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At least 1,063 records · Page 59Linked to original sources

2D IR spectra of cyanide in water investigated by molecular dynamics simulations

Using classical molecular dynamics simulations, the 2D infrared (IR) spectroscopy of CN − solvated in D 2 O is investigated. Depending on the force field parametrizations, most of which are based on multipolar interactions for the CN − molecule, the frequency-frequency correlation function and observables computed from it differ. Most notably, models based on multipoles for CN − and TIP3P for water yield quantitatively correct results when compared with experiments. Furthermore, the recent finding that T 1 times are sensitive to the van der Waals ranges on the CN − is confirmed in the present study. For the linear IR spectrum, the best model reproduces the full widths at half maximum almost quantitatively (13.0 cm −1 vs. 14.9 cm −1 ) if the rotational contribution to the linewidth is included. Without the rotational contribution, the lines are too narrow by about a factor of two, which agrees with Raman and IR experiments. The computed and experimental tilt angles (or nodal slopes) α as a function of the 2D IR waiting time compare favorably with the measured ones and the frequency fluctuation correlation function is invariably found to contain three time scales: a sub-ps, 1 ps, and one on the 10-ps time scale. These time scales are discussed in terms of the structural dynamics of the surrounding solvent and it is found that the longest time scale (≈10 ps) most likely corresponds to solvent exchange between the first and second solvation shell, in agreement with interpretations from nuclear magnetic resonance measurements.

Journal of Chemical Physics↗

Disinfection of three wading boot surfaces infested with New Zealand mudsnails

New Zealand mudsnails Potamopyrgus antipodarum (NZMS) have been introduced into many continents and are easily transported live while attached to wading and other field gear. We quantified the relative attachment by different life stages of NZMS to felt, neoprene, and rubber-soled boots exposed to two densities of NZMS in experimental exposure totes. Attachment by NZMS occurred on boots of all surfaces, but the highest numbers of all life stages occurred on boots with felt surfaces. We found a 15–20-min bath application of 20 g/L Virkon Aquatic was a reliable tool to disinfect boot surfaces infested with NZMS and other aquatic invertebrates. Our studies support that spray application of this disinfectant was not reliable to provide complete mortality of attached adult NZMS or neonates. Wading gear surfaces exposed to repeated bath disinfections showed little deterioration. Our results provide strong evidence that bath disinfections with Virkon Aquatic are helpful to assure biosecurity in field and hatchery settings, but applications should be coupled with cleaning procedures to remove organic materials that can deactivate the reagent.

North American Journal of Fisheries Management↗

Effect of corolla slitting and nectar robbery by the Eastern Carpenter Bee (Hymenoptera: Apidae) on fruit quality of Vaccinium corymbosum, L.; (Ericales: Ericaceae).

Eastern carpenter bees, Xylocopa virginica (L.) (Hymenoptera: Apidae), are among the most abundant native bee visitors to highbush blueberry, Vaccinium corymbosum L., flowers in the northeastern United States, and they sometimes display corolla-slitting behavior to rob nectar. We studied foraging behavior of X. virginica on 14 blueberry cultivars in an experimental planting in Rhode Island, and assessed factors related to slitting frequency, and the effects of slitting on fruit set and blueberry quality. Among 14 cultivars in bloom, an average of 35% (range 16–67%) of flowers were slit in 2017, and 39% (range 20–62%) in 2018. Factors that affected the proportion of corollas slit included cultivar, anther length, flower volume, and number of days in bloom at or above 15°C. Corolla slitting did not affect fruit set. Average weight and percent soluble solids of fruit resulting from slit and non-slit corollas did not differ significantly in two early- ( ‘ Bluehaven ’ , ‘ Earliblue ’ ), two mid- ( ‘ Collins ’ , ‘ Bluecrop ’ ), and two late-season ( ‘ Herbert ’ , ‘ Lateblue ’ ) ripening cultivars in 2017. In 2018, average fruit weight and percent soluble solids resulting from slit and non-slit flowers did not differ significantly in most cultivars, but slit corollas resulted in berries with greater mass in two cultivars, ‘ Bluehaven ’ and ‘ Collins ’ . ‘ Collins ’ fruit from non-slit corollas had a significantly higher percentage of soluble solids at maturity than fruit from slit corollas in 2018. Corolla slitting and nectar robbery by X. virginica did not have a significant negative effect on fruit quality under the described growing conditions and pollinator community.

Rhode Island↗

Hierarchical clustering for paired watershed experiments: Case study in southeastern Arizona, U.S.A.

Watershed studies are often onerous due to a lack of data available to portray baseline conditions with which to compare results of monitoring environmental effects. A paired-watershed approach is often adopted to simulate baseline conditions in an adjacent watershed that can be comparable but assumes there is a quantifiable relationship between the control and treated watersheds. Finding suitably matched pairs that can most accurately depict similar responses is challenging and attributes are rarely quantified. In southeastern Arizona, United States, researchers are investigating the effectiveness of watershed restoration techniques employed by land managers. We selected Smith Canyon to develop a rigorous and quantitatively defensible paired-watershed experimental design. The Smith Canyon watershed consists of 91 structurally similar sub-basins that have a defined basin-like structure and flow channel, allowing for consideration as replicate units. We developed a statistical approach to group sub-basins based on similar structural, biophysical, and hydrologic traits. Our geospatial database consisted of 35 environmental variables, which we reduced to 12 through a correlation analysis. We identified three primary collections of paired sub-basins within the larger watershed. These clusters are being used to inform studies actively being employed in the watershed. Overall, we propose a hierarchical clustering protocol for justification of watershed pairing experiments.

Arizona↗

Mobilization of major inorganic ions during experimental diagenesis of characterized peats

Laboratory experiments were undertaken to study changes in concentrations of major inorganic ions during simulated burial of peats to about 1.5 km. Cladium, Rhizophora, and Cyrilla peats were first analyzed to determine cation distributions among fractions of the initial materials and minerals in residues from wet oxidation. Subsamples of the peats (80 g) were then subjected to increasing temperatures and pressures in steps of 5??C and 300 psi at 2-day intervals and produced solutions collected. After six steps, starting from 30??C and 300 psi, a final temperature of 60??C and a final pressure of 2100 psi were achieved. The system was then allowed to stand for an additional 2 weeks at 60??C and 2100 psi. Treatments resulted in highly altered organic solids resembling lignite and expelled solutions of systematically varying compositions. Solutions from each step were analyzed for Na+, Ca2+, Mg2+, total dissolved Si (Si(T)), Cl-, SO42-, and organic acids and anions (OAAs). Some data on total dissolved Al (Al(T)) were also collected. Mobilization of major ions from peats during these experiments is controlled by at least three processes: (1) loss of dissolved ions in original porewater expelled during compaction, (2) loss of adsorbed cations as adsorption sites are lost during modification of organic solids, and (3) increased dissolution of inorganic phases at later steps due to increased temperatures (Si(T)) and increased complexing by OAAs (Al(T)). In general, results provide insight into early post-burial inorganic changes occurring during maturation of terrestrial organic matter. (C) 2000 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

Beta-thymosin gene polymorphism associated with freshwater invasiveness of alewife ( Alosa pseudoharengus )

Predicting the success of a species’ colonization into a novel environment is routinely considered to be predicated on niche-space similarity and vacancy, as well as propagule pressure. The role genomic variation plays in colonization success (and the interaction with environment) may be suggested, but has not rigorously been documented. To test an hypothesis that previously observed ecotype-specific polymorphisms between anadromous and landlocked alewife (Alosa pseudoharengus) populations are an adaptive response to osmoregulatory challenges rather than a result of allele sampling at founding, we examined multiple anadromous and landlocked (colonized) populations for their allelic profiles at a conserved region (3’-UTR end) of a β-thymosin gene whose protein product plays a central role in the organization of cytoskeleton. The putatively ancestral β-thymosin allele was prevalent in anadromous populations, whereas a newly derived allele was overrepresented in landlocked populations; a third allele was exclusive to the anadromous populations. We also conducted a complementary set of salinity exposure experiments to test osmoregulatory performance of the alewife ecotypes in contrasting saline environments. The pattern of variation and results from these challenges indicate a strong association of β-thymosin with colonization success and a transition for species with an anadromous life-history to one with only a freshwater component.

Journal of Experimental Zoology↗

Geothermal elements in lichens of Yellowstone National Park, USA

Geothermal features (e.g. geysers, fumaroles, vents, and springs) emit gaseous mercury, sulfur and heavy metals and therefore, are natural sources of these elements in the atmosphere. Field studies of heavy metals in lichens in Italy have detected elevated concentrations near geothermal power plants, and have determined that the origin of mercury is from soil degassing, not soil particles. We studied this phenomenon in a geothermal area without power plants to determine the natural levels of mercury and other elements. Two common and abundant species of epiphytic lichens, Bryoria fremontii and Letharia vulpina , were collected at six localities in Yellowstone National Park, USA in 1998 and analyzed for 22 chemical elements. Thirteen elements differed significantly between species. Some elements were significantly higher in the southern part of the park, while others were higher in the north. Levels of most elements were comparable with those in other national parks and wilderness areas in the region, except Hg, which was unusually high. The most likely sources of this element are the geothermal features, which are known emitters of Hg. Multivariate analyses revealed strong positive associations of Hg with S, and negative associations with soil elements, providing strong evidence that the Hg in the lichens is the result of soil degassing of elemental Hg rather than particulate Hg directly from soils. Average Hg levels in the lichens were 140 p.p.b. in Bryoria and 110 p.p.b. in Letharia , but maxima were 291 and 243 p.p.b., respectively. In spite of this, both species were healthy and abundant throughout the park.

Idaho, Montana, Wyoming↗

Multiple stresses from a single agent: Diverse responses to the experimental acidification of Little Rock Lake, Wisconsin

A single stress, acidification with sulfuric acid, was applied to Little Rack Lake in a whole-ecosystem manipulation. We documented a wide range of responses to the acidification, including increases in the concentrations of various chemicals, shifts in microbial processes and a major increase in water clarity to UV-B radiation. Each of these changes could in itself be considered as a separate ecosystem stress that is distinct from the intended manipulation. Acidification in Little Rock Lake was accompanied by a number of substantial changes in the occurrence of organisms. A series of detailed investigations indicates that the mechanisms underlying these organismal changes are varied but cannot usually be tied to the direct effects of acidification. Overall, our results demonstrate how multiple stresses can arise from a single agent operating on an ecosystem and suggest that singly operating stresses may actually be quite rare.

Limnology and Oceanography↗

Multiple stresses from a single agent: Diverse responses to the experimental acidification of Little Rock Lake, Wisconsin

A single stress, acidification with sulfuric acid, was applied to Little Rock Lake in a whole-ecosystem manipulation. We documented a wide range of responses to the acidification, including increases in the concentrations of various chemicals, shifts in microbial processes and a major increase in water clarity to UV-B radiation. Each of these changes could in itself be considered as a separate ecosystem stress that is distinct from the intended manipulation. Acidification in Little Rock Lake was accompanied by a number of substantial changes in the occurrence of organisms. A series of detailed investigations indicates that the mechanisms underlying these organismal changes are varied but cannot usually be tied to the direct effects of acidification. Overall, our results demonstrate how multiple stresses can arise from a single agent operating on an ecosystem and suggest that singly operating stresses may actually be quite rare.

Limnology and Oceanography↗

Dynamic risk from Mexican wolves and mountain lions influences elk foraging behavior

Foraging time is a major component of ungulate activity budgets but can be limited by anti-predator behaviors (e.g., vigilance). Multitasking can reduce the nutritional costs of vigilance under heightened predation risk, but this may depend on the response of prey to risk from multiple predators across a complex spatiotemporal landscape. Mexican gray wolves ( Canis lupus baileyi ) and mountain lions ( Puma concolor ) are primary predators for elk ( Cervus canadensis ) in the Mexican wolf experimental population area in east-central Arizona and west-central New Mexico. We observed elk foraging across varying levels of wolf risk throughout all seasons and diel periods to quantify proportions of foraging, intense vigilance, and multitasking at the individual and herd levels. We quantified encounter and kill risk from Mexican wolves and mountain lions using habitat selection functions and utilization distributions. We modeled elk behaviors as functions of predicted risk for both predators in addition to temporal and environmental covariates and accounted for human presence. Our results indicate that individual elk reduced foraging in areas with higher predicted risk from Mexican wolves or mountain lions and increased intense vigilance and multitasking in areas with higher wolf risk. A reduction in the proportion of bedded elk in the herd during all diel periods under increased wolf risk supports previous findings. These results also suggest that elk compensate for higher intense vigilance and reduced foraging during foraging bouts by increasing cumulative foraging bouts per day at the cost of resting. Additionally, the probability of multitasking for individuals depended on an interaction between short- and long-term wolf risk, and the likelihood of intense vigilance was highest under the greatest combined spatial and temporal risk from wolves. This research provides insight into the fine-scale and complex behavioral responses of elk to their primary predators and implies a need for researchers to consider these non-consumptive effects in future studies of predator–prey dynamics.

Arizona, New Mexico↗

Laboratory generated M -6 earthquakes

We consider whether mm-scale earthquake-like seismic events generated in laboratory experiments are consistent with our understanding of the physics of larger earthquakes. This work focuses on a population of 48 very small shocks that are foreshocks and aftershocks of stick–slip events occurring on a 2.0 m by 0.4 m simulated strike-slip fault cut through a large granite sample. Unlike the larger stick–slip events that rupture the entirety of the simulated fault, the small foreshocks and aftershocks are contained events whose properties are controlled by the rigidity of the surrounding granite blocks rather than characteristics of the experimental apparatus. The large size of the experimental apparatus, high fidelity sensors, rigorous treatment of wave propagation effects, and in situ system calibration separates this study from traditional acoustic emission analyses and allows these sources to be studied with as much rigor as larger natural earthquakes. The tiny events have short (3–6 μs) rise times and are well modeled by simple double couple focal mechanisms that are consistent with left-lateral slip occurring on a mm-scale patch of the precut fault surface. The repeatability of the experiments indicates that they are the result of frictional processes on the simulated fault surface rather than grain crushing or fracture of fresh rock. Our waveform analysis shows no significant differences (other than size) between the M -7 to M -5.5 earthquakes reported here and larger natural earthquakes. Their source characteristics such as stress drop (1–10 MPa) appear to be entirely consistent with earthquake scaling laws derived for larger earthquakes.

Pure and Applied Geophysics↗

Inferring infection hazard in wildlife populations by linking data across individual and population scales

Our ability to infer unobservable disease-dynamic processes such as force of infection (infection hazard for susceptible hosts) has transformed our understanding of disease transmission mechanisms and capacity to predict disease dynamics. Conventional methods for inferring FOI estimate a time-averaged value and are based on population-level processes. Because many pathogens exhibit epidemic cycling and FOI is the result of processes acting across the scales of individuals and populations, a flexible framework that extends to epidemic dynamics and links within-host processes to FOI is needed. Specifically, within-host antibody kinetics in wildlife hosts can be short-lived and produce patterns that are repeatable across individuals, suggesting individual-level antibody concentrations could be used to infer time since infection and hence FOI. Using simulations and case studies (influenza A in lesser snow geese and Yersinia pestis in coyotes), we argue that with careful experimental and surveillance design, the population-level FOI signal can be recovered from individual-level antibody kinetics, despite substantial individual-level variation. In addition to improving inference, the cross-scale quantitative antibody approach we describe can reveal insights into drivers of individual-based variation in disease response, and the role of poorly understood processes such as secondary infections, in population-level dynamics of disease.

Ecology Letters↗

An experimental investigation of interaction between andesite and hyperacidic volcanic lake water

Alteration in magmatic-hydrothermal systems leads to distinct changes in rock texture and mineralogy, and a strong redistribution of elements between fluid and rock. Here, we experimentally interacted andesite scoria with hyperacidic, high-sulfidation style fluids from Kawah Ijen volcano (Indonesia) at 25 and 100˚C, seeking to reproduce the textures observed in natural samples from this volcano, and to understand the element fluxes that accompany alteration. The susceptibility to alteration in the experiments is Cu-Fe-sulphide > calcic plagioclase > pyroxene > titano-magnetite > sodic plagioclase, with complete preservation of glass. Silicate minerals alter to opaline silica, and gypsum, barite and a Zr-phase precipitate. The selective alteration of the phenocryst minerals results in a preferential release of compatible elements, as the glass is the main incompatible element host. The experiments reproduce the alteration textures of the natural samples, including the preservation of glass, but the predicted compatible over incompatible element enrichment in the alteration element flux is not observed in the natural setting. This suggests that alteration at Kawah Ijen is dominated by lithologies that lack abundant glass, in particular lava flows where the glass has devitrified, despite these lava flows having a lower surface area compared to scoria.

Kawah Ijen↗

An experimental investigation of chemical communication in the polar bear

The polar bear ( U rsus maritimus ), with its wide-ranging movements, solitary existence and seasonal reproduction, is expected to favor chemosignaling over other communication modalities. However, the topography of its Arctic sea ice habitat is generally lacking in stationary vertical substrates routinely used for targeted scent marking in other bears. These environmental constraints may have shaped a marking strategy, unique to polar bears, for widely dispersed continuous dissemination of scent via foot pads. To investigate the role of chemical communication, pedal scents were collected from free-ranging polar bears of different sex and reproductive classes captured on spring sea ice in the Beaufort and Chukchi seas, and presented in a controlled fashion to 26 bears in zoos. Results from behavioral bioassays indicated that bears, especially females, were more likely to approach conspecific scent during the spring than the fall. Male flehmen behavior, indicative of chemosignal delivery to the vomeronasal organ, differentiated scent donor by sex and reproductive condition. Histologic examination of pedal skin collected from two females indicated prominent and profuse apocrine glands in association with large compound hair follicles, suggesting that they may produce scents that function as chemosignals. These results suggest that pedal scent, regardless of origin, conveys information to conspecifics that may facilitate social and reproductive behavior, and that chemical communication in this species has been adaptively shaped by environmental constraints of its habitat. However, continuously distributed scent signals necessary for breeding behavior may prove less effective if current and future environmental conditions cause disruption of scent trails due to increased fracturing of sea ice.

Journal of Zoology↗

Mangrove species' responses to winter air temperature extremes in China

The global distribution and diversity of mangrove forests is greatly influenced by the frequency and intensity of winter air temperature extremes. However, our understanding of how different mangrove species respond to winter temperature extremes has been lacking because extreme freezing and chilling events are, by definition, relatively uncommon and also difficult to replicate experimentally. In this study, we investigated species-specific variation in mangrove responses to winter temperature extremes in China. In 10 sites that span a latitudinal gradient, we quantified species-specific damage and recovery following a chilling event, for mangrove species within and outside of their natural range (i.e., native and non-native species, respectively). To characterize plant stress, we measured tree defoliation and chlorophyll fluorescence approximately one month following the chilling event. To quantify recovery, we measured chlorophyll fluorescence approximately nine months after the chilling event. Our results show high variation in the geographic- and species-specific responses of mangroves to winter temperature extremes. While many species were sensitive to the chilling temperatures (e.g., Bruguiera sexangula and species in the Sonneratia and Rhizophora genera), the temperatures during this event were not cold enough to affect certain species (e.g., Kandelia obovata , Aegiceras corniculatum , Avicennia marina, and Bruguiera gymnorrhiza ). As expected, non-native species were less tolerant of winter temperature extremes than native species. Interestingly, tidal inundation modulated the effects of chilling. In comparison with other temperature-controlled mangrove range limits across the world, the mangrove range limit in China is unique due to the combination of the following three factors: (1) Mangrove species diversity is comparatively high; (2) winter air temperature extremes, rather than means, are particularly intense and play an important ecological role; and (3) due to afforestation and restoration efforts, several species of non-native mangroves have been introduced beyond their natural range limits. Hence, from a global perspective, mangroves in China provide valuable opportunities to advance understanding of the effects of freezing and chilling temperatures on mangroves. Within the context of climate change, our findings provide a foundation for better understanding and preparing for mangrove species-specific responses to future changes in the duration and intensity of winter temperature extremes.

Ecosphere↗

Dynamics and evolution of the Kı̄lauea lower East Rift Zone 2018 fissure 8 lava flow and implications for multiphase magma properties

The 2018 Kı̄lauea lower East Rift Zone (KLERZ) eruption was one of the most voluminous eruptions on the Island of Hawai’i in the past 200 years, leading to major disruption and destroying over 700 homes and structures. The majority of the erupted magma was emitted as a lava flow from Ahu’ailā’au (fissure 8), which was active from late May to early August. To better understand the evolution of long-lived channelized lava flows, we examined the evolution of velocity, texture, and inferred rheology of the fissure 8 lava in space and time. We quantified lava flow surface velocities using particle image velocimetry in more than 200 aerial videos that span the lava flow duration and length. Velocity measurements were analyzed together with vesicularity and crystallinity measurements from 9 co-located post-eruptive field samples to understand the textural evolution of this flow and its impact on lava rheology and flow velocity. The fissure 8 flow was highly vesicular, with 79%–88% vesicularity at the vent, decreasing to 16%–26% vesicularity 12.5 km from the vent. The volume fraction occupied by crystals 50 in size increased from 6% at the vent to about 18% at 12.5 km downstream. We find that the effective flow viscosity increased at a quadratic rate with distance. Using experimentally determined liquid viscosity and applying established models to account for the effect of crystals and bubbles, we attribute this increase primarily to textural evolution driven initially by the near-vent loss of deformable bubbles and later by cooling and crystal growth. We demonstrate the importance of accounting for the evolution of vesicularity and the role of vesicles by showing that utilizing this capability in the open-source thermo-rheological lava flow propagation model PyFLOWGO allows for more accurate predictions of the observed flow velocities. Our modeling results suggest that small bubbles behaving rigidly are required to simulate the observed flow length, speed, and viscosities. Flow velocities of the fissure 8 lava also varied with time, driven by near-daily collapse events of the summit caldera. Temporal velocity changes were characterized by a period of steep acceleration, with the volumetric flux peaking around 4 h after a caldera collapse, followed by a period of gradual deceleration lasting up to 40 h or until the next collapse event. We use this temporal behavior to estimate the compressibility of the magma inside the plumbing system between the summit reservoir and the lower East Rift Zone. Overall, quantifying the spatial and temporal evolution of the KLERZ eruption provides information about magma and lava properties that can inform predictive modeling and hazard assessment during an eruption.

Hawaii↗

Sex differences in the thermoregulation and evaporative water loss of a heterothermic bat, Lasiurus cinereus, during its spring migration

This study quantifies sex differences in thermoregulation and water loss of a small (20-35 g) insectivorous heterothermic mammal, the hoary bat Lasiurus cinereus , during its spring migration. We measured body temperature, metabolic rate and evaporative water loss, and calculated wet thermal conductance, for bats exposed to air temperatures ranging from 0 to 40°C for periods of 2-5 h. Pregnant females maintained normothermic body temperatures (35.7±0.7°C; mean ± s.e.m. ) independent of air temperature. In contrast, males became torpid during the majority (68%) of exposures to air temperatures <25°C. The thermal neutral zone (TNZ) ranged between approximately 30°C and 34°C in both sexes and, within the TNZ, females had lower mass-specific metabolic rates (6.1±0.2 mW g -1 ) than males (9.0±0.9 mW g -1 ). Wet thermal conductance values in torpid bats (0.7±0.5 mW g -1 deg. -1 ) were lower than those of normothermic individuals (1.1±0.3 mW g -1 deg. -1 ). Mass-specific rates of evaporative water loss in males were consistently higher than in females at most air temperatures and rates of water loss in torpid bats were 63±6% of normothermic values. These results suggest that male and pregnant female L. cinereus employ different thermoregulatory strategies during their spring migration. Females defend normothermic body temperatures, presumably to expedite embryonic growth, while males use torpor, presumably to minimize energy and water deficits. These variable thermoregulatory strategies may reflect continental differences in the summer distribution of the sexes.

Journal of Experimental Biology↗

Seismotectonic map of the Eastern United States

The purpose of a seismotectonic map is to describe the distribution of historic seismic activity in relation to geologic structures and tectonic provinces and to identify structures or regions that are characterized by consistent relations between seismic activity and structural features. An experimental study to test the feasibility of preparing such a map and its usefulness in evaluating earthquake hazards was initiated jointly by the U.S. Geological Survey and the former Seismology Division of the National Oceanic and Atmospheric Administration; financial support was provided by the U.S. Atomic Energy Commission. It was hoped that the study would develop evidence for the existence of tectonic regions or structural provinces that are useful in defining parameters of seismic hazard in relation to engineered structures. As with many experiments, this one did not produce the results envisioned at the outset, but it did result, we think, in assembling seismic and structural data useful in evaluating the distribution and origin of earthquakes in the eastern part of the United States and in delimiting areas of relative seismic activity.

Miscellaneous Field Studies Map↗