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At least 109 records · Page 6Linked to original sources
USGS2023

Yellowstone Volcano Observatory 2022 annual report

The Yellowstone Volcano Observatory (YVO) monitors volcanic and hydrothermal activity associated with the Yellowstone magmatic system, carries out research into magmatic processes occurring beneath Yellowstone Caldera, and issues timely warnings and guidance related to potential future geologic hazards. This report summarizes the activities and findings of YVO during the year 2022, focusing on the Yellowstone volcanic system. Highlights of YVO research and related activities during 2022 include deployments of seismometers in Norris Geyser Basin and Upper Geyser Basin to investigate interactions between hydrothermal features and influences from external influences, geological studies of post-glacial hydrothermal activity, refining the ages of Yellowstone volcanic units and updating existing maps of geologic deposits, new mapping of ash-flow deposits on the Sour Creek dome, installation of a new continuous gas monitoring station near Mud Volcano, sampling of gas emissions and thermal waters around Yellowstone National Park to monitor water chemistry over space and time, research into the age and history of Steamboat Geyser in Norris Geyser Basin, and assessment of thermal output based on satellite imagery and chloride flux in rivers. The most noteworthy event of the year was not geophysical, but meteorological. Combined runoff from rain and snowmelt caused substantial flooding in Yellowstone National Park, which caused damage to park roads and infrastructure. Steamboat Geyser, in Norris Geyser Basin, continued the pattern of frequent eruptions that began in 2018 with 11 water eruptions in 2022, the lowest number of annual eruptions in the current eruptive sequence. Total seismicity—2,429 located earthquakes—was slightly less than the 2,773 earthquakes located in 2021 and at the upper end of the historical average range of about 1,500–2,500 earthquakes per year. Overall subsidence of the caldera floor, ongoing since late 2015 or early 2016, continued at rates of a few centimeters (1–2 inches) per year. Satellite deformation measurements indicated the possibility of slight uplift amounting to about 1 centimeter (less than 1 inch) along the north caldera rim in 2021, but satellite data spanning 2022 show no uplift in that area. Throughout 2022, the aviation color code for Yellowstone Caldera remained at “green” and the volcano alert level remained at “normal.”

Wyoming↗
USGS2003

Determining long time-scale hyporheic zone flow paths in Antarctic streams

In the McMurdo Dry Valleys of Antarctica, glaciers are the source of meltwater during the austral summer, and the streams and adjacent hyporheic zones constitute the entire physical watershed; there are no hillslope processes in these systems. Hyporheic zones can extend several metres from each side of the stream, and are up to 70 cm deep, corresponding to a lateral cross‐section as large as 12 m 2 , and water resides in the subsurface year around. In this study, we differentiate between the near‐stream hyporheic zone, which can be characterized with stream tracer experiments, and the extended hyporheic zone, which has a longer time‐scale of exchange. We sampled stream water from Green Creek and from the adjacent saturated alluvium for stable isotopes of D and 18 O to assess the significance and extent of stream‐water exchange between the streams and extended hyporheic zones over long time‐scales (days to weeks). Our results show that water residing in the extended hyporheic zone is much more isotopically enriched (up to 11‰ D and 2·2‰ 18 O) than stream water. This result suggests a long residence time within the extended hyporheic zone, during which fractionation has occurred owing to summer evaporation and winter sublimation of hyporheic water. We found less enriched water in the extended hyporheic zone later in the flow season, suggesting that stream water may be exchanged into and out of this zone, on the time‐scale of weeks to months. The transient storage model OTIS was used to characterize the exchange of stream water with the extended hyporheic zone. Model results yield exchange rates (α) generally an order magnitude lower (10 −5 s −1 ) than those determined using stream‐tracer techniques on the same stream. In light of previous studies in these streams, these results suggest that the hyporheic zones in Antarctic streams have near‐stream zones of rapid stream‐water exchange, where ‘fast’ biogeochemical reactions may influence water chemistry, and extended hyporheic zones, in which slower biogeochemical reaction rates may affect stream‐water chemistry at longer time‐scales.

Hydrological Processes↗
USGS1995

Transfer and accumulation of organochlorines from black-crowned night-heron eggs to chicks

Eggs and sibling 1-, 3-, and 5-d-old chicks from seven black-crowned night-heron ( Nycticorax nycticorax ) broods were collected from Green Bay, Wisconsin, and analyzed for organochlorines. The concentration (μg/g) of nine organochlorines either decreased ( n = 7) or remained the same ( n = 2) as the chicks grew older. In contrast, the total mass (μg) of these nine organochlorines increased ( n = 7) or remained the same ( n = 2) as the chicks grew older. Accumulation rates of mass (μg/d) between egg and 5-d-old chicks for each of the nine organochlorines were positive and varied from 0.2 μg/d ( p,p ′-DDT) to 42 μg/d (PCBs). These results suggest that the loss of contaminant mass from eggs to chicks reported in some earlier studies was because the entire carcass was not analyzed (i.e., not including skin, gastrointestinal tract, etc.). These results also support the use of contaminant accumulation rates as an indicator of local contamination.

Environmental Toxicology and Chemistry↗
USGS2018

Regional variability of nitrate fluxes in the unsaturated zone and groundwater, Wisconsin, USA

Process-based modeling of regional NO3− fluxes to groundwater is critical for understanding and managing water quality, but the complexity of NO3− reactive transport processes make implementation a challenge. This study introduces a regional vertical flux method (VFM) for efficient estimation of reactive transport of NO3− in the vadose zone and groundwater. The regional VFM was applied to 443 well samples in central-eastern Wisconsin. Chemical measurements included O2, NO3−, N2 from denitrification, and atmospheric tracers of groundwater age including carbon-14, chlorofluorocarbons, tritium, and tritiogenic helium. VFM results were consistent with observed chemistry, and calibrated parameters were in-line with estimates from previous studies. Results indicated that (1) unsaturated zone travel times were a substantial portion of the transit time to wells and streams (2) since 1945 fractions of applied N leached to groundwater have increased for manure-N, possibly due to increased injection of liquid manure, and decreased for fertilizer-N, and (3) under current practices and conditions, approximately 60% of the shallow aquifer will eventually be affected by downward migration of NO3−, with denitrification protecting the remaining 40%. Recharge variability strongly affected the unsaturated zone lag times and the eventual depth of the NO3− front. Principal components regression demonstrated that VFM parameters and predictions were significantly correlated with hydrogeochemical landscape features. The diverse and sometimes conflicting aspects of N management (e.g. limiting N volatilization versus limiting N losses to groundwater) warrant continued development of large-scale holistic strategies to manage water quality and quantity.

Wisconsin↗
USGS2002

The effects of atmospheric nitrogen deposition in the Rocky Mountains of Colorado and southern Wyoming— A synthesis and critical assessment of published results

The Rocky Mountain region of Colorado and southern Wyoming receives as much as 7 kilograms per hectare per year ((kg/ha)/yr) of atmospheric nitrogen (N) deposition, an amount that may have caused changes in aquatic and terrestrial life in otherwise pristine ecosystems. The Rocky Mountain National Park, in its role of protecting air-quality related values under provisions of the Clean Air Act Amendments of 1977, has provided support for this synthesis and critical assessment of published literature on the effects of atmospheric N deposition. Results from published studies indicate a long-term increase in the rate of atmospheric N deposition during the 20th century, but no region-wide increase during the past 2 decades, although the rate of atmospheric N deposition has increased at three sites east of the Continental Divide in the Front Range region since the mid-1980s. Much of the increase in atmospheric N deposition at all three sites has resulted from an increase in the ammonium concentrations of wet deposition; this suggests an increase in contributions from agricultural areas or from vehicle traffic east of the Rocky Mountains. Lakes at two study sites in the Front Range (Loch Vale and Green Lakes Valley) had NO 3 - concentrations of 30 to 40 micromoles per liter (µmol/L) during early spring snowmelt and remained at 5 to 10 µmol/L during summer. Retention of N in atmospheric wet deposition in some sub-catchments of these lakes was less than 50 percent, which reflects an advanced stage of N saturation. Nitrate concentrations in surface waters west of the Continental Divide were lower—often less than 10 µmol/L during snowmelt and less than 2 µmol/L during summer -- than surface waters east of the Divide, except in areas such as the Mt. Zirkel Wilderness that receive elevated amounts of atmospheric N deposition of 4 to 5 (kg/ha)/yr. Atmospheric N deposition in the Front Range east of the Divide may have altered the composition of alpine tundra-plant communities and lake diatoms, but additional studies would be needed to definitively demonstrate the hypothesized cause-and-effect relations. Rates of N-mineralization and nitrification in soils of the Front Range have increased in response to increased atmospheric N deposition. Projected future population growth and energy use in Colorado and the west increase the likelihood that the subtle effects of atmospheric N deposition now evident in the Front Range will become more pronounced and widespread in the future. The likelihood of future increased N emissions along the Front Range warrants a continuation of existing long-term precipitation and surface-water chemistry monitoring programs, and an expansion of the networks into areas that receive large amounts of atmospheric N deposition, but currently lack adequate monitoring. Long-term study and expanded sampling are needed to address uncertainties about the effects of atmospheric N deposition on terrestrial plant communities, nutrient limitation in lake plankton, shifts of dominant species within diatom communities, and on amphibian response to episodic surface-water acidification.

Colorado, Wyoming↗
USGS2018

Characterization of water quality in Bushy Park Reservoir, South Carolina, 2013–15

The Bushy Park Reservoir is the principal water supply for 400,000 people in the greater Charleston, South Carolina, area, which includes homes as well as businesses and industries in the Bushy Park Industrial Complex. Charleston Water System and the U.S. Geological Survey conducted a cooperative study during 2013–15 to assess the circulation of Bushy Park Reservoir and its effects on water-quality conditions, specifically, recurring taste-and-odor episodes. This report describes the water-quality data collected for the study that included a combination of discrete water-column sampling at seven locations in the reservoir and longitudinal water-quality profiling surveys of the reservoir and tributaries to characterize the temporal and spatial water-quality dynamics of Bushy Park Reservoir. Water-quality profiling surveys were conducted with an autonomous underwater vehicle equipped with a multiparameter water-quality-sonde bulkhead. Data collected by the autonomous underwater vehicle included water temperature, dissolved oxygen, pH, specific conductance, turbidity, total chlorophyll as fluorescence (estimate of algal biomass), and phycocyanin as fluorescence (estimate of cyanobacteria biomass) data. Characterization of the water-quality conditions in the reservoir included comparison to established State nutrient guidelines, identification of any spatial and seasonal variation in water-quality conditions and phytoplankton community structures, and assessment of the degree of influence of water-quality conditions related to Foster Creek and Durham Canal inflows, especially during periods of elevated taste-and-odor concentrations. Depth-profile and autonomous underwater vehicle survey data were used to identify areas within the reservoir where greater phytoplankton and cyanobacteria densities were most likely occurring. Water-quality survey results indicated that Bushy Park Reservoir tended to stratify thermally at a depth of about 20 feet from June to early October. The stratification was limited to the deeper portions of the reservoir near the dam and often dissipated within the reservoir near the CWS intake less than a mile upstream from the dam. Where thermally stratified, a corresponding depletion of dissolved oxygen also occurred at about the same depth and resulted in an anoxic hypolimnion below the 25-foot depth and an increase in specific conductance, likely due to re-mobilized metals and phosphorus under reducing conditions. In general, chlorophyll estimated from fluorescence exhibited some spatial variation, but no strong consistent pattern or “hot spot” was observed. Phycocyanin, estimated from relative fluorescence unit output as blue-green algae cell density, periodically seemed to be greater in the upper portion of the reservoir, but those differences may be attributed to increased turbidity and the potential change in phytoplankton community structure that affects fluorescence. Increased phycocyanin was observed at about the 10-foot depth during the summer months. A constant production of 2-methylisoborneol (MIB) near the dam and geosmin in the middle and upper portions of the reservoir appears to be occurring during the summer and early fall in the reservoir, but concentrations of these compounds tend to be between 10 and 15 nanograms per liter, which is at the Charleston Water System treatment threshold. At the Bushy Park Reservoir intake, the dominant taste-and-odor compound tended to be MIB, measured at a 2- or 3-to-1 ratio with geosmin during the summer and fall. During springtime episodes, however, when taste-and-odor compound concentrations typically are elevated above the Charleston Water System treatment threshold, the spatial distribution of geosmin concentrations greater than 15 nanograms per liter (28 to 38 nanograms per liter) was best explained by in situ production in the lower portion of the Bushy Park Reservoir near the dam rather than transport from Foster Creek. This pattern seems to indicate a possible shift in phytoplankton communities (or, at least, cyanobacteria communities) from MIB producers to geosmin producers. The spatial and seasonal assessment of water-quality conditions in Bushy Park Reservoir identified seasonal differences in water chemistry and spatial differences between the upper and lower portions of the reservoir that correspond to the location of elevated geosmin concentrations. On the basis of the spatial and seasonal assessment of actinomycetes concentrations compared to taste-and-odor compound concentrations, cyanobacteria production likely was the dominant source of the taste-and-odor episodes rather than actinomycetes. The lack of spatial and seasonal patterns in actinomycetes concentrations did not correspond to the springtime geosmin concentrations that were elevated above the Charleston Water System treatment threshold in the lower portion of the reservoir. Additionally, actinomycetes concentrations, although ubiquitous, had a median of about 9 and maximum of about 20 colonies per milliliter, which can be considered low for elevated taste-and-odor compound production. Nonetheless, the potential exists for actinomycetes to be a secondary source of taste-and-odor production and could explain some of the ubiquitous occurrence of low-level taste-and-odor production, such as MIB concentrations, observed throughout the summer and early fall months. When evaluated by biovolume, cyanobacteria were not the dominant phytoplankton group in Bushy Park Reservoir during the study period. Dolichospermum planctonicum (previously Anabaena planktonica ) was the dominant genera of the cyanobacteria group during spring periods. The geosmin-producing genera that were identified in the 2014 and 2015 spring communities in Bushy Park Reservoir were not observed in the 1999 and 2000 algal taxonomic data. A more robust examination of phytoplankton species was conducted by using a multivariate analysis that identified seasonal changes in phytoplankton community structure. These seasonal phytoplankton communities appeared to be explained by seasonal changes in water chemistry and may be responsible for episodes of taste-and-odor occurrence, especially geosmin. The most probable source of geosmin identified during the study was D. planctonicum . In a synoptic sampling event during a taste-and-odor episode in April 2015, cyanobacteria, not acinomycetes, also was indicated to be the more prevalent source of the geosmin. Although the Edisto River intake and its associated supply tunnel to the treatment facility had relatively high actinomycetes concentrations (130 and 140 colonies per milliliter, respectively) compared to the Bushy Park intake and tunnel (2 colonies per milliliter), corresponding geosmin concentrations were below 5 nanograms per liter for source water from the Edisto River intake and tunnel. Elevated geosmin concentrations above the Charleston Water System treatment threshold were identified in source waters from the Bushy Park Reservoir. The cyanobacteria community at the sampled sites in April 2015 was statistically similar to the community in the Bushy Park Reservoir in April 2014, when geosmin concentrations also were elevated. The only geosmin-producing genus identified at the Bushy Park intake, however, was D. planctonicum .

South Carolina↗
USGS2003

Sulfur geochemistry of hydrothermal waters in Yellowstone National Park, Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters

A sampling protocol for the retention, extraction, and analysis of sulfoxyanions in hydrothermal waters has been developed in the laboratory and tested at Yellowstone National Park and Green Lake, NY. Initial laboratory testing of the anion-exchange resin Bio-Rad??? AG1-X8 indicated that the resin was well suited for the sampling, preservation, and extraction of sulfate and thiosulfate. Synthetic solutions containing sulfate and thiosulfate were passed through AG1-X8 resin columns and eluted with 1 and 3 M KCl, respectively. Recovery ranged from 89 to 100%. Comparison of results for water samples collected from five pools in Yellowstone National Park between on-site IC analysis (U.S. Geological Survey mobile lab) and IC analysis of resin-stored sample at SUNY-Stony Brook indicates 96 to 100% agreement for three pools (Cinder, Cistern, and an unnamed pool near Cistern) and 76 and 63% agreement for two pools (Sulfur Dust and Frying Pan). Attempts to extract polythionates from the AG1-X8 resin were made using HCl solutions, but were unsuccessful. Bio-Rad??? AG2-X8, an anion-exchange resin with weaker binding sites than the AG1-X8 resin, is better suited for polythionate extraction. Sulfate and thiosulfate extraction with this resin has been accomplished with KCl solutions of 0.1 and 0.5 M, respectively. Trithionate and tetrathionate can be extracted with 4 M KCl. Higher polythionates can be extracted with 9 M hydrochloric acid. Polythionate concentrations can then be determined directly using ion chromatographic methods, and laboratory results indicate recovery of up to 90% for synthetic polythionate solutions using AG2-X8 resin columns. ?? The Royal Society of Chemistry and the Division of Geochemistry of the American Chemical Society 2003.

Geochemical Transactions↗
USGS1995

Inter-relation of cytochrome P450 and contaminants burdens in sibling heron embryos and nestlings

Hepatic cytochrome P450-associated monooxygenase activities were measured in 11-day-old nestling black-crowned night-herons (Nycticorax nycticorax) collected from a reference site (next to the Chincoteague National Wildlife Refuge, Virginia) and three polluted sites (Cat Island, Green Bay, Lake Michigan, Wisconsin; Bair Island, San Francisco Bay, California; West Marin Island, San Francisco Bay, California). Activities of arylhydrocarbon hydroxylase (AHH) and benzyl-oxyresorufin-O-dealkylase (BROD) weremodestly elevated (<three-fold) in nestlings from polluted sites. Concentrations of p,p?DDE, other organochlorinepesticides and total PCBs in nestlings were greatest at contaminated sites, although much lower than found in concurrently collected eggs and pipping embryos. At these low pollutant concentrations there was little correlation between monooxygenase activity and contaminant levels in nestlings. These observations markedly contrast the pronounced monooxygenase induction (up to 85-fold) and its significant correlation with total PCBs, arylhydrocarbon receptor-active PCB congeners and toxic equivalents in concurrently collected night-heron embryos that were often siblings of the nestlings. The present findings suggest that cytochrome P450-associated monooxygenase activity of heron nestlings may have only limited value as a biomarker of exposure at this rapid-growth life stage.

Society of Environmental Toxicology and Chemistry,↗
USGS1988

Chemistry, mineralogy and origin of the clay-hill nitrate deposits, Amargosa River valley, Death Valley region, California, U.S.A.

The clay-hill nitrate deposits of the Amargosa River valley, California, are caliche-type accumulations of water-soluble saline minerals in clay-rich soils on saline lake beds of Miocene, Pliocene(?) and Pleistocene age. The soils have a maximum thickness of ??? 50 cm, and commonly consist of three layers: (1) an upper 5-10 cm of saline-free soil; (2) an underlying 15-20 cm of rubbly saline soil; and (3) a hard nitrate-rich caliche, 10-20 cm thick, at the bottom of the soil profile. The saline constituents, which make up as much as 50% of the caliche, are chiefly Cl-, NO-3, SO2-4 and Na+. In addition are minor amounts of K+, Mg2+ and Ca2+, varying, though generally minor, amounts of B2O3 and CO2-3, and trace amounts of I (probably as IO-3), NO-2, CrO2-4 and Mo (probably as MoO2-4). The water-soluble saline materials have an I/Br ratio of ??? 1, which is much higher than nearly all other saline depostis. The principal saline minerals of the caliche are halite (NaCl), nitratite (NaNO3), darapskite (Na3(SO4)(NO3)??H2O), glauberite (Na2Ca(SO4)2), gypsum (CaSO4??2H2O) and anhydrite (CaSO4). Borax (Na2B4O5(OH)4??8H2O), tincalconite (Na2B4O5(OH)4??3H2O) and trona (Na3(CO3)(HCO3)??2H2O) are abundant locally. The clay-hill nitrate deposits are analogous to the well-known Chilean nitrate deposits, and probably are of similar origin. Whereas the Chilean deposits are in permeable soils of the nearly rainless Atacama Desert, the clay-hill deposits are in relatively impervious clay-rich soils that inhibited leaching by rain water. The annual rainfall in the Death Valley region of ??? 5 cm is sufficient to leach water-soluble minerals from the more permeable soils. The clay-hill deposits contain saline materials from the lake beds beneath the nitrate deposits are well as wind-transported materials from nearby clay-hill soils, playas and salt marshes. The nitrate is probably of organic origin, consisting of atmospheric nitrogen fixed as protein by photoautotrophic blue-green algae, which are thought to form crusts on soils at the sites of the deposits when moistened by rainfall. The protein is subsequently transformed to nitrate by autotophic bacteria. ?? 1988.

Chemical Geology↗
USGS1996

Cytochrome P450 and contaminant concentrations in nestling black-crowned night-herons and their interrelation with sibling embryos

Hepatic cytochrome P450-associated monooxygenase activities were measured in 11-d-old nestling black-crowned night-herons ( Nycticorax nycticorax ) collected from a reference site (next to Chincoteague National Wildlife Refuge, VA, USA) and three contaminated sites (Cat Island, Green Bay, WI, USA; Bair Island, San Francisco Bay, CA, USA; and West Marin Island, San Francisco Bay, CA, USA). Arylhydrocarbon hydroxylase and benzyloxyresorufin- O -dealkylase activities of nestlings from contaminated sites were only slightly elevated (less than threefold) compared with the reference site. Organochlorine pesticide and total polychlorinated biphenyl (PCB) concentrations in nestlings were greatest at contaminated sites, although much lower than found in concurrently collected eggs and pipping embryos. Pollutant concentrations of nestlings were rarely associated with monooxygenase activity. In contrast, concurrently collected pipping heron embryos (often siblings of the nestlings) exhibited pronounced monooxygenase induction (means at contaminated sites were elevated up to sevenfold and values of some embryos exceeded 25-fold induction). Furthermore, monooxygenase activity of pipping embryos was significantly correlated with total PCBs, arylhydrocarbon receptor-active PCB congeners, and toxic equivalents. The modest monooxygenase responses of heron nestlings suggest that this biomarker may have only limited value during this rapid-growth life stage.

California, Virginia, Wisconsin↗
USGS2024

In situ lung dust analysis by automated Field Emission Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy: A method for assessing inorganic particles in tissue from coal miners

Context.— Overexposure to respirable coal mine dust can cause severe lung disease including progressive massive fibrosis (PMF). Field emission scanning electron microscopy with energy dispersive x-ray spectroscopy (FESEM-EDS) has been used for in situ lung dust particle analysis for evaluation of disease etiology. Automating such work can reduce time, costs, and user bias. Objective.— To develop and test an automated FESEM-EDS method for in situ analysis of inorganic particles in coal miner lung tissue. Design.— We programmed an automated FESEM-EDS procedure to collect particle size and elemental data, using lung tissue from 10 underground coal miners with PMF and 4 control cases. A statistical clustering approach was used to establish classification criteria based on particle chemistry. Data were correlated to PMF/non-PMF areas of the tissue, using corresponding brightfield microscopy images. Results for each miner case were compared with a separate corresponding analysis of particles recovered following tissue digestion. Results.— In situ analysis of miner tissues showed higher particle number densities than controls and densities were generally higher in PMF than non-PMF areas. Particle counts were typically dominated by aluminum silicates with varying percentages of silica. Compared to digestion results for the miner tissues, in situ results indicated lower density of particles (number per tissue volume), larger size, and a lower ratio of silica to total silicates—probably due to frequent particle clustering in situ. Conclusions.— Automated FESEM-EDS analysis of lung dust is feasible in situ and could be applied to a larger set of mineral dust–exposed lung tissues to investigate specific histologic features of PMF and other dust-related occupational diseases.

Archives of Pathology↗
USGS1998

Reproduction and environmental contamination in tree swallows nesting in the Fox River drainage and Green Bay, Wisconsin, USA

Concentration, accumulation, and effects of polychlorinated biphenyls (PCBs) o nreproduction in tree swallows ( Tachycineta bicolor ) were studied at four sites in the Fox River drainage and in Green Bay, Lake Michigan, Wisconsin, USA, in 1994 and 1995. Total PCBs in eggs and newly hatched young (mean = 3.01 μg/g wet weight, years and sites combined) and 12-d-old nestlings (mean = 2.34 μg/g wet weight) at two contaminated sites (Kidney Island and Arrowhead) were higher than concentrations at two reference sites (Lake Poygan and High Cliff State Park, years and sites combined, pippers mean = 0.26 μg/g, nestlings mean = 0.01 μg/g). Concentrations of 11 PCB congeners were also higher at contaminated compared to reference sites. Polychlorinated biphenyls (PCBs) accumulated in nestlings at a higher rate (1.34–6.69 μg/d) at contaminated sites compared to reference locations (0.06–0.42 μg/d). Dichlorodiphenyldichloroethylene (DDE) was the only other organochlorine found in all samples; concentrations for all samples averaged ≤0.20 μg/g wet weight. Total PCBs and p,p ′-DDE concentrations did not differ among clutches where all eggs hatched, some eggs hatched, and no eggs hatched.

Wisconsin↗
USGS2010

Breakpoint analysis and assessment of selected stressor variables on benthic macroinvertebrate and fish communities in Indiana streams: Implications for developing nutrient criteria

Water chemistry, periphyton and seston chlorophyll a (CHL a ), and biological community data were collected from 321 sites from 2001 through 2005 to (1) determine statistically and ecologically significant relations among the stressor (total nitrogen, total phosphorus, periphyton and seston CHL a , and turbidity) variables and response (biological community) variables; and, (2) determine the breakpoint of biological community attributes and metrics in response to changes in stressor variables. Because of the typically weak relations among the stressor and response variables, methods were developed to reduce the effects of non-nutrient biological stressors that could mask the effect of nutrients. Stressor variable concentrations ranged from 0.30 to 11.0 milligrams per liter (mg/L) for total nitrogen, 0.025 to 1.33 mg/L for total phosphorus, 2.9 to 768 milligrams per square meter (mg/m 2 ) for periphyton CHL a , and 0.37 to 42 micrograms per liter (µg/L) for seston CHL a . Turbidity, another stressor variable, ranged from 0.8 to 65.4 Nephelometric turbidity units (NTUs). When the nutrient and CHL a data were compared to Dodds’ trophic classifications, 75.0 percent of the values for total nitrogen, 46.6 percent of the values for total phosphorus, 35.8 percent of the values for periphyton CHL a , and 3.5 percent of the values for seston CHL a , were eutrophic. The invertebrate communities were dominated by families considered highly nutrient tolerant, Chironimidae, (41.7 percent relative abundance), Hydropsychidae, (17.3 percent relative abundance), and Baetidae, (10.2 percent relative abundance). Fish communities were dominated by algivores and nutrient-tolerant species, specifically central stonerollers (13.3 percent relative abundance), creek chubs (9.9 percent relative abundance), and bluntnose minnows (9.3 percent relative abundance). Although not the dominant taxa, white sucker, spotted sucker, green sunfish, and bluegill species were correlated (p ‹0.05) with the stressor variables. The median breakpoints ranged from 2.4 to 3.3 mg/L for total nitrogen, from 0.042 to 0.129 mg/L for total phosphorus, from 54 to 68 mg/m 2 for periphyton CHL a , from 4.5 to 7.5 µg/L for seston CHL a , and from 14.1 to 16.1 NTU for turbidity. The breakpoints determined in this study, in addition to Dodds’ trophic classifications, were used as multiple lines of evidence to show changes in fish and invertebrate community and attributes based on annual exposure to nutrients.

Indiana↗
USGS1997

Distribution of organochlorine contaminants in double-crested cormorant eggs and sibling embryos

Double-crested cormorant ( Phalacrocorax auritus ) fresh eggs and sibling embryos at pipping were collected from a polychlorinated biphenyl (PCB)-contaminated colony in Green Bay, Wisconsin, USA. Egg contents were analyzed for organochlorine (OC) contaminants, including 15 arylhydrocarbon-active PCB congeners. In order to determine the significance of tissue removal on the subsequent estimate of contaminant burden, embryos were decapitated and the heads, yolk sac, liver, fecal sac (allantois), and carcass remainder were analyzed separately. The distribution of contaminant concentration in the embryos was yolk sac > liver > carcass > head > fecal sac. The distribution of contaminant mass in the embryos was yolk sac > carcass > liver > head > fecal sac. For example, mass of total PCBs (TPCB) was yolk sac = 58%, carcass = 31%, liver = 5%, head = 3%, and fecal sac = 1%. Eighteen additional OCs, including 13 PCB congeners, had distribution patterns similar to that of TPCB concentration and mass. Excluding the head of the embryo from the chemical analysis overestimated TPCB concentrations by 15% (16 vs 14 μg/g). In contrast, excluding the liver from the chemical analysis underestimated TPCB concentration by only 4% (13.5 vs 14 μg/g). Mean concentrations of OCs were not significantly different between fresh eggs and sibling embryos.

Environmental Toxicology and Chemistry↗
USGS2008

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗
USGS2007

Hydrothermal nontronite formation at Eolo Seamount (Aeolian volcanic arc, Tyrrhenian Sea)

A sediment core containing a yellowish-green clay bed was recovered from an area of extensive hydrothermal deposition at the SE slope of the Eolo Seamount, Tyrrhenian Sea. The clay bed is composed of pure nontronite (described for the first time in the Tyrrhenian Sea), which appears to be the most aluminous nontronite ever found among the seafloor hydrothermal deposits. The high Al content suggests precipitation from Al-containing hydrothermal solutions. The REE distribution of the Eolo nontronite has a V-shape pattern. The heavy REE enrichment is in part due to their preferential partitioning in the nontronite structure. This enrichment was possibly further enhanced by the HREE preferential sorption on bacterial cell walls. The light REE enrichment is the result of scavenging uptake by one of the nontronite precursors, i.e., poorly-ordered Fe-oxyhydroxides, from the hydrothermal fluids. Oxygen isotopic composition of the nontronite yields a formation temperature of 30????C, consistent with a low-temperature hydrothermal origin. The relatively radiogenic Nd isotopic signature of the nontronite compared to the present-day Mediterranean seawater indicates that approximately half of Nd, and presumably the rest of the LREE, are derived from local volcanic sources. On the other hand, 87Sr/86Sr is dominated by present-day seawater Sr. Scanning electron microscopy investigation revealed that the nontronite is composed of aggregates of lepispheres and tube-like filaments, which are indicative of bacteria assisted precipitation. Bacteria inhabiting this hydrothermal site likely acted as reactive geochemical surfaces on which poorly-ordered hydrothermal Fe-oxyhydroxides and silica precipitated. Upon aging, the interactions of these primary hydrothermal precipitates coating bacterial filaments and cell walls likely led to the formation of nontronite. Finally, the well-balanced interlayer and layer charges of the crystal lattice of seafloor hydrothermal nontronite decrease its sorption capacity to zero. Thus the ubiquitous nontronite precipitation along the active plate boundaries and around the hot spots has no significant impact on oceanic trace element chemistry. ?? 2007 Elsevier B.V. All rights reserved.

Chemical Geology↗
USGS1989

Multiple hydrothermal and metamorphic events in the Kidd Creek volcanogenic massive sulphide deposit, Timmins, Ontario: evidence from tourmalines and chlorites

Tourmaline and chlorite are the principal ferromagnesian silicate minerals in the Kidd Creek massive sulphide deposit. Tourmaline is most common in sphalerite-rich peripheral margins of the chalcopyrite stringer zone. Within the north orebody, samples typically contain <1% tourmaline, but small areas (hand-specimen scale) may have 10–20%. Chlorite is more widely distributed and in places constitutes 30–50% of rock volumes. Associated assemblages may include quartz, sulphides (principally chalcopyrite, sphalerite, and (or) pyrite), carbonate, albite, sericite, and rare fluorite, allanite, or zoisite(?).The tourmalines and chlorites record a series of multiple hydrothermal and metamorphic events. Paragenetic studies suggest that tourmaline was deposited during several discrete stages of mineralization, as evidenced by brecciation and cross-cutting relationships. Most of the tourmalines have two concentric growth zones defined by different colours (green, brown, blue, yellow). Some tourmalines also display pale discordant rims that cross-cut and embay the inner growth zones and polycrystalline, multiple-extinction domains. Late sulphide veinlets (chalcopyrite, pyrrhotite) transect the inner growth zones and pale discordant rims of many crystals. The concentric growth zones are interpreted as primary features developed by the main ore-forming hydrothermal system, whereas the discordant rims, polycrystalline domains, and cross-cutting sulphide veinlets reflect post-ore metamorphic processes.Detailed electron microprobe analyses of tourmalines show a wide compositional range, from Fe-rich dravite nearly to end-member schorl, with Fe/(Fe + Mg) ratios varying from 0.33 to 0.92; only minor amounts of Ca are present, yielding uniformly high Na/(Na + Ca) ratios of 0.84–0.99. Two sets of chemical zoning trends are identified in the tourmalines, involving systematic changes in Fe/(Fe + Mg), Na/(Na + Ca), Al, and Ti that are believed to reflect internal coupled substitutions (e.g.,  + Ti = Na + Al) and local mineral equilibria (e.g., tourmaline–chlorite). Analyses of the pale discordant reaction rims show consistent depletion of Fe, Ca, and Ti, presumably by fluid–solid reactions during post-ore metamorphism.Chlorites also show an extensive range in composition, from ripidolite nearly to end-member daphnite, with Fe/(Fe + Mg) ratios of 0.43–0.98 and Si cation values of 5.00–5.39. Chlorites from the fringes of the footwall stringer zone have narrow compositional ranges, whereas chlorites near footwall rhyolite sills in the core of the stringer zone display major variations in Fe/(Fe + Mg) ratios, including one sample with a range of 0.68–0.95. The former group of chlorites has Fe/(Fe + Mg) ratios that correlate well with those of coexisting tourmalines (exclusive of late reaction rims). Data for the latter group, in contrast, fall off equilibrium K D curves, indicating that the tourmalines and chlorites within these samples are not in chemical equilibrium. The chlorites are believed to have been altered (overprinted) by Fe-rich hydrothermal fluids apparently generated during intrusion of the rhyolite sills. The tourmalines, however, are unaffected and retain primary chemical signatures.Variations in mineral proportions and mineral chemistry within the deposit mainly depend on fluctuations in temperature, pH, water/rock ratios, and amounts of entrained seawater. The major proposed control is mixing between high-temperature, Fe-rich end-member hydrothermal fluids and cold, Mg-rich entrained seawater. Fe/(Fe + Mg) variations in footwall tourmalines (and equilibrium chlorites) are believed to largely reflect the progressive infiltration of Mg-rich seawater into the margins and top of the hydrothermal system. The more Fe-rich compositions of Kidd Creek tourmalines relative to those from sediment-hosted massive sulphide deposits (e.g., Sullivan, British Columbia) may be related to the preferential generation of end-member hydrothermal fluids in proximal volcanic environments like that at Kidd Creek.

Ontario↗
USGS1973

Lake Michigan: Man's effects on native fish stocks and other biota

Man's activities have caused great changes in Lake Michigan in the past 120 years. Although changes in water chemistry and lower biota have been generally modest (except locally), those in native fish stocks have been vast. Exploitation, exotic fish species, and eutrophication and other forms of pollution all have played a role in bringing about the changes (mostly declines in abundance) in fish populations. Exploitation resulted in a noticeable reduction in abundance of certain native species (especially whitefish) soon after the establishment of the commercial fishery in the 1840's. By the 1930's the sturgeon and the two largest deepwater ciscoes (Coregonus nigripinnis and C. johannae) became severely depleted. Other species- whitefish (Coregonus clupeaformis), lake trout (Salvelinus namaycush), and lake herring (C. artedii)- remained important commercially, but at a lower level of production than originally; greatly increased fishing effort and efficiency were required to maintain even these decreased catches. The catch of intermediate-size ciscoes held relatively stable, but again only through sharply increased fishing effort and efficiency. The earliest serious effects of exotic fish species on native fish stocks may have been during the 1930's, when smelt (Osmerus mordax), first became abundant. Powerful influences by exotics were not obvious, however, until the 1940's, when the sea lamprey's (Petromyzon marinus) predation on several species, particularly the lake trout, became critical. In the 1950's the sea lamprey was joined by the alewife (Alosa pseudoharengus), another exotic strongly deleterious to several native fish. The alewife apparently inhibited reproduction of deepwater ciscoes, yellow perch (Perca flavescens), deepwater sculpins (Myoxocephalus quadricornis), emerald shiners (Notropis atherinoides), and perhaps others (through competing with young, or feeding on them). At the same time, however, the alewife as a prolific forage fish has made possible the highly successful introduction of several species of salmonines. The effects of accelerated eutrophication and other pollution, although not always as easy to identify as the influences of other factors, were nevertheless clearly important as early as the mid-1800's. The first conspicuous contamination of Lake Michigan was by sawmill wastes, which covered spawning grounds in streams and around stream mouths. This type of pollution was particularly destructive to whitefish. Other forms of stream degradation (e.g., dams, deforestation of watersheds) although not strictly "pollution," must also have been detrimental to stream spawners. Heavy pollution in southern Green Bay (a large area of the bottom of which is now covered with anoxic gray sludge) probably has resulted in reduction in abundance of several species, e.g., lake herring and walleye (Stizostedion v. vitreum). Exploitation was largely responsible for the changes in Lake Michigan fish stocks before the invasion of the smelt, and probably before the invasion of the sea lamprey. The lamprey and alewife, however, have exerted a greater impact than the fishery on native fish populations in recent decades. Accelerated eutrophication and other pollution, although important, have not equalled the other factors in causing changes in native fish populations.

Technical Report↗