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At least 109 records · Page 6Linked to original sources

Franciscan group in Coast Ranges and its equivalents in Sacramento Valley, California

The Franciscan group is an assemblage of detrital and chemical sedimentary and volcanic rocks that crops out discontinuously in a structurally complex, northwesterly trending belt along the Coast Ranges of Cahfornia. On the east, along the west side of the Sacramento Valley, a thick section of detrital sedimentary rocks has been subdivided into the Knoxville, Paskenta, and Horsetown forma tions of Late Jurassic and Early Cretaceous age, and several units of early Late Cretaceous age. The Sacramento Valley section represents deposition during most of the time from Late Jurassic to early Late Cretaceous. The Franciscan group is widely held to be restricted to Late Jurassic age, the Knoxville formation to be an upper shaly phase of the Franciscan group, and the two to be overlain unconformably by detrital strata of Cretaceous age. Sparse paleontologic evidence indicates this view to be incorrect. Rather, the Franciscan group seems mainly to have been deposited contemporaneously with the Knoxville, Paskenta, Horsetown, and lower Upper Cretaceous strata, as fossils ranging from Late Jurassic to early Late Cretaceous in age have been found in the Franciscan group. The Franciscan group and strata of the Sacramento Valley section therefore may represent two fades of the same stratigraphic section.

California↗

K-feldspar content of Jurassic and Cretaceous graywackes of northern Coast Ranges and Sacramento Valley, California

Graywackes of Late Jurassic to Late Cretaceous age are the predominant rocks in the northern Coast Ranges and the western Sacramento Valley provinces in California. These graywackes are similar in appearance, but their content of K-feldspar, which can be readily estimated after selective staining, differs widely. Study of several hundred specimens indicates that K-feldspar content is helpful in correlating or distinguishing these rocks, and sheds light on the geologic history of western California. In the Sacramento Valley a conformable sequence of Knoxville (Upper Jurassic), Shasta (Lower Cretaceous), and Upper Cretaceous rocks progressively increases in average K-feldspar content with decreasing age. Graywackes of the Franciscan formation, lying in the Coast Ranges farther west, generally contain no K-feldspar, although some contain a trace, and a few of more uncertain affiliation contain large amounts. Another belt of graywackes, west of the Franciscan formation and paralleling the Pacific shore, contains nearly as much K-feldspar as the Upper Cretaceous rocks of the Sacramento Valley, and most of these rocks are probably of middle Cretaceous age. The writers attribute the increase of K-feldspar with decreasing age of the rocks of the Sacramento Valley to changes in the source area, which is believed to be the Klamath Mountains and the Sierra Nevada. The changes include an increase in proportion of granitic rocks to others as the areas were stripped, and more abundant K-feldspar in the younger granitic rocks. The high K-feldspar content in the middle Cretaceous rocks of the coastal belt suggests that the rocks were deposited in the same basin as the Sacramento Valley rocks.

California↗

Occurrence and geochemistry of natural gases, Piceance Basin, northwest Colorado

The Piceance basin is a hydrocarbon-rich province that has natural gas production from reservoirs ranging in age from Late Jurassic to Eocene and large undeveloped resources of natural gas in coal beds and tight sandstone reservoirs of Cretaceous age. Gases from all producing intervals are of predominantly thermal origin and become isotopically heavier (delta isotope{13}C[1]: -51.3 to -29.1 o/oo) and chemically drier (C[1]/C[1-5]: 0.26 to 1.00) with increasing thermal maturity of reservoirs (R[o]: 0.45 to 2.40%) over a depth range of 1100 to 11,702 ft (335-3567 m). Scatter in trend is attributed to source rock differences and considerable vertical and lateral migration. Based on chemical and isotopic composition, three major types of gases can be distinguished: those generated from mixed type II and III kerogens, those from dispersed type III kerogen, and those from coal. Gases generated from mixed type II and III kerogens are produced from the Upper Jurassic Morrison Formation, the Lower Cretaceous Cedar Mountain Formation, the Upper Cretaceous Dakota Sandstone, the Upper Cretaceous Mancos "B" producing interval, and marginal marine sandstones of the Upper Cretaceous Iles producing interval. These gases are associated with minor amounts of oil and probably were generated from kerogen in the marine Mancos Shale. Gases generated from dispersed type III kerogen are produced from nonmarine sandstones of the Upper Cretaceous Williams Fork producing inter al and from thermally immature reservoirs in the overlying Paleocene and Eocene Fort Union and Wasatch Formations. These nonassociated gases contain large amounts of CO[2] and probably were generated from carbonaceous shales in the Williams Fork producing interval. Their presence in immature Fort Union and Wasatch reservoirs implies considerable vertical migration. The third type of gas is methane rich, is produced by devolatilization of humic coal, and is generally in coal beds of the Cameo-Fairfield zone of the Williams Fork producing interval. These gases are not the major source for adjacent sandstone reservoirs. A fourth, distinct type of isotopically light thermogenic gas occurs in immature reservoirs of the Eocene Green River Formation. This gas is inferred to have migrated from u identified deeper, more mature source rocks.

Colorado↗

Late Laramide thrust-related and evaporite-domed anticlines in the southern Piceance Basin, northeastern Colorado Plateau

New seismic and gravity data across the hydrocarbon-producing Divide Creek and Wolf Creek anticlines in the southern Piceance basin reveal contrasting styles of deformation within two widely separated time frames. Seismic data indicate that prebasin Paleozoic deformation resulted in block faulting of the Precambrian crystalline basement rocks and overlying Cambrian through Middle Pennsylvanian strata. Movement along these block faults throughout much of Pennsylvanian time, during northeast-southwest crustal extension, likely influenced distribution of the Middle Pennsylvanian (Desmoinesian) evaporite-rich facies. Younger rocks, including the thick succession of Cenozoic basin strata, then buried the Paleozoic structures. Tectonic reconfiguration of the basin's eastern margin occurred during late Laramide northeast-southwest compression, when a basement-involved thrust block, whose surface expression is the Grand Hogback monocline, moved into the Piceance basin. A decollement developed in front of the thrust block within the mechanically weak Desmoinesian evaporites and splayed out basinward as small-scale imbricate thrusts in the Upper Cretaceous Mancos Shale. The Divide Creek anticline formed above these splays as thrusting locally overthickened the shale and repeated the sandstone units between it and the evaporites. The Wolf Creek anticline to the east, however, is due to both depositional and tectonic thickening of the evaporite section along the decollement. Gravity data confirm that excess mater al of relatively low density exists beneath the Wolf Creek structure, whereas material of relatively higher density (overthickened shale) is found beneath the Divide Creek anticline. Thrust-related basin margins and intrabasin folds structurally analogous to the Divide Creek and Wolf Creek anticlines may be more common than presently recognized in the Rocky Mountain foreland. One well-documented example is the Pinedale anticline in the northern Green River basin, Wyoming, which, like the Divide Creek anticline, developed above a zone of splay faults from a decollement in front of a large thrust block.

Colorado↗

An analysis of a seismic reflection from the base of a gas hydrate zone, offshore Peru

Seismic reflection data recorded near ODP Site 688, offshore Peru, exhibit a persistent bottom-simulating reflector (BSR) from a depth corresponding to the theoretical base of the gas hydrate stability field. Although gas hydrate has been recovered in cores from scientific drilling in both the Pacific and the Atlantic, drilling in areas exhibiting a BSR has usually been avoided because of the perceived risk of releasing free gas trapped beneath the hydrated sediments. To carry out a quantitative analysis of the BSR, the seismic data were reprocessed using signature deconvolution and true amplitude recovery techniques. Synthetic seismograms that were created using acoustic parameters extracted from the seismic data and physical properties from Site 688 borehole measurement were compared to the observed seismic data to estimate the thickness of the free-gas zone. Results indicate the BSR is discontinuous laterally. Where the BSR is of high amplitude, free gas in a zone 5.5-17 m thick beneath the hydrated sediments provides the observed waveform; where the BSR amplitude is low, the free-gas zone is much thinner than 5.5 m or is entirely absent.

American Association of Petroleum Geologists Bulle↗

Molecular and isotopic gas composition of the Devonian Berea Sandstone and implications for gas evolution, eastern Kentucky

Since 2011, the Devonian Berea Sandstone in northeastern Kentucky has produced oil where thermal maturity studies indicate that likely source rocks, namely, the Devonian Ohio Shale and Mississippian Sunbury Shale, are thermally immature. Downdip, where source rocks are mature for oil, the Berea Sandstone and Ohio Shale primarily produce gas. To investigate this thermal maturity discordancy, the molecular and isotopic composition of gases from the Berea Sandstone (oil associated) and Ohio Shale (nonassociated) were analyzed to understand the gas generation and migration history. Collected along a northwest-southeast transect in eastern Kentucky, samples range from 1079 to 4602 ft, respectively. All are wet gases with a thermogenic origin (δ 13 C-CH 4 = −53.5‰ to −46.1‰). This is mostly consistent with a reevaluation of thermal maturity in a companion study that expands the area mature for oil. Gas migration is required, however, in updip parts of the Berea play where vitrinite reflectance ( VR o ) values are less than 0.6%. Southeast regional dip exerts a first-order influence on thermal maturity as gases become drier and isotopically heavier downdip. Correlation of δ 13 C values for heavier hydrocarbon gases in a natural gas plot with VR o contour spacing demonstrates the influence of nearby source rock thermal maturity on gas composition. Downdip, migration of oil and the attendant increase in permeability relative to gas may account for the dominance of gas production in the Ohio Shale. Migration along with basin uplift after the Alleghany orogeny may have contributed to development of a gas phase that exsolved from oil.

Kentucky↗

Source rock contributions to the Lower Cretaceous heavy oil accumulations in Alberta: a basin modeling study

The origin of the immense oil sand deposits in Lower Cretaceous reservoirs of the Western Canada sedimentary basin is still a matter of debate, specifically with respect to the original in-place volumes and contributing source rocks. In this study, the contributions from the main source rocks were addressed using a three-dimensional petroleum system model calibrated to well data. A sensitivity analysis of source rock definition was performed in the case of the two main contributors, which are the Lower Jurassic Gordondale Member of the Fernie Group and the Upper Devonian–Lower Mississippian Exshaw Formation. This sensitivity analysis included variations of assigned total organic carbon and hydrogen index for both source intervals, and in the case of the Exshaw Formation, variations of thickness in areas beneath the Rocky Mountains were also considered. All of the modeled source rocks reached the early or main oil generation stages by 60 Ma, before the onset of the Laramide orogeny. Reconstructed oil accumulations were initially modest because of limited trapping efficiency. This was improved by defining lateral stratigraphic seals within the carrier system. An additional sealing effect by biodegraded oil may have hindered the migration of petroleum in the northern areas, but not to the east of Athabasca. In the latter case, the main trapping controls are dominantly stratigraphic and structural. Our model, based on available data, identifies the Gordondale source rock as the contributor of more than 54% of the oil in the Athabasca and Peace River accumulations, followed by minor amounts from Exshaw (15%) and other Devonian to Lower Jurassic source rocks. The proposed strong contribution of petroleum from the Exshaw Formation source rock to the Athabasca oil sands is only reproduced by assuming 25 m (82 ft) of mature Exshaw in the kitchen areas, with original total organic carbon of 9% or more.

Alberta↗

Petroleum system analysis of the Hunton Group in West Edmond field, Oklahoma

West Edmond field, located in central Oklahoma, is one of the largest oil accumulations in the Silurian–Devonian Hunton Group in this part of the Anadarko Basin. Production from all stratigraphic units in the field exceeds 170 million barrels of oil (MMBO) and 400 billion cubic feet of gas (BCFG), of which approximately 60 MMBO and 100 BCFG have been produced from the Hunton Group. Oil and gas are stratigraphically trapped to the east against the Nemaha uplift, to the north by a regional wedge-out of Hunton strata, and by intraformational diagenetic traps. Hunton Group reservoirs are the Bois d'Arc and Frisco Limestones, with lesser production from the Chimneyhill subgroup, Haragan Shale, and Henryhouse Formation. Hunton Group cores from three wells that were examined petrographically indicate that complex diagenetic relations influence permeability and reservoir quality. Greatest porosity and permeability are associated with secondary dissolution in packstones and grainstones, forming hydrocarbon reservoirs. The overlying Devonian–Mississippian Woodford Shale is the major petroleum source rock for the Hunton Group in the field, based on one-dimensional and four-dimensional petroleum system models that were calibrated to well temperature and Woodford Shale vitrinite reflectance data. The source rock is marginally mature to mature for oil generation in the area of the West Edmond field, and migration of Woodford oil and gas from deeper parts of the basin also contributed to hydrocarbon accumulation.

Oklahoma↗

Pore-throat sizes in sandstones, siltstones, and shales: Reply

In his discussion of my article (Nelson, 2009), W. K. Camp takes issue with the concept that buoyancy is not the dominant force in forming and maintaining the distribution of gas in tight-gas accumulations (Camp, 2011). I will restrict my response to the issues he raised regarding buoyant versus nonbuoyant drive and to a few comments regarding water saturation and production. I claim that the pressure generated in petroleum source rocks (P g ), instead of the buoyancy pressure (P b ), provides the energy to charge most tight sandstones with gas. The arguments are fourfold: (1) buoyant columns of sufficient height seldom exist in low-permeability sand-shale sequences, (2) tight-gas systems display a pressure profile that declines instead of increases upward, (3) gas is pervasive in overpressured systems, and (4) source rocks can generate pore pressures sufficiently high to charge tight sandstones.

American Association of Petroleum Geologists Bulle↗

Black shale source rocks and oil generation in the Cambrian and Ordovician of the central Appalachian Basin, USA

Nearly 600 million bbl of oil (MMBO) and 1 to 1.5 trillion ft 3 (tcf) of gas have been produced from Cambrian and Ordovician reservoirs (carbonate and sandstone) in the Ohio part of the Appalachian basin and on adjoining arches in Ohio, Indiana, and Ontario, Canada. Most of the oil and gas is concentrated in the giant Lima-Indiana field on the Findlay and Kankakee arches and in small fields distributed along the Knox unconformity. Based on new geochemical analyses of oils, potential source rocks, bitumen extracts, and previously published geochemical data, we conclude that the oils in both groups of fields originated from Middle and Upper Ordovician black shale (Utica and Antes shales) in the Appalachian basin. Moreover, we suggest that approximately 300 MMBO and many trillions of cubic feet of gas in the Lower Silurian Clinton sands of eastern Ohio originated in these same source rocks. Oils from the Cambrian and Ordovician reservoirs have similar saturated hydrocarbon compositions, biomarker distributions, and carbon isotope signatures. Regional variations in the oils are attributed to differences in thermal maturation rather than to differences in source. Total organic carbon content, genetic potential, regional extent, and bitumen extract geochemistry identify the black shale of the Utica and Antes shales as the most plausible source of the oils. Other Cambrian and Ordovician shale and carbonate units, such as the Wells Creek formation, which rests on the Knox unconformity, and the Rome Formation and Conasauga Group in the Rome trough, are considered to be only local petroleum sources. T max , CAI, and pyrolysis yields from drill-hole cuttings and core indicate that the Utica Shale in eastern and central Ohio is mature with respect to oil generation. Burial, thermal, and hydrocarbon-generation history models suggest that much of the oil was generated from the Utica-Antes source in the late Paleozoic during the Alleghanian orogeny. A pervasive fracture network controlled by basement tectonics aided in the distribution of oil from the source to the trap. This fracture network permitted oil to move laterally and stratigraphically downsection through eastward-dipping, impermeable carbonate sequences to carrier zones such as the Middle Ordovician Knox unconformity, and to reservoirs such as porous dolomite in the Middle Ordovician Trenton Limestone in the Lima-Indiana field. Some of the oil and gas from the Utica-Antes source escaped vertically through a partially fractured, leaky Upper Ordovician shale seal into widespread Lower Silurian sandstone reservoirs.

Ohio, Ontario↗

Radiogenic heat production in sedimentary rocks of the Gulf of Mexico basin, south Texas

Radiogenic heat production within the sedimentary section of the Gulf of Mexico basin is a significant source of heat. Radiogenic heat should be included in thermal models of this basin (and perhaps other sedimentary basins). We calculate that radiogenic heat may contribute up to 26% of the overall surface heat-flow density for an area in south Texas. Based on measurements of the radioactive decay rate of a-particles, potassium concentration, and bulk density, we calculate radiogenic heat production for Stuart City (Lower Cretaceous) limestones, Wilcox (Eocene) sandstones and mudrocks, and Frio (Oligocene) sandstones and mudrocks from south Texas. Heat production rates range from a low of 0.07 ±0.01 µW/m 3 in clean Stuart City limestones to 2.21 ±0.24 µW/m 3 in Frio mudrocks. Mean heat production rates for Wilcox sandstones, Frio sandstones, Wilcox mudrocks, and Frio mudrocks are 0.88, 1.19, 1.50, and 1.72 µW/m3, respectively. In general, the mudrocks produce about 30-40% more heat than stratigraphically equivalent sandstones. Frio rocks produce about 15% more heat than Wilcox rocks per unit volume of clastic rock (sandstone/mudrock). A one-dimensional heat- conduction model indicates that this radiogenic heat source has a significant effect on subsurface temperatures. If a thermal model were calibrated to observed temperatures by optimizing basal heat-flow density and ignoring sediment heat production, the extrapolated present-day temperature of a deeply buried source rock would be overestimated.

American Association of Petroleum Geologists Bulle↗

Porosity evolution of upper Miocene reefs, Almeria Province, southern Spain

Sea cliffs 40 km east of Almeria, southeastern Spain, expose upper Miocene reefs and patch reefs of the Plomo formation. These reefs are formed of scleractinian corals, calcareous algae, and mollusks. The reef cores are as much as 65 m thick and several hundred meters wide. Fore-reef talus beds extend 1,300 m across and are 40 m thick. The reefs and reef breccias are composed of calcitic dolomite. They lie on volcanic rocks that have a K-Ar date of 11.5 m.y. and in turn are overlain by the upper Miocene Vicar Formation. In the reef cores and fore-reef breccia beds, porosity is both primary and postdepositional. Primary porosity is of three types: (a) boring clam holes in the scleractinian coral heads, cemented reef rocks, and breccias; (b) intraparticle porosity within the corals, Halimeda plates, and vermetid worm tubes; and (c) interparticle porosity between bioclastic fragments and in the reef breccia. Postdepositional moldic porosity was formed by the solution of aragonitic material such as molluscan and coral fragments. The Plomo reef carbonate rocks have high porosity and permeability, and retain a great amount of depositional porosity. Pores range in size from a few micrometers to 30 cm. The extensive intercrystalline porosity and high permeability resulted from dolomitization of micritic matrix. Dolomite rhombs are between 10 and 30 µ across. More moldic porosity was formed by the dissolution of the calcite bioclasts. Some porosity reduction has occurred by incomplete and partial sparry calcite infilling of interparticular, moldic, and intercrystalline voids. The high porosity and permeability of these reefs make them important targets for petroleum exploration in the western Mediterranean off southern Spain. In these offshore areas in the subsurface the volcanic ridge and the Plomo reef complex are locally onlapped or overlapped by 350 m or more of Miocene(?) and Pliocene fine-grained sedimentary rocks. The possibility exists that the buried Plomo reef deposits may form traps for oil and gas in the offshore areas southwest of the type locality. Stratigraphic traps also may occur where the Neogene sequence above the Plomo reef complex onlaps the volcanic ridge.

Almeria Province↗

Organic composition of some Upper Cretaceous shale, Powder River Basin, Wyoming

The lower Upper Cretaceous strata in northeastern Wyoming, which have yielded major quantities of oil and gas, were sampled at boreholes in Converse, Johnson, and Weston Counties. Cores of noncalcareous shale of largely nearshore-marine origin were obtained from the Frontier Formation and the overlying Cody Shale at depths of 3,780.6 to 3,879.9 m in Converse County, near the axis of the Powder River basin, and at depths of less than 320 m in Johnson County, on the western flank of the basin. Cores of calcareous and noncalcareous shale representing offshore-marine and nearshore-marine environments were acquired from the Belle Fourche Shale, Greenhorn Formation, and Carlile Shale at depths of less than 270 m in Weston County, on the eastern flank of the Powder River basin. Analyses of the shale for organic carbon content, total pyrolytic hydrocarbon yield, volatile hydrocarbon content, temperature of maximum pyrolytic yield, and vitrinite reflectance indicate that the amount and character of the organic matter in the sampled rocks is related to the content of calcium carbonate, the depositional environment, and the burial depth of the strata. On the east flank of the Powder River basin, calcareous shale of offshore-marine origin contains abundant hydrogen-rich organic matter derived mainly from aquatic plants. Noncalcareous shale of largely nearshore-marine origin, on the west flank of the basin, locally contains significant hydrogen-poor organic matter derived mostly from land plants. The noncalcareous, nearshore-marine shale in the middle of the basin probably contained similar amounts of hydrogendeficient organic matter prior to deep burial and thermal alteration. The calcareous shale in Weston County is a potentially rich source of oil and gas, but it is thermally immature and is in a very early stage of the hydrocarbon-generation process. The noncalcareous shale in Johnson County is a potential source rock for gas, but also is in an early stage of thermal alteration. In Converse County, the sampled beds are thermally mature and have generated hydrocarbons. The extent of this contribution of hydrocarbons to the commercial petroleum occurrences of the area can be inferred from the composition of the original organic matter in the beds. Furthermore, the degree of thermal alteration of the organic matter at these localities indicates that the depth of the sampled strata was never as great on the flanks of the Powder River basin as in the basin center.

Wyoming↗

Shallow, low-permeability reservoirs of northern Great Plains: Assessment of their natural gas resources.

Major resources of natural gas are entrapped in low-permeability, low-pressure reservoirs at depths less than 4,000 ft (1,200 m) in the northern Great Plains. This shallow gas is the product of the immature stage of hydrocarbon generation and is referred to as biogenic gas. Prospective low-permeability, gas-bearing reservoirs range in age from late Early to Late Cretaceous and include most of the section from the base of the Mowry Shale to the top of the Judith River Formation. For detailed examination, the potential reservoir section was divided into five intervals represented by one or more formations and their correlatives. The intervals selected correspond to (1) Mowry Shale, (2) Belle Fourche Shale and Greenhorn Formation, (3) Carlile Shale, (4) Niobrara and Telegrap Creek Formations and Eagle Sandstone, and (5) Claggett Shale and Judith River Formation and their equivalents. Within each interval, several different facies are developed. The following facies were identified and mapped for each interval: nonmarine rocks, coastal sandstones, shelf sandstones, siltstones, shales, and chalks. Two types of shelf sandstone were differentiated but generally not mapped separately because of lack of well log control. The "sand ridge" type has reservoir properties comparable to coastal sandstones and occurs as isolated tongues as much as 75 ft (23 m) thick. The second type of shelf sandstone is in beds commonly less than 1 in. (3 cm) thick which are interbedded with shale and contain a high content of allogenic silt- and clay-size material. It is impossible to differentiate these individual beds on conventional well logs. The siltstone and shale facies are grouped to ether because conventional logs cannot distinguish between these two rock types, particularly when they are interbedded. For future evaluation of natural gas resources from low-permeability reservoirs, it will be necessary to differentiate between the siltstone and shale facies and to identify individual beds, particularly very thin ones, within the shelf sandstone facies. Each facies contains distinct reservoir types, some of which are low in permeability. The most promising low-permeability reservoirs are developed in the shelf sandstone, siltstone, and chalk facies. Reservoirs within these facies are particularly attractive because they are enveloped by thick sequences of shale which serve as both a source and a seal for the gas. When naturally fractured, these shales also may be low-productivity gas reservoirs similar to the Devonian shales of the Appalachian basin. In addition, facies with low-permeability reservoirs are present over most of the study area when maps for all of the intervals are combined. Natural gas is produced from low-permeability reservoirs in the northern Great Plains in the southern part of western Canada. Established production covers an area of approximately 8,000 sq mi (20,700 sq km) where reported recoverable reserves average as much as 2 Bcf sq mi. Using these reserve data as an analog, the United States portion may contain resources of natural gas in excess of 100 Tcf. The volume of recoverable gas in the United States will depend on the development of improved recovery technology and higher gas prices relative to costs.

northern Great Plains↗

Origin of gasoline-range hydrocarbons and their migration by solution in carbon dioxide in Norton basin, Alaska.

Carbon dioxide from a submarine seep in Norton Sound, Alaska, carries a minor component of gas- and gasoline-range hydrocarbons. The molecular and isotopic compositions of the hydrocarbon gases and the presence of gasoline-range hydrocarbons indicate that these molecules are derived from thermal alteration of marine and/or nonmarine organic matter buried within Norton basin. In the gasoline-range hydrocarbons, individual cyclic and branched-chain molecules are much more abundant than straight-chain hydrocarbons. This distribution suggests that the hydrocarbon mixture is an immature, petroleumlike condensate of lower temperature origin than normal crude oil. The submarine seep provides a natural example in support of a carbon dioxide solution transport mechanism thought to be operative in the migration of hydrocarbons in certain reservoirs.

Alaska↗

Organic content of Devonian shale in western Appalachian basin

In the organic-rich facies of the Devonian shale in the western part of the Appalachian basin, the distribution of organic matter provides an indirect measure of both gas in place and the capacity of the shale to supply gas to permeable pathways.The boundary between organic-rich ('black') and organic-poor ('gray') facies is defined here as 2% organic content by volume. The thickness of organic-rich facies ranges from 200ft in central Kentucky to 1000ft along the Kentucky-West Virginia border. The average content of the organic-rich facies increases from 5% by volume on the edge to 16% in central Kentucky. The net thickness of organic matter in the organic-rich facies shows the amount of organic material in the shale, and is the most fundamental of the organic-content characterizations. Net thickness of organic matter ranges between 20 and 80ft (6.1 and 24.4m) within the mapped area.-from Author

kentucky, New York, Ohio, Pennsylvania, Virginia, ↗

Northwest margin of California continental borderland: Marine geology and tectonic evolution

The northwest margin of the California continental borderland consists mainly of two northwest-trending pre-Neogene lithologic belts blanketed by Miocene and younger strata. These belts, which are lithologically and structurally correlated with the Franciscan Complex and Great Valley sequence of northern California, are interpreted to represent facies corresponding to the subduction complex and forearc-basin deposits of a late Mesozoic and Paleogene continental-margin arc-trench system. The outer belt, which forms the acoustic basement underlying the continental slope and Patton Ridge, is characterized by: (1) moderately high compressional velocities (5.1 to 6.2 km/sec), (2) discordant and discontinuous seismic reflectors, and (3) nonfossiliferous and diverse rock types t at range in metamorphic grade from zeolite-bearing arkosic sandstone to blueschist. Landward, the inner Great Valley sequence belt underlies Santa Rosa-Cortes Ridge and Santa Cruz and San Nicolas Basins; in contrast to the outer belt, this belt is characterized by: (1) intermediate compressional velocities (4.5 to 4.6 km/sec), (2) concordant and relatively continuous reflectors, and (3) a thick turbidite sequence of relatively undeformed and unmetamorphosed fossiliferous Cretaceous and Paleogene strata. The inner belt overlies a 6.6-km/sec layer that is probably oceanic crust, a relation consistent with the hypothesis that trapped old oceanic crust underlies the forearc basins along parts of some convergent margins. Well-developed wrench-fault structures in overlying Miocene strata record a transition from Paleogene subduction to Neogene transform faulting. Related events include widespread andesitic to dacitic volcanism and concurrent uplift and erosion of Miocene and older rocks. The proximity of these Miocene silicic volcanic rocks to the paleotrench (< 20 km) is best explained as resulting from passage of the southward-migrating Rivera ridge-fault-trench triple junction along the margin. On the basis of the age of the adjacent sea floor, passage of this triple junction occurred about 17 m.y. ago, a date that corresponds closely to the inception of volcanism and uplift in the northwest margin of the borderland. A widespread unconformity that separates highly deformed lower and lower middle iocene strata from relatively undeformed younger strata is assumed to mark the subsequent onset of wrench faulting. The timing of volcanism and uplift, and of the slightly younger wrenching event, closely matches the plate-tectonic model of Atwater and Molnar if the northwest margin of the borderland is restored to an earlier tectonic setting off Baja California, approximately 260 km southeast of its present position.

California↗