SEARCH · USGS Science

Results for “Atmosphere - Ocean”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,081 records · Page 60Linked to original sources

USGS2007

Water Budgets: Foundations for Effective Water-Resources and Environmental Management

INTRODUCTION Water budgets provide a means for evaluating availability and sustainability of a water supply. A water budget simply states that the rate of change in water stored in an area, such as a watershed, is balanced by the rate at which water flows into and out of the area. An understanding of water budgets and underlying hydrologic processes provides a foundation for effective water-resource and environmental planning and management. Observed changes in water budgets of an area over time can be used to assess the effects of climate variability and human activities on water resources. Comparison of water budgets from different areas allows the effects of factors such as geology, soils, vegetation, and land use on the hydrologic cycle to be quantified. Human activities affect the natural hydrologic cycle in many ways. Modifications of the land to accommodate agriculture, such as installation of drainage and irrigation systems, alter infiltration, runoff, evaporation, and plant transpiration rates. Buildings, roads, and parking lots in urban areas tend to increase runoff and decrease infiltration. Dams reduce flooding in many areas. Water budgets provide a basis for assessing how a natural or human-induced change in one part of the hydrologic cycle may affect other aspects of the cycle. This report provides an overview and qualitative description of water budgets as foundations for effective water-resources and environmental management of freshwater hydrologic systems. Perhaps of most interest to the hydrologic community, the concepts presented are also relevant to the fields of agriculture, atmospheric studies, meteorology, climatology, ecology, limnology, mining, water supply, flood control, reservoir management, wetland studies, pollution control, and other areas of science, society, and industry. The first part of the report describes water storage and movement in the atmosphere, on land surface, and in the subsurface, as well as water exchange among these compartments. Our ability to measure these phenomena and inherent uncertainties in measurement techniques also are discussed. The latter part of the report presents a number of case studies that illustrate how water-budget studies are conducted, documents how human activities affect water budgets, and describes how water budgets are used to address water and environmental issues.

Circular↗

USGS1984

Acid precipitation; an annotated bibliography

This collection of 1660 bibliographies references on the causes and environmental effects of acidic atmospheric deposition was compiled from computerized literature searches of earth-science and chemistry data bases. Categories of information are (1) atmospheric chemistry (gases and aerosols), (2) precipitation chemistry, (3) transport and deposition (wet and dry), (4) aquatic environments (biological and hydrological), (5) terrestrial environments, (6) effects on materials and structures, (7) air and precipitation monitoring and data collection, and (8) modeling studies. References date from the late 1800 's through December 1981. The bibliography includes short summaries of most documents. Omitted are unpublished manuscripts, publications in press, master 's theses and doctoral dissertations, newspaper articles, and book reviews. Coauthors and subject indexes are included. (USGS)

Circular↗

USGS2014

A 19-year record of chemical and isotopic composition of water from springs of the Shenandoah National Park, Virginia, 1995-2014

During October 1995 through March 2014, the U.S. Geological Survey in cooperation with the National Park Service, Luray, Virginia Station collected and analyzed samples of selected springs, air and unsaturated-zone gases in Shenandoah National Park, Virginia. The 19-year record of measurements of chemical and isotopic composition of water discharging from 34 springs located along the crest of the Blue Ridge Mountains in Shenandoah National Park, Virginia, is reported. These data include field measurements of water temperature, specific conductance, concentrations of dissolved oxygen (O 2 ), and pH. Laboratory measurements included major-, minor-, and trace-element chemistry; concentrations of dissolved gases (nitrogen, [N 2 ] argon [Ar], oxygen, and carbon dioxide [CO 2 ]); concentrations of dissolved trace atmospheric gases, including trichlorofluoromethane (CFC-11), dichlorodifluoromethane (CFC-12), and trichlorotrifluoroethane (CFC-113) and sulfur hexafluoride (SF 6 ); and hydrogen stable isotopic composition (δ 2 H) and oxygen isotopic composition (δ 18 O) of water. The data include an up to 14-year time series record of monthly sampling at five springs collected between 1995 and 2013. The measurements included temperature, specific conductance, pH, and discharge recorded at 30-minute intervals. Atmospheric mixing ratios of CFC-11, CFC-12, CFC-113, trifluorobromomethane (CF 3 Br), SF 6 , and trifluoromethyl sulfur pentafluoride (SF 5 CF 3 ) in air from the Big Meadows Air Monitoring Station, Shenandoah National Park, were measured at approximately weekly intervals from September 1995 through March 2014. Additional data include monthly (between May 2001 and August 2003) measurements of temperature, N 2 , O 2 , Ar, CO 2 , CFC-12, CFC-11, CFC-113, and SF 6 concentrations in unsaturated-zone air from seven multilevel piezometers in Shenandoah National Park and at the U.S. Geological Survey National Center in Reston, Virginia. All samples were analyzed at the U.S. Geological Survey Laboratories in Reston, Virginia.

Virginia↗

USGS1999

Trends in precipitation and stream-water chemistry in the northeastern United States, water years 1984-96

Trends in precipitation and stream-water chemistry during water years 1984-96 were examined at eight precipitation monitoring sites and five nearby streams operated by the U.S. Geological Survey in the northeastern United States. The statistical analyses indicate the following: 1)Stream-water sulfate (SO4) concentrations decreased at seven of eight precipitation monitoring sites and in each of five streams. 2)Calcium plus magnesium (Ca + Mg) concentrations decreased at seven of eight precipitation monitoring sites and in three of five streams. 3)Precipitation acidity decreased at five of eight precipitation monitoring sites, but alkalinity increased in only one stream. These results indicate that decreases in atmospheric deposition of SO4 have resulted in decreased precipitation acidity. The chemical response of stream water to changes in precipitation chemistry was complex. Decreases in stream-water SO4 concentrations generally matched decreases of precipitation SO4. In stream water, increases in alkalinity were uncommon because decreases in SO4 concentrations often were accompanied by decreases in Ca + Mg concentrations. The decreases in Ca + Mg concentrations might be related to depletion of base cations from soil caused by long-term exposure to acidic deposition. Increases in streamwater alkalinity might not occur until rates of acidic deposition are reduced to substantially less than the rate of cation resupply by weathering and atmospheric deposition. In areas where forests are aggrading, recovery of stream-water alkalinity will be delayed further because of the acidifying effect of biomass accumulation.

Fact Sheet↗

USGS1998

Nutrient sources within the Upper Mississippi River Basin, Minnesota and Wisconsin, 1991-93

The amount of nutrients contained in fertilizer, livestock manure, municipal wastewater, atmospheric deposition, and legume residues were quantified in each of the major drainage basins within the Upper Mississippi River Basin study unit (fig. 1) as part of the U.S. Geological Survey's National Water-Quality Assessment Program. These sources of nutrients may potentially affect surface- and ground-water quality, so knowledge about the relative importance of each source may assist in the management of surface and ground waters within the study unit. The relative importance of each nutrient source was expected to vary among each of the four drainage basins due to differences in land use across the study unit. Fertilizer and livestock manure were potentially large sources of nitrogen and phosphorus in each of the four drainage basins. However, nitrogen in legume residues was a more important source in the Upper Mississippi, St. Croix, and Lower Mississippi River Basins because hay comprised a larger part of the total acreage of crops grown in these basins. Atmospheric deposition comprised a larger percentage of the nitrogen sources in the St. Croix River Basin compared to the other three drainage basins probably because amounts of the other sources are relatively low. Nitrogen and phosphorus yields in streams were greatest in the Lower Mississippi River Basin and the Minnesota River Basin, where amounts of nonpoint sources of these constituents also were the greatest per square mile.

Minnesota, Wisconsin↗

USGS2023

Geologic carbon management options for the North Atlantic-Appalachian Region

Introduction The U.S. Geological Survey (USGS) North Atlantic-Appalachian Region is developing the regionwide capacity to provide timely science support for decision-makers attempting to enhance carbon removal, sequestration, and emissions mitigation to meet national atmospheric carbon reduction goals. The U.S. Environmental Protection Agency (EPA) reported that in 2021, the fourteen States and the District of Columbia in the northeastern region account about for approximately 18 percent of the total national greenhouse gas (GHG) emissions. This Fact Sheet provides a summary of USGS science information and ongoing and new investigations or data-collection programs that may help the northeastern region decrease the release of carbon-containing GHG to the atmosphere.

Connecticut, Delaware, Maine, Maryland, Massachuse↗

USGS1996

Environmental behavior and fate of methyl tert-butyl ether (MTBE)

When gasoline that has been oxygenated with methyl tert-butyl ether (MTBE) comes in contact with water, large amounts of MTBE can dissolve; at 25 degrees Celsius the water solubility of MTBE is about 5,000 milligrams per liter for a gasoline that is 10 percent MTBE by weight. In contrast, for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 milligrams per liter. MTBE sorbs only weakly to soil and aquifer materials; therefore, sorption will not significantly retard MTBE's transport by ground water. In addition, MTBE generally resists degradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 days in a regional airshed. MTBE in the air tends to partition into atmospheric water, including precipitation. However, washout of gas-phase MTBE by precipitation would not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation is nevertheless strong enough to allow for up to 3 micrograms per liter or more inputs of MTBE to surface and ground water.

Fact Sheet↗

USGS2025

PFAS sampling activities in the U.S. Geological Survey national networks

Per- and polyfluoroalkyl substances (PFAS), frequently called “forever chemicals,” are used for a wide variety of industrial purposes and are often found in common household and industrial items such as firefighting foams, non-stick cookware, and water-resistant materials. The contamination of water, air, and soil by PFAS is a national and global issue due to their widespread occurrence in multiple applications and resistance to biodegradation and other traditional treatment processes. Research indicates that many PFAS can be emitted to the atmosphere and transported and deposited long distances from the source. The U.S. Geological Survey (USGS) Water Resources Mission Area received funding to implement a national-scale sampling effort to assess PFAS occurrence. To follow agency directives, the National Water Quality Network (NWQN) added PFAS sample monitoring for both surface water and groundwater, and also added PFAS monitoring to selected sites in the National Atmospheric Deposition Program (NADP).

General Information Product↗

USGS2000

Assessment of Folsom Lake Watershed response to historical and potential future climate scenarios

An integrated forecast-control system was designed to allow the profitable use of ensemble forecasts for the operational management of multi-purpose reservoirs. The system ingests large-scale climate model monthly precipitation through the adjustment of the marginal distribution of reservoir-catchment precipitation to reflect occurrence of monthly climate precipitation amounts in the extreme terciles of their distribution. Generation of ensemble reservoir inflow forecasts is then accomplished with due account for atmospheric- forcing and hydrologic- model uncertainties. These ensemble forecasts are ingested by the decision component of the integrated system, which generates non- inferior trade-off surfaces and, given management preferences, estimates of reservoir- management benefits over given periods. In collaboration with the Bureau of Reclamation and the California Nevada River Forecast Center, the integrated system is applied to Folsom Lake in California to evaluate the benefits for flood control, hydroelectric energy production, and low flow augmentation. In addition to retrospective studies involving the historical period 1964-1993, system simulations were performed for the future period 2001-2030, under a control (constant future greenhouse-gas concentrations assumed at the present levels) and a greenhouse-gas- increase (1-% per annum increase assumed) scenario. The present paper presents and validates ensemble 30-day reservoir- inflow forecasts under a variety of situations. Corresponding reservoir management results are presented in Yao and Georgakakos, A., this issue. Principle conclusions of this paper are that the integrated system provides reliable ensemble inflow volume forecasts at the 5-% confidence level for the majority of the deciles of forecast frequency, and that the use of climate model simulations is beneficial mainly during high flow periods. It is also found that, for future periods with potential sharp climatic increases of precipitation amount and to maintain good reliability levels, operational ensemble inflow forecasting should involve atmospheric forcing from appropriate climatic periods.

Open-File Report↗

USGS2001

A guide to potential soil carbon sequestration: Land-use management for mitigation of greenhouse gas emissions

Terrestrial carbon sequestration has a potential role in reducing the recent increase in atmospheric carbon dioxide (CO2) that is, in part, contributing to global warming. Because the most stable long-term surface reservoir for carbon is the soil, changes in agriculture and forestry can potentially reduce atmospheric CO2 through increased soil-carbon storage. If local governments and regional planning agencies are to effect changes in land-use management that could mitigate the impacts of increased greenhouse gas (GHG) emissions, it is essential to know how carbon is cycled and distributed on the landscape. Only then can a cost/benefit analysis be applied to carbon sequestration as a potential land-use management tool for mitigation of GHG emissions. For the past several years, the U.S. Geological Survey (USGS) has been researching the role of terrestrial carbon in the global carbon cycle. Data from these investigations now allow the USGS to begin to (1) 'map' carbon at national, regional, and local scales; (2) calculate present carbon storage at land surface; and (3) identify those areas having the greatest potential to sequester carbon.

North Carolina↗

USGS2002

Rocky Mountain snowpack chemistry network: History, methods, and the importance of monitoring mountain ecosystems

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey to more thoroughly determine the quality of precipitation and to identify sources of atmospherically deposited pollution in a network of high-elevation sites. Depth-integrated samples of seasonal snowpacks at 52 sampling sites, in a network from New Mexico to Montana, were collected and analyzed each year since 1993. The results of the first 5 years (1993–97) of the program are discussed in this report. Spatial patterns in regional data have emerged from the geographically distributed chemical concentrations of ammonium, nitrate, and sulfate that clearly indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Snowpacks in northern Colorado that lie adjacent to both the highly developed Denver metropolitan area to the east and coal-fired powerplants to the west had the highest overall concentrations of nitrate and sulfate in the network. Ammonium concentrations were highest in northwestern Wyoming and southern Montana.

Rocky Mountains↗

USGS2002

AVIRIS data calibration information: Oquirrh and East Tintic mountains, Utah

The information contained herein pertains to the original reflectance calibration derived solely from the Saltair beach site on the shores of Great Salt Lake. The reflectance data derived from this calibration becomes markedly affected by residual absorptions due to atmospheric water vapor and carbon dioxide within short horizontal and vertical distances from the calibration site due to the presence of what is believed to be a distinct microclimate by the lake. Subsequent to the development of this web site, a new reflectance calibration was derived which mitigated these effects. Reflectance spectra of bright areas of known composition in the East Tintic Mountains, far from Great Salt Lake, were sampled from the calibrated high altitude AVIRIS data cubes and edited, or "polished," to identify artifacts related to residual absorptions of atmospheric gases, particulates, and sensor noise. The subtle artifacts identified in this way were incorporated into the multiplier spectra derived from the original calibration site, generating new multiplier spectra that were used to re-calibrate the ATREM- and path radiance-corrected cubes to reflectance. This process generated a reflectance calibration customized for the Oquirrh/East Tintic Mountain region.

Utah↗

USGS2003

Preliminary Mineralogic and Stable Isotope Studies of Altered Summit and Flank Rocks and Osceola Mudflow Deposits on Mount Rainier, Washington

About 5600 years ago part of Mount Rainier?s edifice collapsed with the resultant Osceola Mudflow traveling more than 120 km and covering an area of at least 505 km2. Mineralogic and stable isotope studies were conducted on altered rocks from outcrops near the summit and east flank of the volcano and samples of clasts and matrix from the Osceola Mudflow. Results of these analyses are used to constrain processes responsible for pre-collapse alteration and provide insight into the role of alteration in edifice instability prior to the Osceola collapse event. Jarosite, pyrite, alunite, and kaolinite occur in hydrothermally altered rock exposed in summit scarps formed by edifice collapse events and in altered rock within the east-west structural zone (EWSZ) of the volcano?s east flank. Deposits of the Osceola Mudflow contain clasts of variably altered and unaltered andesite within a clay-rich matrix. Minerals detected in samples from the edifice are also present in many of the clasts. The matrix includes abundant smectite, kaolinite and variably abundant jarosite. Hydrothermal fluid compositions calculated from hydrogen and oxygen isotope data of alunite, and smectite on Mount Rainier reflect mixing of magmatic and meteoric waters. The range in the dD values of modern meteoric water on the volcano (-85 to 155?) reflect the influence of elevation on the dD of precipitation. The d34S and d18OSO4 values of alunite, gypsum and jarosite are distinct but together range from 1.7 to 17.6? and -12.3 to 15.0?, respectively; both parameters increase from jarosite to gypsum to alunite. The variations in sulfur isotope composition are attributed to the varying contributions of disproportionation of magmatic SO2, the supergene oxidation of hydrothermal pyrite and possible oxidation of H2S to the parent aqueous sulfate. The 18OSO4 values of jarosite are the lowest recorded for the mineral, consistent with a supergene origin. The mineralogy and isotope composition of alteration minerals define two and possibly three environments of alteration. At deeper levels magmatic vapor, H2S, SO2 and other gases from venting magmas migrated upward and condensed into the meteoric water. Disproportionation of SO2 into aqueous sulfate and H2S resulted in acid-sulfate (alunite + kaolinite + pyrite) and related argillic and propylitic alteration envelopes in a magmatic hydrothermal environment. At shallow levels H2S reacted with andesite to form pyrite that is associated with smectite along fractures on both the flanks and upper edifice. It is not clear to what extent H2S was oxidized by atmospheric O2 to form aqueous sulfate in a steam-heated environment. Near the ground surface, pyrite is oxidized by atmospheric oxygen resulting in soluble iron-and aluminum-hydroxysulfates. These supergene hydroxysulfates, which may also form around fumaroles from the oxidation of H2S, are subject to continuous solution and redeposition.

Open-File Report↗

USGS2003

Rocky Mountain snowpack chemistry at selected sites for 2001

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey, in cooperation with the National Park Service, U.S. Department of Agriculture Forest Service, and other agencies, to more thoroughly determine the chemical composition of precipitation and to identify sources of atmospherically deposited contaminants in a network of high-elevation sites. Samples of seasonal snowpacks at 57 geographically distributed sites, in a regional network from New Mexico to Montana, were collected and analyzed for major ions (including ammonium, nitrate, and sulfate), alkalinity, and dissolved organic carbon during 2001. Sites selected in this report have been sampled annually since 1993, enabling identification of increases or decreases in chemical concentrations from year to year. Spatial patterns in snowpack-chemical data for concentrations of ammonium, nitrate, and sulfate indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Results for the 2001 snowpack-chemistry analyses, however, indicate increases in concentrations of ammonium and nitrate in particular at sites where past concentrations typically were lower. Since 1993, concentrations of nitrate and sulfate were highest from snowpack samples in northern Colorado that were collected from sites adjacent to the Denver metropolitan area to the east and the coal-fired powerplants to the west. In 2001, relatively high concentrations of nitrate (12.3 to 23.0 microequivalents per liter (?eq/L) and sulfate (7.7 to 12.5 ?eq/L) were detected in Montana and Wyoming. Ammonium concentrations were highest in north-central Colorado (14.5 to 16.9 ?eq/L) and southwestern Montana (12.8 to 14.2 ?eq/L).

Open-File Report↗

USGS2004

Mineral commodity profiles: nitrogen

Overview -- Nitrogen (N) is an essential element of life and a part of all animal and plant proteins. As a part of the DNA and RNA molecules, nitrogen is an essential constituent of each individual's genetic blueprint. As an essential element in the chlorophyll molecule, nitrogen is vital to a plant's ability to photosynthesize. Some crop plants, such as alfalfa, peas, peanuts, and soybeans, can convert atmospheric nitrogen into a usable form by a process referred to as 'fixation.' Most of the nitrogen that is available for crop production, however, comes from decomposing animal and plant waste or from commercially produced fertilizers. Commercial fertilizers contain nitrogen in the form of ammonium and/or nitrate or in a form that is quickly converted to the ammonium or nitrate form once the fertilizer is applied to the soil. Ammonia is generally the source of nitrogen in fertilizers. Anhydrous ammonia is commercially produced by reacting nitrogen with hydrogen under high temperatures and pressures. The source of nitrogen is the atmosphere, which is almost 80 percent nitrogen. Hydrogen is derived from a variety of raw materials, which include water, and crude oil, coal, and natural gas hydrocarbons. Nitrogen-based fertilizers are produced from ammonia feedstocks through a variety of chemical processes. Small quantities of nitrates are produced from mineral resources principally in Chile. In 2002, anhydrous ammonia and other nitrogen materials were produced in more than 70 countries. Global ammonia production was 108 million metric tons (Mt) of contained nitrogen. With 28 percent of this total, China was the largest producer of ammonia. Asia contributed 46 percent of total world ammonia production, and countries of the former U.S.S.R. represented 13 percent. North America also produced 13 percent of the total; Western Europe, 9 percent; the Middle East, 7 percent; Central America and South America, 5 percent; Eastern Europe, 3 percent; and Africa and Oceania contributed the remaining 4 percent (International Fertilizer Industry Association, 2003b, p. 1-4). In 2002, world ammonia exports were 13.1 Mt of contained nitrogen. Trinidad and Tobago (22 percent), Russia (18 percent), Ukraine (10 percent), and Indonesia (7 percent) accounted for 57 percent of the world total. The largest importing regions were North America with 36 percent of the total followed by Western Europe with 23 percent and Asia with 22 percent (International Fertilizer Industry Association, 2003b, p. 5L-11). In 2002, world urea production was 51.4 Mt of contained nitrogen, and exports were 12.0 Mt of contained nitrogen. China and India, which were the two largest producing countries, accounted for 48 percent of world production. The United States and Canada produced about 10 percent of the total. Russia and Ukraine together accounted for 28 percent of total urea exports; Central America and South America, 27 percent; and Asia, North America, and Western Europe, 10 percent each. North America accounted for 36 percent of the total urea imports; Western Europe, 23 percent; and Asia, 22 percent (International Fertilizer Industry Association, 2003f, p. 1-15). Ammonia production capacity in North America and Western Europe is projected to decline through 2004, and capacity in other world regions is projected to increase. Fluctuating natural gas prices are mainly responsible for the capacity decline in North America. Ammonia production capacity is continuing to shift to world regions that have abundant sources of natural gas, and away from those where costs (raw material, labor, environmental compliance) are higher.

Open-File Report↗

USGS2005

Determination of total mercury in biological and geological samples

The analytical chemist is faced with several challenges when determining mercury in biological and geological materials. These challenges include widespread mercury contamination, both in the laboratory and the environment, possible losses of mercury during sample preparation and digestion, the wide range of mercury values commonly observed, ranging from the low nanogram per gram or per liter for background areas to hundreds of milligrams per kilogram in contaminated or ore-bearing areas, great matrix diversity, and sample heterogeneity1. These factors can be naturally occurring or anthropogenic, but must be addressed to provide a precise and accurate analysis. Although there are many instrumental methods available for the successful determination of mercury, no one technique will address all problems or all samples all of the time. The approach for the determination of mercury used at the U.S. Geological Survey, Crustal Imaging and Characterization Team, Denver Laboratories, utilizes a suite of complementary instrumental methods when approaching a study requiring mercury analyses. Typically, a study could require the analysis of waters, leachates or selective digestions of solids, vegetation, and biological materials such as tissue, bone, or shell, soils, rocks, sediments, coals, sludges, and(or) ashes. No one digestion or sample preparation method will be suitable for all of these matrices. The digestions typically employed at our laboratories include: (i) a closed-vessel microwave method using nitric acid and hydrogen peroxide, followed by digestion/dilution with a nitric acid/sodium dichromate solution, (ii) a robotic open test-tube digestion with nitric acid and sodium dichromate, (iii) a sealed Teflon? vessel with nitric acid and sodium dichromate, (iv) a sealed glass bottle with nitric acid and sodium dichromate, or (v) open test tube digestion with nitric and sulfuric acids and vanadium pentoxide. The common factor in all these digestions is that they are very oxidative to ensure the conversion of all mercury forms into Hg (II). Each method of digestion has its advantages and limitations. The method of detection used in our laboratories involves a combination of an in-house, custom, classic continuous-flow cold-vapor atomic absorption spectrometry (CVAAS), a commercially available, automated, flow-injection and a continuous flow cold-vapor atomic fluorescence spectrometry (CV-AFS) systems, and a relatively new, automated and integrated approach where solid or liquid samples are thermally decomposed under an oxygen atmosphere (a nitrogen atmosphere is used for coals) and the released mercury vapor trapped onto a gold gauze and then thermally released into an AAS system. Other less frequently used instrumental methods available for the determination of mercury include inductively coupled plasma ? optical emission spectrometry (ICP-OES), inductively couple plasma ? mass spectrometry (ICP-MS) (both solution nebulization and laser ablation), and instrumental neutron activation analysis (INAA). Results from two case studies involving the determination of mercury in the challenging matrices of biological materials will be presented. These will include fillet, liver and stomach-content samples from grayling for a baseline/background study in Alaska, and samples of meat tissue and shell material from Tanner crabs from Glacier Bay, Alaska. These studies show that the method of digestion is more important than a very sensitive detection limit for mercury.

Open-File Report↗

USGS2007

Analysis of continuous GPS measurements from southern Victoria Land, Antarctica

Several years of continuous data have been collected at remote bedrock Global Positioning System (GPS) sites in southern Victoria Land, Antarctica. Annual to sub-annual variations are observed in the position time-series. An atmospheric pressure loading (APL) effect is calculated from pressure field anomalies supplied by the European Centre for Medium-Range Weather Forecasts (ECMWF) model loading an elastic Earth model. The predicted APL signal has a moderate correlation with the vertical position time-series at McMurdo, Ross Island (International Global Navigation Satellite System Service (IGS) station MCM4), produced using a global solution. In contrast, a local solution in which MCM4 is the fiducial site generates a vertical time series for a remote site in Victoria Land (Cape Roberts, ROB4) which exhibits a low, inverse correlation with the predicted atmospheric pressure loading signal. If, in the future, known and well modeled geophysical loads can be separated from the time-series, then local hydrological loading, of interest for glaciological and climate applications, can potentially be extracted from the GPS time-series.

Open-File Report↗

USGS2007

Debris flows and record floods from extreme mesoscale convective thunderstorms over the Santa Catalina Mountains, Arizona

Ample geologic evidence indicates early Holocene and Pleistocene debris flows from the south side of the Santa Catalina Mountains north of Tucson, Arizona, but few records document historical events. On July 31, 2006, an unusual set of atmospheric conditions aligned to produce record floods and an unprecedented number of debris flows in the Santa Catalinas. During the week prior to the event, an upper-level area of low pressure centered near Albuquerque, New Mexico generated widespread heavy rainfall in southern Arizona. After midnight on July 31, a strong complex of thunderstorms developed over central Arizona in a deformation zone that formed on the back side of the upper-level low. High atmospheric moisture (2.00' of precipitable water) coupled with cooling aloft spawned a mesoscale thunderstorm complex that moved southeast into the Tucson basin. A 15-20 knot low-level southwesterly wind developed with a significant upslope component over the south face of the Santa Catalina Mountains advecting moist and unstable air into the merging storms. National Weather Service radar indicated that a swath of 3-6' of rainfall occurred over the lower and middle elevations of the southern Santa Catalina Mountains. This intense rain falling on saturated soil triggered over 250 hillslope failures and debris flows throughout the mountain range. Sabino Canyon, a heavily used recreation area administered by the U.S. Forest Service, was the epicenter of mass wasting, where at least 18 debris flows removed structures, destroyed the roadway in multiple locations, and closed public access for months. The debris flows were followed by streamflow floods which eclipsed the record discharge in the 75-year gaging record of Sabino Creek. In five canyons adjacent to Sabino Canyon, debris flows approached or excited the mountain front, compromising floow conveyance structures and flooding some homes.

Arizona↗