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Investigating permafrost carbon dynamics in Alaska with artificial intelligence

Positive feedbacks between permafrost degradation and the release of soil carbon into the atmosphere impact land–atmosphere interactions, disrupt the global carbon cycle, and accelerate climate change. The widespread distribution of thawing permafrost is causing a cascade of geophysical and biochemical disturbances with global impacts. Currently, few earth system models account for permafrost carbon feedback (PCF) mechanisms. This research study integrates artificial intelligence (AI) tools and information derived from field-scale surveys across the tundra and boreal landscapes in Alaska. We identify and interpret the permafrost carbon cycling links and feedback sensitivities with GeoCryoAI, a hybridized multimodal deep learning (DL) architecture of stacked convolutionally layered, memory-encoded recurrent neural networks (NN). This framework integrates in-situ measurements and flux tower observations for teacher forcing and model training. Preliminary experiments to quantify, validate, and forecast permafrost degradation and carbon efflux across Alaska demonstrate the fidelity of this data-driven architecture. More specifically, GeoCryoAI logs the ecological memory and effectively learns covariate dynamics while demonstrating an aptitude to simulate and forecast PCF dynamics—active layer thickness (ALT), carbon dioxide flux (CO 2 ), and methane flux (CH 4 )—with high precision and minimal loss (i.e. ALT RMSE : 1.327 cm [1969–2022]; CO 2 RMSE : 0.697 µ molCO 2 m −2 s −1 [2003–2021]; CH 4 RMSE : 0.715 nmolCH 4 m −2 s −1 [2011–2022]). ALT variability is a sensitive harbinger of change, a unique signal characterizing the PCF, and our model is the first characterization of these dynamics across space and time.

Alaska↗

Contributions to economic geology, 1918, Part I, Metals and nonmetals except fuel

The Survey's "Contributions to economic geology " have been published annually since 1902. In 1906 the increase in the number of papers coming under this (Classification made it necessary to divide the contributions into two parts, one including, papers on metals and nonmetals except fuels and the other including papers on mineral fuels. In 1915 the year included in the title was changed from the year in which the field work reported in these papers was done to the year of publication, and in consequence there was no volume entitled "Contributions to economic geology, 1914.” The subjoined table gives a summary of these bulletins. As the subtitle indicates, the papers included in these volumes are of two classes (1) short papers giving comparatively detailed descriptions of occurrences that have economic interest but are not of sufficient importance to warrant a more extended description; (2) preliminary reports on economic investigations the results of which are to be published later in more detailed form. These papers are such only as Have a direct economic bearing, all topics of purely scientific interest being excluded. Brief abstracts of the publications of the year are given in the annual report of the Director. The complete list of Survey publications affords, by means of finding lists of subjects and of authors, further aid in ascertaining the extent of the Survey's work in economic geology. The reports on work in Alaska have been printed in a separate series since 1904, the volumes so far issued being Bulletins 259, 284, 314, 345, 379, 442, 480, 520, 542, 592, 622, 642, and 662.

Bulletin↗

Bacterial and enchytraeid abundance accelerate soil carbon turnover along a lowland vegetation gradient in interior Alaska

Boreal wetlands are characterized by a mosaic of plant communities, including forests, shrublands, grasslands, and fens, which are structured largely by changes in topography and water table position. The soil associated with these plant communities contain quantitatively and qualitatively different forms of soil organic matter (SOM) and nutrient availability that drive changes in biogeochemical cycling rates. Therefore different boreal plant communities likely contain different soil biotic communities which in turn affect rates of organic matter decomposition. We examined relationships between plant communities, microbial communities, enchytraeids, and soil C turnover in near-surface soils along a shallow topographic soil moisture and vegetation gradient in interior Alaska. We tested the hypothesis that as soil moisture increases along the gradient, surface soils would become increasingly dominated by bacteria and mesofauna and have more rapid rates of C turnover. We utilized bomb radiocarbon techniques to infer rates of C turnover and the 13C isotopic composition of SOM and respired CO 2 to infer the degree of soil humification. Soil phenol oxidase and peroxidase enzyme activities were generally higher in the rich fen compared with the forest and bog birch sites. Results indicated greater C fluxes and more rapid C turnover in the surface soils of the fen sites compared to the wetland forest and shrub sites. Quantitative PCR analyses of soil bacteria and archaea, combined with enchytraeid counts, indicated that surface soils from the lowland fen ecosystems had higher abundances of these microbial and mesofaunal groups. Fungal abundance was highly variable and not significantly different among sites. Microbial data was utilized in a food web model that confirmed that rapidly cycling systems are dominated by bacterial activity and enchytraeid grazing. However, our results also suggest that oxidative enzymes play an important role in the C mineralization process in saturated systems, which has been often ignored.

Soil Biology and Biochemistry↗

Geochronology of augen gneiss and related rocks, Yukon-Tanana terrane, east-central Alaska

Using several isotopic techniques, we have determined the ages of selected metamorphic rocks in the Yukon-Tanana terrane (YTT) of east-central Alaska. U-Pb zircon data from an augen gneiss body in the Big Delta quadrangle indicate that the granitoid protolith of the gneiss was intruded 341 ± 3 m.y. ago (lower intercept age). An upper intercept age of 2,136 ± 31 m.y. indicates an inherited early Proterozoic component in these zircons. This inheritance age is substantiated by a Sm-Nd whole-rock model age of 2.09 ± 0.08 b.y. from the Big Delta augen gneiss body. Detrital zircons from quartzitic wall rocks to this body were also derived from an early Proterozoic (∼2.1 to 2.3 b.y. old) crustal source(s). Zircons from three other augen gneisses occurring in an east-west belt which extends into the southern Yukon Territory, Canada, have similar Mississippian and early Proterozoic intercept ages. A Rb-Sr whole-rock isochron from widely separated bodies of augen gneiss has an age of 333 ± 26 m.y. and an initial 87 Sr/ 86 Sr ratio of 0.728 ± 0.002, confirming the Mississippian intrusive age for the protolith. The high initial 87 Sr/ 86 Sr ratio further indicates an old crustal component in these rocks. A Rb-Sr mineral isochron (115 ± 4 m.y.), K-Ar data from hornblende and micas (128 to 107 m.y.), and U-Pb data from sphene (134. m.y.) from augen gneiss and related rocks are similar to many K-Ar ages in this region and confirm the occurrence of an early Cretaceous thermal event. U-Pb ages of zircons from three metavolcanic units in the YTT suggest that extrusion of the protoliths of these rocks occurred 360–380 m.y. ago. Scatter in the data is caused by ubiquitous inheritance and multiple lead-loss events.

Alaska↗

Preliminary integrated geologic map databases for the United States: Alabama, Florida, Georgia, Mississippi, North Carolina, and South Carolina

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national digital geologic maps attributed with age and lithology information. Such maps can be conveniently used to generate derivative maps for purposes including mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This Open-File Report is a preliminary version of part of a series of integrated state geologic map databases that cover the entire United States. The only national-scale digital geologic maps that portray most or all of the United States for the conterminous U.S. are the digital version of the King and Beikman (1974a, b) map at a scale of 1:2,500,000, as digitized by Schruben and others (1994) and the digital version of the Geologic Map of North America (Reed and others, 2005a, b) compiled at a scale of 1:5,000,000 which is currently being prepared by the U.S. Geological Survey. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis of this product. In a few cases, new digital compilations were prepared (e.g. OH, SC, SD) or existing paper maps were digitized (e.g. KY, TX). For Alaska and Hawaii, new regional maps are being compiled and ultimately new state maps will be produced. The digital geologic maps are presented in standardized formats as ARC/INFO (.e00) export files and as ArcView shape (.shp) files. Accompanying these spatial databases are a set of five supplemental data tables that relate the map units to detailed lithologic and age information. The maps for the CONUS have been fitted to a common set of state boundaries based on the 1:100,000 topographic map series of the United States Geological Survey (USGS). When the individual state maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps. No attempt has been made to reconcile differences in mapped geology across state lines.

Alabama, Florida, Georgia, Mississippi, North Caro↗

Preliminary integrated geologic map databases for the United States: Central states: Montana, Wyoming, Colorado, New Mexico, North Dakota, South Dakota, Nebraska, Kansas, Oklahoma, Texas, Iowa, Missouri, Arkansas, and Louisiana

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national digital geologic maps attributed with age and lithology information. Such maps can be conveniently used to generate derivative maps for purposes including mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This Open-File Report is a preliminary version of part of a series of integrated state geologic map databases that cover the entire United States. The only national-scale digital geologic maps that portray most or all of the United States for the conterminous U.S. are the digital version of the King and Beikman (1974a, b) map at a scale of 1:2,500,000, as digitized by Schruben and others (1994) and the digital version of the Geologic Map of North America (Reed and others, 2005a, b) compiled at a scale of 1:5,000,000 which is currently being prepared by the U.S. Geological Survey. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis of this product. In a few cases, new digital compilations were prepared (e.g. OH, SC, SD) or existing paper maps were digitized (e.g. KY, TX). For Alaska and Hawaii, new regional maps are being compiled and ultimately new state maps will be produced. The digital geologic maps are presented in standardized formats as ARC/INFO (.e00) export files and as ArcView shape (.shp) files. Accompanying these spatial databases are a set of five supplemental data tables that relate the map units to detailed lithologic and age information. The maps for the CONUS have been fitted to a common set of state boundaries based on the 1:100,000 topographic map series of the United States Geological Survey (USGS). When the individual state maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps. No attempt has been made to reconcile differences in mapped geology across state lines. This is the first version of this product and it will be subsequently updated to include four additional states (North Dakota, South Dakota, Nebraska, and Iowa)

Arkansas, Colorado, Iowa, Kansas, Louisiana, Misso↗

Preliminary integrated geologic map databases for the United States: Minnesota, Wisconsin, Michigan, Illinois, and Indiana

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national digital geologic maps attributed with age and lithology information. Such maps can be conveniently used to generate derivative maps for purposes including mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This Open-File Report is a preliminary version of part of a series of integrated state geologic map databases that cover the entire United States. The only national-scale digital geologic maps that portray most or all of the United States for the conterminous U.S. are the digital version of the King and Beikman (1974a, b) map at a scale of 1:2,500,000, as digitized by Schruben and others (1994) and the generalized digital version (Reed and Bush, 2004) of the Geologic Map of North America (Reed and others, 2005a, b) compiled at a scale of 1:5,000,000. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis for this product. In a few cases, new digital compilations were prepared (e.g. Ohio, South Carolina, South Dakota) or existing paper maps were digitized (e.g. Kentucky, Texas). Also as part of this series, new regional maps for Alaska and Hawaii are being compiled and ultimately new state maps will be produced. The digital geologic maps are presented in standardized formats as ARC/INFO export (.e00) files and as ArcView shape (.shp) files. Accompanying these spatial databases are a set of five supplemental attribute tables that relate the map units to detailed lithologic and age information. The maps for the CONUS have been fitted to a common set of state boundaries based on the 1:100,000 topographic map series of the United States Geological Survey (USGS). When the individual state maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps. No attempt has been made to reconcile differences in mapped geology across state lines.

Illinois, Indiana, Michigan, Minnesota, Wisconsin↗

Preliminary integrated geologic map databases for the United States: Kentucky, Ohio, Tennessee, and West Virginia

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national digital geologic maps attributed with age and lithology information. Such maps can be conveniently used to generate derivative maps for purposes including mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This Open-File Report is a preliminary version of part of a series of integrated state geologic map databases that cover the entire United States. The only national-scale digital geologic maps that portray most or all of the United States for the conterminous U.S. are the digital version of the King and Beikman (1974a, b) map at a scale of 1:2,500,000, as digitized by Schruben and others (1994) and the generalized digital version (Reed and Bush, 2004) of the Geologic Map of North America (Reed and others, 2005a, b) compiled at a scale of 1:5,000,000. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis for this product. In a few cases, new digital compilations were prepared (e.g. Ohio, South Carloina, South Dakota) or existing paper maps were digitized (e.g. Kentucky, Texas). Also as part of this series, new regional maps for Alaska and Hawaii are being compiled and ultimately new state maps will be produced. The digital geologic maps are presented in standardized formats as ARC/INFO export (.e00) files and as ArcView shape (.shp) files. Accompanying these spatial databases are a set of five supplemental attribute tables that relate the map units to detailed lithologic and age information. The maps for the CONUS have been fitted to a common set of state boundaries based on the 1:100,000 topographic map series of the United States Geological Survey (USGS). When the individual state maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps. No attempt has been made to reconcile differences in mapped geology across state lines.

Kentucky, Ohio, Tennessee, West Virginia↗

Preliminary integrated geologic map databases for the United States: Delaware, Maryland, New York, Pennsylvania, and Virginia

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national digital geologic maps attributed with age and lithology information. Such maps can be conveniently used to generate derivative maps for purposes including mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This Open-File Report is a preliminary version of part of a series of integrated state geologic map databases that cover the entire United States. The only national-scale digital geologic maps that portray most or all of the United States for the conterminous U.S. are the digital version of the King and Beikman (1974a, b) map at a scale of 1:2,500,000, as digitized by Schruben and others (1994) and the generalized digital version (Reed and Bush, 2004) of the Geologic Map of North America (Reed and others, 2005a, b) compiled at a scale of 1:5,000,000. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis for this product. In a few cases, new digital compilations were prepared (e.g. Ohio, South Carloina, South Dakota) or existing paper maps were digitized (e.g. Kentucky, Texas). Also as part of this series, new regional maps for Alaska and Hawaii are being compiled and ultimately new state maps will be produced. The digital geologic maps are presented in standardized formats as ARC/INFO export (.e00) files and as ArcView shape (.shp) files. Accompanying these spatial databases are a set of five supplemental attribute tables that relate the map units to detailed lithologic and age information. The maps for the CONUS have been fitted to a common set of state boundaries based on the 1:100,000 topographic map series of the United States Geological Survey (USGS). When the individual state maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps. No attempt has been made to reconcile differences in mapped geology across state lines.

Delaware, Maryland, New York, Pennsylvania, Virgin↗

Reconnaissance for uranium and thorium in Alaska, 1954

During 1954 reconnaissance investigations to locate minable deposits of uranium and thorium in Alaska were unsuccessful. Areas examined, from which prospectors had submitted radioactive samples, include Cap Yakataga, Kodiak Island, and Shirley Lake. Unconcentrated gravels from the beach at Cape Yakataga average about 0.001 percent equivalent uranium. Uranothorianite has been identified by X-ray diffraction data and is the principal source of radioactivity in the Cape Yakataga beach sands studied; but the zircon, monazite, and uranothorite are also radioactive. The black, opaque uranothorianite generally occurs as minute euhedral cubs, the majority of which will pass through a 100-mesh screen. The bedrock source of the radioactive samples from Kodiak Island was not found; the maximum radioactivity of samples from the Shirley Lake area was equivalent to about 0.02 percent uranium. Radiometric traverses of the 460-foot level of the Garnet shaft of the Nixon Fork mine in the Nixon Fork mining district indicated a maximum of 0.15 mr/hr. In the Hot Springs district, drill hole concentrates of gravels examined contained a maximum of 0.03 percent equivalent uranium. A radioactivity anomaly noted during the Survey's airborne reconnaissance of portions of the Territory during 1954 is located in the Fairhaven district. A ground check disclosed that the radioactivity was due to accessory minerals in the granitic rock.

Alaska↗

Porphyry deposits of the Canadian Cordillera

Porphyry deposits are intrusion-related, large tonnage low grade mineral deposits with metal assemblages that may include all or some of copper, molybdenum, gold and silver. The genesis of these deposits is related to the emplacement of intermediate to felsic, hypabyssal, generally porphyritic intrusions that are commonly formed at convergent plate margins. Porphyry deposits of the Canadian Cordillera occur in association with two distinctive intrusive suites: calc-alkalic and alkalic. In the Canadian Cordillera, these deposits formed during two separate time periods: Late Triassic to Middle Jurassic (early Mesozoic), and Late Cretaceous to Eocene (Mesozoic-Cenozoic). Deposits of the early Mesozoic period occur in at least three different arc terranes (Wrangellia, Stikinia and Quesnellia) with a single deposit occurring in the oceanic assemblage of the Cache Creek terrane. These terranes were located outboard from continental North America during formation of most of their contained early Mesozoic porphyry deposits. Some of the deposits of this early period may have been emplaced during terrane collisions. Metal assemblages in deposits of the calc-alkalic suite include Mo-Cu (Brenda), Cu-Mo (Highland Valley, Gibraltar), Cu-Mo-Au-Ag (Island Copper, Schaft Creek) and Cu-Au (Kemess, Kerr).The alkalic suite deposits are characterized by a Cu-Au assemblage (Copper Mountain, Afton-Ajax, Mt. Milligan, Mount Polley, Galore Creek). Although silver is recovered from calc-alkalic and alkalic porphyry copper mining operations, silver data are seldom included in the published reserve figures. Those available are in the range of 1-2 grams per tonne (g??t-1). Alkalic suite deposits are restricted to the early Mesozoic and display distinctive petrology, alteration and mineralization that suggest a similar tectonic setting for both Quesnellia and Stikinia in Early Jurassic time. The younger deposits, late Mesozoic to Cenozoic in age, formed in an intracontinental setting, after the outboard host arc and related terranes accreted to the western margin of North America. These deposits are interpreted to occur in continental arc settings, and individual deposits are hosted by a variety of older country rocks. These younger deposits also show a spectrum of metal associations: Cu-Mo (Huckleberry, Berg), Cu-Au (-Mo) (Bell, Granisle, Fish Lake, Casino), Mo (Endako, Boss Mountain, Kit-sault, Quartz Hill), Mo-W (Logtung), Au-W (Dublin Gulch) and Au (Ft. Knox). There may be a continuum between Mo, Mo-W, Au-Mo-W and Au deposits. The distribution and timing of these post-accretion deposits likely reflect major crustal structures and subduction geometry. Cordilleran porphyry metallic deposits show the full range of morphological and depth relationships found in porphyry deposits worldwide. In addition, the Cordillera contains numerous alkalic suite deposits, which are rare worldwide: the unusual, possibly syntectonic Gibraltar deposit; and end-member gold-rich granite-hosted deposits, such as Ft. Knox (Alaska).

Geoscience Canada↗

Great Basin Paleontological Bibliography

Introduction This work was conceived as a derivative product for 'The Metallogeny of the Great Basin' project of the Mineral Resources Program of the U.S. Geological Survey. In the course of preparing a fossil database for the Great Basin that could be accessed from the Internet, it was determined that a comprehensive paleontological bibliography must first be compiled, something that had not previously been done. This bibliography includes published papers and abstracts as well as unpublished theses and dissertations on fossils and stratigraphy in Nevada and adjoining portions of California and Utah. This bibliography is broken into first-order headings by geologic age, secondary headings by taxonomic group, followed by ancillary topics of interest to both paleontologists and stratigraphers; paleoecology, stratigraphy, sedimentary petrology, paleogeography, tectonics, and petroleum potential. References were derived from usage of Georef, consultation with numerous paleontologists and geologists working in the Great Basin, and literature currently on hand with the authors. As this is a Web-accessible bibliography, we hope to periodically update it with new citations or older references that we have missed during this compilation. Hence, the authors would be grateful to receive notice of any new or old papers that the readers think should be added. As a final note, we gratefully acknowledge the helpful reviews provided by A. Elizabeth J. Crafford (Anchorage, Alaska) and William R. Page (USGS, Denver, Colorado).

Open-File Report↗

Sulphide petrology and ore genesis of the stratabound Sheep Creek sediment-hosted Zn–Pb–Ag–Sn prospect, and U–Pb zircon constraints on the timing of magmatism in the northern Alaska Range

The Sheep Creek prospect is a stratabound Zn–Pb–Ag–Sn massive sulfide occurrence in the Bonnifield mining district, northern Alaska Range. The prospect is within a quartz–sericite–graphite–chlorite schist unit associated with Devonian carbonaceous and siliceous metasedimentary rocks. Volcanogenic massive sulfide (VMS) deposits in the district are hosted in felsic metavolcanic rocks (362 ± 2 Ma) associated with siliciclastic and carbonaceous sedimentary rocks that overlie the stratigraphic sequence hosting the Sheep Creek prospect. Felsic metaigneous rocks in underlying units are 372 ± 4 to 366 ± 4 Ma. Sheep Creek is atypical of the other sulfide deposits in the district in (1) having Sn grades up to 1.2%; (2) being contained in fine-grained, quartz-rich rocks and quartz–pebble conglomerate that likely originated as chert and chert-clast sediment, respectively; and (3) showing minimal evidence of volcanic components in the host rocks. Comparison of immobile trace-element proportions for graphitic and siliceous rocks from the Sheep Creek area with those for argillite associated with the Bonnifield VMS deposits indicates a continental volcanic-arc provenance for the former and a within-plate and passive margin provenance for the latter. In contrast to previously published interpretations, our data analysis supports a clastic-dominated (CD) rather than a VMS affinity for the Sheep Creek prospect. In our model, Zn–Pb–Ag–Sn mineralization formed by syngenetic or early diagenetic processes on or beneath the seafloor, possibly in the shallow-water environment of an outer continental shelf setting. Potential analogues are the Paleozoic CD deposits in the Canadian Selwyn Basin outboard of the Laurentian continental margin.

Alaska↗

Oil in the Alaska North Slope gas hydrate reservoir: Micro-CT and flow simulation insights into permeability

Gas hydrate-bearing sands on the Alaska North Slope (ANS) host minor volumes of crude oil whose impact on formation permeability has never been quantified relative to a gas hydrate reservoir system. Here, we combine in situ pressure-core microcomputed-tomography (μ-CT), thermogravimetric analysis (TGA), gas-chromatography–mass-spectrometry (GC–MS), scanning-electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS), and Stokes-flow simulation to (i) quantify oil saturation, (ii) infer its source, and (iii) evaluate its influence on permeability after gas-hydrate dissociation. μ-CT and SEM-EDS imaging identify the host sediment as silty, with some grain-coating clay present. Eight representative 300 3 -voxel subvolumes extracted from a preserved pressure core (Core 15P-3c, from the B1 sand (unit B), HYDRATE 02 Geo Data Well (GDW), 886.96–887.29 m measured depth, MD) exhibit porosities of 0.34–0.37 and an average oil saturation of 0.09 ± 0.03, in comparison to an independent TGA-based estimate of 0.16. GC-MS fingerprints obtained from an adjacent depressurized core (Core 17P-1, 891.37–891.44 m MD), together with oil pore habit revealed by μ-CT, suggest that the oil is partly native but also includes contributions from mineral oil-based drilling fluid contamination. Further analysis of oil–porewater interactions and flushing tests confirms that native oil saturation in the analyzed samples ranges from 0.04 to 0.08 with an average of approximately 0.06, and the oil is highly immobile. Flow simulations demonstrate that the native oil saturation of ≈0.06 reduces permeability by approximately 50% due to both pore blockage and increased flow-path tortuosity. These findings reveal the potential presence of native oil within the ANS gas hydrate reservoir and suggest that future simulation models may need to account for its impact on permeability to improve long-term performance predictions of gas and water production.

Alaska↗

The Tintina Gold Belt - A global perspective

The so-called Tintina Gold Belt extends for more than 1000 km along the length of the northern North American Cordillera. Middle to Late Cretaceous Au deposits within the belt have various similar characteristics, among which are a spatial and temporal association with magmatism; Bi-W-Te signatures in deposits hosted by granitod stocks and As-Sb signatures where hosted by sedimentary rocks and dyke systems; and δ180 values consistently > 12 per mil for Au-bearing quartz. Nevertheless significant differences in structural styles, levels of deposit emplacement, ore-fluid chemistry, and Au grades suggest that the characteristics represent a broad range of deposit types. Many of these are best classified as orogenic Au deposits in the Yukon-Tanana terrane, as epithermal and porphyry-style Au deposits in the Kuskokwim region, and as Au-bearing, granite-related veins and stockworks, replacements, and skarns, as well as associated polymetallic lodes, in central Yukon. The diverse types of Au deposits and associated plutons of the Tintina Gold Belt collectively define a 45-m.y.-long period of arc magmatism that migrated northwesterly, for about 1000 km, across the active collisional margin of Cretaceous northwestern North America. The initiation of fluid flow and plutonism in Albian time seems to correlate with the onset of oblique subduction and dextral strike-slip on the Denali-Farewell, Tintina-Kaltag, and related fault systems. Initial Au-vein formation and subduction-related magmatism at about 115-110 Ma (e.g., including the Goodpaster and Fortymile districts), within the seaward side of the Yukon-Tanana terrane, correlate with the arrival of the Wrangellia superterrane off the continental margin. Dextral translation of the allochthonous Wrangellia block was associated with the migration of the thermal pulse to the northwest at about 95-90 Ma. Orogenic (or so­ called mesotherrnal) and granitoid-related Au deposits formed across the width of the Yukon-Tanana terrane (e.g., Fort Knox, True North, Ryan Lode, Kantishna district) and inland into the passive-margin rocks of the Selwyn basin ( e.g., Scheelite Dome, Brewery Creek, Dublin Gulch), respectively. By 70 Ma, the arc had migrated to the vicinity of present-day southwestern Alaska, where it was associated with the formation of additional orogenic Au deposits (e.g., Willow Creek district) and, within still-preserved shallow crustal levels, epithermal Au systems (e.g., Donlin Creek). The Au-bearing deposits of the Tintina Gold Belt are typical of those found in most well-preserved, moderate- to high-temperature Phanerozoic collisional orogens. Around the circum-Pacific region, these would include large areas of Mesozoic tectonism along the Cordilleran orogen, throughout the Russian Far East, and along the margins of the North China craton. Favorable terrain for such Au belts of Paleozoic age worldwide include the active Gondwana margins (e.g., Tasman orogenic system, northern Africa, Telfer district), and the northern margins ( e.g., Caledonian Kazakhstania, Uralian orogen, Baikal orogen, Tian Shan orogenic system) and western margins ( e.g., southern European massifs) to the Paleo-Tethys Ocean. Gold lodes in all of the Phanerozoic belts are dominated by orogenic Au-deposit types; other deposit types are concentrated where relatively shallow levels to the orogens are locally preserved. A significant percentage of the lode-gold resource in many areas was lost to placer accumulation that began forming approximately 100 m.y. after hypogene ore formation, except where continent-continent collision "cratonized" highly mineralized terranes in central Asia.

Book chapter↗

Hydrogeochemistry in the Yukon-Tanana Upland region of east-central Alaska: Possible exploration tool for porphyry-style deposits

A hydrogeochemical study using high resolution ICP-MS was undertaken at the Taurus and other porphyry Cu-Mo(-Au) occurrences and Ag-Au-Cu (+/- Pb, Zn) occurrences with epithermal-style characteristics in the Yukon-Tanana upland region of eastern Alaska. Surface water samples were collected from 30 sites on creeks that drain known deposits and occurrences and surrounding presumably unmineralized areas. Water samples for the entire ∼9 km length of McCord Creek, which drains the Taurus deposit, and those from streams draining the areas at and near the Bluff and Dennison porphyry occurrences have high conductivity values (492 to 1250 μS/cm) and consistently high concentrations of B (3-250 μg/L), Co (2.3 to 42 μg/L), Mn (339 to 4750 μg/L), Re (0.012 to 0.1 μg/L), and SO 4 2- (>200 mg/L), all of which are well above the median value for this data set and significantly greater than concentrations in water samples from the unmineralized areas. These are the best pathfinder elements specifically for porphyry style deposits because most of them are not anomalous in waters near epithermal occurrences. Copper concentrations are high (up to 115 μg/L) in some low-pH water samples from McCord Creek and drainages around Bluff, and a few near neutral pH waters have high molybdenum (>1 μg/L), but neither element is consistently anomalous in close vicinity to the porphyry occurrences, possibly due to a metal-poor, sulfide-poor leached cap (average of ∼50 m) that overlies supergene and hypogene mineralized zones and is the dominant rock at surface. High concentrations of Bi and/or As occur in many waters associated with mineralized areas, particularly the Bluff and Dennison occurrences. In general, the element associations related to porphyry deposits reflect the deposit mineralogy, as well as size of the footprint related to alteration and mineralization.

Alaska↗

Multistage hydrothermal silicification and Fe-Tl-As-Sb-Ge-REE enrichment in the Red Dog Zn-Pb-Ag district, northern Alaska: Geochemistry, origin, and exploration applications

Geochemical analyses of major, trace, and rare earth elements (REE) in more than 200 samples of variably silicified and altered wall rocks, massive and banded sulfide, silica rock, and sulfide-rich and unmineralized barite were obtained from the Main, Aqqaluk, and Anarraaq deposits in the Red Dog Zn-Pb-Ag district of northern Alaska. Detailed lithogeochemical profiles for two drill cores at Aqqaluk display an antithetic relationship between SiO2/Al2O3 and TiO2/Zr which, together with textural information, suggest preferential silicification of carbonate-bearing sediments. Data for both drill cores also show generally high Tl, Sb, As, and Ge and uniformly positive Eu anomalies (Eu/Eu* > 1.0). Similar high Tl, Sb, As, Ge, and Eu/Eu* values are present in the footwall and shallow hanging wall of Zn-Pb-Ag sulfide intervals at Anarraaq but are not as widely dispersed. Net chemical changes for altered wall rocks in the district, on the basis of average Al-normalized data relative to unaltered black shales of the host Kuna Formation, include large enrichments (>50%) of Fe, Ba, Eu, V, S, Co, Zn, Pb, Tl, As, Sb, and Ge at both Red Dog and Anarraaq, Si at Red Dog, and Sr, U, and Se at Anarraaq. Large depletions (>50%) are evident for Ca at both Red Dog and Anarraaq, for Mg, P, and Y at Red Dog, and for Na at Anarraaq. At both Red Dog and Anarraaq, wall-rock alteration removed calcite and minor dolomite during hydrothermal decarbonation reactions and introduced Si, Eu, and Ge during silicification. Sulfidation reactions deposited Fe, S, Co, Zn, Pb, Tl, As, and Sb; barite mineralization introduced Ba, S, and Sr. Light REE and U were mobilized locally. This alteration and mineralization occurred during Mississippi an hydrothermal events that predated the Middle Jurassic-Cretaceous Brookian orogeny. Early hydrothermal silicification at Red Dog took place prior to or during massive sulfide mineralization, on the basis of the dominantly planar nature of Zn-Pb veins, which suggests filling of fractures that developed in previously lithified rock. Uniformly low Ca and Mg and uniformly negative Ce anomalies in highly siliceous Red Dog wall rocks reflect hydrothermal decarbonation reactions and pervasive silicification owing to conductive cooling of oxidized metalliferous fluids. Similar Ca and Mg depletions are evident at Anarraaq but generally lack associated silicification, possibly because temperatures of the hydrothermal fluids were too low (<180??C) or because the thermal contrast between the fluids and wall rocks was smaller owing to the greater depth of alteration and mineralization there, compared with Red Dog. Chalcophile element anomalies (Fe, Zn, Pb, Tl, As, Sb) in wall rocks at both Red Dog and Anarraq are attributed to sulfidation reactions, coeval with subsurface Zn-Pb-Ag mineralization, during the mixing of oxidized metalliferous fluids with H2S-rich fluids derived locally within the Kuna Formation. Sedimentary wall rocks in the Red Dog district are characterized by a distinctive suite of geochemical anomalies, especially for Zn, Pb, Tl, As, Sb, Ge, and Eu/Eu*. At the Aqqaluk deposit, wall rocks without visible sphalerite or galena (<300 ppm Zn + Pb) have anomalous Eu/Eu*, Tl, Sb, and As for up to ???100 m stratigraphically below Zn-rich silica rock. At Anarraaq, the Tl anomaly is most extensively developed, and enrichment relative to unaltered black shale of the Kuna Formation is present up to 62 m above the highest Zn-Pb sulfide zones. The magnitude of the enrichment and systematic behavior of Tl in the district make Tl a promising geochemical exploration guide for Red Dog-type Zn-Pb-Ag deposits elsewhere. ?? 2004 by Economic Geology.

Economic Geology↗

Magnesite and brucite in the United States, exclusive of Alaska and Hawaii

The important deposits of magnesite (MgCO 3 ) and brucite (MgO.H 2 O) in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. Single deposits and groups of deposits are shown by geometric symbols according to four size categories based on estimated production plus reserves. These categories are: less than 10,000 tons, 10,000 to 100,000 tons, 100,000 to 1,000,000 tons, and more than 1,000,000 tons. Occurrences of mineralogic interest only are not shown. All map locations are numbered consecutively in each State and keyed to the locality index. The geographical coordinates in the locality index represent the centers of the geometric symbols. Thus, the same coordinates are assigned to all deposits covered by a group symbol. The map was compiled from published reports and data in the files of the United States Geological Survey. The names, geographic coordinates, and geologic types of deposits are given in the locality index. The principal published reports used in compiling the map are listed in the selected references. The main types of commercial deposits of magnesite in the United States are: (1) replacement bodies in limestone and dolomite; (2) replacements and veins in serpentine; and (3) sedimentary beds. Other magnesite deposits of varied origin and less common occurrence include beds associated with talc, chlorite, and mica schists; and veins and lenses in altered tuffs. Brucite is a relatively rare mineral of secondary origin which usually accompanies other magnesian minerals, particularly magnesite and hydromagnesite, and is associated with carbonate rocks and serpentine. Magnesite was first mined in California in 1886, and the State was the only domestic producer until the development of the Washington deposits began in 1916. In recent years, the main production of magnesite has been from Stevens County, Washington, and Nye County, Nevada. Production in California has been intermittent since 1945. Magnesite deposits in Texas were mined during and immediately after World War II. At present (1961) the only brucite deposits being worked are those at Gabbs, Nye County, Nevada. They have been mined almost continuously since 1935.

Mineral Investigations Resource Map↗