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Prolonged winter undernutrition and the interpretation of urinary allantoin:creatinine ratios in white-tailed deer

The urinary allantoin:creatinine (A:C) ratio (expressed in micromoles of allantoin to micromoles of creatinine) has shown potential as an index of recent winter energy intake in preliminary controlled studies of elk ( Cervus elaphus ) involving mild condition deterioration (up to 11% loss of body mass). To ensure reliable nutritional assessments of free-ranging cervids by measuring A:C ratios of urine in snow, it is essential to extend this work. We assessed the effect of moderate and severe winter nutritional restriction on urinary A:C ratios of captive white-tailed deer ( Odocoileus virginianus ) that lost up to 32% body mass and related these ratios to metabolizable energy intake (MEI), body-mass loss, and other reported nutritional indicators. Deer in the control group were fed a low-protein, low-energy diet ad libitum, whereas deer in the treatment group were fed restricted amounts of the same diet. MEI was below the winter maintenance requirement for all deer, but was lower ( P = 0.029) in treatment deer than in control deer. Percent body-mass loss differed between the two groups as the study progressed, and represented the full range of physiological tolerance (0-32% loss). Mean A:C ratios of control deer, which lost up to 17.4% body mass, showed a slight increasing ( P = 0.086) trend, whereas initially similar A:C ratios of severely restricted deer increased ( P = 0.0002) markedly by the eighth week (0.52 vs. 0.09 µmol:µmol). The urinary A:C ratio was not related ( P = 0.839) to recent (2 days prior to urine sampling) MEI, but there was a marginally significant relation ( r 2 = 0.42, P = 0.110) between the A:C ratio and cumulative percent mass loss. The urinary A:C ratio was directly related to urinary urea nitrogen:creatinine ( r 2 = 0.59, P < 0.0001) and 3-methylhistidine:creatinine ( r 2 = 0.43, P < 0.0001) ratios. This study confirms that elevated and increasing A:C ratios may be due either to increasing energy intake or to accelerated tissue catabolism and increased endogenous contributions to urinary allantoin excretion.

Canadian Journal of Zoology↗

Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA

Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge–magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0·5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0·1 and 0·5 mm) that have core An contents of 66–69, and microlites (long axis < 0·1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution–precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma bodies.

Journal of Petrology↗

Constraints on the composition of ore fluids and implications for mineralising events at the Cleo gold deposit, Eastern Goldfields Province, Western Australia

The Cleo gold deposit, 55 km south of Laverton in the Eastern Goldfields Province of Western Australia, is characterised by banded iron-formation (BIF)-hosted ore zones in the gently dipping Sunrise Shear Zone and high-grade vein-hosted ore in the Western Lodes. There is evidence that gold mineralisation in the Western Lodes (which occurred at ca 2655 Ma) post-dates the majority of displacement along the Sunrise Shear Zone, but it remains uncertain if the ore in both structures formed simultaneously or separately. Overall, the Pb, Nd, Sr, C. O and S isotopic compositions of ore-related minerals from both the Western Lodes and ore zones in the Sunrise Shear Zone are similar. Early low-salinity aqueous-carbonic fluids and late high-salinity fluids with similar characteristics are trapped in inclusions in quartz veins from both the Sunrise Shear Zone and the Western Lodes. The early CO2, CO2-H2O, and H2O- dominant inclusions are interpreted as being related to ore formation, and to have formed from a single low-salinity aqueous-carbonic fluid as a result of intermittent fluid immiscibility. Homogenisation temperatures indicate that these inclusions were trapped at approximately 280??C and at approximately 4 km depth, in the deeper epizonal range. Differences between the ore zones are detected in the trace-element composition of gold samples, with gold from the Sunrise Shear Zone enriched in Ni, Pb, Sn, Te and Zn, and depleted In As, Bi, Cd, Cu and Sb, relative to gold from the Western Lodes. Although there are differences in gold composition between the Sunrise Shear Zone and Western Lodes, and hence the metal content of ore fluids may have varied slightly between the different ore zones, no other systematic fluid or solute differences are detected between the ore zones. Given the fact that the ore fluids in each zone have very similar bulk properties, the considerable differences in gold grade, sulfide mineral abundance, and ore textures between the two ore zones most likely result from different gold-deposition mechanisms. The association of ore zones in the Sunrise Shear Zone with pyrite-replaced BIF suggests that wall-rock sulfidation was the most significant mechanism of gold precipitation, through the destabilisation of gold-bisulfide complexes. The Western Lodes, however, do not exhibit any host-rock preference and multistage veins commonly contain coarse-grained gold. Fluid-inclusion characteristics and breccia textures in veins in the Western Lodes suggest that rapid pressure changes, brought about by intermittent release of overpressured fluids and concomitant phase separation, are likely to have caused the destabilisation of gold-thiocomplexes, leading to formation of higher-grade gold ore zones.

Australian Journal of Earth Sciences↗

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets↗

Overview of the Spirit Mars Exploration Rover mission to Gusev Crater: Landing site to Backstay Rock in the Columbia Hills

Spirit landed on the floor of Gusev Crater and conducted initial operations on soil‐covered, rock‐strewn cratered plains underlain by olivine‐bearing basalts. Plains surface rocks are covered by wind‐blown dust and show evidence for surface enrichment of soluble species as vein and void‐filling materials and coatings. The surface enrichment is the result of a minor amount of transport and deposition by aqueous processes. Layered granular deposits were discovered in the Columbia Hills, with outcrops that tend to dip conformably with the topography. The granular rocks are interpreted to be volcanic ash and/or impact ejecta deposits that have been modified by aqueous fluids during and/or after emplacement. Soils consist of basaltic deposits that are weakly cohesive, relatively poorly sorted, and covered by a veneer of wind‐blown dust. The soils have been homogenized by wind transport over at least the several kilometer length scale traversed by the rover. Mobilization of soluble species has occurred within at least two soil deposits examined. The presence of monolayers of coarse sand on wind‐blown bedforms, together with even spacing of granule‐sized surface clasts, suggests that some of the soil surfaces encountered by Spirit have not been modified by wind for some time. On the other hand, dust deposits on the surface and rover deck have changed during the course of the mission. Detection of dust devils, monitoring of the dust opacity and lower boundary layer, and coordinated experiments with orbiters provided new insights into atmosphere‐surface dynamics.

Journal of Geophysical Research E: Planets↗

Paleomagnetic data bearing on style of Miocene deformation in the Lake Mead area, Southern Nevada

Paleomagnetic and structural data from intermediate to mafic composition lava flows and related dikes in all major blocks of the late Miocene Hamblin-Cleopatra Volcano, which was structurally dismembered during the development of the Lake Mead Fault System (LMFS), provide limits on the magnitude and sense of tilting and vertical axis rotation of crust during extension of this part of the Basin and Range province. Sinistral separation along the fault system dissected the volcano into three major blocks. The eastern, Cleopatra Lobe of the volcano is structurally the most intact section of the volcano. Normal and reverse polarity data from paleomagnetic sites collected along traverses in the Cleopatra Lobe yield an in situ grand mean of Declination (D) = 339??, Inclination (I) = +54??, ??95 = 3.1??, k = 27.2, N = 81 sites. The rocks of the central core of the volcano yield an in situ grand mean of D = 3??, I = + 59??, ??95 = 6.8??, k = 42.5, N = 11 sites (six normal, five reverse polarity). Sites collected within the western Hamblin Lobe of the volcano are exclusively of reverse polarity and yield an overall in situ mean of D = 168??, I = -58??, ??95 = 6.5??. k = 28.9, N = 18 sites. Interpretation of the paleomagnetic data in the context of the structural history of the volcano and surrounding area, considers the possibility of two different types of structural corrections. A stratigraphic tilt correction involves restoring flows to the horizontal using the present strike. This correction assumes no initial, possibly radial, dip of flows of the volcano and is considered invalid. A structural tilt correction to the data assumes that dikes of the radiating swarm associated with the volcano were originally vertical and results in block mean directions of D = 9??, I = +53??, ??95 = 3.1??, k = 27.2, and D = 58??, I = + 78??, ??95 = 6.8, k = 42.5, for the Cleopatra Lobe and the central intrusive core, respectively. The data from the Cleopatra Lobe are slightly discordant, in a clockwise sense, from expected middle- to late-Miocene field directions. The data from the volcano are not consistent with a proposed structural model of uniform, moderate magnitude, statistically significant, counter-clockwise vertical axis rotation of fault-bounded blocks during overall sinsitral displacement along the LMFS. We also analyzed dikes of the northernmost part of the Miocene Wilson Ridge hypabyssal igneous complex, strata of the Triassic Chinle Formation, and basalt flows of the Miocene West End Wash/Callville Mesa volcanic centers. Dikes in the Wilson Ridge pluton and the Triassic strata yield magnetizations with directions suggestive of statistically significant, clockwise, vertical-axis rotations consistent with local, large-magnitude shear of crustal fragments near some of the faults of the LMFS. Late Cenozoic deformation of the Hamblin-Cleopatra volcano area appears to have been non-uniform in scale and magnitude and no single structural model, involving strictly strike-slip faulting, can account for the observed paleomagnetic data. ?? 2001 Elsevier Science Ltd. All rights reserved.

Journal of Structural Geology↗

The 40Ar/39Ar thermochronology of the eastern Mojave Desert, California, and adjacent western Arizona with implications for the evolution of metamorphic core complexes

Mesozoic thickening and Cenozoic extension resulted in the juxtaposition of upper and middle crustal rocks in the eastern Mojave Desert, southeastern California and western Arizona. The application of 40 Ar/ 39 Ar thermochronology to rocks in this region provides information about the timing and nature of thrusting, plutonism, metamorphism, denudation, and detachment faulting. The 40 Ar/ 39 Ar ages of 175 to 125 Ma from the Clipper, Piute, Turtle, Mohave, Bill Williams, and Hualapai Mountains are interpreted to be the result of a middle Mesozoic thermal event(s) caused by crustal thickening. The 40 Ar/ 39 Ar data from the Clipper and Piute Mountains suggest that this thermal event was followed by a period of cooling at rates of 1°–5°C/m.y. Orogenesis culminated during the Late Cretaceous when rocks exposed in the Old Woman‐Piute, Chemehuevi, and Sacramento Mountains attained temperatures >500°C which reset the K–Ar systems of minerals from Proterozoic rocks. High‐grade metamorphism in the Old Woman Mountains area was caused by the intrusion of the Old Woman‐Piute batholith at 73±1 Ma. Cooling rates following batholith emplacement in the Old Woman Mountains were ∼100°C/m.y. between 73 and 70 Ma and 5°–10°C/m.y. from 70 to ∼30 Ma. Between 65 and 25 Ma the entire eastern Mojave Desert underwent a period of cooling at a rate of 2°–10°C/m.y. By 30 Ma, rocks exposed in the Old Woman‐Piute, Marble, Ship, Clipper, and Turtle Mountains were below ∼100°C. The 40 Ar/ 39 Ar ages from the Sacramento Mountains suggest that mylonitization caused by the onset of regional extension occurred at 23±1 Ma. When extension started in the Chemehuevi Mountains, rocks exposed in the southwestern and northeastern portions of footwall to the Chemehuevi detachment fault were at ∼180°C and ∼350°C, respectively. This suggests that the exposed part of the Chemehuevi detachment fault initiated at a dip of 5°–30° or as a series of higher‐angle faults that cut to a depth of 10–12 km and were later rotated to their present dip. Unroofing of the footwalls to detachment faults in the Sacramento and Chemehuevi Mountains resulted in average cooling rates of 10°–50°C/m.y. between 22 and 15 Ma.

California↗

Insights into glendonite formation from the upper Oligocene Sagavanirktok Formation, North Slope, Alaska

The type locality for the upper Oligocene Nuwok Member of the Sagavanirktok Formation (Carter Creek, North Slope, Alaska, USA) contains abundant occurrence of glendonite, a pseudomorph after the calcium carbonate mineral ikaite, which typically forms in the shallow subsurface of cold marine sediments. The region during the time of Nuwok Member deposition was located at a high latitude, similar to today, and the study site is characterized by sands and silty muds interpreted here to have been deposited in coastal and shelfal marine environments. Isotopic (Sr) and biostratigraphic (foraminifera) evidence presented here refine the depositional age of the outcrop to approximately 24 Ma. Glendonites occur in two basic forms: radial clusters, commonly centered around a single larger primary crystal ( approx. 10 cm; Type A) and larger single blades generally without accessory crystals (approx. 15–25 cm; Type B). Microscopic examination revealed a sequence of multiple types of replacive calcite that formed as a direct result of ikaite transformation: Type 1 rhombohedral crystals characterized by microporous and inclusion-rich cores and concentric zones, Type 2A, composed of clear calcite that overgrew and augmented Type 1 crystals, and inclusion-rich, microcrystalline Type 2B, which formed a matrix surrounding the rhombs and commonly dominates the outer rims of glendonite specimens. Type 3 calcite precipitated as fibrous, botryoidal epitaxial cement atop previous phases and is not ikaite-derived. These phases are distributed in similar ways in all examined specimens and are consistent with several previously described glendonite occurrences around the world, despite differing diagenetic and geologic histories. Stable isotope evidence (δ13C and δ18O) suggests sourcing of glendonite carbon from both organic and methanogenic sources. Glendonites of the Nuwok Member can therefore assist in the determination of a more comprehensive ikaite transformation model, improving our understanding of glendonite formation and the sedimentological and environmental context of their occurrence. Oligocene glendonites are uncommon globally; the well-preserved occurrence described here can allow future studies to better reconstruct Arctic environmental conditions and paleoclimates during this time.

Alaska↗

Use of geoelectrical methods in groundwater pollution surveys in a coastal environment

The pollution of coastal aquifers by old landfills can contaminate valuable and scarce water resources in the freshwater lens utilized seasonably by overcrowded communities. The pollutants will ultimately flow into the sea where they may also cause a coastal water pollution problem. We have detected pollution in the freshwater lens from a sanitary landfill near Provincetown, Cape Cod, using the geoelectrical resistivity method. This survey included Schlumberger geoelectrical depth soundings and a horizontal geoelectrical profile using the Wenner configuration. The geoelectrical survey was conducted at a site along Highway 6 where it passes the coastal town of Provincetown and a sanitary landfill that has been in operation since 1954. The depth soundings suggest the characteristic decrease in resistivity vs. depth from the high resistivity of the unsaturated zone to the low resistivity of the saltwater saturated zone. The freshwater lens is clearly identified by the change in slope of the steeply dipping curve of resistivity versus electrode spacing. Interpretations made using a multilayer program, Geomate, resulted in layer resistivities between 460 and 95 ohm?m for the freshwater lens. A comparison with well water resistivities suggests that a layer resistivity of 230 ohm?m or lower is indicative of pollution in the freshwater lens. The results of the geoelectrical depth soundings were confirmed in the Wenner horizontal profile. Both measurements suggest that the pollutants do not spread evenly as one would expect for a homogeneous and isotropic medium. Instead, a preferred channel for the flow of the pollutants is observed along a path from the landfill toward the shoreline. The depth to the saltwater/freshwater interface or, more specifically, to the low resistivity-high resistivity interface appears to be shallow where the freshwater lens is polluted. This was confirmed by pore water well samples that were highly mineralized. The equilibrium postulated by the Ghyben-Herzberg relation appears to be disturbed in the area of aquifer pollution. This rise in the conductivity boundary is caused by the highly mineralized bottom of the contaminant plume that submerges into the saltwater saturated zone. In the area of high freshwater pollution the groundwater can be subdivided into three layers that show a decrease in resistivity with depth. The formation factor, F, defined as the ratio of bulk aquifer resistivity to pore water resistivity, shows unusually high values between 10 and 12. These high values are unexpected for an unconsolidated sand. Pollution residues are suspected to clog the pores and thus to increase the resistivity. It is possible that iron-oxidizing bacteria and the precipitation of dissolved iron or organic pollutants are the cause of the high values of F. If proven correct, these interesting possibilities could lead to future new applications of the geoelectrical resistivity method in contaminant hydroloy.

Journal of Applied Geophysics↗

An axial view of a metamorphic core complex: Crustal structure of the Whipple and Chemehuevi Mountains, southeastern California

A 135‐km‐long, NW‐SE trending, seismic refraction/wide‐angle reflection profile provides a unique along‐strike view of the crustal structure of a belt of metamorphic core complexes in southeastern California: the Whipple, Chemehuevi, and Sacramento mountains metamorphic core complexes. Interpretation of the seismic data was done by two‐dimensional forward modeling of travel times and amplitudes. The final model consists of (1) a thin (< 1.5 km) veneer of upper plate and fractured lower plate rocks (velocities of 1.5–5.3 km s −1 ) overlying a fairly homogeneous basement with velocities of 6.0 km s −1 ; (2) a localized, high‐velocity (6.4 km s −1 ) body, situated directly beneath the Whipple Mountains; (3) a 6.3–6.4 km s −1 middle crust that is thickest beneath the core complexes; (4) a 6.65±0.15 km s −1 lower crust; (5) crustal thickness of 27 km with a deeper crustal root (3 km) beneath the Whipple Mountains metamorphic core complex; and (6) a P n velocity of 8.0±0.10 km s −1 . The crustal structure that underlies the belt of metamorphic core complexes provides new insights into the processes that control extension in the deep crust. Upper crustal velocities are higher beneath the Whipple Mountains (where velocities increase to 6.4 km s −1 at ∼5 km depth) than beneath the Chemehuevi and Sacramento mountains. In addition, midcrustal discontinuities rise 2–5 km beneath the Whipple complex compared to the other complexes. These observations support greater uplift and a slightly deeper midcrustal origin for the rocks now exposed in the core of the Whipple Mountains compared to rocks in the Chemehuevi and Sacramento mountains. Despite the enhanced uplift and extension in the Whipple Mountains, the crust is thicker here (30 km) than anywhere else along the Colorado River extensional corridor. This may be in part a relic of compressional and magmatic thickening during the Mesozoic. However, we suggest that inflation of the crust during Tertiary extension was the dominant mechanism. Both mantle‐derived magmatism and lateral ductile inflow in the crust are proposed.

Arizona, California↗

Igneous history of the Koyukuk terrane, western Alaska: Constraints on the origin, evolution, and ultimate collision of an accreted island arc terrane

The Koyukuk terrane of western Alaska consists of volcanic, volcaniclastic, and plutonic rocks which range from Late Paleozoic to Early Cretaceous in age. The terrane crops out in a U-shaped belt which is roughly paralleled by outer belts of ultramafic rocks, oceanic plate basalts and cherts, and retrograded blueschist facies rocks of continental protolith. These rocks have been interpreted as components of a volcanic arc terrane that collided with the North American continental margin in Early Cretaceous time. The Koyukuk terrane consists of four time-stratigraphic units: (1) pre-Middle Jurassic basalts, (2) Middle and Late Jurassic granitic rocks, (3) lower Lower Cretaceous volcanic rocks, and (4) upper Lower Cretaceous volcanic rocks. Limited chemical data from the basalts of unit 1 indicate that they were erupted in a nonarc tectonic environment, possibly in an oceanic island or back arc setting. Units 2, 3, and 4 have the characteristics of subduction-related volcanic rocks (i.e., depleted Nb and Ta and enriched alkaline elements, relative to the light rare earth elements). Unit 3 contains tholeiitic, calc-alkaline, and alkaline rocks with chondrite-normalized rare earth element patterns that range from flat (La N /Yb N = 1) to highly light rare earth element enriched (La N /Yb N > 15). The highly alkaline or shoshonitic lavas were erupted toward the end of unit 3 time (Valanginian) during the final stages of arc-continent collision. These alkaline lavas could have been derived by very small degrees of partial melting of a similar source to that of the earlier arc lavas. Unit 4 lavas are also alkaline or shoshonitic, but their incompatible element composition indicates that they were derived from a different source than that of the earlier arc lavas. These late alkaline lavas are chemically similar to crosscutting mid-Cretaceous plutons whose isotopic compositions (Arth et al., this issue ( a )) suggest derivation by partial melting of distinctly older subcontinental lithosphere. We speculate that the parental magmas of unit 4 lavas may also have been derived by partial melting of this subcontinental mantle which was underthrust beneath the Koyukuk arc terrane during the final stage of arc-continent collision.

Journal of Geophysical Research Solid Earth↗

SHRIMP U-Pb evidence for a Late Silurian age of metasedimentary rocks in the Merrimack and Putnam-Nashoba terranes, eastern New England

U-Pb ages of detrital, metamorphic, and magmatic zircon and metamorphic monazite and titanite provide evidence for the ages of deposition and metamorphism of metasedimentary rocks from the Merrimack and Putnam-Nashoba terranes of eastern New England. Rocks from these terranes are interpreted here as having been deposited in the middle Paleozoic above Neoproterozoic basement of the Gander terrane and juxtaposed by Late Paleozoic thrusting in thin, fault-bounded slices. The correlative Hebron and Berwick formations (Merrimack terrane) and Tatnic Hill Formation (Putnam-Nashoba terrane), contain detrital zircons with Mesoproterozoic, Ordovician, and Silurian age populations. On the basis of the age of the youngest detrital zircon population (???425 Ma), the Hebron, Berwick and Tatnic Hill formations are no older than Late Silurian (Wenlockian). The minimum deposition ages of the Hebron and Berwick are constrained by ages of cross-cutting plutons (414 ?? 3 and 418 ?? 2 Ma, respectively). The Tatnic Hill Formation must be older than the oldest metamorphic monazite and zircon (???407 Ma). Thus, all three of these units were deposited between ???425 and 418 Ma, probably in the Ludlovian. Age populations of detrital zircons suggest Laurentian and Ordovician arc provenance to the west. High grade metamorphism of the Tatnic Hill Formation soon after deposition probably requires that sedimentation and burial occurred in a fore-arc environment, whereas time-equivalent calcareous sediments of the Hebron and Berwick formations probably originated in a back-arc setting. In contrast to age data from the Berwick Formation, the Kittery Formation contains primarily Mesoproterozoic detrital zircons; only 2 younger grains were identified. The absence of a significant Ordovician population, in addition to paleocurrent directions from the east and structural data indicating thrusting, suggest that the Kittery was derived from peri-Gondwanan sources and deposited in the Fredericton Sea. Thus, the Kittery should not be considered part of the Laurentian-derived Merrimack terrane; it more likely correlates with the early Silurian Fredericton terrane of northeastern New England and Maritime Canada.

American Journal of Science↗

Wildfire reveals transient changes to individual traits and population responses of a native bumble bee ( Bombus vosnesenskii )

1. Fire-induced changes in the abundance and distribution of organisms, especially plants, can alter resource landscapes for mobile consumers driving bottom-up effects on their population sizes, morphologies, and reproductive potential. We expect these impacts to be most striking for obligate visitors of plants, like bees and other pollinators, but these impacts can be difficult to interpret due to the limited information provided by forager counts in the absence of survival or fitness proxies. 2. Increased bumble bee worker abundance is often coincident with the pulses of flowers that follow recent fire. However, it is unknown if observed postfire activity is due to underlying population growth or a stable pool of colonies recruiting more foragers to abundant resource patches. This distinction is necessary for determining the net impact of disturbance on bumble bees: are there population-wide responses or do just a few colonies reap the rewards? 3. We estimated colony abundance before and after fire in burned and unburned areas using a genetic mark-recapture framework. We paired colony abundance estimates with measures of body size, counts of queens, and estimates of foraging and dispersal to assess changes in worker size, reproductive output, and landscape-scale movements. 4. Higher floral abundance following fire not only increased forager abundance, but also the number of colonies from which those foragers came. Importantly, despite a larger population size we also observed increased mean worker size. Two years following fire, queen abundance was higher in both burned and unburned sites, potentially due to the dispersal of queens from burned into unburned areas. The effects of fire were transient; within two growing seasons, worker abundance was substantially reduced across the entire sampling area and body sizes were similar between burned and unburned sites. 5. Our results reveal how disturbance can temporarily release populations from resource limitation, boosting the genetic diversity, body size, and reproductive output of populations. Given that the effects of fire on bumble bees acted indirectly through pulsed resource availability, it is likely our results are generalizable to other situations, such as habitat restorations, where resource density is enhanced within the landscape.

California↗

Mathematical modelling of anisotropy of illite-rich shale

The estimation of illite-rich shale anisotropy to account for the alignment of clays and gas- or brine-filled cracks is presented via mathematical modelling. Such estimation requires analysis to interpret the dominance of one effect over another. This knowledge can help to evaluate the permeability in the unconventional reservoir, stress orientation, and the seal capacity for the conventional reservoir. Effective media modelling is used to predict the elastic properties of the illite-rich shale and to identify the dominant contributions to the shale anisotropy. We consider two principal reasons of the shale anisotropy: orientation of clay platelets and orientation of fluid-filled cracks. In reality, both of these two factors affect the shale anisotropy. The goal of this study is, first, to separately analyse the effect of these two factors to reveal the specific features in P- and S-wave velocity behaviour typical of each of the factors, and, then, consider a combined effect of the factors when the cracks are horizontally or vertically aligned. To do this, we construct four models of shale. The behaviour of P- and S-wave velocities is analysed when gas- and water-filled cracks embedded in a host matrix are randomly oriented, or horizontally or vertically aligned. The host matrix can be either isotropic or anisotropic (of VTI symmetry). In such a modelling, we use published data on mineralogy and clay platelet alignment along with other micromechanical measurements. In the model, where the host matrix is isotropic, the presence of a singularity point (when the difference V S1 - V S2 changes its sign) in shear wave velocities is an indicator of brine-filled aligned cracks. In the model with the VTI host matrix and horizontally aligned cracks filled with gas, an increase in their volume concentration leads to that the azimuth at which the singularity is observed moves toward the symmetry axis. In this case, if the clay content is small (around 20 per cent), the singularity point may even vanish. The Thomsen parameters are helpful in fluid type indication in shale. An indicator of gas-filled aligned cracks is ?? > ??. If aligned cracks in illite-rich shale are brine-filled, ?? < ??. Negative value of ?? indicates brine-filled cracks in illite-rich shale. A shale with brine-filled cracks exhibits higher V p /V s ratio in the vertical direction as compared to the gas-filled shale. A disorientation of clay platelets and brine-filled cracks may lead to that the singularity point is absent for brine-saturated shale as well. In this case one can also observe ?? > ?? and decreased values of V p /V s in the vertical direction as in the case of gas-filled cracks. In the presence of vertically aligned cracks, shales exhibit distinctly revealed features of orthorhombic symmetry. The results have important applications where seismic measurements are applied to predict the maturity state of the shale. ?? 2009 The Authors Journal compilation ?? 2009 RAS.

Conference Paper↗

The Yellowstone-Snake River Plain seismic profiling experiment: Crustal structure of the Eastern Snake River Plain

Seismic refraction profiles recorded along the eastern Snake River Plain (ESRP) in southeastern Idaho during the 1978 Yellowstone-Snake River Plain cooperative seismic profiling experiment are interpreted to infer the crustal velocity and attenuation (Q-1) structure of the ESRP. Travel-time and synthetic seismogram modeling of a 250 km reversed refraction profile as well as a 100 km detailed profile indicate that the crust of the ESRP is highly anomalous. Approximately 3 to 6 km of volcanic rocks (with some interbedded sediments) overlie an upper-crustal layer (compressional velocity ≅6.1 km/s) which thins southwestward along the ESRP from a thickness of 10 km near Island Park Caldera to 2 to 3 km beneath the central and southwestern portions of the ESRP. An intermediate-velocity (≅6.5 km/s) layer extends from ≅10 to ≅20 km depth. A thick (≅22 km) lower crust of compressional velocity 6.8 km/s, a total crustal thickness of ≅42 km, and a P n velocity of ≅7.9 km/s is observed in the ESRP, similar to the western Snake River Plain and the Rocky Mountains Provinces. High attenuation is evident on the amplitude corrected seismic data due to low-Q values in the volcanic rocks (Q p = 20 to 200) and throughout the crust (Q p = 160 to 300). Based on these characteristics of the crustal structure and volcanic-age progression data, it is suggested that the ESRP has resulted from an intensive period of intrusion of mantle-derived basaltic magma into the upper crust generating explosive silicic volcanism and associated regional uplift and caldera collapse. This activity began about 15 m.y. ago in southwestern Idaho and has migrated northeast to its present position at Yellowstone. Subsequent cooling of the intruded upper crust results in the 6.5 km/s velocity intermediate layer. Crustal subsidence and periodic basaltic volcanism as represented by the ESRP complete the sequence of crustal evolution.

Journal of Geophysical Research B: Solid Earth↗

Multiple-bench architecture and interpretations of original mire phases - Examples from the Middle Pennyslvanian of the Central Appalachian Basin, USA

Coal seams often exhibit lateral and vertical variability in composition. When sampled as a whole seam this variability is masked. But if a seam is subdivided into correlateable components, this variability can be tested and better understood. Herein, an architectural approach is used to divide seams into intra-seam components. Clastic splits and mineral partings, as well as persistent fusain and durain layers, can be used as intra-seam bounding units to subdivide a seam into subdivisions called benches. Regional examination of Lower and Middle Pennsylvanian-age coal seams shows that many contain laterally persistent bounding surfaces that can be used to define multiple benches of coal within each seam. Inter-bench analyses from some of the most extensively mined seams in the central Appalachian Basin show that individual benches often have different spatial and quality trends. Hence, some component of whole-seam variability is a function of changes in the relative contribution of these different benches to the seam as a whole. Many coal benches also exhibit intra-bench variation in coal parameters. Intra-bench variation can be analyzed in terms of parameters such as sulfur content and ash yield in order to address changes in coal quality for regional resource evaluation. Intra-bench variation can also be analyzed in terms of a combination of palynologic, petrographic, and geochemical parameters, termed compositional groups, in order to better understand the development of the original mire systems. Compositional groups are defined by ranges of multiple criteria, which are inferred to owe their origin to the mire type in which they formed. Vertical changes in compositional groups within coal benches can be used to infer paleo-edaphic conditions during peat accumulation. If seam thickness is a product of bench configuration, and trends in compositional groups occur in benches, then trends in quality can be marginally predicted based upon seam thickness and inferred bench architecture. Additionally, changes in inter-bench and intra-bench thickness and compositional profiles can be used to infer original depositional controls, such as paleotopography, syndepositional structural movement, and syndepositional clastic influx for more accurate reserve estimates. ?? 2002 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology↗

Spawning activity of paddlefish (Polyodon spathula) in the lower Black River, Wisconsin

We present indirect evidence of successful paddlefish ( Polyodon spathula reproduction in 1989 and 1991 in the lower Black River, Wisconsin, about 5 km upstream of the confluence with the upper Mississippi River. This is the first indication of successful reproduction by paddlefish at the northern end of its range in the central United States. Attempts to document paddlefish Polyodon spathula reproduction by sampling eggs and larvae began in the early 1900s (e.g., Stockard 1907), but the exact timing and location of fish spawning were unknown until the early 1960s. Actual spawning by paddlefish was first observed over gravel bars in the Osage River, Missouri, by Purkett (1961), who then collected eggs and larvae. Paddlefish eggs and larvae have since been collected below dams on the Missouri (Ruelle and Hudson 1977, Unkenholz 1982), Cumberland, and Tennessee Rivers (Pasch et al. 1980, Wall us 1986). However, the spawning areas for most paddlefish populations remain unknown. Because larval paddlefish are rarely sampled, the presence of post-larval and juvenile paddlefish is often interpreted as indirect evidence of successful reproduction. Such evidence has been used in Illinois (Adams 1942), Oklahoma (Houser and Bross 1959), the Missouri River along the Nebraska-South Dakota border (Ruelle and Hudson 1977), Pool 13 of the upper Mississippi River (Gengerke 1978), and Louisiana (Reed et al. 1992) to document successful paddlefish reproduction. We gathered similar evidence from the lower Black River, near La Crosse, Wisconsin. This information is important because Wisconsin represents the northern limit for paddlefish in the central United States (Gengerke 1986) and because attempts to document reproduction by the few remaining localized populations in the state have been unsuccessful (Lyons, In press). Additionally, paddlefish are of special concern in Wisconsin because of low numbers and limited distribution (Johnson 1987). During November 1990, we observed a small paddlefish (about 700 mm total length, TL) in the catch of commercial seine fishermen working in the lower Black River (about 5 km upstream from its confluence with the Mississippi River). On April 15, 1992, commercial fishermen working the same section of the Black River found five small paddlefish (<350 mm TL) in their catch. Additionally, three small paddlefish (about 800 mm TL) were taken on December 28, 1992, during commercial seining operations in the lower Black River. In Pool 13 of the upper Mississippi River, age-1 paddlefish averaged 498 mm fork length (Gengerke 1978), and the growth of paddlefish is faster in backwaters than in the main channel (Rosen 1976, Russell 1986). Therefore, we think that the three 800-mm paddlefish taken on December 28, 1992 were age-1 fish that hatched during spring 1991 near the Lake Onalaska spillway on the lower Black River. We also think that the 700-mm paddlefish observed in November 1990 was an age-1 fish that had hatched in the same area during spring 1989.

Journal of Freshwater Ecology↗

Stratigraphy, conodont dating, and paleotectonic interpretation of the type Milligen Formation (Devonian), Wood River area, Idaho

The Milligen Formation at and near its type locality in the Wood River area is considerably older than and unrelated to rocks of Early Mississippian age called Milligen Formation in the Lost River Range and other ranges of east-central Idaho. Conodont faunas were found in limestones of a thin upper member of the sparsely fossiliferous marine Milligen Formation in its principal reference section at Milligen Gulch, at Fisher Canyon, and near Bellevue, Idaho. The faunas include indigenous conodonts here assigned to the early Late Devonian (early Frasnian) Lower and Middle Polygnathus asymmetricus Zones, and reworked conodonts derived from several Middle and Early Devonian conodont zones. An underlying much thicker argillite member of the Milligen contains fewer limestones, but a thin encrinite interbed near the middle of the member yielded early Middle Devonian (Eifelian) conodonts. This lower member probably represents most of Middle and Early Devonian time. Although its base is nowhere exposed in the Wood River area, the Milligen is inferred to have been deposited on the Silurian Trail Creek Formation, which crops out just to the east in the Pioneer Mountains. The age of the Milligen is therefore wholly Devonian and the highest fossiliferous beds are no younger than early Late Devonian. Reworked Middle and Early Devonian conodonts in limestone turbidites of the upper member of the Milligen Formation are identical to conodonts found in shelf (miogeosynclinal) carbonate rocks farther east. A postulated eastern source for the turbidites is supported by new data on the distribution, thickness, and tectonic facies of Devonian rocks that suggest the presence of a Late Devonian ridge on the continental shelf east of the Milligen depositional area. The Milligen Formation was intensely folded and was emergent during most of the Mississippian time when it formed part of the Antler Highlands, which shed flysch sediments eastward into the Copper basin. The Wood River Formation of Pennsylvanian and Permian age was then deposited over a subdued topography on the Milligen Formation. The Hailey Conglomerate Member at the base of the Wood River filled many irregularities in the surface. This depositional contact later was largely destroyed and the contact between the Milligen and Wood River is now a regional thrust fault at most places.

Idaho↗