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At least 1,063 records · Page 59Linked to original sources

Pliocene-climate history of the western United States derived from lacustrine ostracodes

Pliocene sediments from several sites in western North America contain ostracodes indicating deposition in lacustrine and wetland settings. The ostracodes offer a means of reconstructing the aquatic paleoenvironment. Because water temperature, chemistry, and lake volume are coupled to climate, reconstruction of these parameters provides a direct insight into Pliocene climate. The site ages were determined from tephrochronology, paleomagnetics, and associated mammals. The morphology of many ostracode species also provides direct information about the paleoenvironment in which they lived. During the Pliocene (about 3.5-2.5 Ma) some species have unusually ornate carapace morphology indicative of large geologically stable lakes, which must have required a stable climate to sustain them. North American Pliocene climate changed from a modern-like state 4.5-3.5 Ma to a period with greater precipitation and less evaporation than today, 3.5-2.5 Ma. This wetter period, inferred from the large geologically long-lived lakes, implies a stable atmospheric circulation pattern. The stable circulation pattern collapsed around 2.5 Ma and climate returned to a modern-like situation.

western United States↗

Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream

The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by ~30% and is accompanied by net loss of channel discharge and extensive surface–subsurface exchange. The corresponding net NO3− uptake length is 37 ± 13 km (42 ± 12 km when normalized to the conservative solute Cl−), and the areal NO3− uptake rate is 0.5 μmol m−2 s−1. The observed reduction in [NO3−] along the reach results from one or more internal sinks, not dilution by ground water, hill-slope water, or other water inputs. Observed reductions in [NO3−] and channel discharge along the experimental reach result in a net loss of 200–400 kg/d of NO3−-N, ~50% of the input load. High-resolution (temporal and spatial) sampling indicates that most of the NO3− loss occurs along the lower part of the reach, where there is the greatest seepage loss and surface–subsurface exchange of water. Stable isotopes of NO3−, total dissolved P concentrations, and streambed chemical profiles suggest that denitrification is the most significant NO3− sink along the reach. Denitrification efficiency, as expressed through downstream enrichment in 15N-NO3−, varies considerably during the water year. When discharge is greater (typically earlier in the water year), denitrification is least efficient and downstream enrichment in 15N-NO3− is greatest. When discharge is lower, denitrification in the streambed appears to occur with greater efficiency, resulting in lower downstream enrichment in 15N-NO3−.

California↗

Groundwater environmental tracer data collected from the Chicot, Evangeline, and Jasper aquifers in Montgomery County and adjacent counties, Texas, 2008

The Gulf Coast aquifer system is the primary water supply for Montgomery County in southeastern Texas, including part of the Houston metropolitan area and the cities of Magnolia, Conroe, and The Woodlands Township, Texas. The U.S. Geological Survey, in cooperation with the Lone Star Groundwater Conservation District, collected environmental tracer data in the Gulf Coast aquifer system, primarily in Montgomery County. Forty existing groundwater wells screened in the Gulf Coast aquifer system were selected for sampling in Montgomery County (38 wells), Waller County (1 well), and Walker County (1 well). Groundwater-quality samples, physicochemical properties, and water-level data were collected once from each of the 40 wells during March-September 2008. Groundwater-quality samples were analyzed for dissolved gases and the environmental tracers sulfur hexafluoride, chlorofluorocarbons, tritium, helium-4, and helium-3/tritium. Water samples were collected and processed onsite using methods designed to minimize changes to the water-sample chemistry or contamination from the atmosphere. Replicate samples for quality assurance and quality control were collected with each environmental sample. Well-construction information and environmental tracer data for March-September 2008 are presented.

Montgomery, Texas↗

Understanding processes affecting mineral deposits in humid environments

Recent interdisciplinary studies by the U.S. Geological Survey have resulted in substantial progress toward understanding the influence that climate and hydrology have on the geochemical signatures of mineral deposits and the resulting mine wastes in the eastern United States. Specific areas of focus include the release, transport, and fate of acid, metals, and associated elements from inactive mines in temperate coastal areas and of metals from unmined mineral deposits in tropical to subtropical areas; the influence of climate, geology, and hydrology on remediation options for abandoned mines; and the application of radiogenic isotopes to uniquely apportion source contributions that distinguish natural from mining sources and extent of metal transport. The environmental effects of abandoned mines and unmined mineral deposits result from a complex interaction of a variety of chemical and physical factors. These include the geology of the mineral deposit, the hydrologic setting of the mineral deposit and associated mine wastes, the chemistry of waters interacting with the deposit and associated waste material, the engineering of a mine as it relates to the reactivity of mine wastes, and climate, which affects such factors as temperature and the amounts of precipitation and evapotranspiration; these factors, in turn, influence the environmental behavior of mineral deposits. The role of climate is becoming increasingly important in environmental investigations of mineral deposits because of the growing concerns about climate change.

Fact Sheet↗

Monitoring the southwestern Wyoming landscape—A foundation for management and science

Natural resource monitoring involves repeated collections of resource condition data and analyses to detect possible changes and identify underlying causes of changes. For natural resource agencies, monitoring provides the foundation for management and science. Specifically, analyses of monitoring data allow managers to better understand effects of land-use and other changes on important natural resources and to achieve their conservation and management goals. Examples of natural resources monitored on public lands include wildlife habitats, plant productivity, animal movements and population trends, soil chemistry, and water quality and quantity. Broader definitions of monitoring also recognize the need for scientifically valid data to help support planning efforts and informed decisions, to develop adaptive management strategies, and to provide the means for evaluating management outcomes.

Wyoming↗

Chemistry and movement of ground water, Nevada Test Site

Three chemical types of ground water are distinguished at the Nevada Test Site and vicinity. A sodium-potassium water is related to tuff (in part zeolitized) and to alluvium containing detrital tuff. A calcium-magnesium water is related to limestone and dolomite, or to alluvium containing detritus of these rock types. A mixed chemical type, containing about as much sodium and potassium as calcium and magnesium, may result from the addition of one of the first two types of water to the other; to passage of water first through tuff and then through carbonate rock, or vice versa; and to ion-exchange during water travel. Consideration of the distribution of these water types, together with the distribution of sodium in the water and progressive changes in the dissolved solids, suggests that the ground water in the Nevada Test Site probably moves toward the Amargosa Desert, not into Indian Spring Valley and thence southeastward toward Las Vegas. The low dissolved solids content of ground-water reservoirs in alluvium and tuff of the enclosed basins indicates that recharge is local in origin.

Open-File Report↗

The springs of Lake Pátzcuaro: chemistry, salt-balance, and implications for the water balance of the lake

Lake Pa??tzcuaro, the center of the ancient Tarascan civilization located in the Mexican altiplano west of the city of Morelia, has neither river input nor outflow. The relatively constant lake-salinity over the past centuries indicates the lake is in chemical steady state. Springs of the south shore constitute the primary visible input to the lake, so influx and discharge must be via sub-lacustrine ground water. The authors report on the chemistry and stable isotope composition of the springs, deeming them representative of ground-water input. The springs are dominated by Ca, Mg and Na, whereas the lake is dominated by Na. Combining these results with previously published precipitation/rainfall measurements on the lake, the authors calculate the chemical evolution from spring water to lake water, and also calculate a salt balance of the ground-water-lake system. Comparing Cl and ??18O compositions in the springs and lake water indicates that 75-80% of the spring water is lost evaporatively during evolution toward lake composition. During evaporation Ca and Mg are lost from the water by carbonate precipitation. Each liter of spring water discharging into the lake precipitates about 18.7 mg of CaCO3. Salt balance calculations indicate that ground water input to the lake is 85.9??106 m3/a and ground water discharge from the lake is 23.0??106 m3/a. Thus, the discharge is about 27% of the input, with the rest balanced by evaporation. A calculation of time to reach steady-state ab initio indicates that the Cl concentration of the present day lake would be reached in about 150 a. ?? 2004 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

Water, energy, and biogeochemical budgets investigation at Panola Mountain research watershed, Stockbridge, Georgia; A research plan

The Panola Mountain Research Watershed (PMRW), located in the Panola Mountain State Conservation Park near Stockbridge, Georgia has been selected as a core research watershed under the Water, Energy and Biogeochemical Budgets (WEBB) research initiative of the U.S. Geological Survey (USGS) Global Climate Change Program. This research plan describes ongoing and planned research activities at PMRW from 1984 to 1994. Since 1984, PMRW has been studied as a geochemical process research site under the U.S. Acid Precipitation Thrust Program. Research conducted under this Thrust Program focused on the estimation of dry atmospheric deposition, short-term temporal variability of streamwater chemistry, sulfate adsorption characteristics of the soils, groundwater chemistry, throughfall chemistry, and streamwater quality. The Acid Precipitation Thrust Program continues (1993) to support data collection and a water-quality laboratory. Proposed research to be supported by the WEBB program is organized in 3 interrelated categories: streamflow generation and water-quality evolution, weathering and geochemical evolution, and regulation of soil-water chemistry. Proposed research on streamflow generation and water-quality evolution will focus on subsurface water movement, its influence in streamflow generation, and the associated chemical changes of the water that take place along its flowpath. Proposed research on weathering and geochemical evolution will identify the sources of cations observed in the streamwater at Panola Mountain and quantify the changes in cation source during storms. Proposed research on regulation of soil-water chemistry will focus on the poorly understood processes that regulate soil-water and groundwater chemistry. (USGS)

Georgia↗

Questa baseline and pre-mining ground-water quality invistigation. 13. Mineral microscopy and chemistry of mined and unmined porphyry molybdenum mineralization along the Red River, New Mexico: Implications for ground- and surface-water quality

This report is one in a series presenting results of an interdisciplinary U.S. Geological Survey (USGS) study of ground-water quality in the lower Red River watershed prior to open-pit and underground molybdenite mining at Molycorp's Questa mine. The stretch of the Red River watershed that extends from just upstream of the town of Red River to just above the town of Questa includes several mineralized areas in addition to the one mined by Molycorp. Natural erosion and weathering of pyrite-rich rocks in the mineralized areas has created a series of erosional scars along this stretch of the Red River that contribute acidic waters, as well as mineralized alluvial material and sediments, to the river. The overall goal of the USGS study is to infer the pre-mining ground-water quality at the Molycorp mine site. An integrated geologic, hydrologic, and geochemical model for ground water in the mineralized but unmined Straight Creek drainage is being used as an analogue for the geologic, geochemical, and hydrologic conditions that influenced ground-water quality and quantity at the mine site prior to mining. This report summarizes results of reconnaissance mineralogical and chemical characterization studies of rock samples collected from the various scars and the Molycorp open pit, and of drill cuttings or drill core from bedrock beneath the scars and adjacent debris fans.

New Mexico↗

Landscape geochemistry near mineralized areas of eastern Alaska: Chapter H in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

The Pogo lode gold deposit was discovered in eastern Alaska in the early 1990s and provided the opportunity to study elemental distribution and mobility in the natural environment prior to mine development. Studying mineralized systems prior to mining allows us to compare the natural biogeochemical signature in mineralized versus nonmineralized areas. The resultant data and interpretation also provide a baseline for evaluating what, if any, changes in elemental distribution result from development. This report investigates the chemistry of stream water, streambed sediment, and soil in the context of regional bedrock geology. The major-ion chemistry of the waters reflects a rock-dominated aqueous system, and the waters are classified as Ca 2+ and Mg 2+ - HCO 3 - to Ca 2+ and Mg 2+ - SO 4 -2 waters. Creeks draining the gneissic lithologies tend to be more sulfate dominated than those draining the intrusive units. Sulfate also dominated creeks draining mineralized areas; however, the underlying paragneiss unit could be contributing substantially to the sulfate concentration, and the sulfate concentration in these creeks may reflect a complex baltholith-paragneiss boundary rather than mineralization. Arsenic concentrations in bed sediments were elevated in mineralized areas relative to nonmineralized areas. Elevated concentrations of nickel, chromium, iron, manganese, and cobalt appear to reflect the presence of ultramafic rocks in the drainage. In general, aqueous metal concentrations were below the State of Alaska’s Aquatic Life Criteria and Drinking Water Standards, with the exception of arsenic in stream water, which ranged in concentration from less than 1 to 14 micrograms per liter (μg/L) and exceeded the drinking water standard at one site. The arsenic and antimony concentration in the A, B, and C soil horizons ranged from 3 to 410 milligrams per kilogram (mg/kg), 6.1 to 440 mg/kg, and 2 to 300 mg/kg, respectively, for arsenic and 0.4 to 24 mg/kg, 0.6 to 25 mg/kg, and 0.2 to 16 mg/kg, respectively, for antimony. The arsenic and antimony concentrations in stream waters correlate well with the concentrations in soils. However, significantly less arsenic and antimony was extracted from C horizon soils in water leaching experiments, indicating that the arsenic and antimony in the C horizon is present in a less available form than in the A or B horizons. Arsenic and antimony uptake by grayleaf willow (Salix glauca L.) appears minimal, with arsenic concentrations ranging from less than 0.01 to 0.14 mg/kg and antimony concentrations ranging from less than 0.003 to 0.23 mg/kg in willow leaves. In general, the highest concentrations of both arsenic and antimony in water and soils were found near mineralized areas. Elevated arsenic concentrations were also found in bed sediments from mineralized areas. In these sample matrices, the presence of arsenic and (or) antimony was a good indicator of contact with mineralized rock units.

Alaska;Yukon↗

Analysis of water use associated with hydraulic fracturing and determination of baseline water quality in watersheds within the shale play of eastern Ohio, 2021–23

The U.S. Geological Survey, in cooperation with the Ohio Department of Natural Resources, performed a two-part study to (1) assess water use and temporal trends and changes in streamflow, and to (2) characterize 2021–23 baseline water quality, as they relate to oil and gas extraction activities in selected eastern Ohio watersheds. Between calendar years 2010 and 2019, hydraulic fracturing water withdrawals totaling about 27,168 million gallons were reported at 643 locations in Ohio. In 2021, wells developed with hydraulic fracturing were the source of most of the oil and gas produced in Ohio. Daily streamflow time-series data from seven study gages and two reference gages were used to assess temporal trends and changes in streamflow. The study gages were in basins with reported water withdrawals for hydraulic fracturing. The reference gages, which have long periods of record and were subject to minimal streamflow regulation, were in nearby basins with no hydraulic fracturing water withdrawals. Trend slopes for the period of record annual minimum and median daily streamflows and for annual daily streamflow nonexceedance probabilities less than 0.9 were all uniformly positive at the study and reference gages. This trend indicates a consistently increasing pattern over the periods of record, except for high flows. In addition, analyses of annual streamflow statistics showed no general indication that low flows or extreme low flows at the reference or study gages have lowered, become more frequent, or lengthened in duration since 2010, when records for hydraulic fracturing water withdrawals began in Ohio. In fact, in almost all cases, the opposite was indicated. Nonexceedance percentiles of daily streamflows were compared between the full and pre-2012 periods of record for reference and study gages. The streamflows associated with nonexceedance percentiles in the lower quartile of daily streamflows determined for the full period of record were larger than or equal to those determined for the pre-2012 period of record for all study and reference gages. This indicates that low flows did not decrease during the post-2011 period of record when water was withdrawn for hydraulic fracturing. Water-quality data were collected eight times at each of eight sampling sites (six of which were colocated with the study gages). Sampling was done during a variety of flow conditions to assess baseline water quality. In 2021, the 8 sampling sites had drainage basins that were wholly or partially within 7 of the 10 most active counties in Ohio for oil and gas development. As part of the record of baseline conditions, water-quality data were used to assess (1) water types based on major-ion chemistry; (2) sources of salinity to streams; (3) exceedances of aquatic life use criteria; and (4) the correlations between water chemistry and drainage-basin characteristics, such as density of oil and gas wells, density of wastewater treatment plants, or the percentage of different types of land cover (agriculture, developed, forest). Seven of the water-quality sampling sites were designated as coal-mine impacted based on criteria developed for assessing mine-drainage impacts in Ohio. Mine drainage from historical coal mining in the region likely affected the quality of these streams and complicated the use of some constituents typically used as indicators of oil and gas influence. Based on major-ion chemistry, three main types of water were in the study area―sulfate (three sites), calcium-bicarbonate (one site), and mixed bicarbonate-chloride (four sites) type waters. One site had samples with a higher proportion of sodium and chloride ions than other stream samples, indicating potential contamination with oil-field brine or road salt. Binary mixing curves revealed that 11 samples from 4 of the sampling sites likely contained a component of brine. The results of the baseline assessment of surface-water quality in the study area showed no exceedances of Ohio Environmental Protection Agency aquatic life use criteria. Spearman’s rank correlation coefficients indicated no significant positive correlations with the density of vertical or horizontal oil and gas wells.

Ohio↗

Quality of streams in Johnson County, Kansas, 2002--10

Stream quality in Johnson County, northeastern Kansas, was assessed on the basis of land use, hydrology, stream-water and streambed-sediment chemistry, riparian and in-stream habitat, and periphyton and macroinvertebrate community data collected from 22 sites during 2002 through 2010. Stream conditions at the end of the study period are evaluated and compared to previous years, stream biological communities and physical and chemical conditions are characterized, streams are described relative to Kansas Department of Health and Environment impairment categories and water-quality standards, and environmental factors that most strongly correlate with biological stream quality are evaluated. The information is useful for improving water-quality management programs, documenting changing conditions with time, and evaluating compliance with water-quality standards, total maximum daily loads (TMDLs), National Pollutant Discharge Elimination System (NPDES) permit conditions, and other established guidelines and goals. Constituent concentrations in water during base flow varied across the study area and 2010 conditions were not markedly different from those measured in 2003, 2004, and 2007. Generally the highest specific conductance and concentrations of dissolved solids and major ions in water occurred at urban sites except the upstream Cedar Creek site, which is rural and has a large area of commercial and industrial land less than 1 mile upstream on both sides of the creek. The highest base-flow nutrient concentrations in water occurred downstream from wastewater treatment facilities. Water chemistry data represent base-flow conditions only, and do not show the variability in concentrations that occurs during stormwater runoff. Constituent concentrations in streambed sediment also varied across the study area and some notable changes occurred from previously collected data. High organic carbon and nutrient concentrations at the rural Big Bull Creek site in 2003 decreased to at least one-fourth of those concentrations in 2007 and 2010 likely because of the reduction in upstream wastewater discharge contributions. The highest concentrations of trace metals in 2010 occurred at urban sites on Mill and Indian Creeks. Zinc was the only metal to exceed the probable effects concentration in 2010, which occurred at a site on Indian Creek. In 2007, chromium and nickel at the upstream urban Cedar Creek site exceeded the probable effects concentrations, and in 2003, no metals exceeded the probable effects concentrations. Of 72 organic compounds analyzed in streambed sediment, 26 were detected including pesticides, polycyclic aromatic hydrocarbons (PAHs), fuel products, fragrances, preservatives, plasticizers, manufacturing byproducts, flame retardants, and disinfectants. All 6 PAH compounds analyzed were detected, and the probable effects concentrations for 4 of the 6 PAH compounds analyzed were exceeded in 2010. Only five pesticide compounds were detected in streambed sediment, including carbazole and four pyrethroid compounds. Chronic toxicity guidelines for pyrethroid compounds were exceeded at five sites. Biological conditions reflected a gradient in urban land use, with the less disturbed streams located in rural areas of Johnson County. About 19 percent of sites in 2010 (four sites) were fully supporting of aquatic life on the basis of the four metrics used by Kansas Department of Health and Environment to categorize sites. This is a notable difference compared to previous years when no sites (in 2003 and 2004) or just one site (in 2007) was fully supporting of aquatic life. Multimetric macroinvertebrate scores improved at the Big Bull Creek site where wastewater discharges were reduced in 2007. Environmental variables that consistently were highly negatively correlated with biological conditions were percent impervious surface and percent urban land use. In addition, density of stormwater outfall points adjacent to streams was significantly negatively correlated with biological conditions. Specific conductance of water and sum of PAH concentrations in streambed sediment also were significantly negatively correlated with biological conditions. Total nitrogen in water and total phosphorus in streambed sediment were correlated with most of the invertebrate variables, which is a notable difference from previous analyses using smaller datasets, in which nutrient relations were weak or not detected. The most important habitat variables were sinuosity, length and continuity of natural buffers, riffle substrate embeddedness, and substrate cover diversity, each of which was correlated with all invertebrate metrics including a 10-metric combined score. Correlation analysis indicated that if riparian and in-stream habitat conditions improve then so might invertebrate communities and stream biological quality. Sixty-two percent of the variance in macroinvertebrate community metrics was explained by the single environmental factor, percent impervious surface. Invertebrate responses to urbanization in Johnson County indicated linearity rather than identifiable thresholds. Multiple linear regression models developed for each of the four macroinvertebrate metrics used to determine aquatic-life-support status indicated that percent impervious surface, as a measure of urban land use, explained 34 to 67 percent of the variability in biological communities. Results indicate that although multiple factors are correlated with stream quality degradation, general urbanization, as indicated by impervious surface area or urban land use, consistently is determined to be the fundamental factor causing change in stream quality. Effects of urbanization on Johnson County streams are similar to effects described in national studies that assess effects of urbanization on stream health. Individually important environmental factors such as specific conductance of water, PAHs in streambed sediment, and stream buffer conditions, are affected by urbanization and, collectively, all contribute to stream impairments. Policies and management practices that may be most important in protecting the health of streams in Johnson County are those minimizing the effects of impervious surface, protecting stream corridors, and decreasing the loads of sediment, nutrients, and toxic chemicals that directly enter streams through stormwater runoff and discharges.

Kansas↗

Interactions between groundwater and surface water in a Virginia coastal plain watershed. 2. Acid-base chemistry

A field study of surface water and groundwater interactions during baseflow and stormflow conditions was performed at the Reedy Creek watershed in the Virginia Coastal Plain. Three estimates of the average saturated hydraulic conductivity ( K s ) of the unconfined aquifer were in reasonable agreement (ranging from 0.0033 to 0.010 cm/s), indicating that baseflow in the creek is entirely from the drainage of shallow groundwater from the relatively thin (1–6 m thick) unconfined aquifer. This relatively permeable surficial aquifer was found to be underlain by dark, olive grey, clay-silt and diatomaceous Miocene deposits of low permeability known as the Calvert Formation, which is believed to function as a confining bed in the area. A chemical hydrograph separation technique was used to resolve the contributions of [old] (pre-event) and [new] (event) water to stormflow. Results from a major rainstorm indicated that old water dominated the stormflow response of the watershed, although the new water contribution approached 40% at the hydrograph peak. Stormflow at Reedy Creek appears to result from saturation overland flow from variable source areas which include the stream channels and a significant part of the riparian wetland area. This response appears to be attributable to the transient dynamics of the shallow groundwater flow system and to the formation of localized groundwater mounds which raise the water-table to the wetland surface.

Hydrological Processes↗

Geochemistry of surface-waters in mineralized and non-mineralized areas of the Yukon-Tanana Uplands

The U.S. Geological Survey (USGS) and Alaska Department of Natural Resources (ADNR) are continuing investigations on element mobility in mineralized and non-mineralized areas of the Yukon-Tanana Upland in east-central Alaska. The chemistry of stream water is evaluated in the context of regional bedrock geology and geologic structure. Sampling sites were located in the Big Delta B2 quadrangle, which includes the mineralized areas of the Pogo claim block. The area is typified by steep, subarctic-alpine, boreal forest catchment basins. Samples were collected from catchments that either cross structural features and lithologic contacts, or are underlain by a single lithology. Waters are generally dilute (< 213 mg/L TDS), and are classified as Ca 2+ and Mg 2+ -HCO 3 - to Ca 2+ and Mg 2+ -SO 4 2- waters. Gneissic lithologies are more SO42- dominated than the intrusive units. The major-ion chemistry of the waters reflects a rock-dominated aqueous system. Trace-element concentrations in water are generally low; however, As and Sb are detected near mineralized areas but in most cases rapidly attenuated downstream and processes other than simple dilution are controlling the concentrations of these trace elements. There is a tendency toward increasing SO 4 2- concentrations downstream in waters both proximal and distal to mineralized areas. More work is necessary to determine what proportion of the increase in SO 4 2- could be derived from the oxidation of sulfide minerals as opposed to water influenced by the underlying gneissic units.

Conference Paper↗

Hydrogeochemistry of rivers and lakes

This chapter has three principal objectives: (1) to summarize the present chemical composition of North American surface waters and point out any discernible trends with time; (2) to review chemical and biochemical principles and processes that control natural water composition, and the ways in which these may be involved in attaining the particular chemical compositions and trends that we can observe; and (3) to point out some of the more important factors that must be considered in collecting surface-water-quality data. This discussion is concerned principally with inorganic chemistry and geochemistry. However, biochemical processes in river and lake water influence their chemical composition extensively, and specific effects are pointed out. Aquatic biology is discussed in another chapter. The physical processes occurring in lakes also have very important effects on water chemistry; these aspects of limnology are covered more fully in a separate chapter. Data on which this chapter is based relate mostly to waters of Canada, the United States, and Mexico. For most of Central America, very little water-quality information is available. Tables 1 through 3 contain analytical data for river waters that illustrate some of the principles discussed, and summarize major features of the chemical composition of North American surface waters. To a certain extent, at least, one would expect the average concentrations of dissolved elements in surface fresh water to reflect the relative abundance of the elements in the crustal rocks exposed at and near the land surface.

Book chapter↗