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At least 1,045 records · Page 58Linked to original sources

A review of land–sea coupling by groundwater discharge of nitrogen to New England estuaries: Mechanisms and effects

Hydrologists have long been concerned with the interface of groundwater flow into estuaries, but not until the end of the last century did other disciplines realize the major role played by groundwater transport of nutrients to estuaries. Mass balance and stable isotopic data suggest that land-derived NO 3 , NH 4 , and dissolved organic N do enter estuaries in amounts likely to affect the function of the receiving ecosystem. Because of increasing human occupancy of the coastal zone, the nutrient loads borne by groundwater have increased in recent decades, in spite of substantial interception of nutrients within the land and aquifer components of watersheds. Groundwater-borne nutrient loads have increased the N content of receiving estuaries, increased phytoplankton and macroalgal production and biomass, decreased the area of seagrasses, and created a cascade of associated ecological changes. This linkage between land use and eutrophication of estuaries occurs in spite of mechanisms, including uptake of land-derived N by riparian vegetation and fringing wetlands, “unloading” by rapid water removal, and direct N inputs to estuaries, that tend to uncouple the effects of land use on receiving estuaries. It can be expected that as human activity on coastal watersheds continues to increase, the role of groundwater-borne nutrients to the receiving estuary will also increase.

New England↗

A multiple-tracer approach to understanding regional groundwaterflow in the Snake Valley area of the eastern Great Basin, USA

Groundwater in Snake Valley and surrounding basins in the eastern Great Basin province of the western United States is being targeted for large-scale groundwater extraction and export. Concern about declining groundwater levels and spring flows in western Utah as a result of the proposed groundwater withdrawals has led to efforts that have improved the understanding of this regional groundwater flow system. In this study, environmental tracers (del2H, del18O, 3H, 14C, 3He, 4He, 20Ne, 40Ar, 84Kr, and 129Xe) and major ions from 142 sites were evaluated to investigate groundwater recharge and flow-path characteristics. With few exceptions, del2H and del18O show that most valley groundwater has similar ratios to mountain springs, indicating recharge is dominated by relatively high-altitude precipitation. The spatial distribution of 3H, terrigenic helium (4Heterr), and 3H/3He ages shows that modern groundwater (<60 yr) in valley aquifers is found only in the western third of the study area. Pleistocene and late-Holocene groundwater is found in the eastern parts of the study area. The age of Pleistocene groundwater is supported by minimum adjusted radiocarbon ages of up to 32 ka. Noble gas recharge temperatures (NGTs) are generally 1–11 degrees C in Snake and southern Spring Valleys and >11 degrees C to the east of Snake Valley and indicate a hydraulic discontinuity between Snake and Tule Valleys across the northern Confusion Range. The combination of NGTs and 4Heterr shows that the majority of Snake Valley groundwater discharges as springs, evapotranspiration, and well withdrawals within Snake Valley rather than continuing northeastward to discharge at either Fish Springs or the Great Salt Lake Playa. The refined understanding of groundwater recharge and flow paths acquired from this multi-tracer investigation has broad implications for interbasin subsurface flow estimates and future groundwater development.

Nevada, Utah↗

Shallow bedrock limits groundwater seepage-based headwater climate refugia

Groundwater/surface-water exchanges in streams are inexorably linked to adjacent aquifer dynamics. As surface-water temperatures continue to increase with climate warming, refugia created by groundwater connectivity is expected to enable cold water fish species to survive. The shallow alluvial aquifers that source groundwater seepage to headwater streams, however, may also be sensitive to seasonal and long-term air temperature dynamics. Depth to bedrock can directly influence shallow aquifer flow and thermal sensitivity, but is typically ill-defined along the stream corridor in steep mountain catchments. We employ rapid, cost-effective passive seismic measurements to evaluate the variable thickness of the shallow colluvial and alluvial aquifer sediments along a headwater stream supporting cold water-dependent brook trout ( Salvelinus fontinalis ) in Shenandoah National Park, VA, USA. Using a mean depth to bedrock of 2.6 m, numerical models predicted strong sensitivity of shallow aquifer temperature to the downward propagation of surface heat. The annual temperature dynamics (annual signal amplitude attenuation and phase shift) of potential seepage sourced from the shallow modeled aquifer were compared to several years of paired observed stream and air temperature records. Annual stream water temperature patterns were found to lag local air temperature by ∼8–19 d along the stream corridor, indicating that thermal exchange between the stream and shallow groundwater is spatially variable. Locations with greater annual signal phase lag were also associated with locally increased amplitude attenuation, further suggestion of year-round buffering of channel water temperature by groundwater seepage. Numerical models of shallow groundwater temperature that incorporate regional expected climate warming trends indicate that the summer cooling capacity of this groundwater seepage will be reduced over time, and lower-elevation stream sections may no longer serve as larger-scale climate refugia for cold water fish species, even with strong groundwater discharge.

Limnologica - Ecology and Management of Inland Wat↗

Water levels and selected water-quality conditions in the Mississippi River Valley alluvial aquifer in Eastern Arkansas, 2008

During the spring of 2008, the U.S. Geological Survey, in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey, measured 670 water levels in 659 wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas. Groundwater levels are affected by groundwater withdrawals resulting in potentiometric-surface depressions. In 2008, the lowest water-level altitude was 69 feet above National Geodetic Vertical Datum of 1929 in the center of Arkansas County. The highest water-level altitude was 288 feet above National Geodetic Vertical Datum of 1929 in northeastern Clay County on the west side of Crowleys Ridge. Two large depressions in the potentiometric surface are located in Arkansas, Lonoke, and Prairie Counties and west of Crowleys Ridge in Craighead, Cross, Lee, Monroe, Poinsett, St. Francis, and Woodruff Counties. The elongated depression in Arkansas, Lonoke, and Prairie Counties has two areas that have changed in horizontal area or depth when compared to previous conditions of the aquifer. The area in Arkansas County in the southeastern half of the depression has not expanded horizontally from recent years, although the center of the depression has deepened. The area in Lonoke and Prairie Counties in the northwestern half of the depression has not expanded and water level in the deeper part of the depression has risen. In Lonoke and Prairie Counties in the northwestern half of the depression, the 90-foot contour shown on the 2006 potentiometric-surface map is not shown on the 2008 potentiometric-surface map. Along the west side of Crowleys Ridge, the area enclosed by 140-foot contour in Cross and Poinsett Counties has expanded further south into Cross County. The 130-foot contour in Poinsett County expanded north in 2008. The 130-foot contour is shown in Cross County, which was not evident in previous years. The 130-foot contour in St. Francis, Monroe, and Woodruff Counties in 2006 is not shown on the 2008 potentiometric-surface map. A map showing the difference in water level was constructed using 595 differences in water levels measured in 585 wells during 2008 and 2004. The difference in measured water levels from 2004 to 2008 ranged from -20.6 feet to 25.9 feet, with a mean of -1.6 feet. The largest decline of -20.6 feet occurred in Randolph County and the largest rise of 25.9 feet occurred in Prairie County. Out of the 595 differences, 442 were declines (74.3 percent), 10 were no difference (values of 0.0 ft) (1.7 percent), and 143 were rises (24.0 percent). Five areas are dominated by declines that are west of Crowleys Ridge; in eastern Craighead County; in southern Mississippi and Crittenden Counties; in eastern Lonoke and western Prairie Counties; and in Arkansas, Ashley, Chicot, Desha, Drew, and Lincoln Counties. Long-term water-level changes were evaluated using hydrographs from 173 wells in the Mississippi River Valley alluvial aquifer for the period 1984 to 2008. The mean annual rise or decline in water level for the entire study area was -0.38 feet per year (ft/yr) with a range of -4.86 to 0.58 ft/yr. Independence and White Counties are the only counties with a mean annual rise from 1984 to 2008. Mean annual declines between -0.50 ft/yr and 0.00 ft/yr occurred in Arkansas, Chicot, Clay, Craighead, Crittenden, Drew, Greene, Jefferson, Mississippi, Monroe, Phillips, Poinsett, Prairie, Pulaski, Randolph, and Woodruff Counties. Mean annual declines between -1.00 ft/yr and -0.50 ft/yr occurred in Ashley, Desha, Jackson, Lee, Lincoln, and St. Francis Counties. Mean annual declines between -1.50 ft/yr and -1.00 ft/yr occurred in Cross and Lonoke Counties. The analysis of long-term water-level changes in Arkansas, Lonoke, and Prairie Counties shows the elongation of the depression in these three counties. Arkansas and Prairie Counties have two different rates of annual decline for the two hydrographs shown for each county. Water levels in the two we

Scientific Investigations Report↗

Geochemical modeling of iron, sulfur, oxygen and carbon in a coastal plain aquifer

Fe(III) reduction in the Magothy aquifer of Long Island, NY, results in high dissolved-iron concentrations that degrade water quality. Geochemical modeling was used to constrain iron-related geochemical processes and redox zonation along a flow path. The observed increase in dissolved inorganic carbon is consistent with the oxidation of sedimentary organic matter coupled to the reduction of O2 and SO4/2- in the aerobic zone, and to the reduction of SO4/2- in the anaerobic zone; estimated rates of CO2 production through reduction of Fe(III) were relatively minor by comparison. The rates of CO2 production calculated from dissolved inorganic carbon mass transfer (2.55 x 10-4 to 48.6 x 10-4 mmol 1-1 yr-1) generally were comparable to the calculated rates of CO2 production by the combined reduction of O2, Fe(III) and SO4/2- (1.31 x 10-4 to 15 x 10-4 mmol 1-1 yr-1). The overall increase in SO4/2- concentrations along the flow path, together with the results of mass-balance calculations, and variations in ??34S values along the flow path indicate that SO4/2- loss through microbial reduction is exceeded by SO4/2- gain through diffusion from sediments and through the oxidation of FeS2. Geochemichal and microbial data on cores indicate that Fe(III) oxyhydroxide coatings on sediment grains in local, organic carbon- and SO4/2- -rich zones have localized SO4/2- -reducing zones in which the formation of iron disulfides been depleted by microbial reduction and resulted in decreases dissolved iron concentrations. These localized zones of SO4/2- reduction, which are important for assessing zones of low dissolved iron for water-supply development, could be overlooked by aquifer studies that rely only on groundwater data from well-water samples for geochemical modeling. (C) 2000 Elsevier Science B.V.Fe(III) reduction in the Magothy aquifer of Long Island, NY, results in high dissolved-iron concentrations that degrade water quality. Geochemical modeling was used to constrain iron-related geochemical processes and redox zonation along a flow path. The observed increase in dissolved inorganic carbon is consistent with the oxidation of sedimentary organic matter coupled to the reduction of O2 and SO42- in the aerobic zone, and to the reduction of SO42- in the anaerobic zone; estimated rates of CO2 production through reduction of Fe(III) were relatively minor by comparison. The rates of CO2 production calculated from dissolved inorganic carbon mass transfer (2.55??10-4 to 48.6??10-4mmol l-1yr-1) generally were comparable to the calculated rates of CO2 production by the combined reduction of O2, Fe(III) and SO42- (1.31??10-4 to 15??10-4mmol l-1yr-1). The overall increase in SO42- concentrations along the flow path, together with the results of mass-balance calculations, and variations in ??34S values along the flow path indicate that SO42- loss through microbial reduction is exceeded by SO42- gain through diffusion from sediments and through the oxidation of FeS2. Geochemical and microbial data on cores indicate that Fe(III) oxyhydroxide coatings on sediment grains in local, organic carbon- and SO42--rich zones have been depleted by microbial reduction and resulted in localized SO42--reducing zones in which the formation of iron disulfides decreases dissolved iron concentrations. These localized zones of SO42- reduction, which are important for assessing zones of low dissolved iron for water-supply development, could be overlooked by aquifer studies that rely only on groundwater data from well-water samples for geochemical modeling.

Journal of Hydrology↗

Mercury speciation and mobilization in a wastewater-contaminated groundwater plume

We measured the concentration and speciation of mercury (Hg) in groundwater down-gradient from the site of wastewater infiltration beds operated by the Massachusetts Military Reservation, western Cape Cod, Massachusetts. Total mercury concentrations in oxic, mildly acidic, uncontaminated groundwater are 0.5–1 pM, and aquifer sediments have 0.5–1 ppb mercury. The plume of impacted groundwater created by the wastewater disposal is still evident, although inputs ceased in 1995, as indicated by anoxia extending at least 3 km down-gradient from the disposal site. Solutes indicative of a progression of anaerobic metabolisms are observed vertically and horizontally within the plume, with elevated nitrate concentrations and nitrate reduction surrounding a region with elevated iron concentrations indicating iron reduction. Mercury concentrations up to 800 pM were observed in shallow groundwater directly under the former infiltration beds, but concentrations decreased with depth and with distance down-gradient. Mercury speciation showed significant connections to the redox and metabolic state of the groundwater, with relatively little methylated Hg within the iron reducing sector of the plume, and dominance of this form within the higher nitrate/ammonium zone. Furthermore, substantial reduction of Hg(II) to Hg0 within the core of the anoxic zone was observed when iron reduction was evident. These trends not only provide insight into the biogeochemical factors controlling the interplay of Hg species in natural waters, but also support hypotheses that anoxia and eutrophication in groundwater facilitate the mobilization of natural and anthropogenic Hg from watersheds/aquifers, which can be transported down-gradient to freshwaters and the coastal zone.

Massachusetts↗

Deep subsurface microbial processes

Information on the microbiology of the deep subsurface is necessary in order to understand the factors controlling the rate and extent of the microbially catalyzed redox reactions that influence the geophysical properties of these environments. Furthermore, there is an increasing threat that deep aquifers, an important drinking water resource, may be contaminated by man's activities, and there is a need to predict the extent to which microbial activity may remediate such contamination. Metabolically active microorganisms can be recovered from a diversity of deep subsurface environments. The available evidence suggests that these microorganisms are responsible for catalyzing the oxidation of organic matter coupled to a variety of electron acceptors just as microorganisms do in surface sediments, but at much slower rates. The technical difficulties in aseptically sampling deep subsurface sediments and the fact that microbial processes in laboratory incubations of deep subsurface material often do not mimic in situ processes frequently necessitate that microbial activity in the deep subsurface be inferred through nonmicrobiological analyses of ground water. These approaches include measurements of dissolved H 2 , which can predict the predominant microbially catalyzed redox reactions in aquifers, as well as geochemical and groundwater flow modeling, which can be used to estimate the rates of microbial processes. Microorganisms recovered from the deep subsurface have the potential to affect the fate of toxic organics and inorganic contaminants in groundwater. Microbial activity also greatly influences the chemistry of many pristine groundwaters and contributes to such phenomena as porosity development in carbonate aquifers, accumulation of undesirably high concentrations of dissolved iron, and production of methane and hydrogen sulfide. Although the last decade has seen a dramatic increase in interest in deep subsurface microbiology, in comparison with the study of other habitats, the study of deep subsurface microbiology is still in its infancy.

Reviews of Geophysics↗

Mount St. Helens: Controlled-source audio-frequency magnetotelluric (CSAMT) data and inversions

This report describes a series of geoelectrical soundings carried out on and near Mount St. Helens volcano, Washington, in 2010&ndash;2011. These soundings used a controlled-source audio-frequency magnetotelluric (CSAMT) approach (Zonge and Hughes, 1991; Simpson and Bahr, 2005). We chose CSAMT for logistical reasons: It can be deployed by helicopter, has an effective depth of penetration of as much as 1 kilometer, and requires less wire than a Schlumberger sounding. This Data Series provides the edited data for these CSAMT soundings as well as several different types of 1-D inversions (where the signal data are converted to conductivity-versus-depth models). In addition, we include a map showing station locations on and around the volcano and the Pumice Plain to the north. The apparent conductivity (or its inverse, apparent resistivity) measured by a geoelectrical system is caused by several factors. The most important of these are water-filled rock porosity and the presence of water-filled fractures; however, rock type and minerals (for instance, sulfides and clay content) also contribute to apparent conductivity. In situations with little recharge (for instance, in arid regions), variations in ionic content of water occupying pore space and fractures sampled by the measurement system must also be factored in (Wynn, 2006). Variations in ionic content may also be present in hydrothermal fluids surrounding volcanoes in wet regions. In unusual cases, temperature may also affect apparent conductivity (Keller, 1989; Palacky, 1989). There is relatively little hydrothermal alteration (and thus fewer clay minerals that might add to the apparent conductivity) in the eruptive products of Mount St. Helens (Reid and others, 2010), so conductors observed in the Fischer, Occam, and Marquardt inversion results later in this report are thus believed to map zones with significant water content. Geoelectrical surveys thus have the potential to reveal subsurface regions with significant groundwater content, including perched and regional aquifers. Reid and others (2001) and Reid (2004) have suggested that groundwater involvement may figure in both the scale and the character of some if not all volcanic edifice collapse events. Ongoing research by the U.S. Geological Survey (USGS) and others aims to better understand the contribution of groundwater to both edifice pore pressure and rock alteration as well as its direct influence on eruption processes by violent interaction with magma (Schmincke, 1998).

Washington↗

Louisiana hydrologic atlas map no. 2: Areal extent of freshwater in major aquifers of Louisiana

The areal availability of freshwater (cl content < 250 mg/L) in 14 major aquifers in Louisiana was investigated. The depth of occurrence of fresh groundwater in Louisiana is variable. The aquifers were mapped to show their areal extent from the outcrop or subcrop to the downdip limit of freshwater. Water in each aquifer becomes saline downdip; but in most areas an overlying (younger) aquifer contains freshwater. None of the major aquifer contains freshwater in northern Louisiana where the Vicksburg and Jackson groups crop out and the underlying Cockfield aquifer (Cockfield Formation) contains saline water.

Louisiana↗

Interpretation of hydrogeologic data to support groundwater management, Bazile Groundwater Management Area, northeast Nebraska, 2019—A case demonstration of the Nebraska Geocloud

Nitrate, age tracer, and continuous groundwater-level data were interpreted in conjunction with airborne electromagnetic (AEM) survey data to understand the movement of nitrate within the Bazile Groundwater Management Area (BGMA) in northeastern Nebraska. Previously published age tracer data and nitrate data indicated vertical stratification of groundwater quality. Younger groundwater sampled within shallow parts of the aquifer had higher concentrations of nitrate, with 70 percent exceeding the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter. In contrast, groundwater sampled from deeper parts of the aquifer indicated that nitrate concentrations were less than 2 milligrams per liter and that groundwater likely recharged prior to widespread use of commercial fertilizer. The hydrostratigraphic interpretation of AEM profiles indicated that shallow and deep monitoring wells were often screened within the same homogenous zone of aquifer material. In contrast, test-hole logs indicated that there often are fine-grained layers within these homogenous zones that separate the shallow and deep monitoring well screens, but these fine-grained layers are not detected by the AEM technique because of decreased resolution of the AEM technique with depth. The stratification of groundwater ages and nitrate concentrations likely was caused by groundwater-flow paths of different length, location and time of recharge, and denitrification. Within paleochannels interpreted from AEM and test-hole data, pesticides detected in groundwater generally coincide with elevated nitrate concentrations. Continuous groundwater-level data from four monitoring well nests indicated that groundwater pumping can impose or increase downward hydraulic gradients and facilitate the downward movement of nitrate into deeper parts of the High Plains aquifer. Given the density of irrigation wells within the BGMA, this effect on the hydraulic gradient is likely prevalent in other areas of the BGMA. Understanding seasonal water-level changes can allow water managers to better predict and assess the hydraulic gradient and the vulnerability of groundwater in deeper parts of the High Plains aquifer. Nitrate, age tracer, and continuous groundwater-level data within the BGMA were interpreted in conjunction with AEM data as a case demonstration of the Nebraska Geocloud. The Nebraska Geocloud was initiated to protect taxpayer investments in AEM data collection and realize maximum benefit of these data by creating a publicly available, online digital database for long-term data storage. The Lower Platte North, Lower Platte South, Papio-Missouri River, Nemaha, Lower Loup, Central Platte, Upper Elkhorn, Lower Elkhorn, Lower Niobrara, and Lewis and Clark Natural Resources Districts; the University of Nebraska-Lincoln Conservation and Survey Division, Nebraska Natural Resources Commission, Nebraska Department of Natural Resources; and the U.S. Geological Survey entered a cooperative agreement to begin a program of data management and research aimed at understanding the best use of AEM for groundwater sustainability and management. Resulting case-study interpretations are provided to guide use of the Nebraska Geocloud to assess water-quality conditions and can be used by water managers and staff to address applicable water resource problems.

Nebraska↗

Geohydrology and Water Quality of the Valley-Fill Aquifer System in the Upper Sixmile Creek and West Branch Owego Creek Valleys in the Town of Caroline, Tompkins County, New York

In 2002, the U.S. Geological Survey, in cooperation with the Town of Caroline and Tompkins County Planning Department, began a study of the valley-fill aquifer system in upper Sixmile Creek and headwaters of West Branch Owego Creek valleys in the Town of Caroline, NY. The purpose of the study is to provide geohydrologic data to county and town planners as they develop a strategy to manage and protect their water resources. The first aquifer reach investigated in this series is in the Town of Caroline and includes the upper Sixmile Creek valley and part of West Branch Owego Creek valley. The portions of the valley-fill aquifer system that are comprised of saturated coarse-grained sediments including medium to coarse sand and sandy gravel form the major aquifers. Confined sand and gravel units form the major aquifers in the western and central portions of the upper Sixmile Creek valley, and an unconfined sand and gravel unit forms the major aquifer in the eastern portion of the upper Sixmile Creek valley and in the headwaters of the West Branch Owego Creek valley. The valley-fill deposits are thinnest near the edges of the valley where they pinch out along the till-mantled bedrock valley walls. The thickness of the valley fill in the deepest part of the valley, at the western end of the study area, is about 100 feet (ft); the thickness is greater than 165 ft on top of the Valley Heads Moraine in the central part of the valley. An estimated 750 people live over and rely on groundwater from the valley-fill aquifers in upper Sixmile Creek and West Branch Owego Creek valleys. Most groundwater withdrawn from the valley-fill aquifers is pumped from wells with open-ended 6-inch diameter casings; the remaining withdrawals are from shallow dug wells or cisterns that collect groundwater that discharges to springs (especially in the Brooktondale area). The valley-fill aquifers are the sources of water for about 200 households, several apartment complexes, two mobile home parks, a school, and several farms and small businesses. Most groundwater that is withdrawn from pumped wells is returned to the groundwater system via septic systems. Groundwater in the upper and basal confined aquifers in the upper Sixmile Creek valley is under artesian conditions everywhere except where the water discharges to springs along bluffs in the western end of the Sixmile Creek valley. Principal sources of recharge to the confined aquifers are (1) the sides of the valley where the confined aquifers may extend up along the flank of the bedrock valley wall and crop out at land surface or are overlain and in contact with surficial coarse-grained deltaic and fluvial sediments that provide a pathway through which direct precipitation and seepage losses from tributary streams can reach the buried aquifers, or (2) where the buried aquifers are isolated and receive recharge only from adjacent fine-grained sediment and bedrock. The base-flow and runoff components of total streamflow at two streamgages, Sixmile Creek at Brooktondale and Sixmile Creek at Bethel Grove, were calculated using hydrograph-separation techniques from 2003 to 2007 discharge records. Base flow constituted 64 and 56 percent of the total annual flow at the Brooktondale and Bethel Grove streamgages, respectively. Water-quality samples were collected from 2003 to 2005, with 10 surface-water samples collected seasonally during base-flow conditions at the Sixmile Creek at Brooktondale streamgage, and 12 samples were collected during base-flow conditions at several selected tributaries from 2004 to 2005. The predominant cation detected in the surface-water samples was calcium, but moderate amounts of magnesium, silica, and sodium were also detected; the major anions were bicarbonate, chloride, and sulfate. Sodium and chloride concentrations were relatively low in all samples but increased downstream from the Sixmile Creek sampling site at Six Hundred Road near Slaterville Springs, NY, to B

Scientific Investigations Report↗

Geohydrology and water quality of the northern and central parts of the Tug Hill glacial aquifer, Jefferson and Oswego Counties, north-central New York

The northern and central parts of the Tug Hill glacial aquifer consist of a 29-mile-long, crescent-shaped, mixture of glaciofluvial, glaciolacustrine, and recent alluvial deposits of predominantly sand and gravel on the western side of the Tug Hill Plateau in Jefferson and Oswego Counties in north-central New York. Approximately 11,400 people are supplied by groundwater that is withdrawn from municipal and nonmunicipal wells in the northern and central parts of the aquifer. In addition, many farms, several industries, and a large New York State fish hatchery also rely on the water from the aquifer. In the early 2000s, anticipated developmental pressures from potential new industries (including a proposed water-bottling plant in the central part of the Tug Hill glacial aquifer) and expansion of the Fort Drum military base north of Watertown (with the projected increase in population extending into the northern part of the aquifer) prompted the Tug Hill Commission, local municipal officials, and representatives from the New York State Department of Environmental Conservation to initiate a geohydrologic study with the U.S. Geological Survey. The information from this study is intended to help the state, counties, and local communities make sound policy decisions about their use of this large groundwater resource. The northern part of the Tug Hill glacial aquifer is a combination of glaciofluvial outwash and alluvial sand and gravel in the Sandy Creek Valley northeast of Adams, New York, and mostly glaciolacustrine beach and deltaic sand or sand and gravel north and south of the village of Adams. The southern and eastern areas of the central part of the aquifer are composed mostly of glaciofluvial sediments such as kames, kame moraines, and kame terraces, whereas most of the western areas of the central part are composed mostly of glaciolacustrine sediments such as deltaic sand and beach sand and gravel. The northern and central parts of the aquifer are unconfined. Recharge to the northern and central parts of the aquifer is from three main sources: (1) precipitation that falls directly onto the aquifer; (2) unchannelized runoff (overland flow) and groundwater from till and bedrock in the Tug Hill Plateau that seeps into the eastern side of the aquifer; and (3) streams that drain the Tug Hill Plateau and flow across and lose water to the aquifer. Groundwater discharges to springs, seeps, headwaters of streams, and wetlands in the middle area of the central part of the aquifer and along the entire western boundary of the northern and central parts of the aquifer; pumping wells; artificial ditches; and deeply incised streams in the northern and central parts of the aquifer. The groundwater discharge to such streams is critical in supporting the salmonid fishery in the central part of the aquifer. Groundwater levels were measured on July 17, 2014, at 22 wells throughout the northern and central parts of the aquifer. Water-table contours were drawn on the basis of the measured July 2014 water levels, historical water-level data, and surface-water levels where surface water in the channels was expected to be hydraulically connected to the groundwater system. The water table generally slopes from east to west throughout the northern and central parts of the aquifer; this slope also indicates that the direction of groundwater flow is generally from east to west. Water-quality samples were collected from 23 stream sites during base-flow conditions, and groundwater-quality and other types of environmental samples were collected from 20 wells in the northern and central parts of the Tug Hill glacial aquifer. The results of the sampling indicate that surface water and groundwater are generally of good quality. Comparison of the median concentration values of major ions in groundwater samples indicated that hardness in the northern part of the aquifer was about twice as great, and concentrations of calcium and sodium were more than three times as great, as in the central part of the aquifer. As was the case with surface water, the much greater median concentrations in groundwater of calcium, hardness, and alkalinity in the northern part of the aquifer are due to the dissolution of limestone that underlies most of that area and to the high-carbonate content of the clasts in the sand and gravel. There was little to no difference among the median values for bromide, fluoride, silica, and iron in the two parts of the aquifer. Concentrations of most other major ions were slightly greater in the northern part than in the central part of the Tug Hill glacial aquifer, except for magnesium, whose concentration was greater in the central part. Median concentrations of nutrients were generally greatest in surface water and groundwater in the northern part of the aquifer.

New York↗

Water resources and effects of ground-water development in Pasco County, Florida

Ninety-nine percent of the 79.72 million gal/d of water used in Pasco County, Florida is groundwater from the Upper Floridan aquifer. In addition, 53.5 million gal/d is exported for use in Pinellas County. Chemical quality of the water generally falls within recommended limits for drinking water except near the coast. A groundwater flow model was used to predict drawdowns in water levels under five different development plans for west Pasco County. One of these plans was incorporated in an estimated groundwater development plan for 2035 for Pasco, Pinellas, and part of Hillsborough County. Reduction in evapotranspiration accounts for nearly all the water required for each development plan. Two plans showed less effect in drawdown and potential of saltwater intrusion than the other three. For the overall groundwater development plan for Pasco, Pinellas, and parts of Hillsborough Counties, the average potentiometric surface in 2035 would be from 8 ft higher to 20 ft lower than the average 1976-77 potentiometric surface. Reductions in head would increase the potential for infiltration of contaminants in areas where surficial materials are thin, sinkhole development in sinkhole prone areas, and upconing and lateral intrusion of saltwater. The potential for dewatering the surficial aquifer is great in the Cross Bar Ranch and Cypress Creek well-field areas. Evapotranspiration of groundwater would be reduced by 19% between 1976-77 and 2035. Exchange of water between the rivers and the aquifers will be reduced by 13%. Springflow will be reduced by 6%, and three springs will cease to flow. Model boundary inflow and outflow also will be reduced.

Florida↗

Potentiometric surface and water-level difference maps of selected confined aquifers in Southern Maryland and Maryland’s Eastern Shore, 1975-2013

Groundwater is the principal source of freshwater supply in most of Southern Maryland and Maryland&rsquo;s Eastern Shore. It is also the source of freshwater supply used in the operation of the Calvert Cliffs, Chalk Point, and Morgantown power plants. Increased groundwater withdrawals over the last several decades have caused groundwater levels to decline. This report presents potentiometric-surface maps of the Aquia and Magothy aquifers and the Upper Patapsco, Lower Patapsco, and Patuxent aquifer systems using water levels measured during September 2013. Water-level difference maps are also presented for four of these aquifers. The water-level differences in the Aquia aquifer are shown using groundwater-level data from 1982 and 2013, while the water-level differences are presented for the Magothy aquifer using data from 1975 and 2013. Water-level difference maps for both the Upper Patapsco and Lower Patapsco aquifer systems are presented using data from 1990 and 2013. The potentiometric surface maps show water levels ranging from 165 feet above sea level to 199 feet below sea level. Water levels have declined by as much as 113 feet in the Aquia aquifer since 1982, 81 feet in the Magothy aquifer since 1975, and 61 and 95 feet in the Upper Patapsco and Lower Patapsco aquifer systems, respectively, since 1990.

Maryland, Virginia↗

Simulation of groundwater budgets and travel times for watersheds on the north shore of Long Island Sound, with implications for nitrogen-transport studies

Aquatic systems in and around the Long Island Sound (LIS) provide a variety of ecological and economic benefits, but in some areas of the LIS, aquatic ecosystems have become degraded by excess nitrogen. A substantial fraction of the nitrogen inputs to the LIS are transported through the groundwater-flow system. Because groundwater travel times in surficial aquifers can exceed 100 years, multiyear lags are introduced between inputs at the water table in recharge areas and discharge to inland or coastal receiving waters. The U.S. Geological Survey, in cooperation with the Connecticut Department of Energy and Environmental Protection and the U.S. Environmental Protection Agency’s Long Island Sound Study, developed a steady-state groundwater model of the watersheds draining from the northern shore of the LIS for the purpose of calculating groundwater budgets and travel times to coastal waters. The model was developed by using the MODFLOW–NWT software and existing spatial data on aquifers, river networks, land-surface altitudes, land cover, groundwater recharge, and water use. Coastal waters were delineated on the basis of the National Wetland Inventory; all non-coastal waters were collectively termed “inland waters.” A coarse-resolution model was calibrated by using the PEST++ software, long-term records of water levels in 65 wells, stream altitudes from 477 streams, base-flow records for 14 streamgages that are relatively unaffected by withdrawals, and error metrics based on incorrectly simulated flooding and incorrectly simulated dry streams. The calibrated values were used in a fine-resolution model in which the mean absolute residuals were 4.5 meters for groundwater levels, 1.3 meters for stream altitudes, and 7,200 cubic meters per day (2.9 cubic feet per second) for base flow. About 89 percent of the terrestrial cells were correctly simulated with the water table below land surface, and nearly 90 percent of the cells representing streams were correctly simulated as having the water table above the stream bottom. Together, these metrics suggest that this model is robust for simulating regional-scale groundwater patterns. Simulated groundwater budgets were compiled for the entire study area, for each HUC12 (Hydrologic Unit Code no. 12) watershed and its adjacent coastal waters, if applicable, within the study area, and for 14 coastal-embayment watersheds. Most groundwater (90.6 percent of inflows) discharged to inland waters, with smaller fractions to coastal waters (7.0 percent) and well withdrawals (2.4 percent). When computed for HUC12 watersheds with coastal discharge, the portions of groundwater discharging to coastal waters ranged from 0.02 to 66 percent of groundwater outflows, with a median of 13 percent. Within priority-embayment watersheds, the portions of groundwater discharging to coastal waters ranged from 2 to 56 percent, with a median of 15 percent. Groundwater travel times also were simulated for the entire study area, for each HUC12 watershed and its adjacent coastal waters, if applicable, within the study area and for 14 priority coastal embayments. Within the entire study area, the median groundwater travel time was 1.9 years, with an interquartile range of 0.1 to 5.9 years. Sensitivity analysis of groundwater travel times within a subbasin in the study area indicates that the travel times are a function of the grid resolution, with coarser grids resulting in shorter median travel times. Travel times for groundwater discharging to coastal waters were similar to travel times for groundwater discharging to inland waters, with a median of 1.9 years. Median travel times for the HUC12 watersheds ranged from 0.9 to 53.5 years, with a median of 1.8 years. Among HUC12 watersheds that include coastal areas, travel times for groundwater discharging to coastal waters ranged from less than 1 to 61.6 years, with a median of 2.8 years. The HUC12 watersheds with the longest simulated travel times were in the urban area near New York City where the model performance is less accurate. Median travel times for groundwater discharging to coastal waters within the priority-embayment watersheds ranged from less than 1 to 18.6 years, with a median of 2.3 years. A more focused analysis was conducted for the Niantic River watershed to demonstrate the applicability of the regional model to local-scale nitrogen-transport analyses by using nitrogen-input and -attenuation rates from literature sources. Nitrogen inputs were estimated by using land-cover-based loading factors, and attenuation was estimated by using attenuation factors based on geologic zones and soil properties. Based on this analysis, groundwater transports an estimated 22,000 kilograms of nitrogen per year (2.9 kilograms of nitrogen per hectare per year) to streams, rivers, and coastal waters within the Niantic River watershed. Approximately 36 percent of discharging nitrogen is from atmospheric-deposition sources, 38 percent is from fertilizers, and 26 percent is from septic systems. Most of the groundwater-transported nitrogen (88 percent) discharges first to streams and rivers, with only 12 percent discharging directly to coastal waters. Travel times for groundwater-transported nitrogen ranged from less than 1 day to more than 100 years, with a median of 1.6 years.

Connecticut, New York, Rhode Island↗

Hydrochemical tracers in the middle Rio Grande Basin, USA: 1. Conceptualization of groundwater flow

Chemical and isotopic data for groundwater from throughout the Middle Rio Grande Basin, central New Mexico, USA, were used to identify and map groundwater flow from 12 sources of water to the basin, evaluate radiocarbon ages, and refine the conceptual model of the Santa Fe Group aquifer system. Hydrochemical zones, representing groundwater flow over thousands to tens of thousands of years, can be traced over large distances through the primarily siliciclastic aquifer system. The locations of the hydrochemical zones mostly reflect the “modern” predevelopment hydraulic-head distribution, but are inconsistent with a trough in predevelopment water levels in the west-central part of the basin, indicating that this trough is a transient rather than a long-term feature of the aquifer system. Radiocarbon ages adjusted for geochemical reactions, mixing, and evapotranspiration/dilution processes in the aquifer system were nearly identical to the unadjusted radiocarbon ages, and ranged from modern to more than 30 ka. Age gradients from piezometer nests ranged from 0.1 to 2 year cm –1 and indicate a recharge rate of about 3 cm year –1 for recharge along the eastern mountain front and infiltration from the Rio Grande near Albuquerque. There has been appreciably less recharge along the eastern mountain front north and south of Albuquerque.

Rio Grande Basin↗

A 3-Dimensional Model of Water-Bearing Sequences in the Dominguez Gap Region, Long Beach, California

A 3-dimensional computer model of the Quaternary sequence stratigraphy in the Dominguez gap region of Long Beach, California has been developed to provide a robust chronostratigraphic framework for hydrologic and tectonic studies. The model consists of 13 layers within a 16.5 by 16.1 km (10.25 by 10 mile) square area and extends downward to an altitude of -900 meters (-2952.76 feet). Ten sequences of late Pliocene to Holocene age are identified and correlated within the model. Primary data to build the model comes from five reference core holes, extensive high-resolution seismic data obtained in San Pedro Bay, and logs from several hundred water and oil wells drilled in the region. The model is best constrained in the vicinity of the Dominguez gap seawater intrusion barrier where a dense network of subsurface data exist. The resultant stratigraphic framework and geologic structure differs significantly from what has been proposed in earlier studies. An important new discovery from this approach is the recognition of ongoing tectonic deformation throughout nearly all of Quaternary time that has impacted the geometry and character of the sequences. Anticlinal folding along a NW-SE trend, probably associated with Quaternary reactivation of the Wilmington anticline, has uplifted and thinned deposits along the fold crest, which intersects the Dominguez gap seawater barrier near Pacific Coast Highway. A W-NW trending fault system that approximately parallels the fold crest has also been identified. This fault progressively displaces all but the youngest sequences down to the north and serves as the southern termination of the classic Silverado aquifer. Uplift and erosion of fining-upward paralic sequences along the crest of the young fold has removed or thinned many of the fine-grained beds that serve to protect the underlying Silverado aquifer from seawater contaminated shallow groundwater. As a result of this process, the potential exists for vertical migration of seawater into the producing aquifers and subsequent landward migration of intruded waters beneath the existing Dominguez barrier. Incipient invasion of the Silverado aquifer by chloride-enriched waters is observed in a recently drilled well located along the crest of the fold seaward of the barrier and at a depth of 440 feet (134 meters). These new observations and interpretations indicate that the new sequence-based approach to defining the stratigraphy of the Dominguez Gap area may have important implications for seawater intrusion management. To test this, it will be useful to overlay existing water-quality and water level data onto the framework model and to incorporate the new stratigraphy into a transport model.

Open-File Report↗

Sources of high-chloride water and managed aquifer recharge in an alluvial aquifer in California, USA

As a result of pumping in excess of recharge, water levels in alluvial aquifers within the Eastern San Joaquin Groundwater Subbasin, 130 km east of San Francisco (California, USA), declined below sea level in the early 1950s and have remained so to the present. Chloride concentrations in some wells increased during that time and exceeded the US Environmental Protection Agency&rsquo;s secondary maximum contaminant level of 250 mg/L, resulting in removal of some wells from service. Sources of high-chloride water include irrigation return in 16 % of sampled wells and water from delta sediments and deeper groundwater in 50 % of sampled wells. Chloride concentrations resulting from irrigation return commonly did not exceed 100 mg/L, although nitrate concentrations were as high as 25 mg/L as nitrogen. Chloride concentrations ranged from less than 100&ndash;2,050 mg/L in wells affected by water from delta sediments and deeper groundwater. Sequential electromagnetic logs show movement of high-chloride water from delta sediments to pumping wells through permeable interconnected aquifer layers. &delta;D and &delta;18O data show most groundwater originated as recharge along the front of the Sierra Nevada, but tritium and carbon-14 data suggest recharge rates in this area are low and have decreased over recent geologic time. Managed aquifer recharge at two sites show differences in water-level responses to recharge and in the physical movement of recharged water with depth related to subsurface geology. Well-bore flow logs also show rapid movement of water from recharge sites through permeable interconnected aquifer layers to pumping wells.

California↗