for these rocks are also transitional (basalts and gabbros: ??-Nd = 4-9 and 87Sr/86Sr initial at 215 Ma = 0.7037-0.7074). Together these data are interpreted to reflect variable assimilation of mature island-arc crust by more primitive melts having the characteristics of either mid-ocean ridge (MORB) or intraplate (within-plate) basalts (WPB). The ore and host-rock geochemistry and the sulfosalt-rich mineralogy of the deposits are strikingly similar to recent descriptions of active sea-floor hydrothermal (white smoker) systems in back arcs of the southwest Pacific Ocean. These data, in concert with existing faunal ages, record the formation of a belt of VMS deposits

Conference Paper↗
USGS1965

Nature and origin of the high-grade hematite ores of Minas Gerais, Brazil

The high - grade hematite deposits of Minas Gerais , Brazil , are those averaging more than 66% Fe and less than 1.5% H20+. They occur in the Caue Itabirite, a metamorphosed oxide-facies iron formation of Pre-cambrian age. This formation was intricately folded during an orogeny that metamorphosed pelitic rocks to the greenschist and almandine-amphi-bole fades, accompanied by the formation of granitic rocks. The folding produced much plastic rock flowage toward the axes of many folds, thickness of the itabirite ranging from a few to more than 1,400 m. Of 40 ore bodies on which enough information for judgments is available, 11 probably contain more than 100 million tons, 22 between 10 and 100 million tons, and 7 less than 10 million tons. At least two are thought to be larger than 400 million tons. The great majority of these ore bodies are associated with folded structures in the host itabirite, a few are associated with preore thrust faults, and some with abrupt steepening of regional linear structure. Most of the ore occurs in the lower, more siliceous two-thirds of the itabirite; some occurs in the upper third, which is locally dolomitic. Some of the ore is foliated, some unfoliated; the unfoliated cuts the foliated and heals ore breccias. The ore mineral is dominantly hematite . Ore was formed during the metamorphic cycle, after the folding. It is localized in relatively low-pressure, hence higher permeability, parts of folds. Ore replaced pre-existing itabirite, preserving structures. Regional metamorphism indicates that the metasomatizing fluids were at high temperature and under high confining pressure. Increasing solubility of quartz with gradually rising temperature caused metasomatic replacement of quartz by hematite picked up from iron formation by throughpassing fluids during the rising temperature cycle of metamorphism. Source of fluids is thought to have been first the metasedimentary rocks, then granitic gneiss and intrusive granite; the source of heat to have been the metasomatizing fluids and intrusive granite. The unfoliated iron ore healing brecciated foliated ore was deposited during the waning metamorphic cycle. Gold ore with associated tourmaline and cassiterite is found in porous but not massive iron ore . The abundant soft high - grade hematite ore formed from the more porous parts of the hard ore bodies, where metasomatism had not been complete, by supergene leaching of very minor quantities of hematite from crystal boundaries.

Minas Gerais↗
USGS1999

Connecting onshore and offshore near-surface geology: Delaware's sand inventory project

Beginning in 1988, the Delaware Geological Survey began a program to inventory on-land sand resources suitable for beach nourishment. The inventory included an assessment of the native beach textures using existing data and developing parameters of what would be considered suitable sand textures for Delaware's Atlantic beaches. An assessment of the economics of on-land sand resources was also conducted, and it was determined that the cost of the sand was competitive with offshore dredging costs. In addition, the sand resources were put into a geologic context for purposes of predicting which depositional environments and lithostratigraphic units were most likely to produce suitable sand resources. The results of the work identified several suitable on-land sand resource areas in the Omar and Beaverdam formations that were deposited in barrier-tidal delta and fluvial-estuarine environments, respectively. The identified on-land resources areas have not been utilized due to difficulties of truck transport and development pressures in the resource areas. The Delaware Geological Survey's participation in years 8, 9, and 10 of the Continental Margins Program was developed to extend the known resource areas onshore to offshore Delaware in order to determine potential offshore sand resources for beach nourishment. Years 8 and 9 involved primarily the collection of all available data on the offshore geology. These data included all seismic lines, surface grab samples, and cores. The data were filtered for those that had reliable locations and geologic information that could be used for geologic investigations. Year 10 completed the investigations onshore by construction of a geologic cross-section from data along the coast of Delaware from Cape Henlopen to Fenwick. This cross section identified the geologic units and potential sand resource bodies as found immediately along the coast. These units and resources are currently being extended offshore and tied to known and potential sand resources as part of the continuing cooperative effort between the Delaware Geological Survey and the Minerals Management Service's INTERMAR office as sand resources are identified in federal waters off Delaware. Offshore sand resources are found in the Pliocene Beaverdam Formation offshore where overlying Quaternary units have been stripped, in the tidal delta complexes of several Quaternary units likely equivalent to the onshore Omar Formation, and in late Pleistocene- and Holocene-age shoal complexes. Onshore lithostratigraphic units can be traced offshore and show another reason for continued geologic mapping both onshore and offshore.The Delaware Geological Survey's participation in years 8, 9, and 10 of the Continental Margins Program was developed to extend the known resource areas onshore to offshore Delaware in order to determine potential offshore sand resources for beach nourishment. Years 8 and 9 involved primarily the collection of all available data on the offshore geology. These data included all seismic lines, surface grab samples, and cores. The data were filtered for those that had reliable locations and geologic information that could be used for geologic investigations. Year 10 completed the investigations onshore by construction of a geologic cross-section from data along the coast of Delaware from cape Henlopen to Fenwick.

Marine Georesources and Geotechnology↗
USGS2005

Water withdrawals for irrigation, municipal, mining, thermoelectric-power, and drainage uses in Arizona outside of active management areas, 1991-2000

Economic development in Arizona is largely influenced by access to adequate water supplies owing to the State's predominantly semiarid to arid climate. Water demand is met by pumping ground water from aquifers or by con­veying surface water through a system of reservoirs and canals. Water-withdrawal data provide important information on how water demand affects the State's water resources. Information on water withdrawals also can help planners and managers assess the effectiveness of water-management policies, regulations, and conservation activities. This report includes water-withdrawal data for irrigation, municipal, mining, thermoelectric-power, and drainage uses for 1991-2000, and describes the methods used to collect, compile, and estimate the data. Data are reported for the Arizona Department of Water Resources ground-water basins outside of Active Management Areas. Because of the climate, ground water and surface water are used to irrigate nearly all agricultural fields in Arizona. Irrigation accounted for the largest use of water in the study area during 1991-2000. The amount of water withdrawn for irrigation varies greatly from year to year for some of the basins, primarily because of differences in the consumptive water requirement for different crops and because of changes in irrigated acreage. The population of Arizona increased about 35 percent from 1991 to 2000-from about 3.79 million in 1991 to about 5.13 million in 2000. Correspondingly, water withdrawal for municipal use increased steadily in most of the basins during 1991-2000. Ground-water withdrawals for mining did not show any consistent trends during 1991-2000. Increases and decreases in withdrawals for mining were most likely due to variations in mineral production. Mineral prices and competition from mining in other States and foreign countries probably result in annual increases or decreases in mineral production in Arizona. Between 1991 and 2000, ground-water withdrawals for thermoelectric-power generation generally increased owing to an increase in production of electricity. Ground-water withdrawals for drainage of agricultural lands in the Lower Gila and Yuma Basins varied irregularly from year to year. Annual total water withdrawals are not presented in this report because for some years irrigation values for some of the basins are reported as "less than 1,000 acre-feet," and municipal and mining values for some of the basins are reported as "less than 300 acre-feet."

Arizona↗
USGS2026

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas↗