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At least 1,045 records · Page 58Linked to original sources
USGS1985

The Schwartzwalder uranium deposit, II: Age of uranium mineralization and lead isotope constraints on genesis

U-Pb isotope analyses of ores from the Schwartzwalder uranium mine, Colorado, show that these ores have high amounts of initial (common) Pb and that the initial Pb was both variable and relatively radiogenic in its Pb isotope ratios ( 206 Pb/ 204 Pb = 26-30). As a result, the only useful approach to dating these ores is with U-Pb isochrons, and even so, some means of dealing with the variable initial Pb isotope ratios is required. Because the common Pb in these ores was apparently derived from sources of similar age and Th/U, the observed 208 Pb/ 204 Pb of these Th-free ores can be used either to identify sample suites with similar initial Pb isotope ratios or to normalize for the variable initial Pb isotope ratios. The resulting U-Pb isochrons indicate an age of mineralization for both Illinois vein and Titan vein ores of 69.3 + or - 1.1 m.y., suggesting that the deposit was formed during the earliest stages of Laramide uplift and under at least 3 km of Phanerozoic cover. The initial Pb isotope systematics of the ores show that the metals in the Schwartzwalder ores were derived from source(s) of 1,730 + or - 130-m.y.-age, with a Th/U of 2.2 + or - 0.2 and 238 U/ 204 Pb of 30 to 60. These restrictions on the source(s) of the metals rule out the possibility that the deposit could have been formed by remobilization of a Proterozoic uranium deposit, and both the 69.3-m.y.-age of the ores and their initial Pb isotope ratios preclude any contribution of metals to the deposit by younger volcanics such as those in the Denver Formation.

Economic Geology↗
USGS1954

Water resources of the Grand Rapids area, Michigan

The Grand Rapids area, Michigan, has three sources from which to obtain its water supply: Lake Michigan, the Grand River and its tributaries, and ground water. Each of the first two and possibly the third is capable of supplying the entire needs of the area. This area is now obtaining a part of its supply from each of these sources. Of the average use of 50 mgd (million gallons per day) during 1951, Lake Michigan supplied 29 mgd; the Grand River and its tributaries supplied 1 mgd; and ground water supplied 20 mgd. Lake Michigan offers a practically unlimited source of potable water. However, the cost of delivery to the Grand Rapids area presents an economic problem in the further development of this source. Even without storage the Grand River can provide an adequate supply for the city of Grand Rapids. The present average use of the city of Grand Rapids is about 30 mgd and the maximum use is about 60 mgd, while the average flow of the Grand River is 2, 495 mgd or 3, 860 cfs (cubic feet per second) and the minimum daily flow recorded is 246 mgd. The quality and temperature of water in the Grand River is less desirable than Lake Michigan water. However, with proper treatment its chemical quality can be made entirely satisfactory. The city of Grand Rapids is actively engaged in a study that will lead to the expansion of its present water-supply facilities to meet the expected growth in population in Grand Rapids and its environs. Ground-water aquifers in the area are a large potential source of supply. The Grand Rapids area is underlain by glacial material containing a moderately hard to very hard water of varying chemical composition but suitable for most uses. The glacial outwash and lacustrine deposits bordering principal streams afford the greatest potential for the development of large supplies of potable ground water. Below the glacial drift, bedrock formations contain water that is extremely hard and moderately to highly mineralized. Thus the major sources of usable ground water are the glacial drift and some parts of the bedrock. Wherever the bedrock yields large quantities of water, the water is generally of inferior quality. Any development should be preceded by test drilling and careful hydrologic and geologic studies of the area under consideration and chemical analysis of the water found.

Michigan↗
USGS1971

Evolution of thought on ore controls in east Tennessee

All early students of the zinc and barite deposits of East Tennessee, noting the geographic coincidence of the principal mining area with complex late Paleozoic geologic structure, concluded that (1) the ore-bearing breccias were produced by Appalachian tectonic forces and that (2) mineralizing solutions gained access through fault-produced channelways. In 1931, Ulrich suggested that the breccias were produced by collapse and fragmentation resulting from solution of the carbonate rocks. This idea was promptly rejected by most geologists, and for the next 15 years nearly all papers on these deposits contained refutations of Ulrich's hypothesis and "proof" of the late Paleozoic tectonic origin of the breccias. Recognition by Odell in 1950 of a spatial association between thinning of the lime-stone zone of the Kingsport Formation and the presence of ore bodies, plus the observation that all identifiable blocks in the breccias were displaced downward as much as 30 to 50 feet, led him to suggest that foundering of the rocks over solution-thinned zones produced the breccias. Hydrothermal fluids, rather than ordinary ground water, were thought to be the dissolving agent.Kendall, in 1960, described a stratified "varved" matrix with detrital sphalerite grains in many breccias at Jefferson City, in which lamination is parallel to bedding of the host Kingsport Formation, indicating that both brecciation and mineralization occurred while the rocks were horizontal. Ruskell about 1960 pointed out the similarity between cross sections of southwest Wisconsin ore bodies and those of East Tennessee when the latter were rotated to a horizontal position. Detailed studies of the post-Knox unconformity led to recognition of a paleokarst topography of considerable relief developed on this surface. Regional stratigraphic studies of the Knox Group by Harris demonstrated the probability of pre-Middle Ordovician exposure of the Kingsport somewhere to the north or northwest, providing a recharge area for ground waters at that time. Detailed mapping of ore bodies, barren areas, and related structures by the mining-company geologists, plus application of the principles of ground-water hydrology and rock mechanics, has led to the theory, generally accepted in the district, of solution-collapse origin of the breccias, probably during Ordovician time.

Tennessee↗
USGS1961

Copper, vanadium, and uranium deposits in sandstone-their distribution and geochemical cycles

Deposits of copper , vanadium , and uranium in nonmarine sandstones are numerous and widespread. Copper deposits , with or without uranium , are mainly resident in first-generation arkosic sandstones derived from granitic rock terrains; deposits rich in vanadium , with or without much uranium , are dominantly in second-generation sandstones derived from sedimentary rocks; and the uranium deposits with little or no vanadium or copper are in either first- or second-generation sandstones, many of which are associated with beds containing volcanic debris. All three metals are dispersed in igneous rocks but not in close association. Copper and uranium enter the hydrothermal environment, but the record of vanadium in hydrothermal solutions and veins is scant. Some of the uranium and most of the copper minerals in igneous rocks and veins oxidize readily and the metals go into surface- and ground-water solutions, but the vanadium in igneous rocks is not so easily mobilized-under normal geologic conditions, conceivably it may require diagenetic reactions and a second period of weathering to solubilize much vanadium . All three metals precipitate from solutions in the presence of a reducing agent, such as carbonaceous material or associated sulfide ions, either in sediments as they accumulate or in existing rocks. These geochemical habits permit the concept that copper and uranium are made available by weathering of igneous rock terrains and hence might accumulate in first-generation sediments, whereas vanadium would be commonly available only after a second period of weathering. Perhaps the oxidation or devitrification of volcanic debris may contribute uranium to ground waters as does the weathering, of igneous rocks.

Economic Geology↗
USGS1983

Geological and geochemical studies in the Wadi Bidah District, Kingdom of Saudi Arabia

Geological and geochemical followup studies of airborne electromagnetic anomalies in the Wadi Bidah district, southwestern Saudi Arabia, did not reveal metals of economic grade. Investigation of an anomaly enclosing the Rabathan ancient mine disclosed tightly folded and sheared Proterozoic tuffaceous rocks interlayered mostly with chert, dolomite, carbonaceous rocks, and volcanic wacke including cherty iron-manganese formations slightly anomalous in copper and zinc. Three drill holes placed to test anomalies within these formations yielded negative results. Studies of a long, narrow anomaly north of the Rabathan area indicated a similar geological environment. This northern area also contains limited zones that are highly anomalous in copper and zinc and extensive zones that are slightly anomalous in those metals. Drilling was not undertaken in this area. The Bilajimah airborne electromagnetic anomaly west of Wadi Bidah coincides with a broad synclinorium of layered felsic turfs and gossans. Geochemical studies indicated slightly anomalous copper, zinc, and silver values in gossans within the anomaly area. Two drill holes intersected carbonaceous rock that contained approximately 15 percent pyrrhotite and traces of sphalerite and chalcopyrite. Two geophysically anomalous areas west of Wadi Bidah surround ancient mines at Mahawiyah and Khayal al Masna'ah. Results of geochemical sampling at these workings were positive. An airborne electromagnetic anomaly located in the Assifar area in the southwestern corner of the Wadi Bidah district is underlain principally by metasedimentary rocks that include large linear zones of cherty iron-manganese formation and a few gossans .containing secondary base metal minerals. Detailed mapping and sampling of the Mulhal ancient mine, located west of Wadi Bidah, revealed two types of polymetallic gossans : (1) stratiform deposits interlayered with ignimbrites and mafic volcanic rocks and (2) barite-bearing gossanous material in shear zones that grade into hydrothermally altered shear zones and extend beyond the mine area. The gossans and gossanous shear zones contain anomalous amounts of gold, silver, lead, copper, zinc, barium, and selenium. Two gossans west of Wadi Bidah were mapped and sampled in detail; both gossans are interlayered, with siliceous volcanic rocks. Although the gossan at Jabal Mohr covers a large area, it contains low amounts of precious and base metals. The gossan at Mulhal No. 2 contains moderate to high amounts of gold, silver, copper, lead, and zinc.

Open-File Report↗
USGS2017

Tellurium

Tellurium (Te) is a very rare element that averages only 3 parts per billion in Earth’s upper crust. It shows a close association with gold and may be present in orebodies of most gold deposit types at levels of tens to hundreds of parts per million. In large-tonnage mineral deposits, such as porphyry copper and seafloor volcanogenic massive sulfide deposits, sulfide minerals may contain hundreds of parts per million tellurium, although the orebodies likely have overall concentrations of 0.1 to 1.0 parts per million tellurium. Tellurium is presently recovered as a primary ore from only two districts in the world; these are the gold-tellurium epithermal vein deposits located adjacent to one another at Dashuigou and Majiagou (Sichuan Province) in southwestern China, and the epithermal-like mineralization at the Kankberg deposit in the Skellefteå VMS district of Västerbotten County, Sweden. Combined, these two groups of deposits account for about 15 percent (about 70 metric tons) of the annual global production of between 450 and 470 metric tons of tellurium. Most of the world’s tellurium, however, is produced as a byproduct of the mining of porphyry copper deposits. These deposits typically yield concentrations of 1 to 4 percent tellurium in the anode slimes recovered during copper refining. Present production of tellurium from the United States is solely from the anode slimes at ASARCO LLC’s copper refinery in Amarillo, Texas, and may total about 50 metric tons per year. The main uses of tellurium are in photovoltaic solar cells and as an additive to copper, lead, and steel alloys in various types of machinery. The environmental data available regarding the mining of tellurium are limited; most concerns to date have focused on the more-abundant metals present in the large-tonnage deposits from which tellurium is recovered as a byproduct. Global reserves of tellurium are estimated to be 24,000 metric tons, based on the amount of tellurium likely contained in global copper reserves and on a 50 percent recovery rate from refinery anode slimes during the commonly used electrolytic process, also known as solvent extraction-electrolytic refining. If the more economical solvent-leach process—a process that does not recover tellurium—is increasingly used in the future to recover lower grades of copper from porphyry and other large-tonnage deposits, then additional high-grade tellurium-rich gold deposits may become new primary sources for tellurium, particularly epithermal vein deposits associated with alkaline magmatism.

Professional Paper↗
USGS2019

Assessment of undiscovered copper resources of the world, 2015

The U.S. Geological Survey completed the first-ever global assessment of undiscovered copper resources for the two most significant sources of global copper supply: porphyry copper deposits and sediment-hosted stratabound copper deposits. The geology-based study identified 236 areas for undiscovered copper in 11 regions of the world. Estimated amounts of undiscovered copper resources are reported at different levels of probability. The results of the assessment indicate that a mean of at least 3,500 million metric tons (Mt) of undiscovered copper associated with these deposit types may exist worldwide, exceeding the 2,100 Mt of identified copper resources tabulated for these deposit types. Porphyry copper deposits contain 1,800 Mt of identified copper resources and are estimated to contain a mean of at least 3,100 Mt of undiscovered copper resources. South America is the dominant source for both identified and undiscovered porphyry copper resources. However, several regions of Asia, including China, have significant potential for undiscovered porphyry copper resources. The amount of mean undiscovered porphyry copper resources that may be economic to extract varies as a function of likely depth to a deposit and quality of local infrastructure that could support mining. Sediment-hosted stratabound copper deposits contain 310 Mt of identified copper resources and are estimated to contain a mean of at least 420 Mt of undiscovered copper resources. The sedimentary basins that may contain significant undiscovered copper resources are the Katanga Basin in central Africa, the Southern Permian Basin of Poland and Germany, the Chu-Sarysu Basin of Kazakhstan, and the Kodar-Udokan area of Russia. Sedimentary basins in the Northwest Botswana Rift in Botswana and Namibia, the Benguela and Cuanza Basins of Angola, and the Cambrian rocks of Egypt, Israel, and Jordan are recognized as having significant potential for undiscovered copper resources in sediment-hosted stratabound copper deposits; however, these areas require additional research, analysis, and evaluation before quantitative resource estimates can be made. The estimate of at least 3,500 Mt of undiscovered copper in two deposit types provides a basis for long-range planning for this important commodity. U.S. copper consumption is 2 Mt per year, world consumption is about 20 Mt per year, and global production from these two deposit types is about 12 Mt per year. Total global copper production from all deposit types from 1879 to 2012 was about 600 Mt. The world’s use of mineral resources, such as copper, will continue to increase in the foreseeable future to support a growing world population and increasing standards of living. The world has sufficient copper to last for decades. However, increases in exploration and growth in mining capacity will be necessary to identify and develop undiscovered resources to supply projected demand.

Scientific Investigations Report↗
USGS1964

Nickeliferous laterites in southwestern Oregon and northwestern California

Deposits of ferruginous nickeliferous lateritic soils formed by weathering in place of ultramafic rocks occur at several places in northwestern California and southwestern Oregon, mostly in the Klamath Mountains province. Most of the deposits have been derived from relatively fresh peridotite, although at least one deposit was formed on serpentinite. The accumulations of lateritic soil are on flat-lying to gently sloping surfaces in a terrain that has been extensively dissected and deeply entrenched.The thickness of the deposits ranges from a few feet to more than 50 feet, and may vary widely in any given deposit, for the bedrock surface is commonly highly irregular. The deposit at Nickel Mountain, Oregon, is unique, because it is the only one in which the nickel silicate, garnierite, is plentiful. At Nickel Mountain, garnierite, accompanied by abundant microcrystalline quartz, occurs in veinlike bodies and boxworks that lie at the base of the soil zone and persist in depth along joints and fractures into the underlying slightly weathered or fresh peridotite.Mineralogical studies and chemical analyses show that weathering of the ultramafic rocks destroyed olivine and much of the orthopyroxene and serpentine minerals. Secondary minerals formed are predominantly hydrated ferric oxides (goethite); minor amounts of a montmorillonite mineral, chlorite, and talc were also identified. The kaolin group and bauxite minerals were not found. Except for garnierite at the Nickel Mountain deposit, no nickel-bearing mineral was identified. Nickel may occur, however, in montmorillonite, chlorite, and talc where it substitutes for Mg to a limited extent; in serpentine minerals that were not destroyed by weathering; and possibly in combination with ferric hydroxides. Cobalt may also occur in the clay minerals and probably is associated with trace amounts of manganese oxide or hydroxides.The lateritic soils in northwestern California and southwestern Oregon are similar to soils formed by lateritic weathering of ultramafic rocks in Cuba, the Philippines, New Caledonia, and other tropical regions of the world. They have, however, a higher content of SiO 2 and MgO, and a lower content of Fe 2 O 3 than deposits formed in tropical climates. The California and Oregon deposits are considerably smaller and lower in average metal content which, because they are widely scattered in a rugged, relatively isolated terrain, makes them unpromising as likely reserves for commercial exploitation in the foreseeable future.Most of the deposits are regarded as having been formed by chemical weathering in a climate having alternating wet and dry seasons, probably similar to that prevailing today. Their age is uncertain but may range from post-Miocene to Pleistocene.

California, Oregon↗
USGS1970

An appraisal of the Jabal Idsas magnetite mineralization based on diamond drill hole N40A

Diamond Drill Bole N40, intended to test the magnetite mineralization at Jabal Idsas, was aborted because of technical difficulties and a new hole, N4OA, was drilled at the same site in February of 1968 to an inclined down-the-hole depth of 445.7 meters. Disseminated magnetite and locally massive lenses, veins, and breccia fillings of magnetite were encountered along most of this length, but more consistently between the depths of 82 and 435 meters. The average iron content of this section in the form of magnetite was 16.4 percent. Several sections, each about 20 meters in length, contained from 22.4 to 31 percent iron. Extrapolation of costs from current taconite iron ore operations in the United States, beneficiating ores averaging 23 percent iron, suggests that ore of similar or possibly lower iron content from Jabal Ideas could be mined and processed at comparable if not at somewhat lower costs. The beneficiation product, containing about 64 percent iron, would have a current value of $16.00 per long ton at the point of use. On the basis of information presently available there is a reasonable expectation that reserves of the order of 75 to 125 million tons could be developed at Jabal Ideas to sustain a similar operation. Tin, not previously reported from this district, was found in the cores in small but widely distributed amounts averaging perhaps .01 percent. Although the amount is anomalous it is probably not of economic significance in the magnetite area, but one should not at this stage discount the possibility of finding higher concentrations of tin elsewhere in the district. The origin of the magnetite in this geologic setting is attributed largely to the uralitization of high-iron pyroxene. It is believed that this interpretation is a more useful guide to further exploration than other explanations previously adduced.

Jabal Idsas↗
USGS2026

Geochemical geodatabase of sedimentary strata (coal, coal-adjacent rocks, tuffaceous oil shale, phosphate-rich rocks) and produced water in the Uinta region, Utah and Colorado

The Geochemical Geodatabase of Sedimentary Strata (Coal, Coal-adjacent Rocks, Tuffaceous Oil Shale, Phosphate-rich Rocks) and Produced Water in the Uinta Region, Utah and Colorado, consists of compiled datasets acquired as part of the Carbon Ore, Rare Earth, and Critical Mineral (CORE-CM) Uinta Region assessment funded by the U.S. Department of Energy (DEFE0032046, 2021–2024; Birgenheier et al., 2024). The CORE-CM assessment focused on providing comprehensive geological and geochemical characterization of current and prospective sedimentary-hosted resources including coal, oil shale, phosphatic limestone, and produced water from oil and gas targets present in eastern Utah and northwestern Colorado (Figure 1). This Data Series includes a geodatabase that consists of analytical geochemical data collected September 2021 through December 2024 via portable X-ray fluorescence (pXRF), and laboratory measured analyses produced by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectroscopy (ICP-OES). The coal-related geochemical data are derived primarily from the Cretaceous Blackhawk Formation and Ferron Sandstone of Utah, and the Mesaverde Group of Colorado. Additional non-coal resources assessed include oil shale-bearing strata of the Eocene upper Green River Formation (Utah and Colorado), phosphate-rich limestone of the Permian Park City Formation (Utah) and produced water from oil and gas-bearing strata of the Eocene Green River and Wasatch Formations (Uinta Basin) and the Pennsylvanian Paradox Formation (Paradox Basin) (Table 1). The CORE-CM assessment included a wide range of lithologies present in the coal, oil shale, and phosphate geologic resource systems whether or not the specific lithology has current economic value. Geochemical analyses of produced water from oil and gas wells focused on current and emerging hydrocarbon targets in the central Uinta Basin and northern Paradox Basin. A total of 13,092 geochemical analyses from these geologic systems is provided in the included geodatabase. A series of coal quality data (e.g., composition and maceral analyses) is also included in the database and was digitized from archived coal samples from the Utah Geological Survey (Appendix A).

Colorado, Utah↗
USGS1964

Evaluation of hydrogeology and hydrogeochemistry of Truckee Meadows area, Washoe County, Nevada

Practically all the ground water of economic importance in the Truckee Meadows area, an alluviated intermontane basin in western Nevada is in the valley fill, which consists of unconsolidated and partially consolidated sedimentary deposits. The Mesozoic and Cenozoic consolidated rocks of the mountains bordering the valley contain some water in fractures and other openings, but they have virtually no interstitial permeability. The permeability of the valley fill is extremely variable. The Truckee Formation, which is the oldest deposit of the valley fill, yields very little water to wells. Permeable lenses of sand and gravel in the valley fill that are younger than the Truckee Formation yield moderate to large amounts of water to wells. The estimated average annual recharge to and discharge from the groundwater reservoir is 35,000 acre-feet. About 25,000 acre-feet of the recharge is from the infiltration of irrigation water diverted from the Truckee River. Most of the discharge is by evapotranspiration and by seepage to ditches and streams. Some water in the area is unsuitable for many uses because of its poor chemical quality. Water in the Steamboat Springs area is hot and has high concentrations of chloride and dissolved solids. Both water draining areas of bleached rock and ground water downgradient from areas of leached rock have high concentrations of sulfate and dissolved solids. Surface water of low dissolved-solids content mixes with and dilutes some highly mineralized ground water. Increased pumping in discharge areas will help to alleviate waterlogged conditions and will decrease ground-water losses by evapotranspiration. Increased pumping near the Truckee River may induce recharge from the river to the ground-water system.

Water Supply Paper↗
USGS1984

Systematics of stretching of fluid inclusions; I. Fluorite and sphalerite at 1 atmosphere confining pressure

More than 1,300 measurements on fluid inclusions in fluorite and sphalerite indicate that stretching proceeds systematically and predictably. In order to generate internal pressures that are sufficiently high to cause stretching, most inclusions must be heated beyond their initial homogenization temperatures, i.e., overheated. The amount of overheating necessary to initiate stretching depends on the P-V-T-X properties of the inclusion fluid, the inclusion size and shape, physical properties of the host mineral, and the confining pressure. In the range of homogenization temperatures and salinities examined in this study, the amount of overheating necessary to initiate stretching of inclusions in fluorite is inversely related to inclusion volume. The results of this study show that the measured homogenization temperature of a fluid inclusion may be considerably higher than the true homogenization temperature if the internal pressure reached sufficiently high values during previous testing in the laboratory or, less likely, during postentrapment thermal events in nature. The systematic relationship between the internal pressure necessary to initiate stretching and the inclusion volume provides a means of recognizing previously stretched inclusions and estimating the magnitude of postentrapment thermal events. Furthermore, reproducibility of homogenization temperature measurements, lack of microscopically observable fractures in the inclusion walls, and the lack of a noticeable increase in the vapor bubble size after heating are insufficient to prove that an inclusion has not stretched.

Economic Geology↗
USGS1979

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗
USGS1974

Economic geology of the Isla de Mona Quadrangle, Puerto Rico

Limiting this tableland In the northern part of Isla de Mona are sheer sea cliffs chiefly exposing the Isla de Mona Dolomite. Around the southern part of the island are Irregular cliffs and steep slopes that chiefly expose the Lirio Limestone. The structure of Isla de Mona consists of two gentle complex folds a broad anticline that trends and plunges gently south-southeast through the central and western parts of Isla de Mona, and a parallel syncline through-the eastern part of the Island that also has a chiefly south-southeast plunge. A near-vertical fault that strikes northwest, then north from the central part to the north coast of Isla de Mona displaces bedrock of the eastern block downward about 10 m. Many caves, including one cave system more than 100,000 m2 in total area, are localized in the lower 10 m of the Lirio Limestone, adjacent to the cliffs peripheral to the upland surface, and numerous small caves occur higher in the Lirio. A few small caves also are found In the Isla de Mona Dolomite. However, the total floor area of all caves on Isla de Mona probably is less than 1 percent of the area of the Island. Almost all caves on Isla de Mona contain phosphorite, which was mined extensively during the late 19th and early 20th centuries. Phosphorite accumulation locally may have exceeded 3.5 m in thickness, but probably averaged less than 1.5 m thick. A fair estimate of original reserves of phosphorite in 12 surveyed caves is about 151,000 m3 of which about 125,500 m3 probably has been removed in mining. Original reserves in the entire island are estimated to have been in the range 158,000 to 235,500 m3. Converted to metric tons, remaining reserves of cave phosphorite probably are considerably less than 50,000. The very pure limestone and calcitic dolomite that form the bedrock of Isla de Mona are abundant industrial-mineral resources. In addition, these carbonate rocks and the beach deposits are sources of construction materials for some classes of engineering works. The structure of Isla de Mona suggests some possibility of favorable zones for accumulation of oil and gas, but no source rocks are known, and there are no confirmed reports of oil and gas from any nearby area. Known supplies of fresh water on Isla de Mona are very small, but wells dug in coastal lowlands or drilled In the upland surface might yield moderate quantities of groundwater.

Open-File Report↗
USGS1985

Near-infrared spectra of West Shasta gossans compared with true and false gossans from Australia and Saudi Arabia

The near-infrared spectra of a suite of outcrop samples of massive sulfide gossans and false gossans representing three different weathering environments were measured and studied with X-ray, scanning electron microscope, and energy dispersive X-ray. Gossans that formed in a humid tropical environment are represented by samples from the Mt. Isa area, Queensland, Australia, and gossans that formed in an arid environment are represented by samples from several locations in Saudi Arabia. The gossans of the West Shasta massive sulfide district in California represent a weathering environment intermediate between these two extremes.On the basis of these spectral measurements, true gossans after massive sulfide deposits have spectra in the 800 to 2,500 nanometer (nm) region that are distinctly different from the spectra of false gossans. In the humid tropical environment, highly leached, newly formed kaolin minerals in the gossan cause spectral differences at about 1,400 to 2,200 nm. In the arid environment, true gossans preserve talc and minor mica from the massive sulfide deposit; these minerals are not observed in false gossans. These minerals result in spectral differences in the 2,200- to 2,300-nm region. In addition, true gossans generally have goethite spectral bands at about 900 nm as opposed to hematite spectral bands at about 850 nm for the false gossans.False gossans are not known in the West Shasta district; however, the gossan at the largest deposit, Iron Mountain, is a true gossan that has the distinctive spectral features of goethite at about 900 nm and diaspore in the 1,400- to 2,500-nm region. The other gossans also have the spectral features of goethite, but they contain a less leached mixture of kaolinite plus illite and have distinctive spectral features in the 1,400- to 2,500-nm region. These spectral differences define two groups of West Shasta gossans--inner gossans in large deposits and outer gossans at the margins of large deposits and in lesser massive sulfide deposits.

Economic Geology↗
USGS2010

Sediment-hosted lead-zinc deposits in Earth history

Sediment-hosted Pb-Zn deposits can be divided into two major subtypes. The first subtype is clastic-dominated lead-zinc (CD Pb-Zn) ores, which are hosted in shale, sandstone, siltstone, or mixed clastic rocks, or occur as carbonate replacement, within a CD sedimentary rock sequence. This subtype includes deposits that have been traditionally referred to as sedimentary exhalative (SEDEX) deposits. The CD Pb-Zn deposits occur in passive margins, back-arcs and continental rifts, and sag basins, which are tectonic settings that, in some cases, are transitional into one another. The second subtype of sediment-hosted Pb-Zn deposits is the Mississippi Valley-type (MVT Pb-Zn) that occurs in platform carbonate sequences, typically in passive-margin tectonic settings. Considering that the redox state of sulfur is one of the major controls on the extraction, transport, and deposition of Pb and Zn at shallow crustal sites, sediment-hosted Pb-Zn ores can be considered a special rock type that recorded the oxygenation of Earth’s hydrosphere. The emergence of CD and MVT deposits in the rock record between 2.02 Ga, the age of the earliest known deposit of these ores, and 1.85 to 1.58 Ga, a major period of CD Pb-Zn mineralization in Australia and India, corresponds to a time after the Great Oxygenation Event that occurred at ca 2.4 to 1.8 Ga. Contributing to the abundance of CD deposits at ca 1.85 to 1.58 Ga was the following: (1) enhanced oxidation of sulfides in the crust that provided sulfate to the hydrosphere and Pb and Zn to sediments; (2) development of major redox and compositional gradients in the oceans; (3) first formation of significant sulfate-bearing evaporites; (4) formation of red beds and oxidized aquifers, possibly containing easily extractable Pb and Zn; (5) evolution of sulfate-reducing bacteria; and (6) formation of large and long-lived basins on stable cratons. Although MVT and CD deposits appeared for the first time in Earth history at 2.02 Ga, only CD deposits were important repositories for Pb and Zn in sediments between the Great Oxygenation Event, until after the second oxidation of the atmosphere in the late Neoproterozic. Increased oxygenation of the oceans following the second oxidation event led to an abundance of evaporites, resulting oxidized brines, and a dramatic increase in the volume of coarse-grained and permeable carbonates of the Paleozoic carbonate platforms, which host many of the great MVT deposits. The MVT deposits reached their maximum abundance during the final assembly of Pangea from Devonian into the Carboniferous. This was also a time for important CD mineral deposit formation along passive margins in evaporative belts of Pangea. Following the breakup of Pangea, a new era of MVT ores began with the onset of the assembly of the Neosupercontinent. A significant limitation on interpreting the secular distribution of the deposits is that there is no way to quantitatively evaluate the removal of deposits from the rock record through tectonic recycling. Considering that most of the sedimentary rock record has been recycled, most sediment-hosted Pb-Zn deposits probably have also been destroyed by subduction and erosion, or modified by metamorphism and tectonism, so that they are no longer recognizable. Thus, the uneven secular distribution of sediment-hosted Pb-Zn deposits reflects the genesis of these deposits, linked to Earth’s evolving tectonic and geochemical systems, as well as an unknown amount of recycling of the sedimentary rock record.

Economic Geology↗
USGS1971

The effect of salinity on the maximum thermal gradient of a hydrothermal system at hydrostatic pressure

The effect of salinity on the temperature-depth relations of a brine of constant composition, enclosed in a vein system, but freely connected to the surface, and everywhere at the boiling point for the hydrostatic head, was calculated by using a mathematical model. The Na-Ca-K-Cl brines which are found in thermal springs and in fluid inclusions in ore minerals were approximated by the available data for vapor-saturated NaCl-H 2 O solutions. In general, the results are similar to those calculated by D. E. White in 1968 for H 2 O, except that the gradients are steeper because of the increase in density and the decrease in vapor pressure caused by the dissolved salt. As a practical rule, the depth to an isotherm in a 5, 10, 15, 20, and 25 wt percent NaCl brine system is, respectively, 92, 84, 77, 70, and 63 percent (+ or -2 percent) of the depth to the same isotherm in an H 2 O system. From the data presented, the minimum depth to the growth site of crystals containing fluid inclusions which indicate boiling of the brine can be estimated. Among other applications, these results are useful toward the understanding of the behavior of brines in geothermal areas which may or may not contain compositional stratification.

Economic Geology↗
USGS1982

Mineralogy and geochemistry of Fe-Ti oxide and apatite (nelsonite) deposits and evaluation of the liquid immiscibility hypothesis.

Modal mineralogy determined for 32 Fe-Ti oxide and apatite rocks from localities in Virginia, New York, Quebec, Norway, and Sweden largely supports the 2:1 oxide:apatite ratio suggested as a eutectic mixture by Philpotts (1967). A fairly consistent suite of accessory minerals, including biotite, clinoamphibole, spinel, zircon, and sulfides, is present. Some silicate accessory minerals tend to form glomeroporphyritic intergrowths in an equigranular matrix of nelsonite, suggesting that the accessories are xenocrysts that have been trapped in an oxide-apatite liquid. This liquid may represent an extreme case of partitioning of high charge-density cations into a low silica, phosphorus-enriched immiscible melt. Temperature and oxygen fugacity estimates for oxide pairs in nelsonites range from 600 degrees to 1,000 degrees C and 10 (super -20) to 10 (super -11) atm f (sub o 2 ) and bracket an equilibration path that is close to the FMQ buffer curve. Several stages of exsolution are evident in Fe-Ti oxides of some deposits. Nelsonites contain fluorapatite that is enriched in light lanthanides. The occurrence of nelsonite "dikes" in Roseland anorthosite and associated rocks of the Roseland-Piney River district of Virginia is explained by the infilling of fractures with nelsonite liquid that has settled out of an overlying ferrodiorite pluton.

Economic Geology↗