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Clean coal initiatives in Indiana

Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

International Journal of Energy Sector Management↗

Modeling subsurface performance of a geothermal reservoir using machine learning

Geothermal power plants typically show decreasing heat and power production rates over time. Mitigation strategies include optimizing the management of existing wells—increasing or decreasing the fluid flow rates across the wells—and drilling new wells at appropriate locations. The latter is expensive, time-consuming, and subject to many engineering constraints, but the former is a viable mechanism for periodic adjustment of the available fluid allocations. In this study, we describe a new approach combining reservoir modeling and machine learning to produce models that enable such a strategy. Our computational approach allows us, first, to translate sets of potential flow rates for the active wells into reservoir-wide estimates of produced energy, and second, to find optimal flow allocations among the studied sets. In our computational experiments, we utilize collections of simulations for a specific reservoir (which capture subsurface characterization and realize history matching) along with machine learning models that predict temperature and pressure timeseries for production wells. We evaluate this approach using an “open-source” reservoir we have constructed that captures many of the characteristics of Brady Hot Springs, a commercially operational geothermal field in Nevada, USA. Selected results from a reservoir model of Brady Hot Springs itself are presented to show successful application to an existing system. In both cases, energy predictions prove to be highly accurate: all observed prediction errors do not exceed 3.68% for temperatures and 4.75% for pressures. In a cumulative energy estimation, we observe prediction errors that are less than 4.04%. A typical reservoir simulation for Brady Hot Springs completes in approximately 4 h, whereas our machine learning models yield accurate 20-year predictions for temperatures, pressures, and produced energy in 0.9 s. This paper aims to demonstrate how the models and techniques from our study can be applied to achieve rapid exploration of controlled parameters and optimization of other geothermal reservoirs.

Energies↗

Influence of vertical and lateral heat transfer on permafrost thaw, peatland landscape transition, and groundwater flow

Recent climate change has reduced the spatial extent and thickness of permafrost in many discontinuous permafrost regions. Rapid permafrost thaw is producing distinct landscape changes in the Taiga Plains of the Northwest Territories, Canada. As permafrost bodies underlying forested peat plateaus shrink, the landscape slowly transitions into unforested wetlands. The expansion of wetlands has enhanced the hydrologic connectivity of many watersheds via new surface and near-surface flow paths, and increased streamflow has been observed. Furthermore, the decrease in forested peat plateaus results in a net loss of boreal forest and associated ecosystems. This study investigates fundamental processes that contribute to permafrost thaw by comparing observed and simulated thaw development and landscape transition of a peat plateau-wetland complex in the Northwest Territories, Canada from 1970 to 2012. Measured climate data are first used to drive surface energy balance simulations for the wetland and peat plateau. Near-surface soil temperatures simulated in the surface energy balance model are then applied as the upper boundary condition to a three-dimensional model of subsurface water flow and coupled energy transport with freeze-thaw. Simulation results demonstrate that lateral heat transfer, which is not considered in many permafrost models, can influence permafrost thaw rates. Furthermore, the simulations indicate that landscape evolution arising from permafrost thaw acts as a positive feedback mechanism that increases the energy absorbed at the land surface and produces additional permafrost thaw. The modeling results also demonstrate that flow rates in local groundwater flow systems may be enhanced by the degradation of isolated permafrost bodies.

Northwest Territories↗

Does tidal marsh restoration lead to the recovery of trophic pathways that support estuarine fishes?

Evaluation of tidal marsh restoration success is typically based on the recovery of habitat size and target species. However, food-web structure may provide valuable insight into ecosystem functioning trajectories. Here, we studied restored tidal marshes of different ages ( new , young , old ; spanning 1–150 years) in comparison with nearby reference sites along the San Francisco Estuary. We asked: (1) How does restoration help recover energy pathways that support fishes? (2) Do fishes rely more on algal versus detrital pathways in restored sites?; and (3) How does food-web structure vary as a function of species origin and life history? To answer these questions, we sampled fish ( n = 806) and basal resources (emergent vegetation and phytoplankton; n = 109) seasonally over two hydrologically contrasting years. Using stable isotopes (δ 13 C, δ 15 N, and δ 34 S), we calculated fish isotopic niche volumes, food chain lengths, and the relative importance of algal versus detrital energy pathways. We found that food chains in restored sites were 8% shorter than in their paired reference sites. Additionally, the young and old restored sites had 37% smaller niche volumes than their references, but the opposite was true for the new restored site (11% larger), illustrating the characteristic trophic surge of early succession. Fishes found in restored sites relied significantly less on detrital energy (7% less) than fishes found in reference sites, and resident fishes showed 12% higher reliance on the detrital pathway than transient species. Finally, most of the native niche volume overlapped with that of introduced fish, which was in turn 38% larger, and a similar pattern was observed when comparing resident to transient fish. Our findings demonstrate that food-web structure does not immediately recover with tidal marsh restoration, even if fish assemblages are species-rich; and show that transient trophic surges may complicate restoration success assessments of newly restored marshes. We contend that incorporating recovery of energy pathways as an indicator of performance may help strengthen monitoring and design of wetland ecosystem restoration projects.

California↗

Geographic variation and thermal plasticity shape salamander metabolic rates under current and future climates

Predicted changes in global temperature are expected to increase extinction risk for ectotherms, primarily through increased metabolic rates. Higher metabolic rates generate increased maintenance energy costs which are a major component of energy budgets. Organisms often employ plastic or evolutionary (e.g., local adaptation) mechanisms to optimize metabolic rate with respect to their environment. We examined relationships between temperature and standard metabolic rate across four populations of a widespread amphibian species to determine if populations vary in metabolic response and if their metabolic rates are plastic to seasonal thermal cues. Populations from warmer climates lowered metabolic rates when acclimating to summer temperatures as compared to spring temperatures. This may act as an energy saving mechanism during the warmest time of the year. No such plasticity was evident in populations from cooler climates. Both juvenile and adult salamanders exhibited metabolic plasticity. Although some populations responded to historic climate thermal cues, no populations showed plastic metabolic rate responses to future climate temperatures, indicating there are constraints on plastic responses. We postulate that impacts of warming will likely impact the energy budgets of salamanders, potentially affecting key demographic rates, such as individual growth and investment in reproduction.

Ecology and Evolution↗

The nitrogen window for arctic herbivores: plant phenology and protein gain of migratory caribou (Rangifer tarandus)

Terrestrial plants are often limited by nitrogen (N) in arctic systems, but constraints of N supply on herbivores are typically considered secondary to those of energy. We tested the hypothesis that forage N is more limiting than energy for arctic caribou by collecting key forages (three species of graminoids, three species of woody browse, and one genus of forb) over three summers in the migratory range of the Central Arctic Herd in Alaska from the Brooks Range to the Coastal Plain on the Arctic Ocean. We combined in vitro digestion and detergent extraction to measure fiber, digestible energy, and usable fractions of N in forages ( n = 771). Digestible energy content fell below the minimum threshold value of 9 kJ/g for one single forage group: graminoids, and only beyond 64–75 d from parturition (6 June), whereas all forages fell below the minimum threshold value for digestible N (1% of dry matter) before female caribou would have weaned their calves at 100 d from parturition. The window for digestible N was shortest for browse, which fell below 1% at 30–41 d from parturition, whereas digestible N contents of graminoids were adequate until 46–57 d from parturition. The low quality of browse as a source of N was also apparent from concentrations of available N (i.e., the N not bound to fiber) that were <1% at 72–80 d from parturition. The Coastal Plain may be favored by female caribou because available and digestible concentrations of N are not only greater than those on the Brooks Range, the window of usable N on the Coastal Plain extends the period of protein gain for females and their calves by 17 d. Conversely, inland areas with greater biomass and densities of digestible N than the Coastal Plain may be more favorable for large male caribou that begin gaining protein from spring to breed in autumn. Our study provides evidence that phenological windows for protein gain in caribou are both spatially and temporally dynamic and likely to affect the distribution and growth of the population.

Ecosphere↗

Large-scale control site selection for population monitoring: an example assessing Sage-grouse trends

Human impacts on wildlife populations are widespread and prolific and understanding wildlife responses to human impacts is a fundamental component of wildlife management. The first step to understanding wildlife responses is the documentation of changes in wildlife population parameters, such as population size. Meaningful assessment of population changes in potentially impacted sites requires the establishment of monitoring at similar, nonimpacted, control sites. However, it is often difficult to identify appropriate control sites in wildlife populations. We demonstrated use of Geographic Information System (GIS) data across large spatial scales to select biologically relevant control sites for population monitoring. Greater sage-grouse (Centrocercus urophasianus; hearafter, sage-grouse) are negatively affected by energy development, and monitoring of sage-grouse population within energy development areas is necessary to detect population-level responses. Weused population data (1995&ndash;2012) from an energy development area in Wyoming, USA, the Atlantic Rim Project Area (ARPA), and GIS data to identify control sites that were not impacted by energy development for population monitoring. Control sites were surrounded by similar habitat and were within similar climate areas to the ARPA. We developed nonlinear trend models for both the ARPA and control sites and compared long-term trends from the 2 areas. We found little difference between the ARPA and control sites trends over time. This research demonstrated an approach for control site selection across large landscapes and can be used as a template for similar impact-monitoring studies. It is important to note that identification of changes in population parameters between control and treatment sites is only the first step in understanding the mechanisms that underlie those changes. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.

Wyoming↗

The biogeochemistry of anchialine caves: Progress and possibilities

Recent investigations of anchialine caves and sinkholes have identified complex food webs dependent on detrital and, in some cases, chemosynthetically produced organic matter. Chemosynthetic microbes in anchialine systems obtain energy from reduced compounds produced during organic matter degradation (e.g., sulfide, ammonium, and methane), similar to what occurs in deep ocean cold seeps and mud volcanoes, but distinct from dominant processes operating at hydrothermal vents and sulfurous mineral caves where the primary energy source is mantle derived. This review includes case studies from both anchialine and non-anchialine habitats, where evidence for in situ chemosynthetic production of organic matter and its subsequent transfer to higher trophic level metazoans is documented. The energy sources and pathways identified are synthesized to develop conceptual models for elemental cycles and energy cascades that occur within oligotrophic and eutrophic anchialine caves. Strategies and techniques for testing the hypothesis of chemosynthesis as an active process in anchialine caves are also suggested.

Hydrobiologia↗

The solubility of strontianite (SrCO 3 ) in CO 2 -H 2 O solutions between 2 and 91°C, the association constants of SrHCO + 3 (aq) and SrCO 0 3 (aq) between 5 and 80°C, and an evaluation of the thermodynamic properties of Sr 2+ (aq) and SrCO 3 (cr) at 25°C and 1 atm total pressure

Seventy new measurements (Sr T -P co2 of the solubility of strontianite were used to evaluate the equilibrium constant for the reaction SrCO 3 ( cr ) = Sr 2+ ( aq ) + CO 2&minus; 3 ( aq ) between 2 and 91 &deg;C. The temperature dependence of the equilibrium constant is given by the expression Log K = 155.0305 &minus; 7239.594/ T &minus; 56.58638 log T where T is in degrees Kelvin. The log K of strontianite, the Gibbs energy, enthalpy and entropy of the reaction at 25&deg;C are &minus;9.271 &plusmn; 0.020, 52.919 &plusmn; 0.08 kJ &middot; mol &minus;1 , &minus;1.67 &plusmn; 1.30 kJ &middot; mol &minus;1 , and &minus;183.1 &plusmn; 4.0 J &middot; mol &minus;1 &middot; K &minus;1 , respectively. The equilibrium constants are consistent with an aqueous model that includes the ion pairs SrHCO + 3 (aq) and SrCO 0 3 (aq) which were evaluated by potentiometric methods between 5 and 80&deg;C. The equilibrium constant for the association reaction Sr 2+ ( aq ) + HCO &minus; 3 ( aq ) = SrHCO + 3 aq ) is given by the expression Log K SrHCO + 3 = &minus;3.248 + 0.014867 T . The log of the association constant, the Gibbs energy, enthalpy and entropy of the reaction at 25&deg;C are 1.18, &minus;6.76 kJ &middot; mol &minus;1 , 25.30 kJ &middot; mol &minus;1 , and 107.5 J &middot; mol &minus;1 &middot; K &minus;1 , respectively. The equilibrium constant for the association reaction Sr 2+ ( aq ) + CO 2&minus; 3 ( aq ) = SrCO 0 3 aq ) is given by the expression Log K SrCO 0 3 = &minus;1.019 + 0.012826 T . The log of the association constant, the Gibbs energy, enthalpy, and entropy of the reaction at 25&deg;C are 2.81, &minus;16.01 kJ &middot; mol &minus;1 ,21.83 kJ &middot; mol &minus;1 , and 126.9 J &middot; mol &minus;1 &middot; K &minus;1 , respectively. These results lead to reliable calculation of the aqueous speciation and solubility of strontianite in the system SrCO 3 -CO 2 -H 2 O from 0 to more than 90&deg;C. Literature data on the solubility of strontianite have been evaluated and compared with these results. Our new data for strontianite have been used in an evaluation of the thermodynamic properties of Sr 2+ (aq), SrCO 3 (cr) and related compounds. The following values are recommended for the standard enthalpy (kJ &middot; mol &minus;1 ), Gibbs energy (kJ &middot; mol &minus;1 ), and entropy (J &middot; mol &minus;1 &middot; K &minus;1 ), respectively, of Sr 2+ aq): &minus;550.90 &plusmn; 0.50, &minus;563.83 &plusmn; 0.8 and &minus;31.50 &plusmn; 2.0, and for SrCO 3 (cr): &minus;1225.77 &plusmn; 1.1, &minus;1144.73 &plusmn; 1.0 and 97.2.

Geochimica et Cosmochimica Acta↗

Hydraulics and basin morphometry of the largest flash floods in the conterminous United States

The maximum rainfall-runoff floods measured by indirect methods in small basins (0.39-370 km 2 ) in the conterminous United States are examined. This analysis identified twelve floods that were the largest ever measured. These floods all occurred in semiarid to arid areas. For eleven of the twelve largest rainfall-runoff floods measured in small basins by the slope-area method, values of hydraulic depth; hydraulic radius; width-depth ratio; n value; mean velocity; velocity-head coefficient; Froude number; water-surface, energy, and channel slopes; shear stress; and unit stream power are tabulated. Estimated composite n values weighted by subsection conveyance range from 0.028 to 0.048 with a mean of 0.038. Mean velocities ranged from 3.47 to 9.97 m s −1 . Froude numbers ranged from 0.81 to 2.49, with 9 of 12 floods having values greater than 1.00. Water-surface, energy, and channel slopes vary considerably for each flood. Energy slope always was less than water-surface slope by values of 1–104%. Channel slope was greater than energy slope in eight floods. Shear stresses ranged between 61 and 855 N m −2 , and unit stream power from 212 to 8131 w m −1 . Floods in these small basins produced shear stresses and unit stream powers several hundred times greater than floods in large rivers. Floods on other small streams, with smaller unit discharges, produced greater shear stresses and stream powers. This indicates that the force of a flood is controlled by the depth-slope product, not absolute discharge. In the twelve watersheds studied, basin relief ranged from 165 to 1280 m, elongation ratios ranged from 0.55 to 0.80, the number of first-order streams (basin magnitude) ranged from 10 to 4297, drainage density ranged from 4.1 to 10.9 km km −2 , basin slope ranged from 0.0043 to 0.2486, relief ratio ranged from 0.0097 to 0.34, ruggedness number ranged from 0.69 to 7.17, and first-order channel frequency ranged from 5.1 to 38.6 km −2 . Elongation ratios were larger, and drainage density and first-order channel frequency lower, than other small flash-flood prone basins in the United States. These twelve basins have neither the most favorable morphometric characteristics which contribute to flash-flood peaks, nor did the storms causing these flash floods have the greatest short-duration intensities. Maximum flood peaks originate from an optimal combination of basin morphology and physiography, and storm intensity.

conterminous United States↗

Assessment of lupin flour as a diet ingredient for rainbow trout (Salmo gairdneri)

Studies were conducted to determine the value of lupin flour as a replacement for full-fat soybean meal (FFSM) in the diet of rainbow trout ( Salmo gairdneri ). Energy and digestibility values for lupin were determined using a metabolism chamber and it was found that trout utilize lupin well. The gross energy, metabolizable energy, and the percent digestibilities of protein and energy for lupin were found to be 4757 kcal/kg, 2797 kcal/kg, 85.2%, and 66.1%, respectively. When plant protein (either FFSM or lupin flour) was used as a supplemental dietary protein source to fish meal, or when the plant protein was the primary dietary protein source, fish fed diets where lupin completely replaced FFSM gained 99–106% of the weight of those fed the FFSM and had statistically equal feed efficiency ratios ranging from 80 to 83%. Although some minor dietary alterations may be needed (e.g., lowering the fat content of the diet) to maintain the economic advantage of lupin over soybean meal, lupin appears to be a useful source of protein for trout and may represent another economical plant protein alternative to fish meal.

Aquaculture↗

Geology of the Devonian black shales of the Appalachian Basin

Black shales of Devonian age in the Appalachian Basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies by Federal and State agencies and academic institutions produced a regional stratigraphic network that correlates the 15 ft black shale sequence in Tennessee with 3000 ft of interbedded black and gray shales in central New York. These studies correlate the classic Devonian black shale sequence in New York with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long-range correlations within the Appalachian Basin. Basinwide correlations, including the subsurface rocks, provided a basis for determining the areal distribution and thickness of the important black shale units. The organic carbon content of the dark shales generally increases from east to west across the basin and is sufficient to qualify as a hydrocarbon source rock. Significant structural features that involve the black shale and their hydrocarbon potential are the Rome trough, Kentucky River and Irvine-Paint Creek fault zone, and regional decollements and ramp zones.

Kentucky, Maryland, New York, Ohio, Pennsylvania, ↗

Methods for regional assessment of geothermal resources

A consistent, agreed-upon terminology is prerequisite for geothermal resource assessment. Accordingly, we propose a logical, sequential subdivision of the "geothermal resource base", accepting its definition as all the thermal energy in the earth's crust under a given area, measured from mean annual temperature. That part of the resource base which is shallow enough to be tapped by production drilling is termed the "accessible resource base", and it in turn is divided into "useful" and "residual" components. The useful component (i.e. the thermal energy that could reasonably be extracted at costs competitive with other forms of energy at some specified future time) is termed the "geothermal resource". This in turn is divided into "economic" and "subeconomic" components, based on conditions existing at the time of assessment. In the format of a McKelvey diagram, this logic defines the vertical axis (degree of economic feasibility). The horizontal axis (degree of geologic assurance) contains "identified" and "undiscovered" components. "Reserve" is then designated as the identified economic resource. All categories should be expressed in units of thermal energy, with resource and reserve figures calculated at wellhead, prior to the inevitable large losses inherent in any practical thermal use or in conversion to electricity. Methods for assessing geothermal resources can be grouped into 4 classes: (a) surface thermal flux, (b) volume, (c) planar fracture and (d) magmatic heat budget. The volume method appears to be most useful because (1) it is applicable to virtually any geologic environment, (2) the required parameters can in Sprinciple be measured or estimated, (3) the inevitable errors are in part compensated and (4) the major uncertainties (recoverability and resupply) are amenable to resolution in the foreseeable future. The major weakness in all the methods rests in the estimation of how much of the accessible resource base can be extracted at some time in the future. In a manner similar to mineral and fuel assessment, this recoverability is expressed as a "recovery factor". For an ideally permeable hot-water system, the recovery factor may be as much as 50% and seems to be independent of temperature. It must decrease as effective porosity (??e) decreases, but the relation between the two is little more than a guess. On the other hand, for favorable systems like Larderello that produce steam by a mechanism of intergranular vaporization, the recovery factor is probably around 15-20%, decreasing to zero at an effective porosity of zero. According to the anlysis of Bodvarsson (1974), it increases with decreasing reservoir temperature, and as pointed out by Nathenson (1975a) is limited at low temperatures by the need to have sufficient reservoir pressure for extraction and use. The extent to which a geothermal reservoir can be resupplied with heat during "industrial" times of 10-100 yr can be evaluated using simple analytical models. The results, combined with gravity and levelling data of Hunt (1977) for Wairakei and Isherwood (1977) for The Geysers, confirm earlier conclusions by Ramey (1970) and Nathenson (1975a) that resupply to reservoirs producing only steam can be neglected, and the conclusion of Nathenson (1975a) that it may be significant for hot-water systems of high natural discharge. Major subjects that demand continuing investigation include: 1. 1. Determination of recovery factors as functions of temperature and effective porosity, particularly for hot-water systems. 2. 2. Evaluation of fluid recharge and heat resupply by repetitive gravity, levelling and underground temperature surveys in producing geothermal fields. 3. 3. Analysis of the extent to which a recovery factor can be enhanced by stimulation and by use of confined circulation loops. ?? 1979.

Geothermics↗

Rivers and streams: Ecosystem dynamics and integrating paradigms

Full understanding of running waters requires an ecosystem perspective, which encompasses the physical and chemical setting in interaction with dependent biological communities. Several conceptual models or paradigms of river and stream ecosystems that capture critical components of lotic ecosystems have been developed, including the ‘river continuum concept’, to describe fluxes of matter and energy within the stream or river channel together with exchanges between the channel and its terrestrial setting. A complete ecosystem perspective includes consideration of hierarchical spatial scales in a temporal context. Flow of energy in lotic ecosystems is driven by two alternative energy sources: sunlight regulating in-stream photosynthesis and plant litter derived from the stream-side riparian corridor or floodplain. Energy transfers within the ecosystem pass through micro- and macroproducers (algae and vascular hydrophytes) and micro- and macroconsumers (microorganisms, invertebrates, and vertebrates). Material fluxes encompass the cycling of key nutrients, such as nitrogen and phosphorus, and the transport, storage, and metabolism of dissolved (DOM) and particulate (POM) organic matter (OM). Growth of lotic periphyton (algae and associated microbes, microzoans, and detritus) and coarse (CPOM) and fine (FPOM) particulate organic matter constitute the food resources of nonpredaceous running-water invertebrates (e.g., shredders that consume CPOM and collectors that feed on FPOM and associated microbes of both).

Book chapter↗

Development of a benchmark eddy flux evapotranspiration dataset for evaluation of satellite-driven evapotranspiration models over the CONUS

A large sample of ground-based evapotranspiration (ET) measurements made in the United States, primarily from eddy covariance systems, were post-processed to produce a benchmark ET dataset. The dataset was produced primarily to support the intercomparison and evaluation of the OpenET satellite-based remote sensing ET (RSET) models and could also be used to evaluate ET data from other models and approaches. OpenET is a web-based service that makes field-delineated and pixel-level ET estimates from well-established RSET models readily available to water managers, agricultural producers, and the public. The benchmark dataset is composed of flux and meteorological data from a variety of providers covering native vegetation and agricultural settings. Flux footprint predictions were developed for each station and included static flux footprints developed based on average wind direction and speed, as well as dynamic hourly footprints that were generated with a physically based model of upwind source area. The two footprint prediction methods were rigorously compared to evaluate their relative spatial coverage. Data from all sources were post-processed in a consistent and reproducible manner including data handling, gap-filling, temporal aggregation, and energy balance closure correction. The resulting dataset included 243,048 daily and 5,284 monthly ET values from 194 stations, with all data falling between 1995 and 2021. We assessed average daily energy imbalance using 172 flux sites with a total of 193,021 days of data, finding that overall turbulent fluxes were understated by about 12% on average relative to available energy. Multiple linear regression analyses indicated that daily average latent energy flux may be typically understated slightly more than sensible heat flux. This dataset was developed to provide a consistent reference to support evaluation of RSET data being developed for a wide range of applications related to water accounting and water resources management at field to watershed scales.

continental United States↗

Field observations and long short-term memory modeling of spectral wave evolution at living shorelines in Chesapeake Bay, USA

Living shorelines as a nature-based solution for climate change adaptation were constructed in many places around the world. The success of this type of projects requires long-term monitoring for adaptive management. The paper presents a novel framework leveraging scientific machine learning methods for accurate and rapid prediction of long-term hydrodynamic forcing impacting living shorelines using short-term measurements of water levels and wind waves in the largest estuary in the U.S. Different from existing data-driven wave prediction models focusing on significant wave heights, this study is focused on the prediction of wave energy spectra in shallow water using winds and tides as the input feature and short-term measurements of wave spectra and water depths as the label. Long Short-Term Memory (LSTM) models were developed using four-month wave measurements in the stormy seasons to predict integral wave parameters and energy spectra for multiple years. The developed models accurately predicted wave heights, peak periods, and energy spectra around the living shorelines, capturing complex wave dynamics, such as wave generation by wind, nonlinear wave-wave interactions, and depth-limited wave breaking in the shallow water of a large estuary. The validated models were then used to determine the long-term wave forcing impacting the living shorelines based on the modeled wave characteristics and spectra. Model results show that the surrogate models utilizing LSTM to predict wave spectra in the frequency domain enable long-term predictions of spectral wave evolution with a minimal computational cost. Our findings provide valuable insights into the efficacy of living shorelines in attenuating wave energy and demonstrate the utility of this approach in assessing the effectiveness of such living shoreline structures.

Applied Ocean Research↗

Component identification of solid biomass fuels using reflected light microscopy: Interlaboratory study 2

As nations transition toward sustainable energy systems , biomass has become a vital component of global energy portfolios. Derived from organic materials such as wood, agricultural residues, forestry byproducts, and organic waste, biomass is a renewable energy source with significant environmental and economic benefits. Responsible biomass energy production can improve waste management, reduce emissions of greenhouse gases, and mitigate environmental pollution. However, as the diversity of biomass-derived fuels increases, robust quality assessment methods are essential to ensure their efficiency, safety, and minimal environmental impact. Reflected light microscopy (RLM) is one such technique with the potential to complement conventional physico-chemical analyses by enabling a rapid identification of material constituents and impurities. To refine this methodology and evaluate the reproducibility of solid biomass component identification using RLM, an interlaboratory study (ILS) was conducted. The study involved the recognition of 58 components across 45 photomicrographs, with the participation of 65 scientists and students from 25 countries. The participants faced high difficulty identifying some of the marked components, and as a result, the percentage of correct answers ranged from 19.0 % to 98.3 %, with an average correct identification rate of 62.7 %. The most challenging aspects of the identification process included distinguishing between woody and non-woody (agro) biomass, accurately identifying petroleum-derived materials, and differentiating agro biomass from inorganic matter. The results suggest that while RLM is an important tool for characterizing solid biomass, further development of methodology guidelines and training are necessary to enhance its effectiveness. Future research should prioritize preparing detailed, image-rich, microscopic morphological descriptions of biomass fuel components, which could improve the accuracy and reliability of using RLM in biomass fuel characterization.

International Journal of Coal Geology↗

Waves, watersheds, and sediment in a coral reef embayment: Towards parsimonious models of accumulation and composition

High sedimentation rates can damage coral reef ecosystems. Sedimentation rates are controlled by both sediment loads from watersheds and resuspension by waves and associated circulation patterns, but the outcomes are system specific and difficult to predict. The percent terrigenous (non-organic and non-carbonaceous) material in sediment is also often used as an indicator of watershed influence, but its dynamics are poorly understood. Sediment accumulation rates, particle size, and percent terrigenous were monitored quasi-monthly for one year (March 2014-April 2015) at nine sites in a coral reef-fringed embayment in American Samoa, where an aggregate quarry had increased sediment loads to the coast but mitigation reduced loads during the monitored period. Gross and net sediment accumulation rates were measured using sediment traps and SedPods (pods), respectively. Gross accumulation rates exceeded thresholds for impacts on coral health during at least one collection period at most sites, with more exceedances on the northern reef where water residence times and sediment availability are higher and corals show signs of sediment stress. Percent terrigenous of coarse sediment was higher in the traps and pods compared with the surrounding benthic sediment, indicating that some of the terrigenous sediment was advected through the bay without accumulating on the reef. The 95th percentile of hourly wave energy density ( E 95 ) taken from a global wave model (WaveWatch 3) was the best predictor of gross accumulation rates of both total and carbonate sediment in a log-log regression at most ( n = 6) sites ( R 2 range 0.72-0.92), indicating a strong role of resuspension of benthic sediment. Gross accumulation rates of terrigenous sediment were not correlated with E 95 and only correlated with SSY at the site nearest the stream mouth, indicating that most terrigenous sediment was not from resuspended benthic material but rather from a consistent watershed source. Percent terrigenous decreased with increasing wave energy due to high accumulation rates of carbonates during periods of high wave energy. Detection of the impact of sediment mitigation at the quarry on sediment accumulation was complicated by low wave energy in the period following mitigation. The use of gross accumulation rates and percent terrigenous as indicators of the magnitude and sources of sediment accumulation over time needs to account for wave-induced resuspension, which can be modelled with a simple power function using inputs from a global wave model.

Estuarine, Coastal and Shelf Science↗