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USGS2012

Method for estimating potential wetland extent by utilizing streamflow statistics and flood-inundation mapping techniques: Pilot study for land along the Wabash River near Terre Haute, Indiana

Potential wetland extents were estimated for a 14-mile reach of the Wabash River near Terre Haute, Indiana. This pilot study was completed by the U.S. Geological Survey in cooperation with the U.S. Department of Agriculture, Natural Resources Conservation Service (NRCS). The study showed that potential wetland extents can be estimated by analyzing streamflow statistics with the available streamgage data, calculating the approximate water-surface elevation along the river, and generating maps by use of flood-inundation mapping techniques. Planning successful restorations for Wetland Reserve Program (WRP) easements requires a determination of areas that show evidence of being in a zone prone to sustained or frequent flooding. Zone determinations of this type are used by WRP planners to define the actively inundated area and make decisions on restoration-practice installation. According to WRP planning guidelines, a site needs to show evidence of being in an "inundation zone" that is prone to sustained or frequent flooding for a period of 7 consecutive days at least once every 2 years on average in order to meet the planning criteria for determining a wetland for a restoration in agricultural land. By calculating the annual highest 7-consecutive-day mean discharge with a 2-year recurrence interval (7MQ2) at a streamgage on the basis of available streamflow data, one can determine the water-surface elevation corresponding to the calculated flow that defines the estimated inundation zone along the river. By using the estimated water-surface elevation ("inundation elevation") along the river, an approximate extent of potential wetland for a restoration in agricultural land can be mapped. As part of the pilot study, a set of maps representing the estimated potential wetland extents was generated in a geographic information system (GIS) application by combining (1) a digital water-surface plane representing the surface of inundation elevation that sloped in the downstream direction of flow and (2) land-surface elevation data. These map products from the pilot study will aid the NRCS and its partners with the onsite inundation-zone verification in agricultural land for a potential restoration and will assist in determining at what elevation to plant hardwood trees for increased survivability on ground above frequently flooded terraces.

Indiana↗

USGS2013

Concentration, flux, and the analysis of trends of total and dissolved phosphorus, total nitrogen, and chloride in 18 tributaries to Lake Champlain, Vermont and New York, 1990–2011

Annual concentration, flux, and yield for total phosphorus, dissolved phosphorus, total nitrogen, and chloride for 18 tributaries to Lake Champlain were estimated for 1990 through 2011 using a weighted regression method based on time, tributary streamflows (discharges), and seasonal factors. The weighted regression method generated two series of daily estimates of flux and concentration during the period of record: one based on observed discharges and a second based on a flow-normalization procedure that removes random variation due to year-to-year climate-driven effects. The flownormalized estimate for a given date is similar to an average estimate of concentration or flux that would be made if all of the observed discharges for that date were equally likely to have occurred. The flux bias statistic showed that 68 of the 72 flux regression models were minimally biased. Temporal trends in the concentrations and fluxes were determined by calculating percent changes in flow-normalized annual fluxes for the full period of analysis (1990 through 2010) and for the decades 1990–2000 and 2000–2010. Basinwide, flow-normalized total phosphorus flux decreased by 42 metric tons per year (t/yr) between 1990 and 2010. This net result reflects a basinwide decrease in flux of 21 metric tons (t) between 1990 and 2000, followed by a decrease of 20 t between 2000 and 2010; both results were largely influenced by flux patterns in the large tributaries on the eastern side of the basin. A comparison of results for total phosphorus for the two separate decades of analysis found that more tributaries had decreasing concentrations and flux rates in the second decade than the first. An overall reduction in dissolved phosphorus flux of 0.7 t/yr was seen in the Lake Champlain Basin during the full period of analysis. That very small net change in flux reflects substantial reductions between 1990 and 2000 from eastern tributaries, especially in Otter Creek and the LaPlatte and Winooski Rivers that largely were offset by increases in the Missisquoi and Saranac Rivers in the second decade (between 2000 and 2010). The number of tributaries that had increases in dissolved phosphorus concentrations stayed constant at 13 or 14 during the period of analysis. Total nitrogen concentration and flux for most of the monitored tributaries in the Lake Champlain Basin have decreased since 1990. Between 1990 and 2010, flow-normalized total nitrogen flux decreased by 386 t/yr, which reflects an increase of 440 t/yr between 1990 and 2000 and a decrease of 826 t/yr between 2000 and 2010. All individual tributaries except the Winooski River had decreases in total nitrogen concentration and flux between 2000 and 2010. The decrease in total nitrogen flux over the period of record could be related to the decrease in nitrogen from atmospheric deposition observed in Vermont or to concurrent benefits realized from the implementation of agricultural best-management practices in the Lake Champlain Basin that were designed primarily to reduce phosphorus runoff. For chloride, large increases in flow-normalized concentrations and flux between 1990 and 2000 for 17 of the 18 tributaries diminished to small increases or decreases between 2000 and 2010. Between 1990 and 2010, flow-normalized flux increased by 32,225 t/yr, 78 percent of which (25,163 t) was realized during the first decade, from 1990 through 2000. The five tributaries that had decreasing concentration and flux of chloride between 2000 and 2010 were all on the eastern side of Lake Champlain, possibly related to reductions since 1999 in winter road salt application in Vermont. Positive correlations of phosphorus flux and changes in phosphorus concentration and flux in tributaries with phosphorus inputs to basins from point sources, suggest that point sources have an effect on stream phosphorus chemistry. Several measures of changes in agricultural statistics, such as agricultural land use, acres of land in farms, acres of cropland, and acres of corn for grain or seed, are positively correlated with changes in phosphorus concentration or flux in the tributaries. Negative correlations of the amount of money spent on agricultural best-management practices with changes in phosphorus concentration or flux in the tributaries, suggest that best-management practices may be an effective tool, along with point-source reductions, in making progress towards management goals for phosphorus reductions in Lake Champlain.

New York;Vermont↗

USGS2014

Assessment of conservation easements, total phosphorus, and total suspended solids in West Fork Beaver Creek, Minnesota, 1999-2012

This study examined conservation easements and their effectiveness at reducing phosphorus and solids transport to streams. The U.S. Geological Survey cooperated with the Minnesota Board of Water and Soil Resources and worked collaboratively with the Hawk Creek Watershed Project to examine the West Fork Beaver Creek Basin in Renville County, which has the largest number of Reinvest In Minnesota land retirement contracts in the State (as of 2013). Among all conservation easement programs, a total of 24,218 acres of agricultural land were retired throughout Renville County, and 2,718 acres were retired in the West Fork Beaver Creek Basin from 1987 through 2012. Total land retirement increased steadily from 1987 until 2000. In 2000, land retirement increased sharply because of the Minnesota River Conservation Reserve Enhancement Program, then leveled off when the program ended in 2002. Streamflow data were collected during 1999 through 2011, and total phosphorus and total suspended solids data were collected during 1999 through 2012. During this period, the highest peak streamflow of 1,320 cubic feet per second was in March 2010. Total phosphorus and total suspended solids are constituents that tend to increase with increases in streamflow. Annual flow-weighted mean total-phosphorus concentrations ranged from 0.140 to 0.759 milligrams per liter, and annual flow-weighted mean total suspended solids concentrations ranged from 21.3 to 217 milligrams per liter. Annual flow-weighted mean total phosphorus and total suspended solids concentrations decreased steadily during the first 4 years of water-quality sample collection. A downward trend in flow-weighted mean total-phosphorus concentrations was significant from 1999 through 2008; however, flow-weighted total-phosphorus concentrations increased substantially in 2009, and the total phosphorus trend was no longer significant. The high annual flow-weighted mean concentrations for total phosphorus and total suspended solids in 2009 were affected by outlier concentrations documented in March 2009. Agricultural land-retirement data only were available through 2008; therefore, it was not possible to compare total phosphorus and total suspended solids concentrations to agricultural land-retirement data for 2009–11. A downward trend in annual flow-weighted mean total-phosphorus concentrations was related significantly to annual land retirement for 1999–2008. The relation between annual flow-weighted mean total suspended solids concentration and annual land retirement was not statistically significant for 1999–2008. If land-retirement data had been available for 2009–11, it is possible that the relation between total phosphorus and land retirement would no longer be evident because of the marked increase in flow-weighted concentrations during 2009. Alternatively, the increase in annual flow-weighted mean total-phosphorus concentrations during 2009–11 may be because of other factors, including industrial discharges, increases in drain tile installation, changes in land use including decreases in agricultural land retirement after 2008, increases in erosion, increases in phosphorus applications to fields, or unknown causes. Inclusion of land-retirement effects in agency planning along with other factors adds perspective with regard to the broader picture of interdependent systems and allows agencies to make informed decisions on the benefits of perpetual easements compared to limited duration easements.

Minnesota↗

USGS2014

Water movement through the unsaturated zone of the High Plains Aquifer in the Central Platte Natural Resources District, Nebraska, 2008-12

Uncertainty about the effects of land use and climate on water movement in the unsaturated zone and on groundwater recharge rates can lead to uncertainty in water budgets used for groundwater-flow models. To better understand these effects, a cooperative study between the U.S. Geological Survey and the Central Platte Natural Resources District was initiated in 2007 to determine field-based estimates of recharge rates in selected land-use areas of the Central Platte Natural Resources District in Nebraska. Measured total water potential and unsaturated-zone profiles of tritium, chloride, nitrate as nitrogen, and bromide, along with groundwater-age dates, were used to evaluate water movement in the unsaturated zone and groundwater recharge rates in the central Platte River study area. Eight study sites represented an east-west precipitation contrast across the study area—four beneath groundwater-irrigated cropland (sites 2, 5, and 6 were irrigated corn and site 7 was irrigated alfalfa/corn rotation), three beneath rangeland (sites 1, 4, and 8), and one beneath nonirrigated cropland, or dryland (site 3). Measurements of transient vertical gradients in total water potential indicated that periodic wetting fronts reached greater mean maximum depths beneath the irrigated sites than beneath the rangeland sites, in part, because of the presence of greater and constant antecedent moisture. Beneath the rangeland sites, greater temporal variation in antecedent moisture and total water potential existed and was, in part, likely a result of local precipitation and evapotranspiration. Moreover, greater variability was noticed in the total water potential profiles beneath the western sites than the corresponding eastern sites, which was attributed to less mean annual precipitation in the west. The depth of the peak post-bomb tritium concentration or the interface between the pre-bomb/post-bomb tritium, along with a tritium mass balance, within sampled soil profiles were used to estimate water fluxes in the unsaturated zone at three of the eight study sites: site 2 (irrigated), site 3 (dryland), and site 8 (rangeland). Estimates for recharge were about 68 millimeters per year [(mm/yr), post-bomb peak], 133 to 159 mm/yr (tritium interface), and 137 mm/yr (mass balance) at site 2 (irrigated); about 63 mm/yr (tritium interface) and 12 mm/yr (mass balance) at site 3 (dryland); and about 53 mm/yr (tritium interface) and 10 mm/yr (mass balance) at site 8 (rangeland). Recharge values from the mass balance at site 2 were more than an order of magnitude greater than recharge values at site 3, suggesting irrigation is an important control on water movement through the unsaturated zone. For the remaining five sites, the post-bomb tritium had flushed through the system and recharge was considered modern (within 10 years of sampling). The chloride mass-balance method was used to determine water fluxes below the root zone (less than 2 meters below land surface) at the rangeland sites: sites 1, 4, and 8. At these rangeland sites, water fluxes ranged from 1.8 to 96 mm/yr at site 1, 1.1 to 9.6 mm/yr at site 4, and 1.1 to 68 mm/yr at site 8, with mean rates of 21, 4.3, and 13 mm/yr, respectively. Site 1 had a greater mean water flux, which was consistent with the greater precipitation in the east than at site 8 in the west. Chloride mass balance was not calculated at the irrigated and dryland sites because of uncertainty about additional sources of chloride. Concentrations of nitrate as nitrogen in pore water in the unsaturated zone were larger beneath the irrigated and dryland (agricultural) sites compared with the rangeland sites. The larger concentrations at the agricultural sites are consistent with the application of nitrogen fertilizer at the agricultural sites and no substantial accumulation at the rangeland sites. The shape of the nitrate as nitrogen and chloride concentration profiles at site 1 (rangeland) indicate a reasonably larger and more consistent water flux in the UZ than beneath the other two rangeland sites (sites 4 or 8). Excluding site 7, the general shape of the nitrate as nitrogen profiles was similar beneath the agricultural sites and supports the estimates of water movement and recharge rates determined from the tritium and chloride methods. Movement of bromide through the unsaturated zone indicated greater water fluxes are found beneath irrigated lands than beneath rangeland. Bromide profiles in the unsaturated zone, determined from center of mass and peak displacement methods, document water fluxes ranged from 58 to 394 mm/yr beneath irrigated sites and 9 to 201 mm/yr beneath rangeland sites. Water-flux estimates from the potassium bromide tests at most sites did not represent overall recharge rates because the bromide remained primarily in the root zone. Apparent groundwater age was used to determine the groundwater residence time at the eight sites and to estimate recharge rates. Groundwater ages in the study area ranged from old water (defined here as groundwater that was recharged more than 50 years ago) to modern (defined here as groundwater that has recharged within the past 10 years). Groundwater ages indicated that the shallow monitoring wells generally had younger residence times, whereas the deeper monitoring wells generally had the older residence times. Groundwater dates from the shallowest monitoring wells were used to determine recharge rates at the water table. These rates generally were similar to recharge rates determined from tritium and chloride mass-balance methods. Groundwater recharge rates generally increased with well depth, and the deeper monitoring wells likely do not represent local recharge conditions but recharge from a regional flow system that receives recharge from distant sources. Overall, these data generally indicate that water movement within the unsaturated zone primarily is affected by spatial contrasts in mean annual precipitation and by the land use or land cover. The eight unsaturated-zone sites each generated unique, valuable datasets that likely will improve the understanding of water movement and recharge rates in the central Platte River valley.

Nebraska↗

USGS2020

Spatially referenced models of streamflow and nitrogen, phosphorus, and suspended-sediment loads in streams of the northeastern United States

SPAtially Referenced Regression On Watershed attributes (SPARROW) models were developed to quantify and improve the understanding of the sources, fate, and transport of nitrogen, phosphorus, and suspended sediment in the northeastern United States. Excessive nutrients and suspended sediment from upland watersheds and tributary streams have contributed to ecological and economic degradation of northeastern surface waters. Recent efforts to reduce the flux of nutrients and suspended sediment in northeastern streams and to downstream estuaries have met with mixed results, and expected ecological improvements have been observed in some areas but not in others. Effective watershed management and restoration to improve surface-water quality are complicated by the multitude of nutrient sources in the Northeast and the multitude of natural and human landscape processes affecting the delivery of nutrients and suspended sediment from upland areas to and within surface waters. Individual models were constructed representing streamflow and the loads of total nitrogen, total phosphorus, and suspended sediment from watersheds draining to the Atlantic Ocean from southern Virginia through Maine. Northeastern streams contribute 303,000 metric tons (t) of nitrogen, 25,300 t of phosphorus, and 14,700,000 t of suspended sediment, annually (on average), to waters along the Atlantic Coast of North America. Although atmospheric deposition and natural mineral erosion contribute to nitrogen and phosphorus loads, respectively, in northeastern streams, most of the contributions are attributable to urban or agricultural sources. Within the Northeast, average yields of nutrients are therefore generally greater from densely populated or intensively cultivated areas of the mid-Atlantic region, the Hudson, Mohawk, and Connecticut River valleys, and the coastal areas of southern New England than in predominantly forested areas such as northern New England. Average upland sediment yields are similarly greater from agricultural areas than from urban or forested areas and are therefore generally greatest in areas yielding the greatest nutrients. Landscape conditions that are significant to nitrogen delivery from uplands to streams likely reflect the importance of groundwater transport in carbonate settings and of denitrification for removing nitrogen from uplands. Nitrogen losses to streams in agricultural areas are apparently mitigated by the use of cover crops but are exacerbated by the use of conservation tillage or no-till practices. The transport of phosphorus and suspended sediment from uplands to streams is greater in areas of more erodible soils but mitigated in agricultural areas with greater use of conservation tillage or no-till practices. Loads of nutrients and suspended sediment are significantly reduced within the stream network in impounded reaches, and nitrogen load is also significantly reduced in small flowing reaches.

Scientific Investigations Report↗

USGS2020

Pilot-scale testing of dairy manure treatments to reduce nutrient transport from land application, northwest Ohio, 2015–17

Manure and wastewater from large livestock operations have the potential to negatively affect surface water and groundwater, including the eutrophication of surface waters and harmful algal blooms. In the Western Lake Erie Basin, where there is a high density of animal agriculture, harmful algal blooms have been attributed, in part, to phosphorus loading from dairy manure and fertilizer applications. Liquid lagoon manure produced by dairy operations typically has low nutrient concentrations and high-water content, so transportation costs are high relative to the value of the nutrients when applied to fields. Treatment systems are needed to transform manure into a dewatered product that is more economical to transport greater distances and that slows and (or) reduces the release of nutrients in soil, allowing nutrients to remain available for crop growth. This study was designed to pilot test a treatment solution in the Western Lake Erie Basin. The U.S. Geological Survey and Bowling Green State University field tested a dewatering treatment process (coagulant/polymer mixture) for dairy manure at pilot-scale test plots at The Ohio State University Agricultural Research and Development Center Northwest Agricultural Research Station. Automatic samplers were used to collect samples during 13 baseline and 9 post-manure application rainfall events that resulted in substantial surface runoff and (or) tile flow from October 2015 through early November 2017. Results are reported for three test plots that received liquid lagoon manure (raw manure) and three test plots that received polymer-treated manure (treated manure). Nutrient concentrations and flow volumes in surface runoff and tile flow were determined in baseline and post-manure application rainfall events. Nutrient concentration ranges are reported for 9 baseline and 9 post-manure application events as follows: dissolved reactive phosphorus, less than (<) 0.013−2.16 milligrams per liter (mg/L); nitrate plus nitrite, filtered, 0.32−77 mg/L; ammonia, filtered, <0.05−2.6 mg/L; total phosphorus, <0.01−12.8 mg/L; and total nitrogen, 1.49−77.2 mg/L. Volumes are reported for 6 baseline and 9 post-manure application rainfall events. None of the post-manure application runoff volumes were significantly different by plot or by treatment type (raw manure versus treated manure). Because concentrations alone do not reflect the true effects of different manure treatments, loads and flow-weighted mean concentrations of nutrients during post-manure application rainfall events were compared between plots with treated manure and those with raw manure. Loads of dissolved reactive phosphorus, total phosphorus, nitrate plus nitrite, and total nitrogen were calculated using the U.S. Geological Survey Graphical Constituent Loading and Analysis System. Loads of ammonia were not calculated because many of the ammonia concentrations were below the reporting limit. During the post-manure application period, higher nitrogen loads resulted from tile flow than surface runoff. For phosphorus, the opposite was true in that higher loads resulted from surface runoff than tile flow. Combined loads (surface runoff and tile flow) of dissolved reactive phosphorus were significantly different between raw manure and treated manure plots, but there was no significant difference in combined loads of total phosphorus, nitrate plus nitrite, or total nitrogen between raw manure and treated manure plots. Flow-weighted mean concentrations were calculated for the combined loads for the post-manure application rainfall events. Flow-weighted mean concentrations of dissolved reactive phosphorus and, to a lesser extent, total phosphorus were significantly different between raw manure and treated manure plots. Flow-weighted mean concentrations of nitrate plus nitrite and total nitrogen were not significantly different between raw manure and treated manure plots. The differences in loads and flow-weighted mean concentrations between raw manure and treated manure plots indicate that dissolved reactive phosphorus was likely retained in the soil and hydrological transport was reduced for the plots amended with the treated manure as compared to raw manure. Although confirmation field testing needs to be done, these results indicate that the use of this coagulant/polymer mixture shows potential in helping to reduce flow of dissolved phosphorus from agricultural fields with applied manure.

Ohio↗

USGS2021

Sediment budget for watersheds of West Maui, Hawaii

Episodic runoff brings suspended sediment to West Maui’s nearshore waters, turning them from blue to brown. This pollution degrades the ecological, cultural, and recreational value of these iconic nearshore waters. We used mapping, monitoring, and modeling to identify and quantify the watershed sources for fine sediment that pollutes the nearshore each year. These results focus strategies to reduce pollution on the outstanding sources for this sediment. Terrestrial runoff causing coastal plumes now occurs when two or more hours of rain falls at rates greater than 10–20 millimeter (mm) per hour in source watersheds. Analysis of recent and historical rainfall indicates that West Maui communities can expect rainfalls to bring coastal plumes at least 3–5 times per year. Former agricultural fields and some unimproved roads are possible sources for the fine sediment of these plumes. We found, however, that these obvious sources do not produce plumes during small annual storms, because they drain water at rates that far exceed most annual rainfalls and because there is no evidence for runoff from rains that caused recent plumes. Streambanks now eroding into historic fill terraces of sands, silts, and clays are a more plausible source. These terraces are found only downstream of historical agricultural fields and are composed of silt and fine sand. Surveys show that the fill terraces occupy ~40 percent of streambank length, making them extensive. During 2015–2016, these deposits eroded at median rates of 5–24 mm per year. Summed over West Maui’s watersheds, these rates imply sediment loads carried to the coast that can be ten times or more than modeled pre-human values. A sediment budget indicates that bank erosion of fill terraces from a few watersheds likely dominates the current annual fine-sediment load to the nearshore, with Kahana Stream watershed producing the largest annual input of 285 metric tons, the equivalent of 29 dump-truck loads every year. Although past large storms have contributed to sediment loading, annual plume generation is now caused by smaller rainfalls eroding these near-stream terrace deposits, a legacy of historic agriculture. Treatments of former agricultural fields, roads, and reserve forests are consequently not likely to measurably effect sediment pollution from smaller, more frequent storms. Increased runoff from residential and commercial development of West Maui has the potential to exacerbate sediment plumes from such storms.

Hawaii↗

USGS2021

Evaluation of hydrologic simulation models for fields with subsurface drainage to mitigated wetlands in Barnes, Dickey, and Sargent Counties, North Dakota

Proper identification of wetlands, along with a better understanding of the hydrology of mitigated wetlands, is needed to assist with conservation efforts aimed at maintaining the productivity and ecological function (wetland mitigation) of agricultural lands. The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Natural Resources Conservation Service, completed a study to evaluate two models for simulating hydrologic conditions in fields with subsurface drainage to mitigated wetlands at several sites in North Dakota. These two models were evaluated as possible tools for water resource managers to use for designing wetland mitigation projects in the area in the future. The Soil-Plant-Atmosphere-Water (SPAW) model simulates the daily hydrologic water budgets of agricultural landscapes by two linked routines, one for farm fields (field hydrology) and one for impoundments such as wetlands and ponds (pond model). The DRAINMOD model was used in conjunction with the SPAW model because although the SPAW model can be used to simulate the hydrology of small drainage basins containing wetlands, the SPAW model does not contain routines to simulate drainage, either subsurface drainage or surface (drainage ditches), that can directly affect the wetland hydrology. The wetlands in the study areas in this report are all downstream from and adjacent to drained agricultural fields. SPAW and DRAINMOD models were developed and calibrated at three study areas (study areas B, D, and S) to evaluate how the models simulated field-scale hydrologic characteristics and the water balance in wetlands from January 1, 2003, through December 31, 2018. The SPAW model developed for study area B included five modeled fields in the field hydrology portion of SPAW that contributed inflow to one wetland simulated in the pond model portion of SPAW. Simulated wetland water depths were most similar to water depths measured at site BWET1, with an absolute mean error of 0.10 foot and a root mean square error of 0.14 foot. Site BWET2 had slightly larger errors, with an absolute mean error of 0.22 foot and a root mean square error of 0.28 foot. Simulated water depths were similar to the pattern of measured water depths at BWET1 and BWET2 from about mid-April 2018 through about mid-September 2018, but overpredicted water depths in the fall from about mid-September 2018 through about mid-October 2018. The SPAW model developed for study area D included six modeled fields in the field hydrology portion of SPAW that contributed inflow to five wetlands connected in series in the pond model portion of SPAW. Simulated water depths compared relatively well to water depths in the five wetlands, with the absolute mean error ranging from 0.17 foot (DWET1) to 0.39 foot (DWET2), and the root mean square error ranging from 0.28 foot (DWET1) to 0.56 foot (DWET5). The SPAW model developed for study area S included one modeled field in the field hydrology portion of SPAW that contributed inflow to one wetland in the pond model portion of SPAW. Among the SPAW models developed for the three study areas, the model for study area S had the best comparison between simulated and measured water depths, with an absolute mean error of 0.06 foot and a root mean square error of 0.10 foot. DRAINMOD models were developed and calibrated at the three study areas and provided inflow from subsurface drainage discharge to the SPAW models for simulating water levels in wetlands in the study areas. The calibrated DRAINMOD model for study area B showed the variability of hydrologic processes in the modeled field throughout the wide range of hydrologic conditions from January 1, 2003, through December 31, 2018. In general, the discharge through the modeled subsurface drainage system was in the spring and early summer (April through June) most years, with little to no discharge later in the year. Although the subsurface drainage system in study area D was the most complex among the three study areas and was simplified into a uniform system within DRAINMOD, simulated water table depths at study area D correlated better to measured water table depths compared to results from the model applications at the other two study areas. Simulated water table depths had an absolute mean error of 0.30 foot and root mean square error of 0.37 foot at site DGW1 and an absolute mean error of 0.29 foot and a root mean square error of 0.34 foot at site DGW2. Although the subsurface drainage system in study area S was the simplest and the modeled field was the smallest among the three study areas, simulated water table depths at study area S did not correlate as well to measured water table depths compared to results from the model applications at the other two study areas. The SPAW and DRAINMOD model applications at the three study areas in southeast North Dakota adequately simulated the hydrologic processes for fields with subsurface drainage that are connected to adjacent wetlands. However, more measured data would be needed to fully evaluate the models throughout the range of possible climatic conditions.

North Dakota↗

USGS2022

Simulation of groundwater and surface-water resources of the San Antonio Creek Valley watershed, Santa Barbara County, California

In the San Antonio Creek Valley watershed (SACVW), western Santa Barbara County, California, groundwater is the primary source of water for agricultural irrigation, the town of Los Alamos, and supplemental water to Vandenberg Space Force Base (VSFB). Groundwater pumpage has increased since the 1970s as non-irrigated agricultural land has been converted to irrigated land and as local pumping for municipal use has increased. This increase in groundwater use has resulted in declining groundwater levels, adjustments in surface-water flows and species habitats, and changes in water quality. Water managers are addressing the challenges of meeting this increased demand while maintaining sustainable groundwater supplies. To address these challenges, Santa Barbara County Water Agency, Vandenberg Space Force Base (VSFB), and the U.S. Geological Survey (USGS) undertook a cooperative study to characterize the integrated hydrologic system of the SACVW and develop tools to better understand and manage the groundwater system. The objectives of this study were to improve the understanding of the integrated hydrologic system and incorporate the understanding into an integrated groundwater and surface-water flow model that can be used to help manage the water resources in the SACVW. The San Antonio Creek integrated model (SACIM) was developed using the USGS coupled groundwater and surface-water flow model to simulate the hydrologic system of the SACVW and provide annual and average water budgets for 1948–2018 water years. Results from the SACIM indicated that between 1948 and 2018, total groundwater from storage (storage depletion) for the period was 453,300 acre-feet (acre-ft). Agricultural pumpage was the largest discharge and accounted for a total of 1,020,000 acre-ft of groundwater. Increased pumpage since the mid-1980s (of which agricultural pumpage is the primary component) is tied to an increased rate of storage depletion and reduced rates of groundwater evapotranspiration and surface leakage (groundwater discharge to the surface and soil zone). The increased pumpage also reduced subsurface inflow to Barka Slough, resulting in a decline in upward flow through the underlying hydrogeologic units and surface leakage. In addition to quantifying historical changes in the integrated hydrologic system, the SACIM is a tool than can be used by water managers to evaluate the effects of different climatic and hydrologic conditions and management strategies.

California↗

USGS2023

Status and trends of total nitrogen and total phosphorus concentrations, loads, and yields in streams of Mississippi, water years 2008–18

To assess the status and trends of conditions of surface waters throughout Mississippi, the U.S. Geological Survey, in cooperation with the Mississippi Department of Environmental Quality (MDEQ), summarized concentrations and estimated loads, yields, trends, and spatial and temporal patterns of total nitrogen (TN) and total phosphorus (TP) at 20 stream sites in MDEQ’s ambient water-quality monitoring network and 2 stream sites in the U.S. Geological Survey’s National Water-Quality Assessment Project’s monitoring network. Comparison of streamflow at the time of water-quality sample collection to flow-duration curves for each site showed that samples were relatively evenly spread over a wide range of flows, indicating that load estimations were representative of a wide range of flows. Relation of streamflow to concentrations of TN and TP varied among sites and land use. Sites with high agriculture land use in the drainage basin tended to have a positive correlation between streamflow and concentration, suggesting influence of event-driven nonpoint-source runoff. Sites near urban (developed) areas tended to have a negative correlation between streamflow and concentration, suggesting chronic point-source influences during low-flow conditions. Sites with high forest land use and lower agriculture and urban (developed) land use showed little to no association between streamflow and concentration. Seasonal distributions of concentrations of TN and TP also corresponded closely with variations in land use. Sites near urban (developed) land had the highest concentrations in late summer and fall, sites with a high percentage of agricultural land had the highest concentrations in the spring, and sites that were primarily forested or with little developed land did not exhibit substantial changes in concentration across seasons. Eight sites had statistical likelihoods for upward trends of TN loads, and seven sites had statistical likelihoods for downward trends. Trends in TN loads at six sites were considered “about as likely as not,” meaning that a site has an equal chance of having an upward or downward trend. Trend results of mean annual flow-normalized loads of TP for the period of analysis (2008–18) showed that 16 sites had upward trends, 3 sites had downward trends, and 2 sites were considered “about as likely as not.” Results from our study were compared to results from existing regional models to assess accuracy of predictions at a local scale. Comparisons of yields predicted from 2012 regional-scale SPAtially Referenced Regressions on Watershed attributes (SPARROW) to results from this study showed the 2012 SPARROW-predicted estimates varied in consistency with results from this study. The 2012 SPARROW-prediction model underestimated TN yields, more often and by a slightly larger degree, more than it overestimated TN yields. The 2012 SPARROW-predicted model tended to underestimate yields at study sites with higher yields. All four sites in the predominantly agricultural area of northwest Mississippi, locally known as the Mississippi Delta, were underestimated by 2012 SPARROW. For TP, yield comparisons at sites with lower yields were consistent, yields at sites with midrange yields tended to be overestimated by SPARROW, and yields at sites with high yields tended to be underestimated by SPARROW. TP yields at four sites in the Mississippi Delta were underestimated by the 2012 SPARROW-predicted model. Results of select sites from our study were also compared to other published load estimates from an earlier time period to evaluate possible trends. Comparison of TN yields at four sites and TP yields at three sites from the study-derived estimates to estimates made from data spanning 1993–2004 showed decreasing TN yields at all four sites and decreasing TP yields at two of three sites, with increasing yields of TP at the Yazoo River lower site. Also, a third comparison of the TN and TP yields of the Yazoo River lower site of this study to estimates made from data spanning 1996–97 showed decreasing TN yields but similar TP yields. This suggests that TN yields may have decreased over the last 20–30 years, but TP yields remain constant or are increasing.

Mississippi↗

USGS2023

Evaluation of stream capture related to groundwater pumping, Lower Humboldt River Basin, Nevada

The Humboldt River Basin is the only river basin that is contained entirely within the State of Nevada. The effect of groundwater pumping on the Humboldt River is not well understood. Tools are needed to determine stream capture and manage groundwater pumping in the Humboldt River Basin. The objective of this study is to estimate capture and storage change caused by groundwater withdrawals in the lower Humboldt River Basin that can provide the Nevada State Engineer with data and information needed to manage groundwater and surface-water resources. A numerical groundwater flow model was developed for the purpose of estimating stream capture from pre-2016 and future pumping as well as for any location of potential future pumping within the lower Humboldt River Basin. This model was developed using MODFLOW-NWT to represent the lower Humboldt River Basin hydrologic system, including Humboldt River; Rye Patch Reservoir; groundwater evapotranspiration; pumping from municipal, agricultural, mining, and domestic wells; and agricultural drains. Aquifer properties were calibrated using results from numerous single- and multi-well aquifer tests (Nadler, 2020) and through the process of model calibration. Historical capture was estimated for 1960–2016 and predictive capture for the system was projected 100 years into the future (2017–2116) based on historical pumping patterns. Stream capture and drain capture are relatively low for the historical and predictive periods. During the historical period, increased pumping during dry years caused increased connections with capture sources and less water sourced to wells from aquifer storage. Storage and groundwater levels generally recovered during subsequent wet years. Overall, storage change has been the main source of water to wells in the lower Humboldt River Basin, followed by groundwater evapotranspiration capture. During the predictive period, pumping is projected to remain constant and capture 9 percent of stream water after 100 years. Capture and storage change maps were created to visualize spatial variability in potential capture and storage change through time and to provide a database of results that can be used to manage groundwater and surface-water resources. These maps show that potential stream capture would be a minor source of water to wells located across most of the simulated area, except for locations close to the Humboldt River and Rye Patch Reservoir. Drains also would be a minor potential source of water to wells except for those directly adjacent to the drains. In general, the potential supply of water to wells is storage-dominated and over time groundwater evapotranspiration-dominated in the agricultural area. Capture difference maps were generated to visualize where potential capture results might have greater limitations associated with nonlinear flow processes, such as head-dependent boundary conditions. Higher capture differences indicate larger capture map bias and therefore greater capture map uncertainty due to the inability of capture maps to account for nonlinear flow processes. Stream capture differences are highest directly adjacent to the river but are otherwise minimal. Drain capture differences are highest in the region of the agricultural drain network but are otherwise minimal. The Humboldt River, Rye Patch Reservoir, and drains introduce very little nonlinearity to the model, and their associated capture map bias is minimal. Potential groundwater evapotranspiration capture introduces a fair amount of nonlinearity to the model and has the potential to result in significant, localized groundwater evapotranspiration capture map bias over time. Groundwater evapotranspiration capture differences are the result of higher pumping rates lowering the water table below the root zone faster than lower pumping rates and essentially removing groundwater evapotranspiration as a potential source of capture faster than lower pumping rates. Wells that can no longer source their supply through groundwater evapotranspiration capture then generally source more of their water from storage. Thus, storage change bias increases over time as well. Capture prediction uncertainty due to parameter estimation was evaluated using a covariance matrix adaptation-evolution strategy. One hundred Monte Carlo realizations of model parameters were applied to the model to assess capture uncertainty at 13 grid cell locations within the model domain. In general, results indicated that greater capture uncertainty for a given source (river, drains, or evapotranspiration) is associated with proximity of a pumping well to that source. The magnitude of maximum capture fraction uncertainties after 100 years of pumping for stream capture, drain capture, groundwater evapotranspiration capture, and storage change were plus or minus (±) 0.17, ±0.10, ±0.20, and ±0.22, respectively.

Nevada↗

USGS2024

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon↗

USGS2000

Pesticides in surface water measured at select sites in the Sacramento River basin, California, 1996-1998

Pesticides were measured in one urban stream, one agricultural stream, one site on the Sacramento River, and one large flood control channel over a period of 18 months during 1996-1998. All sites were located within the Sacramento River Basin of California. Measurements were made on 83 pesticides or pesticide transformation products by either gas chromatography/mass spectrometry or by high performance liquid chromatography with ultraviolet light spectrometry. Some pesticides were detected frequently at the agricultural stream and downstream in the Sacramento River and at the flood control channel of the Sacramento River. These were pesticides related to rice farming (molinate, carbofuran, thiobencarb, and bentazon); herbicides used both agriculturally or for roadside maintenance (diuron, simazine, and metolachlor); or insecticides used on orchards and row corps (diazinon and chlorpyrifos). No pesticide concen-trations above enforceable water quality criteria were measured at either the agricultural site or the Sacramento River sites. In contrast to the agricul-tural site, insecticides used for household, lawn, or garden maintenance were the most frequently detected pesticides at the urban site. Diazinon, an organophosphate insecticide, exceeded recom-mended criteria for the protection of aquatic life, and the diazinon levels were frequently above known toxic levels for certain zooplankton species at the urban site. Because of the low discharge of the urban stream, pesticide concentrations were greatly diluted upon mixing with Sacramento River water.

California↗

USGS2003

Periphyton communities in streams of the Ozark Plateaus and their relations to selected environmental factors

During August through September of 1993- 95, 83 periphyton samples were collected at 51 stream sites in the Ozark Plateaus. These sites were categorized into six land-use categories (20 forest, 18 agriculture, 10 mining, 1 urban, 1 urban/ mining, and 1 mix), based on land-use percentages in the basin upstream from the site. Results indicate that periphyton communities of riffles of Ozark streams are affected by natural and land-use related factors. These factors include nutrients, dissolved organic carbon, alkalinity, canopy shading, suspended sediment, embeddedness, stream morphometry, and velocity. For several measures of periphyton communities, statistically significant (p<0.05) differences were found among sites assigned to agriculture, forest, and mining categories. Blue-green algae biovolume, relative abundance of blue-green algae, relative biovolume of diatoms, relative abundance of oligotrophic algae, relative abundance of tolerant taxa, and condition index values were among the measures that differed among land-use categories. Although no environmental factors were significantly correlated with total biovolume, several factors were significantly correlated with biovolume of blue-green algae or biovolume of diatoms. Biovolume of blue-green algae was correlated with percent agriculture land use. Biovolume of diatoms was correlated with orthophosphate, total phosphorus, alkalinity, velocity, embeddedness, and dissolved organic carbon. Diatoms often composed the largest percentage of the biovolume (relative biovolume). Diatom relative biovolume was much higher at mining sites (generally 75 to 90 percent of the total biovolume) than at forest or agriculture sites (generally 15 to 80 percent) and was correlated with several factors, including many land-use related factors. The diatoms Cymbella affinis and Cymbella delicatula and the blue-green algae Calothrix often were the most common (relative abundance and relative biovolume) algae in samples. Detrended correspondence analysis (DCA) and hierarchical cluster analyses results indicated differences among land-use category sites. The DCA results were correlated with a number of land-use related factors and channel morphometry. Grazers (specifically, snails and stonerollers) are related to periphyton biovolume and community composition. Total periphyton and diatom biovolume typically were highest at sites where snail density was lowest. Lower relative abundances of diatoms usually occurred at sites with higher snail densities and stoneroller relative abundances.

Arkansas, Kansas, Missouri, Oklahoma↗

USGS2002

Possible sources of nitrate in ground water at swine licensed-managed feeding operations in Oklahoma, 2001

Samples collected and analyzed by the Oklahoma Department of Agriculture, Food, and Forestry from 1999 to 2001 determined that nitrate exceeded the U.S. Environmental Protection Agency maximum contaminant level for public drinking-water supplies of 10 milligrams per liter as nitrogen in 79 monitoring wells at 35 swine licensed-managed feeding operations (LMFO) in Oklahoma. The LMFOs are located in rural agricultural settings where long-term agriculture has potentially affected the ground-water quality in some areas. Land use prior to the construction of the LMFOs was assessed to evaluate the types of agricultural land use within a 500-meter radius of the sampled wells. Chemical and microbiological techniques were used to determine the possible sources of nitrate in water sampled from 10 wastewater lagoons and 79 wells. Samples were analyzed for dissolved major ions, dissolved trace elements, dissolved nutrients, nitrogen isotope ratios of nitrate and ammonia, wastewater organic compounds, and fecal coliform bacteria. Bacteria ribotyping analysis was done on selected samples to identify possible specific animal sources. A decision process was developed to identify the possible sources of nitrate. First, nitrogen isotope ratios were used to define sources as animal, mixed animal and fertilizer, or fertilizer. Second, wastewater organic compound detections, nitrogen-isotope ratios, fecal coliform bacteria detections, and ribotyping were used to refine the identification of possible sources as LFMO waste, fertilizer, or unidentified animal or mixtures of these sources. Additional evidence provided by ribotyping and wastewater organic compound data can, in some cases, specifically indicate the animal source. Detections of three or more wastewater organic compounds that are indicators of animal sources and detections of fecal coliform bacteria provided additional evidence of an animal source. LMFO waste was designated as a possible source of nitrate in water from 10 wells. The source of waste in water from five of those wells was determined through ribotyping, and the source of waste in water from the remaining five wells was determined by detections of three or more animal-waste compounds in the well samples. LMFO waste in the water from wells with unidentified animal source of nitrate does not indicate that LMFO waste was not the source, but indicated that multiple animal sources, including LMFO waste, may be the source of the nitrate.

Water-Resources Investigations Report↗

USGS2003

Nitrogen and phosphorus in streams of the Great Miami River Basin, Ohio, 1998–2000

Sources and loads of nitrogen and phosphorus in streams of the Great Miami River Basin were evaluated as part of the National Water-Quality Assessment program. Water samples were collected by the U.S. Geological Survey from October 1998 through September 2000 (water years 1999 and 2000) at five locations in Ohio on a routine schedule and additionally during selected high streamflows. Stillwater River near Union, Great Miami River near Vandalia, and Mad River near Eagle City were selected to represent predominantly agricultural areas upstream from the Dayton metropolitan area. Holes Creek near Kettering is in the Dayton metropolitan area and was selected to represent an urban area in the Great Miami River Basin. Great Miami River at Hamilton is downstream from the Dayton and Hamilton-Middletown metropolitan areas and was selected to represent mixed agricultural and urban land uses of the Great Miami River Basin. Inputs of nitrogen and phosphorus to streams from point and nonpoint sources were estimated for the three agricultural basins and for the Great Miami River Basin as a whole. Nutrient inputs from point sources were computed from the facilities that discharge one-half million gallons or more per day into streams of the Great Miami River Basin. Nonpoint-source inputs estimated in this report are atmospheric deposition and commercial-fertilizer and manure applications. Loads of ammonia, nitrate, total nitrogen, orthophosphate, and total phosphorus from the five sites were computed with the ESTIMATOR program. The computations show nitrate to be the primary component of instream nitrogen loads, and particulate phosphorus to be the primary component of instream phosphorus loads. The Mad River contributed the smallest loads of total nitrogen and total phosphorus to the study area upstream from Dayton, whereas the Upper Great Miami River (upstream from Vandalia) contributed the largest loads of total nitrogen and total phosphorus to the Great Miami River Basin upstream from Dayton. An evaluation of monthly mean loads shows that nutrient loads were highest during winter 1999 and lowest during the drought of summer and autumn 1999. During the 1999 drought, point sources were the primary contributors of nitrogen and phosphorus loads to most of the study area. Nonpoint sources, however, were the primary contributors of nitrogen and phosphorus loads during months of high streamflow. Nonpoint sources were also the primary contributors of nitrogen loads to the Mad River during the 1999 drought, owing to unusually large amounts of ground-water discharge to the stream. The Stillwater River Basin had the highest nutrient yields in the study area during months of high streamflow; however, the Mad River Basin had the highest yields of all nutrients except ammonia during the months of the 1999 drought. The high wet-weather yields in the Stillwater River Basin were caused by agricultural runoff, whereas high yields in the Mad River Basin during drought resulted from the large, sustained contribution of ground water to streamflow throughout the year. In the basins upstream from Dayton, an estimated 19 to 25 percent of the nonpoint source of nitrogen and 4 to 5 percent of the nonpoint source of phosphorus that was deposited or applied to the land was transported into streams.

Ohio↗

USGS2001

Relation of Mercury to Other Chemical Constituents in Ground Water in the Kirkwood-Cohansey Aquifer System, New Jersey Coastal Plain, and Mechanisms for Mobilization of Mercury from Sediments to Ground Water

Water from 265 domestic wells that tap the unconfined Kirkwood-Cohansey aquifer system in the Coastal Plain of New Jersey contained concentrations of mercury that are equal to or exceed the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 2 ug/L (micrograms per liter). The wells range in depth from 50 to 200 feet, and are located in 32 discrete, mostly residential, areas that were developed primarily on former agricultural land during the 1950?s through the 1970?s. Concentrations in two other areas exceeded 1 ug/L. Naturally occurring mercury concentrations in ground water from the Kirkwood-Cohansey aquifer system typically are less than 0.01 ug/L, but concentrations in water from some wells were as much as 42 ug/L. No evidence currently exists that conclusively links known point sources such as landfills, industrial operations, or commercial enterprises to most of the elevated concentrations of mercury in ground water in the residential areas. Possible sources of the mercury include pesticides and atmospheric deposition. Analysis of water from wells in 6 of the 34 areas for other constituents indicates that nitrate concentrations also commonly are elevated above background levels (which typically are undetectable at 0.01 milligrams per liter), and exceed the MCL of 10 milligrams per liter in some samples. Several volatile organic compounds (VOCs), including chloroform, also have been measured in water from wells at many of the 34 sites. Analytical results for water samples collected at several depths from boreholes at 2 of the 34 sites indicate elevated concentrations of calcium, magnesium, barium, strontium, nitrate, and chloride, which may be related to both agricultural chemical applications and septic-system effluent. Determinations of tritium and helium concentrations indicate that water containing elevated concentrations of mercury recharged the aquifer between 9.4 and 79 years ago, which includes the period during which many of the 34 sites were undergoing a change from agricultural or undeveloped to residential land use. Batch equilibrium experiments were used to measure adsorption of dissolved mercury, mercuric chloride, and phenylmercuric acetate by aquifer sediments at pH 3.5-4.0, 4.5-5.0, and 5.5-6.0. In nearly all cases, 55 to 95 percent of the mercury added to the sediments was adsorbed. Mercury mobilization from aquifer sediments inoculated with mercury was investigated by leaching the sediments with two concentrations of nitric acid (a component of acid rain), a sodium chloride solution (simulating road salt), and three fertilizer solutions. A solution of 20-20-20 (nitrogenphosphorous-potassium) fertilizer removed virtually all of the mercury with which the sediments had been inoculated. The sodium chloride solution was moderately effective in removing applied mercury from the sediments, as was a solution of nitric acid. A more dilute nitric acid solution and two sodium nitrate fertilizer solutions were less effective. Results of these experiments indicate that mercury adsorbs to aquifer sediments, but that varying amounts can be removed by infiltrating solutions, some of which can be related to specific land uses. Land-use history at the 34 sites generally indicates a change from agricultural or undeveloped settings to residential settings. Whatever the source of mercury to these sites, a change in the geochemical environment of the soil and aquifer brought about by land-use change probably provides mechanisms for mobilizing the mercury from soils and sediments to ground water.

Water-Resources Investigations Report↗

USGS1982

Effects of land use on surface-water quality in the East Everglades, Dade County, Florida

Water-quality characteristics were determined at five developed areas in the East Everglades, Dade County, Florida, during the 1978 wet season (June through October). These areas are designated as: Coopertown; Chekika Hammock State Park; residential area; rock-plowed tomato field; and Cracker Jack Slough agricultural area. Data from the developed areas were compared with data from four baseline sites in undeveloped areas to determine the effects of land use on the surface-water quality. The rock-plowed tomato field was the only area where surface-water quality was affected. Water quality at this field is affected by agricultural activities and chemical applications as indicated by increased concentrations of orthophosphate, organic nitrogen, organic carbon, copper, manganese, mercury, and potassium. The remaining four areas of land use had water-quality characteristics typical of baseline sites in nearby Northeast Shark River Slough or Taylor Slough. Chemical analyses of soil indicated chlorinated-hydrocarbon insecticide residues at Coopertown and the two agricultural areas, Cracker Jack Slough and the rock-plowed tomato field. Trace elements in concentrations greater than base level occurred at both agricultural areas (manganese), Chekika Hammock State Park (manganese), and at Coopertown (lead and zinc). (USGS)

Florida↗