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Widespread occurrence of (per)chlorate in the Solar System

Perchlorate (ClO− 4 ) and chlorate (ClO− 3 ) are ubiquitous on Earth and ClO− 4 has also been found on Mars. These species can play important roles in geochemical processes such as oxidation of organic matter and as biological electron acceptors, and are also indicators of important photochemical reactions involving oxyanions; on Mars they could be relevant for human habitability both in terms of in situ resource utilization and potential human health effects. For the first time, we extracted, detected and quantified ClO− 4 and ClO− 3 in extraterrestrial, non-planetary samples: regolith and rock samples from the Moon, and two chondrite meteorites (Murchison and Fayetteville). Lunar samples were collected by astronauts during the Apollo program, and meteorite samples were recovered immediately after their fall. This fact, together with the heterogeneous distribution of ClO− 4 and ClO− 3 within some of the samples, and their relative abundance with respect to other soluble species (e.g., NO− 3 ) are consistent with an extraterrestrial origin of the oxychlorine species. Our results, combined with the previously reported widespread occurrence on Earth and Mars, indicate that ClO− 4 and ClO− 3 could be present throughout the Solar System.

Earth and Planetary Science Letters↗

Ultramafic float rocks at Jezero crater (Mars): Excavation of lower crustal rocks or mantle peridotites by impact cratering?

Based on observation and data from meteorites and in situ scientific missions, experiments as well as models, the Martian mantle is assumed to share some compositional and mineralogical affinity with the terrestrial mantle. However, there might be subtle differences like the Martian mantle being more ferroan. Yet, we do not have any direct analysis of a Martian mantle rock to confirm this assumption. NASA’s Perseverance rover found olivine-rich boulder-sized float rocks on the upper Jezero fan (Mars). These boulders have an ultramafic composition and their mineralogy is dominantly composed of Fo 73±3 olivine with high-Mg orthopyroxene, Cr-rich Ti-Fe oxides and minor plagioclase and high-Ca pyroxene. Microtextural and petrological analysis reveals that these minerals crystallized at equilibrium. In addition, these boulders are different from all the bedrocks analyzed by Perseverance along its traverse which are crustal igneous rocks and sediments. Comparing our data to Martian meteorites and available Mars bulk silicate models (BSM), we discuss that these boulders could represent primitive melts and/or lower crustal material, and we specifically hypothesize that they could be mantle peridotites. We propose that these putative mantle rocks could have been excavated by the succession of impacts from the shallow mantle or lower crust in the Isidis region where Jezero crater is located. These olivine-rich boulders could thereby constitute the first direct analysis of a Martian mantle rock.

Earth and Planetary Science Letters↗

Hydrocarbons on Saturn's satellites Iapetus and Phoebe

Material of low geometric albedo (pV ??? 0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or "dark") material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ???65 km. The spectral region 3-3.6 ??m reveals a broad absorption band, centered at 3.29 ??m, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the C{single bond}H stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to {single bond}CH2{single bond} stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust. ?? 2007 Elsevier Inc. All rights reserved.

Icarus↗

Applications of the 190Pt-186Os isotope system to geochemistry and cosmochemistry

Platinum is fractionated from osmium primarily as a consequence of processes involving sulfide and metal crystallization. Consequently, the 190 Pt 186 Os isotope system ( 190 Pt → 186 Os + α) shows promise for dating some types of magmatic sulfide ores and evolved iron meteorites. The first 190 Pt 186 Os isochrons are presented here for ores from the ca. 251 Ma Noril'sk, Siberia plume, and for group IIAB magmatic iron meteorites. Given the known age of the Noril'sk system, a decay constant for 190 Pt is determined to be 1.542 × 10 −12 a −1 , with ±1% uncertainty. The isochron generated for the IIAB irons is consistent with this decay constant and the known age of the group. The 186 Os/ 188 Os ratios of presumably young, mantle-derived osmiridiums and also the carbonaceous chondrite Allende were measured to high-precision to constrain the composition of the modern upper mantle. These compositions overlap, indicating that the upper mantle is chondritic within the level of resolution now available. Our best estimate for this 186 Os/ 188 Os ratio is 0.119834 ± 2 (2σ M ). The 190 Pt/ 186 Os ratios determined for six enstatite chondrites average 0.001659 ± 75, which is very similar to published values for carbonaceous chondrites. Using this ratio and the presumed composition of the modern upper mantle and chondrites, a solar system initial 186 Os/ 188 Os ratio of 0.119820 is calculated. In comparison to the modern upper mantle composition, the 186 Os/ 188 Os ratio of the Noril'sk plume was approximately 0.012% enriched in 186 Os. Possible reasons for this heterogeneity include the recycling of Pt-rich crust into the mantle source of the plume and derivation of the osmium from the outer core. Derivation of the osmium from the outer core is our favored model.

Geochimica et Cosmochimica Acta↗

Visible and near-infrared multispectral analysis of geochemically measured rock fragments at the Opportunity landing site in Meridiani Planum

We have used visible and near‐infrared Panoramic Camera (Pancam) spectral data acquired by the Opportunity rover to analyze 15 rock fragments at the Meridiani Planum landing site. These spectral results were then compared to geochemistry measurements made by the in situ instruments Mössbauer (MB) and Alpha Particle X‐ray Spectrometer (APXS) to determine the feasibility of mineralogic characterization from Pancam data. Our results suggest that dust and alteration rinds coat many rock fragments, which limits our ability to adequately measure the mineralogy of some rocks from Pancam spectra relative to the different field of view and penetration depths of MB and APXS. Viewing and lighting geometry, along with sampling size, also complicate the spectral characterization of the rocks. Rock fragments with the same geochemistry of sulfate‐rich outcrops have similar spectra, although the sulfate‐rich composition cannot be ascertained based upon Pancam spectra alone. FeNi meteorites have spectral characteristics, particularly ferric oxide coatings, that generally differentiate them from other rocks at the landing site. Stony meteorites and impact fragments with unknown compositions have a diverse range of spectral properties and are not well constrained nor diagnostic in Pancam data. Bounce Rock, with its unique basalt composition, is easily differentiated in the Pancam data from all other rock types at Meridiani Planum. Our Pancam analyses of small pebbles adjacent to these 15 rock fragments suggests that other rock types may exist at the landing site but have not yet been geochemically measured.

Journal of Geophysical Research E: Planets↗

Origin of magnetite and pyrrhotite in carbonaceous chondrites

CARBONACEOUS chondrites, although comprising only about 2% of known meteorites, are extremely interesting for scientific investigation. Their mineral constitution, and the correspondence between their bulk chemical composition and the solar abundance of condensable elements, indicate that minimum chemical fractionation and thermal alteration have occurred. The mineral phases observed in these primitive chondrites are sufficiently unique, with respect to other meteorite classes, to have elicited considerable speculation about the physical environment in which they formed 1–7 .

Nature↗

Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review

This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O 2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors.

Chemical Geology↗

Formation of replicating saponite from a gel in the presence of oxalate: implications for the formation of clay minerals in carbonaceous chondrites and the origin of life

The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous chondrites. These clay minerals are the product of aqueous alteration of anhydrous mineral phases, such as olivine and orthopyroxene, that are often present in the chondrules. Moreover, there is a strong correlation in the occurrence of clay minerals and the presence of polar organic molecules. It has been shown in laboratory experiments at low temperature and ambient pressure that polar organic molecules, such as the oxalate found in meteorites, can catalyze the crystallization of clay minerals. In this study, we show that oxalate is a robust catalyst in the crystallization of saponite, an Al- and Mg-rich, trioctahedral 2:1 layer silicate, from a silicate gel at 60°C and ambient pressure. High-resolution transmission electron microscopy analysis of the saponite treated with octadecylammonium (n(C)=18) cations revealed the presence of 2:1 layer structures that have variable interlayer charge. The crystallization of these differently charged 2:1 layer silicates most likely occurred independently. The fact that 2:1 layer silicates with variable charge formed in the same gel has implications for our understanding of the origin of life, as these 2:1 clay minerals most likely replicate by a mechanism of template-catalyzed polymerization and transmit the charge distribution from layer to layer. If polar organic molecules like oxalate can catalyze the formation of clay-mineral crystals, which in turn promote clay microenvironments and provide abundant adsorption sites for other organic molecules present in solution, the interaction among these adsorbed molecules could lead to the polymerization of more complex organic molecules like RNA from nucleotides on early Earth.

Astrobiology↗

Metallic spherules in tektites from Isabela, Philippine Islands

Iron-nickel spherules, as much as 0.5 mm in diameter, have been found completely embedded in some philippinites. The spherules consist mainly of kamacite with unidentified pink inclusions. The meteoritic origin of these spherules seems reasonable, suggesting that the tektites containing them were formed by asteroidal or meteoritic impact.

Isabela↗

Maskelynite: Formation by explosive shock

When high pressure (250 to 300 kilobars) was applied suddenly (shock-loading) to gabbro, the plagioclase was transformed to a noncrystalline phase (maskelynite) by a solid-state reaction at a low temperature, while the proxene remained crystalline. The shock-loaded gabbro resembles meteorites of the shergottite class; this suggests that the latter formed as a result of shock. The shock-loading of gabbro at 600 to 800 kilobars raised the temperature above the melting range of the plagioclase.

Science↗

Lunar metallic particle ("mini-moon"): An interpretation

A troilite-rich nickel-iron particle ("mini-moon") recovered from the moon may be a mound detached from a sphere of silicate glass. Erosion and pitting of the particle may have been caused by passage through a cloud of hot gas and particulate matter formed by meteorite impact on the lunar surface. This explanation is in contrast to the theory that the particle was meteoritically derived molten material that was furrowed during solidification after lunar impact, subsequently pitted by high-velocity particles, and then abraded and polished by drifting dust while on the lunar surface.

Science↗

Roadblocks on the kill curve: Testing the Raup hypothesis

The documented presence of two large (~100-km diameter), possibly coeval impact craters of late Eocene age, requires modification of the impact-kill curve proposed by David M. Raup. Though the estimated meteorite size for each crater alone is large enough to have produced considerable global environmental stress, no horizons of mass mortality or pulsed extinction are known to be associated with either crater or their ejecta deposits. Thus, either there is no fixed relationship between extinction magnitude and crater diameter, or a meteorite that would produce a crater of >100-km diameter is required to raise extinction rates significantly above a ~5% background level. Both impacts took place ~1-2 m.y. before the "Terminal Eocene Event" ( =early Oligocene pulsed extinction). Their collective long-term environmental effects, however, may have either delayed that extinction pulse or produced threshold conditions necessary for it to take place.

Palaios↗

Astronomical observations of volatiles on asteroids

We have long known that water and hydroxyl are important components in meteorites and asteroids. However, in the time since the publication of Asteroids III, evolution of astronomical instrumentation, laboratory capabilities, and theoretical models have led to great advances in our understanding of H 2 O/OH on small bodies, and spacecraft observations of the Moon and Vesta have important implications for our interpretations of the asteroidal population. We begin this chapter with the importance of water/OH in asteroids, after which we will discuss their spectral features throughout the visible and near-infrared. We continue with an overview of the findings in meteorites and asteroids, closing with a discussion of future opportunities, the results from which we can anticipate finding in Asteroids V. Because this topic is of broad importance to asteroids, we also point to relevant in-depth discussions elsewhere in this volume.

Book chapter↗

Astrogeologic studies, semiannual progress report, February 26, 1961 to August 24, 1961

This report is the second semiannual report on a geological program of research conducted by the Geological Survey on behalf of the National Aeronautics and Space Administration. This research is being carried out under the Branch of Astrogeology. The long-range objectives of this program are to determine and map the stratigraphy and structure of the Moon's crust, to develop basic information on processes that have led to the present condition of the Moon's surface, and to work out the sequence of events in the geologic history recorded in the Moon's stratigraphy and structure. The work includes three closely interrelated areas of study: (1) investigation of the chemistry, petrography, and physical properties of extraterrestrial materials that may have been derived from the Moon, such as tektites, certain types of meteorites, and extraterrestrial dust; (2) experimental and field investigations of the mechanics and phenomena of impact of high-speed objects and of cratering; and (3) geologic mapping of the Moon. Immediate objectives for the fiscal year 1961 have included the preparation of geologic maps for the nominal target area for the Ranger Project of the National Aeronautics and Space Administration. Field and laboratory work on craters was directed toward developing data and an adequate theory for the integrated effect of meteoroid bombardment of the lunar surface. Special attention has been given to phase changes and solid state changes produced in rock by meteorite impact. American and Philippine tektites were the principal materials of possible lunar origin to receive detailed petrographic and chemical analysis.

Open-File Report↗

Glaciers of Antarctica

Of all the world's continents Antarctica is the coldest, the highest, and the least known. It is one and a half times the size of the United States, and on it lies 91 percent (30,109,800 km 3 ) of the estimated volume of all the ice on Earth. Because so little is known about Antarctic glaciers compared with what is known about glaciers in populated countries, satellite imagery represents a great leap forward in the provision of basic data. From the coast of Antarctica to about 81?south latitude, there are 2,514 Landsat nominal scene centers (the fixed geographic position of the intersection of orbital paths and latitudinal rows). If there were cloud-free images for all these geographic centers, only about 520 Landsat images would be needed to provide complete coverage. Because of cloud cover, however, only about 70 percent of the Landsat imaging area, or 55 percent of the continent, is covered by good quality Landsat images. To date, only about 20 percent of Antarctica has been mapped at scales of 1:250,000 or larger, but these maps do include about half of the coastline. The area of Antarctica that could be planimetrically mapped at a scale of 1:250,000 would be tripled if the available Landsat images were used in image map production. This chapter contains brief descriptions and interpretations of features seen in 62 carefully selected Landsat images or image mosaics. Images were chosen on the basis of quality and interest; for this reason they are far from evenly spaced around the continent. Space limitations allow less than 15 percent of the Landsat imaging area of Antarctica to be shown in the illustrations reproduced in this chapter. Unfortunately, a wealth of glaciological and other features of compelling interest is present in the many hundreds of images that could not be included. To help show some important features beyond the limit of Landsat coverage, and as an aid to the interpretation of certain features seen in the images, 38 oblique aerial photographs have been included. Again, these represent only a small fraction of the large number of aerial photographs now available in various national collections. The chapter is divided into five geographic sections. The first is the Transantarctic Mountains in the Ross Sea area. Some very large outlet glaciers flow from the East Antarctic ice sheet through the Transantarctic Mountains to the Ross Ice Shelf. Byrd Glacier, one of the largest in the world, drains an area of more than 1,000,000 km 2 . Next, images from the Indian Ocean sector are discussed. These include the Lambert Glacier- Amery Ice Shelf system, so large that about 25 images must be mosaicked to cover its complex system of tributary glaciers. Shirase Glacier, a tidal outlet glacier in the sector, flows at a speed of 2.5 km a -l . About 200 km inland and 200 km west of Shirase Glacier lie the Queen Fabiola ("Yamato") Mountains, whose extensive exposures of `blue ice' lay claim to being the world's most important meteorite-collecting locality, with more than 4,700 meteorite fragments discovered since 1969. The Atlantic Ocean sector is fringed by ice shelves into which flow large ice streams like Jutulstraumen, Stancomb-Wills, Slessor, and Recovery Glaciers. Filchner and Ronne Ice Shelves together cover an area two-thirds the size of Texas. From the western margin of the Ronne Ice Shelf, the north-trending arc of the Antarctic Peninsula, with its fjord and alpine landscape and fringing ice shelves, stretches towards South America. The Pacific Ocean sector begins with the Ellsworth Mountains, which include the highest peaks (Vinson Massif at 4,897 m) in Antarctica. The area between the Ellsworth Mountains and the eastern margin of the Ross Ice Shelf is fringed with small ice shelves and some major outlet glaciers. One of these, Pine Island Glacier, was found from comparing 1973 and 1975 images to have an average ice-front velocity of 2.4 km a -1 . This part of Antarctica contains many dormant volcanoes; the summits of servers, such as Mount Takahe with its 8-km-wide summit caldera, protrude through the West Antarctic ice sheet.

Professional Paper↗

Chapter 9: Theory and processes relating to the lunar maria from the surveyor experiments

Prior to the Surveyor missions, there were three principal theories about the chemical constitution of the lunar maria: that the maria were (1) chondritic, (2) basaltic, or (3) silicic. Three types of materials recovered on Earth were suspected of coming from the maria: (1) chondritic meteorites, (2) basaltic achondrites, and (3) tektites. The Surveyor chemists have now spoken: Turkevich, Franzgrote, and Patterson find that, in Mare Tranquillitatis (ref. 9-1) and Sinus Medii (see ch. 7 of this report), the composition is basaltic. It is unmistakably too poor in magnesium to be like either kind of chondritic meteorite. It is too rich in the heavier elements, iron and calcium, to resemble terrestrial silicic rocks (the granitic kindred) or tektites.

Book chapter↗

A petrographical and geochemical study of quartzose nodules, country rocks, and dike rocks from the Upheaval Dome structure, Utah

Upheaval Dome, in Canyonlands National Park, Utah, USA, is a unique structure on the Colorado Plateau. It has earlier been interpreted as an impact structure or as a pinched-off salt diapir. Some subrounded quartzose fragments were found in a ring depression near the eastern margin of the structure and, based on vesicularity and apparent flow structure, the fragments were interpreted by early researchers as 'impactites.' Our petrographic studies show no indication of a high-temperature history and are in agreement with a slow, low-temperature formation of the quartz nodules. Compositionally, the lag deposit samples are almost pure SiO2. They show no chemical similarity to any of the possible target rocks (e.g., Navajo Sandstone), from which they should have formed by melting if they were impactites. Instead, the samples have relatively high contents of elements that indicate fluid interaction (e.g., hydrothermal growth), such as As, Sb, Ba, and U, and show positive Ce anomalies. Thus, we interpret the 'lag deposit samples' as normal low-temperature (hydrothermally-grown?) quartz that show no indication of being impact-derived. In addition, a petrographic and geochemical analysis of a series of dike samples yielded no evidence for shock metamorphism or a meteoritic component.

Utah↗

Hydrothermal alteration at the Lonar Lake impact structure, India: Implications for impact cratering on Mars

The 50,000 year old, 1.8 km diameter Lonar crater is one of only two known terrestrial craters to be emplaced in basaltic target rock (the 65 million year old Deccan Traps). The composition of the Lonar basalts is similar to martian basaltic meteorites, which establishes Lonar as an excellent analogue for similarly sized craters on the surface of Mars. Samples from cores drilled into the Lonar crater floor show that there are basaltic impact breccias that have been altered by post‐impact hydrothermal processes to produce an assemblage of secondary alteration minerals. Microprobe data and X‐ray diffraction analyses show that the alteration mineral assemblage consists primarily of saponite, with minor celadonite, and carbonate. Thermodynamic modeling and terrestrial volcanic analogues were used to demonstrate that these clay minerals formed at temperatures between 130°C and 200°C. By comparing the Lonar alteration assemblage with alteration at other terrestrial craters, we conclude that the Lonar crater represents a lower size limit for impact‐induced hydrothermal activity. Based on these results, we suggest that similarly sized craters on Mars have the potential to form hydrothermal systems, as long as liquid water was present on or near the martian surface. Furthermore, the Fe‐rich alteration minerals produced by post‐impact hydrothermal processes could contribute to the minor iron enrichment associated with the formation of the martian soil.

Lonar Lake; Mars↗