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USGS2026

Quality of groundwater used for domestic supply in the western Central Valley, California—2023

More than 2 million Californians rely on groundwater from domestic wells for their drinking-water supply. This report summarizes a 2023 California Groundwater Ambient Monitoring and Assessment Priority Basin Project water-quality survey of 44 domestic and small-system drinking-water supply wells in the western Sacramento Valley (basin number 5-021) and San Joaquin Valley (basin number 5-022) groundwater basins in the Central Valley, California, where more than 88,000 residents are estimated to utilize privately owned, domestic wells. The study area includes the Corning, Colusa, Yolo, and Solano subbasins (subbasin numbers 5-021.51, 5-021.52, 5-021.67, and 5-021.66, respectively) of the Sacramento Valley groundwater basin, and the East Contra Costa, Tracy, Delta-Mendota, and Westside subbasins (subbasin numbers 5-022.19, 5-022.15, 5-022.07, and 5-022.09, respectively) of the San Joaquin Valley groundwater basin. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of the aquifer system rather than groundwater resources used for public drinking-water supply, which are typically drawn from deeper parts. This assessment characterized the quality of ambient groundwater used for domestic supply, rather than the quality of drinking water at a tap or faucet, which may be filtered or treated after extraction. To provide context, concentrations of constituents in groundwater were compared to Federal and State of California regulatory and non-regulatory benchmarks for drinking-water quality. Regulatory benchmarks were U.S. Environmental Protection Agency and State of California maximum contaminant levels (MCLs) for drinking water. Non-regulatory benchmarks were State of California secondary maximum contaminant levels (SMCLs) for managing aesthetic conditions, such as taste, odor, or color. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking supply that have water-quality constituents present at high concentrations (greater than the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth of the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other California Groundwater Ambient Monitoring and Assessment Priority Basin Project study areas. In this study, inorganic constituents in groundwater were greater than regulatory benchmarks for public drinking-water quality in 30 percent of domestic groundwater resources. Inorganic constituents present at concentrations greater than MCLs for drinking water were hexavalent chromium, total chromium, and nitrate. Total dissolved solids, manganese, and iron were present at concentrations greater than their SMCL in 27 percent of domestic groundwater resources. 1,2,3-trichloropropane was present at concentrations greater than State of California MCLs for drinking water in 2.3 percent of domestic groundwater resources and was the only volatile organic compound detected at concentrations greater than a benchmark. Per-and polyfluoroalkyl substances were detected in 16 percent of domestic groundwater resources, and 2.3 percent had concentrations greater than U.S. Environmental Protection Agency MCLs. Total coliform bacteria and enterococci were detected in 9.1 and 2.3 percent of domestic groundwater resources, respectively. To understand groundwater quality in the study area, factors that affect groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential physical and chemical variables. Relevant factors include the oxidation-reduction conditions of groundwater, agricultural land use, and geologic sources of aquifer sediments. Manganese and iron concentrations were affected by oxidation-reduction state. Nitrate concentrations were affected by the interplay of agricultural practices and denitrification, where denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Ultramafic aquifer sediments in the western Central Valley provide a geogenic source for chromium and hexavalent chromium. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials, but agricultural practices may also contribute to these concentrations.

California↗

USGS2002

Water and bed-sediment quality in the vicinity of Berlin Lake, Ohio, 2001

Berlin Lake, in northeast Ohio, was created by the U.S. Army Corps of Engineers in 1943 and is used primarily for flood control for the upper reaches of the Mahoning River. The area surrounding and under the lake has been tapped for oil and natural gas production. One of the by-products of oil and gas production is concentrated salt water or brine, which might have an effect on the chemical quality of area potable-water sources. This report presents the results of a U.S. Geological Survey baseline study to collect current (2001) water and sediment-quality data and to characterize water quality in the Berlin Lake watershed. Chloride-to-bromide ratios were used to detect the presence of brine in water samples and to indicate possible adverse effects on water quality. Analyses of ground-water samples from domestic wells in the area indicate a source of chloride and bromide, but defining the source would require more data collection. Analyses of specific conductance and dissolved solids indicate that 78 percent (14 of 18) of the ground-water samples exceeded the Secondary Maximum Contaminant Level for dissolved solids in public water supplies of 500 milligrams per liter (mg/L), compared to 6 percent of samples exceeding 500 mg/L in two nearby studies. Surface water was analyzed twice, once each during low-flow and surface runoff conditions. A comparison of the 2001 data to historical chloride concentrations, accounting for seasonal changes, does not indicate an increase in chloride loads for surface water in the area of Berlin Lake. Polycyclic aromatic hydrocarbons were found in bed-sediment samples collected from the mouths of major tributaries to Berlin Lake. Polycyclic aromatic hydrocarbons are produced during the incomplete combustion of organic carbon materials such as wood and fossil fuels, and they are components of petroleum products.

Water-Resources Investigations Report↗

USGS1987

Overview of surface-water quality in Ohio's coal regions

This report is designed to provide the nontechnical audience with some of the results of an 'Assessment of Water Quality in Streams Draining Coal-Producing Areas in Ohio,' by Christine L. Pfaff and others (published by the U.S. Geological Survey in 1981). The purpose of the assessment was to document the occurrence of certain chemical constituents in streams in Ohio's coal region and determine to what extent the presence of these constituents was related to mining. Ohio's most productive coal seams are associated with the Allegheny and Monongahela Formation of Pennsylvanian age. These coals were mined by underground methods very early in Ohio's history. Underground mining continues in the state today; however, surface mining now produces significantly more coal. Acid mine drainage from unreclaimed surface and underground mines has affected surface-water quality in Ohio for many years, and recently has led to establishment of reclamation programs by State and Federal agencies. In their assessment of Ohio's coal region, Pfaff and others sampled 150 sites in small watersheds underlain by the Allegheny and the Monogahela Formations. Each site represented only one of four land-use types (active-mine, unmined, abandoned-mine, or reclaimed). Statistical analysis of data from the unmined, abandoned-mine, and reclaimed sites showed that there were significant differences in pH, specific conductance, alkalinity, and concentrations of sulfate and aluminum among abandoned-mine and unmined sites. Reclaimed sites had average pH values and aluminum concentrations similar to those unmined sites. Average specific conductance and sulfate concentrations were about the same for reclaimed abandoned-mine sites, but were significantly lower at unmined sites; specific conductance and sulfate concentration, in fact, proved to be reliable indicators of basins that had been disturbed by mining. Alkalinity was significantly different for all three land uses, the highest values being found at reclaimed sites. The relationship revealed by this study may be useful in designing future water-quality sampling programs in Ohio's coal region.

Water-Resources Investigations Report↗

USGS1998

Revised Methods for Characterizing Stream Habitat in the National Water-Quality Assessment Program

Stream habitat is characterized in the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program as part of an integrated physical, chemical, and biological assessment of the Nation's water quality. The goal of stream habitat characterization is to relate habitat to other physical, chemical, and biological factors that describe water-quality conditions. To accomplish this goal, environmental settings are described at sites selected for water-quality assessment. In addition, spatial and temporal patterns in habitat are examined at local, regional, and national scales. This habitat protocol contains updated methods for evaluating habitat in NAWQA Study Units. Revisions are based on lessons learned after 6 years of applying the original NAWQA habitat protocol to NAWQA Study Unit ecological surveys. Similar to the original protocol, these revised methods for evaluating stream habitat are based on a spatially hierarchical framework that incorporates habitat data at basin, segment, reach, and microhabitat scales. This framework provides a basis for national consistency in collection techniques while allowing flexibility in habitat assessment within individual Study Units. Procedures are described for collecting habitat data at basin and segment scales; these procedures include use of geographic information system data bases, topographic maps, and aerial photographs. Data collected at the reach scale include channel, bank, and riparian characteristics.

Water-Resources Investigations Report↗

USGS1998

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin— Ground-water quality in the Prairie du Chien-Jordan aquifer, 1996

The Prairie du Chien-Jordan (PDCJ) aquifer (Prairie du Chien-Trempealeau aquifer in Wisconsin), composed of dolomite and sandstone of Cambrian to Ordovician age, is the principal bedrock aquifer in the Upper Mississippi River study unit of the National Water-Quality Assessment (NAWQA) Program. The aquifer supplies approximately 75 percent of the ground water withdrawn in the area. In certain areas, the aquifer is overlain by bedrock or glacial deposits having low hydraulic conductivity (termed "confined portion" of the aquifer in this report). In other areas the aquifer is overlain by glacial sand and gravel deposits having greater hydraulic conductivity (termed "unconfined portion" of the aquifer in this report). Differences in the hydrogeologic characteristics of these overlying units have potential to affect the downward movement of water and of contaminants into the aquifer from the land surface. Ground-water samples were collected from 50 domestic wells completed in this aquifer in July, August, and September of 1996 as part of the U.S. Geological Survey's National WaterQuality Assessment Program. The purpose of this report is to describe the chemical characteristics of water in the PDCJ aquifer and to summarize the differences in water quality in confined and unconfined portions of the aquifer. Twenty-five wells were sampled in each portion of the aquifer. Water samples from the wells were measured for physical parameters and analyzed for concentrations of major ions, nutrients, dissolved organic carbon, trace metals, radon, tritium, pesticides, and volatile organic compounds. Differences in anthropogenic and naturally occurring materials in water between confined and unconfined portions of the PDCJ aquifer are small and frequently the differences are not statistically significant at the 95 percent confidence level. Dissolved oxygen concentrations were slightly less and specific conductances and alkalinities were slightly greater in water in the confined portion of the aquifer. Only the differences in specific conductance and alkalinity, however, were statistically significant at the 95 percent confidence level (two sample t-test). Concentrations of most major ions were generally greater in water from the confined portion of the aquifer. Nitrate (nitrite plus nitrate as N) and phosphorus were generally greater in the unconfined portion of the PDCJ aquifer although the differences were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). In the confined portion of the aquifer no samples exceeded the maximum contaminant level of 10 milligrams per liter for nitrate. In the unconfined portion of the aquifer nitrate in two samples exceeded the maximum contaminant level of 10 milligrams per liter. Phosphorus concentrations were generally about an order of magnitude less than nitrate concentrations. Iron and manganese concentrations commonly exceeded the secondary maximum contaminant levels set by the U.S. Environmental Protection Agency and were generally greater in the confined portion of the PDCJ aquifer, although the differences were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). Radon concentrations were greater in the confined portion of the aquifer than in the unconfined portion, although the difference was not statistically significant at the 95 percent confidence level (two sample t-test), with medians of 500 and 340 picoCuries per liter, respectively. Sixty-six percent of the radon concentrations were greater than the suspended maximum contaminant level of 300 picoCuries per liter. Tritium concentrations indicate that water in the unconfined portion of the PDCJ aquifer may have been recharged more recently than water in the confined portion of the aquifer, although differences in tritium concentrations between confined and unconfined portions of the aquifer were not statistically significant at the 95 percent confidence level (nonparametric MannWhitney test). Atrazine and its metabolite, deethylatrazine, were the most frequently detected pesticide compounds in water samples from the PDCJ aquifer. Volatile organic compounds were detected in 41 of the 50 water samples, but none of the concentrations exceeded 1 microgram per liter. Concentrations of volatile organic compounds were slightly greater in the unconfined portion, although the differences in detection rates were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). Carbon disulfide and methyl chloride were the most frequently detected volatile organic compounds. Water in the unconfined portion of the PDCJ aquifer in Minnesota and Wisconsin appears to be affected to a greater degree by anthropogenic activities than water in the confined portion of the aquifer. Water in the confined portion has a longer residence time and greater concentrations of dissolution products of minerals. In general, however, differences in anthropogenic and naturally occurring materials among confined and unconfined portions of the aquifer are small and frequently not significantly different.

Minnesota, Wisconsin↗

USGS1973

The chemistry of five accessory rock-forming apatites

Chemical and physical data are given for five samples of rock-forming apatite from diverse geologic environments in Nevada and Colorado. Four of these apatites contain rare-earth assemblages in which the cerium group is well represented but the yttrium group predominates. The fifth apatite contains a highly fractionated assemblage of the lighter (cerium group) rare earths similar to the assemblage typical of alkulic rocks.

Nevada, Colorado↗

USGS1965

Quality of surface water in the Sevier Lake basin, Utah

Few data are available on the quality of surface waters in the Sevier Lake basin. Because of the need for information not only on the chemical-quality but also on the other water-quality characteristics of the basin, the U.S. Geological Survey, as part of its cooperative program with the Utah State Engineer, evaluated the available data in 1963. Based on this evaluation, a reconnaissance was designed to obtain some of the needed water-quality information. To extend the applicability of the basic information, the Utah State Engineer, the Utah State Department of Health, the Water Commissioner for the Sevier River, and the Soil Conservation Service and Forest Service of the U.S. Department of Agriculture assisted in the planning and in the selection of sampling sites. This report presents the results of the data-collection phase of the reconnaissance. A companion interpretive report will be prepared later. The data were collected primarily by the U.S. Geological Survey as part of its cooperative programs with the State Engineer of Utah and the Utah Geological and Mineralogical Survey. The work was under the supervision of R. H. Langford, district chemist of the Quality of Water Branch, Water Resources Division, U.S. Geological Survey.

Utah↗

USGS1978

Chemical, physical, biochemical, and bacteriological characteristics at selected stream sites in Puerto Rico, 1976-77

In 1969, the Caribbean District of the U.S. Geological Survey, in cooperation with the Commonwealth of Puerto Rico, initiated the operation of a network to monitor some parameters indicative of water-quality changes at selected stream sites. The initial network consisted of 18 stations, which were expanded to 20 in 1971, and to 30 in 1973 (Reed and others, 1971, 1972, Quinones, 1975). In 1974, at the request of the Environmental Quality Board of Puerto Rico, the network was modified to conform with the Environmental Protection Agency National Water Quality Surveillance System. Under the revised concept, monitoring stations were established at sites near the headwaters and mouths of the principal rivers in Puerto Rico. Most of the stations in the p-evious network were located at sites downstream in the valleys in order that the overall water-quality conditions in the principal rivers could be monitored. The purpose of the present network is to monitor changes in water quality between the upstream and downstream stations. The expanded network consisted of 58 stations. During 1976, five had been discontinued. One other was added late in 1976. Progress reports have been published in 1976 (Quinones and others) and 1977 (Quinones and others). Most of the stations in the original network have been maintained, thus providing sore degree of continuity. The monitoring stations used in this report are shown in figure 1 and listed in table 2. This report summarizes the results of the network operation from July 1976 to August 1977.

Puerto Rico↗

USGS2008

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

USGS1980

Chemical and physical characteristics of precipitation at selected sites in Florida

Infrequent sampling of precipitation in Florida has been conducted by the U.S. Geological Survey since 1965. A summary of the historical data from 24 sites throughout Florida indicate that the principal ionic composition of atmospheric precipitation samples is calcium-sodium and bicarbonate-chloride with an average specific conductance of 32 micromhos per centimeter at 25 C. Historically, much of the sampling focused on primary nutrients and selected trace elements. Historical data indicate that nitrogen and phosphorus concentrations averaged 1.1 and 0.1 milligrams per liter, respectively. The limited trace metal data indicate that motor-vehicle activity may have a significant impact on local precipitation quality. Lead, for example, was measured in concentrations of as much as 2,400 micrograms per liter in samples collected in a highly populated, commerical area in south Florida. Statistical testing indicated that most major inorganic constituents, primary nutrients, and trace metals were significantly differnet among the sampling sites. The pH data indicated a range of about 5.0 to 7.0, but only limited pH data were collected and analyzed at the historical sites in such a timely manner as to represent pH conditions of the atmospheric precipitation during active rainfall. A critical review of the historical data suggested that while they may reflect local atmospheric quality conditions they likely do not define baseline conditions from a regional perspective. The application of these data were generally limited regarding regional extrapolation due to lack of standardization of sampling techniques, variable methods of sample preservation, nonuniform sampling intervals, variable sample sizes, and different periods of record. (USGS)

Water-Resources Investigations Report↗

USGS1985

The Schwartzwalder uranium deposit. I: Geology and structural controls on mineralization.

Numerous uranium veins occupy fractures and faults in brittle Proterozoic gneisses along the east central Front Range of Colorado. The deposit size correlates with the density and localization of brittle fracture. The largest deposit, the Schwartzwalder, is explained by a singular configuration of complexly broken, deep-reaching brittle gneisses between impervious schists. The gneisses are described as being derived from volcanic rocks, shales, and chemical sediments, including iron, quartz and sulphide formations.-G.J.N.

Economic Geology↗

USGS1993

Distribution of fluoride in ground water of West Virginia

This report describes the results of a study by the U.S. Geological Survey, in cooperation with the West Virginia Geological and Economic Survey, to evaluate the distribution of fluoride in ground water of West Virginia. Fluoride is a natural chemical constituent in domestic and public water supplies in West Virginia. Fluoride concentrations of about 1.0 milligram per liter in drinking water are beneficial to dental health. Concentrations greater than 2.0 milligrams per liter, however, could harm teeth and bones. Fluoride concentra- tions in ground water of West Virginia range from less than 0.1 to 12 milligrams per liter. Fluoride concentrations that exceed 2.0 milligrams per liter are found in wells drilled to all depths, wells drilled in all topographic settings, and wells drilled into most geologic units. Most fluoride concentrations that exceed 2.0 milligrams per liter are located at sites clustered in the northwestern part of the State.

Open-File Report↗

USGS2020

Compounds of emerging concern detected in water samples from potable water and wastewater treatment plants and detected in water and bed-sediment samples from sites on the Trinity River, Dallas, Texas, 2009–13

The population in the Dallas-Fort Worth metropolitan area in northern Texas is rapidly growing, resulting in a rapid increase in the demand for potable water and an increase in the discharge of wastewater treatment plant effluent. An assessment of compounds of emerging concern (CECs) in samples collected at potable water and wastewater treatment plants in Dallas and downstream from Dallas in the Trinity River was completed by the U.S. Geological Survey in cooperation with the City of Dallas, Dallas Water Utilities. CECs are synthetic or naturally occurring chemicals that are not commonly monitored in the environment but can enter the environment and cause known or suspected adverse ecological or human health effects. CECs can enter the environment through nonpoint sources (for example, runoff) and point sources (for example, concentrated animal feeding operations and treated-effluent discharge from wastewater treatment plants), which can increase concentrations of CECs especially in highly populated areas. CECs include pharmaceuticals (prescription and nonprescription), steroidal hormones, stanols, sterols, detergents and detergent metabolites (hereinafter referred to as “detergents”), personal-use products, pesticides, polycyclic aromatic hydrocarbons (PAHs), flame retardants, plasticizers, and other organic compounds used in everyday domestic, agricultural, and industrial applications. The release of CECs to the environment went largely unrecognized until relatively recently. Increased loading of certain CECs to the environment, combined with advancements in laboratory analysis methods that resulted in appreciably lower detection levels, brought greater attention to the release of CECs. In addition, synthesis of new chemicals or changes in use and disposal of existing chemicals can create new sources of CECs. Some CECs are endocrine disrupting compounds (EDCs), which can elicit adverse effects on development, behavior, and reproduction of wildlife and can cause dysfunction of human and wildlife endocrine (hormone) systems. Results of studies in the United States and Europe indicate that CECs, their metabolites, and industrial, agricultural, and household wastewater products are present in the aquatic environment, water treatment plants, and septic systems. CECs, especially pharmaceuticals, are of interest because of their persistence, widespread use, and potential to cause adverse effects in humans and nontargeted organisms. There is also concern that some CECs and EDCs resist degradation of water treatment processes at potable water treatment plants (PWTPs) and wastewater treatment plants (WWTPs) and that treated-effluent discharge could contain compounds that negatively affect biota living in receiving waters. Therefore, CECs and EDCs are more likely to be detected in environmental samples collected near areas of high population density where treated effluent from WWTPs can contribute substantially to receiving waters. The U.S. Geological Survey, in cooperation with the City of Dallas, Dallas Water Utilities, evaluated the occurrence and concentrations of selected CECs in samples collected at PWTPs and WWTPs in Dallas and downstream from the Dallas-Fort Worth metropolitan area in the Trinity River, Texas, from August 2009 to December 2013. Water samples were collected at three PWTP sites, two WWTP sites, and five study sites on the Trinity River; all sites where samples were collected were in or downstream from Dallas. These water samples were analyzed for 120 CECs, including human-health pharmaceuticals (prescription and nonprescription), antibiotics, steroidal hormones, stanols, sterols, detergents, personal-use products (flavors and fragrances), pesticides and repellents, industrial wastewater compounds, disinfection compounds, PAHs, flame retardants, and plasticizers. Additionally, bed-sediment samples were collected at each of the five Trinity River sites. The bed-sediment samples were analyzed for 57 CECs. In general, the water treatment processes at PWTPs and WWTPs were effective at reducing detections and concentrations of CECs to undetectable levels or transforming the compounds into degradates that were not analyzed. There were 14 and 73 CECs detected in raw water and in untreated-influent water at PWTPs and WWTPs, respectively. Of these, 11 of the 14 CECs detected in raw-water samples and 44 of the 73 CECs detected in untreated-influent samples were not detected in finished water or in treated-effluent water samples, respectively, indicating that these compounds were removed or degraded to compounds that were not analyzed. Some CECs, however, are resistant to degradation and were detected in untreated and treated water at PWTPs and at WWTPs. The three CECs detected at PWTPs in raw-water and finished-water samples were tris(dichloroisopropyl)phosphate, benzophenone, and methyl salicylate. At WWTPs, 29 CECs were detected, including carbamazepine, sulfamethoxazole, 4-androstene-3,17- dione , 3-beta-coprostanol, acetyl-hexamethyl-tetrahydronaphthalene (AHTN), hexahydro-hexamethyl-cyclopenta-benzopyran (HHCB), 1,4-dichlorobenzene, tribromomethane, benzophenone, and tris(dichloroisopropyl)phosphate, in untreated and treated water, indicating that treatment processes likely did not remove or degrade these compounds. Of the 23 CECs detected in stream-water samples collected at 5 sites on the Trinity River in or near Dallas, 10 CECs (carbamazepine, sulfamethoxazole, caffeine, 3-beta-coprostanol, cholesterol, HHCB, benzophenone, triethyl citrate, tributyl phosphate, and tris(dichloroisopropyl)phosphate) were detected at all 5 sites. The 10 CECs detected in water samples collected at all 5 sites on the Trinity River were also detected in treated-effluent water at WWTPs. Eleven of the 57 targeted CECs were detected in bed-sediment samples collected at study sites on the Trinity River. Of these 11 CECs, only 2 (beta-sitosterol and cholesterol) were detected in bed-sediment samples at all 5 sites on the Trinity River. Nine of these 11 CECs were not detected in any water-column sample, likely because of the strong hydrophobic characteristics of these compounds. Results from water treatment plants indicate that the water treatment process is less effective for removing or degrading compounds that are engineered to be resistant to degradation. These results also indicate the presence of CECs and EDCs at locations upstream from PWTPs in Dallas. Results from Trinity River main-stem sites indicate that some compounds are naturally attenuated during transport, but a few are persistent throughout the study reach. Many CECs and EDCs are hydrophobic and were only detected in bed sediment, indicating multiple pathways through which CECs can persist in the environment. In general, concentrations of CECs in the Dallas-Fort Worth metropolitan area were similar to those found in metropolitan areas nationwide.

Texas↗

USGS2000

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska↗

USGS2015

Estimation of unaltered daily mean streamflow at ungaged streams of New York, excluding Long Island, water years 1961-2010

The lakes, rivers, and streams of New York State provide an essential water resource for the State. The information provided by time series hydrologic data is essential to understanding ways to promote healthy instream ecology and to strengthen the scientific basis for sound water management decision making in New York. The U.S. Geological Survey, in cooperation with The Nature Conservancy and the New York State Energy Research and Development Authority, has developed the New York Streamflow Estimation Tool to estimate a daily mean hydrograph for the period from October 1, 1960, to September 30, 2010, at ungaged locations across the State. The New York Streamflow Estimation Tool produces a complete estimated daily mean time series from which daily flow statistics can be estimated. In addition, the New York Streamflow Estimation Tool provides a means for quantitative flow assessments at ungaged locations that can be used to address the objectives of the Clean Water Act—to restore and maintain the chemical, physical, and biological integrity of the Nation’s waters. The New York Streamflow Estimation Tool uses data from the U.S. Geological Survey streamflow network for selected streamgages in New York (excluding Long Island) and surrounding States with shared hydrologic boundaries, and physical and climate basin characteristics to estimate the natural unaltered streamflow at ungaged stream locations. The unaltered streamflow is representative of flows that are minimally altered by regulation, diversion, or mining, and other anthropogenic activities. With the streamflow network data, flow-duration exceedance probability equations were developed to estimate unaltered streamflow exceedance probabilities at an ungaged location using a methodology that equates streamflow as a percentile from a flow-duration curve for a particular day at a hydrologically similar reference streamgage with streamflow as a percentile from the flow-duration curve for the same day at an ungaged location. The reference streamgage is selected using map correlation, a geostatistical method in which variogram models are developed that correlate streamflow at one streamgage with streamflows at all other locations in the study area. Regression equations used to predict 17 flow-duration exceedance probabilities were developed to estimate the flow-duration curves at ungaged locations for New York using geographic information system-derived basin characteristics. A graphical user interface, with an integrated spreadsheet summary report, has been developed to estimate and display the daily mean streamflows and statistics and to evaluate different water management or water withdrawal scenarios with the estimated monthly data. This package of regression equations, U.S. Geological Survey streamgage data, and spreadsheet application produces an interactive tool to estimate an unaltered daily streamflow hydrograph and streamflow statistics at ungaged sites in New York. Among other uses, the New York Streamflow Estimation Tool can assist water managers with permitting water withdrawals, implementing habitat protection, estimating contaminant loads, or determining the potential affect from chemical spills.

New York↗

USGS2006

An update of hydrologic conditions and distribution of selected constituents in water, Snake River Plain aquifer, Idaho National Laboratory, Idaho, Emphasis 1999-2001

Radiochemical and chemical wastewater discharged since 1952 to infiltration ponds, evaporation ponds, and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the Snake River Plain aquifer underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains ground-water monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer. This report presents an analysis of water-level and water-quality data collected from wells in the USGS ground-water monitoring networks during 1999-2001. Water in the Snake River Plain aquifer moves principally through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer is recharged principally from infiltration of irrigation water, infiltration of streamflow, ground-water inflow from adjoining mountain drainage basins, and infiltration of precipitation. Water levels in wells rose in the northern and west-central parts of the INL by 1 to 3 feet, and declined in the southwestern parts of the INL by up to 4 feet during 1999-2001. Detectable concentrations of radiochemical constituents in water samples from wells in the Snake River Plain aquifer at the INL generally decreased or remained constant during 1999-2001. Decreases in concentrations were attributed to decreased rates of radioactive-waste disposal, radioactive decay, changes in waste-disposal methods, and dilution from recharge. Tritium concentrations in water samples decreased as much as 8.3 picocuries per milliliter (pCi/mL) during 1999-2001, ranging from 0.43?0.14 to 13.6?0.6 pCi/mL in October 2001. Tritium concentrations in five wells near the Idaho Nuclear Technology and Engineering Center (INTEC) increased a few picocuries per milliliter from October 2000 to October 2001. Strontium-90 concentrations decreased or remained constant during 1999-2001, ranging from 2.1?0.6 to 42.4?1.4 pCi/L in October 2001. During 1999-2001, concentrations of cesium-137, plutonium-238, and plutonium-239, -240 (undivided) were less than the reporting level in water samples from all wells sampled at the INL. The concentration of americium-241 in one sample was 0.003?0.001 pCi/L, the reporting level for that constituent. Cobalt-60 was not detected in any samples collected during 1999-2001. Changes in detectable concentrations of nonradioactive chemical constituents in water from the Snake River Plain aquifer at the INL varied during 1999-2001. In October 2001, water from one well south of the Reactor Technology Complex (RTC) [known as the Test Reactor Area (TRA) until 2005] contained 139 micrograms per liter (?g/L) of chromium, a decrease from the concentration of 168 ?g/L detected in October 1998. Other water samples contained from less than 16.7 to 21.3 ?g/L of chromium. In October 2001, concentrations of sodium in water samples from most of the wells in the southern part of the INL were larger than the background concentration of 10 mg/L, but were similar to or slightly less than October 1998 concentrations. The largest sodium concentration was 75 milligrams per liter (mg/L) in water from well USGS 113. In 2001, chloride concentrations in most water samples from the INTEC and the Central Facilities Area (CFA) exceeded ambient concentrations of 10 and 20 mg/L, respectively. Chloride concentrations in water from wells near the RTC were less than 20 mg/L. At the Radioactive Waste Management Complex (RWMC), chloride concentrations in water from wells USGS 88, 89, and 120 were 81, 40, and 23 mg/L, respectively. Concentrations of chloride in all other wells near the RWMC were less than 19 mg/L. During 2001, concentrations of sulfate in water from two wells near the RTC, two wells near the RWMC, and one well near the CFA exceeded 40 mg/L, the estimated background concentration of sulfate in the Snake River

Scientific Investigations Report↗

USGS1980

Evaporite encrustations and sulphide oxidation products from the southern Antarctic peninsula.

White evaporite encrustations collected from 66 sites scattered over 30 000km2 of S.Antarctic Peninsula are dominantly gypsum and calcite, and subordinate aragonite and thenardite. Natrojarosite occurs as locally developed yellow surface stains on c30% of the white encrustations examined. Water, which forms by the melting of snow blown into cracks in highly fractured rocks by ground blizzards, dissolves soluble ions from minerals in these rocks as it percolates into them. The white encrustations appear to be deposited when this water later rises to the surface by capillary action and evaporates.-from Author Antarctica chemical weathering evaporites sulphide oxidation.

New Zealand Journal of Geology and Geophysics↗

USGS1915

Analyses of rocks and minerals from the laboratory of the United States Geological Survey, 1880 to 1914

The present Geological Survey of the United States was organized in 1879. In 1880, in connection with the Colorado work, a chemical laboratory was established at Denver in charge of W. F. Hillebrand, with whom were associated Antony Guyard and, later, L. G. Eakins. In 1882 W. H. Melville was placed in charge of a second laboratory at San Francisco, and in the autumn of 1883 the central laboratory was started in Washington, with myself as chief chemist. In November, 1885, Dr. Hillebrand was transferred to Washington; early in 1888 he was followed by Mr. Eakins, and the Denver laboratory was discontinued. In the spring of 1890 Dr. Melville also was transferred to Washington, and since then the geochemical work of the Survey has been concentrated at headquarters. The special laboratories of the water-resources and technologic branches of the Survey are not included in this statement and their work is not represented in this bulletin. Up to January 1, 1914, nearly 8,000 analyses have been made in the laboratory at Washington of rocks, minerals, ores, waters, sediments, coals, metals, and other substances with which geology has to do. Some-hundreds of analyses were also made in the laboratories at Denver and San Francisco. A fair amount of research work upon mineralogical and analytical problems has also been done. In *all of this work the following chemists have been employed: E. T. Allen, R. K. Bailey, Charles Catlett, T. M. Chatard, F. W. Clarke, L. G. Eakins, J. G. Fairchild, F. A. Gooch, Antony Guyard, W. B. Hicks, W. F. Hillebrand, W. F. Hunt, W. H. Melville, H. C. McNeil, Chase Palmer, R. B. Riggs, W. T. Schaller, E. A. Schneider, George Steiger, H. N. Stokes, E. C. Sullivan, William Valentine, R. C. Wells, W. C. Wheeler, and J. E. Whitfield. At present, January 1, 1914, eight of these chemists are employed in the Survey. Other officers of the Survey have been occupied more or less with chemical questions, but the men named in this list were connected directly with the laboratory. Some work for the chemical division has also been done by chemists not regularly on the rolls of the Survey, but their analyses, with the exception of a single group to be noted later, do not fall within the scope of this paper.

Bulletin↗