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At least 109 records · Page 6Linked to original sources
USGS1978

Overburden chemistry and mineralogy at Hanging Woman Creek, Big Horn County, Montana, and recommendations for sampling at similar sites

Cored overburden rock of the Fort Union Formation at the Hanging Woman Creek potential coal mine site was classified in hand specimen on the basis of color and grain size into 3 types: sandstone. siltstone-plus-shale, and dark shale. The samples were analyzed for bulk chemistry and mineralogy. In general the samples of sandstone contain the lowest concentrations of elements of environmental concern (arsenic, beryllium, mercury. molybdenum, selenium and sulfur), and samples of the dark shale contain the highest. Comparison of samples within each rock type shows that chemical composition does not change systematically across the study site (a distance of 5 km), and almost as much information about overburden chemistry could have been obtained from a single hole drilled anywhere on the site. Overburden data from other sites in the region show that rocks at the Hanging Woman Creek site are chemically similar to those of the region as a whole, which suggests that the rock chemistry at other sites in the region could also be estimated from a low-density drilling and sampling pattern.

Montana↗
USGS1994

Chemistry of spring and well waters on Kilauea Volcano, Hawaii, and vicinity

Published and new data for chemical and isotopic samples from wells and springs on Kilauea Volcano and vicinity are presented. These data are used to understand processes that determine the chemistry of dilute meteoric water, mixtures with sea water, and thermal water. Data for well and spring samples of non-thermal water indicate that mixing with sea water and dissolution of rock from weathering are the major processes that determine the composition of dissolved constituents in water. Data from coastal springs demonstrate that there is a large thermal system south of the lower east rift of Kilauea. Samples of thermal water from shallow wells in the lower east rift and vicinity have rather variable chemistry indicating that a number of processes operate in the near surface. Water sampled from the available deep wells is different in composition from the shallow thermal water, indicating that generally there is not a significant component of deep water in the shallow wells. Data for samples from available deep wells show significant gradients in chemistry and steam content of the reservoir fluid. These gradients are interpreted to indicate that the reservoir tapped by the existing wells is an evolving vapor-dominated system.

Open-File Report↗
USGS1995

K1-95-HW: Cruise report 1995 - Preliminary results, phase III: Sediment chemistry and biological sampling survey

Mamala Bay, off the south shore of the island of Oahu, has been used as a repository of dredged material primarily from Pearl and Honolulu Harbors for over a century. The U.S. Geological Survey, U.S. Army Corps of Engineers, and the U.S. Environmental Protection Agency are conducting an integrated study on the distribution and character of dredged materials as well as the effects of dredged material on the marine environment. A three phase study is providing information to evaluate the effects on seafloor substrate and the benthic fauna. The studies include geophysical profiling and imaging, bottom photography, sampling, chemical and physical analyses of sediment, and evaluations of the benthic population, population density, and adverse impacts to the benthic fauna. Phase 1, conducted in 1993, inventoried the seafloor via remote sensing. Sidescan sonar and subbottom profilers characterized the seafloor in and around the disposal sites, and the resulting products reveal the character and extent of the dredged material. These data were used to plan Phase 2 in 1994, a sampling program that employed subbottom profilers, video and still photography, and seafloor sampling to ground truth the sonar mosaic and identify the seafloor substrates responsible for the various acoustic signatures on the sonar images and subbottom profiles. Box coring provided the samples necessary to distinguish dredged material from native sediment, and for the chemical analyses used to determine contaminant concentrations. Phase 3 studies conducted in June of 1995 consisted of box core sampling for chemical and biological analyses. Specific studies include: infaunal taxonomy and population density, bioassay/bioaccumulation, sediment chemistry, and post-disposal resuspension and transport. The 1995 survey, conducted June 14 through 17, resulted in the collection of 39 box cores from 20 different stations. Multiple box cores were composited at 7 different locations occupied in 1994, to provide the material required for the 7 bioassay and bioaccumulation analyses currently underway (Figure 1). Seventeen of the 20 stations occupied provided the biological samples for the benthic infaunal identification and population density study conducted by Dr. Julie Brock of the University of Hawaii, and the sediment chemistry analyses conducted (and completed) by Quanterra Environmental Laboratories (Figure 1). Seven of the 20 stations occupied in 1995 were occupied in 1994, and provide the data for direct comparison of sediment chemistry at the same sites from two consecutive years. The sum total of the data collected from all three phases of the monitoring program will provide the U.S. Army Corps of Engineers and the U.S. Environmental Protection Agency with the information required to make informed decisions as to the management of the South Oahu disposal site in Mamala Bay.

Hawai'i↗
USGS1999

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona, 1997

The Black Mesa monitoring program is designed to document long-term effects of ground-water from the N aquifer by industrial and municipal users. The N aquifer is the major source of water in the 5,400-square-mile Black Mesa area, and the ground water occurs under confined and unconfined conditions. Monitoring activities include continuous and periodic measurements of (1) ground-water pumpage from the confined and unconfined parts of the aquifer, (2) ground-water levels in the confined and unconfined parts of the aquifer, (3) surface-water discharge, and (4) chemistry of the ground water and surface water. In 1997, ground-water withdrawals for industrial and municipal use totaled about 7,090 acre-feet, which is less than a 1-percent increase from 1996. Pumpage from the confined part of the aquifer increased by about 2 percent to 5,510 acre-feet, and pumpage from the unconfined part of the aquifer decreased by about 4 percent to 1,580 acre-feet. Water-level declines in the confined part during 1997 were recorded in 5 of 12 wells; however, the median change was a rise of about 0.2 foot as opposed to a decline of 2.8 feet for 1996. Water-level declines in the unconfined part were recorded in 7 of 15 wells, and the median change was 0.0 foot in 1997 as opposed to a decline of 0.5 foot in 1996. The low-flow discharge at the Moenkopi streamflow-gaging station ranged from 1.6 to 2.0 cubic feet per second in 1997. Streamflow-discharge measurements also were made at Laguna Creek, Dinnebito Wash, and Polacca Wash during 1997. The low-flow discharge ranged from 2.3 to 4.2 cubic feet per second at Laguna Creek, 0.44 to 0.48 cubic foot per second at Dinnebito Wash, and 0.15 to 0.26 cubic foot per second at Polacca Wash. Discharge was measured at three springs. Discharge from Moenkopi School Spring increased by about 3 gallons per minute from the measurement in 1996. Discharge from an unnamed spring near Dennehotso increased by 9.9 gallons per minute from the measurement made in 1996; however, discharge decreased slightly at Burro Spring. Regionally, long-term water-chemistry data for wells and springs have remained stable. Locally, water-chemistry data for some wells have shown marked increases in concentrations of major constituents.

Arizona↗
USGS1987

Hydrology and chemistry of selected prairie wetlands in the Cottonwood Lake area, Stutsman County, North Dakota, 1979-82

The relation of hydrologic setting and temporal variability in hydrology to nutrient content and geochemical characteristics of a group of prairie wetlands and adjacent ground water was studied during the period 1979-82. Although data were collected from many wetlands and wells at the study site, emphasis in this report primarily is on four wetlands two seasonal and two semipermanent and four wells contiguous to them along a hydrologic section. The seasonal wetlands, T8 and T3, contained water only for a few weeks to months after filling in spring and early summer; both were completely dry by August. The semipermanent wetlands, PI and P8, contained water throughout each year and were ice covered in winter. One wetland, T8, recharges ground water. Wetlands PI and P8 are in areas of ground-water discharge. None of the wetlands received water by channelized surface-water inlets. Only wetland P8 had a channelized surface-water outlet. Ground-water-level data showed that high points of the water table did not always occur beneath land-surface highs. Reversals of ground-water flow occurred occasionally between two of the wetlands, T3 and PI. Significant differences existed in the chemical composition of the wetlands based on their hydrologic setting. In general, the dominant cation and anion in the wetlands were potassium and bicarbonate in wetland T8, calcium and sulfate in wetland T3, magnesium and sulfate in wetland PI, and magnesium and bicarbonate in wetland P8. Significant seasonal differences existed in the water chemistry of the wetlands in ground-water discharge areas. Water in three of the wetlands, T3, Pi, and P8, was most dilute while they filled in spring after icemelt. Concentration increased during the open-water period, and two of the wetlands, PI and P8, became most concentrated under ice cover. Concentrations of total phosphorus and total nitrogen were greatest in wetlands in areas of ground-water recharge and least in wetlands in areas of ground-water discharge. Differences in the chemistry of water from wells in the adjacent ground water resulted primarily from the positions of the wells in the ground-water flow system. The chemical type of water from well 12, which was located in a ground-water recharge area, was calcium sodium bicarbonate. Water from well 4, located downgradient from wetland T8, and from well 16, located downgradient from wetland PI, typically was a calcium sulfate type. Water from well 13, located between wetlands T3 and PI in an area of changing ground-water flow directions, was a magnesium sulfate type. Data from this study show that an understanding of hydrologic conditions is important in the interpretation of the water chemistry of wetlands in the study area.

Professional Paper↗
USGS2006

Geohydrological characterization, water-chemistry, and ground-water flow simulation model of the Sonoma Valley area, Sonoma County, California

The Sonoma Valley, located about 30 miles north of San Francisco, is one of several basins in Sonoma County that use a combination of ground water and water delivered from the Russian River for supply. Over the past 30 years, Sonoma Valley has experienced rapid population growth and land-use changes. In particular, there has been a significant increase in irrigated agriculture, predominantly vineyards. To provide a better understanding of the ground-water/surface-water system in Sonoma Valley, the U.S. Geological Survey compiled and evaluated existing data, collected and analyzed new data, and developed a ground-water flow model to better understand and manage the ground-water system. The new data collected include subsurface lithology, gravity measurements, groundwater levels, streamflow gains and losses, temperature, water chemistry, and stable isotopes. Sonoma Valley is drained by Sonoma Creek, which discharges into San Pablo Bay. The long-term average annual volume of precipitation in the watershed is estimated to be 269,000 acre-feet. Recharge to the ground-water system is primarily from direct precipitation and Sonoma Creek. Discharge from the ground-water system is predominantly outflow to Sonoma Creek, pumpage, and outflow to marshlands and to San Pablo Bay. Geologic units of most importance for groundwater supply are the Quaternary alluvial deposits, the Glen Ellen Formation, the Huichica Formation, and the Sonoma Volcanics. In this report, the ground-water system is divided into three depth-based geohydrologic units: upper (less than 200 feet below land surface), middle (between 200 and 500 feet), and lower (greater than 500 feet). Synoptic streamflow measurements were made along Sonoma Creek and indicate those reaches with statistically significant gains or losses. Changes in ground-water levels in wells were analyzed by comparing historical contour maps with the contour map for 2003. In addition, individual hydrographs were evaluated to assess temporal changes by region. In recent years, pumping depressions have developed southeast of Sonoma and southwest of El Verano. Water-chemistry data for samples collected from 75 wells during 2002-04 indicate that the ground-water quality in the study area generally is acceptable for potable use. The water from some wells, however, contains one or more constituents in excess of the recommended standards for drinking water. The chemical composition of water from creeks, springs, and wells sampled for major ions plot within three groups on a trilinear diagram: mixed-bicarbonate, sodium-mixed anion, and sodium-bicarbonate. An area of saline ground water in the southern part of the Sonoma Valley appears to have shifted since the late 1940s and early 1950s, expanding in one area, but receding in another. Sparse temperature data from wells southwest of the known occurrence of thermal water suggest that thermal water may be present beneath a larger part of the valley than previously thought. Thermal water contains higher concentrations of dissolved minerals than nonthermal waters because mineral solubilities generally increase with temperature. Geohydrologic Characterization, Water-Chemistry, and Ground-Water Flow Simulation Model of the Sonoma Valley Area, Sonoma County, California Oxygen-18 (d18 O) and deuterium (dD) values for water from most wells plot along the global meteoric water line, indicating that recharge primarily is derived from the direct infiltration of precipitation or the infiltration of seepage from creeks. Samples from shallow- and intermediate-depth wells located near Sonoma Creek and (or) in the vicinity of Shellville plot to the right of the global meteoric water line, indicating that these waters are partly evaporated. The d18 O and dD composition of water from sampled wells indicates that water from wells deeper than 200 feet is isotopically lighter (more negative) than water from wells less than 200 feet deep, possibly indicating that older ground wate

California↗
USGS2011

Gas and isotope chemistry of thermal features in Yellowstone National Park, Wyoming

This report presents 130 gas analyses and 31 related water analyses on samples collected from thermal features at Yellowstone between 2003 and 2009. An overview of previous studies of gas emissions at Yellowstone is also given. The analytical results from the present study include bulk chemistry of gases and waters and isotope values for water and steam (delta18O, dealtaD), carbon dioxide (delta13C only), methane (delta13C only), helium, neon, and argon. We include appendixes containing photos of sample sites, geographic information system (GIS) files including shape and kml formats, and analytical results in spreadsheets. In addition, we provide a lengthy discussion of previous work on gas chemistry at Yellowstone and a general discussion of the implications of our results. We demonstrate that gases collected from different thermal areas often have distinct chemical signatures, and that differences across the thermal areas are not a simple function of surface temperatures or the type of feature. Instead, gas chemistry and isotopic composition are linked to subsurface lithologies and varying contributions from magmatic, crustal, and meteoric sources.

Wyoming↗
USGS2011

Trends in lake chemistry in response to atmospheric deposition and climate in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming, 1993-2009

In 2010, the U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Forest Service, Air Resource Management, began a study to evaluate long-term trends in lake-water chemistry for 64 high-elevation lakes in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming during 1993 to 2009. The purpose of this report is to describe trends in the chemical composition of these high-elevation lakes. Trends in emissions, atmospheric deposition, and climate variables (air temperature and precipitation amount) are evaluated over a similar period of record to determine likely drivers of changing lake chemistry. Sulfate concentrations in precipitation decreased over the past two decades at high-elevation monitoring stations in the Rocky Mountain region. The trend in deposition chemistry is consistent with regional declines in sulfur dioxide emissions resulting from installation of emission controls at large stationary sources. Trends in nitrogen deposition were not as widespread as those for sulfate. About one-half of monitoring stations showed increases in ammonium concentrations, but few showed significant changes in nitrate concentrations. Trends in nitrogen deposition appear to be inconsistent with available emission inventories, which indicate modest declines in nitrogen emissions in the Rocky Mountain region since the mid-1990s. This discrepancy may reflect uncertainties in emission inventories or changes in atmospheric transformations of nitrogen species that may be affecting deposition processes. Analysis of long-term climate records indicates that average annual mean air temperature minimums have increased from 0.57 to 0.75 °C per decade in mountain areas of the region with warming trends being more pronounced in Colorado. Trends in annual precipitation were not evident over the period 1990 to 2006, although wetter than average years during 1995 to 1997 and drier years during 2001 to 2004 caused a notable decline in precipitation in the middle part of the record.

Colorado;Idaho;Utah;Wyoming↗
USGS2021

Spring types and contributing aquifers from water-chemistry and multivariate statistical analyses for seeps and springs in Theodore Roosevelt National Park, North Dakota, 2018

Water resources in Theodore Roosevelt National Park, North Dakota, support wildlife, visitors, and staff, and play a vital role in supporting the native ecology of the park. The U.S. Geological Survey, in cooperation with the National Park Service, completed field work in 2018 for a study to address concerns about water availability and possible sources of groundwater contamination for seeps and springs in Theodore Roosevelt National Park. The objective of the study was to improve hydrologic knowledge and determine the water composition of 11 seeps and springs in the park by collecting water-chemistry data at springs, streams, wells, and rain collectors. Water samples were collected at 26 sites at springs, streams, wells, and rain collectors in the North and South Units of Theodore Roosevelt National Park. Samples in the North Unit were collected at 5 springs, 1 stream, 2 wells, and 1 rain collector. Samples in the South Unit were collected at 6 springs, 2 streams, 8 wells, and 1 rain collector. Samples from springs, streams, and wells were collected in May, July, and September 2018. Samples from rain collectors were collected when enough daily precipitation accumulated in the collectors. Sampled precipitation events during the study period were in May, June, July, August, and September 2018. Physical properties of sampled water—temperature, pH, and specific conductance—were measured in the field. Water samples were analyzed for stable isotopes of oxygen and hydrogen and for chloride concentration. Recharge rates for aquifers supplying springs were determined using precipitation volume and chloride concentrations for a 12-day period before the sample-collection date. Multivariate statistical analysis methods used on water-chemistry data included principal component analysis, cluster analysis, and end-member mixing analysis. Water composition was used to determine the spring type and contributing aquifers for 11 springs in the North and South Units of Theodore Roosevelt National Park from analyses of water-chemistry data between May and September 2018. In the North Unit, Achenbach Spring was classified as a filtration spring with water from an unconfined part of the upper Fort Union aquifer and infiltration of precipitation. Hagen Spring, Mandal Spring, and Stevens Spring were classified as contact springs supplied by semiconfined parts of the upper Fort Union aquifer. Overlook Spring at one time may have been a natural spring or seep but now is a developed spring that behaves like a flowing artesian well completed in a confined part of the upper Fort Union aquifer. In the South Unit, six springs were classified into two spring types: filtration and contact springs. Boicourt Spring and Sheep Butte Spring were classified as filtration springs that have water supplied by unconfined parts of the upper Fort Union aquifer and infiltrated precipitation. Big Plateau Spring, Lone Tree Spring, Sheep Pasture Spring, and Southeast Corner Spring were classified as contact springs that receive waters from a semiconfined part of the upper Fort Union aquifer.

North Dakota↗
USGS2020

Passive sampling of groundwater wells for determination of water chemistry

Introduction Passive groundwater sampling is defined as the collection of a water sample from a well without the use of purging by a pump or retrieval by a bailer (Interstate Technology and Regulatory Council [ITRC], 2006; American Society for Testing and Materials [ASTM], 2014). No purging means that advection of water is not involved in collecting the water sample from the well. Passive samplers rely on diffusion as the primary process that drives their collection of chemical constituents. Diffusion is the transport of chemicals caused by the presence of a chemical gradient. Chemicals tend to move or diffuse from areas of higher concentration to areas of lower concentration to reach an average or equilibrium concentration. Passive sampling of groundwater relies on the ambient exchange of groundwater in the formation with water in the screened or open interval of a well. In this report, the term formation is used to describe all saturated hydrogeologic units that yield water to a well. If the well opening is unclogged and free of a film of deposits from physical turbidity or chemical precipitation, then the exchange of groundwater is likely adequate, and the water in the open interval will be representative of water in the formation. In some cases, the passive sample from the well opening can be more representative of groundwater from the formation than a sample collected by pumping if pumping induces mixing of water in the open interval with stagnant casing water that has undergone chemical alteration (Harte and others, 2018). In most cases, passive sampling will better represent the ambient groundwater chemistry flowing through the open interval of a well because pumping may capture water of different chemistry from downgradient or lateral areas that would not normally pass through the well. Three basic types of passive samplers are discussed in this report. The first type of passive sampler is the equilibrium-membrane type, which includes a semi-permeable membrane through which chemicals diffuse or permeate. Permeation is simply the process of water or chemicals moving through openings in the membrane. The authors contend that permeation is dominated by diffusion for many of the passive samplers discussed in this report. Some passive equilibrium-membrane-type samplers allow most types of chemical constituents through, whereas others allow the diffusion of only selected groups of chemicals. Once the chemical constituents are inside the membrane, they are retained by the equilibration of concentrations inside the sampler with those outside the sampler. The second type of passive sampler is an equilibrium-thief type, which has no semi-permeable membrane. Chemical constituents simply move through the openings in the body of the sampler either initially through advection and dispersion or over time primarily by diffusion. Chemical constituents reach equilibrium between the water in the sampler and the water in the well and are captured in the sampler when the sampler is closed. The third type of passive sampler is an accumulation-type sampler that contains sorptive media. Selected chemical constituents are sorbed onto the media that the sampler contains for later extraction and analysis. Although passive samplers have been available for more than 15 years (from present [2020]), their use by U.S. Geological Survey (USGS) hydrologists and hydrologic technicians to monitor groundwater quality largely has been limited to selected research studies. The authors believe that this may be the result of (1) a lack of exposure of most USGS personnel to passive samplers and the uses of these samplers and (2) the lack of a USGS-approved protocol for the proper use of these samplers by USGS personnel. This report is an effort to fill those two needs. The focus of this report is on hydraulic, hydrologic, and chemical considerations in the application of passive samplers and interpretation of groundwater chemistry results obtained using passive samplers in wells. This report describes the differences between purging and passive sampling methods in groundwater and explains how and why passive samplers work. The report points out the advantages and limitations of passive samplers in general and for each particular type of passive sampler. Important considerations to be taken into account prior to the use of passive samplers are discussed, such as defining the data-quality objectives, the water-quality constituents to be sampled, sample volumes required for analysis, well construction of the sampling network, and the geologic formations that will be sampled. Potential applications of passive samplers also are discussed, such as chemical-vertical profiling of wells. A general field protocol for the deployment, recovery, and sample collection using these devices is described, and some overall guidance for the practitioner with application examples is given. Comparison methods used to evaluate results from passive sampling versus purge sampling also are discussed.

Techniques and Methods↗
USGS1994

Analysis of meteorological data and water chemistry of Latir Lakes, Taos County, New Mexico, 1985-88

Data were analyzed to determine the chemistry of atmospheric deposition and water of the Latir Lakes in Taos County New Mexico, from 1985 to 1988. The Latir Lakes consist of a series of nine paternoster lakes that range in altitude from 11,061 to 11,893 feet above sea level. The pH of wet precipitation generally ranged from 4.6 to 5.5 and the specific conductance of wet precipitation ranged from 1 to 18 microsiemens per centimeter at 25 degrees Celsius from December 1985 through September 1988. Snowpack chemistry data indicate a change in the specific conductance, pH, and alkalinity of the snowpack from month to month. The dominant cation in the snowpack is calcium, and the dominant anions are nitrate and sulfate. The samples having the smallest values of specific conductance generally did not contain measurable alkalinity. When the snowpack starts to melt in the spring, specific conductance of the entire snowpack decreases, consistent with the hypothesis that the initial fluid draining from the snowpack transports a large amount of dissolved material out of the snowpack. Water chemistries in the Latir Lakes are similar although specific conductance increases downstream from lake 9 to lake 1. Calcium is the dominant cation and the ions that produce alkalinity are the dominant anions. Concentrations of sodium, magnesium, chloride, and sulfate do not vary substantially from year to year or during the year in a particular lake. Alkalinity and calcium concentration, however, do vary from year to year and during the year. The pH of outflow from the Latir Lakes varies from lake to lake and from year to year. In 1986, the range in pH in the lakes was less than 1 unit in mid-June, but was greater than 2.5 units by late October. The pH generally was larger than 7.0 in all of the lakes and was as large as 9.9 in several of the lakes during the period of study. The pH of outflow water generally increases from early spring to late summer in the Latir Lakes, and snowmelt does not seem to cause the pH to decrease in the lakes. Depth profiles of selected lakes indicate that the dissolved-oxygen concentration approaches zero below the thermocline. This suggests biological oxidation of organic matter in the lower zones in these lakes. Because many organisms cannot live in water containing small dissolved-oxygen concentrations, large volumes of water in lakes 9 and 3 probably are not suitable for habitation during the summer months.

Water-Resources Investigations Report↗
USGS1997

Geohydrology and water chemistry in the Rialto-Colton Basin, San Bernardino County, California

The 40-square-mile Rialto-Colton ground- water basin is in western San Bernardino County, California, about 60 miles east of Los Angeles.This basin was chosen for storage of imported water because of the good quality of native ground water, the known capacity for additional ground-water storage in the basin, and the availability of imported water. Because the movement and mixing of imported water needed to be determined, the San Bernardino Valley Municipal Water District entered into a cooperative program with the U.S.Geological Survey in 1991 to study the geohydrology and water chemistry in the Rialto- Colton basin. Ground-water flow and chemistry were investigated using existing data, borehole- geophysical and lithologic logs from newly drilled test holes, measurement of water levels, and chemical analyses of water samples. The Rialto-Colton basin is bounded on the northwest and southeast by the San Gabriel Mountains and the Badlands, respectively. The San Jacinto Fault and Barrier E form the northeastern boundary, and the Rialto-Colton Fault forms the southwestern boundary. Except in the southeastern part of the basin, the San Jacinto and Rialto-Colton Faults act as groundwater barriers that impede ground- water flow into and out of the basin.Barrier E generally does not impede ground- water flow into the basin. The ground-water system consists primarily of gravel, sand, silt, and clay. The maximum thickness is greater than 1,000 feet. The ground- water system is divided into four water-bearing units: river-channel deposits, and upper, middle, and lower water-bearing units. Relatively impermeable consolidated deposits underlie the lower water- bearing unit and form the lower boundary of the ground- water system. Ground water moves from east to west in the river-channel deposits and upper water-bearing unit in the southeastern part of the basin, and from northwest to southeast in the middle and lower water-bearing units. Two major internal faults, Barrier J and an unnamed fault, affect ground-water movement. Ground water moves across Barrier J in the unfaulted part of the ground-water system. The unnamed fault is a partial barrier to ground-water movement in the middle water- bearing unit and an effective barrier in the lower water-bearing unit.Imported water flows laterally across the unnamed fault above the saturated zone. Major sources of recharge to the ground- water system are underflow; precipitation that collects in small streams that drain the San Gabriel Mountains and the Badlands or runs off the mountain front as sheet flow, and sub-surface inflow; imported water; seepage loss from the Santa Ana River and Warm Creek; infiltration of rainfall; and irrigation return flow. The main component of discharge is pumpage. Long-term water levels in production wells reflect precipitation cycles. During a 194777 dry period, water levels in three wells declined almost continuously?as much as 100 feet in one well.Water levels in a well north of Barrier J are not affected by stresses on the groundwater system south of the barrier, indicating that these two parts of the ground-water system are not well connected. Water levels in cluster wells east of the unnamed fault north and south of the Linden Ponds artificial-recharge site rose as much as 70 feet during 1992-95. The rise in water levels in wells near the recharge ponds was observed within 2 months after the beginning of recharge. Water levels in most wells west of the unnamed fault changed very little during 1992-95. Water-chemistry data indicate that chemical characteristics vary within the groundwater system, and that dissolvedsolids concentrations are generally higher in the river-channel deposits, upper water- bearing unit, and the consolidated deposits than in the middle and lower water-bearing units. The chemical characteristics in water from the middle water-bearing unit were similar for most wells sampled west of the unnamed fault. In water from well

Water-Resources Investigations Report↗
USGS2001

Ground-water flow to Death Valley, as inferred from the chemistry and geohydrology of selected springs in Death Valley National Park, California and Nevada

Death Valley lies downgradient from adjacent valleys to the north, south, east, and west in California and Nevada, and is the site of substantial ground-water discharge. The sources of the discharging waters have been discussed by several investigators in the past and are of heightened concern because of the potential disposal of high-level radioactive waste at Yucca Mountain, Nevada, and because of ground-water withdrawals attendant to commercial mining in the northwestern Amargosa Valley region. This report describes high- and low-discharge springs in and along the Amargosa Range that were sampled to augment the level of understanding of the extent and distribution of westward ground-water flow through the range. The Black Mountains do not seem to be part of a significant path of ground-water flow from the Amargosa region. This is attributed to the complex lithology and geologic history of the Black Mountains structural block and to the presence of the intervening Furnace Creek fault zone. The only ground-water discharge associated with the Black Mountains where water chemistry reflects an external source or sources is Saratoga Spring, for which δ 2 H and δ 18 O data indicate recharge in the Spring Mountains to the east. The southern part of the Funeral Mountains transmits a large volume of water through faulted and fractured rocks of Cambrian age that lie at or along the distal part of the northeast -oriented Spotted Range-Mine Mountain structural zone. Waters discharging from springs in the Furnace Creek Ranch vicinity (Travertine and Nevares) both compositionally and isotopically resemble waters from the Ash Meadows spring group in the Amargosa Desert. The Ash Meadows springs and water in the Amargosa Valley alluvium likely are chemically representative of ground water entering the southern Funeral Mountains. Much less ground water flows through the central and northern Funeral Mountains than flows through the southern part, as indicated by the geologic setting and chemistry of Keane Wonder Spring. The northern one-half of the mountains comprises early-to-middle Proterozoic metamorphic rocks that are the core of the Funeral Mountains anticlinorium. The core is largely unfaulted, plunges to the northeast and southwest, and is truncated to some extent on the east by the shallow-dipping Boundary Canyon fault. This structural setting and the paucity of springs in the northern one-half of the Funeral Mountains indicate a long traveltime from the Amargosa region to the western margin of the northern and central parts of the mountains. The Grapevine Mountains include the highest elevations in the Amargosa Range. Substantial precipitation and recharge above about 2,000 meters are evinced by numerous small springs and seeps along the east and west margins. The local nature of the recharge is reflected in δ 2 H and δ 18 O values and in the spring chemistries that indicate control by Tertiary volcanic rocks. The highest spring discharges associated with the Grapevine Mountains are near the north end of the mountains in the Grapevine Ranch area. The springs in this area are similar chemically and isotopically, except for one or two order-of-magnitude differences in calcium, magnesium, and strontium concentrations and a 1.2 per mil difference in δ 13 C values. These differences can be attributed to differences in the distal parts of the respective flow paths. The springs also lie at the end of a northeast -oriented structural zone in the Walker Lane Belt, and their δ 2 H, δ 13 C, and δ 18 O values indicate a recharge area likely to the northeast, outside of the Grapevine Mountains.

California;Nevada↗
USGS1980

The effect of dissolution of volcanic glass on the water chemistry in a tuffaceous aquifer, Rainier Mesa, Nevada

Geochemistry of ground water associated with the Tertiary tuffs within Rainier Mesa, southern Nevada, was investigated to determine the relative importance of glass dissolution in controlling water chemistry. Water samples were obtained both from interstitial pores in core sections and from free-flowing fractures. Cation com- positions showed that calcium and magnesium decreased as a function of depth in the mesa, as sodium increased. The maximum effect occurs within alteration zones containing clinoptilolite and montmorillonite, suggesting these minerals effectively remove bivalent cations from the system. Comparisons are made between compositions of ground waters found within Rainier Mesa that apparently have not reacted with secondary minerals and compositions of waters produced by experimental dissolution of vitric and crystalline tufts which comprise the principal aquifers in the area. The two tuff phases have the same bulk chemistry but produce aqueous solutions of different chemistry. Rapid parabolic dissolution of sodium and silica from, and the retention of, potassium within the vitric phase verify previous predictions concerning water compositions associated with vitric volcanic rocks. Parabolic dissolution of the crystalline phase results in solutions high in calcium and magnesium and low in silica. Extrapolation of the parabolic dissolution mechanism for the vitric tuff to long times successfully reproduces, at com- parable pH, cation ratios existing in Rainier Mesa ground water. Comparison of mass- transfer rates of the vitric and crystalline tuffs indicates that the apparent higher glass-surface to aqueous-volume ratio associated with the vitric rocks may account for dominance of the glass reaction.

Water Supply Paper↗
USGS2021

Changes in soil chemistry and foliar metabolism of Himalayan cedar (Cedrus deodara) and Himalayan spruce (Picea smithiana) along an elevational gradient at Kufri, HP, India: The potential roles of regional pollution and localized grazing

We investigated changes in soil chemistry and foliar metabolism of Himalayan cedar [ Cedrus deodara (Roxb. Ex Lamb.) G.Don] and Himalayan spruce [ Picea smithiana (Wall.) Boiss] trees along a steep elevational gradient in the lower Himalayan Mountains at Kufri, Himachal Pradesh (HP), India. The foliar and soil samples were collected from four locations along a 300 m elevational gradient at ridge, high-, mid-, and low-elevation sites within the forested Shimla Water Catchment Wildlife Sanctuary that provides water for the city of Shimla, HP,. Observations at the time of sampling revealed that the high-elevation site was being heavily grazed. Soils collected at the four sites showed differences in soil chemistry along the gradient. Surface soils (top 10 cm) at the high-elevation site had the highest concentrations of carbon, nitrogen, calcium, magnesium, phosphorus, organic matter, and effective cation exchange capacity, possibly caused by grazing. Mineral soils were slightly acidic at all sites except the mid-elevation site, which was extremely acidic in the upper mineral soil. Similar to surface soil chemistry, foliar metabolism was also comparatively unique for high elevation. In Himalayan cedar foliage, higher concentrations of soluble proteins, polyamines, amino acids, and potassium were observed at the high-elevation site as compared to the ridge, mid and low elevations. No major differences were observed in the metabolic profiles of cedar between the ridge and low elevation ranges. Spruce foliage was sampled only from the ridge and low elevations and its metabolic profiles suggested healthier conditions at the low elevation. The results of the study demonstrate the impact of the interplay between local and regional drivers of forest health on cedar and spruce trees in a forested catchment that acts as a water source for downstream communities.

Himachal Pradesh, Himalayan Mountains, Kufri↗
USGS2010

Evaluation of a portable automated serum chemistry analyzer for field assessment of harlequin ducks, Histrionicus histrionicus

A portable analytical chemistry analyzer was used to make field assessments of wild harlequin ducks ( Histrionicus histrionicus ) in association with telemetry studies of winter survival in Prince William Sound, Alaska. We compared serum chemistry results obtained on-site with results from a traditional laboratory. Particular attention was paid to serum glucose and potassium concentrations as potential indicators of high-risk surgical candidates based on evaluation of the field data. The median differential for glucose values ( 𝑁 = 8 2 ) between methods was 0.6 mmol/L (quartiles 0.3 and 0.9 mmol/L) with the median value higher when assayed on site. Analysis of potassium on site returned a median of 2.7 mmol/L ( 𝑁 = 8 8 ; quartiles 2.4 and 3.0 mmol/L). Serum potassium values were too low for quantitation by the traditional laboratory. Changes in several serum chemistry values following a three-day storm during the study support the value of on site evaluation of serum potassium to identify presurgical patients with increased anesthetic risk.

Alaska↗
USGS2022

Multi-year, spatially extensive, watershed-scale synoptic stream chemistry and water quality conditions for six permafrost-underlain Arctic watersheds

Repeated sampling of spatially distributed river chemistry can be used to assess the location, scale, and persistence of carbon and nutrient contributions to watershed exports. Here, we provide a comprehensive set of water chemistry measurements and ecohydrological metrics describing the biogeochemical conditions of permafrost-affected Arctic watersheds. These data were collected in watershed-wide synoptic campaigns in six stream networks across northern Alaska. Three watersheds are associated with the Arctic Long-Term Ecological Research site at Toolik Field Station (TFS), which were sampled seasonally each June and August from 2016 to 2018. Three watersheds were associated with the National Park Service (NPS) of Alaska and the U.S. Geological Survey (USGS) and were sampled annually from 2015 to 2019. Extensive water chemistry characterization included carbon species, dissolved nutrients, and major ions. The objective of the sampling designs and data acquisition was to characterize terrestrial–aquatic linkages and processing of material in stream networks. The data allow estimation of novel ecohydrological metrics that describe the dominant location, scale, and overall persistence of ecosystem processes in continuous permafrost. These metrics are (1) subcatchment leverage, (2) variance collapse, and (3) spatial persistence. Raw data are available at the National Park Service Integrated Resource Management Applications portal (O'Donnell et al., 2021, https://doi.org/10.5066/P9SBK2DZ ) and within the Environmental Data Initiative (Abbott, 2021, https://doi.org/10.6073/pasta/258a44fb9055163dd4dd4371b9dce945 ).

Alaska↗
USGS2018

Chapter 5: Impact of sedimentary-exhalative hydrothermal systems on marine chemistry and mass extinctions: Applications for ore genesis research and mineral exploration

Times of metal-rich brine discharge into ancient ocean basins, associated with the formation of sedimentary-exhalative (sedex) Zn-Pb-Ba ore deposits, coincided with short-duration positive excursions (“spikes”) in the global marine Sr isotope record. While these spikes are unexplained by conventional oceanic models, chronostratigraphic correlations, combined with mass balance evidence and oceanographic modeling, suggest that the flux of radiogenic Sr from sedex brines during ore formation is sufficient to explain these previously enigmatic 87 Sr/ 86 Sr spikes. We review existing 87 Sr/ 86 Sr data and present new data as verification of these global 87 Sr/ 86 Sr spikes and their correlations with the formation of giant sedex ore deposits. Major events include an 1 ×10 −4 (~0.7078–~0.7079) excursion contemporaneous with formation of the Rammelsberg deposit at ~389 Ma; spikes on the order of 1 to 3 × 10 −4 , coeval with formation of the Meggen deposit at ~381 Ma, several ore deposits in the Macmillan Pass district at ~379 to 375 Ma, and the Silvermines deposits at ~352 Ma; and two >6 × 10 −4 spikes coincident with formation of the giant Navan deposit at ~346 Ma and Red Dog deposits at ~337 Ma. Moreover, the timing of peak 87 Sr/ 86 Sr spikes correlates with global δ 13 C and δ 18 O spikes, deposition of metal-rich black shales and ironstones, metal-induced malformation (teratology) of marine organisms, and mass extinctions. The relationships among these features were poorly understood, but our new model explains how the flux of key biolimiting nutrients and metals contained in sedex brines, demonstrably equivalent to or exceeding that of the total modern riverine flux to the ocean, spurred ocean eutrophication, which, ultimately, through a series of positive feedback mechanisms, may have triggered global chemical and biological events. If, as we hypothesize, sedex hydrothermal systems are recorded in the global marine isotopic, geologic, and biological records, our findings define a new approach to the study of and exploration for sedex deposits. We demonstrate that fluid inclusion solute chemistry and isotopic and stratigraphic studies of sedex deposits, coupled with chronostratigraphic correlation and high-resolution 87 Sr/ 86 Sr isotope chemostratigraphy, can be used to answer long-standing questions about geologic processes responsible for formation of these extraordinary deposits. This approach provides evidence for the age, duration, and fluxes of fluids and metals vented into the ocean by these giant hydrothermal systems. Accordingly, the marine 87 Sr/ 86 Sr curve constitutes a global exploration tool that could be applied to assess the mineral potential of sedimentary basins. To illustrate the potential of this tool to identify favorable stratigraphic ages and basins with potential for undiscovered giant sedex deposits, we highlight several spikes, on par with those characteristic of the Red Dog and Navan deposits, which have not been correlated with known metal deposits. Given these strong temporal correlations, mass balance estimates, and results of ocean chemistry modeling, our study suggests that further work is warranted to determine the extent to which periodic venting of hydrothermal basinal brines into the ocean has influenced the evolution of marine chemistry. Ultimately, these global signatures can be applied to the study of and exploration for sedex deposits.

Book chapter↗