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Net emissions of CH4 and CO2 in Alaska: Implications for the region's greenhouse gas budget

We used a biogeochemistry model, the Terrestrial Ecosystem Model (TEM), to study the net methane (CH4) fluxes between Alaskan ecosystems and the atmosphere. We estimated that the current net emissions of CH4 (emissions minus consumption) from Alaskan soils are ???3 Tg CH 4/yr. Wet tundra ecosystems are responsible for 75% of the region's net emissions, while dry tundra and upland boreal forests are responsible for 50% and 45% of total consumption over the region, respectively. In response to climate change over the 21st century, our simulations indicated that CH 4 emissions from wet soils would be enhanced more than consumption by dry soils of tundra and boreal forests. As a consequence, we projected that net CH4 emissions will almost double by the end of the century in response to high-latitude warming and associated climate changes. When we placed these CH4 emissions in the context of the projected carbon budget (carbon dioxide [CO2] and CH4) for Alaska at the end of the 21st century, we estimated that Alaska will be a net source of greenhouse gases to the atmosphere of 69 Tg CO2 equivalents/yr, that is, a balance between net methane emissions of 131 Tg CO2 equivalents/yr and carbon sequestration of 17 Tg C/yr (62 Tg CO2 equivalents/yr). ?? 2007 by the Ecological Society of America.

Ecological Applications↗

Assessment of boreal forest historical C dynamics in the Yukon River Basin: relative roles of warming and fire regime change

Carbon (C) dynamics of boreal forest ecosystems have substantial implications for efforts to mitigate the rise of atmospheric CO 2 and may be substantially influenced by warming and changing wildfire regimes. In this study we applied a large-scale ecosystem model that included dynamics of organic soil horizons and soil organic matter characteristics of multiple pools to assess forest C stock changes of the Yukon River Basin (YRB) in Alaska, USA, and Canada from 1960 through 2006, a period characterized by substantial climate warming and increases in wildfire. The model was calibrated for major forests with data from long-term research sites and evaluated using a forest inventory database. The regional assessment indicates that forest vegetation C storage increased by 46 Tg C, but that total soil C storage did not change appreciably during this period. However, further analysis suggests that C has been continuously lost from the mineral soil horizon since warming began in the 1970s, but has increased in the amorphous organic soil horizon. Based on a factorial experiment, soil C stocks would have increased by 158 Tg C if the YRB had not undergone warming and changes in fire regime. The analysis also identified that warming and changes in fire regime were approximately equivalent in their effects on soil C storage, and interactions between these two suggests that the loss of organic horizon thickness associated with increases in wildfire made deeper soil C stocks more vulnerable to loss via decomposition. Subbasin analyses indicate that C stock changes were primarily sensitive to the fraction of burned forest area within each subbasin and that boreal forest ecosystems in the YRB are currently transitioning from being sinks to sources at ∼0.7% annual area burned. We conclude that it is important for international mitigation efforts focused on controlling atmospheric CO 2 to consider how climate warming and changes in fire regime may concurrently affect the CO 2 sink strength of boreal forests. It is also important for large-scale biogeochemical and earth system models to include organic soil dynamics in applications to assess regional C dynamics of boreal forests responding to warming and changes in fire regime.

Ecological Applications↗

Controls on methane concentrations and fluxes in streams draining human-dominated landscapes

Streams and rivers are active processors of carbon, leading to significant emissions of CO 2 and possibly CH 4 to the atmosphere. Patterns and controls of CH 4 in fluvial ecosystems remain relatively poorly understood. Furthermore, little is known regarding how major human impacts to fluvial ecosystems may be transforming their role as CH 4 producers and emitters. Here, we examine the consequences of two distinct ecosystem changes as a result of human land use: increased nutrient loading (primarily as nitrate), and increased sediment loading and deposition of fine particles in the benthic zone. We did not find support for the hypothesis that enhanced nitrate loading down-regulates methane production via thermodynamic or toxic effects. We did find strong evidence that increased sedimentation and enhanced organic matter content of the benthos lead to greater methane production (diffusive + ebullitive flux) relative to pristine fluvial systems in northern Wisconsin (upper Midwest, USA). Overall, streams in a human-dominated landscape of southern Wisconsin were major regional sources of CH 4 to the atmosphere, equivalent to ~20% of dairy cattle emissions, or ~50% of a landfill’s annual emissions. We suggest that restoration of the benthic environment (reduced fine deposits) could lead to reduced CH 4 emissions, while decreasing nutrient loading is likely to have limited impacts to this ecosystem process.

Wisconsin↗

Effects of climate change on long-term population growth of pronghorn in an arid environment

Climate often drives ungulate population dynamics, and as climates change, some areas may become unsuitable for species persistence. Unraveling the relationships between climate and population dynamics, and projecting them across time, advances ecological understanding that informs and steers sustainable conservation for species. Using pronghorn ( Antilocapra americana ) as an ecological model, we used a Bayesian approach to analyze long-term population, precipitation, and temperature data from 18 populations in the southwestern United States. We determined which long-term (12 and 24 months) or short-term (gestation trimester and lactation period) climatic conditions best predicted annual rate of population growth (λ). We used these predictions to project population trends through 2090. Projections incorporated downscaled climatic data matched to pronghorn range for each population, given a high and a lower atmospheric CO 2 concentration scenario. Since the 1990s, 15 of the pronghorn populations declined in abundance. Sixteen populations demonstrated a significant relationship between precipitation and λ, and in 13 of these, temperature was also significant. Precipitation predictors of λ were highly seasonal, with lactation being the most important period, followed by early and late gestation. The influence of temperature on λ was less seasonal than precipitation, and lacked a clear temporal pattern. The climatic projections indicated that all of these pronghorn populations would experience increased temperatures, while the direction and magnitude of precipitation had high population-specific variation. Models predicted that nine populations would be extirpated or approaching extirpation by 2090. Results were consistent across both atmospheric CO 2 concentration scenarios, indicating robustness of trends irrespective of climatic severity. In the southwestern United States, the climate underpinning pronghorn populations is shifting, making conditions increasingly inhospitable to pronghorn persistence. This realization informs and steers conservation and management decisions for pronghorn in North America, while exemplifying how similar research can aid ungulates inhabiting arid regions and confronting similar circumstances elsewhere.

Ecosphere↗

Evasion of added isotopic mercury from a northern temperate lake

Isotopically enriched Hg (90% 202Hg) was added to a small lake in Ontario, Canada, at a rate equivalent to approximately threefold the annual direct atmospheric deposition rate that is typical of the northeastern United States. The Hg spike was thoroughly mixed into the epilimnion in nine separate events at two-week intervals throughout the summer growing season for three consecutive years. We measured concentrations of spike and ambient dissolved gaseous Hg (DGM) concentrations in surface water and the rate of volatilization of Hg from the lake on four separate, week-long sampling periods using floating dynamic flux chambers. The relationship between empirically measured rates of spike-Hg evasion were evaluated as functions of DGM concentration, wind velocity, and solar illumination. No individual environmental variable proved to be a strong predictor of the evasion flux. The DGM-normalized flux (expressed as the mass transfer coefficient, k) varied with wind velocity in a manner consistent with existing models of evasion of volatile solutes from natural waters but was higher than model estimates at low wind velocity. The empirical data were used to construct a description of evasion flux as a function of total dissolved Hg, wind, and solar illumination. That model was then applied to data for three summers for the experiment to generate estimates of Hg re-emission from the lake surface to the atmosphere. Based on ratios of spike Hg to ambient Hg in DGM and dissolved total Hg pools, ratios of DGM to total Hg in spike and ambient Hg pools, and flux estimates of spike and ambient Hg, we concluded that the added Hg spike was chemically indistinguishable from the ambient Hg in its behavior. Approximately 45% of Hg added to the lake over the summer was lost via volatilization.

Ontario↗

Application of a source apportionment model in consideration of volatile organic compounds in an urban stream

Position-dependent concentrations of trichloroethylene and methyl-tert-butyl ether are considered for a 2.81-km section of the Aberjona River in Massachusetts, USA. This river flows through Woburn and Winchester (Massachusetts, USA), an area that is highly urbanized, has a long history of industrial activities dating to the early 1800s, and has gained national attention because of contamination from chlorinated solvent compounds in Woburn wells G and H. The river study section is in Winchester and begins approximately five stream kilometers downstream from the Woburn wells superfund site. Approximately 300 toxic release sites are documented in the watershed upstream from the terminus of the study section. The inflow to the river study section is considered one source of contamination. Other sources are the atmosphere, a tributary flow, and groundwater flows entering the river; the latter are categorized according to stream zone (1, 2, 3, etc.). Loss processes considered include outflows to groundwater and water-to-atmosphere transfer of volatile compounds. For both trichloroethylene and methyl-rerf-butyl ether, degradation is neglected over the timescale of interest. Source apportionment fractions with assigned values ??inflow, ??1, ??2, ??3, etc. are tracked by a source apportionment model. The strengths of the groundwater and tributary sources serve as fitting parameters when minimizing a reduced least squares statistic between water concentrations measured during a synoptic study in July 2001 versus predictions from the model. The model fits provide strong evidence of substantial unknown groundwater sources of trichloroethylene and methyl-tert-butyl ether amounting to tens of grams per day of trichloroethylene and methyl-tert-butyl ether in the river along the study section. Modeling in a source apportionment manner can be useful to water quality managers allocating limited resources for remediation and source control. ?? 2007 SETAC.

Environmental Toxicology and Chemistry↗

A search for scale in sea-level studies

Many researchers assume a proportional relationship among the atmospheric CO2 concentration, temperature, and sea level. Thus, the rate of sea-level rise should increase in concert with the documented exponential increase in CO2. Although sea surface temperature has increased in places over the past century and short-term sea level rose abruptly during the 1990s, it is difficult to demonstrate a proportional relationship using existing geologic or historic records. Tide gauge records in the United States cover too short a time interval to verify acceleration in the rate of sea-level rise, although multicentury tide gauge and staff records from the Netherlands and Sweden suggest a mid-19th-century acceleration in sea-level rise. Reconstructions of sea-level changes for the past 1000 years derived using benthic foraminifer data from salt marshes along the East Coast of the United States suggest an increased rate of relative sea-level rise beginning in the 1600s. Geologic records of relative sea-level rise for the past 6000 years are available for several sites along the US East Coast from 14C-dated basal peat below salt marshes and estuarine sediments. When these three scales of sea-level variation are integrated, adjusted for postglacial isostatic movement, and replotted, the range of variation in sea level suggested by basal peat ages is within ??1 meter of the long-term trend. The reconstruction from Long Island Sound data shows a linear rise in sea level beginning in the mid-1600s at a rate consistent with the historic record of mean high water. Long-term tide gauge records from Europe and North America show similar trends since the mid-19th century. There is no clear proportional exponential increase in the rate of sea-level rise. If proportionality exists among sea level, atmospheric CO2, and temperature, there may be a significant time lag before an anthropogenic increase in the rate of sea-level rise occurs.

Journal of Coastal Research↗

The Spar Lake strata-Bound Cu-Ag deposit formed across a mixing zone between trapped natural gas and metals-bearing brine

Ore formation at the Spar Lake red bed-associated strata-bound Cu deposit took place across a mixing and reaction zone between a hot oxidized metals-transporting brine and a reservoir of “sour” (H 2 S-bearing) natural gas trapped in the host sandstones. Fluid inclusion volatile analyses have very high CH 4 concentrations (≥1 mol % in most samples), and a sample from the fringe of the deposit has between 18 and 36 mol % CH 4 . The ratio of CH 4 /CO 2 in fluid inclusions appears to vary regularly across the deposit, with the lowest CH 4 /CO 2 ratios from high-grade chalcocite-bearing ore, and the highest from the chalcopyrite-bearing fringe. The helium R/R a isotope ratios (0.23–0.98) and concentrations define a mixture between crustal and atmospheric helium. The volatiles in fluid inclusions (CH 4 , CO 2 , H 2 S, SO 2 , H 2 , H 2 O, and other organic gases) and values of f O 2 and temperature calculated from the volatiles data all show gradations across the deposit that are completely consistent with such a mixing and reaction zone. Other volatiles from the fluid inclusions (HCl, HF, 3 He, Msup>4 He, N 2 , Ar) characterize the brine and give evidence for only shallow crustal fluids with no magmatic influences. The brine entered the gas reservoir from below and along the axis of the deposit and migrated out along bedding to the southwest, northeast, and northwest. Metals-transporting brines may have been fed into the host sandstones from the East Fault, but that remains uncertain. Abundant ore-stage Fe and Mn calcite cements from the reduced fringe have δ 13 C values as low as −18.4‰, and many values less than −10‰, which indicate that significant carbonate was generated by oxidation of organic carbon from the natural gas. The zone of calcite cements with very low δ 13 C values approximately envelopes chalcocite-bearing ore. Sulfur isotope data of Cu, Pb, and Fe sulfides and barite indicate derivation of roughly half of the orebody sulfide directly from sour gas H 2 S. That sour gas H 2 S had developed in steps known from other sedimentary basins, starting with (1) bacterial sulfate reduction (BSR) of seawater sulfate having δ 34 S of about 20‰ and sequestering of the sulfide in organic matter in source rocks stratigraphically below the deposit host rocks, followed by (2) maturation of the sulfide-bearing organic matter into liquid petroleum with relatively homogeneous sulfide having δ 34 S of 5 ± 5‰, then by (3) thermal cracking of the oil to CH 4 and H 2 S with relatively homogeneous sulfide having δ 34 S closely distributed, about 6‰. The CH 4 and H 2 S migrated and were trapped in sandstones of the upper member of the Revett Formation, where they were later met by the 200°C metals-transporting brine. There was additional contribution of sulfide to ore from later thermochemical sulfate reduction (TSR) operating on sulfate δ 34 S of 20 to 29‰ in both formation waters and metals-transporting solutions. A large range of δ 34 S in sulfides resulted as the 6‰ sour gas sulfide was supplemented with varying proportions of 20 to 29‰ sulfide from TSR.

Economic Geology↗

Some limitations on the possible composition of the ore-forming fluid

The activity ratios of various important anions (S (super =) , CO 3 (super =) , SO 4 (super =) , OH (super -) , F (super -) , and Cl (super -) ) in hydrothermal solutions at the time of deposition are evaluated using a simple thermodynamic technique. The ratios are interpreted in the light of the mineralogy of ore deposits and limits are placed on the variability of each ratio in hydrothermal solutions. All of the calculations are made for 25 degrees C and cautious extrapolation to higher temperatures seems justified; however, additional data for elevated temperatures and pressures are needed before more than approximate values may be assigned to these ratios in the ore-forming fluid.The calculated partial pressure of CO 2 in the ore fluid is generally less than one atmosphere, which suggests that a dense CO 2 phase cannot be considered an important ore fluid for most deposits. The partial pressure of H 2 S is usually less than 10 (super -4) atmosphere, which makes it extremely difficult to defend the theory that metals (other than the easily complexible mercury, arsenic, antimony, and perhaps gold and silver) are transported in quantity as complex sulfides or hydrosulfides. The sulfate to sulfide ratio is such that the oxidation potential at the time of deposition is defined by the following equation: Eh (in volts) = 0.22 + or - 0.04 - 0.059 pH.

Economic Geology↗

Nitrogen loads through baseflow, stormflow, and underflow to Rehoboth Bay, Delaware

A detailed study of water and nitrogen (N) discharge from a small, representative subwatershed of Rehoboth Bay, Delaware, was conducted to determine total N loads to the bay. The concentrations of ammonium (NH 4+), nitrate + nitrite (NO3- + NO2-), and dissolved and particulate organic N were determined in baseflow and storm waters discharging from Bundicks Branch from October 1998 to April 2002. A novel hydrographic separation model that accounts for significant decreases in baseflow during storm events was developed to estimate N loads during unsampled storms. Nitrogen loads based on gauged flows alone (7100-19100 kg/yr) significantly underestimated those based on land use-land cover (LULC) and estimated N export factors from different classes of LULC (32000-40600 kg/yr). However, when ungauged underflow and associated N loads were included in the total loads (25500-33800 kg/yr), there was much better agreement with LULC export models. This suggests that in permeable coastal plain sediments, underflow contributes significantly to N fluxes to estuarine receiving waters, particularly in drier years. Based on the similarity in LULC, N loads from the Bundicks Branch subwatershed were used to estimate upland loads to the entire Rehoboth Bay Watershed (259000-316000 kg/yr). These N loads from the watershed were much greater than those from direct atmospheric deposition (49000-64500 kg/yr) and from a local wastewater treatment plant (9700-13700 kg/yr). While the watershed was the principal source of N at all times during the year, the relative contributions from the watershed, wastewater, and direct atmospheric deposition varied predictably with season. ?? ASA, CSSA, SSSA.

Journal of Environmental Quality↗

Calcium depletion in a Southeastern United States forest ecosystem

Forest soil Ca depletion through leaching and vegetation uptake may threaten long-term sustainability of forest productivity in the southeastern USA. This study was conducted to assess Ca pools and fluxes in a representative southern Piedmont forest to determine the soil Ca depletion rate. Soil Ca storage, Ca inputs in atmospheric deposition, and outputs in soil leaching and vegetation uptake were investigated at the Panola Mountain Research Watershed (PMRW) near Atlanta, GA. Average annual outputs of 12.3 kg ha −1 yr −1 in uptake into merchantable wood and 2.71 kg ha −1 yr −1 soil leaching exceeded inputs in atmospheric deposition of 2.24 kg ha −1 yr −1 The annual rate of Ca uptake into merchantable wood exceeds soil leaching losses by a factor of more than five. The potential for primary mineral weathering to provide a substantial amount of Ca inputs is low. Estimates of Ca replenishment through mineral weathering in the surface 1 m of soil and saprolite was estimated to be 0.12 kg ha −1 yr −1 The weathering rate in saprolite and partially weathered bedrock below the surface 1 m is similarly quite low because mineral Ca is largely depleted. The soil Ca depletion rate at PMRW is estimated to be 12.7 kg ha −1 yr −1 At PMRW and similar hardwood-dominated forests in the Piedmont physiographic province, Ca depletion will probably reduce soil reserves to less than the requirement for a merchantable forest stand in ≈80 yr. This assessment and comparable analyses at other southeastern USA forest sites suggests that there is a strong potential for a regional problem in forest nutrition in the long term.

Soil Science Society of America Journal↗

Formation and loss of humic substances during decomposition in a pine forest floor

Since twice as much C is sequestered in soils as is contained in the atmosphere, the factors controlling the decomposition rate of soil C are important to the assessment of the effects of climatic change. The formation of chemically resistant humic substances might be an important process controlling recycling of CO 2 to the atmosphere. Our objectives were to measure the rate of formation and loss of humic substances during 13 yr of litter decomposition . We placed nets on the floor of a white pine (Pinus strobus) forest to separate each annual layer of litter for 13 yr and measured humic substance concentration using NaOH extraction followed by chromatographic fractionation. The humic acid fraction increased from 2.1% of the C in litterfall to 15.7% after 1 yr. On a grams per square meter (g m -2 ) basis the humic substance fraction increased during the first year and then declined, with a half decay time (t 1/2 ) of 5.1 yr, which was significantly slower than the bulk litter (t 1/2 = 3.9 yr). The carboxylic C concentration estimated from 13 C nuclear magnetic resonance (NMR) increased in the litter over time, though total mass of carboxylic acid C in the forest floor also declined over the 13-yr period (t 1/2 = 4.6 yr). While humic substances in the forest floor decomposed at a somewhat slower rate than bulk litter during Years 1 to 13, they decomposed much faster than has been calculated from 14 C dating of the refractory fraction of organic matter in the mineral soil.

Soil Science Society of America Journal↗

Experimental studies and model analysis of noble gas fractionation in porous media

The noble gases, which are chemically inert under normal terrestrial conditions but vary systematically across a wide range of atomic mass and diffusivity, offer a multicomponent approach to investigating gas dynamics in unsaturated soil horizons, including transfer of gas between saturated zones, unsaturated zones, and the atmosphere. To evaluate the degree to which fractionation of noble gases in the presence of an advective–diffusive flux agrees with existing theory, a simple laboratory sand column experiment was conducted. Pure CO2 was injected at the base of the column, providing a series of constant CO2 fluxes through the column. At five fixed sampling depths within the system, samples were collected for CO2 and noble gas analyses, and ambient pressures were measured. Both the advection–diffusion and dusty gas models were used to simulate the behavior of CO2 and noble gases under the experimental conditions, and the simulations were compared with the measured depth-dependent concentration profiles of the gases. Given the relatively high permeability of the sand column (5 ´ 10−11 m2), Knudsen diffusion terms were small, and both the dusty gas model and the advection–diffusion model accurately predicted the concentration profiles of the CO2 and atmospheric noble gases across a range of CO2 flux from ?700 to 10,000 g m−2 d−1. The agreement between predicted and measured gas concentrations demonstrated that, when applied to natural systems, the multi-component capability provided by the noble gases can be exploited to constrain component and total gas fluxes of non-conserved (CO2) and conserved (noble gas) species or attributes of the soil column relevant to gas transport, such as porosity, tortuosity, and gas saturation.

Vadose Zone Journal↗

Global warming and prairie wetlands: potential consequences for waterfowl habitat

The accumulation of greenhouse gasses in the atmosphere is expected to warm the earth's climate at an unprecedented rate (Ramanathan 1988, Schneider 1989). If the climate models are correct, within 100 years the earth will not only be warmer than it has been during the past million years, but the change will have occurred more rapidly than any on record. Many profound changes in the earth's environment are expected, including rising sea level, increasing aridity in continental interiors, and melting permafrost. Ecosystems are expected to respond variously to a rapidly changing climate. Tree ranges in eastern North American are expected to shift northward, and seed dispersal may not be adequate to maintain current diversity (Cohn 1989, Johnson and Webb 1989). In coastal wetlands, rising sea level from melting icecaps and thermal expansion could flood salt-grass marshes and generally reduce the size and productivity of the intertidal zone (Peters and Darling 1985). As yet, little attention has been given to the possible effects of climatic warming on inland prairie wetland ecosystems. These wetlands, located in the glaciated portion of the North American Great Plains (Figure 1), constitute the single most important breeding area for waterfowl on this continent (Hubbard 1988). This region annually produces 50-80% of the continent's total duck production (Batt et al. 1989). These marshes also support a variety of other wildlife, including many species of nongame birds, muskrat, and mink (Kantrud et al. 1989a). Prairie wetlands are relatively shallow, water-holding depressions that vary in size, water permanence, and water chemistry. Permanence types include temporary ponds (typically holding water for a few weeks in the springs), seasonal ponds (holding water from spring until early summer), semipermanent ponds (holding water throughout the growing season during most years), and large permanent lakes (Stewart and Kantrud 1971). Refilling usually occurs in spring from precipitation and runoff from melting snow on frozen or saturated soils (Figure 2). Annual water levels fluctuate widely due to climate variability in the Great Plains (Borchert 1950, Kantrud et al. 1989b). Climate affects the quality of habitat for breeding waterfowl by controlling regional water conditions--water depth, areal extent, and length of wet/dry cycles (Cowardin et al. 1988)--and vegetation patterns such as the cover ration (the ratio of emergent plant cover to open water). With increased levels of atmospheric carbon dioxide, climate models project warmer and, in some cases, drier conditions for the northern Great Plains (Karl et al. 1991, Manabe and Wetherald 1986, Mitchell 1983, Rind and Lebedeff 1984). In general, a warmer, drier climate could lower waterfowl production directly by increasing the frequency of dry basins and indirectly by producing less favorable cover rations (i.e., heavy emergent cover with few or no open-water areas). The possibility of diminished waterfowl production in a greenhouse climate comes at a time when waterfowl numbers have sharply declined for other reasons (Johnson and Shaffer 1987). Breeding habitat continues to be lost or altered by agriculture, grazing, burning, mowing, sedimentation, and drainage (Kantrud et al. 1989b). For example, it has been estimated that 60% of the wetland area in North Dakota has been drained (Tiner 1984). Pesticides entering wetlands from adjacent agricultural fields have been destructive to aquatic invertebrate populations and have significantly lowered duckling survival (Grue et al. 1988). In this article, we discuss current understanding and projections of global warming; review wetland vegetation dynamics to establish the strong relationship among climate, wetland hydrology, vegetation patterns, and waterflow habitat; discuss the potential effects of a greenhouse warming on these relationships; and illustrate the potential effects of climate change on wetland habitat by using a simulation model. The extent to which intensive management of the waterfowl resource will be needed in the future strongly depends on whether a changing climate exacerbates the current problem of waterfowl decline. Should this occur, efforts outlined the recent North American Waterfowl Management Plan between the United States and Canada to reduce the current decline (Patterson and Nelson 1988) may need to be redoubled in coming years.

BioScience↗

Early Pliocene (Zanclean) stratigraphic framework for PRISM5/PlioMIP3 time slices

Global reconstructions of Pliocene climate provide important insights into how the climate system operates under elevated temperatures and atmospheric CO2 levels. These reconstructions have been used extensively in paleoclimate modeling experiments for comparison to simulated conditions, and as boundary conditions.Most previous work focused on the Late Pliocene interval known as the mid Piacenzian Warm Period (mPWP), the interval originally identified by the U.S. Geological Survey Pliocene Research, Interpretation and Synoptic Mapping Project (PRISM) as the PRISM interval or Mid Pliocene Warm Period. The term Mid Pliocene Warm Period is a misnomer due to changes to the geological time scale, and its use should be discontinued. The Pliocene Model Intercomparison Project (PlioMIP), now in its third phase, is expanding to include a focus on the Early Pliocene (Zanclean). PlioMIP3 experiments will allow comparison of environmental and climatic conditions before and after closure of the Central American Seaway (CAS). PlioMIP3 used the annual insolation pattern at the top of the atmosphere to determine time slices in the Zanclean that have orbital configurations that are most similar to modern. Two have been selected by PlioMIP and adopted by PRISM for inclusion in future studies: PRISM5.1 (4.474 Ma) and PRISM5.2 (4.870 Ma). Here we establish the stratigraphic framework for these Early Pliocene time slices and furnish information to help locate these intervals in proxy records of paleoenvironmental data using oxygen isotope stratigraphy, paleomagnetic stratigraphy, biostratigraphy, and biochronology (calibrated planktic foraminifer and calcareous nannofossil events).

Stratigraphy↗

Effects of external water on volcanic column height and collapse

Volcanic plumes are important because they spread volcanic material, can impact climate, and pose hazards to aviation. Among eruption processes, column collapse is arguably the most consequential in terms of direct impacts, as it marks the onset of ground-hugging pyroclastic density currents that pose the greatest immediate threat to life and infrastructure. This study inves- tigates how external water, such as is incorporated during subaqueous eruptions, affects the critical condition (including mass eruption rate, temperature, and gas fraction) at which column collapse occurs in the atmosphere, referred to as “the column collapse condition”. We use the 1-D plume model, Plumeria , to explore how variations in external water (0–60 wt.%), vent exit velocity (75–125 m s −1 ), and initial magma temperature (700–1100 °C) affect the column collapse condition. We find that the occurrence of column collapse is highly sensitive to the amount of external water. Small amounts of external water (⪅ 25 wt.%) suppress column collapse, whereas higher amounts of water encourage collapse. Using more than 150,000 simulations, we map out the highly non-linear shape of the column collapse condition as a function of mass eruption rates and external water contents. The Richardson number, the ratio of buoyancy to shear forces, offers a useful framework for defining the column collapse condition for eruptions involving external water. This work enhances our understanding of how external water ingestion affects volcanic plume dynamics, including height and column collapse conditions. Recent shallow submarine eruptions that produced very tall atmospheric plumes and partial column collapse (e.g. the 2021 Fukutoku-Oka-no-Ba eruption in Japan and the 2022 Hunga eruption in Tonga) demonstrate the importance of understanding how external water influences the collapse of eruption columns.

Volcanica↗

Biophysical warming patterns of an open-top chamber and its short-term influence on a Phragmites wetland ecosystem in China

Passive-warming, open-top chambers (OTCs) are widely applied for studying the effects of future climate warming on coastal wetlands. In this study, a set of six OTCs were established at a Phragmites wetland located in the Yellow River Delta of Dongying City, China. With data collected through online transmission and in-situ sensors, the attributes and patterns of realized OTCs warming are demonstrated. The authors also quantified the preliminary influence of experimental chamber warming on plant traits. OTCs produced an elevated average air temperature of 0.8°C (relative to controls) during the growing season (June to October) of 2018, and soil temperatures actually decreased by 0.54°C at a depth of 5 cm and 0.46°C at a depth of 30 cm in the OTCs. Variations in diel patterns of warming depend greatly on the heat sources of incoming radiation in the daytime versus soil heat flux at night. Warming effects were often larger during instantaneous analyses and influenced OTCs air temperatures from −2.5°C to 8.3°C dependent on various meteorological conditions at any given time, ranging from cooling influences from vertical heat exchange and vegetation to radiation-associated warming. Night-time temperature depressions in the OTCs were due to the low turbulence inside OTCs and changes in surface soil-atmosphere heat transfer. Plant shoot density, basal diameter, and biomass of Phragmites decreased by 23.2%, 6.3%, and 34.0%, respectively, under experimental warming versus controls, and plant height increased by 4.3%, reflecting less carbon allocation to stem structures as plants in the OTCs experienced simultaneous wind buffering. While these passive-warming OTCs created the desired warming effects both to the atmosphere and soils, pest damages on the plant leaves and lodging within the OTCs were extensive and serious, creating the need to consider control options for these chambers and the replicated OTCs studies underway in other Chinese Phragmites marshes (Panjin and Yancheng).

Shandong Province↗

Geothermal energy: clean power from the Earth's heat

Societies in the 21st century require enormous amounts of energy to drive the machines of commerce and to sustain the lifestyles that many people have come to expect. Today, most of this energy is derived from oil, natural gas, and coal, supplemented by nuclear power. Local exceptions exist, but oil is by far the most common source of energy worldwide. Oil resources, however, are nonrenewable and concentrated in only a few places around the globe, creating uncertainty in long-term supply for many nations. At the time of the Middle East oil embargo of the 1970s, about a third of the United States oil supply was imported, mostly from that region. An interruption in the flow of this import disrupted nearly every citizen’s daily life, as well as the Nation’s economy. In response, the Federal Government launched substantial programs to accelerate development of means to increasingly harness “alternative energies”—primarily biomass, geothermal, solar, and wind. The new emphasis on simultaneously pursuing development of several sources of energy recognized the timeless wisdom found in the proverb of “not putting all eggs in one basket.” This book helps explain the role that geothermal resources can play in helping promote such diversity and in satisfying our Nation’s vast energy needs as we enter a new millennium. For centuries, people have enjoyed the benefits of geothermal energy available at hot springs, but it is only through technological advances made during the 20th century that we can tap this energy source in the subsurface and use it in a variety of ways, including the generation of electricity. Geothermal resources are simply exploitable concentrations of the Earth’s natural heat (thermal energy). The Earth is a bountiful source of thermal energy, continuously producing heat at depth, primarily by the decay of naturally occurring radioactive isotopes—principally of uranium, thorium, and potassium—that occur in small amounts in all rocks. This heat then rises to and through the Earth’s surface, where it escapes into the atmosphere. The amount of heat that flows annually from the Earth into the atmosphere is enormous—equivalent to ten times the annual energy consumption of the United States and more than that needed to power all nations of the world, if it could be fully harnessed. Even if only 1 percent of the thermal energy contained within the uppermost 10 kilometers of our planet could be tapped, this amount would be 500 times that contained in all oil and gas resources of the world. How might we benefit from this vast amount of thermal energy beneath our feet? Where, by what means, and how much of the Earth’s natural heat can be usefully harnessed? These are especially important questions to contemplate, because global population is expected to soon exceed seven billion and many scientists believe that the world’s fossilfuel resources may be substantially depleted within this century. Faced with such prospects, both the public and private sectors are working toward more fully utilizing the Earth’s abundant thermal energy and other alternative energy resources. A skeptic might question the wisdom of devoting much national effort to geothermal energy development, especially because many experts think that geothermal heat can contribute at most about 10 percent to the Nation’s energy supply using current technologies. However, ongoing advances in exploration and heat-extraction technologies are improving our ability to use the resource and may substantially increase the geothermal contribution to the Nation’s energy supply. In an attempt to help national planners and average citizens alike understand the nature and energy potential of geothermal resources, this book (1) describes the distribution and nature of geothermal energy, (2) reviews the common types of geothermal systems that provide useful energy with current technology, (3) considers potential geothermal resources that might someday be tapped with developing technologies, and (4) summarizes the role of earth-science information in assessing and harnessing geothermal resources wherever they occur worldwide. The predecessor to this book (Tapping the Earth’s Natural Heat, U.S. Geological Survey Circular 1125, published in 1994) summarized the situation in the early 1990s. In an effort to support national energy planners, this new circular incorporates more recent advances in geothermal science and technology.

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