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At least 1,045 records · Page 58Linked to original sources

Computer program calculation of gas supersaturation in water

A short computer program, written in BASIC for the Apple IIe or IBM PC computer, efficiently performs all the calculations required to determine gas pressure and percent saturation values for water. Input for the program is limited to empirical determinations of barometric pressure, water temperature, differential dissolved gas pressures, dissolved oxygen, and salinity. An optional routine is included for obtaining a printed report of input data and results. The program can be easily modified to run on most other microcomputers that use BASIC programming language.

Progressive Fish-Culturist↗

Applying computer simulation models as learning tools in fishery management

Computer models can be powerful tools for addressing many problems in fishery management, but uncertainty about how to apply models and how they should perform can lead to a cautious approach to modeling. Within this approach, we expect models to make quantitative predictions but only after all model inputs have been estimated from empirical data and after the model has been tested for agreement with an independent data set. I review the limitations to this approach and show how models can be more useful as tools for organizing data and concepts, learning about the system to be managed, and exploring management options. Fishery management requires deciding what actions to pursue to meet management objectives. Models do not make decisions for us but can provide valuable input to the decision‐making process. When empirical data are lacking. preliminary modeling with parameters derived from other sources can help determine priorities for data collection. When evaluating models for management applications, we should attempt to define the conditions under which the model is a useful, analytical tool (its domain of applicability) and should focus on the decisions made using modeling results, rather than on quantitative model predictions. I describe an example of modeling used as a learning tool for the yellow perch Perca flavescens fishery in Green Bay, Lake Michigan.

Wisconsin↗

Ice processes affect habitat use and movements of adult cutthroat trout and brook trout in a Wyoming foothills stream

Habitat use and movements of 25 adult cutthroat trout Oncorhynchus clarkii and 25 adult brook trout Salvelinus fontinalis from fall through winter 2002-2003 were assessed by means of radiotelemetry in a 7-km reach of a Rocky Mountains foothills stream. Temporal dynamics of winter habitat conditions were evaluated by regularly measuring the features of 30 pools and 5 beaver Castor canadensis ponds in the study reach. Groundwater inputs at three locations raised mean daily water temperatures in the stream channel during winter to 0.2-0.6??C and kept at least 250 m of the downstream channel free of ice, but the lack of surface ice further downstream led to the occurrence of frazil ice and anchor ice in pools and unstable habitat conditions for trout. Pools in segments that were not affected by groundwater inputs and beaver ponds tended to be stable and snow accumulated on the surface ice. Pools throughout the study reach tended to become more stable as snow accumulated. Both cutthroat trout and brook trout selected beaver ponds as winter progressed but tended to use lateral scour pools in proportion to their availability. Tagged fish not in beaver ponds selected lateral scour pools that were deeper than average and stable during winter. Movement frequencies by tagged fish decreased from fall through winter, but some individuals of both species moved during winter. Ice processes affected both the habitat use and movement patterns of cutthroat trout and brook trout in this foothills stream.

North American Journal of Fisheries Management↗

Spatial modeling of wild bird risk factors to investigate highly pathogenic A(H5N1) avian influenza virus transmission

One of the longest-persisting avian influenza viruses in history, highly pathogenic avian influenza virus (HPAIV) A(H5N1), continues to evolve after 18 years, advancing the threat of a global pandemic. Wild waterfowl (family Anatidae), are reported as secondary transmitters of HPAIV, and primary reservoirs for low-pathogenic avian influenza viruses, yet spatial inputs for disease risk modeling for this group have been lacking. Using GIS and Monte Carlo simulations, we developed geospatial indices of waterfowl abundance at 1 and 30 km resolutions and for the breeding and wintering seasons for China, the epicenter of H5N1. Two spatial layers were developed: cumulative waterfowl abundance (WAB), a measure of predicted abundance across species, and cumulative abundance weighted by H5N1 prevalence (WPR), whereby abundance for each species was adjusted based on prevalence values then totaled across species. Spatial patterns of the model output differed between seasons, with higher WAB and WPR in the northern and western regions of China for the breeding season and in the southeast for the wintering season. Uncertainty measures indicated highest error in southeastern China for both WAB and WPR. We also explored the effect of resampling waterfowl layers from 1 km to 30 km resolution for multi-scale risk modeling. Results indicated low average difference (less than 0.16 and 0.01 standard deviations for WAB and WPR, respectively), with greatest differences in the north for the breeding season and southeast for the wintering season. This work provides the first geospatial models of waterfowl abundance available for China. The indices provide important inputs for modeling disease transmission risk at the interface of poultry and wild birds. These models are easily adaptable, have broad utility to both disease and conservation needs, and will be available to the scientific community for advanced modeling applications.

Avian Diseases↗

Evaluation of landscape models for wolverines in the interior Northwest, United States of America

The wolverine (Gulo gulo) is an uncommon, wide-ranging carnivore of conservation concern. We evaluated performance of landscape models for wolverines within their historical range at 2 scales in the interior Northwest based on recent observations (n = 421) from Washington, Oregon, Idaho, and Montana. At the subbasin scale, simple overlays of habitat and road-density classes were effective in predicting observations of wolverines. At the watershed scale, we used a Bayesian belief network model to provide spatially explicit estimates of relative habitat capability. The model has 3 inputs: amount of habitat, human population density, and road density. At both scales, the best models revealed strong correspondence between means of predicted counts of wolverines and means of observed counts (P < 0.001). Our results can be used to guide regional conservation planning for this elusive animal.

Journal of Mammalogy↗

Fertility of the early post-eruptive surfaces of Kasatochi Island volcano

In the four years after the 2008 eruption and burial of Kasatochi Island volcano, erosion and the return of bird activity have resulted in new and altered land surfaces and initiation of ecosystem recovery. We examined fertility characteristics of the recently deposited pyroclastic surfaces, patches of legacy pre-eruptive surface soil (LS), and a post-eruptive surface with recent bird roosting activity. Pyroclastic materials were found lacking in N, but P, K, and other macronutrients were in sufficient supply for plants. Erosion and leaching are moving mobile P and Fe downslope to deposition fan areas. Legacy soil patches that currently support plants have available-N at levels (10–22 mg N kg -1 ) similar to those added by birds in a recent bird roosting area. Roosting increased surface available N from <1 mg N kg -1 in the new pyroclastic surfaces to up to 42 mg N kg -1 and increased soil biological respiration of CO 2 from essentially zero to a level about 40% that of the LS surface. Laboratory plant growth trials using Lupinus nootkatensis and Leymus mollis indicated that the influence of eroded and redeposited LS in amounts as little as 10% by volume mixed with new pyroclastic materials could aid plant recovery by supplying vital N and soil biota to plants as propagules are introduced to the new surface. Erosion-exposure of fertile pre-eruptive soils and erosion-mixing of pre-eruptive soils with newly erupted materials, along with inputs of nutrients from bird activities, each will exert significant influences on the surface fertility and recovery pattern of the new post-eruptive Kasatochi volcano. For this environment, these influences could help to speed recovery of a more diverse plant community by providing N (LS and bird inputs) as alternatives to relying most heavily on N-fixing plants to build soil fertility.

Alaska↗

An automatic P‐Phase arrival‐time picker

Presented is a new approach for picking P ‐phase arrival time in single‐component acceleration or broadband velocity records without requiring detection interval or threshold settings. The algorithm P PHASE P ICKER transforms the signal into a response domain of a single‐degree‐of‐freedom (SDOF) oscillator with viscous damping and then tracks the rate of change of dissipated damping energy to pick P ‐wave phases. The SDOF oscillator has a short natural period and a correspondingly high resonant frequency, which is higher than most frequencies in a seismic wave. It also has a high damping ratio (60% of critical). At this damping level, the frequency response approaches the Butterworth maximally flat magnitude filter, and phase angles are preserved. The relative input energy imparted to the oscillator by the input signal is converted to elastic strain energy and then dissipated by the damping element as damping energy. The damping energy yields a smooth envelope over time; it is zero in the beginning of the signal, zero or near zero before the P ‐phase arrival, and builds up rapidly with the P wave. Because the damping energy function changes considerably at the onset of the P wave, it is used as a metric to track and pick the P ‐phase arrival time. The P PHASE P ICKER detects P ‐phase onset using the histogram method. Its performance is compared with picking techniques using short‐term‐average to long‐term‐average ratio, and a picking method that finds the first P ‐phase arrival time using the Akaike information criterion. A large set of records with various intensities and signal‐to‐noise ratios is used for testing the P PHASE P ICKER , and it is demonstrated that P PHASE P ICKER is able to more accurately pick the onset of genuine signals against the background noise and to correctly distinguish between whether the first arrival is a P wave (emergent or impulsive) or whether the signal is from a faulty sensor.

Bulletin of the Seismological Society of America↗

Seismic‐hazard forecast for 2016 including induced and natural earthquakes in the central and eastern United States

The U.S. Geological Survey (USGS) has produced a one‐year (2016) probabilistic seismic‐hazard assessment for the central and eastern United States (CEUS) that includes contributions from both induced and natural earthquakes that are constructed with probabilistic methods using alternative data and inputs. This hazard assessment builds on our 2016 final model ( Petersen et al. , 2016 ) by adding sensitivity studies, illustrating hazard in new ways, incorporating new population data, and discussing potential improvements. The model considers short‐term seismic activity rates (primarily 2014–2015) and assumes that the activity rates will remain stationary over short time intervals. The final model considers different ways of categorizing induced and natural earthquakes by incorporating two equally weighted earthquake rate submodels that are composed of alternative earthquake inputs for catalog duration, smoothing parameters, maximum magnitudes, and ground‐motion models. These alternatives represent uncertainties on how we calculate earthquake occurrence and the diversity of opinion within the science community. In this article, we also test sensitivity to the minimum moment magnitude between M 4 and M 4.7 and the choice of applying a declustered catalog with b =1.0 rather than the full catalog with b =1.3. We incorporate two earthquake rate submodels: in the informed submodel we classify earthquakes as induced or natural, and in the adaptive submodel we do not differentiate. The alternative submodel hazard maps both depict high hazard and these are combined in the final model. Results depict several ground‐shaking measures as well as intensity and include maps showing a high‐hazard level (1% probability of exceedance in 1 year or greater). Ground motions reach 0.6 g horizontal peak ground acceleration (PGA) in north‐central Oklahoma and southern Kansas, and about 0.2 g PGA in the Raton basin of Colorado and New Mexico, in central Arkansas, and in north‐central Texas near Dallas–Fort Worth. The chance of having levels of ground motions corresponding to modified Mercalli intensity (MMI) VI or greater earthquake shaking is 2%–12% per year in north‐central Oklahoma and southern Kansas and New Madrid similar to the chance of damage at sites in high‐hazard portions of California caused by natural earthquakes. Hazard is also significant in the Raton basin of Colorado/New Mexico; north‐central Arkansas; Dallas–Fort Worth, Texas; and in a few other areas. Hazard probabilities are much lower (by about half or more) for exceeding MMI VII or VIII. Hazard is 3‐ to 10‐fold higher near some areas of active‐induced earthquakes than in the 2014 USGS National Seismic Hazard Model (NSHM), which did not consider induced earthquakes. This study in conjunction with the LandScan TM Database (2013) indicates that about 8 million people live in areas of active injection wells that have a greater than 1% chance of experiencing damaging ground shaking (MMI≥VI) in 2016. The final model has high uncertainty, and engineers, regulators, and industry should use these assessments cautiously to make informed decisions on mitigating the potential effects of induced and natural earthquakes.

Seismological Research Letters↗

Annualized earthquake loss estimates for California and their sensitivity to site amplification

Input datasets for annualized earthquake loss (AEL) estimation for California were updated recently by the scientific community, and include the National Seismic Hazard Model (NSHM), site‐response model, and estimates of shear‐wave velocity. Additionally, the Federal Emergency Management Agency’s loss estimation tool, Hazus, was updated to include the most recent census and economic exposure data. These enhancements necessitated a revisit to our previous AEL estimates and a study of the sensitivity of AEL estimates subjected to alternate inputs for site amplification. The NSHM ground motions for a uniform site condition are modified to account for the effect of local near‐surface geology. The site conditions are approximated in three ways: (1) by VS30 (time‐averaged shear‐wave velocity in the upper 30 m) value obtained from a geology‐ and topography‐based map consisting of 15 VS30 groups, (2) by site classes categorized according to National Earthquake Hazards Reduction Program (NEHRP) site classification, and (3) by a uniform NEHRP site class D. In case 1, ground motions are amplified using the Seyhan and Stewart (2014) semiempirical nonlinear amplification model. In cases 2 and 3, ground motions are amplified using the 2014 version of the NEHRP site amplification factors, which are also based on the Seyhan and Stewart model but are approximated to facilitate their use for building code applications. Estimated AELs are presented at multiple resolutions, starting with the state level assessment and followed by detailed assessments for counties, metropolitan statistical areas (MSAs), and cities. AEL estimate at the state level is ∼$3.7 billion, 70% of which is contributed from Los Angeles–Long Beach–Santa Ana, San Francisco–Oakland–Fremont, and Riverside–San Bernardino–Ontario MSAs. The statewide AEL estimate is insensitive to alternate assumptions of site amplification. However, we note significant differences in AEL estimates among the three sensitivity cases for smaller geographic units.

California↗

Unexpected dominance of parent-material strontium in a tropical forest on highly weathered soils

Controls over nutrient supply are key to understanding the structure and functioning of terrestrial ecosystems. Conceptual models once held that in situ mineral weathering was the primary long-term control over the availability of many plant nutrients, including the base cations calcium (Ca), magnesium (Mg), and potassium (K). Recent evidence has shown that atmospheric sources of these “rock-derived” nutrients can dominate actively cycling ecosystem pools, especially in systems on highly weathered soils. Such studies have relied heavily on the use of strontium isotopes as a proxy for base-cation cycling. Here we show that vegetation and soil-exchangeable pools of strontium in a tropical rainforest on highly weathered soils are still dominated by local rock sources. This pattern exists despite substantial atmospheric inputs of Sr, Ca, K, and Mg, and despite nearly 100% depletion of these elements from the top 1 m of soil. We present a model demonstrating that modest weathering inputs, resulting from tectonically driven erosion, could maintain parent-material dominance of actively cycling Sr. The majority of tropical forests are on highly weathered soils, but our results suggest that these forests may still show considerable variation in their primary sources of essential nutrients.

Ecology↗

Variation in &delta; 13 C and &delta; 15 N diet&ndash;vibrissae trophic discrimination factors in a wild population of California sea otters

The ability to quantify dietary inputs using stable isotope data depends on accurate estimates of isotopic differences between a consumer (c) and its diet (d), commonly referred to as trophic discrimination factors (TDFs) and denoted by &Delta; c-d . At present, TDFs are available for only a few mammals and are usually derived in captive settings. The magnitude of TDFs and the degree to which they vary in wild populations is unknown. We determined &delta; 13 C and &delta; 15 N TDFs for vibrissae (i.e., whiskers), a tissue that is rapidly becoming an informative isotopic substrate for ecologists, of a wild population of sea otters for which individual diet has been quantified through extensive observational study. This is one of the very few studies that report TDFs for free-living wild animals feeding on natural diets. Trophic discrimination factors of 2.2‰ &plusmn; 0.7‰ for &delta; 13 C and 3.5‰ &plusmn; 0.6‰ for &delta; 15 N (mean &plusmn; SD) were similar to those reported for captive carnivores, and variation in individual &delta; 13 C TDFs was negatively but significantly related to sea urchin consumption. This pattern may relate to the lipid-rich diet consumed by most sea otters in this population and suggests that it may not be appropriate to lipid-extract prey samples when using the isotopic composition of keratinaceous tissues to examine diet in consumers that frequently consume lipid-rich foods, such as many marine mammals and seabirds. We suggest that inherent variation in TDFs should be included in isotopically based estimates of trophic level, food chain length, and mixing models used to quantify dietary inputs in wild populations; this practice will further define the capabilities and limitations of isotopic approaches in ecological studies.

Ecological Applications↗

Denitrification across landscapes and waterscapes: A synthesis

Denitrification is a critical process regulating the removal of bioavailable nitrogen (N) from natural and human-altered systems. While it has been extensively studied in terrestrial, freshwater, and marine systems, there has been limited communication among denitrification scientists working in these individual systems. Here, we compare rates of denitrification and controlling factors across a range of ecosystem types. We suggest that terrestrial, freshwater, and marine systems in which denitrification occurs can be organized along a continuum ranging from (1) those in which nitrification and denitrification are tightly coupled in space and time to (2) those in which nitrate production and denitrification are relatively decoupled. In aquatic ecosystems, N inputs influence denitrification rates whereas hydrology and geomorphology influence the proportion of N inputs that are denitrified. Relationships between denitrification and water residence time and N load are remarkably similar across lakes, river reaches, estuaries, and continental shelves. Spatially distributed global models of denitrification suggest that continental shelf sediments account for the largest portion (44%) of total global denitrification, followed by terrestrial soils (22%) and oceanic oxygen minimum zones (OMZs; 14%). Freshwater systems (groundwater, lakes, rivers) account for about 20% and estuaries 1% of total global denitrification. Denitrification of land-based N sources is distributed somewhat differently. Within watersheds, the amount of land-based N denitrified is generally highest in terrestrial soils, with progressively smaller amounts denitrified in groundwater, rivers, lakes and reservoirs, and estuaries. A number of regional exceptions to this general trend of decreasing denitrification in a downstream direction exist, including significant denitrification in continental shelves of N from terrestrial sources. Though terrestrial soils and groundwater are responsible for much denitrification at the watershed scale, per-area denitrification rates in soils and groundwater (kg N·km −2 ·yr −1 ) are, on average, approximately one-tenth the per-area rates of denitrification in lakes, rivers, estuaries, continental shelves, or OMZs. A number of potential approaches to increase denitrification on the landscape, and thus decrease N export to sensitive coastal systems exist. However, these have not generally been widely tested for their effectiveness at scales required to significantly reduce N export at the whole watershed scale.

Ecological Applications↗

Terrestrial carbon is a resource, but not a subsidy, for lake zooplankton

Inputs of terrestrial organic carbon (t-OC) into lakes are often considered a resource subsidy for aquatic consumer production. Although there is evidence that terrestrial carbon can be incorporated into the tissues of aquatic consumers, its ability to enhance consumer production has been debated. Our research aims to evaluate the net effect of t-OC input on zooplankton. We used a survey of zooplankton production and resource use in ten lakes along a naturally occurring gradient of t-OC concentration to address these questions. Total and group-specific zooplankton production was negatively related to t-OC. Residual variation in zooplankton production that was not explained by t-OC was negatively related to terrestrial resource use (allochthony) by zooplankton. These results challenge the designation of terrestrial carbon as a resource subsidy; rather, the negative effect of reduced light penetration on the amount of suitable habitat and the low resource quality of t-OC appear to diminish zooplankton production. Our findings suggest that ongoing continental-scale increases in t-OC concentrations of lakes will likely have negative impacts on the productivity of aquatic food webs.

Michigan;Wisconsin↗

Accounting for groundwater in stream fish thermal habitat responses to climate change

Forecasting climate change effects on aquatic fauna and their habitat requires an understanding of how water temperature responds to changing air temperature (i.e., thermal sensitivity). Previous efforts to forecast climate effects on brook trout habitat have generally assumed uniform air-water temperature relationships over large areas that cannot account for groundwater inputs and other processes that operate at finer spatial scales. We developed regression models that accounted for groundwater influences on thermal sensitivity from measured air-water temperature relationships within forested watersheds in eastern North America (Shenandoah National Park, USA, 78 sites in 9 watersheds). We used these reach-scale models to forecast climate change effects on stream temperature and brook trout thermal habitat, and compared our results to previous forecasts based upon large-scale models. Observed stream temperatures were generally less sensitive to air temperature than previously assumed, and we attribute this to the moderating effect of shallow groundwater inputs. Predicted groundwater temperatures from air-water regression models corresponded well to observed groundwater temperatures elsewhere in the study area. Predictions of brook trout future habitat loss derived from our fine-grained models were far less pessimistic than those from prior models developed at coarser spatial resolutions. However, our models also revealed spatial variation in thermal sensitivity within and among catchments resulting in a patchy distribution of thermally suitable habitat. Habitat fragmentation due to thermal barriers therefore may have an increasingly important role for trout population viability in headwater streams. Our results demonstrate that simple adjustments to air-water temperature regression models can provide a powerful and cost-effective approach for predicting future stream temperatures while accounting for effects of groundwater.

Virginia↗

Development of a mercury speciation, fate, and biotic uptake (BIOTRANSPEC) model: Application to Lahontan Reservoir (Nevada, USA)

A mathematically linked mercury transport, speciation, kinetic, and simple biotic uptake (BIOTRANSPEC) model has been developed. An extension of the metal transport and speciation (TRANSPEC) model, BIOTRANSPEC estimates the fate and biotic uptake of inorganic (Hg(II)), elemental (Hg(0)) and organic (MeHg) forms of mercury and their species in the dissolved, colloidal (e.g., dissolved organic matter [DOM]), and particulate phases of surface aquatic systems. A pseudo-steady state version of the model was used to describe mercury dynamics in Lahontan Reservoir (near Carson City, NV, USA), where internal loading of the historically deposited mercury is remobilized, thereby maintaining elevated water concentrations. The Carson River is the main source of total mercury (THg), of which more than 90% is tightly bound in a gold-silver-mercury amalgam, to the system through loadings in the spring, with negligible input from the atmospheric deposition. The speciation results suggest that aqueous species are dominated by Hg-DOM, Hg(OH)2, and HgClOH. Sediment-to-water diffusion of MeHg and Hg-DOM accounts for approximately 10% of total loadings to the water column. The water column acts as a net sink for MeHg by reducing its levels through two competitive processes: Uptake by fish, and net MeHg demethylation. Although reservoir sediments produce significant amounts of MeHg (4 g/d), its transport from sediment to water is limited (1.6 g/d), possibly because of its adsorption on metal oxides of iron and manganese at the sediment-water interface. Fish accumulate approximately 45% of the total MeHg mass in the water column, and 9% of total MeHg uptake by fish leaves the system because of fishing. Results from this new model reiterate the previous conclusion that more than 90% of THg input is retained in sediment, which perpetuates elevated water concentrations.

Nevada↗

Benthic nutrient sources to hypereutrophic Upper Klamath Lake, Oregon, USA

Three collecting trips were coordinated in April, May, and August 2006 to sample the water column and benthos of hypereutrophic Upper Klamath Lake (OR, USA) through the annual cyanophyte bloom of Aphanizomenon flos‐aquae . A pore‐water profiler was designed and fabricated to obtain the first high‐resolution (centimeter‐scale) estimates of the vertical concentration gradients of macro‐ and micronutrients for diffusive‐flux determinations. A consistently positive benthic flux for soluble reactive phosphorus (SRP) was observed with solute release from the sediment, ranging between 0.4 and 6.1 mg/m 2 /d. The mass flux over an approximate 200‐km 2 lake area was comparable in magnitude to riverine inputs. An additional concern related to fish toxicity was identified when dissolved ammonium also displayed consistently positive benthic fluxes of 4 to 134 mg/m 2 /d, again comparable to riverine inputs. Although phosphorus was a logical initial choice by water quality managers for the limiting nutrient when nitrogen‐fixing cyanophytes dominate, initial trace‐element results from the lake and major inflowing tributaries suggested that the role of iron limitation on primary productivity should be investigated. Dissolved iron became depleted in the lake water column during the course of the algal bloom, while dissolved ammonium and SRP increased. Elevated macroinvertebrate densities, at least of the order of 10 4 individuals/m 2 , suggested that the diffusive‐flux estimates may be significantly enhanced by bioturbation. In addition, heat‐flux modeling indicated that groundwater advection of nutrients could also significantly contribute to internal nutrient loading. Accurate environmental assessments of lentic systems and reasonable expectations for point‐source management require quantitative consideration of internal solute sources.

Environmental Toxicology and Chemistry↗

Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream

The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by ~30% and is accompanied by net loss of channel discharge and extensive surface–subsurface exchange. The corresponding net NO3− uptake length is 37 ± 13 km (42 ± 12 km when normalized to the conservative solute Cl−), and the areal NO3− uptake rate is 0.5 μmol m−2 s−1. The observed reduction in [NO3−] along the reach results from one or more internal sinks, not dilution by ground water, hill-slope water, or other water inputs. Observed reductions in [NO3−] and channel discharge along the experimental reach result in a net loss of 200–400 kg/d of NO3−-N, ~50% of the input load. High-resolution (temporal and spatial) sampling indicates that most of the NO3− loss occurs along the lower part of the reach, where there is the greatest seepage loss and surface–subsurface exchange of water. Stable isotopes of NO3−, total dissolved P concentrations, and streambed chemical profiles suggest that denitrification is the most significant NO3− sink along the reach. Denitrification efficiency, as expressed through downstream enrichment in 15N-NO3−, varies considerably during the water year. When discharge is greater (typically earlier in the water year), denitrification is least efficient and downstream enrichment in 15N-NO3− is greatest. When discharge is lower, denitrification in the streambed appears to occur with greater efficiency, resulting in lower downstream enrichment in 15N-NO3−.

California↗

In situ benthic nutrient flux and sediment oxygen demand in Barnegat Bay, New Jersey

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, measured sediment oxygen demand (SOD) and benthic nutrient fluxes throughout Barnegat Bay, New Jersey. SOD was determined in situ using chambers equipped with optical dissolved oxygen sensors. The benthic nutrient fluxes of ammonia (NH3), nitrite + nitrate (plus ions; here, referred to as NO32), soluble reactive phosphorous (SRP), and dissolved silica (SiO2) were measured with in situ equilibrium dialysis samplers. Measurements were made at nine stations around the periphery and at three mid-Bay locations from August 2012 to October 2013. The SOD ranged from −1.5 to −8.4 g of oxygen (O2) m−2 d−1. The SOD rates varied as a function of water temperature and followed the van't Hoff rate equation for change in reaction rate with temperature, with a temperature coefficient (Θ) that varied among sites and averaged 1.083. The highest SOD rates in the bay were measured near the mouth of the Toms River embayment. Concentrations in the upper 1 m of sediment pore water were found up to 23 mg N L−1 for NH4+ and 6.7 mg P L−1 for SRP. Maximum measured fluxes into the overlying water were 3.0 × 10−2 g NH3–N m−2 d−1, 7.0 × 10−4 g NO32–N m−2 d−1, 1.9 × 10−3 g P m−2 d−1, and 3.6 × 10−3g SiO2 m−2 d−1. Using the measured benthic N and P fluxes, daily nutrient inputs derived from sediment recycling are shown to be comparable in scale to freshwater tributary inputs to the bay.

New Jersey↗