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Sulfur-to-iron ratio as a proxy for degree of organic sulfurization

The degree of organic sulfurization is broadly relevant yet underreported. We present a statistically significant correlation between whole rock S/Fe and the measured degree of organic sulfurization in the thermally immature Cenomanian–Turonian Eagle Ford Group. This relationship shows a sink switch for sulfur from pyrite to organic matter. Excess iron and excess sulfur relative to pyrite, which are mathematically related to S/Fe, provide better insights into organic sulfurization than previous approaches that calculate excess iron relative to detrital iron based on aluminum concentrations. Organic sulfurization and S/Fe are tightly coupled in the Eagle Ford partially due to limited sulfur- and iron-bearing components. Similar relationships could exist in other thermally immature, organic-rich, anoxia-prone, calcareous mudstones. The degree of organic sulfurization was estimated from S/Fe, which was used to map stratigraphic and regional variations of organic sulfurization across the Eagle Ford and to investigate how organic sulfurization relates to organic enrichment, organic preservation, and depositional redox chemistry. The extent of organic sulfurization is more tightly linked to organic preservation than enrichment. Together, organic sulfurization and Mo provide concordant evidence for depositional euxinia. The relationship between Mo and degree of organic sulfurization could indicate that sulfurized organic matter provides a pathway for Mo enrichment, but future work needs to disentangle direct mechanisms from indirect covariations between Mo, organic content, and degree of organic sulfurization. Whole rock elemental chemistry and programmed pyrolysis provide insights into organic sulfurization variations that can be upscaled and can guide subsequent detailed organic sulfur analyses.

Arkansas, Louisiana, Oklahoma, Texas↗

Advancing subsurface investigations beyond the borehole with passive seismic horizontal-to-vertical spectral ratio and electromagnetic geophysical methods at transportation infrastructure sites in New Hampshire

The U.S. Geological Survey (USGS), in cooperation with the New Hampshire Department of Transportation (NHDOT), surveyed transportation infrastructure sites using rapidly deployable geophysical methods to assess benefits added to a comprehensive site characterization with traditional geotechnical techniques. Horizontal-to-vertical spectral-ratio (HVSR) passive-seismic and electromagnetic-induction (EMI) methods were applied at 4 sites including a roadway-stream crossing, roadway-bridge rail-trail crossing, commuter-parking expansion, and a railroad-adjacent river-cutbank slope-failure site. Additionally, ground-penetrating-radar (GPR) was used at the slope-failure site. Typically, subsurface geotechnical properties are determined from boring data; however, borings are often spaced hundreds of feet apart, potentially missing important spatial variability between boreholes. Geotechnical site characterization including geophysical surveys helped provide a more accurate characterization by using continuous or near continuous profiling. Three-component ambient noise measured with HVSR methods were used to determine resonance frequency and estimate sediment thickness. The method works when there is a strong shear-wave acoustic impedance contrast (> 2:1) between sediment and bedrock. Sediment thickness estimates from HVSR measurements were combined with boring data to make detailed maps of the bedrock surface altitude. The bulk electrical conductivity of the subsurface was indirectly measured with EMI methods and was used to identify lithologic variations, shallow bedrock, and conductive groundwater. Ground penetrating radar, which transmits pulses of electromagnetic energy into the subsurface and records the amplitude and timing of reflected signals, was used to identify bedding and changes in lithology or water content. By combining geophysical and boring data analyses, transportation projects produced more spatially comprehensive representations of geotechnical subsurface conditions than would be determined using conventional borings alone.

New Hampshire↗

A three-dimensional geologic framework model of the northern Great Plains region of Montana, North Dakota, South Dakota, and Wyoming, USA

This report presents a new three-dimensional geologic framework model (GFM) of the northern Great Plains region, encompassing parts of Montana, North Dakota, South Dakota, and Wyoming. The model provides a regionally consistent, geographic information system (GIS)-ready representation of Phanerozoic sedimentary strata, major fault systems, and Precambrian basement geometry across two sedimentary basins and adjacent uplifts. More than 300,000 geologic and geophysical data inputs were synthesized to model 41 stratigraphic horizons and 47 faults, yielding an internally coherent, sealed-volume interpretation of the subsurface. The modeling workflow developed for this study demonstrates an efficient and scalable approach for constructing basin-to regional-scale GFMs in geologically complex and data-variable settings. Although model fidelity varies with data density and quality, the resulting geometry is broadly consistent with 1:500,000-scale geologic mapping and highlights areas where additional geologic study is most needed. The three-dimensional GFM provides a foundational framework to support groundwater, energy, and mineral resource assessments, and offers a transferable methodology for potential future U.S. Geological Survey efforts to build large-area subsurface models in underexplored regions of the United States.

Montana, North Dakota, South Dakota, Wyoming↗

Detection and mapping of fractures and cavities using borehole radar

Borehole radar can be used in a single-hole reflection mode or in a cross-hole tomography mode. In the reflection mode, radar provides an image of discontinuities in the bedrock surrounding a borehole, including bedding planes, lithologic contacts, fractures, and cavities. The measurements are either directional or omni-directional, depending upon the type of equipment and antennas. In the tomography mode, where the transmitter and receiver are in separate boreholes, radar provides an image of the planar section between the boreholes. The radius of investigation depends on the antenna frequency and the electrical conductivity of the bedrock. For a central frequency of 100 megahertz, in the reflection mode the ranges are typically 10 to 40 meters in resistive solid rock and less than 5 meters in conductive, clay-rich, or silty rock. Single-hole and cross-hole radar also have been used for water-supply investigations in the northeast-ern United States. Borehole radar was used to investigate crystalline bedrock in two rapidly developing com-munities that rely on water resources in the bedrock. The surveys were conducted and interpreted along with data from other borehole geophysical tools. The borehole radar surveys were used to identify the location and orientation of reflectors, locate the primary pathways of flow to the supply wells, and identify aquifer character-istics that may be useful in siting a production well and protecting high-yielding wells in crystalline rocks. Borehole radar has been used to investigate fractures, cavities, and lithologic changes at several sites in Europe. The radar data has been interpreted in conjuction with the results of modeling of borehole-radar re-sponse. At the Grimsel nuclear waste laboratory in Switzerland, single-hole reflection and tomography methods were used to characterize the rock in inclined boreholes. At numerous geotechnical sites in Belgium, France, and the Netherlands, borehole radar has been used to characterize the rock and identify fractures and cavities.

Conference Paper↗

Satellite-derived, melt-season surface temperature of the Greenland Ice Sheet (2000-2005) and its relationship to mass balance

Mean, clear-sky surface temperature of the Greenland Ice Sheet was measured for each melt season from 2000 to 2005 using Moderate-Resolution Imaging Spectroradiometer (MODIS)–derived land-surface temperature (LST) data-product maps. During the period of most-active melt, the mean, clear-sky surface temperature of the ice sheet was highest in 2002 (−8.29 ± 5.29°C) and 2005 (−8.29 ± 5.43°C), compared to a 6-year mean of −9.04 ± 5.59°C, in agreement with recent work by other investigators showing unusually extensive melt in 2002 and 2005. Surface-temperature variability shows a correspondence with the dry-snow facies of the ice sheet; a reduction in area of the dry-snow facies would indicate a more-negative mass balance. Surface-temperature variability generally increased during the study period and is most pronounced in the 2005 melt season; this is consistent with surface instability caused by air-temperature fluctuations.

Geophysical Research Letters↗

Analysis of fractures intersecting Kahi Puka Well 1 and its relation to the growth of the island of Hawaii

As part of the Hawaii Scientific Drilling Project, Kahi Puka Well 1 penetrated about 275 m of Mauna Loa basalts overlying a sequence of Mauna Kea flow units as it was drilled and cored to a total depth of 1053 m below land surface. A borehole televiewer (BHTV) was run in most of the well in successive stages prior to casing in order to obtain magnetically oriented acoustic images of the borehole wall. A total of 283 individual fractures were identified from this log and characterized in terms of strike and dip. These data are divided into three vertical sections based upon age and volcanic source, and lower hemisphere stereographic plots identify two predominant, subparallel fracture subsets common to each section. Assuming that most of the steeply dipping fractures observed in the BHTV log are tensile features generated within basalt flows during deposition and cooling, this fracture information can be combined with models of the evolution of the island of Hawaii to investigate the depositional history of these Mauna Loa and Mauna Kea basalts over the past 400 kyr. The directions of high-angle fractures appear to be generally parallel to topography or to the coastline at the time of deposition, as is supported by surface mapping of modern flows. Consequently, an overall counterclockwise rotation of about 75?? in the strike of these fractures from the bottom to the top of the well represents a systematic change in depositional slope direction over time. We attribute the observed rotation in the orientations of the two predominant fracture subsets over the past 400 kyr to changes in the configurations of volcanic sources during shield building and to the structural interference of adjacent volcanoes that produces shifts in topographic patterns.

Journal of Geophysical Research B: Solid Earth↗

Archive of digitized analog boomer and minisparker seismic reflection data collected from the Alabama-Mississippi-Louisiana Shelf during cruises onboard the R/V Carancahua and R/V Gyre, April and July, 1981

In April and July of 1981, the U.S. Geological Survey (USGS) conducted geophysical surveys to investigate the shallow geologic framework of the Alabama-Mississippi-Louisiana Shelf in the northern Gulf of Mexico. Work was conducted onboard the Texas A&M University R/V Carancahua and the R/V Gyre to develop a geologic understanding of the study area and to locate potential hazards related to offshore oil and gas production. While the R/V Carancahua only collected boomer data, the R/V Gyre used a 400-Joule minisparker, 3.5-kilohertz (kHz) subbottom profiler, 12-kHz precision depth recorder, and two air guns. The authors selected the minisparker data set because, unlike with the boomer data, it provided the most complete record. This report is part of a series to digitally archive the legacy analog data collected from the Mississippi-Alabama SHelf (MASH). The MASH data rescue project is a cooperative effort by the USGS and the Minerals Management Service (MMS). This report serves as an archive of high-resolution scanned Tagged Image File Format (TIFF) and Graphics Interchange Format (GIF) images of the original boomer and minisparker paper records, navigation files, trackline maps, Geographic Information System (GIS) files, cruise logs, and formal Federal Geographic Data Committee (FGDC) metadata.

Alabama, Louisiana, Mississippi↗

Map showing sediment isopachs in the deep-sea basins of the Pacific continental margin, Cape Mendocino to Point Conception

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing depth to basement in the deep-sea basins of the Pacific continental margin, Cape Mendocino to Point Conception

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing sediment isopachs in the deep-sea basins of the Pacific Continental Margin, Strait of Juan de Fuca to Cape Mendocino

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing depth to basement in the deep-sea basins of the Pacific continental margin, Strait of Juan de Fuca to Cape Mendocino

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Investigation of the potential for concealed base-metal mineralization at the Drenchwater Creek Zn-Pb-Ag occurrence, northern Alaska, using geology, reconnaissance geochemistry, and airborne electromagnetic geophysics

In 2005, the U.S. Geological Survey, Bureau of Land Management, and State of Alaska cooperated on an investigation of the mineral potential of a southern part of the National Petroleum Reserve in Alaska, Howard Pass quadrangle, to provide background information for future land-use decisions. The investigation incorporated an airborne electromagnetic (EM) survey covering 1,500 mi 2 (~3,900 km 2 ), including flight lines directly over the Drenchwater Creek sediment-hosted Zn-Pb-Ag occurrence, the largest known base-metal occurrence in the survey area. Samples from the mineralized outcrop and rubblecrop contain metal concentrations that can exceed 11 percent Zn+Pb, with appreciable amounts of Ag. Soil samples with anomalous Pb concentrations are distributed near the sulfide-bearing outcrops and along a >2.5 km zone comprising mudstone, shale, and volcanic rocks of the Kuna Formation. No drilling has taken place at the Drenchwater occurrence, so alternative data sources (for example, geophysics) are especially important in assessing possible indicators of mineralization. Data from the 2005 electromagnetic survey define the geophysical character of the rocks at Drenchwater and, in combination with geological and surface-geochemical data, can aid in assessing the possible shallow (up to about 50 m), subsurface lateral extent of base-metal sulfide accumulations at Drenchwater. A distinct >3-km-long electromagnetic conductive zone (observed in apparent resistivity maps) coincides with, and extends further westward than, mineralized shale outcrops and soils anomalously high in Pb concentrations within the Kuna Formation; this conductive zone may indicate sulfide-rich rock. Models of electrical resistivity with depth, generated from inversion of electromagnetic data, which provide alongflight-line conductivity-depth profiles to between 25 and 50 m below ground surface, show that the shallow subsurface conductive zone occurs in areas of known mineralized outcrops and thins to the east. Broader, more conductive rock along the western ~1 km of the geophysical anomaly does not reach ground surface. These data suggest that the Drenchwater deposit is more extensive than previously thought. The application of inversion modeling also was applied to another smaller geochemical anomaly in the Twistem Creek area. The results are inconclusive, but they suggest that there may be a local conductive zone, possibly due to sulfides.

Professional Paper↗

Metallogeny of the Great Basin: Crustal evolution, fluid flow, and ore deposits

The Great Basin physiographic province in the Western United States contains a diverse assortment of world-class ore deposits. It currently (2006) is the world’s second leading producer of gold, contains large silver and base metal (Cu, Zn, Pb, Mo, W) deposits, a variety of other important metallic (Fe, Ni, Be, REE’s, Hg, PGE) and industrial mineral (diatomite, barite, perlite, kaolinite, gallium) resources, as well as petroleum and geothermal energy resources. Ore deposits are most numerous and largest in size in linear mineral belts with complex geology. U.S. Geological Survey (USGS) scientists are in the final year of a research project initiated in the fall of 2001 to increase understanding of relations between crustal evolution, fluid flow, and ore deposits in the Great Basin. Because of its substantial past and current mineral production, this region has been the focus of numerous investigations over the past century and is the site of ongoing research by industry, academia, and state agencies. A variety of geoinformatic tools was used to organize, reinterpret, and display, in space and time, the large amounts of geologic, geophysical, geochemical, and hydrologic information deemed pertinent to this problem. This information, in combination with concentrated research on (1) critical aspects of the geologic history, (2) an area in northern Nevada that encompasses the major mineral belts, and (3) important mining districts and deposits, is producing new insights about the interplay between key tectonic events, hydrothermal fluid flow, and ore genesis in mineral belts. The results suggest that the Archean to Holocene history of the Great Basin was punctuated by several tectonic events that caused fluids of different origins (sea water, basinal brine, meteoric water, metamorphic water, magmatic water) to move through the crust. Basement faults reactivated during these events localized deformation, sedimentation, magmatism, and hydrothermal fluid flow in overlying rocks to form mineral belts that contain ore deposits of different types and ages that are locally superimposed (demonstrating inheritance). Fluid flow in these systems also was influenced by the distribution of permeable lithologies and paleotopographic highs and lows. Hydrothermal fluids evolved from their initial chemistries towards compositions that reflect the ƒ O 2 and ƒ S 2 buffering capacity of, and the ligands and metals present in, the rocks (±older mineralization) through which they moved. In northern Nevada, where gold deposits are relatively common, carbonaceous, pyritic strata buffered fluids of diverse origins to H 2 S-rich compositions so they could transport gold repeatedly over Paleozoic-Cenozoic time (convergent evolution). Ore formed where metal-laden fluids encountered effective physicochemical traps. Maps of Neogene basin fill and erosion surfaces identify areas where preexisting ore deposits have been progressively exposed or concealed. Comparisons with analogous terrains and deposit types in other parts of the world provide global context. The initial findings and some of the databases, geologic maps, sections, reconstructions, hydrogeologic models, topical syntheses, regional overviews, short courses, field guides, and deposit comparisons produced by project staff and associated managers, contractors, and collaborators have been presented in numerous abstracts, symposia, USGS publications, and professional journals over the last 5 years (see the extensive bibliography). Notable among these was the 2005 Geological Society of Nevada symposium in Reno, Nevada, and the 2005 Geological Society of America annual meeting in Salt Lake City, Utah, where project results were presented to audiences from around the nation and world. The final results of the project will be submitted for publication in 2007 to appropriate USGS and professional journals. A special issue of GEOSPHERE, scheduled for publication in 2007, will be devoted to the results of this project and related work. This special issue will reach an international audience and be available worldwide on the internet. Much of the research for this project has concentrated on areas that will receive the focused attention of the mining industry in the future. As such, the data and interpretations generated by this project have direct use for land-use managers in Federal, State, and local agencies. Improved hydrogeologic models developed by this project will considerably enhance ongoing and future water resource investigations in the region. The increased understanding of when, where, and how hydrothermal systems produce significant economic deposits has direct uses for mineral exploration and for future USGS mineral resource assessments in the Great Basin and other parts of the world.

Great Basin↗

Stratigraphic cross sections of the Niobrara Interval of the Upper Cretaceous Cody Shale in the Bighorn Basin, Wyoming and Montana

The Bighorn Basin is one of many structural and sedimentary basins that formed in the Rocky Mountain foreland during the Laramide orogeny. The basin is nearly 180 miles long, 100 miles wide, and encompasses about 10,400 square miles in northern Wyoming and southern Montana. The basin is bounded by major basement uplifts that include the Pryor uplift on the northeast, the Beartooth uplift on the northwest, the Bighorn uplift on the east, and the Owl Creek uplift on the south. The northern margin includes a zone of faulting and folding referred to as the Nye-Bowler lineament. The western margin is formed by volcanic rocks of the Absaroka Range. Many important conventional oil and gas fields producing from reservoirs ranging in age from Cambrian through Tertiary have been discovered in this basin. In addition, an extensive unconventional overpressured basin-centered gas accumulation may be present in Cretaceous strata in the deeper parts of the basin. It has long been suggested that various Upper Cretaceous marine shales, including the Cody Shale, are the principal hydrocarbon source rocks for many of these accumulations. With recent advances and success in horizontal drilling and multistage fracture stimulation, there has been an increase in exploration and completion of wells in these marine shales in other Rocky Mountain Laramide basins that were traditionally thought of only as hydrocarbon source rocks. The stratigraphic cross sections presented in this report were constructed as part of a project carried out by the U.S. Geological Survey to characterize and evaluate the undiscovered continuous (unconventional) oil and gas resources of the Niobrara interval in the lower part of the Upper Cretaceous Cody Shale in the Bighorn Basin. These cross sections were constructed using borehole geophysical logs from wells drilled for oil and gas exploration and production. The stratigraphic interval extends from the upper part of the Frontier Formation to the middle part of the Cody Shale. The datum is the base of the “chalk kick” marker bed, a distinctive resistivity peak or zone in the lower part of the Cody Shale. A gamma ray and (or) spontaneous potential log was used in combination with a resistivity log to identify and correlate units. Marine molluscan index fossils collected from nearby outcrop sections were projected into the subsurface to help determine the relative ages of the strata and aid in correlation.

Montana, Wyoming↗

Case study for delineating a contributing area to a water-supply well in a fractured crystalline-bedrock aquifer, Stewartstown, Pennsylvania

The Trouts Lane well field in Stewartstown, Pa., was selected as a case study for delineating a contributing area in a fractured crystalline-bedrock aquifer. The study emphasized the importance of refining the understanding of boundary conditions and major heterogeneities that affect ground-water movement to the supply well by conducting (1) fracture-trace mapping, (2) borehole logging and flow measurements, (3) ground-water level monitoring, (4) aquifer testing, and (5) geochemical sampling. Methods and approach used in this study could be applicable for other wells in crystalline-bedrock terranes in southeastern Pennsylvania. Methods of primary importance for refining the understanding of hydrology at the Trouts Lane well field were the aquifer tests, water-level measurements, and geophysical logging. Results from the constant-discharge aquifer test helped identify a major north-south trending hydraulic connection between supply well SW6 and a domestic-supply well. Aquifer-test results also indicated fractures that transmit most water to the supply well are hydraulically well-connected to the shallow regolith and highly weathered schist. Results from slug tests provided estimates of transmissivity and the nonuniform distribution of transmissivity throughout the well field, indicating the water-producing fractures are not evenly distributed and ground-water velocities must vary considerably throughout the well field. Water levels, which were easy to measure, provided additional evidence of hydraulic connections among wells. More importantly, they allowed the water-table configuration to be mapped. Borehole geophysics and flow measurements within the well were very useful because results indicated water entered supply well SW6 through bedrock fractures at very shallow depths—less than 60 ft below land surface; therefore, the area providing recharge to the well is probably in the immediate vicinity. Preliminary delineations of the contributing area and the 90-day time-of-travel area were computed from a steady-state water budget and a time-of-travel equation. This easy approach provides insight into the size (but not the shape) of contributing areas. Three other approaches were used to refine the contributing-area shape: (1) uniform-flow equation, (2) water-table mapping, and (3) numerical modeling. The contributing areas computed from each approach differed depending on the simplification of the hydrogeologic framework that was made in each method of analysis. Although the approaches vary in complexity, regardless of the approach used, an estimate of the water-table configuration in the vicinity of the well field was key for making the best possible delineation of the contributing area. A major limitation of this investigation was the inability to refine the delineation of the time-of-travel area. A time-of-travel area is based on the distance water travels in a given time. Because a few discrete fractures probably supply a significant amount of water to supply well SW6, the effective porosity (and hence, traveltime) of ground water is best estimated using tracers.

Water-Resources Investigations Report↗

Young (<7 Ma) gold deposits and active geothermal systems of the Great Basin: Enigmas, questions, and exploration potential

Young gold systems in the Great Basin (£ 7 Ma), though not as well studied as their older counterparts, comprise a rapidly growing and in some ways controversial group. The gold inventory for these systems has more than doubled in the last 5 years from roughly 370 tonnes (12 Moz) to 890 tonnes (29 Moz). Although these deposits are characterized by low grades, tonnages can be high and stripping ratios low, and they have been mined profitably, as exemplified by Florida Canyon and Hycroft. Active geothermal systems in the Great Basin also comprise a rapidly growing group, as evidenced by a number of recent discoveries of geothermal groundwater and a more than 50% increase in electricity production capacity from these systems in the last 5 years. Many young gold deposits are closely associated with active geothermal systems, suggesting that gold deposits may be forming today in the Great Basin. Measured or estimated geothermal reservoir temperatures commonly approach or exceed 200∞C, and other characteristics and processes (advanced argillic caps, hydrothermal eruption breccias) of these young deposits resemble those of nearby Tertiary precious metal deposits. Nonetheless, many young gold systems, especially in Nevada, are not associated with coeval igneous rocks. Similarly, almost all electricity-grade geothermal systems in Nevada are not associated with Quaternary silicic volcanic rocks, and have lower temperature gradients, lower 3He/4He ratios, and lower dissolved trace element concentrations than most magmatic-heated geothermal systems elsewhere in the world. The increasing economic significance of young gold deposits and active geothermal systems justifies more research to better understand their origins, particularly because in some aspects they remain enigmatic and controversial. Are young gold deposits in Nevada truly amagmatic, or have they received metal and fluid contributions from magmas deeper within the crust? Has gold in these deposits been remobilized from older gold mineralization? Current research is investigating these and other questions to improve our genetic understanding of these young gold systems, which in turn can lead to improved exploration targeting. The recent rapid growth in resources for both young gold deposits and geothermal systems underscores their underdeveloped exploration potential. Even though many young gold deposits exhibit relatively shallow hot-springs-style mineralization, their young age may preclude exposure by erosion. Uplift along active normal faults has exposed some deposits (e.g., Florida Canyon, Dixie Comstock, Wind Mountain), but in other areas, such as the Walker Lane, where strike-slip faulting is prevalent, the opportunities for exposure can be limited. Many active geothermal systems are also concealed below the surface in that hot springs or steam vents may be absent above areas of thermal groundwater. With sources of energy to support mine production becoming more problematic, the potential advantages of simultaneously exploring for young gold deposits and spatially associated geothermal systems are becoming more apparent. Exploration methods recently proven effective in geothermal exploration that can be adapted to gold exploration include temperature surveys, hyperspectral remote sensing, geophysical surveys, water analyses, and detailed mapping of geothermal-related features and related fault systems.

Conference Paper↗

Modeled coastal-ocean pathways of land-sourced contaminants in the aftermath of Hurricane Florence

Extreme precipitation during Hurricane Florence, which made landfall in North Carolina in September 2018, led to breaches of hog waste lagoons, coal ash pits, and wastewater facilities. In the weeks following the storm, freshwater discharge carried pollutants, sediment, organic matter, and debris to the coastal ocean, contributing to beach closures, algae blooms, hypoxia, and other ecosystem impacts. Here, the ocean pathways of land-sourced contaminants following Hurricane Florence are investigated using the Regional Ocean Modeling System (ROMS) with a river point source with fixed water properties from a hydrologic model (WRF-Hydro) of the Cape Fear River Basin, North Carolina's largest watershed. Patterns of contaminant transport in the coastal ocean are quantified with a finite duration tracer release based on observed flooding of agricultural and industrial facilities. A suite of synthetic events also was simulated to investigate the sensitivity of the river plume transport pathways to river discharge and wind direction. The simulated Hurricane Florence discharge event led to westward (downcoast) transport of contaminants in a coastal current, along with intermittent storage and release of material in an offshore (bulge) or eastward (upcoast) region near the river mouth, modulated by alternating upwelling and downwelling winds. The river plume patterns led to a delayed onset and long duration of contaminants affecting beaches 100 km to the west, days to weeks after the storm. Maps of the onset and duration of hypothetical water quality hazards for a range of weather conditions may provide guidance to managers on the timing of swimming/shellfishing advisories and water quality sampling.

Journal of Geophysical Research: Oceans↗

Three-dimensional geologic framework model of the Rio San Jose groundwater basin and adjacent areas, New Mexico

As part of a U.S. Geological Survey study in cooperation with the Bureau of Reclamation and the Pueblo of Acoma, New Mexico, and the Pueblo of Laguna, New Mexico, a digital three-dimensional geologic framework model was constructed for the Rio San Jose and its surface-water drainage basin in west-central New Mexico. This three-dimensional model defines the altitude, thickness, and extent of 18 geologic units for use in a regional numerical hydrologic model. The model included an undifferentiated Proterozoic basement layer, 13 consolidated Paleozoic and Mesozoic rock units, and 4 Cenozoic units. Model input data were compiled from published cross sections, well data, structure contour maps, selected geophysical data, and data derived from geologic maps and structural features in the study area. These data were used to construct faulted surfaces that represent the upper and lower subsurface geologic unit boundaries. The digital three-dimensional geologic framework model combines faults, the altitude of the tops of each geologic unit, and boundary lines depicting the subsurface extent of each geologic unit. The digital three-dimensional geologic model described in this report and the corresponding data release represents the generalized geometry of the subsurface geologic units; it reproduces with reasonable accuracy the input geologic data and is consistent with previously published subsurface conceptualizations of the region. The geologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

New Mexico↗