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Core microbiomes as a potential fingerprinting method of Western USA dust sources

Introduction: Changing frequency and intensity of dust emissions impacts ecosystems and human health. Dust carries microbes, nutrients, heavy metals, and other materials that may change environmental biogeochemistry at deposition sites. Identifying dust sources provides key information on where and when mitigation strategies should be employed. However, commonly used geochemical or isotopic tracers are often not capable of distinguishing between geographic regions. Methods: We explored whether soil bacterial communities may provide distinct fingerprints of dust sources in the western United States. We identified bacterial core communities of dust from ten locations monitored by the National Wind Erosion Research Network (NWERN) with varied land use (cropland, rangeland, and playa), and compared communities to location, soil, and regional characteristics. Samples were collected monthly from Modified Wilson and Cooke (MWAC) samplers, composited by season (spring, summer, and fall), and analyzed using 16S rRNA sequencing. Results: We found distinct bacterial core communities that reflected dust source characteristics. In order of importance, precipitation levels ( p = 0.0001), location ( p = 0.0001), soil texture ( p = 0.0001), seasonality ( p = 0.0001), and elevation (p = 0.0002) were correlated with bacterial community composition. Discussion: Distinct bacterial core communities were associated with site characteristics such as biocrusts, playas, and military base proximity. Our results suggest that the use of core microbiomes may offer a fingerprinting method to identify dust source regions.

Colorado, Nevada, New Mexico, North Dakota, Oklaho

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

The 1912 Ms 7.2 earthquake in the Denali region of central Alaska

The 2002 M w 7.9 earthquake in central Alaska ruptured 340 km on three faults—Susitna Glacier thrust fault, Denali fault, Totschunda fault—crossing both the Richardson Highway and the Alaska Pipeline. Its occurrence prompted renewed interest in historical large earthquakes that possibly originated on the Denali fault. One of these earthquakes was a M s 7.2 event on July 7, 1912, which we revisit with two approaches: (1) probabilistic relocation of the epicenter using globally recorded arrival times, and (2) compilation and reassessment of shaking intensity reports to estimate a macroseismic epicenter. Our preferred instrumental epicenter is west of the Parks Highway and in agreement with the maximum‐reported shaking, which was from the Parker–Browne expedition of Denali. We also relocated a M s 6.4 aftershock, whose epicenter is 11 km from the mainshock. Candidate faults for the 1912 earthquake include the Denali fault, the McLeod Creek thrust fault, and the Kantishna Hills thrust fault. Future analysis of active faults, paleoseismic results, 1912 instrumental data, and 1912 felt reports may help in interpreting the fault and mechanism of the 1912 earthquake.

Alaska

Explosive trachyte eruptions from the Al Efairia volcanic center in northern Harrat Rahat, Kingdom of Saudi Arabia

Harrat Rahat is an alkali basalt, continental, intraplate volcanic field located within the central-western part of the Kingdom of Saudi Arabia. The northern quarter of Harrat Rahat contains evolved volcanic products that achieve trachyte compositions (>60 weight percent SiO 2 ). Within the Al Efairia volcanic center, pyroclastic-flow and -surge deposits that reflect explosive trachyte volcanism (and minor exposed lava domes that reflect effusive trachyte eruptions) sit at the surface as the youngest expression of volcanic activity within this part of the Harrat Rahat volcanic field. Five trachyte deposits emplaced explosively have been identified within the Al Efairia volcanic center based on geologic mapping, petrography, geochemistry, and paleomagnetism. These units are the trachytes of Um Rgaibah, Gura 5, Gura 4, Al Efairia, and Al Qayf, in descending stratigraphic order. Here, we present 14 40 Ar/ 39 Ar analyses from four of these units, which yield eruption ages of 4.2±5.2 thousand years (ka) for the trachyte of Um Rgaibah, 79.7±1.6 ka for the trachyte of Gura 5, 84.3±1.6 ka for the trachyte of Gura 4, and 88.0±1.8 ka for the trachyte of Al Efairia. The eruption age of the trachyte of Al Qayf has been constrained to between 410.3±3.4 and 418.8±1.9 ka using paleomagnetic correlations and 40 Ar/ 39 Ar ages from overlying and underlying intermediate composition lava flows. Most of these trachytes have distinct geochemical compositions, petrographic characteristics, and directions of remanent magnetization. The exceptions are for the trachytes of Gura 4 and Gura 5, which overlap in their geochemical, petrographic, paleomagnetic, and geochronologic affinities. Based on these similarities, we interpret the trachytes of Gura 4 and Gura 5 to have erupted during a closely spaced (a few decades) time interval from the same magma batch but from craters that are >2 kilometers (km) apart. The eruption of the trachyte of Al Efairia at 88.0±1.8 ka is the result of a different magma batch that erupted a few thousand years prior to the trachytes of Gura 4 and Gura 5. The Al Efairia volcanic center is remarkably different from the Matan volcanic center located ~10 km to the north, which has also erupted young (<150 ka) trachytes. The Matan volcanic center has been shown to produce trachyte compositions only after eruption of basalt followed by intermediate lava flows, whereas only trachyte compositions have erupted within the Al Efairia volcanic center over this same time interval.

Al Efairia volcanic center, Harrat Rahat

Navigating uncertainty and competing objectives: Spring chinook salmon recovery in the upper Willamette river

Globally, anadromous fish populations are threatened with extinction due to multiple factors, including river impoundments that block migration, widespread alteration of physical habitat, temperature, and flow regimes, commercial and recreational harvest, changes in biological communities, and long-term climate trends. In this synthesis, we describe how physical and biological factors, policy and law, and public resource allocation affect management of spring-run Chinook Salmon ( Oncorhynchus tshawytscha ) in the Upper Willamette River (UWR), Oregon, USA. Efforts to restore salmon populations often involve trade-offs, for example, water management decisions must account for flood control, agricultural and municipal water use, and management of other species. UWR Chinook Salmon recovery efforts are also governed by multiple laws, policies, and action agencies that in some cases have incongruent objectives. Competing and conflicting objectives, combined with uncertainty regarding the outcomes of proposed management actions, create significant challenges for decision makers. Resource limitations, regulatory constraints, and incongruent objectives have created challenges for managers in the UWR, but opportunities exist for improved adaptive management and collaboration, which could build trust and engagement among stakeholders and ultimately support the successful implementation of decision tools. A suite of decision support tools that have been used in the Willamette River basin and elsewhere across the range of Pacific salmon have the potential to enhance decision processes. These tools can be effective when decision makers and stakeholders commit to long-term, collaborative utilization of the tools for decision making, and when available resources and regulatory environments are conducive to implementation and adaptive refinement of both the decision-support tools and management plans. The general biological and institutional principles discussed for UWR Chinook Salmon in this work apply more generally to populations of anadromous fishes across their range, especially to populations in highly regulated river systems.

Oregon

Geology of an area near Brentwood, Williamson County, Tennessee

The lithology and geologic structure of an area near Brentwood, Williamson County, Tennessee, were studied to define the potential aquifers and confining units of the ground-water flow system. Four formations were identified. They are, in descending order, the Bigby-Cannon Limestone, the Hermitage Formation, the Carters Limestone, and the Lebanon Limestone. The Bigby-Cannon Limestone and the Carters Limestone are potential aquifers. The Hermitage Formation and the Lebanon Limestone are confining units. The Bigby-Cannon Limestone and the Hermitage Formation have been affected by recent erosion. Any variation of the Carters Limestone is controlled by pre-Carters erosion of the top of the Lebanon Limestone. The thickness of the Carters Limestone ranges from 65 to 79 feet. Structurally, the area reflects the regional northwest dip. A small scale anti-cline-syncline pair also is evident. This feature is not a result of erosion and also occurs in the T-3 bentonite bed in the Carters Limestone.

Tennessee

Technique for simulating peak-flow hydrographs in Maryland

The efficient design and management of many bridges, culverts, embankments, and flood-protection structures may require the estimation of time-of-inundation and (or) storage of floodwater relating to such structures. These estimates can be made on the basis of information derived from the peak-flow hydrograph. Average peak-flow hydrographs corresponding to a peak discharge of specific recurrence interval can be simulated for drainage basins having drainage areas less than 500 square miles in Maryland, using a direct technique of known accuracy. The technique uses dimensionless hydrographs in conjunction with estimates of basin lagtime and instantaneous peak flow. Ordinary least-squares regression analysis was used to develop an equation for estimating basin lagtime in Maryland. Drainage area, main channel slope, forest cover, and impervious area were determined to be the significant explanatory variables necessary to estimate average basin lagtime at the 95-percent confidence interval. Qualitative variables included in the equation adequately correct for geographic bias across the State. The average standard error of prediction associated with the equation is approximated as plus or minus (+/-) 37.6 percent. Volume correction factors may be applied to the basin lagtime on the basis of a comparison between actual and estimated hydrograph volumes prior to hydrograph simulation. Three dimensionless hydrographs were developed and tested using data collected during 278 significant rainfall-runoff events at 81 stream-gaging stations distributed throughout Maryland and Delaware. The data represent a range of drainage area sizes and basin conditions. The technique was verified by applying it to the simulation of 20 peak-flow events and comparing actual and simulated hydrograph widths at 50 and 75 percent of the observed peak-flow levels. The events chosen are considered extreme in that the average recurrence interval of the selected peak flows is 130 years. The average standard errors of prediction were +/- 61 and +/- 56 percent at the 50 and 75 percent of peak-flow hydrograph widths, respectively.

Maryland

Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York

Subaerially exposed Iceberg Lake sediments: An exceptional record of historical subaqueous earthquake disturbance at the eastern edge of the Alaskan-Aleutian subduction zone

Paleoseismic records are limited in the Yakutat Terrane (eastern edge of the Alaskan-Aleutian subduction zone) due to the extensive ice cover that hinders traditional methods such as trenching of the faults, but lacustrine sediments offer an alternative archive. We investigated lakebed sediments exposed after recent outburst floods (1999 CE) at Iceberg Lake, a glacier-dammed basin whose stratigraphy was revealed after the lake drained and partially eroded. We logged outcrops across the basin and sampled their sediments. Between annually laminated background deposits, we identified sediment gravity flow beds and in-situ soft-sediment deformation structures (convolutions, sand blows, and fractures) interpreted to be earthquake-induced. Our age model links some of the uppermost depositional and deformational events to the 1958, 1964 and 1979 CE earthquakes. These results demonstrate that Iceberg Lake was a sensitive recorder of seismic shaking and its sediments hold strong potential for producing a paleoseismic record for the northern Yakutat Terrane.

Alaska

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment

Wave propagation in layered soil deposits

Recent advances in the general theory of viscoelastic waves and rays in layered media provide a rigorous mathematical framework for site-specific, soil-response models used for earthquake resistant design. The advances provide general closed-form anelastic solutions for the classic problems of the response of a stack of soil layers to S and P waves, ray theory for reflected and refracted waves, Rayleigh- and Love-Type surface waves, and head waves. These general solutions valid for anelastic media regardless of the amount of material damping yield new insights regarding the characteristics of seismic waves and their ray paths that are not provided by conventional models. They provide corresponding numerical ground-response models and ray-tracing computation algorithms that account for changes in velocity and attenuation of anelastic waves associated with changes in inhomogeneity of the waves induced by anelastic soil and soil-rock boundaries. These anelastic effects manifest themselves as variations in amplitude response, amplitude attenuation, raypath location, and travel time as observed at the Earth’s surface. Implications of these anelastic effects for soil-response models used for earthquake resistant design are provided herein.

Conference Paper

Relationship of atmospheric nitrogen deposition to soil nitrogen cycling along an elevation gradient in the Colorado Front Range

Microbial processing of atmospheric nitrogen (N) deposition regulates the retention and mobilization of N in soils, with important implications for water quality. Understanding the links between N deposition, microbial communities, N transformations, and water quality is critical as N deposition shifts toward reduced N and remains persistently high in many regions. Here, we investigated these connections along an elevation transect in the Colorado Front Range. Although rates of N deposition and pools of extractable N increased down the elevation transect, soil microbial communities and N transformation rates did not follow clear elevational patterns. The subalpine microbial community was distinct, corresponding to a high C:N ratio and low pH, while the microbial communities at the lower elevation sites were all very similar. Net nitrification, mineralization, and nitrification potential rates were highest at the Plains (1,700 m) and Montane (2,527 m) sites, suggesting that these ecosystems mobilize N. In contrast, the net immobilization of N observed at the Foothills (1,978 m) and Subalpine (3,015 m) sites suggests that these ecosystems retain N deposition. The contrast in N transformation rates between the plains and foothills, both of which receive elevated N deposition, may be due to spatial heterogeneity not captured in this study and warrants further investigation. Stream N concentrations from the subalpine to the foothills were consistently low, indicating that these soils are currently able to process and retain N deposition, but this may be disrupted if drought, wildfire, or land-use change alter the ability of the soils to retain N.

Colorado

Relationship between peak and cumulative ground motions from 49 Mw 3-6 earthquakes in the San Francisco Bay Area

We examine the relationship between peak ground velocity (PGV) and cumulative absolute displacement (CAD) for 49 M w 3 – 6 earthquakes in the San Francisco Bay Area (SFBA) and gain insight into the spatiotemporal partitioning of seismic energy in ground motion records with respect to source, path, and site effects. PGV and CAD are positively correlated, but there can be large deviations from the average trend. For example, ground motion records with either very long duration resonance or short pulse-like motions will have higher or lower CAD, respectively, but could have very similar PGV. We perform principal component analysis (PCA) on PGV-CAD for >7000 records in the SFBA with the goal of investigating what influences positive or negative anomalies in cumulative motions. PCA rotates the PGV-CAD datapoints into two principal components, where the one with the larger variance, which we call the “primary intensity” represents mostly the distance-dependence of ground motion amplitudes. The other principal component, which we call the “excess motion”, represents the deviation from cumulative motions that would be typical for a ground motion record with a given PGV. The excess motion will be positive in the case of records with long duration ringing and will be negative for short duration pulse-like ground motions. We find that excess motion is generally positive at sites in sedimentary basins and in soft sediments around the SF Bay. Excess motion is generally negative in the very near field, as well as at sites on hard bedrock. We discuss the findings here in terms of implications for seismic hazard applications and other wave propagation phenomena.

California

Evaluating Laramide orogenesis via flexural basin response in the San Juan basin, New Mexico and Colorado

A challenge in interpreting the location, timing, and magnitude of ancient orogenic events is that ongoing uplift and erosion in the hinterlands often destroys much of the primary record of these events. However, basin-thickness patterns in the sedimentary record can provide complimentary evidence of uplift via flexural effects. Here, we deploy well-log correlation, isochores, basin modeling, flexural modeling, and subcrop mapping to evaluate the Late Cretaceous to Paleogene basin response to Laramide tectonism in the San Juan basin. A wedge of upper Campanian to Maastrichtian sedimentary rock thickens from 200 to 800 meters from southeast to northwest in the basin. This pattern can be successfully simulated via flexural modeling if we infer early Laramide uplift along the northwest basin flank that produced a 0.8 km high topographic load. The Laramide unconformity bounds the top of this Upper Cretaceous sedimentary wedge and truncates progressively older strata to the east, further supporting a westward tilt of the basin. The onset of Campanian Laramide flexure may have also contributed to the profound transgression from the upper Menefee Formation to the Lewis Shale. The Paleocene isochore map displays an approximately symmetrical pattern, with thickening towards the center of the basin. This suggests the possibility of competing flexural loads. The base Eocene structure indicates an asymmetric deep on the northeast flank of the basin, providing flexural evidence of contemporaneous uplift/loading of the Nacimiento uplift and Archuleta arch; this has been modeled as ~2.1 km load height. Both Cretaceous and Paleocene sedimentary wedges are narrow, suggesting low flexural rigidity; modeled effective elastic thicknesses (EET) are 20-30 km, comparable to estimates of modern EET for the region.

Colorado, New Mexico

Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona

Helium detection as a guide for uranium exploration

Helium, a byproduct of radioactive decay, may prove to be a valuable indicator of the presence and distribution of uranium deposits. Recent technological advances permit the development of instrumentation not previously adapted for this purpose. Commercially available equipment can provide high sensitivity at low cost and allow reasonable mobility for field use. A truck-mounted mass-spectrometer, tuned for helium-4, permits immediate adjustment or modification of sampling patterns in response to accumulating data. The inlet system of the spectrometer has been designed to allow flexibility in gas analyses from various sample types--soil gas, atmosphere, or gases in water. Sensitivity of the instrument is better than 50 parts of helium per 10 9 parts of gas. Replicate samples and standards can be analyzed in only 3 minutes. Helium in soil gas is being used for the initial evaluation of the technique. A hollow probe, as much as 2 m long, is driven into the ground; and a 10-cc syringe is used to purge the probe and extract the gas. This sample is then injected into the inlet system and introduced into the spectrometer at constant pressure. The output signal is displayed on a chart recorder. Investigations can be performed on a qualitative, relative basis, or on a quantitative basis by comparison to calibrated helium standards. Preliminary field testing includes studies of the responses to variations in wind speed, temperature, barometric pressure, moisture, and sampling depth over extended time periods, as well as studies of geologic controls on the helium content in soil gas. Surveys over known uranium occurrences reveal some anomalous helium distributions. This report describes an updated technological approach to an old idea: that of using helium, a byproduct of uranium radioactive decay, as an exploration tool for uranium. Helium is the sixth most abundant gas found in the earth's atmosphere (Table 1). It is an inert gas and very mobile, mixing rapidly. When the alpha particles from the radioactive decay of uranium and thorium pick up two electrons, atoms of the isotope helium-4 are formed. Several helium-4 atoms are produced from each decay series of U-238, U-235, and Th-232 (fig. 1). The half-lives of the parent isotopes are5also shown in figure 1. One gram of uranium will produce ~10 5 atoms of helium-4 per second, and one gram of thorium produces ~2.5 x 10 4 atoms of helium-4 per second (fig. 2). Calculations of the helium produced from the crust and mantle reveal that 1,125 x 10 30 atoms per year are produced, but only 7 x 10 30 atoms per year escape from the earth (Damon and Kulp, 1958). More is being produced than is being lost; in fact, the total atmospheric content of helium could be produced in only 2 million years (MacDonald, 1963)! However, all the crustal and mantle helium-4 does not degas into the atmosphere as it is formed. It is trapped in crystal lattices and in pore spaces within the earth. What this means is that there is excess helium-4 in the earth--excess, that is, compared to the atmospheric concentration in equilibrium with the helium-4 escape rate into space and the helium-4 flux from the crust and mantle (Nicolet, 1957). Near-surface pockets of high helium-4 concentrations are known, and some natural gas fields are so enriched that they are the source for commercial production of helium. Work by Roberts and others (1975) has shown high helium concentration in the soil gas associated with geothermal areas; and work by Clark and Kugler (1973), Dyck (1975), and Goldak (1974), for example, has noted high helium concentrations in soils and waters in the vicinity of uranium deposits. These latter studies certainly indicate the potential of helium detection for use as an exploration tool for uranium.

Open-File Report