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Geology and assessment of undiscovered oil and gas resources of the Laptev Sea Shelf Province, 2008

The U.S. Geological Survey (USGS) recently assessed the potential for undiscovered oil and gas resources of the Laptev Sea Shelf Province as part of the 2008 Circum-Arctic Resource Appraisal (CARA) program. The province is situated in the Russian Federation and is located between the Taimyr Peninsula and the Novosibirsk (New Siberian) Islands. Three assessment units (AUs) were defined for this study: the West Laptev Grabens AU, the East Laptev Horsts AU, and the Anisin-Novosibirsk AU, two of which were assessed for undiscovered, technically recoverable resources. The East Laptev Horsts AU was not quantitatively assessed. The estimated mean volumes of undiscovered oil and gas for the Laptev Sea Shelf Province are approximately 3 billion barrels of crude oil, 32 trillion cubic feet of natural gas, and <1 billion barrels of natural gas liquids, all north of the Arctic Circle.

Professional Paper↗

Geology and water resources of the northern portion of the Black Hills and adjoining regions in South Dakota and Wyoming

This paper, which supplements the report on the geology and water resources of the southern half of the Black Hills, published in 1901, is the result of studies made at intervals during the years 1899 to 1907. It relates to an area of about 7,500 square miles, situated about half in South Dakota and half in the northeast corner of Wyoming (Pl. II), and covering the northern half of the Black Hills uplift and a wide area of adjacent plains. The report describes the geology of the sedimentary rocks - their stratigraphy, structure, and history - and discusses their mineral resources, including underground water, coal, gypsum, etc. It also contains information respecting surface waters available for irrigation and stock raising, timber, climate, and the history of the topographic development of the region. The crystalline rocks of the central portion of the Black Hills area and the various igneous rocks of later age are shown on some of the accompanying maps but without differentiation, as the study of their geology was not within the scope of the investigation; neither are their mineral resources considered here, for these are treated in other publications. In the field work I have been assisted mainly by Prof. C. C. O'Harra, of the School of Mines at Rapid, who has mapped the geology of large areas about Aladdin, the Devils Tower, Belle Fourche, and Rapid. Dr. W. S. Tangier Smith has mapped portions of the Bear Lodge and Nigger Hill uplifts, and Mr. C. A. Fisher has assisted in portions of the work. The geology of the region from Sturgis to a point beyond Spearfish Canyon was mapped by Prof. T. A. Jaggar, jr., with the assistance of Mr. J. M. Boutwell, in 1898 and 1899. It is desirable to repeat here the statement made in my previous report that all who study the geology of the Black Hills must feel impressed by the remarkably clear general conceptions of the geologic relations of this region afforded by the survey made by Mr. Henry Newton over a quarter of a century ago. In one short season, with many unfavorable conditions for traveling, he determined most of the broader features and recorded many of the essential details. His posthumous report, edited by Mr. G. K. Gilbert, will always remain a standard work on Black Hills geology. Later studies have added greatly to our knowledge of the details of the stratigraphy and structure, the distribution of the rocks and minerals, and the age of the beds, and have afforded means for a more complete elucidation of the geologic history, especially the physiographic development of the Black Hills region.

South Dakota, Wyoming↗

Summary appraisals of the nation's ground-water resources – Upper Colorado region

The Upper Colorado Region covers about 113,500 square miles (293,965 km 2 ) in parts of Arizona, Colorado, New Mexico, Utah, and Wyoming. Drainage from about 97 percent of the region is to the Colorado River. About 60 percent of the land is owned or administered by the Federal Government, and another 15 percent is in Indian trust. The predominantly arid to semiarid region is sparsely populated (averaging about three persons per square mile, or about two and one-half persons per km 2 ) and is used chiefly for grazing, recreation, and mineral development. The water supply for the region comes from precipitation within the region, which averages about 95 million acre-feet (117,182.5 hm 3 ) per year. Development of the region's water supply has been limited almost entirely to surface water. Only about 2 percent of the total estimated volume of water withdrawn (about 5.7 million acre-ft, or 7,030.9 hm 3 ) and consumed (about 3.6 million acre-ft, or 4,440.6 hm 3 ) in the region in 1970 came directly from ground-water sources. By the year 2020 consumptive use of water within the region and water exports to adjacent regions are expected to total more than 6.5 million acre-feet (8,017.8 hm 3 ) per year. Use of the ground-water resources of the Upper Colorado Region in water-resources management can help to meet these water needs. A tremendous amount of water is stored in the rocks (ground-water reservoirs) of the Upper Colorado Region. Recoverable water in just the upper 100 feet (30.5 m) of saturated rocks is estimated to be as much as 115 million acre-feet (141,852.5 hm 3 ). That amount is nearly four times the total active storage capacity of all surface-water reservoirs in the region. The average annual replenishable supply of the ground-water reservoir is about 4 million acre-feet (4,934 hm 3 ). This amount of water could irrigate about 1.3 million acres (526,1,10 ha) of crops having an annual water requirement of 3 feet per acre (0.9 m/ha), or it could provide about 3,600 million gallons (13,627,440 m 3 ) per day for industrial use. Most of the ground water is in consolidated rocks, which generally yield water to wells slowly. Much of the ground water is saline and, in some places, occurs at great depths. Nevertheless, the ground water is more uniformly distributed than is surface water, both areally and with time; therefore, it can be used advantageously in overall waterresources management. Recent advancements in the field of demineralization and in evaluation and development of ground water make this possible. Options available for use of ground water in water-resources management&middot;in the&middot;region include conjunctive use with surface water or development of ground water as an independent supply. The latter option could be for & perennial supply or for a time-limited supply (mining ground water), depending on the need and the existing ground-water conditions. All options can be carried out so as to meet the requirements of the Colorado River Compact. The options could be implemented to optimally develop the Upper Colorado River Basin's allocation of Colorado River water while meeting the Compact commitments to the Lower Basin.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Summary appraisals of the nation's ground-water resources–Texas-Gulf region

Ground water in the Texas-Gulf Region is a large and important resource that can provide a more significant percentage of the total water supply of the region. Total water requirements within the region are projected to rise sharply from 14 million acre-feet (17 cubic kilometres) in 1970 to nearly 26 million acre-feet (32 cubic kilometres) in 2020. About half of the water used in 1970 was ground water. An estimated total of 1.04 billion acre-feet (1,280 cubic kilometres) of recoverable water containing less than 3,000 milligrams per litre dissolved solids is stored above a depth of 400 feet (122 metres) in the aquifers of the region. In addition, part of an estimated 3.28 billion acre-feet (4,040 cubic kilometres) of water in storage below 400 feet (122 metres) is recoverable. Although not all of the ground water in storage is recoverable, a significant amount is available for development; and an enormous quantity is accessible should occasions prompt its use on a time-limited basis. The total steady-state yield (amount of water that approximates the maximum perennial replenishment from precipitation) of the region's aquifers is about 4.6 million acre-feet (5.7 cubic kilometres) annually, or about 2.3 times the ground-water usage in 1970 if the large mining draft on the High Plains is not considered as part of the total steady-state yield. Because of the large quantity of recoverable groundwater in storage, the steady-state yield can be augmented for a very long time on a "deferred" basis, whereby the economic use of the water that is withdrawn from storage in excess of the steady-state yield may result in a strengthened economy. An important goal in programs for meeting future water needs should be to identify the full potential of the available ground-water resources. The subsurface reservoirs may be utilized not only as sources of fresh and treatable water, but as storage facilities for other freshwater supplies and as possible sources of geothermal energy. Some saline-water reservoirs may be suitable for liquid-waste storage or disposal. Large-scale and unregulated ground-water pumping may result in hydrologic problems such as declining water levels, streamflow depletion, and land-surface subsidence; but studies on proper development of the ground-water reservoirs could provide solutions to many of the problems. Water rights and other legal concepts should be based on sound hydrologic principles to assist development of water resources in an orderly and efficient manner. Because significant amounts of ground water are available, the opportunities for expanded and conjunctive use of ground water and surface water should be considered in regional plans for water development and conservation. The complexities of water management and the difficulties of achieving an integrated system of total-water management will require additional technical information.

Louisiana, New Mexico, Texas↗

Summary appraisals of the nation's ground-water resources – Great Lakes region

The Great Lakes Regions, as a whole, has abundant supplies of water. Nearly 805,000 billion cubic feet of water is contained in the Great Lakes. An additional 35,000 billion cubic feet of potable ground water is available from storage in the region. Estimated ground-water discharge to the streams and lakes of the region is 26 billion gallons per day. Despite this abundance of water, the United States part of the Great Lakes basin is faced with many water-related problems, most of which involve water quality and water supply. Other problems concern periods of low flow in streams, preservation of wetlands, detrimental effects of erosion, and flooding. The significance of ground water in these problems is often overlooked. Ground water can be an alternative to surface water as a source of supply, or it can be used conjunctively with surface water to provide flexibility in water-supply management. Ground water supplied approximately 1,800 million gallons per day of the 39,900 million gallons. per day used in the Great Lakes Region in 1970. The ground-water contribution was only 4.5 percent of the water used. Thus, ground water represents a potential source of supply for much of the region. It also can be used, where conditions permit, to maintain lake levels and flow in streams, to dilute poor quality surface water, and to maintain or create wetlands and ponds. In managing water resources, ground water and surface water should be considered parts of a single system. Management includes not only planning and controlling the development but also monitoring the effects of this development. Recent advances in ground-water hydrology have provided methods to resolve some of the development and management questions that formerly slowed the development of ground water. All of the States in the Great Lakes Region have some regulations to control the development or protect the quality of the ground water. These regulations, however, are not as comprehensive as those governing surface water. Future legislation could be designed to encourage the development of ground water and, at the same time, to protect the resource. Efficient development and management of ground-water resources requires a through knowledge of the system. Reports on ground water are available for about 80 percent of tbe Great Lakes Region. Most of these reports, however, are not sufficiently detailed to be useful in comprehensive planning. As ground-water development continues, quantitative groundwater studies, utilizing models as predictive tools, will enable this development to proceed in an efficient manner.

Illinois, Indiana, Michigan, Minnesota, New York, ↗

Summary appraisals of the nation's ground-water resources – Hawaii region

The water resources of the Hawaii Region, taken as a whole, are far greater than foreseeable future demands on them, but this is not so for the individual islands. Each and every island is independent with respect to water supply, and the occurrence and availability of water vary widely from island to island. The ground-water resources offer better prospects for supplying additional water needs in the future than the surface-water resources. Most of the surface supplies that are easy to develop have been fully utilized where needed, and conduits and reservoirs necessary to develop new or additional supplies would generally require large and perhaps prohibitive outlays of capital. In 1975, ground water supplied 46 percent, and surface water 54 percent of the water needs but, in the years ahead, these percentages will likely be reversed as more ground-water development takes place. Total water use, in 1975, averaged about 1,775 million gallons per day, ofwhich about 810 million gallons per day was ground water. The total water use is divided into public supply, 11 percent; self-supplied industrial use, 23 percent; and agricultural, 66 percent. Rainfall is the principal source of ground-water recharge. Local mean annual rainfall ranges from less than 20 inches to more than 300 inches, with the annual average rainfall on the large islands exposed to the trade winds being slightly more than 73 inches and that on the small islands situated in the rain shadow of the larger islands being less than 26 inches. Ground-water recharge has been estimated at about 2,400 billion gallons per year (6.5 billion gallons per day) or roughly 30 percent of the rainfall. Most fresh ground water in the region is stored below sea level in porous lava flows, much of it as basal-water lenses floating on saline ground water, as distinguished from dike-impounded water in the interior of the islands. The basal-water lens is maintained by recharge, which, if reduced, leads to thinning of the lens and subsequent encroachment of seawater. Seawater is the biggest pollutant of freshwater, and many of the ground-water problems are, in some way, associated with the encroachment of saline water induced by development. The major problem areas include the entire island of Oahu, south Kohala-Kona coast on the island of Hawaii, Lahaina District in Maui, and the Koloa and Kekaha-Mana areas in Kauai.

Hawaii↗

Summary appraisals of the nation's ground-water resources – Lower Mississippi region

The Lower Mississippi Region comprises an area of 102,400 square miles (265,200 square kilometers). Almost all this area is in the physiographic province known as the Gulf Coastal Plain. Three small areas on the northwest boundary of the region are in the Interior Highlands. The Lower Mississippi Region has an abundance of ground water. The geologic structure in that part of the region within the Coastal Plain is an elongated trough which has been filled with permeable materials, resulting in vast subsurface reservoirs. Except in local areas where continued large withdrawals have caused significant water-level declines, these reservoirs are full. Recharge to the region's aquifers is primarily from rainfall. Annual rainfall in most of the region is well distributed throughout the year and is sufficient to satisfy evapotranspiration requirements and still provide recharge to the aquifers. An estimated 844 billion cubic feet (24 billion cubic meters) of fresh ground water is available for withdrawal annually in the region. Only about one-third of this quantity is being utilized. Therefore, on this basis alone, the region still has much potential for ground-water development. The Coastal Plain aquifers within the Lower Mississippi Region contain large reserves of saltwater in the downdip limits of the aquifers. The quantity of saltwater in the region is several times that of freshwater. As desalinization techniques are developed and as more uses are found for saltwater, this reserve could become an important source of water for the region. At present (1976), the most productive and potentially productive aquifers or aquifer systems in the region are the Mississippi River valley alluvial aquifer of Quaternary age and the Sparta Sand and the Memphis aquifer (Memphis Sand in Tennessee) of Tertiary age. The Sparta Sand and the Memphis aquifer are heavily utilized and have shown significant water-level declines. However, selected well hydrographs indicate that water levels may be stabilizing under present pumping conditions. The Mississippi River valley alluvial aquifer is the most extensive high-yielding aquifer in the region; yields of several thousand gallons per minute may be obtained at depths of less than 200 feet (61 meters). To obtain maximum benefit from the vast quantities of ground water in the region, adequate attention must be given to the effects of proposed development upon the ground-water regime. Knowledge of the geologic structure and hydraulic properties of the aquifer systems is essential to an evaluation of the effects of such development. Some studies have been made in sufficient detail to provide this knowledge, but additional studies are needed. Activities that could cause significant changes in the groundwater regime should be undertaken only after all available information has been considered. Failure to seek out and use such information may result in inefficient development of the groundwater resource and, in some instances, degradation of the quality of the resource. Some changes always result from ground-water development. The possible changes can be grouped into three categories: hydraulic, water quality, and those affecting the physical framework of the aquifers. Generally, they are small in magnitude and areal extent. Because these changes occur below the ground surface, they are unknown to the ground-water user unless they noticeably affect the quantity or quality of water produced or cause obvious physical effects, such as land subsidence. Great advances have been made in hydrologic technology in recent years. Predictive models have been developed that make it possible for the hydroiogist to simulate aquifer responses to proposed development or other stresses. These models would be invaluable tools in progressive water-resources planning and management.

Arkansas, Kentucky, Louisiana, Mississippi, Missou↗

Characterization of Ground-Water Quality, Upper Republican Natural Resources District, Nebraska, 1998-2001

Nearly all rural inhabitants and livestock in the Upper Republican Natural Resources District (URNRD) in southwestern Nebraska use ground water that can be affected by elevated nitrate concentrations. The development of ground-water irrigation in this area has increased the vulnerability of ground water to the introduction of fertilizers and other agricultural chemicals. In 1998, the U.S. Geological Survey, in cooperation with the Upper Republican Natural Resources District, began a study to characterize the quality of ground water in the Upper Republican Natural Resources District area with respect to physical properties and concentrations of major ions, coliform bacteria, nitrate, and pesticides, and to assess the presence of nitrogen concentrations in the unsaturated zone. At selected well sites, the ground-water characterization also included tritium and nitrogen-isotope analyses to provide information about the approximate age of the ground water and potential sources of nitrogen detected in ground-water samples, respectively. In 1998, ground-water samples were collected from 101 randomly selected domestic-well sites. Of the 101 samples collected, 26 tested positive for total coliform bacteria, exceeding the U.S. Environmental Protection Agency's Maximum Contaminant Level (MCL) of zero colonies. In 1999, ground-water samples were collected from 31 of the 101 well sites, and 16 tested positive for coliform bacteria. Nitrates were detected in ground water from all domestic-well samples and from all but four of the irrigation-well samples collected from 1998 to 2001. Eight percent of the domestic-well samples and 3 percent of the irrigation-well samples had nitrate concentrations exceeding the U.S. Environmental Protection Agency's MCL for drinking water of 10 milligrams per liter. Areas with nitrate concentrations exceeding 6 milligrams per liter, the URNRD's ground-water management-plan action level, were found predominantly in north-central Chase, western and south-central Dundy, and south-central Perkins Counties. Generally, these concentrations were detected in samples from wells located in upland areas with permeable soils and a high percentage of cropland. In 1999, 31 of the ground-water samples collected from irrigation wells were analyzed for pesticides, and 14 samples (45 percent) had detectable concentrations of at least one pesticide compound. In 2000, all of the 23 irrigation-well samples analyzed had one or more pesticides present at detectable concentrations. In 2001, 12 of 26 domestic-well samples (46 percent) had detectable concentrations. Although the analytical method used during the study was changed to increase the number of pesticides included in the analyses, the pesticides detected in the ground-water samples from domestic and irrigation wells were limited to the commonly used herbicide compounds acetochlor, alachlor, atrazine, metolachlor, prometon, propachlor, propazine, trifluralin, and the atrazine degradation product deethylatrazine. Of the compounds detected, only atrazine (3.0 micrograms per liter) and alachlor (2.0 micrograms per liter) have MCLs established by the U.S. Environmental Protection Agency. None of the ground-water samples from the URNRD study area had concentrations that exceeded either MCL. Tritium age-dating analyses indicate water from about one-third of the sites entered the ground-water system prior to 1952. Because the increase in agricultural practices occurred during the 1950s and 1960s, it can be assumed that this water was not influenced by agricultural practices. Nitrogen-isotope speciation analyses for samples from three irrigation wells indicated that the source of nitrates in the ground water probably is synthetic fertilizer; however, the source at most irrigation wells probably is either naturally occurring or a mixture of water from various anthropogenic sources (such as synthetic fertilizer and animal waste).

Scientific Investigations Report↗

Groundwater resources of the East Mountain area, Bernalillo, Sandoval, Santa Fe, and Torrance Counties, New Mexico, 2005

The groundwater resources of about 400 square miles of the East Mountain area of Bernalillo, Sandoval, Santa Fe, and Torrance Counties in central New Mexico were evaluated by using groundwater levels and water-quality analyses, and updated geologic mapping. Substantial development in the study area (population increased by 11,000, or 50 percent, from 1990 through 2000) has raised concerns about the effects of growth on water resources. The last comprehensive examination of the water resources of the study area was done in 1980-this study examines a slightly different area and incorporates data collected in the intervening 25 years. The East Mountain area is geologically and hydrologically complex-in addition to the geologic units, such features as the Sandia Mountains, Tijeras and Gutierrez Faults, Tijeras syncline and anticline, and the Estancia Basin affect the movement, availability, and water quality of the groundwater system. The stratigraphic units were separated into eight hydrostratigraphic units, each having distinct hydraulic and chemical properties. Overall, the major hydrostratigraphic units are the Madera-Sandia and Abo-Yeso; however, other units are the primary source of supply in some areas. Despite the eight previously defined hydrostratigraphic units, water-level contours were drawn on the generalized regional potentiometric map assuming all hydrostratigraphic units are connected and function as a single aquifer system. Groundwater originates as infiltration of precipitation in upland areas (Sandia, Manzano, and Manzanita Mountains, and the Ortiz Porphyry Belt) and moves downgradient into the Tijeras Graben, Tijeras Canyon, San Pedro synclinorium, and the Hagan, Estancia, and Espanola Basins. The study area was divided into eight groundwater areas defined on the basis of geologic, hydrologic, and geochemical information-Tijeras Canyon, Cedar Crest, Tijeras Graben, Estancia Basin, San Pedro Creek, Ortiz Porphyry Belt, Hagan Basin, and Upper Sandia Mountains. View report for unabridged abstract.

Scientific Investigations Report↗

Alluvial diamond resource potential and production capacity assessment of the Central African Republic

In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflict concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberly Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. Over 70 countries were included as members of the KPCS at the end of 2007. To prevent trade in "conflict diamonds" while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was (1) to assess the naturally occurring endowment of diamonds in the Central African Republic (potential resources) based on geological evidence, previous studies, and recent field data and (2) to assess the diamond-production capacity and measure the intensity of mining activity. Several possible methods can be used to estimate the potential diamond resource. However, because there is generally a lack of sufficient and consistent data recording all diamond mining in the Central African Republic and because time to conduct fieldwork and accessibility to the diamond mining areas are limited, two different methodologies were used: the volume and grade approach and the content per kilometer approach. Estimates are that approximately 39,000,000 carats of alluvial diamonds remain in the eastern and western zones of the CAR combined. This amount is roughly twice the total amount of diamonds reportedly exported from the Central African Republic since 1931. Production capacity is calculated to be 840,000 carats per year, a number that is nearly twice the 450,000 carats per year reported annually by the Central African Republic. The difference in the two numbers reflects the lack of sufficient data on diamond resource grades, worker productivity, and the number and locations of sites being worked.

Scientific Investigations Report↗

Alluvial diamond resource potential and production capacity assessment of Mali

In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflictual concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. Over 70 countries were included as members of the KPCS at the end of 2007. To prevent trade in "conflict diamonds" while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was (1) to assess the naturally occurring endowment of diamonds in Mali (potential resources) based on geological evidence, previous studies, and recent field data and (2) to assess the diamond-production capacity and measure the intensity of mining activity. Several possible methods can be used to estimate the potential diamond resource. However, because there is generally a lack of sufficient and consistent data recording all diamond mining in Mali and because time to conduct fieldwork and accessibility to the diamond mining areas are limited, four different methodologies were used: the cylindrical calculation of the primary kimberlitic deposits, the surface area methodology, the volume and grade approach, and the content per kilometer approach. Approximately 700,000 carats are estimated to be in the alluvial deposits of the Kenieba region, with 540,000 carats calculated to lie within the concentration grade deposits. Additionally, 580,000 carats are estimated to have been released from the primary kimberlites in the region. Therefore, the total estimated diamond resources in the Kenieba region are thought to be nearly 1,300,000 carats. The Bougouni zones are estimated to have 1,000,000 carats with more than half, 630,000 carats, contained in concentrated deposits. When combined, the Kenieba and Bougouni regions of Mali are estimated to be host to 2,300,000 carats of diamonds.

Scientific Investigations Report↗

Potash: a global overview of evaporate-related potash resources, including spatial databases of deposits, occurrences, and permissive tracts

Potash is mined worldwide to provide potassium, an essential nutrient for food crops. Evaporite-hosted potash deposits are the largest source of salts that contain potassium in water-soluble form, including potassium chloride, potassium-magnesium chloride, potassium sulfate, and potassium nitrate. Thick sections of evaporitic salt that form laterally continuous strata in sedimentary evaporite basins are the most common host for stratabound and halokinetic potash-bearing salt deposits. Potash-bearing basins may host tens of millions to more than 100 billion metric tons of potassium oxide (K 2 O). Examples of these deposits include those in the Elk Point Basin in Canada, the Pripyat Basin in Belarus, the Solikamsk Basin in Russia, and the Zechstein Basin in Germany. This report describes a global, evaporite-related potash deposits and occurrences database and a potash tracts database. Chapter 1 summarizes potash resource history and use. Chapter 2 describes a global potash deposits and occurrences database, which contains more than 900 site records. Chapter 3 describes a potash tracts database, which contains 84 tracts with geology permissive for the presence of evaporite-hosted potash resources, including areas with active evaporite-related potash production, areas with known mineralization that has not been quantified or exploited, and areas with potential for undiscovered potash resources. Chapter 4 describes geographic information system (GIS) data files that include (1) potash deposits and occurrences data, (2) potash tract data, (3) reference databases for potash deposit and tract data, and (4) representative graphics of geologic features related to potash tracts and deposits. Summary descriptive models for stratabound potash-bearing salt and halokinetic potash-bearing salt are included in appendixes A and B, respectively. A glossary of salt- and potash-related terms is contained in appendix C and a list of database abbreviations is given in appendix D. Appendix E describes GIS data files, and appendix F is a guide to using the geodatabase.

Scientific Investigations Report↗

Natural resource mitigation, adaptation and research needs related to climate change in the Great Basin and Mojave Desert

This report synthesizes the knowledge, opinions, and concerns of many Federal and State land managers, scientists, stakeholders, and partners from a workshop, held at the University of Nevada, Las Vegas, on April 20-22, 2010. Land managers, research scientists, and resource specialists identified common concerns regarding the potential effects of climate change on public lands and natural resources in the Great Basin and Mojave Desert and developed recommendations for mitigation, adaptation, and research needs. Water and, conversely, the effects of drought emerged as a common theme in all breakout sessions on terrestrial and aquatic species at risk, managing across boundaries, monitoring, and ecosystem services. Climate change models for the southwestern deserts predict general warming and drying with increasing precipitation variability year to year. Scientists noted that under these changing conditions the past may no longer be a guide to the future in which managers envision increasing conflicts between human water uses and sustaining ecosystems. Increasing environmental stress also is expected as a consequence of shifting ecosystem boundaries and species distributions, expansion of non-native species, and decoupling of biotic mutualisms, leading to increasingly unstable biologic communities. Managers uniformly expressed a desire to work across management and agency boundaries at a landscape scale but conceded that conflicting agency missions and budgetary constraints often impede collaboration. More and better science is needed to cope with the effects of climate change but, perhaps even more important is the application of science to management issues using the methods of adaptive management based on long-term monitoring to assess the merits of management actions. Access to data is essential for science-based land management. Basic inventories, spatial databases, baseline condition assessments, data quality assurance, and data sharing were identified as top information priorities by all participants at this workshop. Optimizing the utility of ecosystem monitoring data will require standardizing monitoring protocols across agencies. Better communication among researchers and managers and cooperation through partnerships to manage resources across boundaries were emphasized as necessary for adapting to changing climatic conditions. However, even these strategies may be insufficient unless policy mandates, agency missions, and funding are coordinated at a high level.

Scientific Investigations Report↗

Water resources of the Iroquois National Wildlife Refuge, Genesee and Orleans counties, New York 2008-2010

A 2-year study of the water resources of the Iroquois National Wildlife Refuge (Refuge) in western New York was carried out in 2009-2010 in cooperation with the U.S. Fish and Wildlife Service to assist the Refuge in the development of a 15-year Comprehensive Conservtion plan. The study focused on Oak Orchard Creek, which flows through the Refuge, the groundwater resources that underlie the Refuge, and the possible changes to these resources related to the potential development of a bedrock quarry along the northern side of the Refuge. Oak Orchard Creek was monitored seasonally for flow and water quality; four tributary streams, which flowed only during early spring, also were monitored. A continuous streamgage was operated on Oak Orchard Creek, just north of the Refuge at Harrison Road. Four bedrock wells were drilled within the Refuge to determine the type and thickness of unconsolidated glacial sediments and to characterize the thickness and type of bedrock units beneath the Refuge, primarily the Lockport Dolomite. Water levels were monitored in 17 wells within and adjacent to the Refuge and water-quality samples were collected from 11 wells and 6 springs and analyzed for physical properties, nutrients, major ions, and trace metals. Flow in Oak Orchard Creek is from two different sources. During spring runoff, flow from the Onondaga Limestone Escarpment, several miles south of the Refuge, supplements surface-water runoff and groundwater discharge from the Salina Group to the south and east of the Refuge. Flow to Oak Orchard Creek also comes from surface-water runoff from the Lockport Dolomite Escarpment, north of the Refuge, and from groundwater discharging from the Lockport Dolomite and unconsolidated deposits that overlie the Lockport Dolomite. During the summer and fall low-flow period, only small quantities of groundwater flow from the Salina shales and Lockport Dolomite bedrock and the unconsolidated sediments that overlie them; most of this flow is lost to wetland evapotranspiration, and the remainder enters Oak Orchard Creek. Water quality in the Oak Orchard Creek is affected not only by these groundwater sources but also by surface runoff from agricultural areas and the New York State Wildlife Management Area east of the Refuge. Based on the results of the drilling program, the Lockport Dolomite underlies nearly all the Refuge. The Refuge wetlands lie within a bedrock trough between the Lockport Dolomite and Onondaga Limestone Escarpments, to the north and south, respectively. This bedrock trough was filled with mostly fine-grained sediments when Glacial Lake Tonawanda was present following the last period of glaciation. These fine-grained sediments became the substrate on which the wetlands were formed along Oak Orchard Creek and nearby Tonawanda Creek, to the south and west. Water quality in the unconsolidated and bedrock aquifers is variable; poor quality water (sulfide-rich "black water") generally is present south of Oak Orchard Creek and better quality water to the north where the Lockport Dolomite is close to the land surface. A set of springs, the Oak Orchard Acid Springs, is present within the Refuge; the springs are considered unique in New York State because of their naturally low pH (approximately 2.0) and their continual discharge of natural gas. The potential development of a bedrock quarry in the Lockport Dolomite bedrock along the northern border of the Refuge may affect the nearby Refuge wetlands. The extent of drawdown needed to actively quarry the bedrock could change the local hydrology and affect groundwater-flow directions and rates, primarily in the Lockport Dolomite bedrock and possibly the Oak Orchard Acid Springs area, farther to the south. The effect on the volume of flow in Oak Orchard Creek would probably be minimal as a result of the poor interaction between the surface-water and the groundwater systems. Of greater potential effect will be the possible change in the quality of water flowing into the Refuge from the discharge of groundwater during dewatering operations at the quarry; this discharge will flow into the northern part of the Refuge and affect the quantity and quality of wetland areas downstream from the quarry discharge. These changes may affect wetland management activities because of the potential for poorquality water to affect the ecology of the wetlands and the wildlife that use these wetlands.

New York↗

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗

National assessment of geologic carbon dioxide storage resources: allocations of assessed areas to Federal lands

Following the geologic basin-scale assessment of technically accessible carbon dioxide storage resources in onshore areas and State waters of the United States, the U.S. Geological Survey estimated that an area of about 130 million acres (or about 200,000 square miles) of Federal lands overlies these storage resources. Consequently, about 18 percent of the assessed area associated with storage resources is allocated to Federal land management. Assessed areas are allocated to four other general land-ownership categories as follows: State lands about 4.5 percent, Tribal lands about 2.4 percent, private and other lands about 72 percent, and offshore areas about 2.6 percent.

Scientific Investigations Report↗

Water resources during drought conditions and postfire water quality in the upper Rio Hondo Basin, Lincoln County, New Mexico, 2010-13

Stakeholders and water-resource managers in Lincoln County, New Mexico, have had long-standing concerns over the impact of population growth and groundwater withdrawals. These concerns have been exacerbated in recent years by extreme drought conditions and two major wildfires in the upper Rio Hondo Basin, located in south-central New Mexico. The U.S. Geological Survey (USGS), in cooperation with Lincoln County, initiated a study in 2006 to assess and characterize water resources in the upper Rio Hondo Basin. Data collected during water years 2010&ndash;13 are presented and interpreted in this report. All data presented in this report are described in water years unless stated otherwise. Annual mean streamflow at the Rio Ruidoso at Hollywood, N. Mex., streamflow-gaging station was less than 50 percent of the average streamflow during 2011&ndash;13 and was of similar magnitude to annual mean streamflow values measured during the drought of the 1950s. The first zero-streamflow values for the period of record (1954&ndash;2013) were recorded at the Rio Ruidoso at Hollywood, N. Mex., streamflow-gaging station on June 27&ndash;29, 2013. The lowest annual mean streamflow on record (1969&ndash;80; 1988&ndash;2013) occurred in 2011 at the Eagle Creek below South Fork near Alto, N. Mex., streamflow-gaging station, with the station recording zero streamflow for approximately 50 percent of the year. Discrete and continuous groundwater-level measurements indicated basinwide water-level declines during drought conditions in 2011&ndash;13. The average water-level change among 37 wells in which discrete groundwater-level measurements were collected was -7.6 ft from 2010 to 2013. The largest water-level declines were observed in the upper reaches of the Rio Bonito and Rio Ruidoso watersheds, and smaller declines were observed in the lower reaches of the watersheds. In general, water-level changes observed during 2010&ndash;13 were on the order of decadal-scale changes that previously have been observed in the upper Rio Hondo Basin. Stable-isotope data indicate that high-elevation winter precipitation generally contributes more to groundwater recharge than summer rains, except when there are large summer recharge events. This implies that little recharge is occurring at the lower elevations in the upper Rio Hondo Basin because these areas receive a smaller amount of total precipitation, receive a smaller proportion of the annual total falling as winter precipitation, and have higher average temperatures that result in more evaporative losses. Groundwater in the upper Rio Hondo Basin is a mix of younger and older water, and recharge likely is occurring primarily at higher elevations but there may be some areas where localized recharge is occurring at lower elevations. Surface-water- and groundwater-quality results from samples collected in 2012&ndash;13 were examined to characterize overall chemistry and were compared to historical waterquality data from streams in the upper Rio Hondo Basin collected during 1926&ndash;57. In general, specific conductance showed an increasing trend moving eastward (downstream) through the upper Rio Hondo Basin in surface-water and groundwater samples. Surface-water and groundwater samples appear to have similar overall major-ion chemical characteristics when compared to historical water-quality data. Geology was found to influence the chemical characteristics of surface-water and groundwater samples, with relatively higher concentrations of sulfate occurring in samples collected at lower elevations in the Permian regional aquifer system. Surface-water sample results also were analyzed to determine differences in unfiltered and filtered water-quality samples of streams in burned and unburned watersheds after the occurrence of the Little Bear Fire in June 2012. Samples were collected after postfire monsoon rain events and during periods of stable hydrologic conditions. The first postfire monsoon rain event in July 2012 generally produced the highest measured concentrations of selected fire-related constituents in unfiltered samples collected in the burned watersheds relative to later samples collected in burned watersheds and all samples collected in the unburned watershed. Monsoon rain events have impacted water quality by delivering larger sediment loads and fire-related constituents into streams in the upper Rio Hondo Basin. Changes in climate and increased groundwater and surface-water use are likely to affect the availability of water in the upper Rio Hondo Basin. Increased drought probably will increase the potential for wildfires, which can affect downstream water quality and increase flood potential. Climate-research predicted decreases in winter precipitation may have an adverse effect on the amount of groundwater recharge that occurs in the upper Rio Hondo Basin, given the predominance of winter precipitation recharge as indicated by the stable isotope results. Decreases in surface-water supplies because of persistent drought conditions and reductions in the quality of water because of the effects of wildfire may lead to a larger reliance on groundwater reserves in the upper Rio Hondo Basin. Decreasing water levels because of increasing groundwater withdrawal could reduce base flows in the Rio Bonito and Rio Ruidoso. Well organized and scientifically supported regional water-resources management will be necessary for dealing with the likely scenario of increases in demand coupled with decreases in supply in the upper Rio Hondo Basin.

New Mexico↗

Geologic and geophysical models for Osage County, Oklahoma, with implications for groundwater resources

This report summarizes a three-dimensional (3-D) geologic model that was constructed to provide a framework to investigate groundwater resources of the Osage Nation in northeastern Oklahoma. This report also presents an analysis of an airborne electromagnetic (AEM) survey that assessed the spatial variation of electrical resistivity to depths as great as 300 meters in the subsurface. The report and model provide support for a countywide assessment of groundwater resources, emphasizing the Upper Pennsylvanian rock units in the shallow subsurface of central and eastern Osage County having electrical resistivity properties that may indicate aquifers. Surface outcrops and subsurface stratigraphic picks on wire-line geophysical logs of Upper Pennsylvanian&ndash;Lower Permian sedimentary rock were used to construct a 3-D model of the geologic subsurface as an aid for evaluating groundwater resources in Osage County. Quaternary alluvium and terraces along major streams and the Arkansas River are included in the geologic framework model. Data from the AEM survey were subjected to quality-control procedures, truncated at depth of investigation (DOI), and then used to build a 3-D electrical resistivity model making use of secondary and tertiary interpolation profiles between primary data profiles. The AEM data highlight westward-inclined resistivity gradients that parallel the shallow dip of bedrock strata; bodies have resistivity >30 ohm-meters, and extend as much as 10 kilometers (km) down the dip of host geologic units. Volume analysis and internal imaging of an integrated 3-D geology and electrical resistivity model give a proxy for likely aquifer units with large relative volumes of high resistivity: Quaternary alluvium, Elgin Sandstone Lentil in the upper part of the Vamoosa Group, Tallant Formation, and parts of a combined Wann-Iola-Chanute Formation. Less voluminous, high-resistivity bodies correspond to intervals in the lower part of the Vamoosa Group in the east-central part of the county and probable limestone intervals in the upper part of the Vanoss Group in the northwest part of the county. Northwestern and eastern troughs of potable water previously defined for central Osage County generally correspond to down-dip projections of high-resistivity bodies associated with the Elgin Sandstone Lentil of the Vamoosa Group and Tallant Formation, respectively.

Oklahoma↗