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At least 1,063 records · Page 59Linked to original sources

Hydrogeology and shallow groundwater quality in the tidal Anacostia River watershed, Washington, D.C.

Groundwater hydrology and geochemistry within the tidal Anacostia River watershed of Washington, D.C. are related to natural and human influences. The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, began investigating the hydrogeology and groundwater quality of the watershed in 2002. Lithologic coring, groundwater-level and tidal monitoring, and water-quality sampling have been conducted to improve understanding of the groundwater-flow system, geochemistry, water quality, and the likely interaction between groundwater and the tidal Anacostia River. The flow and interaction of shallow groundwater with the tidal Anacostia River and other area streams are affected by diversions, pumping, land reclamation, and other human activities in this highly urbanized watershed. The tidal Anacostia River watershed is underlain by a wedge of unconsolidated sediments that is part of the Atlantic Coastal Plain Physiographic Province. These sediments form a system of confined and unconfined aquifers. The coarse sediments of the Potomac Group sand-dominated lithofacies form the Patuxent aquifer. The Patuxent aquifer crops out and subcrops in the northwestern part of the study area, but is confined to the southeast by the overlying Potomac Group clay-dominated lithofacies. Overlying the Potomac Group is a series of interbedded sands and clays that form an unconfined surficial aquifer system. Regional correlation in the unconfined surficial aquifer system is complicated by local heterogeneity in aquifer sediments. Local perched and semi-confined conditions occur in some areas. Recharge of the confined Patuxent aquifer occurs primarily in the outcrop and subcrop area, although some recharge may also occur through overlying confining units. Recharge to the unconfined surficial aquifer system occurs through infiltration of precipitation and possible artificial recharge from structures such as underground water or sewer pipes. In the Patuxent aquifer, hydraulic gradients indicate downward movement in the outcrop area, whereas hydraulic heads beneath the Anacostia River are higher than land surface, indicating an upward hydraulic gradient. In the unconfined surficial aquifer system, groundwater generally flows from upland recharge areas towards discharge areas near the Anacostia River and its tributaries. Groundwater from the confined part of the Patuxent aquifer also may discharge to the Anacostia River in locations where the overlying clay-dominated lithofacies of the Potomac Group is absent as a result of past geologic and (or) alluvial processes. Geochemistry and groundwater quality are affected by hydrologic conditions as well as anthropogenic influences. Local variability in groundwater quality reflects local variability in hydrogeologic conditions and sources of chemicals. Groundwater ranges from anoxic and iron- or calcium-bicarbonate type, to oxic with elevated nitrate. The occurrence and distribution of pesticides, volatile organic compounds, and other selected chemical compounds in groundwater reflect the multitude of sources common to urban areas, as well as variable hydrogeologic and geochemical conditions that affect their fate and transport in the environment. Overall, concentrations of only a few of the over 200 chemical constituents included in laboratory analyses exceeded regulatory standards or guidance values. These include tetrachloroethene and arsenic, which were each detected one time in different wells. There were also several detections of iron and manganese that exceeded regulatory standards or guidance values that are associated with reducing conditions in aquifer sediments.

Washington, D.C.↗

Detailed description of oil shale organic and mineralogical heterogeneity via fourier transform infrared mircoscopy

Mineralogical and geochemical information on reservoir and source rocks is necessary to assess and produce from petroleum systems. The standard methods in the petroleum industry for obtaining these properties are bulk measurements on homogenized, generally crushed, and pulverized rock samples and can take from hours to days to perform. New methods using Fourier transform infrared (FTIR) spectroscopy have been developed to more rapidly obtain information on mineralogy and geochemistry. However, these methods are also typically performed on bulk, homogenized samples. We present a new approach to rock sample characterization incorporating multivariate analysis and FTIR microscopy to provide non-destructive, spatially resolved mineralogy and geochemistry on whole rock samples. We are able to predict bulk mineralogy and organic carbon content within the same margin of error as standard characterization techniques, including X-ray diffraction (XRD) and total organic carbon (TOC) analysis. Validation of the method was performed using two oil shale samples from the Green River Formation in the Piceance Basin with differing sedimentary structures. One sample represents laminated Green River oil shales, and the other is representative of oil shale breccia. The FTIR microscopy results on the oil shales agree with XRD and LECO TOC data from the homogenized samples but also give additional detail regarding sample heterogeneity by providing information on the distribution of mineral phases and organic content. While measurements for this study were performed on oil shales, the method could also be applied to other geological samples, such as other mudrocks, complex carbonates, and soils.

Energy & Fuels↗

A three-dimensional numerical model of predevelopment conditions in the Death Valley regional ground-water flow system, Nevada and California

In the early 1990's, two numerical models of the Death Valley regional ground-water flow system were developed by the U.S. Department of Energy. In general, the two models were based on the same basic hydrogeologic data set. In 1998, the U.S. Department of Energy requested that the U.S. Geological Survey develop and maintain a ground-water flow model of the Death Valley region in support of U.S. Department of Energy programs at the Nevada Test Site. The purpose of developing this 'second-generation' regional model was to enhance the knowledge an understanding of the ground-water flow system as new information and tools are developed. The U.S. Geological Survey also was encouraged by the U.S. Department of Energy to cooperate to the fullest extent with other Federal, State, and local entities in the region to take advantage of the benefits of their knowledge and expertise. The short-term objective of the Death Valley regional ground-water flow system project was to develop a steady-state representation of the predevelopment conditions of the ground-water flow system utilizing the two geologic interpretations used to develop the previous numerical models. The long-term objective of this project was to construct and calibrate a transient model that simulates the ground-water conditions of the study area over the historical record that utilizes a newly interpreted hydrogeologic conceptual model. This report describes the result of the predevelopment steady-state model construction and calibration. The Death Valley regional ground-water flow system is situated within the southern Great Basin, a subprovince of the Basin and Range physiographic province, bounded by latitudes 35 degrees north and 38 degrees 15 minutes north and by longitudes 115 and 118 degrees west. Hydrology in the region is a result of both the arid climatic conditions and the complex geology. Ground-water flow generally can be described as dominated by interbasinal flow and may be conceptualized as having two main components: a series of relatively shallow and localized flow paths that are superimposed on deeper regional flow paths. A significant component of the regional ground-water flow is through a thick Paleozoic carbonate rock sequence. Throughout the flow system, ground water flows through zones of high transmissivity that have resulted from regional faulting and fracturing. The conceptual model of the Death Valley regional ground-water flow system used for this study is adapted from the two previous ground-water modeling studies. The three-dimensional digital hydrogeologic framework model developed for the region also contains elements of both of the hydrogeologic framework models used in the previous investigations. As dictated by project scope, very little reinterpretation and refinement were made where these two framework models disagree; therefore, limitations in the hydrogeologic representation of the flow system exist. Despite limitations, the framework model provides the best representation to date of the hydrogeologic units and structures that control regional ground-water flow and serves as an important information source used to construct and calibrate the predevelopment, steady-state flow model. In addition to the hydrogeologic framework, a complex array of mechanisms accounts for flow into, through, and out of the regional ground-water flow system. Natural discharges from the regional ground-water flow system occur by evapotranspiration, springs, and subsurface outflow. In this study, evapotranspiration rates were adapted from a related investigation that developed maps of evapotranspiration areas and computed rates from micrometeorological data collected within the local area over a multiyear period. In some cases, historical spring flow records were used to derive ground-water discharge rates for isolated regional springs. For this investigation, a process-based, numerical model was developed to estimat

Water-Resources Investigations Report↗

Earthquakes generated from bedding plane-parallel reverse faults above an active wedge thrust, Seattle fault zone

A key question in earthquake hazard analysis is whether individual faults within fault zones represent independent seismic sources. For the Seattle fault zone, an upper plate structure within the Cascadia convergent margin, evaluating seismic hazard requires understanding how north-side-up, bedding-plane reverse faults, which generate late Holocene fault scarps, interact with the north-vergent master-ramp thrust and overlying backthrust of the fault zone. A regional uplift at A.D. 900–930 involved an earthquake that nucleated at depth and included slip on both the master-ramp thrust and the back-thrust. This earthquake also included slip on some of the <6-km-deep north-side-up, bedding-plane reverse faults. At locales where the north-side-up reverse faults intersect the Puget Sound coast, an earthquake a few centuries earlier than the A.D. 900–930 regional uplift only uplifted areas within hundreds of meters north of the reverse faults. We infer that the bedding-plane reverse faults are seismogenic because shore platforms near the reverse faults have been abruptly uplifted during earthquakes when other shorelines in the Seattle fault zone were unaffected. Faults of the Seattle fault zone therefore can both produce regional uplift earthquakes, with or without surface displacement on the reverse faults, and produce earthquakes that rupture the bedding-plane reverse faults causing fault scarps and uplift localized to hundreds of meters north of these faults. This latter type of earthquake has occurred at least twice and perhaps three times in the late Holocene, and all these earthquakes preceded the regional coseismic uplift of A.D. 900–930. To account for the paleoseismic observations, we propose that the Seattle fault zone is a wedge thrust, with the leading edge being a fault-bend, wedge thrust fold. The active axial surface of the wedge thrust fold is pinned at the tip of the wedge, and a steeply north-dipping sequence of Tertiary sediment forms the south limb of the wedge thrust fold. Some of these steeply north-dipping, bedding-plane surfaces are seismogenic reverse faults that produce scarps. Earthquakes on the wedge thrust produce the regional coseismic uplift events, and earthquakes within the fault-bend fold cause the local uplift earthquakes. Thus, bedding-plane faults can rupture during earthquakes when the wedge thrust does not rupture but instead continues to accumulate seismic energy.

Washington↗

Preliminary report on the geology and hydrology of Mortandad Canyon near Los Alamos, New Mexico, with reference to disposal of liquid low-level radioactive waste

The U.S. Geological Survey, in cooperation with the U.S. Atomic Energy Commission and the Los Alamos Scientific Laboratory, selected the upper part of Mortandad Canyon near Los Alamos, New Mexico for a site for disposal of treated liquid low-level radioactive waste. This report summarizes the part of a study of the geology and hydrology that was done from October 1960 through June 1961. Additional work is being continued. Mortandad Canyon is a narrow east-southeast-trending canyon about 9? miles long that heads on the central part of the Pajarito Plateau at an altitude of about 7,340 feet. The canyon is tributary to the Rio Grande. The drainage area of the part of Mortandad Canyon that was investigated is about 2 square miles, and the total drainage area is about 4.9 square miles. The Pajarito Plateau is capped by the Bandelier Tuff of Pleistocene age. Mortandad Canyon is cut in the Bandelier, and alluvium covers the floor of the canyon to depths ranging from less than 1 foot to as much as 100 feet. The Bandelier is underlain by silt, sand, conglomerate, and interbedded basalt of the Santa Fe Group of Miocene, Pliocene, and Pleistocene(?) age. Some ground water is perched in the alluvium in the canyon; however, the top of the main aquifer is in the Santa Fe Group at a depth of about 990 feet below the canyon floor. Joints in the Bandelier Tuff probably were caused by shrinkage of the tuff during cooling. The joints range in width from hairline cracks to fissures several inches wide. Water can infiltrate along the open joints where the Bandelier is at the surface; however, soil, alluvial fill, and autochthonous clay inhibit infiltration on the tops of mesas and probably in the alluvium-floored canyons also. Thirty-three test holes, each less than 100 feet deep, were drilled in 10 lies across Mortandad Canyon from the western margin of the study area to just west of the Los Alamos-Santa Fe County line. Ten of the holes were cased for observation wells to measure water levels and collect water samples from the alluvium. Twenty-three of the holes were cased to seal out water and were used as access tubes to accommodate a neutron-neutron probe for determining the moisture content of the alluvium and tuff. The source of recharge for the perched ground-water body in the alluvium in Mortandad Canyon is the precipitation in the drainage area of the canyon. During the winter of 1960-61, a snowpack 1-2 feet thick accumulated in the narrow shaded upper part of the canyon. The alluvium below the snowpack received some recharge because of diurnal melting during the winter. In March 1961 the snowmelt water saturated most of the thin alluvium in the upper part of the canyon, and a surface stream began to flow on the alluvium. The maximum flow of the stream was about 250 gpm (gallons per minute). Water from the stream infiltrated the alluvium at the front of the stream and in the reach upstream from the front. A ground-water mound was formed beneath the channel by water infiltrating from the stream. The front of the stream and the front of the ground-water mound advanced eastward to about the middle of the area studied. From this point eastward, the alluvium was thick enough to absorb and transmit the amount of flow in 1961. Late in April the front of the stream retreated, and by the first of May the flow stopped. During and after this period the ground-water mound decayed, and ground-water levels declined in the upper part of the canyon as water drained into the channel and downgradient through the alluvium. The amount of recharge was small in the wide lower part of the canyon during the period of study. The rise in ground-water levels and the increase in moisture content of the alluvium in the lower part of the canyon indicate that water moved downgradient by underflow through the alluvium from the recharge area in the upper part of the canyon. Moisture measurements indicate that only a little water moved into the underlyin

Open-File Report↗

Diel temperature signals track seasonal shifts in localized groundwater contributions to headwater streamflow generation at network scale

Groundwater contributions to streamflow sustain aquatic ecosystem resilience; streams without significant groundwater inputs often have well-coupled air and water temperatures that degrade cold-water habitat during warm low flow periods. Widespread uncertainty in stream-groundwater connectivity across space and time has created disparate predictions of energy and nutrient fluxes across headwater networks, hindering predictions of cold-water habitat resilience under climate change scenarios. Recently, annual paired air and water temperature signals have been harnessed to indicate stream water thermal sensitivity and the dominance of deep versus shallow groundwater influence, although the utility of diel air–water temperature signal metrics for hydrologic inference has remained unexplored. Here we analyzed two consecutive years of locally paired, air–water temperature data from 47 headwater stream sites in the Catskill Mountains, New York, USA, and discovered characteristic seasonal patterns in diel temperature signal sinusoid metrics (amplitude ratio, phase lag, and mean ratio) driven by shifts in streamflow generation mechanisms and stream network position. Hydrologic interpretations of observed patterns were supported by stream heat budget model scenarios and additional analysis of paired air–water temperature data from two streams in Shenandoah National Park, Virginia, USA, with well characterized stream-groundwater connectivity. We found that within smaller tributaries, streamflow generation transitions from runoff to groundwater dominance were driven by hillslope drying during seasonal periods of lower precipitation. This was evidenced by significant correlations (p < 0.01) between daily water:air temperature signal amplitudes (non-linear decreases of ∼ 50 %) and derived base-flow index at 22 of the 28 sites, indicating enhanced local groundwater influence on streamflow promotes decoupling of diel air–water temperature signals. Additionally, ratios between daily water:air temperature signal means were lower in tributaries (∼0.68) when compared to main-stem (∼0.8) sites, increasing linearly throughout the observational period. In conceptual stream heat budget models, groundwater inflow had minimal effects on daily phase lags (∼0.2 hr), but increases in fractional groundwater discharge (0–50 %) depressed daily amplitude (∼20 % to 50 %) and mean ratios (∼15 %), supporting the sensitivity of daily metrics to interpreted changes in seasonal groundwater contributions to streamflow. During observational periods (i.e., April through October 2021 and 2022), significant differences (p < 0.01) between tributary and main-stem air–water metrics occurred when base-flow contributions were highest (∼0.93 vs. ∼ 0.68), as sites lower in the network had daily temperature metrics dominated by stream channel thermal inertia, rather than local groundwater connectivity, showing enhanced air–water diel signal coupling during warmer, drier periods. Divergent air temperature coupling across the network was interpreted as being driven by distance from local groundwater source zones, additional lateral groundwater inflows do not contribute a meaningful fraction to channel discharge lower in the network. Given the growing footprint of stream temperature observations, diel air–water temperature signals can provide distributed metrics sensitive to upstream groundwater discharge. Consequently, these metrics can support ongoing efforts by resource managers and researchers seeking to forecast the resilience of cold-water habitat to climate warming and changing precipitation regimes in mountain headwater streams.

New York, Virginia↗

Characterization of sediment transport upstream and downstream from Lake Emory on the Little Tennessee River near Franklin, North Carolina, 2014–15

Federal, State, and local agencies and organizations have expressed concerns regarding the detrimental effects of excessive sediment transport on aquatic resources and endangered species populations in the upper Little Tennessee River and some of its tributaries. In addition, the storage volume of Lake Emory, which is necessary for flood control and power generation, has been depleted by sediment deposition. To help address these concerns, a 2-year study was conducted in the upper Little Tennessee River Basin to characterize the ambient suspended-sediment concentrations and suspended-sediment loads upstream and downstream from Lake Emory in Franklin, North Carolina. The study was conducted by the U.S. Geological Survey in cooperation with Duke Energy. Suspended-sediment samples were collected periodically, and time series of stage and turbidity data were measured from December 2013 to January 2016 upstream and downstream from Lake Emory. The stage data were used to compute time-series streamflow. Suspended-sediment samples, along with time-series streamflow and turbidity data, were used to develop regression models that were used to estimate time-series suspended-sediment concentrations for the 2014 and 2015 calendar years. These concentrations, along with streamflow data, were used to compute suspended-sediment loads. Selected suspended-sediment samples were collected for analysis of particle-size distribution, with emphasis on high-flow events. Bed-load samples were also collected upstream from Lake Emory. The estimated annual suspended-sediment loads (yields) for the upstream site for the 2014 and 2015 calendar years were 27,000 short tons (92 short tons per square mile) and 63,300 short tons (215 short tons per square mile), respectively. The annual suspended-sediment loads (yields) for the downstream site for 2014 and 2015 were 24,200 short tons (75 short tons per square mile) and 94,300 short tons (292 short tons per square mile), respectively. Overall, the suspended-sediment load at the downstream site was about 28,300 short tons greater than the upstream site over the study period. As expected, high-flow events (the top 5 percent of daily mean flows) accounted for the majority of the sediment load; 80 percent at the upstream site and 90 percent at the downstream site. A similar relation between turbidity (the top 5 percent of daily mean turbidity) and high loads was also noted. In general, when instantaneous streamflows at the upstream site exceeded 5,000 cubic feet per second, increased daily loads were computed at the downstream site. During low to moderate flows, estimated suspended-sediment loads were lower at the downstream site when compared to the upstream site, which suggests that sediment deposition may be occurring in the intervening reach during those conditions. During the high-flow events, the estimated suspended-sediment loads were higher at the downstream site; however, it is impossible to say with certainty whether the increase in loading was due to scouring of lake sediment, contributions from the additional source area, model error, or a combination of one or more of these factors. The computed loads for a one-week period (December 24–31, 2015), during which the two largest high-flow events of the study period occurred, were approximately 52 percent of the 2015 annual sediment load (36 percent of 2-year load) at the upstream site and approximately 72 percent of the 2015 annual sediment load (57 percent of 2-year load) at the downstream site. Six bedload samples were collected during three events; two high-flow events and one base-flow event. The contribution of bedload to the total sediment load was determined to be insignificant for sampled flows. In general, streamflows for long-term streamgages in the study area were below normal for the majority of the study period; however, flows during the last 3 months of the study period were above normal, including the extreme events during the last week of the study period.

North Carolina↗

Completion summary for borehole TAN-2312 at Test Area North, Idaho National Laboratory, Idaho

In 2017, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, drilled and constructed borehole TAN-2312 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory in southeast Idaho. The location of borehole TAN-2312 was selected because it was downgradient from TAN and believed to be the outer extent of waste plumes originating from the TAN facility. Borehole TAN-2312 initially was cored to collect continuous geologic data, and then re-drilled to complete construction as a monitor well. The final construction for borehole TAN-2312 required 16- and 10-inch (in.) diameter carbon-steel well casing to 37 and 228 feet below land surface (ft BLS), respectively, and 9.9-in. diameter open-hole completion below the casing to 522 ft BLS. Depth to water is measured near 244 ft BLS. Following construction and data collection, a temporary submersible pump and water-level access line were placed near 340 ft BLS to allow for aquifer testing, for collecting periodic water samples, and for measuring water levels. Borehole TAN-2312 was cored continuously, starting at the first basalt contact (about 37 ft BLS) to a depth of 568 ft BLS. Not including surface sediment (0–37 ft), recovery of basalt and sediment core at borehole TAN-2312 was about 93 percent; however, core recovery from 170 to 568 ft BLS was 100 percent. Based on visual inspection of core and geophysical data, basalt examined from 37 to 568 ft BLS consists of about 32 basalt flows that range from approximately 3 to 87 ft in thickness and 4 sediment layers with a combined thickness of approximately 76 ft. About 2 ft of total sediment was described for the saturated zone, observed from 244 to 568 ft BLS, near 296 and 481 ft BLS. Sediment described for the saturated zone were composed of fine-grained sand and silt with a lesser amount of clay. Basalt texture for borehole TAN-2312 generally was described as aphanitic, phaneritic, and porphyritic. Basalt flows varied from highly fractured to dense with high to low vesiculation. Geophysical and borehole video logs were collected after core drilling and after final construction at borehole TAN-2312. Geophysical logs were examined synergistically with available core material to suggest zones where groundwater flow was anticipated. Natural gamma log measurements were used to assess sediment layer thickness and location. Neutron and gamma-gamma source logs were used to identify fractured areas for aquifer testing. Acoustic televiewer logs, fluid logs, and electromagnetic flow meter results were used to identify fractures and assess groundwater movement when compared against neutron measurements. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement for borehole TAN-2312. After construction of borehole TAN-2312, a single-well aquifer test was completed September 27, 2017, to provide estimates of transmissivity and hydraulic conductivity. Estimates for transmissivity and hydraulic conductivity were 1.51×102 feet squared per day and 0.23 feet per day, respectively. During the 220-minute aquifer test, well TAN-2312 had about 23 ft of measured drawdown at sustained pumping rate of 27.2 gallons per minute. The transmissivity and hydraulic conductivity estimates for well TAN-2312 were lower than the values determined from previous aquifer tests in other wells near Test Area North. Water samples were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for most of the inorganic constituents showed concentrations near background levels for eastern regional groundwater. Water samples for stable isotopes of oxygen, hydrogen, and sulfur indicated some possible influence of irrigation on the water quality. The volatile organic compound data indicated that this well had some minor influence by wastewater disposal practices at Test Area North.

Idaho↗

Survival of bacterial indicators and the functional diversity of native microbial communities in the Floridan aquifer system, south Florida

The Upper Floridan aquifer in the southern region of Florida is a multi-use, regional scale aquifer that is used as a potable water source and as a repository for passively recharged untreated surface waters, and injected treated surface water and wastewater, industrial wastes, including those which contain greenhouse gases (for example, carbon dioxide). The presence of confined zones within the Floridan aquifer that range in salinity from fresh to brackish allow regulatory agencies to permit the injection of these different types of product waters into specific zones without detrimental effects to humans and terrestrial and aquatic ecosystems. The type of recharge that has received the most regulatory attention in south Florida is aquifer storage and recovery (ASR). The treated water, prior to injection and during recovery, must meet primary and secondary drinking water standards. The primary microbiology drinking water standard is total coliforms, which have been shown to be difficult to inactivate below the regulatory standard during the treatment process at some ASR facilities. The inefficient inactivation of this group of indicator bacteria permits their direct injection into the storage zones of the Floridan aquifer. Prior to this study, the inactivation rates for any member of the total coliform group during exposure to native geochemical conditions in groundwater from any zone of the Floridan aquifer had not been derived. Aboveground flow through mesocosms and diffusion chambers were used to quantify the inactivation rates of two bacterial indicators, Escherichia coli and Pseudomonas aeruginosa, during exposure to groundwater from six wells. These wells collect water from two ASR storage zones: the Upper Floridan aquifer (UFA) and Avon Park Permeable Zone (APPZ). Both bacterial strains followed a biphasic inactivation model. The E. coli populations had slower inactivation rates in the UFA (range: 0.217–0.628 per hour (h -1 )) during the first phase of the model than when exposed to groundwater from the APPZ (range: 0.540–0.684 h -1 ). The inactivation rates for the first phase of the models for P. aeruginosa were not significantly different between the UFA (range: 0.144–0.770 h -1 ) and APPZ (range: 0.159–0.772 h -1 ) aquifer zones. The inactivation rates for the second phase of the model for this P. aeruginosa were also similar between UFA (range: 0.003–0.008 h -1 ) and APPZ (0.004–0.005 h -1 ) zones, although significantly slower than the model’s first phase rates for this bacterial species. Geochemical data were used to determine which dissimilatory biogeochemical reactions were most likely to occur under the native conditions in the UFA and APPZ zones using thermodynamics principles to calculate free energy yields and other cell-related energetics data. The biogeochemical processes of acetotrophic and hydrogenotrophic sulfate reduction, methanogenesis and anaerobic oxidation of methane dominated in all six groundwater sites. A high throughput DNA microarray sequencing technology was used to characterize the diversity in the native aquifer bacterial communities (bacteria and archaea) and assign putative physiological capabilities to the members of those communities. The bacterial communities in both zones of the aquifer were shown to possess the capabilities for primary and secondary fermentation, acetogenesis, methanogenesis, anaerobic methane oxidation, syntrophy with methanogens, ammonification, and sulfate reduction. The data from this study provide the first determination of bacterial indicator survival during exposure to native geochemical conditions of the Floridan aquifer in south Florida. Additionally, the energetics and functional bacterial diversity characterizations are the first descriptions of native bacterial communities in this region of the Floridan aquifer and reveal how these communities persist under such extreme conditions. Collectively, these types of data can be used to develop and refine groundwater models.

Florida↗

Capacity assessment for Earth Monitoring, Analysis, and Prediction (EarthMAP) and future integrated monitoring and predictive science at the U.S. Geological Survey

Executive Summary Managers of our Nation’s resources face unprecedented challenges driven by the convergence of increasing, competing societal demands and a changing climate that affects the stability, vulnerability, and predictability of those resources. To help meet these challenges, the scientific community must take advantage of all available technologies, data, and integrative Earth systems modeling capacity to better inform resource and risk management decisions. This is the overarching goal of the U.S. Geological Survey (USGS) Earth Monitoring, Analysis, and Prediction (EarthMAP) vision: “By 2030, the USGS will deliver well integrated observations and predictions of the future state of natural systems—water, ecosystems, energy, minerals, hazards—at regional and national scales, working primarily with federal, state, and academic partners to develop and operate the capability” (U.S. Geological Survey, 2021). Providing more integrated Earth systems science and actionable information to decision makers, stakeholders, and the public requires a better understanding of the depth and distribution of existing capacity (capabilities, tools, and techniques) across the Bureau. Identifying existing capacity is also a critical first step toward gap analysis and targeted investments to increase capacity over time. The USGS formed a Capacity Assessment Team (CAT) and charged it with (1) conducting a Request for Information (RFI) to identify existing USGS expertise and activities supportive of integrated and predictive science to inform decision making, (2) developing a strategy and proof-of-concept for a continuously updated capacity assessment capability, and (3) identifying lessons learned to inform development of best practices for future capacity assessment efforts. The RFI took the form of a survey, with content guided by the science and technology needs identified in a USGS report titled “Grand Challenges for Integrated U.S. Geological Survey Science—A Workshop Report” (Jenni and others, 2017). The 44-question survey provided respondents the ability to rate their level of experience with a suite of priority disciplines, analysis and modeling approaches, technologies, and stakeholder engagement strategies and to enter optional narrative text for supporting context. An introductory portion focused on general science capacity assessment, followed by three sections targeting capabilities related to the foundational components of EarthMAP: (1) data and information integration, (2) integrated predictive science, and (3) actionable information. The survey results provided a high-level snapshot of USGS capacity in the targeted areas. Respondents (1,035 individuals) represented approximately 13 percent of the USGS across all mission areas and regions. Seventy-four percent of the respondents held a science-focused position title and the remainder had position titles in information technology, computer science, management, administrative, or other (contractors, volunteers, emeritus, and unknown). To provide greater insight into respondent capabilities and activities, information from the U.S. Department of the Interior and USGS enterprise information systems were used to further characterize topical expertise and organizational associations of survey respondents. To address the ongoing need to assess the Bureau’s capacity to address integrated predictive science priorities, the CAT developed a software-based proof-of-concept called the Integrated Science Assessment Information Database (iSAID) for assembling various information sources together toward making the full extent of USGS capabilities and scientific assets available for routine capacity assessment. This proof-of-concept is intended to serve as a catalyst for further development. The process of implementing the EarthMAP capacity assessment survey, analyzing survey responses, and developing the proof-of-concept resulted in lessons learned, findings, and recommendations. Example scenarios throughout the report demonstrate how capacity assessment data can inform science planning. Three overarching findings and recommendations are: (1) Finding: Capacity is limited in some critical disciplines, skills, and technology applications, but “sufficient” depends on the question and the need relative to availability at a given point in time. Recommendation: Develop an on-demand capacity assessment framework that enables rapid identification and evaluation of existing and available expertise to support decision needs as they arise. (2) Finding: Institutional barriers and lack of awareness constrain the ability of USGS staff to adopt new technologies, collaborate across administrative boundaries, and deliver actionable information to stakeholders in a timely manner. However, these barriers are not universally experienced. Recommendation: Pursue more targeted inquiries to clarify which institutional barriers are obstructing the adoption of new technologies and approaches or the sharing of expertise and equipment across organizational and regional boundaries. These inquiries should inform USGS leadership, mission areas, and regions whether policies can be revised or whether a lack of understanding is creating perceived obstacles. Highlight cases when staff have successfully adopted new technologies and approaches to advance EarthMAP priorities and provide actionable information in a timely manner to spread awareness of how perceived obstacles can be navigated and overcome when appropriate. (3) Finding: Examples of people and projects integrating across disciplines and scales and applying advanced approaches to meet complex stakeholder needs exist. Such examples provide transfer value across the spectrum from approach to decision making. Many projects, already underway, appear to meet elements of the EarthMAP vision, and the USGS has people who can provide leadership in multiple types of specific integrated science efforts. Recommendation: Use these findings as a starting point for near-term strategic planning for integrated science. Highlight, incentivize, and build on existing interdisciplinary predictive science and information delivery activities across the USGS to advance toward further realization of an EarthMAP capacity. The CAT efforts to develop and assess existing USGS capacity to advance the EarthMAP vision revealed a fundamental challenge for not only this effort but any effort to assess existing capacity: A considerable amount of thought, time, and effort is required to survey and assess capabilities and tools available to support a given need, yet best results are still likely to provide an incomplete assessment. To better meet the frequent need to assess capabilities, tools, products, and projects that address an expressed strategic priority, the CAT proposes the concept of an on-demand capacity assessment framework supported by a software package that dynamically pulls and integrates information from existing USGS information systems and public domain registries. Although existing USGS enterprise information systems currently lack the structure, cross-system consistency, interoperability, and stability to support a continuously updated capacity assessment capability, we identify reasonable near-term steps to improve the utility of information gathered on expertise and project capacity and to improve the consistency and completeness of information and the ability of USGS systems to share that information. The ability to search and characterize this information will make future assessments of capacity faster, more complete, more efficient, and more targeted. This approach would grow the Bureau’s capacity knowledge over time, iteratively improving the ability to access, leverage, and synthesize existing capabilities and assets as well as identify and fill critical gaps. The greatest promise for developing integrated science could lie in linking across existing projects and expertise to create a multi-project capacity for addressing large, complex environmental issues.

Open-File Report↗

Assessment of thermal maturity trends in Devonian-Mississippian source rocks using Raman spectroscopy: Limitations of peak-fitting method

The thermal maturity of shale is often measured by vitrinite reflectance (VRo). VRo measurements for the Devonian–Mississippian black shale source rocks evaluated herein predicted thermal immaturity in areas where associated reservoir rocks are oil-producing. This limitation of the VRo method led to the current evaluation of Raman spectroscopy as a suitable alternative for developing correlations between thermal maturity and Raman spectra. In this study, Raman spectra of Devonian–Mississippian black shale source rocks were regressed against measured VRo or sample-depth. Attempts were made to develop quantitative correlations of thermal maturity. Using sample-depth as a proxy for thermal maturity is not without limitations as thermal maturity as a function of depth depends on thermal gradient, which can vary through time, subsidence rate, uplift, lack of uplift, and faulting. Correlations between Raman data and vitrinite reflectance or sample-depth were quantified by peak-fitting the spectra. Various peak-fitting procedures were evaluated to determine the effects of the number of peaks and maximum peak widths on correlations between spectral metrics and thermal maturity. Correlations between D-frequency, G-band full width at half maximum (FWHM), and band separation between the G- and D-peaks and thermal maturity provided some degree of linearity throughout most peak-fitting assessments; however, these correlations and those calculated from the G-frequency, D/G FWHM ratio, and D/G peak area ratio also revealed a strong dependence on peak-fitting processes. This dependency on spectral analysis techniques raises questions about the validity of peak-fitting, particularly given the amount of subjective analyst involvement necessary to reconstruct spectra. This research shows how user interpretation and extrapolation affected the comparability of different samples, the accuracy of generated trends, and therefore, the potential of the Raman spectral method to become an industry benchmark as a thermal maturity probe. A Raman method devoid of extensive operator interaction and data manipulation is quintessential for creating a standard method.

Frontiers in Energy Research↗

The U.S. Geological Survey Ecosystem Science Strategy, 2012-2022 - Advancing discovery and application through collaboration

Ecosystem science is critical to making informed decisions about natural resources that can sustain our Nation’s economic and environmental well-being. Resource managers and policy-makers are faced with countless decisions each year at local, state, tribal, territorial, and national levels on issues as diverse as renewable and non-renewable energy development, agriculture, forestry, water supply, and resource allocations at the urban-rural interface. The urgency for sound decision-making is increasing dramatically as the world is being transformed at an unprecedented pace and in uncertain directions. Environmental changes are associated with natural hazards, greenhouse gas emissions, and increasing demands for water, land, food, energy, mineral, and living resources. At risk is the Nation’s environmental capital, the goods and services provided by resilient ecosystems that are vital to the health and well-being of human societies. Ecosystem science—the study of systems of organisms interacting with their environment and the consequences of natural and human-induced change on these systems—is necessary to inform decision-makers as they develop policies to adapt to these changes. This Ecosystems Science Strategy is built on a framework that includes basic and applied science. It highlights the critical roles that USGS scientists and partners can play in building scientific understanding and providing timely information to decision-makers. The strategy underscores the connection between scientific discoveries and the application of new knowledge. The strategy integrates ecosystem science and decision-making, producing new scientific outcomes to assist resource managers and providing public benefits. The USGS is uniquely positioned to play an important role in ecosystem science. With its wide range of expertise, the agency can bring holistic, cross-scale, interdisciplinary capabilities to the design and conduct of monitoring, research, and modeling and to new technologies for data collection, management, and visualization. Collectively, these capabilities can be used to reveal ecological patterns and processes, explain how and why ecosystems change, and forecast change over different spatial and temporal scales. USGS science can provide managers with options and decision-support tools to use resources sustainably. The USGS has long-standing, collaborative relationships with the DOI and other partners in the natural sciences, in both conducting science and its application. The USGS engages these partners in cooperative investigations that otherwise would lack the necessary support or be too expensive for a single bureau to conduct. The heart of this strategy is a framework and vision for USGS ecosystems science that focuses on five long-term goals, which are seen as interconnected and reinforcing components: • Improve understanding of ecosystem structure, function, and processes. The focus for this goal is an understanding of how ecosystems work, including the dynamics of species, their populations, interactions, and genetics, and how they change across spatial and temporal scales. • Advance understanding of how drivers influence ecosystem change. The challenges here are explaining the drivers of ecosystem change, their spatio-temporal patterns, their uncertainties and interactions, and their influence on ecosystem processes and dynamics. • Improve understanding of the services that ecosystems provide to society. Here the emphasis is on the measurement of environmental capital and ecosystem services, and the identification of sources and patterns of change in space and time. • Develop tools, technologies, and capacities to inform decision-making about ecosystems. This includes developing new technologies and approaches for conducting applications-oriented ecosystem science. A principal challenge will be how to quantify uncertainty and incorporate it in decision analysis. • Apply science to enhance strategies for management, conservation, and restoration of ecosystems. These challenges include development of novel approaches to monitoring, assessment, and restoration of ecosystems; new methods to address species of concern and communities at risk; and innovations in decision analysis and support to address imminent ecosystem changes or those that are underway. Closely integrated with the five goals are four strategic approaches that provide the path forward for the USGS Ecosystems Mission Area. These approaches cross-cut all of the goals and are seen as essential to the implementation of this strategy: • Assess information needs for ecosystem science through enhanced partnerships. Work with the DOI and other agencies and institutions to identify, design, and implement priority decision-driven ecological research. • Promote the use of interdisciplinary ecosystem science. Design and conduct interdisciplinary process-oriented research in ecosystem science. • Enhance modeling and forecasting. Build models to forecast ecosystem change, assess future management scenarios, and reduce uncertainties through an adaptive learning process. • Support decision-making. Use quantitative approaches to assess the vulnerabilities of ecosystems, habitats, and species, and evaluate strategies for adaptation, restoration, and sustainable management. Following the strategic approaches are a set of proposed actions that represent a sampling of specific activities that align with this strategy and that address the Nation’s most pressing environmental needs. The strategy emphasizes coordination of activities across the USGS mission areas pursuant to these goals. Ecosystem science is inherently interdisciplinary and requires a broad perspective that incorporates the biological and physical sciences, climate science, information technology, and scientific capacity in mission areas across the Bureau. With its emphasis on coordination, this strategy can provide a critical underpinning for integrated science efforts with scientists from multiple mission areas of the USGS working together. Of course, the USGS will continue to conduct both discipline-specific and interdisciplinary investigations, and both will continue to be vital parts of the ecosystem science portfolio. Finally, the strategy stresses the importance of coordination with other Federal agencies and organizations in the natural resources community. The USGS collaborates with resource agencies in the DOI and other organizations throughout the world to meet societal needs for species and ecosystem management. Working with these agencies and organizations, the USGS will play a key role over the next decade in advancing the scientific foundation for sustaining the natural resources that diverse, productive, resilient ecosystems provide.

Open-File Report↗

Evapotranspiration Rates of Riparian Forests, Platte River, Nebraska, 2002-06

Evapotranspiration (ET) in riparian areas is a poorly understood component of the regional water balance in the Platte River Basin, where competing demands have resulted in water shortages in the ground-water/surface-water system. From April 2002 through March 2006, the U.S. Geological Survey, Nebraska Platte River Cooperative Hydrology Study Group, and Central Platte Natural Resources District conducted a micrometeorological study of water and energy balances at two sites in central Nebraska near Odessa and Gothenburg to improve understanding of ET rates and factors affecting them in Platte River riparian forests. A secondary objective of the study was to constrain estimates of ground-water use by riparian vegetation to satisfy ET consumptive demands, a useful input to regional ground-water flow models. Both study sites are located on large islands within the Platte River characterized by a cottonwood-dominated forest canopy on primarily sandy alluvium. Although both sites are typical of riparian forests along the Platte River in Nebraska, the Odessa understory is dominated by deciduous shrubs, whereas the Gothenburg understory is dominated by eastern redcedars. Additionally, seasonal ground-water levels fluctuated more at Odessa than at Gothenburg. The study period of April 2002 through March 2006 encompassed precipitation conditions ranging from dry to wet. This study characterized the components of the water balance in the riparian zone of each site. ET was evaluated from eddy-covariance sensors installed on towers above the forest canopy at a height of 26.1 meters. Precipitation was measured both above and below the forest canopy. A series of sensors measured soil-moisture availability within the unsaturated zone in two different vertical profiles at each site. Changes in ground-water altitude were evaluated from piezometers. The areal footprint represented in the water balance extended up to 800 meters from each tower. During the study, ET was less variable than precipitation. Annual ET fluctuated about 7 percent from the 4-year mean, ranging from about 514 to 586 millimeters per year (551 on average) at the Odessa site and 535 to 616 millimeters per year (575 on average) at the Gothenburg site. Conversely, annual precipitation fluctuated by about 35 percent from the 4-year mean, ranging from 429 to 844 millimeters per year at Odessa and 359 to 791 millimeters per year at Gothenburg. Of this precipitation, 14 to 15 percent was intercepted by the forest canopy before it could infiltrate into the soil. For the 4-year period, annual ground-water recharge from the riparian measurement zone averaged 76 and 13 millimeters at Odessa and Gothenburg, respectively, to satisfy the water balance at each site. This indicates that, from an annual perspective, ground-water reductions caused by ET may be minimal. This effect varied somewhat and primarily was affected by fluctuations in precipitation. Ground-water discharge occurred during the driest study year (2002), whereas ground-water recharge occurred from 2003 to 2005. These results do not exclude ground water as an important source of water to riparian vegetation - especially to phreatophytes that have the capability of directly using water from the saturated zone - during periods of high ET in the summer, particularly during periods of lower than normal precipitation. However, the calculations indicate that, on an annual (or longer) net-flux basis, ground-water use by riparian forests is likely to be balanced by periods of recharge from excess precipitation at other times of the year. In contrast to more arid settings, where scientific literature indicates that ground water may supply a large fraction of the water used for ET by riparian vegetation, precipitation along the Platte River of Nebraska was great enough - and generally greater than ET - that most or all of the annual ET demand was satisfied by available precipitation. Crop coefficients developed for 15-

Scientific Investigations Report↗

California deepwater investigations and groundtruthing (Cal DIG) I: Fault and shallow geohazard analysis offshore Morro Bay

The California Deepwater Investigations and Groundtruthing (Cal DIG) I project focuses on the potential seafloor hazards and impacts of alternative energy infrastructure in the outer continental shelf region offshore of south-central California. This is one of three reports covering a single study area located between Monterey and Point Conception, California in federal waters outside of the State of California three nautical mile limit and in water depths of 400 to 1500 meters. The goal of this report is to provide baseline geologic interpretations of the area for the purpose of improving regional models of shallow geologic hazards and sedimentary processes. Geophysical and geological data from this project will help to address important issues associated with marine spatial planning and potential offshore infrastructure development, such as offshore floating wind turbines. Datasets covered in this report include comprehensive high-resolution sub-bottom (multi-channel and Chirp seismic reflection profiles), seafloor (bathymetry), and sampling (piston, gravity, and vibracore) data collected in 2018-2019 during a series of seven seagoing geological and geophysical surveys. Specifically, this report outlines interpretation of subsurface geologic structure from the geophysical data, details preliminary core analysis results related to fluid, gas, and sediment transport activity, provides interpretations of the current geohazards in the area, and suggests next steps for improving interpretations of geohazard processes. Specific targets of geohazard interest in the study area are geological structures such as faults and folds, seafloor pockmarks within a large field (the Big Sur pockmark field), submarine channels, and mass wasting (slope failure) features. The vast majority of faults and other structures in the study occur within sediment and rock formations we interpret to be pre-Quaternary (older than 2.58 Myr BP), and thus we interpret that these structures are unlikely to present significant current hazard to seabed infrastructure, although we note that the numerous structures mapped in the study area may have the potential to become reactivated. Similarly, we find no new evidence of Holocene (younger than 11,650 years BP) fluid or gas advection in the Big Sur pockmark field. However, such fluid and gas hazards are currently difficult to assess, as additional analyses and sampling of existing core data is needed to better understand pockmark formation processes and potential gas accumulations we have mapped in the subsurface. Mass wasting along the eastern and western edges of the Santa Lucia Bank during earthquakes, as well as sediment transport down the Lucia Chica and San Simeon channels, are among the most significant, although still likely infrequent during the Holocene, hazards to seabed stability in the study area. Further analyses of the existing cores, including radiocarbon dating, stable isotope, and compositional analyses, are again needed to better understand the timing and sources of the numerous sand deposits found throughout the study area, which may have been transported downslope due to mass wasting and/or earthquake shaking processes.

California↗

Annotated bibliography of scientific research relevant to oil and gas reclamation best management practices in the western United States, published from 1969 through 2020

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey has created a series of annotated bibliographies on topics of management concern for lands in the western United States (U.S.). Oil and gas development on public lands is a long-standing and substantial component of local and regional economies and has expanded in recent decades, particularly on public lands in the western U.S. This development is associated with extensive networks of pipelines, roads, and processing facilities, across which reclamation is Federally mandated following initial well pad development (“interim” reclamation) and once resource extraction is complete (“final” reclamation). Reclamation is critical for recovering ecological services to energy-affected lands, including vegetation productivity, wildlife habitat, water and air quality, and soil stability (for example, resistance to wind and water erosion). However, reclamation of oil and gas affected lands in the western U.S. has proved challenging due to an array of regulatory and environmental factors, such as minimally developed soils, short growing seasons, herbivory, high winds, invasive species, rugged terrain, and in particular, arid climates associated with low total precipitation, high evapotranspiration rates, and highly variable precipitation patterns. We compiled and summarized journal articles, government reports, technical reports, proceedings, and theses and dissertations relevant to oil and gas reclamation. We constrained our search to products published on or before December 31, 2020 but did not limit our search by a starting date; the earliest product resulting from this effort was published in March 1969. Second, we manually scanned the last 15 years (2005-2020) of tables of contents in journals, bibliographies, and proceedings of which we were aware would contain articles highly relevant to this bibliography. We carried out the search for these products through multiple means: (1) performing a structured search of two reference databases, (2) examining articles published since 2005 in highly relevant scientific journals and conference proceedings, and (3) reviewing additional material suggested by authors of products identified in steps 1 and 2. Our search was intentionally broad in order to identify as much relevant work as possible, much of which is professionally applied and tested within the industry of oil and gas reclamation, but which remains unpublished in scientific journals. We refined the initial list of products by removing: (1) duplicates, (2) products not written in English, (3) products that were not relevant to the arid ecosystems of western North America, (4) products that were not released as research, data products, or review articles in journals or as formal scientific reports, and (5) products with data which were not relevant to reclamation of oil and gas-affected lands, or for which the study did not present new data, findings, or syntheses relevant to reclamation of oil and gas-affected lands. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and assigned standardized management topics to each. Management topics are intended to aid online searching within the bibliography and are described in more detail in the Methods Section of this report; they include what type of disturbance the product addresses (well pads, mining, pipelines), what aspect of oil and gas reclamation they pertain to (practices, standards, monitoring), what type of data are present in the product (for instance soil or vegetation recovery data), and an indication if the product were from a source other than a published, peer-reviewed outlet (such as dissertations or unpublished professional reports – these are identified as grey literature). The review process for this annotated bibliography included an initial internal colleague review of each summary, requesting input on each summary from an author of the original product, and a formal peer-review. Our initial searches resulted in 3,197 total products, of which 290 met our criteria for inclusion. “Reclamation Practices” is by far the management topic most addressed, followed by “Reclamation Monitoring,” for example, products assessing what and how monitoring methods are used to track and measure reclamation outcome. This document may be accessed at https://doi.org/10.3133/ofr20231068 or from the U.S. Geological Survey Publication Warehouse ( https://pubs.usgs.gov/ ). The 1-page product summaries herein will also be used to create a bibliography at https://apps.usgs.gov/science-for-resource-managers that includes links to each original product, where available, and in which subject matter will be searchable by topic, location, and year. The studies compiled and summarized here may inform planning and management actions that seek to reclaim landscapes across the western U.S. which have been affected by oil and gas development.

Open-File Report↗

U.S. Geological Survey ecosystems science strategy—Advancing discovery and application through collaboration

Executive Summary Ecosystem science is critical to making informed decisions about natural resources that can sustain our Nation’s economic and environmental well-being. Resource managers and policymakers are faced with countless decisions each year at local, regional, and national levels on issues as diverse as renewable and nonrenewable energy development, agriculture, forestry, water supply, and resource allocations at the urban-rural interface. The urgency for sound decisionmaking is increasing dramatically as the world is being transformed at an unprecedented pace and in uncertain directions. Environmental changes are associated with natural hazards, greenhouse gas emissions, and increasing demands for water, land, food, energy, mineral, and living resources. At risk is the Nation’s environmental capital, the goods and services provided by resilient ecosystems that are vital to the health and wellbeing of human societies. Ecosystem science—the study of systems of organisms interacting with their environment and the consequences of natural and human-induced change on these systems—is necessary to inform decisionmakers as they develop policies to adapt to these changes. This Ecosystems Science Strategy is built on a framework that includes basic and applied science. It highlights the critical roles that U.S. Geological Survey (USGS) scientists and partners can play in building scientific understanding and providing timely information to decisionmakers. The strategy underscores the connection between scientific discoveries and the application of new knowledge, and it integrates ecosystem science and decisionmaking, producing new scientific outcomes to assist resource managers and providing public benefits. We envision the USGS as a leader in integrating scientific information into decisionmaking processes that affect the Nation’s natural resources and human well-being. The USGS is uniquely positioned to play a pivotal role in ecosystem science. With its wide range of expertise, the Bureau can bring holistic, cross-scale, interdisciplinary capabilities to the design and conduct of monitoring, research, and modeling and to new technologies for data collection, management, and visualization. Collectively, these capabilities can be used to reveal ecological patterns and processes, explain how and why ecosystems change, and forecast change over different spatial and temporal scales. USGS science can provide managers with options and decision-support tools to use resources sustainably. The USGS has long-standing, collaborative relationships with the Department of the Interior (DOI) and other partners in the natural sciences, in both conducting science and applying the results. The USGS engages these partners in cooperative investigations that otherwise would lack the necessary support or be too expensive for a single bureau to conduct. The heart of this strategy is a framework for USGS ecosystems science that focuses on five long-term goals, which are seen as interconnected components that reinforce our vision of the USGS providing science that is at the forefront of decisionmaking: Improve understanding of ecosystem structure, function, and processes. The focus for this goal is an understanding of how ecosystems work, including the dynamics of species, their populations, interactions, and genetics, and how they change across spatial and temporal scales. Advance understanding of how drivers influence ecosystem change. The challenges here are explaining the drivers of ecosystem change, their spatio-temporal patterns, their uncertainties and interactions, and their influence on ecosystem processes and dynamics. Improve understanding of the services that ecosystems provide to society. Here the emphasis is on the measurement of environmental capital and ecosystem services, and the identification of sources and patterns of change in space and time. Develop tools, technologies, and capacities to inform decisionmaking about ecosystems. This includes developing new technologies and approaches for conducting applications-oriented ecosystem science. A principal challenge will be how to quantify uncertainty and incorporate it in decision analysis. Apply science to enhance strategies for management, conservation, and restoration of ecosystems. These challenges include development of novel approaches to monitoring, assessment, and restoration of ecosystems; new methods to address species of concern and communities at risk; and innovations in decision analysis and support to address imminent ecosystem changes or those that are underway. Closely integrated with the five goals are four strategic approaches that provide the path forward for the USGS Ecosystems Mission Area. These approaches cross-cut all of the goals and are seen as essential to the implementation of this strategy: Assess information needs for ecosystem science through enhanced partnerships. Work with the DOI and other agencies and institutions to identify, design, and implement priority decision-driven ecological research. Promote the use of interdisciplinary ecosystem science. Design and conduct interdisciplinary process-oriented research in ecosystem science. Enhance modeling and forecasting. Build models to forecast ecosystem change, assess future management scenarios, and reduce uncertainties through an adaptive learning process. Support decisionmaking. Use quantitative approaches to assess the vulnerabilities of ecosystems, habitats, and species, and evaluate strategies for adaptation, restoration, and sustainable management. Following the four strategic approaches are a set of proposed actions that represent a sampling of specific USGS activities that align with this strategy and that address the Nation’s most pressing environmental needs. The strategy emphasizes coordination of activities across the USGS mission areas pursuant to these goals. Ecosystem science is inherently interdisciplinary and requires a broad perspective that incorporates the biological and physical sciences, climate science, information technology, and scientific capacity in mission areas across the Bureau. With its emphasis on coordination, this strategy can provide a critical underpinning for integrated science efforts with scientists from multiple mission areas of the USGS working together. Of course, the USGS will continue to conduct discipline-specific and interdisciplinary investigations, and both will continue to be vital parts of the ecosystem science portfolio. Finally, the strategy stresses the importance of coordination with other Federal agencies and organizations in the natural resources community. The USGS collaborates with resource agencies in the DOI and other organizations throughout the world to meet societal needs for species and ecosystem management. Working with these agencies and organizations, the USGS will play a key role in guiding sound decisionmaking during the next decade by advancing the scientific foundation for sustaining the natural resources that diverse, productive, resilient ecosystems provide.

Circular↗

Large-scale dam removal on the Elwha River, Washington, USA: source-to-sink sediment budget and synthesis

Understanding landscape responses to sediment supply changes constitutes a fundamental part of many problems in geomorphology, but opportunities to study such processes at field scales are rare. The phased removal of two large dams on the Elwha River, Washington, exposed 21 &plusmn; 3 million m 3 , or ~ 30 million tonnes (t), of sediment that had been deposited in the two former reservoirs, allowing a comprehensive investigation of watershed and coastal responses to a substantial increase in sediment supply. Here we provide a source-to-sink sediment budget of this sediment release during the first two years of the project (September 2011&ndash;September 2013) and synthesize the geomorphic changes that occurred to downstream fluvial and coastal landforms. Owing to the phased removal of each dam, the release of sediment to the river was a function of the amount of dam structure removed, the progradation of reservoir delta sediments, exposure of more cohesive lakebed sediment, and the hydrologic conditions of the river. The greatest downstream geomorphic effects were observed after water bodies of both reservoirs were fully drained and fine (silt and clay) and coarse (sand and gravel) sediments were spilling past the former dam sites. After both dams were spilling fine and coarse sediments, river suspended-sediment concentrations were commonly several thousand mg/L with ~ 50% sand during moderate and high river flow. At the same time, a sand and gravel sediment wave dispersed down the river channel, filling channel pools and floodplain channels, aggrading much of the river channel by ~ 1 m, reducing river channel sediment grain sizes by ~ 16-fold, and depositing ~ 2.2 million m 3 of sand and gravel on the seafloor offshore of the river mouth. The total sediment budget during the first two years revealed that the vast majority (~ 90%) of the sediment released from the former reservoirs to the river passed through the fluvial system and was discharged to the coastal waters, where slightly less than half of the sediment was deposited in the river-mouth delta. Although most of the measured fluvial and coastal deposition was sand-sized and coarser (> 0.063 mm), significant mud deposition was observed in and around the mainstem river channel and on the seafloor. Woody debris, ranging from millimeter-size particles to old-growth trees and stumps, was also introduced to fluvial and coastal landforms during the dam removals. At the end of our two-year study, Elwha Dam was completely removed, Glines Canyon Dam had been 75% removed (full removal was completed 2014), and ~ 65% of the combined reservoir sediment masses&mdash;including ~ 8 Mt of fine-grained and ~ 12 Mt of coarse-grained sediment&mdash;remained within the former reservoirs. Reservoir sediment will continue to be released to the Elwha River following our two-year study owing to a ~ 16 m base level drop during the final removal of Glines Canyon Dam and to erosion from floods with larger magnitudes than occurred during our study. Comparisons with a geomorphic synthesis of small dam removals suggest that the rate of sediment erosion as a percent of storage was greater in the Elwha River during the first two years of the project than in the other systems. Comparisons with other Pacific Northwest dam removals suggest that these steep, high-energy rivers have enough stream power to export volumes of sediment deposited over several decades in only months to a few years. These results should assist with predicting and characterizing landscape responses to future dam removals and other perturbations to fluvial and coastal sediment budgets.

Washington↗

Extraction of hydrocarbons from high-maturity Marcellus Shale using supercritical carbon dioxide

Shale is now commonly exploited as a hydrocarbon resource. Due to the high degree of geochemical and petrophysical heterogeneity both between shale reservoirs and within a single reservoir, there is a growing need to find more efficient methods of extracting petroleum compounds (crude oil, natural gas, bitumen) from potential source rocks. In this study, supercritical carbon dioxide (CO 2 ) was used to extract n -aliphatic hydrocarbons from ground samples of Marcellus shale. Samples were collected from vertically drilled wells in central and western Pennsylvania, USA, with total organic carbon (TOC) content ranging from 1.5 to 6.2 wt %. Extraction temperature and pressure conditions (80°C and 21.7 MPa, respectively) were chosen to represent approximate in situ reservoir conditions at sample depth (1920–2280 m). Hydrocarbon yield was evaluated as a function of sample matrix particle size (sieve size) over the following size ranges: 1000–500 μm, 250–125 μm, and 63–25 μm. Several methods of shale characterization including Rock-Eval II pyrolysis, organic petrography, Brunauer–Emmett–Teller surface area, and X-ray diffraction analyses were also performed to better understand potential controls on extraction yields. Despite high sample thermal maturity, results show that supercritical CO 2 can liberate diesel-range ( n -C 11 through n -C 21 ) n -aliphatic hydrocarbons. The total quantity of extracted, resolvable n -aliphatic hydrocarbons ranges from approximately 0.3 to 12 mg of hydrocarbon per gram of TOC. Sieve size does have an effect on extraction yield, with highest recovery from the 250–125 μm size fraction. However, the significance of this effect is limited, likely due to the low size ranges of the extracted shale particles. Additional trends in hydrocarbon yield are observed among all samples, regardless of sieve size: 1) yield increases as a function of specific surface area ( r 2 = 0.78); and 2) both yield and surface area increase with increasing TOC content ( r 2 = 0.97 and 0.86, respectively). Given that supercritical CO 2 is able to mobilize residual organic matter present in overmature shales, this study contributes to a better understanding of the extent and potential factors affecting the extraction process.

Pennsylvania↗