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USGS2008

Tile drainage as karst: Conduit flow and diffuse flow in a tile-drained watershed

The similarity of tiled-drained watersheds to karst drainage basins can be used to improve understanding of watershed-scale nutrient losses from subsurface tile drainage networks. In this study, short-term variations in discharge and chemistry were examined from a tile outlet collecting subsurface tile flow from a 963 ha agricultural watershed. Study objectives were to apply analytical techniques from karst springs to tile discharge to evaluate water sources and estimate the loads of agricultural pollutants discharged from the tile with conduit, intermediate and diffuse flow regimes. A two-member mixing model using nitrate, chloride and specific conductance was used to distinguish rainwater versus groundwater inputs. Results indicated that groundwater comprised 75% of the discharge for a three-day storm period and rainwater was primarily concentrated during the hydrograph peak. A contrasting pattern of solute concentrations and export loads was observed in tile flow. During base flow periods, tile flow consisted of diffuse flow from groundwater sources and contained elevated levels of nitrate, chloride and specific conductance. During storm events, suspended solids and pollutants adhered to soil surfaces (phosphorus, ammonium and organic nitrogen) were concentrated and discharged during the rapid, conduit flow portion of the hydrograph. During a three-day period, conduit flow occurred for 5.6% of the time but accounted for 16.5% of the total flow. Nitrate and chloride were delivered primarily with diffuse flow (more than 70%), whereas 80-94% of total suspended sediment, phosphorus and ammonium were exported with conduit and intermediate flow regimes. Understanding the water sources contributing to tile drainage and the manner by which pollutant discharge occurs from these systems (conduit, intermediate or diffuse flow) may be useful for designing, implementing and evaluating non-point source reduction strategies in tile-drained landscapes. ?? 2007 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2007

Use of a watershed model to characterize the fate and transport of fluometuron, a soil-applied cotton herbicide, in surface water

The Soil and Water Assessment Tool (SWAT) was used to characterize the fate and transport of fluometuron (a herbicide used on cotton) in the Bogue Phalia Basin in northwestern Mississippi, USA. SWAT is a basin-scale watershed model, able to simulate hydrological, chemical, and sediment transport processes. After adjustments to a few parameters (specifically the SURLAG variable, the runoff curve number, Manning's N for overland flow, soil available water capacity, and the base-flow alpha factor) the SWAT model fit the observed streamflow well (the Coefficient of Efficiency and R2 were greater than 60). The results from comparing observed fluometuron concentrations with simulated concentrations were reasonable. The simulated concentrations (which were daily averages) followed the pattern of observed concentrations (instantaneous values) closely, but could be off in magnitude at times. Further calibration might have improved the fit, but given the uncertainties in the input data, it was not clear that any improvement would be due to a better understanding of the input variables. ?? 2007 Taylor & Francis.

International Journal of Environmental Analytical ↗

USGS2020

Increasing rates of carbon burial in southwest Florida coastal wetlands

Rates of organic carbon (OC) burial in some coastal wetlands appear to be greater in recent years than they were in the past. Possible explanations include ongoing mineralization of older OC or the influence of an unaccounted‐for artefact of the methods used to measure burial rates. Alternatively, the trend may represent real acceleration in OC burial. We quantified OC burial rates of mangrove and coastal freshwater marshes in southwest Florida through a comparison of rates derived from 210 Pb, 137 Cs, and surface marker horizons (MHs). Age/depth profiles of lignin: OC were used to assess whether down‐core remineralization had depleted the OC pool relative to lignin, and lignin phenols were used to quantify the variability of lignin degradation. Over the past 120 years, OC burial rates at seven sites increased by factors ranging from 1.4 to 6.2. We propose that these increases represent net acceleration. Change in relative sea‐level rise is the most likely large‐scale driver of acceleration, and sediment deposition from large storms can contribute to periodic increases. Mangrove sites had higher OC and lignin burial rates than marsh sites, indicating inherent differences in OC burial factors between the two habitat types. The higher OC burial rates in mangrove soils mean that their encroachment into coastal freshwater marshes has the potential to increase burial rates in those locations even more than might be expected from the acceleration trends. Regionally, these findings suggest that burial represents a substantially growing proportion of the coastal wetland carbon budget.

Florida↗

USGS2009

Hydrologic characterization of desert soils with varying degrees of pedogenesis: 1. field experiments evaluating plant-relevant soil water behavior

To assess the eff ect of pedogenesis on the soil moisture dynamics infl uencing the character and quality of ecological habitat, we conducted infi ltration and redistribution experiments on three alluvial deposits in the Mojave National Preserve: (i) recently deposited active wash sediments, (ii) a soil of early Holocene age, and (iii) a highly developed soil of late Pleistocene age. At each, we ponded water in a 1-m-diameter infi ltration ring for 2.3 h and monitored soil water content and matric pressure during and atier infi ltration, using probes and electrical resistivity imaging (ERI). Infi ltration and downward fl ow rates were greater in younger material, favoring deep-rooted species. Deep-rooted species tend to colonize the margins of washes, where they are unaff ected by sediment transport that inhibits colonization. The ERI results support important generalizations, for example that shallower than 0.5 m, infi ltrated water persists longer in highly developed soil, favoring shallow-rooted species. Soil moisture data for the two youngest soils suggested that saturation overshoot, which may have signifi cant but unexplored hydroecologic and pedogenic eff ects, occurred at the horizontally advancing weting front. Spatial heterogeneity of soil properties generally increased with pedogenic development. Evidence suggested that some early-stage developmental processes may promote uniformity; the intermediate- age soil appeared to have the least heterogeneity in terms of textural variation with depth, and also the least anisotropy. Lateral heterogeneity was pronounced in older soil, having a multitude of eff ects on the distribution and retention of soil water, and may facilitate certain water-conserving strategies of plants over what would be possible in a laterally homogeneous soil. ?? Soil Science Society of America.

California↗

USGS1955

Flood control problems

Throughout the world, alluvial soils are among the most fertile and easiest cultivated. Alluvial valleys are routes for transportation either by water or by road and railroad. Rivers are sources of water, a necessity of life. But these river valleys and alluvial deposits, which have so many desirable characteristics and which have increased so greatly in population, are periodically occupied by the river in performing its task of removing the excess of precipitation from the land area and carrying away the products of erosion. How a river behaves and how the river flood plain appears depend on the relationships between water and sediment combined with the existing topography. Thus rivers and their alluvial deposits provide an endless variety of forms which are shaped, to a large extent, by the river flow during periods of rapid removal of debris and of excessive rainfall. The mechanics of river formation are such, however, that the highest discharges are not contained within a limited channel. How much water a channel will carry depends upon the frequency of occurrence of a flow. Low flows, which occur very frequently, are not important in channel formation. Neither are the infrequent discharges of very great magnitude which, although powerful, do not occur often enough to shape the channel. Channel characteristics, are dependent on those discharges of moderate size which combine power with frequency of occurrence to modify the channel from. In the highest discharges of a stream, water rises above the confines of its banks and flows over the flood plain. It must be considered, therefore, that floods are natural phenomena which are characteristic of all rivers. They perform a vital function in the maintenance of river forms and out of bank flow may be expected with a reasonable degree of regularity.

Journal of Soil and Water Conservation in India↗

USGS1994

Adsorption and desorption of atrazine and deethylatrazine by low organic carbon geologic materials

The adsorption and desorption of atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) and a primary metabolite, deethylatrazine (2-amino-4-chloro-6-isopropylamino-s-triazine; DEA), by low organic C (≤ 3.3 g kg −1 ) materials were measured by batch-equilibrium techniques. The adsorbents were samples of glacial outwash sand, till, and stream sediments. The adsorption of both atrazine and DEA conformed to linear isotherms. The adsorption of atrazine by most of the adsorbents yielded apparent K oc values that were in excess of those based on surface agricultural soils. Adsorption correlated with only the pH of the sand-water suspensions. The desorption of atrazine was hysteretic under the conditions of the measurement. DEA had a lower affinity for the same adsorbents; the mean ratio of K d values of DEA to those of atrazine was 0.37 ± 0.20. DEA adsorption did not correlate with organic C, surface area, clay content of the adsorbents, or with the pH of the suspensions. DEA adsorption, unlike atrazine, tended to be reversible. There was a linear relationship between the adsorption constants of atrazine and those of DEA.

Journal of Environmental Quality↗

USGS2022

Stream corridor and upland sources of fluvial sediment and phosphorus from a mixed urban-agricultural tributary to the Great Lakes

Like many impaired Great Lakes tributaries, Apple Creek, Wisconsin (119 km 2 ) has Total Maximum Daily Load (TMDL) targets for reducing suspended sediment and total phosphorus by 51.2 % and 64.2 %, respectively. From August 2017 - October 2018, a stream sediment budget and fingerprinting integrated study was conducted to quantify upland and stream corridor sources of suspended sediment and sediment-bound phosphorus. Phosphorus concentrations varied among source groups and fluvial sediments, with higher concentrations among suspended sediment and cropland soils. Eroding streambanks identified in the stream corridor sediment budget accounted for 100 % of the TMDL Soil and Water Assessment Tool (SWAT) suspended sediment load but only 20 % of the total phosphorus load. Fine-grained streambed sediment equated to approximately-three years of modeled suspended sediment load but only one third of total phosphorus load. The two primary sources of fine-grained streambed sediment were streambanks and cropland, with relative streambank contributions increasing with downstream direction and watershed area. The relative proportion of suspended sediment varied by season and streamflow; however, cropland and streambank erosion accounted for 54 % and 23 % of the suspended sediment when weighted by of the proportion for representative streamflow. Urban land was a source in the upper watershed, but the signature was sequestered by a mid-watershed detention basin. Contributions from construction sites were higher in the fall 2018, likely corresponding to increased activity following a wet spring. These integrated techniques helped describe sources, transport, and sinks of fluvial sediment and phosphorus throughout the watershed at a range of spatial and temporal scales.

Wisconsin↗

USGS2023

Barrier island reconfiguration leads to rapid erosion and relocation of a rural Alaska community

Coastal erosion is one of the foremost hazards that circumpolar communities face. Climate change and warming temperatures are anticipated to accelerate coastal change, increasing risk to coastal communities. Most erosion hazard studies for Alaska communities only consider linear erosion and do not anticipate coastal morphologic changes. This study showcases the possibility and consequence of accelerated erosion by examining a shift from stability to rapid erosion that forced the rural Alaska Native village of Meshik (now Port Heiden) to abandon the original town site and relocate inland. A combination of remote sensing, coastal surveys, and community-based monitoring are used to map coastal morphologic changes and identify erosion drivers. The community’s shoreline was stable until a protective barrier island eroded away. The exposure to open ocean waves, coupled with unconsolidated, low-density sediments, led to rapid erosion rates averaging of 5.8 ± 0.6 m/y from the 1970s to 2020s. The sudden and rapid erosion put great stress on Meshik and resulted in the loss of homes, erosion of a safe boat harbor, and pollution of the beach and bay. Erosion of the barrier island coincided with a period of greater storm activity and sea ice decline, but the exact cause for its erosion could not be determined. Many polar communities are built on or behind barriers and are on easily erodible soils such as sands and thawing permafrost. This study highlights the need to study, monitor, and predict morphologic change and regime shifts that can bring catastrophic impacts to coastal communities.

Alaska↗

USGS2018

Fire, flood, and drought: Extreme climate events alter flow paths and stream chemistry

Extreme climate events—such as hurricanes, droughts, extreme precipitation, and wildfires—have the potential to alter watershed processes and stream response. Yet due to the destructive and hazardous nature and unpredictability of such events, capturing their hydrochemical signal is challenging. A 5‐year postwildfire study of stream chemistry in the Fourmile Creek watershed, Colorado Front Range, USA, focused on high‐frequency storm sampling. During the study, the watershed was impacted by three additional extreme climate events—drought and two periods of extreme rainfall totals. These events altered concentration‐discharge relationships in ways that elucidate how hydrologic flow paths and source material availability affect stream water chemistry. Reduced infiltration after wildfire led to overland flow during thunderstorms, which conveyed ash and soil into streams. This resulted in elevated stream concentrations of constituents elevated in ash—Ca, K, Mg, alkalinity, and dissolved organic carbon—along with sediment and nitrate. Subsurface flow paths were bypassed, leading to low concentrations of Na and SiO 2 , which are bedrock derived and not elevated in ash. During drought conditions, when stream discharge was <20% of average, concentrations of sediment, dissolved organic carbon, and Ca fell below average concentrations, but SiO 2 did not. Extreme rainfall totals saturated the subsurface and led to prolonged elevated stream discharge. Concentration‐discharge relationships for bedrock‐derived constituents, such as Ca and SiO 2 , were altered in that time period, while those for dissolved organic carbon were not. Previous disturbances, including historical mining, also affect stream chemistry, and water‐quality impairment can be exacerbated by extreme climate events.

Colorado↗

USGS1978

A field evaluation of subsurface and surface runoff. II. Runoff processes

Combined use of radioisotope tracer, flow rate, specific conductance and suspended-sediment measurements on a large field plot near Stanford, California, has provided more detailed information on surface and subsurface storm runoff processes than would be possible from any single approach used in isolation. Although the plot was surficially uniform, the runoff processes were shown to be grossly nonuniform, both spatially over the plot, and laterally and vertically within the soil. The three types of processes that have been suggested as sources of storm runoff (Horton-type surface runoff, saturated overland flow, and rapid subsurface throughflow) all occurred on the plot. The nonuniformity of the processes supports the partial- and variable-source area concepts. Subsurface storm runoff occurred in a saturated layer above the subsoil horizon, and short travel times resulted from flow through macropores rather than the soil matrix. Consideration of these observations would be necessary for physically realistic modeling of the storm runoff process.

California↗

USGS1986

Use of the chloride ion in determining hydrologic-basin water budgets - A 3-year case study in the San Juan Mountains, Colorado, U.S.A.

Measurement of chloride concentration and water equivalent in precipitation and recharge at a site can be extrapolated to determine available moisture in a nearby basin. This method also may be extrapolated to a basin with similar climatic characteristics if precipitation, vegetation, and topographic data are available. The average accuracy of the total of evaporation, recharge, and runoff (assuming no storage) was about 10% of total precipitation. Soil-moisture measurements indicate the entire 10% error in moisture balance can be attributed to annual changes in storage. Data requirements for the method are considerably less than data requirements for energy-budget methods to determine available moisture. Potential applications of the method to hydrologic problem-solving are: 1. (1) Estimating total available moisture from chloride concentrations in groundwater or surface water or both. 2. (2) Modeling paleoclimate scenarios and evaluating their correctness by comparison with paleo-groundwater chloride concentrations. 3. (3) Providing an independent comparison for water budgets obtained by energy-budget methods. Obviously the method cannot be applied readily to systems with a lithologic source of chloride. Most systems primarily consisting of tuff, intrusive volcanic rock, nonmarine sediments, quartzite, and other metamorphic rocks will be suitable for application of the model.

Colorado↗

USGS2006

Erosion rates at the Mars Exploration Rover landing sites and long-term climate change on Mars

Erosion rates derived from the Gusev cratered plains and the erosion of weak sulfates by saltating sand at Meridiani Planum are so slow that they argue that the present dry and desiccating environment has persisted since the Early Hesperian. In contrast, sedimentary rocks at Meridiani formed in the presence of groundwater and occasional surface water, and many Columbia Hills rocks at Gusev underwent aqueous alteration during the Late Noachian, approximately coeval with a wide variety of geomorphic indicators that indicate a wetter and likely warmer environment. Two-toned rocks, elevated ventifacts, and perched and undercut rocks indicate localized deflation of the Gusev plains and deposition of an equivalent amount of sediment into craters to form hollows, suggesting average erosion rates of ???0.03 nm/yr. Erosion of Hesperian craters, modification of Late Amazonian craters, and the concentration of hematite concretions in the soils of Meridiani yield slightly higher average erosion rates of 1-10 nm/yr in the Amazonian. These erosion rates are 2-5 orders of magnitude lower than the slowest continental denudation rates on Earth, indicating that liquid water was not an active erosional agent. Erosion rates for Meridiani just before deposition of the sulfate-rich sediments and other eroded Noachian areas are comparable with slow denudation rates on Earth that are dominated by liquid water. Available data suggest the climate change at the landing sites from wet and likely warm to dry and desiccating occurred sometime between the Late Noachian and the beginning of the Late Hesperian (3.7-3.5 Ga). Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS2004

Pedogenic silica accumulation in chronosequence soils, southern California

Chronosequential analysis of soil properties has proven to be a valuable approach for estimating ages of geomorphic surfaces where no independent age control exists. In this study we examined pedogenic silica as an indicator of relative ages of soils and geomorphic surfaces, and assessed potential sources of the silica. Pedogenic opaline silica was quantified by tiron (4,5-dihydroxy-1,3-benzene-disulfonic acid [disodium salt], C 6 H 4 Na 2 O 8 S 2 ) extraction for pedons in two different chronosequences in southern California, one in the San Timoteo Badlands and one in Cajon Pass. The soils of both of these chronosequences are developed in arkosic sediments and span 11.5 to 500 ka. The amount of pedogenic silica increases with increasing duration of pedogenesis, and the depth of the maximum silica accumulation generally coincides with the maximum expression of the argillic horizon. Pedogenic silica has accumulated in all of the soils, ranging from 1.2% tiron-extractable Si (Si tn ) in the youngest soil to 4.6% in the oldest. Primary Si decreases with increasing duration of weathering, particularly in the upper horizons, where weathering conditions are most intense. The loss of Si coincides with the loss of Na and K, implicating the weathering of feldspars as the likely source of Si loss. The quantity of Si lost in the upper horizons is adequate to account for the pedogenic silica accumulation in the subsoil. Pedogenic silica was equally effective as pedogenic Fe oxides as an indicator of relative soil age in these soils.

California↗

USGS2021

Uranium(VI) attenuation in a carbonate-bearing oxic alluvial aquifer

Uranium minerals are commonly found in soils and sediment across the United States at an average concentration of 2–4 mg/kg. Uranium occurs in the environment primarily in two forms, the oxidized, mostly soluble uranium(VI) form, or the reduced, sparingly soluble reduced uranium(IV) form. Here we describe subsurface geochemical conditions that result in low uranium concentrations in an alluvial aquifer with naturally occurring uranium in soils and sediments in the presence of complexing ligands under oxidizing conditions. Groundwater was saturated with respect to calcite and contained calcium (78–90 mg/L) with elevated levels of carbonate alkalinity (291–416 mg/L as HCO 3 − ). X-ray adsorption near edge structure (XANES) spectroscopy identified that sediment-associated uranium was oxidized as a uranium(VI) form (85%). Calcite was the predominant mineral by mass in the ultrafine fraction in uranium-bearing sediments (>16 mg/kg). Groundwater geochemical modeling indicated calcite and/or a calcium-uranyl-carbonate mineral such as liebigite in equilibrium with groundwater. The δ 13 C (0.57‰ ± 0.15‰) was indicative of abiotic carbonate deposition. Thus, solid-phase uranium(VI) associated with carbonate is likely maintaining uranium(VI) groundwater levels below the maximum contaminant level (MCL; 30 µg/L), presenting a deposition mechanism for uranium attenuation rather than solely a means of mobilization.

Nebraska↗

USGS2016

Structured heterogeneity in a marine terrace chronosequence: Upland mottling

Soil mottles generally are interpreted as a product of reducing conditions during periods of water saturation. The upland soils of the Santa Cruz, CA, marine terrace chronosequence display an evolving sequence of reticulate mottling from the youngest soil (65 ka) without mottles to the oldest soil (225 ka) with well-developed mottles. The mottles consist of an interconnected network of clay and C-enriched regions (gray, 2.5Y 6/1) bordered by leached parent material (white, 2.5Y 8/1) within a diminishing matrix of oxidized parent material (orange, 7.5YR 5/8). The mottles develop in soils that formed from relatively uniform nearshore sediments and occur below the depth of soil bioturbation. To explore how a presumably wetland feature occurs in an unsaturated upland soil, physical and chemical characteristics of mottle separates (orange, gray, and white) were compared through the deep time represented by the soil chronosequence. Mineralogical, isotopic, and surface-area differences among mottle separates indicate that rhizogenic centimeter-scale mass transfer acting across millennia is an integral part of weathering, pedogenesis, and C and nutrient transfer. Elemental analysis, electron microscopy, and Fe-isotope systematics indicate that mottle development is driven by deep roots together with their fungal and microbial symbionts. Taken together, these data suggest that deep soil horizons on old stable landforms can develop reticulate mottling as the long-term imprint of rhizospheric processes. The processes of rhizogenic mottle formation appear to regulate pedogenesis, nutrients, and C sequestration at depth in unsaturated zones.

California↗

USGS2018

Testing a two-scale focused conservation strategy for reducing phosphorus and sediment loads from agricultural watersheds

This study tested a focused strategy for reducing phosphorus (P) and sediment loads in agricultural streams. The strategy involved selecting small watersheds identified as likely to respond relatively quickly, and then focusing conservation practices on high-contributing fields within those watersheds. Two 5,000 ha (12,360 ac) watersheds in the Driftless Area of south central Wisconsin, previously ranked in the top 6% of similarly sized Wisconsin watersheds for expected responsiveness to conservation efforts to reduce high P and sediment loads, were chosen for the study. The stream outlets from both watersheds were monitored from October of 2006 through September of 2016 for streamflow and concentrations of sediment, total P, and, beginning in October of 2009, total dissolved P. Fields and pastures having the highest potential P delivery to the streams in each watershed were identified using the Wisconsin P Index (Good et al. 2012). After three years of baseline monitoring (2006 to 2009), farmers implemented both field- and farm-based conservation practices in one watershed (treatment) as a means to reduce sediment and P inputs to the stream from the highest contributing areas, whereas there were no out-of-the-ordinary conservation efforts in the second watershed (control). Implementation occurred primarily in 2011 and 2012. In the four years following implementation of conservation practices (2013 through 2016), there was a statistically significant reduction in storm-event suspended sediment loads in the treatment watershed compared to the control watershed when the ground was not frozen ( p = 0.047). While there was an apparent reduction in year-round suspended sediment event loads, it was not statistically significant at the 95% confidence level ( p = 0.15). Total P loads were significantly reduced for runoff events ( p < 0.01) with a median reduction of 50%. Total P and total dissolved P concentrations for low-flow conditions were also significantly reduced ( p < 0.01) compared to the control watershed. This study demonstrated that a strategy that first identifies watersheds likely to respond to conservation efforts and then focuses implementation on relatively high-contributing fields within those watersheds can be successful in reducing stream P concentrations and loads.

Wisconsin↗

USGS2001

Processes controlling the episodic streamwater transport of atrazine and other agrichemicals in an agricultural watershed

Episodic streamwater transport of atrazine (a common agricultural herbicide) and nutrients has been observed throughout agricultural watersheds in the United States and poses a serious threat to the quality of its water resources. Catchment-scale atrazine and nutrient transport processes after agricultural application are still poorly understood, and predicting episodic streamwater composition remains an elusive goal. We instrumented a 1.2-km 2 agricultural catchment near Harrisonburg, Virginia, and examined streamwater, overland flow, soil water, groundwater, and rainfall during the summer of 1998. Storm chemographs demonstrated different patterns for constituents derived primarily from weathering (silica and calcium), compared to constituents derived primarily from early spring land applications (nitrate, atrazine, DOC, potassium, chloride, and sulfate). During storms, the concentrations of silica and calcium decreased, the atrazine response was variable, and the concentrations of nitrate, DOC, potassium, chloride, and sulfate increased; the elevated nitrate signal lagged several hours behind the other elevated constituents. Graphical and statistical analyses indicated a relatively stable spring-fed baseflow was modified by a mixture of overland flow and soil water. A rapid, short-duration overland-flow pulse dominated the streamflow early in the event and contributed most of the potassium, DOC, chloride, suspended sediment, and atrazine. A longer-duration soil–water pulse dominated the streamflow later in the event and contributed the nitrate as well as additional potassium, DOC, sulfate, and atrazine. The contributions to the episodic streamflow were quantified using a flushing model in which overland-flow and soil–water concentrations decreased exponentially with time during an episode. Flushing time constants for the overland-flow and soil–water reservoirs were calculated on a storm-by-storm basis using separate tracers for each time-variable reservoir. Initial component concentrations were estimated through regression analyses. Mass-balance calculations were used for flow separations and to predict the observed streamwater composition. Model forecasts indicated that reduced fertilizer and pesticide application (rather than elimination of overland-flow or soil–water contributions) was necessary to improve the episodic streamwater composition. This study provides important additional understanding of the catchment-scale processes by which land-applied pesticides and nutrients can move through agricultural systems.

Virginia↗

USGS2008

Environmental presence and persistence of pharmaceuticals: An overview

Emerging contaminants (ECs) in the environment – that is, chemicals with domestic, municipal, industrial, or agricultural sources that are not commonly monitored but may have the potential for adverse environmental effects – is a rapidly growing field of research. The use of “emerging” is not intended to infer that the presence of these compounds in the environment is new. These chemicals have been released into the environment as long as they have been in production or, in the case of hormones and other endogenous compounds, since the rise of animal life. What is emerging is the interest by the scientific and lay communities in the presence of these chemicals in the environment, the analytical capabilities required for detection, and the subtle effects that very small concentrations of these chemicals appear to have on aquatic biota. In December 2006, Environmental Science & Technology devoted an entire special issue (volume 40, number 23) to the topic of ECs, illustrating the increased interest in the subject. Within the EGs, one particular class that has seen a substantial increase in research over the past 10 years is pharmaceuticals and personal-care products (PPCPs). This increased research interest can be demonstrated by several means, including requests for proposals from funding agencies, but the clearest indication of a focused effort to understand the introduction, transformation, and potential health and environmental effects of PPCPs and ECs, in general, is the number of published reports. This increase can be shown by examining six environmental journals that regularly publish PPCP-related papers – Chemosphere , Environmental Science & Technology , Environmental Toxicology and Chemistry , Science of the Total Environment , Water Research , and Water Science and Technology . In 1998 there were 22 papers published on pharmaceuticals, antibiotics, or drugs in these 6 journals; by 2006, this number increased sixfold to 132 papers (Figure 1.1). This growth can be attributed to a number of factors. The presence of pharmaceuticals in surface-water samples from Europe and the United States was documented in several sentinel papers. These ground-breaking works encouraged other scientists to examine the rivers, streams, lakes, and reservoirs in their regions for such chemicals. In addition, the intense public attention paid to news reports on the environmental detections of these chemicals and possible effects of aquatic life has made this issue visible to the wastewater-treatment, drinking-water treatment, and regulatory communities. This has driven the funding bodies associated with these communities to fund studies or request proposals that address the presence, fate, and effects of PPCPs in aquatic systems. The release of the first comprehensive reconnaissance of pharmaceuticals and other wastewater contaminants in the United States provides an example of the intense media interest in this topic. Within 6 days on online publication of this study, 72 newspapers across the United States had published articles describing the results, either locally written or based on international media syndicate reports. There also was substantial concurrent coverage by local and national radio and television outlets, including the Cable News Network, ABC World News Tonight , and National Public Radio. A substantial fraction of these news stories may be attributable to press releases and media briefings prior to publication. However, the interest by television and print journalists in reporting the results of a peer-reviewed journal article to the general public was motivated by the recognition that describing the presence of PPCPs in water supplies would be of interest to the public. To better convey the results of the study published by Koplin et al. to the public, a separate general-interest fact sheet was published to summarize the important points of the study. Because PPCPs are commonly and widely used by individuals, there is likely a preexisting, personal identification with these compounds that does not occur for the wide range of other organic and inorganic contaminants whose presence in the environment has previously been described. This greater public “name recognition” makes itself known through the media to the regulatory and technical community and has prompted interest in sponsoring research that defines the composition and concentrations of PPCPs in potential sources and their fate and effects following relase into the environment. Independent of the drivers that potentially fuel the interest in studies of PPCPs, it is clear that PPCP research has grown beyond surface-water studies to examine issues such as: • Presence in other matrices, such as groundwater, landfill leachates, sediments, and biosolids. • Environmental transport and fate in surface water, groundwater, and soils amended with reclaimed water or biosolids. • PPCP source elucidation, such as wastewater treatment plant (WWTP) effluents, confined animal feeding operations (CAFOs), and aquaculture. • Removal during wastewater and drinking-water treatment. • Effects on aquatic ecosystems, terrestrial ecosystems, and human health. The chapters in this book provide an extensive examination of current environmental pharmaceutical research and are divided into three sections: “Occurrence and Analysis of Pharmaceuticals in the Environment,” “Environment Fate and Transformations of Veterinary Pharmaceuticals,” and “treatment of Pharmaceuticals in Drinking Water and Wastewater.” The purpose of this introductory overview chapter is to outline current (2004-2006) knowledge about the presence and concentration of PPCPs as described in the published literature. Previous reviews should be consulted for discussions on pre-2004 publications. Those reviews will provide the reader with a comprehensive introduction to the topic of PPCPs in the environment. This chapter describes the sources of PPCPs and other organic contaminants often associated with human wastewater into the environment, the range of concentrations present in various environmental compartments, and the potential routes of removal/sequestration. An overview of the sources and fate of veterinary pharmaceuticals will be discussed in Chapter 5, “Fate and Transport of Veterinary Medicines in the Soil Environment.”

Book chapter↗